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1.
The number of sinkholes (locally known as obruks) has increased rapidly in recent years near Karap?nar, located in the semi-arid Konya Closed Basin in Central Anatolia. Nineteen sinkholes have formed in the last 33 years (1977–2009) as a result of the collapse of cavity roofs in the Neogene lacustrine limestone in the Obruk Plateau and beneath Quaternary lake sediments in the Karap?nar-Hotam?? Plain. Of these, 13 have formed within the past 4 years (2006–2009). The Obruk Plateau takes its name from the presence of several hundred paleo-sinkholes which formed as a result of natural processes during the Quaternary period. More recently, human activity has induced the formation of new sinkholes, which presents a hazard to life and property. Changing agricultural patterns have led to the opening of thousands of deep wells in recent years, and increased water pumping currently exceeds the sustainable yield of the aquifer. Thus the formation of sinkholes has been triggered by a combination of natural and human causes. The groundwater level has dropped almost 24 m in the vicinity of Karap?nar during the last 26 years (1983–2008). Approximately 8 m of this drop occurred within the 4 years prior to the study (2005–2008). Legally-binding precautions must be taken to prevent further water table decline, in order to decrease sinkhole formation within the basin in the years to come. 相似文献
2.
River water infiltration into an unconfined porous aquifer (∼73% gravels, ∼12% sands, ∼15% silts and clays) in the Petrignano d’Assisi plain, central Italy, was traced combining isotopic techniques (222Rn) with hydrochemical and hydrogeologic techniques in order to characterize the system under study. The 222Rn gave information about the river water residence times within the aquifer and hydrochemical data, in a two-component mixing model, which allowed estimating the extent of mixing between surface waters and groundwater in wells at increasing distances from the river. The mixing measured in the well closer to the riverbank indicated a higher contribution of river water (up to 99%) during the groundwater recession phase and a moderate contribution (up to 64%) during the recharge phase. A model describing 222Rn concentrations in groundwater as the result of both parent/daughter nuclide equilibrium and mixing process (222Rn mixing/saturation model) was used to describe observed Rn concentrations and mixing index trends with the aim of evaluating water mean infiltration velocities along the transect. The stream bank infiltration velocities obtained by the model ranged from 1 m day−1 during groundwater recharge periods, when river water infiltration is lower, to 39 m day−1 during recession phases, when river water infiltration is larger. 相似文献
3.
The Aral Sea has been shrinking since 1963 due to extensive irrigation and the corresponding decline in the river water inflow. Understanding of the current hydrological situation demands an improved understanding of the surface water/groundwater dynamics in the region. 222Rn and 226Ra measurements can be used to trace groundwater discharge into surface waters. Data of these radiometric parameters were not previously available for the study region. We determined 222Rn activities after liquid phase extraction using Liquid Scintillation Counting (LSC) with peak-length discrimination and analyzed 226Ra concentrations in different water compartments of the Amu Darya Delta (surface waters, unconfined groundwater, artesian water, and water profiles from the closed Large Aral Sea (western basin).The water samples comprise a salinity range between 1 and 263 g/l. The seasonal dynamics of solid/water interaction under an arid climate regime force the hydrochemical evolution of the unconfined groundwater in the Amu Darya Delta to high-salinity Na(Mg)Cl(SO4) water types. The dissolved radium concentrations in the waters were mostly very low due to mineral over-saturation, extensive co-precipitation of radium and adsorption of radium on coexisting solid substrates.The analysis of very low 226Ra concentrations (<10 ppq) at remote study sites is a challenge. We used the water samples to test and improve different analytical methods. In particular, we modified a procedure developed for the α-spectrometric determination of 226Ra after solid phase extraction of radium using 3M Empore™ High Performance Extraction Disks (Purkl, 2002) for the analysis of the radionuclide using an ICP sector field mass spectrometer. The 226Ra concentration of 17 unconfined groundwater samples ranged between 0.2 and 5 ppq, and that of 28 artesian waters between <0.2 and 13 ppq. The ICP-MS results conformed satisfactorily to analytical results based on γ-measurements of the 222Rn ingrowth after purging and trapping on super-cooled charcoal. The 226Ra concentrations were positively correlated with the salinity and the dissolved NaCl concentrations. The occurrence of unusually high 226Ra activities is explained by radium release from adsorption sites with increasing salinity. The inferred spatial variability of 222Rn in the Aral Sea and of 222Rn and 226Ra in the groundwater of the Amu Darya Delta is discussed in the context of our own previous hydrochemical studies in the study sites. Relatively low 222Rn activities in the unconfined GW (1–9.5 Bq/l) indicate the alluvial sediments hosting the GW to be a low-238U(226Ra) substrate. Positive correlations between U and 226Ra, and U and 222Rn are likely related to locally deposited Fe(Mn)OOH precipitates. The 222Rn activity of the GW, however, distinctly exceeds the 222Rn concentration in the Aral Sea (10 mBq/l), in principle, making 222Rn a sensitive tracer for the inflow of GW. The high water volume of the Large Aral Sea and wind induced mixing of its water body, however, hamper the detection of local groundwater inflow. 相似文献
4.
《Applied Geochemistry》2006,21(7):1169-1183
The Cornia Plain alluvial aquifer, in Tuscany, is exploited intensely to meet the demand for domestic, irrigation and industrial water supplies. The B concentration of groundwater, however, is often above the European limit of 1 mg L−1, with the result that exploitation of these water resources requires careful management. Boron and Sr isotopes have been used as part of a study on the origin and distribution of B dissolved in groundwater, and indirectly as a contribution to the development of appropriate water management strategies.The geochemistry of the Cornia Plain groundwater changes from a HCO3 facies in the inland areas to a Cl facies along the coastal belt, where seawater intrusion takes place. The B concentration of groundwater increases towards the coastal areas, while the 11B/10B ratio decreases. This indicates that there is an increasing interaction between dissolved B and the sediments forming the aquifer matrix, whose B content is in the order of 100 mg kg−1. Adsorption–desorption exchanges take place between water and the sediment fine fraction rich in clay minerals, with a net release of B from the matrix into the groundwater, and a consequent δ11B shift from positive to negative values. The aquifer matrix sediments therefore seem to be the major source of B dissolved in the groundwater.The groundwater–matrix interactions triggered by the ionic strength increase caused by seawater intrusion can also be detected in the Ca–Na ion exchanges. Dissolved Sr follows a trend similar to that of Ca, while the 87Sr/86Sr ratio is equal to that of the exchangeable Sr of the aquifer matrix and therefore does not change significantly.These results have helped to define a new strategy for groundwater exploitation, with the final objective of reducing B concentration in the water extracted from the aquifer. 相似文献
5.
《Applied Geochemistry》2006,21(11):1868-1879
Ultra-clean sampling methods and approaches typically used in pristine environments were applied to quantify concentrations of Hg species in water and microbial biomass from hot springs of Yellowstone National Park, features that are geologically enriched with Hg. Microbial populations of chemically-diverse hot springs were also characterized using modern methods in molecular biology as the initial step toward ongoing work linking Hg speciation with microbial processes. Molecular methods (amplification of environmental DNA using 16S rDNA primers, cloning, denatured gradient gel electrophoresis (DGGE) screening of clone libraries, and sequencing of representative clones) were used to examine the dominant members of microbial communities in hot springs. Total Hg (THg), monomethylated Hg (MeHg), pH, temperature, and other parameters influential to Hg speciation and microbial ecology are reported for hot springs water and associated microbial mats.Several hot springs indicate the presence of MeHg in microbial mats with concentrations ranging from 1 to 10 ng g−1 (dry weight). Concentrations of THg in mats ranged from 4.9 to 120,000 ng g−1 (dry weight). Combined data from surveys of geothermal water, lakes, and streams show that aqueous THg concentrations range from l to 600 ng L−1. Species and concentrations of THg in mats and water vary significantly between hot springs, as do the microorganisms found at each site. 相似文献
6.
Green Lake Landslide is an ancient giant rock slide in gneiss and granodiorite located in the deeply glaciated Fiordland region of New Zealand. The landslide covers an area of 45 km2 and has a volume of about 27 km3. It is believed to be New Zealand's largest landslide, and possibly the largest landslide of its type on Earth. It is one of 39 known very large (106–107 m3) and giant (≥108 m3) postglacial landslides in Fiordland discussed in the paper. Green Lake Landslide resulted in the collapse of a 9 km segment of the southern Hunter Mountains. Slide debris moved up to 2.5 km laterally and 700 m vertically, and formed a landslide dam about 800 m high, impounding a lake about 11 km long that was eventually infilled with sediments. Geomorphic evidence supported by radiocarbon dating indicates that Green Lake Landslide probably occurred 12 000–13 000 years ago, near the end of the last (Otira) glaciation. The landslide is described, and its geomorphic significance, age, failure mechanism, cause, and relevance in the region are discussed, in relation to other large landslides and recent earthquake-induced landslides in Fiordland. The slope failure occurred on a low-angle fault zone undercut by glacial erosion, and was probably triggered by strong shaking (MM IX–X) associated with a large (≥ M 7.5–8) earthquake, on the Alpine Fault c. 80 km to the northwest. Geology was a major factor that controlled the style and size of Green Lake landslide, and in that respect it is significantly different from most other gigantic landslides. Future large earthquakes on the Alpine Fault in Fiordland are likely to trigger more very large and giant landslides across the region, causing ground damage and devastation on a scale that has not occurred during the last 160 years, with potentially disastrous effects on towns, tourist centres, roads, and infrastructure. The probability of such an event occurring within the next 50 years may be as high as 45%. 相似文献
7.
Extensive coastal dunes occur in the Great Lakes region of North America, including northwestern Michigan where some are perched on high (~ 100 m) bluffs. This study focuses on such a system at Arcadia Dunes and is the first to systematically generate optical ages from stratigraphic sections containing buried soils. Dune growth began ca. 4.5 ka during the Nipissing high lake stand and continued episodically thereafter, with periods of increased sand supply at ca. 3.5 ka and ca. 1.7 ka. The most volumetrically dominant phase of dune growth began ca. 1.0 ka and continued intermittently for about 500 years. It may have begun due to the combined effects of a high lake phase, potential changes in lake hydrodynamics with final isostatic separation of Lake Superior from Lakes Michigan and Huron, and increased drought and hydrologic variability associated with the Medieval Warm Period. Thus, this latest eolian phase likely reflects multiple processes associated with Great Lakes water level and climate variability that may also explain older eolian depositional events. Comparison of Arcadia ages and calendar corrected 14C ages from previous studies indicate broad chronological agreement between events at all sites, although it appears that dune growth began later at Arcadia. 相似文献
8.
Natalija Matić Krešimir Maldini Vlado Cuculić Stanislav Frančišković-Bilinski 《Chemie der Erde / Geochemistry》2012,72(2):179-190
Ten gravity springs from the slopes of the Biokovo Mt, Adriatic coast of Croatia were investigated. Three of them are included in the regional water supply system. The aim of this study was to investigate hydrogeological and geochemical characteristics of watershed, presenting one of the most typical karstic areas in the world.Hydrogeological investigations were performed during two seasons with dye tracing, using Na-fluoresceine which was poured into two pits, observing springs at distances of 1.82–8.8 km. Apparent velocities were 0.21–0.51 cm s?1. Dye tracing was first time partially effective and second time ineffective, what could be due to immanent ore mineralization, which presents a natural barrier and was discovered by geochemical and mineralogical methods.Concentrations of 17 dissolved and total trace elements were determined first time in groundwater samples. Their concentrations were extremely low, more than 3 orders of magnitude less than allowed by the Croatian directives for the first category of groundwater and drinking water. The mass fractions of 60 elements were determined in 3 representative spring sediments. Highest concentrations of some metals in sediments (mg kg?1) are: lead 5440, chromium 118, manganese 935, zinc 116 and barium 238. Origin of some elements and mineralogy is discussed. 相似文献
9.
《Applied Geochemistry》2006,21(10):1799-1817
Release of acid drainage from mine-waste disposal areas is a problem of international scale. Contaminated surface water, derived from mine wastes, orginates both as direct surface runoff and, indirectly, as subsurface groundwater flow. At Camp Lake, a small Canadian Shield lake that is in northern Manitoba and is ice-covered 6 months of the year, direct and indirect release of drainage from an adjacent sulfide-rich tailings impoundment has severely affected the quality of the lake water. Concentrations of the products from sulfide oxidation are extremely high in the pore waters of the tailings impoundment. Groundwater and surface water derived from the impoundment discharge into a semi-isolated shallow bay in Camp Lake. The incorporation of this aqueous effluent has altered the composition of the lake water, which in turn has modified the physical limnology of the lake. Geochemical profiles of the water column indicate that, despite its shallow depth (6 m), the bay is stratified throughout the year. The greatest accumulation of dissolved metals and SO4 is in the lower portion of the water column, with concentrations up to 8500 mg L−1 Fe, 20,000 mg L−1 SO4, 30 mg L−1 Zn, 100 mg L−1 Al, and elevated concentrations of Cu, Cd, Pb and Ni. Meromictic conditions and very high solute concentrations are limited to the bay. Outside the bay, solute concentrations are lower and some stratification of the water column exists. Identification of locations and composition of groundwater discharge relative to lake bathymetry is a fundamental aspect of understanding chemical evolution and physical stability of mine-impacted lakes. 相似文献
10.
《Quaternary Science Reviews》2007,26(11-12):1638-1649
Surface-exposure (10Be) ages have been obtained on boulders from three post-Pinedale end-moraine complexes in the Front Range, Colorado. Boulder rounding appears related to the cirque-to-moraine transport distance at each site with subrounded boulders being typical of the 2-km-long Chicago Lakes Glacier, subangular boulders being typical of the 1-km-long Butler Gulch Glacier, and angular boulders being typical of the few-hundred-m-long Isabelle Glacier. Surface-exposure ages of angular boulders from the Isabelle Glacier moraine, which formed during the Little Ice Age (LIA) according to previous lichenometric dating, indicate cosmogenic inheritance values ranging from 0 to ∼3.0 10Be ka.1 Subangular boulders from the Butler Gulch end moraine yielded surface-exposure ages ranging from 5 to 10.2 10Be ka. We suggest that this moraine was deposited during the 8.2 cal ka event, which has been associated with outburst floods from Lake Agassiz and Lake Ojibway, and that the large age range associated with the Butler Gulch end moraine is caused by cosmogenic shielding of and(or) spalling from boulders that have ages in the younger part of the range and by cosmogenic inheritance in boulders that have ages in the older part of the range. The surface-exposure ages of eight of nine subrounded boulders from the Chicago Lakes area fall within the 13.0–11.7 10Be ka age range, and appear to have been deposited during the Younger Dryas interval. The general lack of inheritance in the eight samples probably stems from the fact that only a few thousand years intervened between the retreat of the Pinedale glacier and the advance of the Chicago Lakes glacier; in addition, bedrock in the Chicago Lakes cirque area may have remained covered with snow and ice during that interval, thus partially shielding the bedrock from cosmogenic radiation. 相似文献
11.
《Applied Geochemistry》2006,21(2):289-304
Mineral springs from Daylesford, Australia discharge at ambient temperatures, have high CO2 contents, and effervesce naturally. Mineral waters have high HCO3 and Na concentrations (up to 4110 and 750 mg/L, respectively) and CO2 concentrations of 620–2520 mg/L. Calcium and Mg concentrations are 61–250 and 44–215 mg/L, respectively, and Si, Sr, Ba, and Li are the most abundant minor and trace elements. The high PCO2 of these waters promotes mineral dissolution, while maintaining low pH values, and geochemical modelling indicates that the CO2-rich mineral water must have interacted with both sediments and basalts. Amorphous silica concentrations and silica geothermometry indicate that these waters are unlikely to have been heated above ambient temperatures and therefore reflect shallow circulation on the order of several hundreds of metres. Variations in minor and trace element composition from closely adjacent spring discharges indicate that groundwater flows within relatively isolated fracture networks. The chemical consistency of individual spring discharges over at least 20 a indicates that flow within these fracture networks has remained isolated over long periods. The mineral water resource is at risk from mixing with potentially contaminated surface water and shallow groundwater in the discharge areas. Increased δ2H values and Cl concentrations, and lower Na concentrations indicate those springs that are most at risk from surface contamination and overpumping. Elevated NO3 concentrations in a few springs indicate that these springs have already been contaminated during discharge. 相似文献
12.
Evidence of precursor phenomena in the Kobe earthquake obtained from atmospheric radon concentration
《Applied Geochemistry》2006,21(6):1064-1072
Atmospheric 222Rn concentrations were determined over a 10a period, which included the date of the Kobe, Japan earthquake, on January 17th 1995. It was found that the seismically related 222Rn anomaly was higher than the 99% confidence limits for the residual value of atmospheric 222Rn which had been observed 2 months before. The residual 222Rn concentration, in which residual values of the daily minimum are the difference between each normal 222Rn concentration (calculated from January 1984 to December 1993) and the daily minimum 222Rn concentration (January 1994 to January 1995), was calculated by applying the exponential smoothing method to the residual values for each day. It was found that the fluctuations of the residual values can be fitted very well to a log-periodic oscillation model. The real residual values stopped increasing at 1994.999 (December 31st 1994), which corresponds with the critical point (tc) of best fit model. This anomalous 222Rn variation can be seen as the result of local stresses, not primary stresses which directly lead to the Kobe earthquake. On the other hand, when the critical exponent (z) and the radial frequency (ω) of the model were simultaneously fixed 0.2 ⩽ z ⩽ 0.6 and 6 ⩽ ω ⩽ 12, tc (critical point) was between January 13th 1995 and January 27th 1995. The Kobe earthquake occurrence date (January 17th 1995) is within this range. Therefore this anomalous 222Rn variation can also be seen as the result of primary stresses which possibly led to the Kobe earthquake. There is a distinct possibility that similar statistical oscillations will be detected in other measurements such as microseismicity, tectonic strain, fluctuation in the ground level, or changes in groundwater elevations and composition. 相似文献
13.
《Quaternary Science Reviews》2005,24(12-13):1463-1478
The aragonite mineralogy and geochemistry of the mollusc faunas preserved at Navan and Bearbrook, Ontario, serve as proxies of original seawater chemistry. The composite section spanning 12,980–10,980 cal yr BP includes the Younger Dryas (YD) paleoclimatic oscillation. Oxygen isotopes demonstrate the onset of cooling with the YD event, in addition to the lowering of marine values by the influx of isotopically light glacial meltwater from Lake Agassiz. Impact of cooling and dilution is reduced or eliminated with the start of the Holocene, when water temperatures and salinities for Champlain Sea (CS) seawater were 8–16 °C and 27–34 ppt, respectively. Overall, oxygen isotope values deceased to −3.5% during the YD mainly due to freshening by glacial meltwater. Carbon isotopes confirm the rise in atmospheric CO2 concentration at the YD–Holocene transition. Marine strontium isotope values for the Allerød–YD–earliest Holocene range from 0.709151 (16,210 cal yr BP) to 0.709145 (12,980 cal yr BP) and 0.709142 (10,950 cal yr BP). The oceanographic changes recorded for the CS are in agreement with the evolutionary phases of Lake Agassiz and deglaciation dynamics of the Laurentide Ice Sheet. The volume and direction of meltwater discharge from Lake Agassiz alternated between the Gulf of Mexico during the Allerød, via the Great Lakes through the CS to the North Atlantic during the YD, and back to the Gulf of Mexico during the early Holocene, but with diminished impact. 相似文献
14.
《Applied Geochemistry》2005,20(1):55-68
In 49 samples of groundwater, sampled in Muzaffargarh District of south-western Punjab, central Pakistan, concentrations of As exceeded the World Health Organisation provisional guideline value, and United States Environmental Protection Agency (USEPA) Maximum Contaminant Level (MCL), of 10 μg L−1 in 58% of samples and reached up to 906 μg L−1. In this semi-arid region canal irrigation has lead to widespread water-logging, and evaporative concentration of salts has the potential to raise As concentrations in shallow groundwater well above 10 μg L−1. In fact, in rural areas, concentrations stay below 25 μg L−1 because As in the oxic shallow groundwater, and in recharging water, is sorbed to aquifer sediments. In some urban areas, however, shallow groundwater is found to contain elevated levels of As. The spatial distribution of As-rich shallow groundwater indicates either direct contamination with industrial or agricultural chemicals, or some other anthropogenic influence. Geochemical evidence suggests that pollutant organics from unconfined sewage and other sources drives reduction of hydrous ferric oxide (HFO) releasing sorbed As to shallow groundwater. The situation is slightly less clear for seven wells sampled which tap deeper groundwater, all of which were found with >50 μg L−1 As. Here As concentrations seem to increase with depth and differing geochemical signatures are seen, suggesting that As concentrations in older groundwater may be governed by different processes. Other data on parameters of potential concern in drinking water are discussed briefly at the end of the paper. 相似文献
15.
Exploration of unconventional natural gas reservoirs such as impermeable shale basins through the use of horizontal drilling and hydraulic fracturing has changed the energy landscape in the USA providing a vast new energy source. The accelerated production of natural gas has triggered a debate concerning the safety and possible environmental impacts of these operations. This study investigates one of the critical aspects of the environmental effects; the possible degradation of water quality in shallow aquifers overlying producing shale formations. The geochemistry of domestic groundwater wells was investigated in aquifers overlying the Fayetteville Shale in north-central Arkansas, where approximately 4000 wells have been drilled since 2004 to extract unconventional natural gas. Monitoring was performed on 127 drinking water wells and the geochemistry of major ions, trace metals, CH4 gas content and its C isotopes (δ13CCH4), and select isotope tracers (δ11B, 87Sr/86Sr, δ2H, δ18O, δ13CDIC) compared to the composition of flowback-water samples directly from Fayetteville Shale gas wells. Dissolved CH4 was detected in 63% of the drinking-water wells (32 of 51 samples), but only six wells exceeded concentrations of 0.5 mg CH4/L. The δ13CCH4 of dissolved CH4 ranged from −42.3‰ to −74.7‰, with the most negative values characteristic of a biogenic source also associated with the highest observed CH4 concentrations, with a possible minor contribution of trace amounts of thermogenic CH4. The majority of these values are distinct from the reported thermogenic composition of the Fayetteville Shale gas (δ13CCH4 = −35.4‰ to −41.9‰). Based on major element chemistry, four shallow groundwater types were identified: (1) low (<100 mg/L) total dissolved solids (TDS), (2) TDS > 100 mg/L and Ca–HCO3 dominated, (3) TDS > 100 mg/L and Na–HCO3 dominated, and (4) slightly saline groundwater with TDS > 100 mg/L and Cl > 20 mg/L with elevated Br/Cl ratios (>0.001). The Sr (87Sr/86Sr = 0.7097–0.7166), C (δ13CDIC = −21.3‰ to −4.7‰), and B (δ11B = 3.9–32.9‰) isotopes clearly reflect water–rock interactions within the aquifer rocks, while the stable O and H isotopic composition mimics the local meteoric water composition. Overall, there was a geochemical gradient from low-mineralized recharge water to more evolved Ca–HCO3, and higher-mineralized Na–HCO3 composition generated by a combination of carbonate dissolution, silicate weathering, and reverse base-exchange reactions. The chemical and isotopic compositions of the bulk shallow groundwater samples were distinct from the Na–Cl type Fayetteville flowback/produced waters (TDS ∼10,000–20,000 mg/L). Yet, the high Br/Cl variations in a small subset of saline shallow groundwater suggest that they were derived from dilution of saline water similar to the brine in the Fayetteville Shale. Nonetheless, no spatial relationship was found between CH4 and salinity occurrences in shallow drinking water wells with proximity to shale-gas drilling sites. The integration of multiple geochemical and isotopic proxies shows no direct evidence of contamination in shallow drinking-water aquifers associated with natural gas extraction from the Fayetteville Shale. 相似文献
16.
Yannick Garcin Annett Junginger Daniel Melnick Daniel O. Olago Manfred R. Strecker Martin H. Trauth 《Quaternary Science Reviews》2009,28(9-10):911-925
The Late Pleistocene to Middle Holocene African Humid Period (AHP) was characterized by dramatic hydrologic fluctuations in the tropics. A better knowledge of the timing, spatial extent, and magnitude of these hydrological fluctuations is essential to decipher the climate-forcing mechanisms that controlled them. The Suguta Valley (2°N, northern Kenya Rift) has recorded extreme environmental changes during the AHP. Extensive outcrops of lacustrine sediments, ubiquitous wave-cut notches, shorelines, and broad terrace treads along the valley margins are the vestiges of Lake Suguta, which once filled an 80 km long and 20 km wide volcano–tectonic depression. Lake Suguta was deep between 16.5 and 8.5 cal ka BP. During its maximum highstand, it attained a water depth of ca 300 m, a surface area of ca 2150 km2, and a volume of ca 390 km3. The spatial distribution of lake sediments, the elevation of palaeo-shorelines, and other geomorphic evidences suggest that palaeo-Lake Suguta had an overflow towards the Turkana basin to the north. After 8.5 cal ka BP, Lake Suguta abruptly disappeared. A comparison of the Lake Suguta water-level curve with other reconstructed water levels from the northern part of the East African Rift System shows that local insolation, which is dominated by precessional cycles, may have controlled the timing of lake highstands in this region. Our data show that changes of lake levels close to the Equator seem to be driven by fluctuations of spring insolation, while fluctuations north of the Equator are apparently related to variations in summer insolation. However, since these inferred timings of lake-level changes are mostly based on the radiocarbon dating of carbonate shells, which may have been affected by a local age reservoir, alternative dating methods are needed to support this regional synthesis. Between 12.7 and 11.8 cal ka BP, approximately during the Northern Hemisphere high-latitude Younger Dryas, the water level of Lake Suguta fell by ca 50 m, suggesting that remote influences also affected local hydrology. 相似文献
17.
This paper investigated the sources and behaviors of sulfate in groundwater of the western North China Plain using sulfur and oxygen isotopic ratios. The groundwaters can be categorized into karst groundwater (KGW), coal mine drainage (CMD) and pore water (subsurface saturated water in interstices of unconsolidated sediment). Pore water in alluvial plain sediments could be further classified into unconfined groundwater (UGW) with depth of less than 30 m and confined groundwater (CGW) with depth of more than 60 m. The isotopic compositions of KGW varied from 9.3‰ to 11.3‰ for δ34SSO4 with the median value of 10.3‰ (n = 4) and 7.9‰ to 15.6‰ for δ18OSO4 with the median value of 14.3‰ (n = 4) respectively, indicating gypsum dissolution in karst aquifers. δ34SSO4 and δ18OSO4 values of sulfate in CMD ranged from 10.8‰ to 12.4‰ and 4.8‰ to 8.7‰ respectively. On the basis of groundwater flow path and geomorphological setting, the pore water samples were divided as three groups: (1) alluvial–proluvial fan (II1) group with high sulfate concentration (median values of 2.37 mM and 1.95 mM for UGW and CGW, respectively) and positive δ34SSO4 and δ18OSO4 values (median values of 8.8‰ and 6.9‰ for UGW, 12.0‰ and 8.0‰ for CGW); (2) proluvial slope (II2) group with low sulfate concentration (median values of 1.56 mM and 0.84 mM for UGW and CGW, respectively) and similar δ34SSO4 and δ18OSO4 values (median values of 9.0‰ and 7.4‰ for UGW, 10.2‰ and 7.7‰ for CGW); and (3) low-lying zone (II3) group with moderate sulfate concentration (median values of 2.13 mM and 1.17 mM for UGW and CGW, respectively) and more positive δ34SSO4 and δ18OSO4 values (median values of 10.7‰ and 7.7‰ for UGW, 20.1‰ and 8.8‰ for CGW). In the present study, three major sources of sulfate could be differentiated as following: sulfate dissolved from Ordovician to Permian rocks (δ34SSO4 = 10–35‰ and δ18OSO4 = 7–20‰), soil sulfate (δ34SSO4 = 5.9‰ and δ18OSO4 = 5.8‰) and sewage water (δ34SSO4 = 10.0‰ and δ18OSO4 = 7.6‰). Kinetic fractionations of sulfur and oxygen isotopes as a result of bacterial sulfate reduction (BSR) were found to be evident in the confined aquifer in stagnant zone (II3), and enrichment factors of sulfate–sulfur and sulfate–oxygen isotopes calculated by Rayleigh equation were −12.1‰ and −4.7‰ respectively along the flow direction of groundwater at depths of 60–100 m. The results obtained in this study confirm that detailed hydrogeological settings and identification of anthropogenic sources are critical for elucidating evolution of δ34SSO4 and δ18OSO4 values along with groundwater flow path, and this work also provides a useful framework for understanding sulfur cycling in alluvial plain aquifers. 相似文献
18.
Sandow Mark Yidana Samuel Ganyaglo Bruce Banoeng-Yakubo Thomas Akabzaa 《Journal of African Earth Sciences》2011,59(2-3):185-194
A conceptual groundwater flow model was developed for the crystalline aquifers in southeastern part of the Eastern region, Ghana. The objective was to determine approximate levels of groundwater recharge, estimate aquifer hydraulic parameters, and then test various scenarios of groundwater extraction under the current conditions of recharge. A steady state groundwater flow model has been calibrated against measured water levels of 19 wells in the area. The resulting recharge is estimated to range from 8.97 × 10?5 m/d to 7.14 × 10?4 m/d resulting in a basin wide average recharge of about 9.6% of total annual precipitation, which results in a basin wide quantitative recharge of about 2.4 million m3/d in the area. This compares to recharge estimated from the chloride mass balance of 7.6% of precipitation determined in this study. The general groundwater flow in the area has also been determined to conform to the general northeast–southwest structural grain of the country. The implication is that the general hydrogeology is controlled by post genetic structural entities imposed on the rocks to create ingresses for sufficient groundwater storage and transport. Calibrated aquifer hydraulic conductivities range between 0.99 m/d and over 19.4 m/d. There is a significant contribution of groundwater discharge to stream flow in the study area. Increasing groundwater extraction will have an effect on stream flow. This study finds that the current groundwater extraction levels represent only 0.17% of the annual recharge from precipitation, and that groundwater can sustain future increased groundwater demands from population growth and industrialization. 相似文献
19.
《Chemie der Erde / Geochemistry》2016,76(2):243-255
A detail investigation was carried out to improve the current knowledge of groundwater salinisation processes in coastal aquifers using hydrochemical and isotopic parameters. Data of major ions for 40 wells located in the Salalah plain aquifer, Sultanate of Oman, were collected during pre-monsoon 2004 and analysed. The groundwater changes along the general flow path towards the coast from fresh (EC < 1500 μS/cm), brackish (EC: 1500–3000 μS/cm) and saline (EC > 3000 μS/cm). Results of inverse modeling simulations using PHREEQC show that dissolution of halite may be the main source of Cl and Na in the study area. Ionic delta calculation indicates that the depletion of Na and K and enrichment of Ca and Mg in groundwater were probably attributed to reverse ion exchange reactions. During a sampling campaign conducted in October 2015, 11 groundwater samples were collected for Cl, Br and isotopic analysis (2H/18O). Molar Cl/Br ratios in fresh groundwater were higher than those of seawater, indicating the impact of halite dissolution on the groundwater quality. For saline groundwater, these ratios were less than those of seawater, showing the influence of anthropogenic input from agriculture on the same. Relatively depleted isotopic signature of all groundwater samples show that the monsoon precipitation is the main source of groundwater recharge in the study area. 相似文献
20.
Multi-tracer investigation of groundwater residence time in a karstic aquifer: Bitter Lakes National Wildlife Refuge, New Mexico, USA 总被引：1，自引：1，他引：0
Several natural and anthropogenic tracers have been used to evaluate groundwater residence time within a karstic limestone aquifer in southeastern New Mexico, USA. Natural groundwater discharge occurs in the lower Pecos Valley from a region of karst springs, wetlands and sinkhole lakes at Bitter Lakes National Wildlife Refuge, on the northeast margin of the Roswell Artesian Basin. The springs and sinkholes are formed in gypsum bedrock that serves as a leaky confining unit for an artesian aquifer in the underlying San Andres limestone. Because wetlands on the Refuge provide habitat for threatened and endangered species, there is concern about the potential for contamination by anthropogenic activity in the aquifer recharge area. Estimates of the time required for groundwater to travel through the artesian aquifer vary widely because of uncertainties regarding karst conduit flow. A better understanding of groundwater residence time is required to make informed decisions about management of water resources and wildlife habitat at Bitter Lakes. Results indicate that the artesian aquifer contains a significant component of water recharged within the last 10–50 years, combined with pre-modern groundwater originating from deeper underlying aquifers, some of which may be indirectly sourced from the high Sacramento Mountains to the west. 相似文献