共查询到18条相似文献，搜索用时 140 毫秒
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以盐湖提锂副产镁渣为原料,经洗涤煅烧制备活性MgO,并与七水硫酸镁混合制备硫氧镁水泥。研究了原料配比(活性MgO:MgSO4:H2O,摩尔比)对硫氧镁水泥试件凝结时间、安定性和抗压强度的影响,并利用XRD和SEM分析试件的物相组成和微观形貌。结果表明:固定H值,随着M值的增大,MOS浆体的凝结时间缩短,28 d的抗压强度先增加后降低,主要水化产物517相先增多后减少,晶体的微观形貌经历了由针丝状晶体—针丝状、短棒状晶体并存—凝胶状、针棒状晶体并存的转变过程;当M=9时,MOS浆体的安定性较差,主要水化产物逐渐变为Mg(OH)2相;固定M值,随着H值的增大,MOS浆体的凝结时间延长,28 d的抗压强度先增加后降低,主要水化产物的种类没有发生明显的变化,当H≥26时,MOS浆体的安定性较差;得出较佳的M值范围为5~7,H值范围为20~24。 相似文献
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低活性氧化镁是制备磷酸镁水泥(MPC)的关键原材料。现行低活性氧化镁的生产方式导致了制备MPC具有能耗高和成本高的缺点,不利于其推广应用。利用盐湖中常见元素如B,Na、K和Cl的助烧结作用,在≤1 200℃煅烧盐湖提锂镁渣、外掺B的轻烧镁粉和水氯镁石的热解产物制备低活性氧化镁。介绍了低活性氧化镁的粒径、比表面积、孔隙率、化学组成、矿物组成和形貌等物理特征,以及低活性氧化镁制备MPC的凝结时间、水化产物、微观结构、抗压强度、体积稳定性等凝结硬化性能,并分析了烧结温度对低活性氧化镁的理化性能及MPC的凝结硬化性能的影响。相比现有技术,利用盐湖共存元素的助烧结作用可将氧化镁的烧结温度由1 500～1 800℃降低到1 200℃以下,有利于实现低活性氧化镁及MPC的低能耗、低成本绿色制备,促进MPC的推广应用。 相似文献
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盐湖卤水提锂工艺的难点之一在于卤水中镁锂比过高。采用红外光谱对非平衡动态降温过程中溶液结构变化进行分析,测定不同类型单盐溶液和卤水的结构变化,并基于此规律强化盐湖尾卤的镁锂分离。结果表明,MgSO4 溶液在40 ℃及以上时, 984 cm-1 处的特征峰显示可能出现接触式离子对结构(Mg2+-SO42-);1 280 cm-1处出现溶剂共享型离子对结构( Mg2+-H2O-SO42-);Li2SO4溶液中出现溶剂共享型离子对结构的可能性低,镁锂之间会出现结构差异。基于如上溶液结构的变化,通过非平衡动态降温过程,实现盐湖尾卤中的镁锂分离,镁锂质量比值可由最初的40降至20左右,Mg2+以MgSO4·nH2O型混合结晶产品的形式从卤水中析出,而液相中Li+的损失率可低至5.01%以下,以此达到了脱镁及锂富集的效果。 相似文献
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硫酸浸出法制备硼酸的废弃母液经过浮选法分离产生的硫酸镁中通常含有硼酸等杂质,为了研究硼酸对硫氧镁水泥凝结硬化及力学性能的影响,以改性硫氧镁水泥(MOS)为基础体系,测试了硼酸含量对硫氧镁水泥凝结时间、抗压和抗折强度的影响,讨论了硼酸对硫氧镁水泥抗水性、水化产物及微观形貌的影响。结果表明:硫氧镁水泥的凝结时间随硼酸含量的增加而延长;硼酸可以明显降低硫氧镁水泥的早期强度,对后期强度的降低作用不及早期明显;试件浸水28 d后,较高含量的硼酸提高了试件抗压强度的软化系数,而降低了抗折强度的软化系数,因此硫酸镁中硼酸含量不应超过0.7%;硫酸镁中硼酸含量不影响硫氧镁水泥水化产物的组成,但降低了水化产物的结晶度并改变其显微结构。 相似文献
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以添加不同掺量填料的氯氧镁水泥(MOC) 试件为基体,在空气和碳化箱中分别养护至规定龄期,研究碳化对掺加填料MOC力学性能的影响,并与空气环境进行对比,运用XRD和SEM分析碳化后水化产物和微观结构的变化规律。结果表明,28d龄期内,随着填料掺量的增加MOC试件碳化后的抗折强度均有所增加,碳化后的抗压强度均有提升,碳化过程反应生成了MgCO<sub>3</sub>,不同碳化龄期的主要物相均为5Mg(OH)<sub>2</sub>.MgCl<sub>2</sub>.8H<sub>2</sub>O(5.1.8),而掺加填料不影响MOC的水化产物的组成。 相似文献
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针对盐湖卤水中镁锂性质相似难以分离的问题,基于CO2溶入卤水后生成的CO32-浓度稳定、CO32-和Mg2+在亚稳状态下易于发生沉淀反应的假设,采用碳酸化反应方法进行镁锂分离研究。通过红外光谱研究了三种不同盐体系的溶液结构,结果表明在氨水调碱后的MgCl2-NH3·H2O-CO2体系中,1?520 cm-1和1?012 cm-1处产生CO32-的伸缩振动峰,CO32-与Mg2+发生沉淀反应后促使Mg2+以固相形式析出;LiCl-NH3·H2O-CO2体系中,在1?012cm-1处产生的信号较弱的CO32-振动峰,由于CO32-与Li+发生的反应不强烈,因此Li+主要还以溶解态形式存在;在MgCl2-LiCl-NH3·H2O-CO2反应体系中,Mg2+影响了1?520 cm-1处的CO32-伸缩振动峰,说明二者易于发生结晶反应,从而促使Mg2+和Li+分别以固液形式富集在两相中,实现了镁锂分离。镁锂溶剂化结构的不同致使碳酸化反应中的发生反应振动的峰值不同,分离实验表明与传统的碳酸盐沉淀法相比,氨水和CO2分离工艺更易于得到高纯度的镁盐产品。 相似文献
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以添加不同掺量填料的氯氧镁水泥(MOC)试件为基体,在空气和碳化箱中分别养护至规定龄期,研究碳化对掺加填料MOC力学性能的影响,并与空气环境进行对比,运用XRD和SEM分析碳化后水化产物和微观结构的变化规律。结果表明,28 d龄期内,随着填料掺量的增加MOC试件碳化后的抗折强度均有所增加,碳化后的抗压强度均有提升,碳化过程反应生成了MgCO_3,不同碳化龄期的主要物相均为5Mg(OH)_2·MgCl_2·8H_2O(5相),而掺加填料不影响MOC的水化产物的组成。 相似文献
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以活性较高的苛性白云石粉和氯化镁溶液制备白云石镁水泥材料。研究氧化镁、氯化镁和水不同配比条件下对白云石镁水泥材料的抗压强度、相组成以及形貌的影响。在所研究的配比条件下,以氧化镁、氯化镁和水摩尔比为3.38∶1.00∶16.86和3.24∶1.00∶16.26配比的镁水泥样块强度较高,结构致密,水化物胶凝相稳定;氯化镁加入量较低,水的加入量较高会使镁水泥试块强度不高;氯化镁加入量较高,水的加入量较低会使镁水泥试块吸潮返卤现象严重,导致强度逐渐下降。 相似文献
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氯氧镁水泥(Magnesium oxychloride cement, MOC)具有快凝、早强、高强、防火和不腐蚀玻璃纤维等优点,非常适合于制作玻璃纤维增强薄壁制品,在农业灌溉工程中具有良好的应用前景。采用XRD和TOPAS分析了新型抗水氯氧镁水泥制成内蒙古防渗渠的物相组成,探讨了氯氧镁水泥制品在自然环境的水化产物与相转变规律、以及相组成对强度的影响。结果表明,在水分缺少的条件下,氯氧镁水泥的水化产物主要为5Mg(OH)_2·MgCl_2·8H_2O(5·1·8)和Mg(OH)_2;在水分充足的条件下,水化产物主要为Mg(OH)_2和5·1·8,碳化产物为碳化氯氧化镁Mg(OH)_2·MgCl_2·2MgCO_3·6H_2O(1·1·2·6)和水菱镁矿4MgCO_3·Mg(OH)_2·4H_2O(4·1·4)。水化产物对强度有促进作用,而碳化产物会降低强度。通过10年的工程环境考验,证明新型氯氧镁水泥制品在环境中能够保持主要强度相5·1·8的稳定性,具有良好的长期力学性能。 相似文献
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This article provides an overview of several previous studies that investigated the stiffness and strength performance of chemically stabilized roadway materials under winter conditions (freeze-thaw cycling). The objective of this research was to understand the behavior of different materials stabilized with different type of binders when they were subjected to freeze-thaw cycling. Nine different materials including natural soils (organic soil, clay, silt, sand, and road surface gravel), reclaimed pavement material, and recycled asphalt pavement stabilized with nine different binders (five different fly ashes, lime, cement, lime kiln dust, cement kiln dust) were discussed. This article investigated how the volume, resilient modulus and unconfined compressive strength of soils/materials stabilized with different binders change in response to freeze-thaw cycling. Overall, the review results indicate that the stiffness and strength of all stabilized materials decrease somewhat with freeze-thaw cycling. However, the reduced strength and stiffness of stabilized materials after freeze-thaw cycling was still higher than that of unstabilized-unfrozen original soils and materials. In addition, materials stabilized with cement kiln dust provided the best performance against freeze-thaw cycling. 相似文献
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Gokhan Baykal 《寒旱区科学》2015,7(5):619-625
The construction period in cold regions is very short due to problems related to excavation and use of frozen soils in embankment construction, which leads to excessive deformations upon thawing. Also, handling of compaction water is critical due to freezing temperatures. Coalburning thermal power plants are very common in cold regions to supply electricity. The inorganic part of the pulverized coal after burning produces fly ash, which is available in large volumes. Due to excavation difficulties and the poor engineering behavior of frozen soils in cold regions, the utilization of fly ash when it is readily available must be promoted. Any construction technique which utilizes alternative materials like fly ash and minimizes water consumption has a potential to extend the short construction season and even allow service and maintenance during extreme weather conditions. This paper presents two potential techniques to solve the moisture affinity of silt-sized materials like fly ash. One technique involves in-plant production of fly ash pellets using cold-bonding pelletization to manufacture aggregates of up to 40,000-μm diameter from 15- to 60-μm-diameter fly ash grains. Large disc pelletizers have annual production capacities of up to one million ton at a reasonable cost. The product has adequate strength for embankment construction even when no water is used and no compaction is applied. The second technique is an in situ mixing technique which uses snow instead of compaction water for fly ash. The snow is the main element in this technique to compact the embankment. Water is needed for the hydration reactions to form cementitious minerals in fly ash. The slower the hydration reaction, the greater the crystal growth of cementitious minerals. In the proposed technique, in situ snow is mixed with fly ash and is compacted on-site. The temperature increase due to the hydration reaction of fly ash upon contact with snow crystals provides water for continued long-term hydration, which results in high strength, a high void ratio, light weight, and high thermal insulation capability. The presented techniques have the potential to extend the short construction season in cold regions and will provide fill material, decreasing the need for excavation. Both techniques are well documented under laboratory conditions, the research results have been published, and the techniques are ready for field trials to assess implementability. 相似文献
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The potassium supplying capacity of the waste mica powder (WMP) was evaluated through chemical and biological means. Four different size fractions of the WMP were studied in laboratory by different chemical extractants. At the same time, experiment of the plant growth was conducted in pot using K-deficient soil. The K release from the WMP by different extractants followed an increasing trend with an increase in the fineness of the particles. The highest K release was recorded by boiling 1 M HNO3 (376.4–1726.4 mg kg?1) followed by 1 M ammonium acetate (33.5–226.5 mg kg?1), 0.01 M citric acid (31.6–158.3 mg kg?1) and water (12.0–112.0 mg kg?1) irrespective of the various size fractions. Significantly, higher cumulative K release from the WMP in successive extraction was recorded with 1 M boiling HNO3 that predicts its slow-release property. The K release by different extractants was correlated significantly and positively with the biomass yield and K uptake by plants. 1 M boiling HNO3 extractable K showed higher correlation values with the biomass yield and K uptake. Therefore, it suggests that the extractant might be a better indicator of K supplying capacity of the WMP. The plant intervention was able to extract 32.8% of total K from the WMP simultaneously improving the exchangeable and non-exchangeable K pool in soil. These above-mentioned results conclude that plants can get access to a significant amount of K from the WMP and it could be an effective source of K in highly weathered tropical soils under K deficiency.
相似文献17.
为了研究氯氧镁水泥(MOC)试件分别在老卤、原卤、海水和淡水4种水环境中强度变化规律,本文以掺加一定量复合改性剂的MOC为基体,将其养护至28天后,分别置于老卤、原卤、海水和淡水中浸泡一定期龄,分析其在4种特定水环境中的强度变化规律。实验结果表明,MOC试件在4种特定水环境中抗压强度变化规律不同。相较于空气中养护,MOC在老卤、原卤、海水和淡水浸泡下,抗压强度逐渐降低,其抗压强度降低程度为老卤<原卤<海水<淡水。经4种特定水环境浸泡后,MOC抗压强度保留相在老卤中最高,其强度保留相高达95.60%,证明MOC试件在老卤中具有较好的抗盐卤腐蚀性能。 相似文献
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K. P. Kodama J. C. Lyons Peter A. Siver Anne-Marie Lott 《Journal of Paleolimnology》1997,17(2):173-189
A combined mineral magnetic and scaled chrysophyte study of lake sediments from Lake Lacawac and Lake Giles in northeastern Pennsylvania was conducted to determine the effects of land-use and sediment source changes on the variation of pH, conductivity, and alkalinity inferred from biotic changes. Ten 30–40 cm long gravity cores were collected from Lake Lacawac and three from Lake Giles. Isothermal remanent magnetizations (IRMs) were given to the lake sediments in a 1.3 T magnetic field to measure magnetic mineral concentration variations. IRM acquisition experiments were conducted to identify magnetic mineralogy. The bedrock, soils and a peat bog on the shores of Lake Lacawac were also sampled for magnetic analysis to determine possible lake sediment sources. The top 10 cm of sediment collected from Lakes Lacawac and Giles was two to four times more magnetic than deeper sediment. 210Pb dating suggests that this intensity increase commenced circa 1900. SEM images of magnetic extracts from the highly magnetic sediments indicates the presence of magnetic fly ash microspheres from fossil fuel burning electric power generation plants. The similarity in magnetic coercivity in the top 8 cm lake sediments and in the peat bog supports an atmospheric source for some of the magnetic minerals in the youngest lake sediments. The highly magnetic sediments also contain an antiferromagnetic mineral in two cores closest to Lake Lacawacs southeastern shore. This magnetic mineral is only present deep in the soil profile and would suggest erosion and significant land-use changes in the Lacawac watershed as another cause for the high magnetic intensities (concentrations) in the top 10 cm of the lake sediments. The most significant changes in the scaled chrysophyte flora occurred immediately above the 10 cm level and were used to infer a doubling of the specific conductivity between circa 1910 and 1929. These variations also support land-use changes in the Lacawac catchment at this time. A similar shift in the scaled chrysophte flora was not observed in the top of Lake Giles, however, distinct changes were found in the deeper sections of the core coupled with a smaller peak in magnetic concentration. Fourier analysis of the 210Pb-dated lake sediment magnetics indicates the presence of a 50 year period, low amplitude variation in the Lake Lacawac, Lake Giles, and Lake Waynewood (Lott et al., 1994) magnetic concentration records. After removal of the land-use/fly ash magnetic concentration peak by Gaussian filtering, the 50 year variation correlates strongly from lake to lake even though the lakes are in different watersheds separated by up to 30 km. When this magnetic variation is compared with Gaussian-filtered rainfall variations observed in New York City and Philadelphia over the past 120–250 years there is a strong correlation suggesting that magnetic concentration variations can record regional rainfall variations with an approximately 50 year period. This result indicates that magnetics could be used to document regional variations in climatic change. 相似文献