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1.
The junctions of cracks in mudcrack, patterned ground, and columnar joint patterns can be categorized into Y, T,and Xtypes. The mean number of sides, ,to the polygonal areas in such nets is = 2(2JT + 3JY + 4JX)/(JT + JY + 2JX)where JT, JY,and JX are the proportions of T, Y,and Xjunctions, respectively.  相似文献   

2.
Equations are developed describing migration of stable isotopes via a fluid phase infiltrating porous media. The formalism of continuum fluid mechanics is used to deal with the problem of microscopic inhomogeneity. Provision is made explicitly for local equilibrium exchange of isotopes between minerals and fluids as well as for kinetic control of isotopic exchange. Changing characteristic parameters of transport systems such as porosity, permeability, and changes in modal proportions of minerals due to precipitation or dissolution are taken into account.The kinetic continuum theory (KCIT) is used to show how to deduce the dominant mechanism of mass transport in metasomatic rocks. Determination of the transport mechanism requires data on the spatial distribution of the reaction progress of exchange reactions between minerals and fluids involving at least two stable isotope systems such as 13C-12C and 18O-16O, for example. It is concluded that a combination of field and laboratory measurements of two or more stable isotope systems can be used to place constraints not only on the mechanism of transport but also on the magnitude of fluid fluxes, the identity of fluid sources, and the molecular species composition of fluids.Variables used C number of chemical components - D i,j hydrodynamic dispersion tensor [m2/s] - D i j diffusion coefficient matrix [m2/s] - D * apparent diffusion coefficient, includes sorption, dispersion, porosity and tortuosity [m2/s] - F number of degrees of freedom (variance) - f i j mass or number of isotope j in fluid species i - g acceleration due to gravity [m/s2] - flow [m3/m2 s] - j isotope species - j chemical element - k coefficient defined in Eq. 17 - K permeability of porous media [m2], [darcy] - L ij phenomenological diffusion coefficient matrix [mol2/j m s] - m number of fluid species - n number of isotope exchange vectors - p number of phases - P pressure [Pa] - P * hydrological pressure potential [Pa] - R j ratio of concentration of rare to common isotope of element j - r number of restrictions imposed on system - s i j mass or number of isotope j in one mole of mineral phase i - t time [s] - V volume [m3] - X i number of moles of fluid species i in unit fluid volume - X l number of moles of mineral l in unit volume - X l j mole fraction of isotope j in one mole mineral l - X * mole fraction with respect to the whole system - z space coordinate [m] - z transformed space coordinate - z * location of an infiltration front [m] - x–y j fractionation factor between two phases, x, y, for isotope j - porosity - fluid viscosity [Ns/m2] - fraction of porosity accessible to a specific mass transport mechanism - chemical potential [j/mole] - stoichiometric reaction coefficient - normalized reaction progress variable - mass, specific mass [gr/cm] - tortuosity - fluid velocity [m/s] - c common isotope - init initial - j isotope species - r rare isotope - tot sum of common and rare isotope - dif diffusive - disp dispersive - eq mineral composition in equilibrium with initial infiltration concentration of the fluid - f fluid - inf infiltrative - r rock, without fluid phase - samp sample - std standard - sys system - tot fluid and rock  相似文献   

3.
Assuming that the partial molar volume of each chemical component in a magma is constant, the magma density, m , is expressed as 1/ m =C i / fi , whereC i is the weight fraction, and fi is the fractionation density of thei th component. Using this linear relationship between 1/ and weight fraction, the density change due to addition or subtraction of any component can be graphically estimated on 1/ vs oxide wt% diagrams. The compositional expansion coefficient of thei th component, fi , is expressed as i = m / fi –1. The compositional expansion coefficient of H2O has a much larger absolute value than those of any other oxide or mineral components, showing that addition of a small amount of H2O can significantly decrease magma density. These simple expressions facilitate the estimation of magma densities during fractionation.  相似文献   

4.
Synthesis experiments in the system MgAl2O4–MgFe2O4 [MgAl2–xFexO4 (0 x 2)] were carried out using a PbF2 flux. The crystalline products synthesized in the compositional range of 0.6 <x 1.2 consisted of two spinel phases, whereas those synthesized in the compositional ranges of 0.0 x 0.6 and 1.2 < x 2.0 crystallized as single spinel phases. Structure refinements of the spinel single crystals, which grew in the ranges of 0.0 x 0.6 and 1.2 < x 2.0, show that the degree of randomness of cation distribution between A and B sites increases as x approaches the two-phase region. This means that the degree of the size mismatch among Mg2+, Fe3+ and Al3+occupying each equivalent mixing site increases as x approaches the two-phase region. Consequently, if the coexistence of two spinels observed in the intermediate compositions reveals the existence of a miscibility gap at low temperatures, this increase in the degree of the size mismatch among the three cations is suggested as a factor of energetic destabilization to form the miscibility gap.  相似文献   

5.
Compositional dependence of apparent partition coefficient of iron and magnesium between coexisting garnet and clinopyroxene from Mt. Higasiakaisi is studied by means of a multicomponent regular solution model. It is shown that garnet and clinopyroxene solid solutions are positively non-ideal, and the non-ideal parameters according to the symmetric regular solution model are 2.58 kcal and 2.39 kcal, respectively, assuming the equilibration temperature of the mass to be 550° C.Notations a i h activity of component i in phase h - ij interaction parameter of component i and j in a solid solution - i activity coefficient of component i - X i mole fraction of component i - K partition coefficient of Fe and Mg between coexisting garnet and clinopyroxene - K apparent partition coefficient of Fe and Mg between coexisting garnet and clinopyroxene - G 0 difference in free energy of the partition reaction - H 0 difference in enthalpy of the partition reaction - S 0 difference in entropy of the partition reaction - R gas constant - G garnet - Alm almandine component - Py pyrope component - Gr grossular component - Sp spessartine component - CPx clinopyroxene - Hd hedenbergite component - Di diopside component - Jd jadeite component - Ts Tschermac's molecule component Deceased on April 17, 1974.  相似文献   

6.
Divariant oxide plus metal assemblages potentially make useful redox sensors for use in hydrothermal and other high pressure experiments. Here we report the calibration of the (Ni, Mn)O/Ni redox sensor in which the Ni/NiO (NNO) oxygen buffer is displaced to lower oxygen chemical potentials (O2), by the solid solution of MnO in the oxide phase. This assemblage was chosen because: (1) it covers a useful range of O2; (2) the system can be calibrated very accurately. Values of O2 defined by the (Ni, Mn)O/Ni assemblage were determined electrochemically, from 900 to 1300 K, using calcia-stabilized zirconia solid electrolytes. The oxide compositions (8 in total, ranging from 0.1X NiO0.8) were analysed afterwards by electron microprobe, and were checked for internal consistency by measuring the lattice parameters (a0), using powder XRD. The accuracies of the measurements, both assessed theoretically and established empirically, are (1): ±80J/mol in O2, ±0.0002 Å in a0 and ±0.002 to 0.005 in X NiO. Activity-composition relations were fitted to the Redlich-Kister formalism. There is a slight asymmetry (corresponding to a subregular model) across the solution with A 0 G =9577(±45) J/mol, and A 1 G =–477(±80) J/mol. The experimental data were also used to derive the parameters Vex, Hex and Sex. There is no obvious relationship between excess volumes and enthalpies of mixing, nor between excess volumes and excess entropies. The experimental data from this study have been used to formulate the (Ni, Mn)O/Ni redox sensor expression: O2 = 2(NNO) + 2RTlnX NiO + 2(1 – X NiO)2[11483 – 1.697T] – 477(4X NiO – 1)(900 < T(K) < 1300) where O2(NNO)=–478967+248.514T–9.7961 T In T, from O'Neill and Pownceby(1993a).  相似文献   

7.
Study of young tectonic movements began at the end of XIXth century and is connected with the names of scientists from various countries. A valuable contribution to development of this branch of science was made by Russian school beginning with works by M. V.Lomonosov in the XVIII century. In XIX century this trend was successfully developed by A. P.Karpinsky, A. P.Pavlov, at the beginning of XXth century - V. A.Obruchev, N. I.Andrusov, A. D.Arkhangelsky, A. L.Reingard. Study of neotectonics in the USSR spread especially widely in the Soviet period (20–40ies) owing to industrial development of the country. Works by V. A.Obruchev, G. F.Mirchink and other Soviet scientists of that period contributed much to formation of a new branch of science — neotectonics.
Zusammenfassung Untersuchungen jungtektonischer Bewegungen begannen am Ende des neunzehnten Jahrhunderts und sind verbunden mit den Namen von Wissenschaftlern aus verschiedenen Ländern. Ein wertvoller Beitrag zur Entwicklung dieser Seite der Wissenschaft wurde von der russischen Schule — beginnend mit den Arbeiten von M. V.Lomonosov im XVIII. Jahrhundert — geleistet. Im neunzehnten Jahrhundert wurde diese Richtung erfolgreich durch A. P.Karpinsky und A. P.Pavlov weitergeführt; Anfang des 20. Jahrhunderts dann von V. A.Obruchev, N. I.Andrusov, A. D.Arkhangelsky, Reingard. Neotektonische Studien entwickelten sich besonders während der sovietischen Ära. Dies geschah in Verbindung mit der industriellen Entwicklung des Landes.Die Arbeiten von V. A.Obruchev, G. F.Mirchink und anderen Wissenschaftlern dieser Periode leisteten einen großen Beitrag zur Entstehung des neuen Wissenschaftszweiges — Neotektonik.
Résumé L'étude des mouvements néotectoniques, qui a débuté à la fin du XIXe siècle, est liée aux noms de savants de pays différents. L'école russe, avec les travaux de M. V. Lomonosov (XVIIIe siècle), a apporté une importante contribution au développement de cette branche des connaissances. Au XIXe siècle, cette direction de recherches s'est développée avec A. P. Karpinsky, A. P. Pavlov et au début du XXe siècle - avec V. A. Obruchev, N. I. Andrusov, A. D. Arkhangelsky et A. L. Reingard. L'étude de la néotectonique en URSS s'est spécialement répandue au cours des années 20–40 gràce au rapide développement industriel du pays. Les travaux de V. A. Obruchev, G. F. Mirchink et d'autres savants soviétiques de cette période ont beaucoup contribué à la formation d'une nouvelle branche de la science-la néotectonique.
XIX . , . . . XIX . . , . . , XX - . . , . . , . . , . . . (20–40 ) . . . , . . . — .
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8.
The Mount Lofty Ranges comprises interlayered marbles, metapsammites, and metapelites that underwent regional metamorphism during the Delamarian Orogeny at 470–515 Ma. Peak metamorphic conditions increased from lowermost biotite grade (350–400°C) to migmatite grade (700°C) over 50–55 km parallel to the lithological strike of the rocks. With increasing metamorphic grade, 18O values of normal metapelites decrease from 14–16 to as low as 9.0, while 18O values of calcite in normal marbles decrease from 22–24 to as low as 13.2 These isotopic changes are far greater than can be accounted for by devolatilisation, implying widespread fluid-rock interaction. Contact metamorphism appears not to have affected the terrain, suggesting that fluid flow occurred during regional metamorphism. Down-temperature fluid flow from synmetamorphic granite plutons (18O=8.4–8.6) that occur at the highest metamorphic grades is unlikely to explain the resetting of oxygen isotopes because: (a) there is a paucity of skarns at granite-metasediment contacts; (b) the marbles generally do not contain low-XCO2 mineral assemblages; (c) there is insufficient granite to provide the required volumes of water; (d) the marbles and metapelites retain a several permil difference in 18O values, even at high metamorphic grades. The oxygen isotope resetting may be accounted for by along-strike up-temperature fluid flow during regional metamorphism with time-integrated fluid fluxes of up to 5x109 moles/m2 (105 m3/m2). If fluid flow occurred over 105–106 years, estimated intrinsic permeabilities are 10-20 to 10-16m2. Variations in 18O at individual outcrops suggest that time-integrated fluid fluxes and intrinsic permeabilities may locally have varied by at least an order of magnitude. A general increase in XCO2 values of marble assemblages with metamorphic grade is also consistent with the up-temperature fluid-flow model. Fluids in the metapelites may have been derived from these rocks by devolatilisation at low metamorphic grades; however, fluids in the marbles were probably derived in part from the surrounding siliceous rocks. The marble-metapelite boundaries preserve steep gradients in both 18O and XCO2 values, suggesting that across-strike fluid fluxes were much lower than those parallel to strike. Up-temperature fluid flow may also have formed orthoamphibole rocks and caused melting of the metapelites at high grades.This paper is a contribution to IGCP Project 304 Lower Crustal Processes  相似文献   

9.
Zusammenfassung 921 Proben von 18 Standard-Profilen des Oberen Wettersteinkalkes (Ober-Ladin/ Unter-Karn) und seiner stratigraphischen Äquivalente Partnachschichten und Arlbergschichten wurden mit Hilfe der AAS auf Ca, Mg und Sr analysiert. Es wurden die Strontium-Verteilungen in den unterschiedenen Faziesbereichen (Riff-, Rand-, Lagunen- und Beckenfazies) und die Einflüsse von Diagenese, Salinität, Tongehalt und Dolomitisierung auf diese Verteilungen untersucht.Im Vergleich mit rezenten Karbonaten sind die Strontium-Mittelwerte in fast allen Faziesbereichen sehr gering (um 100–200 ppm). Diese intensive Strontium-Verarmung wurde wahrscheinlich durch Frischwasser-Einflüsse während verschiedener Diagenesestufen verursacht. Zum Hangenden (Raibler Schichten/Karn) treten in der Lagunen- und Randfazies Horizonte mit hohen Sr-Gehalten auf (1000–6000 ppm), fallweise auch Coelestin, der als Indikator für evaporitische Sedimentationsbedingungen in arider Umgebung gelten kann.
921 samples collected from 18 standard profiles of the Upper Wettersteinkalk (Upper Ladinian/Lower Carnian) and the corresponding Partnachschichten and Arlbergschichten were analysed with aid of AAS for Ca, Mg and Sr. Additional the HCl-insoluble was detected. The strontium-distributions in different facies types (i. e. reef, reef-margin, lagunal and basin facies) and the influences of diagenesis, salinity, clay content and dolomitization on these distributions were investigated.In nearly all facies areas the Sr means are very low (100–200 ppm) compared with recent carbonates. This strong diminution of Sr was caused by fresh-water influence during different stages of diagenesis. Approaching the Raiblian Schists (Carnian) the lagunal and reef-margins facies contain horizons with high Sr values (1000–6000 ppm) and sometimes celestite, which indicates evaporitic sedimentary conditions in an arid climatic environment.
Résumé 921 échantillons provenant de 18 coupes du Wettersteinkalk supérieur (sup. Ladinien/ inf. Carnien) et de ses équivalents stratigraphiques «Partnachschichten» et «Arlbergschichten» ont été analysés à l'aide de l'AAS pour Ca, Mg et Sr. On a examiné la distribution du strontium dans les différents facies lithologiques (p. e. facies récifaux, de bordure, de lagune, de plate-forme carbonatée) et les influences exercées par la diagenèse, la salinité, la teneur en argile et la dolomitisation sur ces distributions.Comparées aux carbonates récents les concentrations en strontium sont très pauvres (de 100 à 200 ppm). Cet appauvrissement intensif en Sr fut produit vraisemblablement par les influences de l'eau douce (eau souterraine ou vadose) au cours des différents stades de la diagenèse. Vers les strates de Carnien (Couches de Raibl) les coupes du Wettersteinkalk supérieur contiennent des horizons avec une grande quantité de strontium (1000–6000 ppm), et quelquefois aussi de la célestine, ce qui indique des conditions évaporitiques de la sédimentation dans un entourage aride.
921 18- ( - ) : « » «» AAS , Mg Sr. (, , ) , , . , 100-200 . , , . ( ) ( 1000-6000 ), , , .
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10.
Zusammenfassung Röntgenographische Untersuchungen an Einkristallen von Arsenbrackebuschit, Pb2(Fe, Zn)(OH, OH2) (AsO4)2 (mit FeZn21), ergaben die RaumgruppeP21/m mita 0=7,763(1) Å,b 0=6.046(1) Å,c 0=9.022(1)Å, =112,5(1)°,V=391,2(1) Å3,Z=2 und x =6,54 g/cm3. Dreidimensionale Fouriersynthesen und Verfeinerungen nach der Methode der kleinsten Quadrate bis zu einemR-Wert von 0,073 zeigten, daß das neue Mineral strukturell einer Gruppe von Blei-Mineralen der allgemeinen Formel Pb2 Me(Z) (XO4) (YO4) — mitMe=Cu2+, Mn2+, Zn2+, Fe3+;X=S, Cr, V, As;Y=P, As, V;Z=OH, OH2 — zuzuordnen ist. Vertreter dieser Gruppe sind z. B. Tsumebit Pb2Cu(OH) (SO4) (PO4), Vauquelinit Pb2Cu(OH) (CrO4) (PO4) und auch Brackebuschit Pb2(Mn, Fe) (OH2) (VO4)2. Strukturelle Verwandtschaft besteht mit Tsumcorit Pb(Zn, Fe)2(OH, OH2)2(AsO4)2, einem weiteren Blei-Arsenat der gleichen Lagerstätte.
Structural investigation of arsenbrackebuschite
Summary X-ray single crystal work on arsenbrackebuschite, Pb2(Fe, Zn) (OH, OH2) (AsO4)2 (with FeZn21), gave space groupP21/m witha 0=7.763(1),b 0=6.046(1),c 0=9.022(1) Å, =112.5(1)°,V=391.2(1) Å3,Z=2 and x =6,54 g/cm3. 3-dimensional Fourier syntheses and least-squares refinement (finalR=0.073) showed that the new mineral belongs to a group of lead minerals with the general formula Pb2 Me(Z) (XO4) (YO4)Me=Cu2+, Mn2+, Zn2+, Fe2+, Fe3+;X=S, Cr, V, As; Y=P, As, V;Z=OH, OH2. Members of this group, are for example tsumebite, Pb2Cu(OH) (SO4)(PO4), vauquelinite, Pb2Cu(OH) (CrO4) (PO4), and brackebuschite, Pb2 (Mn, Fe) (OH2) (VO4)2. A structural relationship exists to tsumcorite, Pb(Zn, Fe)2(OH, OH2)2 (AsO4)2, another lead-arsenate from Tsumeb.

Mit 2 Abbildungen  相似文献   

11.
The state of our knowledge today of the problems of jointing is very unsatisfactory. No clear explanation exists for the origin of joints. Observations available indicate, however, the importance of these phenomena for the morphology and for the distribution of mineralization in the earth's crust. The dependence of the surface features on jointing and on mineralization is indicated and examples of a close relationship of the great circles with jointing, morphology and the distribution of deposits of nickel, platinum, tin and diamonds are described. The paper deals essentially with Africa.
Zusammenfassung Unser Wissen über die Entstehung der Klüftung ist unbefriedigend. Dabei erscheint dieses Problem wichtig genug, um sich eingehender damit zu befassen. Es werden einige Fälle der Spezialklüftung erörtert und auf die Bedeutung der großräumigen rhegmatischen Klüftung hingewiesen. Die charakteristischen Eigenschaften der letzteren werden ausführlich beschrieben. In einem Versuch, die GedankenSpurrs über eine lineare Anlage der Erzlagerstätten zu erweitern, wird auf die große Ähnlichkeit im Verhalten hingewiesen, die zwischen der Klüftung und den Erzlinien besteht.Die auf einem Großkreis liegende Linie der Nickel- und Platinlagerstätten der Alten Welt, die sich von Südafrika bis nach dem Nordpolarmeer hinzieht wird beschrieben, und es wird auf ihre Beziehungen zur Klüftung und zur Morphologie hingewiesen. Eine noch ganz ungeklärte morphologische Beziehung zum Aufbau des Bodens des Indischen Ozeans scheint zu bestehen.Weiterhin wird die Verteilung der Lagerstättenfelder von Zinnerz und Diamanten in Afrika kurz beschrieben und auf das lineare Prinzip ihrer Lage und Form hingewiesen. Das Netzwerk der Erzlinien und der Unterbrechungslinien einzelner Zonen mit einer Nord-West- und Nord-Ost-Orientierung folgt wieder den Großkreisen. Auch hier ist wieder eine deutliche Beziehung zwischen Mineralisation, Klüftung und Morphologie zu beobachten. Damit wird auf einige Grundlagen für eine mögliche künftige Großprospektion hingewiesen.
Résumé L'état de nos connaissances d'aujordhui sur les problèmes des diaclases n'est pas satisfaisant. Il n'y a pas d'explications claires et definies sur leur origine. Les observations faites indiquent cependant l'importance de ce phénomène sur la morphologie et sur la distribution de la minéralisation de la croûte de la terre. La dépendance des traits de surface sur les diaclases et sur la minéralisation est indiquée. Les examples des relations très proches des grands cercles avec les diaclases, la morphologie et avec la distribution des gisements de nickel, de platine, d'étain et des diamants sont donnés. Ce travail est écrit surtout avec raport sur l'Afrique.
. . . . , , .
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12.
Summary Thermochemistry, morphology, optical properties and crystal structure of synthetic bayleyite, Mg2[UO2(CO3)3]·18H2O, monoclinic, have been studied. Incongruent melting at 55°, three steps of dehydration and two steps of decarboxylation have been found by thermochemic investigations. Morphology: Prisms along [001] with {100}, {110}, {210}, {001}, {401}, {021}, {211}, {111} and as the most important forms. Optical data:n =1.453,n =1.498,n =1.499, 2V x =16°,Y=b,X c=11°. Crystal structure: Space groupP21/a,a=26.560(3),b=15.256(2),c=6.505(1) Å, =92.90(1)°,Z=4,R=0.029 for 5126 independent reflections measured with MoK -radiation. The structure is built up from isolated Mg(H2O)6 octahedra, UO2(CO3)3 units and lattice water molecules, all held together by hydrogen bonds only.
Synthetischer Bayleyit, Mg2[UO2(CO3)3]·18H2O: Thermochemie, Kristallographie und Kristallstruktur
Zuseammenfasung Thermochemie, Morphologie, optische Eigenschaften und Kristallstruktur von Bayleyit, Mg2[UO2(CO3)3]·18H2O, monoklin, wurden anhand künstlich hergestellter Kristalle untersucht. Durch thermochemische Untersuchung wurden inkongruentes Schmelzen bei 55°, eine dreistufige Wasserabgabe sowie eine zweistufige CO2-Abgabe festgestellt. Morphologie: parallel zu [001] gestreckte Prismen mit {100}, {110}, {210}, {001}, {401}, {021}, {211}, {111}, und {311} als wichtigste Formen. Optische Daten:n =1.453,n =1.498,n =1.499, 2V x =16°,Y=b,X c=11°. Kristallstruktur: RaumgruppeP21/a,a=26.560(3),b=15.256(2),c=6.505(1) Å, =92.90(1)°,Z=4;R=0.029 für 5126 unabhängige, mit MoK -Strahlung gemessene Reflexe. Die Struktur enthält isolierte Mg(H2O)6-Oktaeder, UO2(CO3)3-Gruppen und freie Wassermoleküle, die ausschließlich durch Wasserstoffbrücken miteinander verknüpft sind.

With 4 Figures  相似文献   

13.
Summary Recent advances in mathematical optimization have resulted in the development of superior techniques for solving realistic decision making problems. The technique called PARETO OPTIMAL SERIAL DYNAMIC PROGRAMMING is presented here as a tool for rational mine planning. This approach always enables the identification of a set of decision alternatives considered superior to the remaining feasible, usually numerous, decision alternatives, when a number of conflicting, noncommensurable, objectives are simultaneously optimized. It is further noted that the decision makers' truly preferred decision is always one of the members identified as the superior set.Notation [A] Number of initial decision alternatives for production stage 1 - [A ] Accumulated pareto optimal stage objective vector at stage for the remainder of the stagesN – - [A] Accumulated non-pareto optimal stage objective vector at stage for the remainder of the stagesN – - [B] Number of initial decision alternatives for production stage 2 - [C] Number of initial decision alternatives for production stageN - [COG k,] Cutoff grade for decision,k, at production stage, - [D] Number of initial pareto solutions for production stage 1 - [D ] Decision at stage - [E] Number of initial pareto solutions for production stage 2 - [F] Number of initial pareto solutions for production stageN - [j] A random objective function - [J] Number of objective functions - [LIFE k,] Minelife for decision,k, at production stage, - [] An arbitrary production stage - [N] Final production stage - [NPV] Expected net present value - [NPV k,] Project net present value for decision,k, at production stage - [OPR k,] Ore production rate for decision,k, at production stage, - [S ] State of the system in stage - [ n] Immediate state objective vector at stage   相似文献   

14.
Summary Based on a X-ray structure analysis it was proved that the mineral schmiederite contains both selenite and selenate groups [a = 9.922(3)Å,b = 5.712(2)Å,c = 9.396(3)Å, = 101.96(3)°, space group P21/m,Z = 2 {Pb2Cu2(OH)4(SeO3)(SeO4)},R w = 0.055 for 1131 reflections up to sin / = 0.65 Å–1]. The crystal structure is closely related to that of linarite [a = 9.701(2) Å,b = 5.650(2) Å,c= 4.690(2)Å, = 102.65(2)°, space group P21/m,Z = 2 {PbCu(OH)2(SO4)},R w = 0.034 for 1991 reflections up to sin / = 1.0 Å–1].The Pb atom in linarite and the Pb(1) atom in schmiederite have each three Pb-O bonds < 2.45 Å with trigonal pyramidal arranged ligands; the Pb(2) atom in schmiederite has only one such near O atom. The Cu atoms are approximately square planar coordinated by hydroxil groups. In addition two further O atoms complete the coordination figure to a strongly distorted octahedron. All the anion groups have the usual geometry.
Kristallstruktur und chemische Formel von Schmiederit, Pb2Cu2(OH)4(SeO3)(SeO4), mit einem Vergleich zu Linarit, PbCu(OH)2(SO4)
Zusammenfassung Basierend auf einer Röntgen-Strukturuntersuchung konnte das Vorliegen von Selenit-und Selenatgruppen im Mineral Schmiederit belegt werden [a=9,922(3) Å,b = 5,712(2) Å,c = 9,396(3) Å, = 101,96(3)°, Raumgruppe P21/m,Z=2 {Pb2Cu2(OH)4(SeO3)(SeO4)},R w = 0,055 für 1131 Reflexe bis sin /, = 0,65 Å–1]. Die Kristallstruktur weist enge Beziehungen zu jener des Linarits auf [a = 9,701(2) Å,b = 5,650(2) Å,c = 4,690(2) Å, = 102,65(2)°, Raumgruppe P21/m,Z=2 {PbCu(OH)2(SO4)},R w = 0,034 für 1991 Reflexe bis sin / = 1,0 Å–1].Das Pb-Atom im Linarit sowie das Pb(1)-Atom im Schmiederit haben jeweils drei Pb-O-Bindungen <,45 Å, wobei die Liganden trigonal pyramidal angeordnet sind; das Pb(2)-Atom im Schmiederit hat hingegen nur ein derart nahes O-Atom. Die Cu-Atome sind etwa quatratisch planar von Hydroxilgruppen koordiniert; zwei weitere O-Atome ergänzen die Koordinationsfigur zur einem stark verzerrten Oktaeder. Die Aniongruppen haben die üblichen Dimensionen.
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15.
The earthquake catalogue of the European area, 1901–1985, with unified magnitudes, has been used for the preparation of epicentre maps of the Mediterranean area. Epicentres have been plotted on three sheets for different magnitude ranges,M B (orm B ) 5, 0,M S (orm B ) = 4.4–4.9,M S (orm B ) 4.3, according to the estimated levels of homogeneity. The first map (M 5) enables an objective comparison of seismicity over the whole Mediterranean area. The other two maps are complementary without the guarantee of completeness. Epicentres define the position of principal earthquake zones and levels of earthquake activity. The maps also serve as the starting point for further data processing. Graphs illustrating the time variation of earthquake activity in the whole area and the mean magnitude-frequency relationships are included.  相似文献   

16.
Zusammenfassung Die Gefügeregelung von Olivin-Porphyroblasten in dunitischen Ultramafititen des Åheimer Komplexes ist durch eine bevorzugteZ-Orientierung parallel zur Lineation-entsprechend der tektonischen B-Achse-gekennzeichnet.X undY liegen mit diskreten Maxima auf einem ac-Gürtel. Die Orientierung der Porphyroblasten entspricht einem reliktisch erhaltenen, älteren Verformungsplan, dessenPT-Bedingungen aus experimentellen Ergebnissen anderer Autoren und mit genetischer Parallelisierung zur Bildung der Granatultramafitite des Gebietes erklärt werden können.Kleine, rekristallisierte Olivinkorn-Einschlüsse in den Porphyroblasten zeigen einen Trend zu einerX-Orientierung senkrecht auf s;Y rotiert dabei in die Richtung der Gesteinslineation. Diese Orientierung ist in vielen, während einer jüngeren, retrograden Metamorphose rekristallisierten Olivingesteinen beobachtbar, welche unter denPT-Bedingungen einer Chlorit-Hornblende-Peridotitfazies stattfand.
Fabric orientation of olivine porphyroblasts in the Ultramafitite Complex of Åheim, Sunnmöre, western Norway
Summary The lattice orientation of olivine porphyroblasts in dunites of the Åheim Ultramafic Complex, western Norway, shows a principal -direction parallel to lineation in the host rock, corresponding to the tectonic B-axis. The other optical axes and form a girdle in the tectonic ac-plane with certain maximas. This orientation is caused by an earlier stress pattern. ThePT-conditions of this deformation may be explained by experimental results of other authors.Small recrystallized olivine inclusions in the blasts tend toward an -orientation perpendicular to S; rotates into the direction of lineartion. The same orientation occurs predominatly in the olivine rocks of the complex, which also have recrystallized during a younger retrograde metamorphism under the conditions of the chlorite amphibole peridotite facies.

Mit 6 Abbildungen

Herrn Prof. Dr. Dr. h. c.B. Sander zum 90. Geburtstag gewidmet.  相似文献   

17.
Usual methods for fitting a straight line, Y = + X,to data fail if the independent variable Xis subject to error. The problem is further complicated if there is no strong reason for selecting one of the two variables as independent; neither of the two lines may be correct. This review article discusses the maximum likelihood estimators of and under functional and structural models. These models involve differing assumptions about the statistical distributions of the dependent and independent variables. In addition, least-squares procedures are also considered. All these methods lead to the same result, a quadratic equation which can be solved to give an estimate of . This result requires knowledge of the ratio of the error variances, = 2/2, where 2 is the variance of the Yresiduals and 2 is the variance of the X residuals. If 2 and 2 are unknown, estimates of can be difficult to obtain. If replicate sampling was employed, estimates of the variances can be made, and then of .Contribution Number 1 of the series of review articles by the Mathematical Geologists of the United States.  相似文献   

18.
Because multidimensional ARMA processes have great potential for the simulation of geological parameters such as aquifer permeability, it was important to resolve which of two proposed alternative methods should be used for determining the two-dimensional weighting parameter, , for a unilateral ARMA (1, 0) process on a square net. Practical simulations demonstrates that the correct formulation is: =10/(1+ 10 2 where r,s is the correlation between lattice points at lagsr and s. When the simulations are performed with correlations of 0.8 or more a residual bias was detected which was found to be caused by a difference in the variance between the one- and two-dimensional models. This can be rectified by modifying the two- dimensional model as follows: zij=(zi–1, j + zi, j–1) + aij where 2=1/(1 + 10 2 ).  相似文献   

19.
Smoothing and interpolation by kriging and with splines   总被引：1，自引：0，他引：1  
Let scalar measurements at distinct points x1, , xn be y1, , yn.We may look for a smooth function f(x)that goes through or near the points (xi, yi).Kriging assumes f(x)is a random function with known (possibly estimable) covariance function (in the simplest case). Splines assume a definition of the smoothness of a nonrandom function f(x).An elementary explanation is given of the fact that spline approximations are special cases of the solution of a kriging problem.  相似文献   

20.
The authoress calculates the frequency of the TiO2-content in the lavas of the active volcanoes and shows by the aid of a quotient =Al2O3 – Na2O/TiO2 the pronounced bimodality of the frequency curve from which she concludes that the great variety of the magmas cannot be explained by a magmatic differentiation but only by a double origin of the magmas from the upper mantle and from the sialic crust of the earth.
Zusammenfassung Die Verfasserin berechnet die Häufigkeit des TiO2-Gehalts in den Laven der tätigen Vulkane und zeigt vermittelst eines Quotienten =Al2O3 – Na2O/TiO2 die ausgesprochene Bimodalität der Häufigkeitskurve, woraus sie den Schluß zieht, daß die große Verschiedenheit der Magmen nicht durch eine magmatische Differentiation erklärt werden kann, sondern daß man eine zwiefache Herkunft der Magmen annehmen muß: aus dem oberen Mantel und aus der sialischen Kruste der Erde.
Résumé L'auteur calcule la fréquence du pourcentage de TiO2 dans les laves des volcans la bimodalité cans actifs et montre, à 1 aide d un quotient =Al2O3 – Na2O/TiO2 la bimodalité prononcée des courbes de fréquence, et en tire la conclusion que la grande variété des magmas ne peut pas être expliquée par une différenciation magmatique, mais par l'origine double des magmas: du manteau supérieur et de la crôute sialique de la terre.
Riassunto L'autrice calcola la frequenza del contenuto in TiO2 nelle lave dei vulcani attivi e dimostra mediante un quoziente =Al2O3 – Na2O/TiO2 la pronunziata bimodalità delle curve di frequenza e ne trae la conclusione che la grande varietà dei magmi non è dovuta a differenziazione magmatica ma ad una duplice provenienza: dal mantello superiore e dalla crosta sialica della terra.
. , , , : 1. , 2. .

Dedicated to Professor Dr. A.Rittmann on the occasion of his 75. birthday

This study is a part of the researches, carried out with the funds of the National Research Council of Italy under the direction of Prof. A.Rittmann.  相似文献   

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