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1.
柴达木石——一种锌和铁的硫酸盐新矿物   总被引:1,自引:0,他引:1  
柴达木石是一种Zn和Fe~(3+)的硫酸盐新矿物,发现于我国青海省柴达木锡铁山铅锌矿氧化带。矿物属单斜晶系,空间群P2_1/m或P2_1,晶胞参数a=9.759(9)A,b=7.134(9)A,c=7.335(11)A,β=106.2(1)°,Z=2。化学分子式为ZnFe~(3+)(SO_4)_2(OH)·4H_2O。它是四水铜铁矾(guildite)的类似物。  相似文献   

2.
彭志忠石产于湖南安化白钨矿区,是一种富含镁、锡、铝的复杂氧化物。矿物为浅黄褐色、浅黄色,少量无色,晶体呈六方板状。晶体化学式为:(Mg,Zn,Fe,Al)_4(Sn,Fe)_2(Al,□)_(10)O_(22)(OH)_2,空间群P_3ml,a=5.692(5)A,c=13.78(2)A,V=386.7A~3,Z=1。D=4.22(3)g/cm~3,H≥8,一轴正晶,ω=1.802(2),ε=1.814(2)。  相似文献   

3.
The crystal structure of lisiguangite,CuPtBiS3,from Yanshan mountains,Chengde Prefecture,Hebei Province,China has been determined by single crystal X-ray diffraction.It belongs to orthorhombic space group P2_12_12_1 with a = 7.7372(15) A,b = 12.844(3) A,c = 4.9062(10) A,V =487.57(17) A~3,Z = 4.The final full-matric least-square refinement on F2 converged with Rl = 0.0495 and wR2 = 0.0992 for 704 observed reflections[I≥2σ(I)].Lisiguangite is the isomorph of known CuNiSbS_3 and CuNiBiS_3· Pt~(2+) and Bi~(3+) have the distorted octahedral coordination enviroments composed of two metal and four S and Cu~(+2) has a distorted tetrahedral coordination environment with four S atoms.Each S atom is surrounded by four metals to give a tetrahedral environment.The crystal structure is a complex 3 dimensional network.  相似文献   

4.
本文利用直接法和富利叶合成侧定了产于我国四川省三叠系蒸发岩里的多钙钾石膏 的晶体结构,结构参数经最小二乘法修正后,,R = 0.084。结构分析表明,多钙钾石膏属单斜晶系,空间群C2/c, a = 17.462 (8)A,b=6.828(2)A,c=18.219(9)A,β=113.45(4)º。,V=1992(1)A3, Z=4, Dm=2,91, Dx=2.90(3)。三个硫酸根四面体各自的平均S-O键长为1,467、 1.464 和1.478A。有三套Ca原子,其中Ca1在二次对称轴上。Ca原子的配位数为9,各自的平均Ca-O键 长为2.516、 2,515和2.459A。K原子的配位数为8。首次测定了矿一物中氢原子的位置,证实矿物含1个结晶水,而不是含1.5个结晶水。晶体化学式为K2Ca5 (SO4)6.H2O。  相似文献   

5.
钴硅锌矿是一种具有特征深蓝紫色、油脂光泽和玻璃光泽的钴锌硅酸盐矿物,属三方晶系。空间群:C_(3j)~2—R3、a=13.9559A,c=9.3364A,c/a=0.6690,V=1574.8104A~3,Z=18。该矿物理论式为(Zn,Co)_2SiO_4,实验式为:(Zn_(1.26),Co_(O.74))SiO_4。据红外光谱以及X射线粉晶分析,其结构与硅锌矿(Zn_2SiO_4)类似。  相似文献   

6.
在分析3CaO·3Al2O3·CaSO4(C4A3S)生成反应热力学参数的基础上,结合变温XRD实验,研究C4A3S在静态空气、流动O2和流动Ar条件下生成的动力学过程,并探讨气氛对C4A2S生成的影响.静态空气下,C4A3S生成反应表观活化能Ea=228 kJ/mol;流通O2气氛下,Ea=68 kJ/mol;流通Ar气氛下,Ea=254kJ/mol.O2气氛能有效地降低C4A3S生成反应表观活化能,惰性(Ar)的贫氧气氛不利于C4A3S生成.  相似文献   

7.
一种硼酸盐的新矿物—袁复礼石   总被引:3,自引:0,他引:3  
袁复礼石是一种Mg、Fe2+、Al和Ti的硼酸盐新矿物,发现于辽宁省宽甸县砖庙硼矿区。该矿物黑色,近不透明,金刚光泽-半金属光泽。反射色亮灰,内反射深红褐色。非均质性弱,偏光色红褐。晶体呈细柱状,O.1×0.2×l mm。晶体化学式为:(Mg0.91Fe2+0.09)(Fe3+0.56Al3+0.19 Mg0.17Ti0.11Fe2+0.10)1.13(B0.92O3.00)O。空间群Pnam, a=9.258(6)A,b=9.351(4)A, c=3.081(2)A,V=266.80(2)A,Z=4。 D=3.80 g/cm3, H=5-6,VHN50=843 kg/mm2,{100}解理完全。红外光谱吸收谱带为:1387, 1210, 1024, 951, 733, 600, 510和408 cm-1。穆斯堡尔谱证明,以三价铁为主,二价铁较少。Fe3+占据M(1)晶位,Fe2+占据M(1)和M(2)晶位。袁复礼石为硼钛镁石的富Fe3+类似物。  相似文献   

8.
多钙钾石膏产于四川省渠县农乐地区中-下三叠统的杂卤石矿层里,与硬石膏一起交。代杂卤石。矿物呈板状,{110}解理中等。比重2.91。折光率:Ng=1.585,Nm=1.5θ8,NP=1.560。二轴晶正,2V=79°。该矿物属单斜晶系。空间群C2/c。晶胞参数:a_0=17.479A,b_0=6.821A,C_0=18.218A,β=113.39°。粉末图的五条强衍射线为:3.01(10)、3.16(8)、3.38(6)、2.83(4)、2.74(3)。根据化学分析计算,其化学式为:K_2SO_4·5CaSO_4·H_2O。结晶水含量2.O4%。文内列出了该矿物的差热(DTA)和热失重(TGA)、红外吸收光谱等新资料。  相似文献   

9.
以作用形式较为简单的双排悬臂抗滑桩(未带连梁)为模型并基于结构力学位移法得出的双排桩滑坡推力传递分配计算公式为基础,结合推力较大的红石包滑坡作为工程实例,分别分析了双排桩静排距,前后排桩的截面尺寸和桩间土弹性模量对推力传递分配的影响,得出了以下结论:(1)当增大后排桩的刚度或减小前排桩的刚度时,桩土相互挤压作用越小, A2/A1随之减小,反之A2/A1增大。(2)增大排距b时,A1减小,A2在b=3~10m时逐渐减小,但是变化幅度不大; 在b=10~21m时,不断增大。(3)当增大桩间土弹性模量时,A2增大。(4)随着前排桩截面高度的增大,A1、A2逐渐增大; 随着后排桩截面高度的增大,A1、A2逐渐减小。  相似文献   

10.
在白云鄂博地区发现的水磷钙钍石呈脉状产于元古代变质石英砂岩中,共生矿物有透辉石、金红石、磷灰石、重晶石、赤铁矿和黄铁矿等。颜色从浅黄色到红褐色乃至黑色,从透明至半透明以至不透明。红褐色水磷钙钍石为玻璃光泽,比重3.42,摩氏硬度4.28—4.29,磁化率(2.34—3.99)×10~(-6)C·G·S·m cm~3/g,平均折光率No=1.65,Ne=1,66,一轴晶(+)。 水磷钙钍石的化学式为:(Ca_(0.5751)Th_(0.4502)U_(0.0070)La_(0.0030))_(1.0353)(P_(0.7578)S_(0.0928))_(0.8506)O_4(CO_3)_(0.1603),0.9H_2O。六方晶系,晶胞参数a=6.94A,c=6.51A。  相似文献   

11.
Pant-y-ffynnon Quarry in South Wales yielded a rich cache of fossils in the early 1950s, including articulated specimens of new species (the small sauropodomorph dinosaur Pantydraco caducus and the crocodylomorph Terrestrisuchus gracilis), but no substantial study of the wider fauna of the Pant-y-ffynnon fissure systems has been published. Here, our overview of existing specimens, a few described but mostly undescribed, as well as freshly processed material, provides a comprehensive picture of the Pant-y-ffynnon palaeo-island of the Late Triassic. This was an island with a relatively impoverished fauna dominated by small clevosaurs (rhynchocephalians), including a new species, Clevosaurus cambrica, described here from a partially articulated specimen and isolated bones. The new species has a dental morphology that is intermediate between the Late Triassic Clevosaurus hudsoni, from Cromhall Quarry to the east, and the younger C. convallis from Pant Quarry to the west, suggesting adaptive radiation of clevosaurs in the palaeo-archipelago. The larger reptiles on the palaeo-island do not exceed 1.5?m in length, including a small carnivorous crocodylomorph, Terrestrisuchus, and a possible example of insular dwarfism in the basal dinosaur Pantydraco.  相似文献   

12.
Robert L. Linnen   《Lithos》2005,80(1-4):267-280
The solubilities of columbite, tantalite, wolframite, rutile, zircon and hafnon were determined as a function of the water contents in peralkaline and subaluminous granite melts. All experiments were conducted at 1035 °C and 2 kbar and the water contents of the melts ranged from nominally dry to approximately 6 wt.% H2O. Accessory phase solubilities are not affected by the water content of the peralkaline melt. By contrast, solubilities are affected by the water content of the subaluminous melt, where the solubilities of all the accessory phases examined increase with the water content of the melt, up to 2 wt.% H2O. At higher water contents, solubilities are nearly constant. It can be concluded that water is not an important control of accessory phase solubility, although the water content will affect diffusivities of components in the melt, thus whether or not accessory phases will be present as restite material. The solubility behaviour in the subaluminous and peralkaline melts supports previous spectroscopic studies, which have observed differences in the coordination of high field strength elements in dry vs. wet subaluminous granitic glasses, but not for peralkaline granitic glasses. Lastly, the fact that wolframite solubility increases with increasing water content in the subaluminous melt suggests that tungsten dissolved as a hexavalent species.  相似文献   

13.
Calcite samples were extracted both from the rock matrix and the superficial coating of a karstified fault plane of an underground quarry, located in the eastern border of the Paris basin. The karstification is dated as Quaternary. Analysis of mechanical calcite twinning reveals that only the calcite matrix has also undergone a compression trending WNW that can be attributed to the Mio-Pliocene alpine collision. Both coating and matrix have undergone a strike-slip regime with σ1 roughly trending north–south, that could correspond to the regional present-day state of stress, a strike-slip compression rather trending NNW, modified by local phenomena. To cite this article: M. Rocher et al., C. R. Geoscience 335 (2003).  相似文献   

14.
HYDROGEOLOGY     
正20141756 Chen Ruige(Mathematical College,China University of Geosciences,Beijing100083,China);Zhou Xun Numerical Simulation of Groundwater Level Fluctuation in a Coastal Confined Aquifer with Sloping Initial Groundwater Level Induced by the Tide(Geological Bulletin of China,ISSN1671-2552,CN11-4648/P,32(7),2013,p.1099-1104,6 illus.,16 refs.) Key words:confined water,groundwater level  相似文献   

15.
正20141408 Cai Jia(Institute of Geology,Chinese Academy of Geological Sciences,Beijing100037,China);Liu Fulai Petrogenesis and Metamorphic P-T Conditions of Garnet-Spinel-Biotitebearing Paragneiss in Danangou Area,Daqingshan-Wulashan Metamorphic Complex Belt(Acta Petrologica Sinica,ISSN1000-0569,CN11-1922/P,29(7),  相似文献   

16.
17.
正20142386An Guoying(China Aero Geophysical Survey and Remote Sensing Center for Land and Resources,Beijing 100083,China)Application of Satellite Remote Sensing in Regional Hydrogeological Investigation:Taking Cenozoic Strata in Wenquan Sheet(1∶250 000)of Karakoram Range as an Example(Geosci-  相似文献   

18.
正20141016An Chengbang(Key Laboratory of Western China’s Environmental Systems,Ministry of Education,Lanzhou University,Lanzhou 730000,China);Zhao Yongtao Lake Records during the Last Glacial Maximum from Xinjiang,NW China and Their Climatic Impli-  相似文献   

19.
正20141538 Cao Qing(School of Earth Sciences and Engineering,Xi’an Petroleum University,Xi’an 710065,China);Zhao Jingzhou Characteristics and Significance of Fluid Inclusions from Majiagou Formation,Yichuan Huangling Area,Ordos Basin(Advances in Earth Science,ISSN1001-8166,CN62-1091/P,28(7),2013,p.819-828,7 illus.,3 tables,43 refs.)  相似文献   

20.
GEOCHEMISTRY     
正20142002 Wei Hualing(Institute of Geophysical and Geochemical Exploration,Chinese Academy of Geological Sciences,Langfang065000,China);Zhou Guohua Element Content and Mineral Compositions in Different Sizes of Soil in Tongling Area,Anhui Province(Geological Bulletin of China,ISSN1671-2552,CN11-4648/P,32(11),2013,p.1861  相似文献   

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