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1.
A high-resolution record of paleostorm events along the French Mediterranean coast over the past 7000 years was established from a lagoonal sediment core in the Gulf of Lions. Integrating grain size, faunal analysis, clay mineralogy and geochemistry data with a chronology derived from radiocarbon dating, we recorded seven periods of increased storm activity at 6300–6100, 5650–5400, 4400–4050, 3650–3200, 2800–2600, 1950–1400 and 400–50 cal yr BP (in the Little Ice Age). In contrast, our results show that the Medieval Climate Anomaly (1150–650 cal yr BP) was characterised by low storm activity.The evidence for high storm activity in the NW Mediterranean Sea is in agreement with the changes in coastal hydrodynamics observed over the Eastern North Atlantic and seems to correspond to Holocene cooling in the North Atlantic. Periods of low SSTs there may have led to a stronger meridional temperature gradient and a southward migration of the westerlies. We hypothesise that the increase in storm activity during Holocene cold events over the North Atlantic and Mediterranean regions was probably due to an increase in the thermal gradient that led to an enhanced lower tropospheric baroclinicity over a large Central Atlantic–European domain.  相似文献   

2.
At present, the climate in south-west Scandinavia is predominantly controlled by westerlies carrying moist Atlantic air, which forms a main source of precipitation in all seasons. Past variations in the ratio between precipitation and evaporation (effective precipitation) from terrestrial sites, however, may indicate changes in the degree of maritime influence. Palaeoclimatic archives in this region are thus ideally situated to study past changes in atmospheric circulation patterns. In this study, multi-proxy comparisons of records from three peat bogs and two lakes are used to reconstruct regional-scale variations of effective precipitation in south-west Sweden during the Late Holocene. The total aeolian sediment influx into two peat bogs is used as a proxy for storm activity. The frequency of storm phases increases strongly after ca 2500 cal yrs BP. Dry conditions occur on a regional scale around 4800–4400, 2000–1700, 1300–1000, 700–500 and 300–100 cal yrs BP. In addition, a comparison to winter precipitation reconstructed from four Norwegian glaciers shows similar variations during the past ca 2000 years. This indicates that the climate in both regions was controlled by large-scale atmospheric circulation dynamics of the North Atlantic region. The strong variability of effective precipitation and storm activity after ca 2500 cal yrs BP indicates a highly variable climate.  相似文献   

3.
《Atmósfera》2014,27(3):317-334
The Loop Current and its shed eddies dominate the circulation and dynamics of the Gulf of Mexico (GoM) basin. Those eddies are strongly energetic and are the cause of intense currents that may penetrate several hundred meters deep. However, there are regions in the GoM and periods of time in which the local atmospheric forcing plays an important role in its dynamics and thermodynamics. The circulation on the shelves, and particularly on the inner shelf, is mainly wind-driven with seasonality, changing direction during the year with periods of favorable upwelling/downwelling conditions. The wind-driven circulation is associated with the transport of waters with different temperature and salinity characteristics from one region to another. The interannual variability of the circulation on the shelves is linked to the atmospheric variability. Intraseasonal variability of the wind patterns considerably affects the likelihood and magnitude of upwelling and downwelling. The geometry of the GoM is such that large-scale winds may drive opposing upcoast/downcoast currents along different parts of the curving coast, resulting in convergence or divergence zones. The width of the shelves in the GoM is variable;while the West Florida Shelf, the Texas-Louisiana shelf and the Campeche Bank are more than 200 km wide, they are narrower near Veracruz and Tabasco. Another consequence of the GoM physiography and the wind forcing is the development of cross-shelf transports in the southern Bay of Campeche, the southern Texas shelf and southeast of the Mississippi river, which in turn vary during the year. During autumn-winter (from September to April), the GoM is affected by cold fronts coming from the northwest United States, which are associated with strong, dry, and cold winds that mix its waters and generate large sensible and latent heat fluxes from the ocean to the atmosphere. These frontal passages also cool the GoM surface waters due to mixing with lower temperature subsurface waters. During summer, tropical cyclones crossing the GoM can dramatically affect circulation and coastal upwelling.  相似文献   

4.
The study area lies between latitude 18–26°N and longitude 73–83°E, and mainly covers the Central India Tectonic Zone (CITZ). The frequency-dependent shear wave quality factor (Qs) has been estimated over the CITZ and its surroundings using Double Spectral Ratio (DSR) method. We have considered 25 local earthquakes with magnitude (ML) varies from 3.0 to 4.7 recorded at 11 stations running under national seismic network. The Fast Fourier Transformed (FFT) spectra were computed from the recorded waveform having time-window from onset of S-phase to 1.0 s and for a frequency-band of 0.1–10 Hz. Three different shear wave velocities (i.e., 3.87, 3.39 and 3.96 km/s) were obtained over the study area based on a pair of earthquakes recorded at a pair of stations. The low Qs values of 51–96 at 1 Hz (i.e., Qs = 51f0.49; Qs = 90f0.488 and Qs = 96f0.53) were found in the area covering the Son–Narmada–Tapti (SONATA) lineament, CITZ, eastern part of the Satpura fold belt, Vindhyan and Gondwana basins, Godavari and Mahanadi grabens, and southern part of Gangetic plain. Intermediate Qs values of the order of 204–277 (i.e., Qs = 204f0.56 and Qs = 277f0.55) were noted in the cartonic areas, namely, Bundelkhand, Dharwar-Bhandara and Bastar. While the higher Qs values of 391–628 at 1 Hz (i.e., Qs = 391f0.49, Qs = 409f0.48, Qs = 417f0.48, Qs = 500f0.66, Qs = 585f0.65 and Qs = 628f0.69) were found in the eastern part of the SONATA, CITZ, and the northeastern part of the Satpura fold belt. The low Qs values might be attributing to the more heterogeneous SONATA rift system. Low Qs values further may presumably be associated with lower-level of seismicity and apparently account for higher tectonic stress accumulation over long duration. The long-term accumulated stress is generally released through occasional triggering of moderate magnitude earthquakes in the SONATA zone. Surrounding the SONATA region, the higher Qs values possibly accounts for a more homogeneous subsurface structure along the SONATA zone.  相似文献   

5.
The radioactive isotope 36Cl, with a half-life of 301 ka, is a valuable chronometer for estimation of groundwater residence time up to 2 millions of years. Aerial thermonuclear fission bomb tests, performed during the late 1950s, injected a massive amount of this isotope into the atmosphere, which exceeded the natural fallout signal. Since this bomb pulse, atmospheric 36Cl deposition tends to return to natural fallout rate. The monitoring of this attenuation can provide a good opportunity to extend the use of this chronometer to shorter time spans. Venice’s lagoon alimentation zone shows groundwaters with residence times distributed over last fifty years. This permits the estimation of a continuous 36Cl deposition curve, free from latitudinal and seasonal variations of the signal. Three old groundwater samples, with residence times comprised in the range −900 to −8000 BP, allow the estimation of a mean natural deposition of 49 at m−2 s−1 and are in good agreement with 36Cl fallout observed for the last 40,000 years by (Plummer et al., 1997). For the bomb pulse period, a fallout of 5300 at m−2 s−1 was calculated. This was followed by a strong attenuation period, taking place until the 1980s, during which the fallout reached values ranging between 167 and 354 at m−2 s−1. The attenuation reached then a plateau: it experienced a slower lowering until the actual deposition, with fallout values calculated between 124 and 252 at m−2 s−1. This persistence of high deposition rate was classically attributed to biological and atmospherical recycling processes or underestimation of the natural atmospheric production of the 36Cl. Additional source of 36Cl production has been envisaged through the activation of chlorine radicals from stratospherical CFCs, leading to a 36Cl production rate comparable with that of Ar spallation from the first approximation. Lastly, the latitudinal factor of the attenuation of the fallout rate is discussed and the impact of the jet streams is proposed as an explanation for the discrepancies in the attenuation rate.  相似文献   

6.
《Applied Geochemistry》2005,20(10):1831-1847
The groundwater contribution into Green Lake and Black Lake (Vescovo Lakes Group), two cover collapse sinkholes in Pontina Plain (Central Italy), was estimated using water chemistry and a 222Rn budget. These data can constrain the interactions between sinkholes and deep seated fluid circulation, with a special focus on the possibility of the bedrock karst aquifer feeding the lake. The Rn budget accounted for all quantifiable surface and subsurface input and output fluxes including the flux across the sediment–water interface. The total value of groundwater discharge into Green Lake and Black Lake (∼540 ± 160 L s−1) obtained from the Rn budget is lower than, but comparable with historical data on the springs group discharge estimated in the same period of the year (800 ± 90 L s−1). Besides being an indirect test for the reliability of the Rn-budget “tool”, it confirms that both Green and Black Lake are effectively springs and not simply “water filled” sinkholes. New data on the water chemistry and the groundwater fluxes into the sinkhole area of Vescovo Lakes allows the assessment of the mechanism responsible for sinkhole formation in Pontina Plain and suggests the necessity of monitoring the changes of physical and chemical parameters of groundwater below the plain in order to mitigate the associated risk.  相似文献   

7.
2-D velocity structure up to the basement is derived by travel-time inversion of the first arrival seismic refraction and wide-angle reflection data along the SW–NE trending Jhagadia–Rajpipla profile, located on the western part of Deccan syneclise in the Narmada–Tapti region. The study region is mostly covered by alluvium. Inversion of refraction and wide-angle reflection data reveals four layered velocity structure above the basement. The first two layers with P-wave velocities of 1.95–2.3 km s?1 and 2.7–3.05 km s?1 represent the Recent and Quaternary sediments respectively. The thickness of these sediments varies from 0.15 km to 3.4 km. The third layer with a P-wave velocity of 4.8–5.1 km s?1 corresponds to the Deccan volcanics, whose thickness varies from 0.5 km to 1.0 km. Presence of a low velocity zone (LVZ) below the high velocity volcanic rocks in the study area is inferred from the travel-time ‘skip’ and amplitude decay of the first arrival refraction data and the wide-angle reflection from top of the LVZ present immediately after the first arrival refraction from Deccan Trap layer. The thickness of the low velocity Mesozoic sediments varies from 0.3 km to 1.7 km. The basement with a P-wave velocity of 5.9–6.15 km s?1 lies at a depth of 4.9 km near Jhagadia and shallows to 1.2 km towards northeast near Rajpipla. The results indicate presence of low velocity Mesozoic sediments hidden below the Deccan Trap layer in the western part of the Deccan syneclise.  相似文献   

8.
Major, trace element and isotopic (Sr, Nd, Pb) data and unspiked K–Ar ages are presented for Quaternary (0.90–0.95 Ma old) basalts from the Hayyabley volcano, Djibouti. These basalts are LREE-depleted (Lan/Smn = 0.76–0.83), with 87Sr/86Sr ratios ranging from 0.70369 to 0.70376, and rather homogeneous 143Nd/144Nd (εNd = + 5.9–+ 7.3) and Pb isotopic compositions (206Pb/204Pb = 18.47–18.55, 207Pb/204Pb = 15.52–15.57, 208Pb/204Pb = 38.62–38.77). They are very different from the underlying enriched Tadjoura Gulf basalts, and from the N-MORB erupted from the nascent oceanic ridges of the Red Sea and Gulf of Aden. Their compositions closely resemble those of (1) depleted Quaternary Manda Hararo basalts from the Afar depression in Ethiopia and (2) one Oligocene basalt from the Ethiopian Plateau trap series. Their trace element and Sr, Nd, Pb isotope systematics suggest the involvement of a discrete but minor LREE-depleted component, which is probably an intrinsic part of the Afar plume.  相似文献   

9.
Drip water, collected above three actively forming stalagmites, has been analyzed and the results discussed using a calcite saturation index versus equilibrium carbon dioxide partial pressure theoretical relationship. Percolating water appears to have been originated from a parent solution in equilibrium with a carbon dioxide rich gas phase having a minimum concentration varying between 15,000 ppmv and 26,000 ppmv while large part of the variability recorded in the cave can be explained by different stage of degassing. Similarly, analyses performed at several cave pools confirm that drip water rapidly achieves equilibrium with the cave atmosphere after impact on the stalagmite apex, while oversaturation is retained longer. Using these boundary conditions, the changes in inorganic carbon concentration in the percolating water have been calculated and converted into fluxes using an average effective infiltration flow estimated from the annual water balance.The predicted flux of carbon dioxide degassing from drip water is in the range of 0.03–0.06 μmol m−2 s−1. This flux has been found to be one of the major sources of carbon dioxide in the cave atmosphere during low ventilation periods.  相似文献   

10.
We calculated the quality factor, Qc, at frequencies from 6 to 24 Hz using coda waves of 97 aftershocks of the Petatlan, Mexico, earthquake (March 14, 1979; MS=7.6). The data were recorded parallel (between Acapulco and Playa Azul) and perpendicular (between Petatlan and Mexico City) to the coast. The results are the following: at 12 and 24 Hz there is no significant difference in the attenuation (Qc−1) along the two paths; at 6 Hz, Qc−1 has a large scatter in both directions. This observation indicates strong site effects at this frequency; average Qc−1 is slightly higher between Petatlan–Acapulco (toward SE) than between Petatlan–Playa Azul (toward NW); and at high frequencies, Qc−1 remains essentially constant perpendicular to the coast. These results show that the large seismic wave amplifications in Mexico City are caused by shallow site effects.  相似文献   

11.
《Quaternary Science Reviews》2007,26(1-2):115-129
The Gulf of California is a marginal seaway under the influence of a monsoon climate that produces cool, dry winters and warm, humid summers. Winds, tidal mixing and coastal-trapped waves forced by climate and the Pacific Ocean control nutrient advection and primary productivity (PP). Strong northwest winds from the subtropical East Pacific High Pressure system begin in November and last until April and drive coastal upwelling along the mainland margin, especially in the central and southern Gulf. In the northern Gulf, particularly around the midrift island, tidal mixing and turbulence occurs year round, advecting nutrients into the mixed layer and high productivity. During summer and early fall months, winds are variable, of less intensity and mainly blow cross-basin except in the most northern Gulf. Summer PP is generally low in the central and southern Gulf except along the mainland where coastal-trapped waves associated with tropical surges and hurricanes generate mixing over the continental shelf. Mesoscale eddies or gyres often associated with jets and filaments extend to depths of 1000 m and transport nutrient-enriched upwelled waters and plankton detritus across the Gulf. The largest and most persistent gyres rotate in an anti-cyclonic direction (east to west) and are a principal source of the plankton export to the peninsula margin.Two major biogenic sediment patterns are present in core-top sediments. Hemipelagic biosiliceous-rich muds are accumulating beneath upwelling areas of high productivity in the central Gulf and along the mainland margin. Calcium carbonate- and organic carbon-rich (OC) sediments are concentrated along the peninsula margin, generally beneath lower productivity waters with the highest OC content in areas with the lowest productivity. The high, uniform biosiliceous content in Guaymas basin, extending southward into Carmen basin reflects the redistribution by mesoscale gyres of phytoplankon debris produced in mainland coastal upwelling and tidally forced areas around the midrift islands.Holocene biogenic patterns are similar to the present day with the major difference in rates of accumulation. Phytoplankton production prior to about 8200 yr BP was significantly higher in the central and southern Gulf, decreased though the mid-Holocene and has been reasonably steady for the past 2500 yr. The strong north–south and east–west gradients in present-day phytoplankton productivity patterns are also reflected in the Holocene sediment record. A series of depositional cycles occur in the biogenic record with the strongest peaks of variability at about 150 (144±18), 200 (198±5) and 350 (350±40) yrs. Longer periodicities are present prior to 3200 yr BP but the 350 yr cycle dominates in the late Holocene where it is best expressed as productivity/dissolution cycles in the carbonate record.  相似文献   

12.
《Atmósfera》2014,27(1):77-89
Wind power density, vertical velocity profiles, and other wind characteristics were established using a 51 m meteorological mast located very close to the shoreline on the northwest of the Yucatan peninsula in the Gulf of Mexico. A comparative study of the wind power density was carried out using information obtained between September 2010 and September 2011. The wind speed probability density function was found to be bimodal due to sea-land breezes, a characteristic that becomes less evident as the vertical distance to the ground increases. The distinction between these two wind regimes was used to fit the Weibull-Weibull curve using a linear least-squares criterion in the parameters. In addition, numerical simulations from a mesoscale model are in close agreement with measurements above z = 50 m (z is the vertical distance to the ground). This result suggests that some mesoscale simulations may serve as a preliminary wind energy assessment tool in coastal zones with extended low-lying areas.  相似文献   

13.
The remains of former lakes show that in the past the Arabian Peninsula experienced much wetter conditions than today. The last of these humid periods dates to about 10 to 5.5 ka ago. The chronological framework for an earlier humid phase, radiocarbon dated to some 35–20 ka, is inconsistent with evidence from other records from the region. Possibly, these ages are significantly underestimating the true depositional age due to methodological problems. The earliest phase of dune accumulation known so far is dated to the penultimate glaciation maximum of the mid latitudes (ca. 150 ka). Subsequently, dune accumulation occurred around 110 ka, 65 ka and 20 ka ago. All these phases concur with rapid drops in global sea level that caused a drying out of the Persian Gulf basin and of the shelf of the Oman coast. In contrast to some previous interpretations, it is concluded here that aeolian deposition has been limited by sediment supply and not by preservation potential.  相似文献   

14.
Ten gravity springs from the slopes of the Biokovo Mt, Adriatic coast of Croatia were investigated. Three of them are included in the regional water supply system. The aim of this study was to investigate hydrogeological and geochemical characteristics of watershed, presenting one of the most typical karstic areas in the world.Hydrogeological investigations were performed during two seasons with dye tracing, using Na-fluoresceine which was poured into two pits, observing springs at distances of 1.82–8.8 km. Apparent velocities were 0.21–0.51 cm s?1. Dye tracing was first time partially effective and second time ineffective, what could be due to immanent ore mineralization, which presents a natural barrier and was discovered by geochemical and mineralogical methods.Concentrations of 17 dissolved and total trace elements were determined first time in groundwater samples. Their concentrations were extremely low, more than 3 orders of magnitude less than allowed by the Croatian directives for the first category of groundwater and drinking water. The mass fractions of 60 elements were determined in 3 representative spring sediments. Highest concentrations of some metals in sediments (mg kg?1) are: lead 5440, chromium 118, manganese 935, zinc 116 and barium 238. Origin of some elements and mineralogy is discussed.  相似文献   

15.
《Applied Geochemistry》2006,21(10):1733-1749
The Tinto and Odiel rivers are heavily affected by acid mine drainage (AMD). However, the exact quantities of contaminants transported into the Huelva estuary and the Gulf of Cadiz are unknown. The existing previous investigations are, in general, based on studies with few data or incorrect methodology, and are therefore unreliable. This study aims to present a reliable estimation of the dissolved contaminant load transported by both rivers for the periods 1995/96 to 2002/03. The methodology used is based principally on the correlation between contaminant concentration and flow rate. The results show that both rivers transport enormous quantities of dissolved contaminants: 7900 t a−1 of Fe, 5800 t a−1 Al, 3500 t a−1 Zn, 1700 t a−1 Cu, 1600 t yr−1 Mn and minor quantities of other metals. These values represent 60% of the global gross flux of dissolved Zn transported by rivers in to the ocean, and 17% of the global gross flux of dissolved Cu.  相似文献   

16.
In the Patía River delta, the best-developed delta on the western margin of South America, a major water diversion started in 1972. The diversion of the Patía flow to the Sanquianga River, the latter a small stream draining internal lakes from the Pacific lowlands, shifted the active delta plain from the south to the north and changed the northern estuarine system into an active delta plain. The Sanquianga Mangrove National Park, a mangrove reserve measuring 800 km2, lies in this former estuary, where major hydrologic and sedimentation changes are occurring. Overall, major environmental consequences of this discharge diversion in terms of geomorphic changes along distributary channels and ecological impacts on mangrove ecosystems are evidenced by: (1) distributary channel accretion by operating processes such as sedimentation, overbank flow, increasing width of levees, sedimentation in crevasses, interdistributary channel fill, and colonization of pioneer mangrove; (2) freshening conditions in the Sanquianga distributary channel, a hydrologic change that has shifted the upper estuarine region (salinity <1%) downstream; (3) downstream advance of freshwater vegetation, which is invading channel banks in the lower and mixing estuarine zones; (4) die-off of approximately 5200 ha of mangrove near the delta apex at Bocas de Satinga, where the highest sediment accumulation rates occur; and (5) recurrent periods of mangrove defoliation due to a worm plague. Further analyses indicate strong mangrove erosion along transgressive barrier islands on the former delta plain. Here tectonic-induced subsidence, relative sea-level rise, and sediment starving conditions due to the channel diversion, are the main causes of the observed retreating conditions of mangrove communities. Our data also indicate that the Patía River has the highest sediment load (27 × 106 t yr−1) and basin-wide sediment yield (1500 t km−2 yr−1) on the west coast of South America. Erosion rates from the Patía catchment have been more pronounced during the decades of 1970–1980 and 1990–2000, as a result of land degradation and deforestation. The high sediment and freshwater inputs into the mangrove ecosystem create additional stress (both at ongoing background levels and, occasionally, at dramatic levels), which may periodically push local environmental parameters beyond the thresholds for mangrove survival. The future environmental state of the Sanquianga Mangrove National Reserve deserves more scientific and governmental attention.  相似文献   

17.
Hurricane Frances is shown to greatly alter the hydrodynamics within Tampa Bay, Florida, and the exchange of water with the Gulf of Mexico in both observational data and a realistic numerical circulation model of the Tampa Bay estuary. Hurricane Frances hit Tampa Bay on September 5, 2004 with surface winds peaking twice near 22 m s−1. There were three stages to the hydrodynamic effect of Frances on Tampa Bay. The first stage included the approach of Frances up to the first wind peak. The winds were to the south and southeast. During this stage sea level was maintained below mean sea level (MSL) and the residual current (demeaned, detided) was weak. The second stage began as the winds turned to the east and northeast, as the eye passed near the bay, and ended as the second wind peak appeared. During this stage the residual currents were strongly positive (into the bay), raising sea level to 1.2 m above MSL at St. Petersburg. The measured residual circulation peaked at over +0.7 m s−1 near the surface. The model shows this velocity peak yielded a maximum volume flux into the bay of +44,227 m3 s−1, displacing a total volume of 1.5 billion m3 in just a few hours, about 42% of the bay volume. In the third stage a strong negative flow developed as the wind and sea level relaxed to near normal levels. The ADCP measured a peak outflow of −0.8 m s−1 during this time. Model results indicate a maximum flux of −37,575 m3 s−1, and that it took about 50 h to drain the extra volume driven into the bay by Hurricane Frances.  相似文献   

18.
《Sedimentary Geology》2006,183(3-4):159-179
In the macrotidal Severn estuary, UK, the dynamics of intertidal fine-gravel dunes were investigated. These dunes are migrating across a bedrock platform. Systematic observations were made of hydraulic climate, geometry, migration rates and internal sedimentary structures of the dunes. During spring tides, the ebb flow is dominant, dunes grow in height and have ebb orientated geometry with bedrock floors in the troughs. During neap tides, a weak flood flow may dominate. Dunes then are flood orientated or symmetrical. Neap dune heights decrease and the eroded sediment is stored in the dune troughs where the bedrock becomes blanketed by muddy gravel. During spring tides, instantaneous bed shear stresses reach 8 N m− 2, sufficient to disrupt a 9 mm-gravel armour layer. However, a sustained bed shear stress of 4 N m− 2 is required to initiate dune migration at which time the critical depth-mean velocity is 1 m s− 1. Ebb and flood inequalities in the bed shear stress explain the changes in dune asymmetry and internal structures. During flood tides, the crests of the dunes reverse such that very mobile sedimentary ‘caps’ overlie a more stable dune ‘core’. Because ebb tides dominate, internal structures of the caps often are characterised by ebb orientated steep open-work foresets developed by strong tidal currents and some lower angle crossbeds deposited as weaker currents degrade foresets. The foresets forming the caps may be grouped into cosets (tidal bundles) and are separated from mud-infused cores of crossbeds that lie below, by reactivation and erosion surfaces blanketed by discontinuous mud drapes. The cores often exhibit distinctive muddy toe sets that define the spacing of tidal cosets.  相似文献   

19.
We report the structure of a novel sunscreen based on the scytoneman skeleton. This pigment, scytonemin-3a-imine, was isolated from cultures of the cyanobacterium, Scytonema hoffmani, only when grown under high to intense (300–1500+ μmol quanta m−2 s−1) light conditions, with or without added UVR (ultraviolet radiation). It was also isolated from samples of natural cyanobacterial mats growing in shallow/short hydroperiod fresh water (Florida Everglades), soils (Loxahatchee, Florida) and saline cyanobacterial mats (Eleuthera, The Bahamas). These natural samples were all growing under intense (e.g. > 1500 μmol quanta m−2 s−1) light conditions. Scytonemin-3a-imine may eventually become a biomarker for such biota.Characterization included UV/Vis spectrophotometry, Fourier transform infrared (FTIR) spectroscopy, matrix assisted laser desorption ionization (MALDI) and electrospray ionization (ESI) mass spectrometry (MS and MSn), and both 1- and 2-D 1H nuclear magnetic resonance (NMR) spectrometry. Derivatization (NaBH4 reduction, acetylation, deuterium exchange) were utilized to confirm structural features. The UV/Vis spectrum had maxima at 237, 366, 437 and 564 nm. The absorption of UVR is in line with other scytoneman-based pigments. The strong visible absorption bands (437 and 564 nm) indicate an alternate or additional physiological role for the pigment. We propose that it may protect both the chlorophyll reaction centers and the cytochromes from excess radiation. We speculate that excitation of the cytochromes, potentially leading to excess electron transport, or photo-oxidative destruction of the cytochromes, may enhance reactive oxygen species (ROS) generation.  相似文献   

20.
《Quaternary Science Reviews》2007,26(1-2):130-141
Analyses of sediment cores from Marcella Lake, a small, hydrologically closed lake in the semi-arid southwest Yukon, provides effective moisture information for the last ∼4500 years at century-scale resolution. Water chemistry and oxygen isotope analyses from lakes and precipitation in the region indicate that Marcella Lake is currently enriched in 18O by summer evaporation. Past lake water values are inferred from oxygen isotope analyses of sedimentary endogenic carbonate in the form of algal Charophyte stem encrustations. A record of the δ18O composition of mean annual precipitation at Jellybean Lake, a nearby evaporation-insensitive system, provides data of simultaneous δ18O variations related to decade-to-century scale shifts in Aleutian Low intensity/position. The difference between the two isotope records, Δδ, represents 18O-enrichment in Marcella Lake water caused by summer effective moisture conditions. Results indicate increased effective moisture between ∼3000 and 1200 cal BP and two marked shifts toward increased aridity at ∼1200 and between 300 and 200 cal BP. These prominent late Holocene changes in effective moisture occurred simultaneously with changes in Aleutian Low circulation patterns over the Gulf of Alaska indicated by Jellybean Lake. The reconstructed climate patterns are consistent with the topographically controlled climatic heterogeneity observed in the coastal mountains and interior valleys of the region today.  相似文献   

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