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1.
Changchengite occurs in chromite orebodies in dunite and in platinum placer deposits in chromite orebodies nearby. The mineral occurs as massive aggregates or veinlets on margins of iridisite (IrS2) and replaces it. Opaque. Lustre metallic. Colour steel-black. Streak black. Hm = 3.7. VHN20= 165 kg/ mm2. Isotropic. Cleavage none. Density 11.96 g/ cm3. Seven electron microprobe analyses give the following mean chemical results (wt. %): S 7.2, Cu 0.3, Te 0.4, Ir 41.2, Pt 2.8 and Bi 47.3 with total 99.1. The simplified formula is IrBiS. The strongest X-ray powder diffraction lines (hkl, d, I) are 210, 2.75 (70); 211, 2.51 (60); 311, 1.860 (100); 440. 1.090 (50) and 600, 1.027 (50). The X-ray powder diffraction pattern is similar to that of mayingite. After the diffraction data are indexed the mineral is determined to be cubic. The space group is P213 with a = 0.6164(4) nm, V = 0.2342 nm3 and Z = 4.  相似文献   

2.
於祖相 《矿物学报》1998,18(2):134-137,T001
富碲马营矿产在纯橄榄岩铬矿体中。在铝矿石及矿体附近的砂矿中均可找到。呈粒状自形结构,直径0.01~0.15mm。与硫铱矿(IrS2)、双峰矿、高台矿、马营矿及(Fe,Ni)9Cu3Ir6S20等紧密共生。有的呈脉状,宽0.1~0.2mm,长1.2mm。金属光泽。不透明,钢灰色,粉末黑色。HM=3.7。VHN50=161kg/mm2(范围132~215kg/mm2)。无解理。无断口。性脆。计算密度为12.2g/cm3。反射色亮白带淡黄色调,内反射无,均质性,双反射与反射多色性无。5个电子探针分析数据平均为(%):Cu0.3,Te32.9,Ir34.7,Pt2.7,Bi28.2,总量98.9。实验式根据原子数3计算为:(Ir(0.92)Pt(0.92)Cu(0.01));(1.00)Bi(0.68)Te(1.31)。简化后的理论式为Ir(Te,Bi)2,而(Ir:Bi:Te=3:2:4)。6条富碲马营矿是强X射线衍射hki、d、I为:210,2.89(60);311,1.95(100);511,1.246(70);520,1.204(60);440,1.145(60);533,0.9891(60)。根据X射线粉晶指标化求得马营矿为等轴晶系,空间群:Pa3,a=0.6486(4)um,V=0.2729nm3,Z=4。富碲马营矿是本文作者对马营矿研究的继续与补充。  相似文献   

3.
於祖相 《矿物学报》1998,18(1):12-16
铂双峰矿产在纯橄榄岩铝矿体中。在铝矿石及矿体邻近的砂矿中均可找到。呈块状聚集体或板片状自形晶,与疏钻矿、含锇自然铱紧密共生。脉状的宽20~301μm,长400~500μm,一般10μm×20μm。金属光泽。条痕黑色。HM=3.05。VHN20=92kg/mm2(平均)。{0001}解理完全。性脆。计算密度为10.21g/cm2。反射色;亮黄白带淡蓝色。内反射无。非均质性中等,偏光色为淡蓝或淡黄。双反射或反射多色性在空气中或油中均未见。5个电子探针分析数据平均(wt%):Cu0.2,Te57.2,Ir24.5,Pt17.2,Bi0.4,总量99.5。实验式为:(IR0.57Pt0.39Cu0.01)0.98(Te1.99Bi0.01)2.00。简化理论式为(11,Pt)Te2。4条最强X射线粉晶衍射线hkl,d,I为:101,2.87(100);102,2.10(70);110,1.98(60);103,1.58O(50)。根据X射线粉晶数据进行指标化,获得铂双峰矿晶胞数据:三方晶系,P3ml,a=0.3973(5),c=0.5315(5)um,V=0.0727nm3,Z=1。铂双峰矿是笔者对双峰矿研究的继续与补充。  相似文献   

4.
新矿物双峰矿—铱的二碲化物   总被引:2,自引:1,他引:2  
於祖相 《矿物学报》1994,14(4):322-326,T002
双峰矿产在纯橄榄岩体铬矿体中。在铬矿石及矿体邻近的砂矿中均可找到,呈块状聚集体或板片状与硫铱矿、锇自然铱矿紧密共生。直径0.5 ̄0.2mm,脉状的宽0.05 ̄0.10mm,长0.5 ̄1.0mm。金属光泽。条痕黑色。H(M)3。VHN20108kg/mm^2(平均)。解理:(0001)完全。性脆。计算密度为10.14g/cm^3。反射色:亮黄白带蓝色调。内反射无。非均质性中等,偏光色为淡蓝或淡黄。双  相似文献   

5.
卫冰洁  张建洪 《现代地质》1991,5(2):184-191,T001
杂铅矿(Izoklakeite)[1]是一个Ag-Cu—Pb—Sb—Bi硫盐矿物。1984年发现于我国广西芒场锡—多金属矿床块状锡石—石英—硫化物矿石中。与毒砂、黄铜矿、黝铝矿、方铅矿(少)、浓红银矿和自然铋,有时也与自然锑等密切共生。文中给出了杂铅矿的若干特征参数。  相似文献   

6.
铋砷黝铜矿在中国的发现与研究   总被引:1,自引:0,他引:1  
铋砷黝铜矿产于广东陆丰中低温热液黄铁矿矿床中,呈它形粒状嵌布在黄铁矿内,粒径0.05~0.22mm,与黄铜矿、针硫铋铝矿共生。反射免呈灰色微带蓝色,均质性。显微硬度Hv=295.5kg/mm2。电子探针成分分析(平均值)为:S24.4%,Cu38.25%,As13.03%,Bi17.人83%,Sb0.48%,Zn2.39%,Fe2.13%,Te1.47%,化学式为:Cu10(Fe0.65Zn0.63Cu0.49)1.77(As2.97Bi1.46Sb0.07)4、50(S12.8Te0.20)13。X射线粉晶衍射强线:2.95(10),2.55(3),1.866(5),1.727(4),1.041(5)。晶胞参数α=1.0218nm。  相似文献   

7.
该铂-金砂矿产于超基性岩体山前谷地的第四纪冲积-洪积层中。在60年代,前人曾对该铂-金砂矿作过初步评价,但对其中的铂族元素矿物未进行过矿物学研究。笔者于1992年夏对该砂矿作了调研,并对吕明鸿工程师所提供的该砂矿的铂族矿物样品进行了物理光学性质研究及电子探针和X射线分析。业已查明,它们主要是铱锇矿、钉铱锇矿、锇铱矿、自然锇、等轴铁铂矿;矿物共生组合为自然金+上述铂族矿物+自然银+铬尖晶石+铬铁矿+磁铁矿+钛铁矿+辰砂。这表明,该铂-金砂矿的物质来源为含铬超基性岩。  相似文献   

8.
Yixunite and damiaoite Were found in a cobalt- and copper-bearing platinum ore vein of a contact metasomatic deposit. The chief ore minerals are bornite, chalcopyrite, magnetite and carrollite. The platinum minerals include moncheite, sperrylite, daomanite, cobalt malanite and cooperite. Yixunite and damiaoite occur as immiscible globules, 1.0 to 2.0 mm in diameter. Yixunite is always in the central part of a globule. It is opaque with metallic lustre, bright white colour and black streak. HM = 5.8; VHN50 = 634 kg/mm2 (573-681 kg/ mm2); insoluble in HCl, HNO3, HF or H3PO4; no cleavage; no magnetism. Density is hard to measure because of small grain size. Calculated density = 18.21 g/cm3. Reflective colour is bright white with a yellowish tint. Isotropic. The mean analytical results (ranges) (%) are: Pt 82.8 (81.8-83.6), In 16.4(15.6-17.1) and total 99.2. The empirical formula (based on 4 atoms) is Pt2.993 In1.007 . The five strongest lines of X-ray diffraction (hkl, d,I) are 111, 2.30 (100); 200, 1.99 (  相似文献   

9.
邛莫金矿床中块硫锑铜矿含硒性及其特征   总被引:3,自引:0,他引:3  
硒的块硫锑铜矿产于西秦岭邛莫金矿床中,与其伴生的矿物有硒汞矿、硒铅矿、硒锑矿、斜方硒镍矿、硒铜镍矿、硒质辉锑矿、自然金以及石英、重晶石等。 含硒的块硫锑铜矿平均显微硬度VHN50=247.5kg/mm2,相当于摩氏硬度4.2。电子探 针分析结果(w,%)为:Sb 25.79,Cu 38.20,S 21.12,Se 1 2.76,Hg 0.0 0~1.49(平均0.58),Ag 0.00~0.33(平均0.09),As 0.00~2.01(平均0.76)。根据成分中S e/(S+Se)比值(原子比)<0.2抑≥0.2,可将所测矿物划分为含硒质块硫锑铜矿与硒质块硫锑 铜矿。它们的化学分子式分别为: (Cu2.84Hg0.01)2.85(Sb1.00A s0.07)1.07(S3.54Se0.46) 4.00和(Cu3.05Hg0.03)3.08(Sb1.07As0.03) 1.10(S2.77Se1.23)4.00。代表性的反射率(%): (470nm) Rγ'=22.84~22.50, Rα'= 27.92~27.99; (550 nm) Rγ'= 22.63~22.76, Rα'=2 7. 79~28.11; (590nm) Rγ'=22.92~22.08, R α'=28.27~28. 72; (650nm) Rγ'=23.08~23.76, Rα'=28.79~29.13。  相似文献   

10.
云南乐红铅锌矿床氧化带中异极矿的矿物学特征及其意义   总被引:7,自引:0,他引:7  
云南乐红铅锌矿床氧化带十分发育,呈细脉或葡萄状产于氧化矿石中的白色矿物曾被认为是菱锌矿,笔者对该矿物作了物理、光学性质,化学发,X射线衍射,红外光谱及失重和差热分析研究,确定其为异极矿。其晶体化学式为Zn3.98(Si2.01Al0.01)2.02O7(OH)2.03.0.88H2O晶胞参数a=0.8380(4)nm,b=1.0718(7)nm,c=0.5125(6)nm。对异极矿矿物学特征的全面  相似文献   

11.
江饶通  陈玫 《矿物学报》1993,13(4):335-340
本文对自然硅进行了矿相学,矿物学研究,该矿物产于福建某地矽卡岩型硫,多金属矿床中,自然硅呈亮灰银白色、强金属光泽。性脆。镜下呈浑圆粒状、乳滴状,均质。实测比重d=2.368。硬度HM=6.76。反射率R:470nm3708;546nm31.27;650nm29.96。经扫描电镜能谱分析、电子探针分析,Si99.87%~99.94%。含少许Al,Ca,Fe机械混入物,X射线粉晶分析,主要X射线粉晶谱  相似文献   

12.
黑铝钙石是一种罕见矿物,在邯邢地区镁铝夕卡岩中,发现一种呈六方片状、黄色半透明的黑铝钙石晶体。本文对该晶体进行了粉晶X射线、四元衍射、电子探针和红外光谱测量,并认为黑铝钙石是镁铝夕卡岩早期阶段的产物,处在一种富铝、贫硅的地球化学环境和高温条件  相似文献   

13.
田澍章  陈静渝 《矿物学报》1990,10(4):382-384
黑铋金矿产于广东封开蚀变花岗岩中,主要伴生矿物有自然金、自然铋、碲铋矿。该矿物的颜色为银白色,在反光镜下反射色为灰色带黄绿色色调,经能谱分析结果Au=65.28%,Bi=34.72%,计算分子式为Au_(1·995)Bi_(1·000),反射率测定为51.5(405mm),48.9(436nm),50.9(480nm)53.7(644nm),51.9(656nm),42.1(700nm)。对该矿物还作了X射线粉晶衍射分析。  相似文献   

14.
我国首次发现的锌—砷黝铜矿   总被引:1,自引:0,他引:1       下载免费PDF全文
锌-砷黝铜矿产于内蒙的某一铅锌矽卡岩矿床中,呈它形粒状集合体,粒径0.2-0.5mm,铅灰色,硬度HvHN=339-388kg/mm2。反射色呈灰蓝色微带绿色。均质性。其成分经电子探针分析(平均值)为:S 25.94,As 10.70,Cu 39.67,Zn 7.36,Sb 9.81,Bi 5.81,Ag 0.18,Fe 0.37(%),化学式为:(Cu10.02Age03)10.05(Zn1.81Fe0.11)1.82(As2.29Sb1.29Bi0.45)4.03S18。X射线分析:晶胞参数a=10.322,粉末衍射强线是2.98,1.82,1.56。  相似文献   

15.
Malanite was first found in veinlets of disseminated copper-nickel ores inZunhua County, Hebei Province, and then in platinum-bearing chromite ores in ShuangfengVillage, Yanshan. In the former case, malanite appears as octahedrons or dodecahedrons asso-ciated with pyrrhotite, pentlandite, sperrylite and cooperite; while in the latter case, it is massiveor present in anhedral glomerocrysts, filling in cracks of iridisite and associated with osmiride,ferrian platinum and iridisite. Malanite is steel-grey in colour, opaque with metallic lustre andblack streaks and brittle with no magnetism. H_M=5.0, VHN_(20)=417kg/mm~2, cleavage {111}sometimes observed. The calculated density is 7.57g/cm~3. The reflective colour is white with alight green tint. Internal reflections are not observed. This mineral is isotropic, showing nobireflection or reflection pleochroism in air. By means of electron microprobe analysis, the em-pirical formula (based on 7 atoms) is expressed as (Cu_(0.93)Fe_(0.06))_(∑0.99)(Pt_(1.03)Ir_(0.66)Rh_(0.04)Pd_(0.03)Co_(0.20)Ni_(0.03))_(1.99)S_(4.03) or (Cu_(0.95)Fe_(0.07))_(∑1.02)(Pt_(1.37)Ir_(0.45)Co_(0.11)Rh_(0.08))_(∑2.01)S_(3.97). Five strongestlines (hkl, d, I) of X-ray powder diffraction data of malanite are 311,2.98(6); 400,2.48(5);333, 1.90(7); 440, 1.75(10); 731, 1.29(5). It was known on the basis of X-ray powder diffractiondata that malanite is cubic, and the space group is Fd3m with α=0.9940nm, V=0.9821(3)nm~3 and Z=4. The type material of malanite is deposited at the Geological Museum of China(GMC)s  相似文献   

16.
产于我国广东省的沃奇纳矿   总被引:1,自引:1,他引:1  
本文的Wodginite产于广东某富钽花岗伟晶岩中,呈不规则粒状,棕红色。文中对该矿物作了探针分析、X射线粉晶衍射,并与国外的同种矿物作了对比,从空间群结构式和阳离子有序式探讨了该矿物译名的新意见。  相似文献   

17.
Tetragonal FeS1−x mackinawite, has been synthesized by reacting metallic iron with a sodium sulfide solution and characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), transmission Mössbauer spectroscopy (TMS) and X-ray photoelectron spectroscopy (XPS). Based on XRD and TEM analyses, synthetic mackinawite exhibits crystallization and is identical to the natural mineral. Unit cell parameters derived from XRD data are a = b = 0.3670 nm and c = 0.5049 nm. The bulk Fe:S ratio derived from the quantitative dispersive energy analysis is practically 1. XPS analyses, however, showed that mackinawite surface is composed of both Fe(II) and Fe(III) species bound to monosulfide. Accordingly, monosulfide is the dominant S species observed at the surface with lesser amount of polysulfides and elemental sulfur. TMS analysis revealed the presence of both Fe(II) and Fe(III) in the mackinawite structure, thus supporting the XPS analysis. We propose that the iron monosulfide phase synthesized by reacting metallic iron and dissolved sulfide is composed of Fe(II) and S(-II) atoms with the presence of a weathered thin layer covering the bulk material that consists of both Fe(II) and Fe(III) bound to S(-II) atoms and in a less extent of polysulfide and elemental sulfur.  相似文献   

18.
为探究南非最近产出的一种新型紫色玉石的矿物学特征及颜色成因,对其进行了常规宝石学特征测试,并采用X射线粉末衍射仪(XRD)、扫描电子显微镜(SEM)及紫外-可见分光光度计(UV-Vis)等仪器对其矿物组成、结构特征、化学成分和致色元素进行了研究。常规宝石学测试结果表明,该玉石折射率为1.54(点测),相对密度为2.1-2.2,摩氏硬度为1-2。XRD分析结果表明样品主要矿物组成为鳞镁铁矿,呈紫色,次要矿物成分为利蛇纹石,呈褐绿色;SEM分析结果显示鳞镁铁矿大多为集合体,主要以鳞片状和纤维状两种集合体形式存在,能谱分析(EDS)结果显示紫色部分主要化学成分为Mg,O,C,Fe,Cr等,佐证了紫色部分为鳞镁铁矿;UV-Vis结合EDS分析结果显示,鳞镁铁矿的紫色可能由Cr致色引起。  相似文献   

19.
湘江铀矿产于湖南某地二迭系岩层中一铀矿床的氧化带中。对该铀矿床的成因目前有两种看法,一种认为是沉积变质型;另一种认为是沉积迭加热液型。湘江铀矿呈浅黄色的粉末状微晶集合体产于硅质岩的裂隙内或风化孔洞中。与铝铀云母,黄铁矿,石英,磷铝石等矿物共生。根据产地命名为湘江铀矿。  相似文献   

20.
Luobusaite: A New Mineral   总被引:6,自引:0,他引:6  
A group of mantle minerals including about 70-80 subtypes of minerals are discovered from a podiform chromitite in Tibet, China. Recovered minerals include diamond, coesite, moissanite, wustite, Fe-silides and a new mineral, luobusaite. All of these minerals were hand-picked from heavymineral separates of the podiform chromitite in the mantle peridotite of an ophiolite. The grains of luobusaite are as host mineral with inclusions of native silicon or as an intergrowth with native silicon and Fe-Si phase. Luobusaite occurs as irregular grains, with 0.1-0.2 mm in size, consisting of very finegrained aggregates. The mineral is steel-grey in color, metallic luster, and opaque. The empirical formula (based on 2 for Si) is Fe0.83Si2, according to the chemical compositions of luobusaite. X-ray powder-diffraction data: orthorhombic system, space group Cmca, a = 9.874 (14) A, b = 7.784 (5) A, c= 7.829(7) A, Z=16.  相似文献   

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