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1.
华南板块西南缘、越北地块以北桂西那坡县城以西及西南一带发育一套晚二叠世基性岩,由层状、似层状次火山岩相辉绿岩、辉绿玢岩及球状岩组成。根据岩石地球化学特征,那坡基性岩可划分为高Ti(TiO_22.8%和Ti/Y500)和低Ti两部分。高Ti基性岩为碱性玄武岩,而低Ti基性岩为拉斑玄武岩。与低Ti基性岩相比,高Ti基性岩整体具有相对较低的SiO_2、MgO和较高的FeO_t、P_2O_5,轻、重稀土分馏明显,富集大离子亲石元素(LILE)和高场强元素(HFSE),显示出似OIB地球化学特征,与峨眉山高Ti玄武岩具高度亲缘性;低Ti基性岩具有相对较高的SiO_2、MgO和较低的FeO_t、P_2O_5,稀土配分曲线较平坦,富集LILE,严重亏损HFSE(Nb、Ta),与岛弧玄武岩地球化学特征类似。从微量元素比值及相关图解对岩浆源区和构造环境判别,那坡高Ti基性岩来自富集OIB地幔源区,而低Ti基性岩兼具OIB和岛弧岩浆源区的过渡特征。结合岩石地球化学特征及区域地质背景,认为那坡高Ti基性岩可能为峨眉山地幔柱岩浆作用的产物,低Ti基性岩为古特提斯俯冲与峨眉山地幔柱共同作用的产物,揭示了那坡地区晚二叠世同时受到峨眉山地幔柱和古特提斯俯冲相互作用的影响。 相似文献
2.
Chalcophile element geochemistry and petrogenesis of high-Ti and low-Ti magmas in the Permian Emeishan large igneous province,SW China 总被引：4，自引：0，他引：4
Christina Yan Wang Mei-Fu Zhou Liang Qi 《Contributions to Mineralogy and Petrology》2011,161(2):237-254
Sulfide-poor mafic layered intrusions, sills/dykes and lava flows in the Funing region, SW China, are part of the ~260 Ma
Emeishan large igneous province. They belong to either a high-Ti group (TiO2 = 1.6–4.4 wt%) with elevated Ti/Y ratios (351–1,018), or a low-Ti group (TiO2 < 1.2 wt%) with low Ti/Y ratios (133–223). This study investigates the role of fractionation of olivine, chromite and sulfide
on the distributions of chalcophile elements, Ni, Cu and PGE, of the high-Ti and low-Ti group rocks at Funing. The high-Ti
group rocks contain 1.6–5.3 ppb Pt + Pd, 0.06–0.43 ppb Ir and 0.01–0.13 ppb Ru, and show relative constant (Cu/Pd)PM ratios (4.0–9.7) and a negative correlation between Ni/Pd and Cu/Ir ratios. Fractionated IPGE/PPGE patterns and very negative
Ru anomalies of the high-Ti group rocks, together with low Fo values (59–62 mol%) of olivine, indicate that the high-Ti magmas
may have experienced fractionation of olivine and chromite under S-undersaturated condition. Based on the PGE concentrations,
the low-Ti group rocks can be further divided into two subgroups; a high-PGE low-Ti subgroup and a low-PGE low-Ti subgroup.
The high-PGE low-Ti group rocks are rich in MgO (10–20 wt%), but Fo values of olivine from the rocks are low (74–76 mol%).
The rocks contain highly variable PGE (Pt + Pd = 1.7–88 ppb, Ir = 0.05–1.3 ppb), Ni (179 –1,380 ppm) and Cu (59–568 ppm).
They have Cu/Zr ratios >1, low (Y/Pd)PM ratios (0.2–7.1) and nearly constant (Cu/Pd)PM ratios (1.5–3.8). The even and parallel chalcophile element patterns of the high-PGE low-Ti subgroup rocks are likely a result
of olivine-dominated fractionation under S-undersaturated condition. The low-PGE low-Ti group rocks have low MgO (4.5–8.9 wt%)
and very poor PGE (Pt + Pd 0.5–1.6 ppb, Ir 0.004–0.02 ppb) with low Cu/Zr ratios (0.1–0.5), high (Y/Pd)PM (26–70) and variable (Cu/Pd)PM ratios (2.8–14). The trough-like chalcophile element patterns of the low-PGE low-Ti subgroup rocks indicate that the magmas
were sulfide saturation and sulfide melts were extracted from the magmas. The extracted sulfide melts might be potential Ni–Cu
sulfide ores at depth in the Funing region. 相似文献
3.
4.
Monireh Poshtkoohi Talat Ahmad Ashwini Kumar Choudhary 《Journal of Earth System Science》2018,127(5):72
Precambrian magmatism in the Biabanak-Bafq district represents an extensive sequence of mafic magmatic rocks. Major, trace and rare earth elements reveal that the low-Ti basement mafic rocks are magnesium tholeiite and low-Ti cover a mafic rock belongs to Fe-tholeiite, whereas, the high-Ti alkaline mafic rocks, as well as dolerites, show much more Fe–Ti enrichment. Primitive mantle normalized trace element patterns show a relative enrichment of LREE and LILE and depletion of HFSE, but have an equally distinct continental signature reflected by marked negative Nb, Sr, P, and Ti anomalies. The composition of the intrusive rocks is consistent with fractional crystallization of olivine ± clinopyroxene ± plagioclase, whereas variations in the Sr and Nd isotope compositions suggest heterogeneous sources and crustal contamination. Low-Ti group samples contain a crustal signature in the form of high La/Yb, Zr/Nb, and negative \(\varepsilon \hbox {Nd}\) values. In contrast, high-Ti mafic magmatic rocks display an increase in La/Yb with a decrease in Proterozoic alkaline rocks recognized across the central Iran. The presence of diverse mafic magmatic rocks probably reflects heterogeneous nature of sub-continental lithospheric mantle (SCLM) source. The mafic magmatism largely represents magmatic arc or rift tectonic setting. It is suggested that the SCLM sources were enriched by subduction processes and asthenospheric upwelling. 相似文献
5.
Evolution of an intra‐oceanic island arc during the Late Silurian to Late Devonian,New England Fold Belt 总被引：1，自引：1，他引：0
Geochemical studies of volcanic rocks in the Gamilaroi terrane and Calliope Volcanic Assemblage, New England Fold Belt, eastern Australia, indicate that the setting in which these rocks formed changed in both space and time. The Upper Silurian to Middle Devonian basalts of the Gamilaroi terrane show flat to slightly light rare‐earth element (LREE) depleted chondrite normalised patterns, depletion of high field strength elements (HFSE) relative to N‐MORB, low Ti/V and high Ti/Zr ratios, high Ni, Cr and large‐ion lithophile element (LILE) contents, features characteristic of intra‐oceanic island arc basaltic magmas. They are associated with low‐K, less mafic volcanics, showing moderate LREE enrichment, low Nb and Y contents and Rb/Zr ratios. The depletion of HFSE in the basalts indicates that the magmas were derived from a refractory source in a supra‐subduction zone setting. The presence of such a zone implies that the arc was associated with a backarc basin, the location of which was to the west where a wide backarc region existed from the Middle Silurian. This polarity of arc and backarc basin suggests that the subduction zone dipped to the west. In contrast to their older counterparts, Middle to Upper Devonian basalts of the Gamilaroi terrane have MORB‐like chondrite normalised patterns and higher Ti and lower LILE contents. Moreover, they have low Ti/Zr ratios and MORB‐like Ti/V ratios and HFSE contents, features typical of backarc basins. Dolerites of the Gamilaroi terrane also have predominantly backarc basin signatures. These features suggest that both the basalts and dolerites have been emplaced in an extensional environment produced during the rifting of the intra‐oceanic island arc lithosphere. A progressive increase in Ti/V ratios, and TiO2 and Fe2O3 contents at constant MgO, of stratigraphically equivalent basalts, towards the north‐northwest part of the belt, is consistent with either greater extension to the north or melting of a more fertile magma source. By contrast, basalts in the southeast part of the terrane have moderately high Ti/Zr and low Ti/V ratios and in some samples, exhibit depletion of HFSE, compositional features transitional between island arc and backarc basin basalts. The Lower to Middle Devonian mafic rocks in the Calliope Volcanic Assemblage show both LREE enriched and depleted chondrite normalised REE patterns. Further, the majority have high Ti/Zr ratios and low Zr contents as well as relatively high Th contents relative to MORB. These features are common to rocks of Middle Devonian age as well as those of Early Devonian age and are suggestive of eruption in an arc setting. Thus, the data from this study provide new evidence for the evolution of the New England Fold Belt from the Late Silurian to the Late Devonian and reveal a history more complicated than previously reported. 相似文献
6.
Tong Hou Zhaochong Zhang Timothy Kusky Yangsong Du Junlai Liu Zhidan Zhao 《Ore Geology Reviews》2011,41(1):133-143
Based on published data, we reappraise the classification of high-Ti and low-Ti basalt from the Emeishan large igneous province (ELIP) and the correlations between basalts and mafic–ultramafic intrusions. Because of the lack of clear spatial and temporal variations of different types of basalts, we suggest that the basalts in the ELIP cannot be classified into high-Ti and low-Ti groups, by TiO2 contents and/or Ti/Y ratios. The distinctive characteristics of these high-Ti and low-Ti lavas probably result largely from the different fractionating assemblages. Whether or not fractional crystallization of the Fe–Ti oxides occurred probably is the key factor that controls the Ti abundances and Ti/Y ratios in the residual melts, e.g., lavas, although the nature of the mantle sources, variable degrees of partial melting of mantle and crustal contamination also influence the geochemical signatures of the lavas. Therefore, neither Ti abundance nor Ti/Y ratios in basalts can reflect the nature of their mantle source. Moreover, the different types of mafic–ultramafic intrusions in the ELIP cannot simply be attributed to be genetically related special types of basalts, either high-Ti or low-Ti basalts. It is likely that they are merely the cumulus phases, i.e. chamber or conduit of the basaltic lavas. Hence, caution should be exercised in the use of high-Ti or low-Ti basalts as prospecting vectors for ore deposits in the region. Potential implications are proposed that both the Fe–V–Ti oxide and Cu–Ni–(PGE) sulfide mineralization in the ELIP intrusions is largely due to the variable differentiation and crustal contamination during magmatic processes. 相似文献
7.
Mei-Fu Zhou Jun-Hong Zhao Liang Qi Wenchao Su Ruizhong Hu 《Contributions to Mineralogy and Petrology》2006,151(1):1-19
Mafic-layered intrusions and sills and spatially associated andesitic basalts are well preserved in the Funing area, SW China.
The 258±3 Ma-layered intrusions are composed of fine-grained gabbro, gabbro and diorite. The 260±3 Ma sills consist of undifferentiated
diabases. Both the layered intrusions and volcanic rocks belong to a low-Ti group, whereas the diabases belong to a high-Ti
group. Rocks of the high-Ti group have FeO, TiO2 and P2O5 higher but MgO and Th/Nb ratios lower than those of the low-Ti group. They have initial 87Sr/86Sr ratios (0.706–0.707) lower and ɛNd (−1.5 to −0.6) higher than the low-Ti equivalents (0.710–0.715 and −9.6 to −4.0, respectively).
The high-Ti group was formed from relatively primitive, high-Ti magmas generated by low degrees (7.3 –9.5%) of partial melting
of an enriched, OIB-type asthenospheric mantle source. The low-Ti group may have formed from melts derived from an EM2-like,
lithospheric mantle source. The mafic rocks at Funing are part of the Emeishan large igneous province formed by a mantle plume
at ∼260 Ma. 相似文献
8.
Summary The Palampur metavolcanics (PV) in the northwest Himalaya are part of the Late Archaean (2.5 Ga) Rampur flood basalt province (RFBP) which represents one of the oldest manifestation of worldwide mafic magmatism. The volcanics occur as mafic lava flows with evidence of two phases of deformation. The first phase resulted in recrystallisation which almost completely obliterated the primary mineralogy, and the second phase was of weak cataclasis. Immobile trace element ratios as well as cation percent Al - (Fe - Ti) - Mg indicate that the volcanics are tholeiitic in composition. The chemical characteristics, such as the decoupling between HFS and LIL elements i.e., distinct negative Sr, Nb and Ti anomalies in the double normalisation ratios spiderdiagram together with low Ti/Y and Zr/Y ratios, testify the rocks as low-Ti continental flood basalts. The chemical variations in the volcanics can be related to varying extents of partial melting of the mantle source(s), followed by fractional crystallisation (predominantly olivine and clinopyroxene over plagioclase). Positive correlation between LREE and Fe abundances, Ce-Nd and Y/Nd-Zr/Y data preclude any significant role of crustal contamination in the evolution of their bulk chemistry. The REE data and [Mg]-[Fe] relations rather suggest that the parental magma of the PV derived from non-pyrolitic source(s) which was heterogeneous with respect to enrichment in Zr, LREE and Fe/Mg ratios. Mantle metasomatism appears to be the main process of such source enrichment, possibly caused by the addition of a volatilerich silicate melt phase.[/ p]
Geochemie und Petrogenese der Palampur Metavulkanite, Lesser Himachal Himalaya, Indien
Zusammenfassung Die Palampur Metavulkanite (PV), im nordwestlichen Himalaya, gehören zur spätarchaiischen (2.5 Ga) Rampur Plateau-Basalt-Provinz (RFBP), die einen der ältesten, weltweiten Phasen von mafischem Magmatismus manifestiert. Die Vulkanite treten als mafische Lavaströme auf und zeigen zwei Phasen von Deformation. Die erste resultierte in einer Rekristallisation, die nahezu den gesamten primären Mineralbestand überprägt hat. Die zweite Phase ist durch schwache Kataklase repräsentiert. Immobile Spurenelementverhältnisse, wie auch die Kationenprozent von Al- (Fe- (-Ti) -Mg, deuten eine tholeiitische Zusammensetzung der Vulkanite an. Die chemischen Charakteristika, die im unterschiedlichen Verhalten der HFS und LIL Elemente deutlich werden, deutlich negative Sr, Nb und Ti Anomalien in den zweifach normalisierten Spiderdiagrammen, niedrige Ti/Y und Zr/Y Verhältnisse, bezeugen, dass es sich um Ti-arme, kontinentale Plateaubasalte handelt. Die chemischen Unterschiede innerhalb der Vulkanite können auf unterschiedliche Grade von Aufschmelzung des (der) Mantelmaterials(e), gefolgt von fraktionierter Kristallisation (vor allem Olivin und Klinopyroxen, untergeordnet Plagioklas), zurückgeführt werden. Positive Korrelation der LREE mit Fe, wie auch die Ce-Nd und Y/Nd-Zr/Y Daten schließen eine signifikante Rolle von Krustenkontamination in der Evolution der Gesteinschemie aus. Die REE Daten und die /Mg/-/Fe/ Verhältnisse lassen eher vermuten, dass das Ausgangsmagma der PV von einem nicht-pyrolitischen Material stammt, welches bezüglich Anreicherung an Zr, LREE und Fe/Mg Verhältnis heterogen gewesen ist. Mantelmetasomatose scheint der Hauptprozeß für diese Anreicherng des Ausgangsmaterials gewesen zu sein, die möglicherweise durch Zufuhr einer silikatischen Schmelzphase, reich an flüchtigen Bestandteilen, hervorgerufen wurde.[/ p]相似文献
9.
乌鞘岭蛇绿混杂岩位于北祁连造山带东段,具有相对完整的蛇绿岩序列,包括：变质地幔橄榄岩单元（蛇纹岩＋辉橄岩）,镁铁质一超镁铁质堆晶岩单元（橄辉岩＋辉石岩）,镁铁质侵入岩单元（辉长岩）,及基性火山岩单元（玄武岩）。依照TiO,的含量,本文从乌鞘岭蛇绿混杂岩中分出两类玄武岩,即：低n玄武岩（Ti02=0．55％～0．76％）和高Ti玄武岩（Ti02=1．35％-1．99％）。低Ti玄武岩大离子亲石元素含量波动较大,具明显n负异常,LREE呈略富集的配分模式,整体上具有弧火山岩的特征;高Ti玄武岩大离子亲石元素含量在小范围内变化,未见Nb、Ti负异常,LPtEE呈略亏损的配分模式,具有典型N—MORB的性质。在构造环境判别图上,低n玄武岩和高Ti玄武岩分别落入陆缘弧和大洋中脊环境。高Ti玄武岩是鸟鞘岭蛇绿混杂岩的一部分,源于亏损地幔的部分熔融,与陆缘弧型低rri玄武岩构造混杂在一起。乌鞘岭蛇绿混杂岩大概于中一晚奥陶世形成于北祁连造山带老虎山一毛毛山弧后盆地。 相似文献
10.
A coherent ophiolitic complex of pyroxenite, serpentinite, metagabbro, mafic volcanics, felsic volcanics and sediments crops out in NW Maine, adjacent to the Chain Lakes massif. The complex (here informally referred to as the Boil Mountain ophiolitic complex) is about 500 m.y. old. The volcanic sequence is not typical of ophiolites in that it contains a large proportion of felsic volcanics. The mafic volcanics are divided into two geochemical groups. A stratigraphically lower group is depleted in Ti, Zr, Y, Cr and REE contents similar to basalts from supra-subduction zone ophiolites. An upper mafic group has trace element contents similar to normal mid-ocean ridge basalts. The felsic volcanics are mostly rhyolitic and similar to low-K rhyolites found in the forearc of the Marianas trench and in an island arc sequence in the Klamath Mountains, California. The flat REE patterns of the felsic volcanic rocks are similar to those found in siliceous rocks in the Oman ophiolite. The presence of thick sequences of felsic volcanics, the abundance of pyroxenite, the low Ti, Zr and REE contents of some mafic rocks, the flat REE patterns of the felsic volcanics, and the composition of clinopyroxene all suggest the complex was formed in the vicinity of a subduction zone. The complex may be correlated with ophiolitic fragments in the eastern part of the Dunnage Zone in Newfoundland, rather than the main ophiolite belt of the western Appalachians. 相似文献
11.
An integrated study on petrology and geochemistry has been carried out on the Late Carboniferous I-type felsic volcanics of the Liushugou Formation in the Bogda belt to constrain the late Paleozoic tectonic evolution of the Bogda belt. The felsic volcanics were dated to be 315 to 319 Ma and are composed of trachy-andesite–trachyte ignimbrites and rhyolite lavas. They are in conformable contact with high-Al basalt. The eruption of the felsic volcanics and high-Al basalt is not bimodal volcanism, but is related to bimodal magma (basaltic and rhyolitic magmas). MELTS modeling and comparison with previous basaltic melting experiments indicate that the felsic volcanics are likely produced by partial melting of hydrated mafic crust rather than fractional crystallization of high-Al basalt. It is also supported by relatively large amounts of felsic volcanics to high-Al basalts and remarkably different incompatible element ratios (e.g., Th/Zr, Nb/Zr and U/Zr) of the rocks. The Bogda felsic volcanics have positive εNd(t) values (6.2–7.4), low Pb isotopes and low zircon saturation temperatures, consistent with a derivation from a juvenile crust in an arc setting. The intermediate ignimbrites display melting–mingling textures and abundant feldspar aggregates and have various δEu ratios, indicating that magma mingling and feldspar fractionation processes may have played an important role in the genesis of the ignimbrites. In contrast, the Early Permian felsic rocks in this region are of post-collisional A-type. We therefore propose that the Bogda belt was an island arc in the Late Carboniferous and then switched to a post-collisional setting in the Early Permian due to the arc–arc collision at the end of the Late Carboniferous. 相似文献
12.
We report a new whole-rock dataset of major and trace element abundances and 87Sr/86Sr–143Nd/144Nd isotope ratios for basaltic to rhyolitic lavas from the Rooiberg continental large igneous province (LIP). The formation of the Paleoproterozoic Rooiberg Group is contemporaneous with and spatially related to the layered intrusion of the Bushveld Complex, which stratigraphically separates the volcanic succession. Our new data confirm the presence of low- and high-Ti mafic and intermediate lavas (basaltic—andesitic compositions) with >?4 wt% MgO, as well as evolved rocks (andesitic—rhyolitic compositions), characterized by MgO contents of <?4 wt%. The high- and low-Ti basaltic lavas have different incompatible trace element ratios (e.g. (La/Sm)N, Nb/Y and Ti/Y), indicating a different petrogenesis. MELTS modelling shows that the evolved lavas are formed by fractional crystallization from the mafic low-Ti lavas at low-to-moderate pressures (~?4 kbar). Primitive mantle-normalized trace element patterns of the Rooiberg rocks show an enrichment of large ion lithophile elements (LILE), rare-earth elements (REE) and pronounced negative anomalies of Nb, Ta, P, Ti and a positive Pb anomaly. Unaltered Rooiberg lavas have negative εNdi (??5.2 to ??9.4) and radiogenic εSri (6.6 to 105) ratios (at 2061 Ma). These data overlap with isotope and trace element compositions of purported parental melts to the Bushveld Complex, especially for the lower zone. We suggest that the Rooiberg suite originated from a source similar to the composition of the B1-magma suggested as parental to the Bushveld Lower Zone, or that the lavas represent eruptive successions of fractional crystallization products related to the ultramafic cumulates that were forming at depth. The Rooiberg magmas may have formed by 10–20% crustal assimilation by the fractionation of a very primitive mantle-derived melt within the upper crust of the Kaapvaal Craton. Alternatively, the magmas represent mixtures of melts from a primitive, sub-lithospheric mantle plume and an enriched sub-continental lithospheric mantle (SCLM) component with harzburgitic composition. Regardless of which of the two scenarios is invoked, the lavas of the Rooiberg Group show geochemical similarities to the Jurassic Karoo flood basalts, implying that the Archean lithosphere strongly affected both of these large-scale melting events. 相似文献
13.
Major, trace element, and Sr isotopic data are reported forvolcanic rocks from the island of Alicudi, Aeolian Arc, SouthernTyrrhenian Sea. The island is constructed of basalt, basalticandesite to high-K andesite lavas, and pyroclastites, whichshow a continuum in the variation of many major and trace elements.Total iron, MgO, CaO, Ni, Co, Sc, and Cr decrease with increasingsilica, whereas incompatible elements Rb, Ba, Th, and LREE displaythe opposite tendency. Very significant positive correlationsare defined by incompatible elements on interelemental variationdiagrams. Sr isotopic ratios vary from 0–70352 to 0–70410.Overall, basalts (0–70352–O-70410) and basalticandesltes (0–70356–0–70409) are enriched in87Sr compared with high-K andesites (O–70352–O–70367),which display the lowest Sr isotopic ratios within the entireAeolian archipelago. Overall negative relationships exist between87Sr/86Sr and several incompatible trace element abundancesand ratios, such as Th, U, LREE, Zr, La/Yb, and Th/Hf. Otherelemental ratios such as La/Rb, Ba/Rb, and Sr/Rb show more complexbehaviour, even though negative correlations with Sr isotopicratios are observed in the basalts. The observed compositional variations are best explained interms of a model in which primitive calc-alkaline magmas evolvedby crystal-liquid fractionation to give a series of variouslydifferentiated liquids, which underwent different degrees ofinteraction with crustal material. The more mafic and hotterbasaltic liquids appear to have assimilated higher amounts ofmetamorphic wall rocks than did the cooler late erupted andesiticmagmas. This process produced significant variations of Sr isotopicratios, Rb, Cs, Rb/Sr ratios, and LILE/Rb ratios in mafic magmas,but had only minor effects on the abundances and ratios of otherincompatible elements such as Th, LREE, La/Yb, and Th/Hf. When compared with mafic rocks from other Aeolian islands, theAlicudi basalts are more primitive geochemically and isotopically.Going eastward, there is a decrease in Ni and Cr abundances,mg-number and Nd isotopic ratios which parallels an increaseof Sr isotopic ratios in basaltic rocks along the arc. Thesecompositional variations are typical of volcanic series whichhave undergone interaction with upper-crustal material, andsuggest that this process may have contributed significantlyto the regional geochemical and isotopic trends observed inthe Aeolian arc. 相似文献
14.
Melting of metasomatized subcontinental lithosphere: undersaturated mafic lavas from Rungwe,Tanzania 总被引：1，自引：0，他引：1
Tanya Furman 《Contributions to Mineralogy and Petrology》1995,122(1-2):97-115
This paper uses the geochemistry of primitive mafic lavas from the Rungwe volcanic province (southwestern Tanzania) to infer
the source mineralogy and melting history. Post-Miocene mafic lavas from Rungwe include alkali basalts, basanites, nephelinites
and picrites with up to 18.9 wt% MgO; nephelinites (>13.5% normative nepheline) are restricted to Kiejo volcano in the southern
portion of the province. Rungwe lavas differ from most Western Rift volcanics in that they are not unusually potassic (K2O/Na2O ca. 0.40). Sparsely phyric mafic lavas contain phenocrysts and xenocrysts of plagioclase (An82–90), clinopyroxene (4.5–9.5 wt% Al2O3), and olivine (Fo79–88); one basanite contains a 1 mm xenocryst of apatite included in magnesian clinopyroxene. All samples have high abundances
of incompatible elements (e.g., 0.7–2.2 wt% P2O5) and are enriched in REE relative to HFSE (Hf, Zr, Ti, Y), Cs, Ba, and K. Some incompatible element ratios are constant throughout
the Rungwe suite (e.g., Zr/Nb, Sr/Ce, K/Rb), but other ratios are extremely variable and exceed the range measured in global
Ocean Island Basalts (OIB) (e.g., Ba/Nb, Sm/Zr, La/Nb, Pb/Ce, Nb/U). The range in degree of silica saturation, and its excellent
correlation with P2O5/Al2O3, indicate that the Rungwe suite records variable degrees of melting. Variations of individual incompatible trace element
abundances in nephelinite and basanite samples suggest that the source contains metasomatic amphibole, ilmenite, apatite,
and zircon. The Rungwe suite is interpreted as a series of low-percentage melts of CO2-rich peridotite at pressures that span the garnet-spinel transition. A geochemical comparison of Rungwe samples to lavas
from other Western Rift volcanic centers requires that the source mineralogy varies along the rift axis, although each province
is underlain by metasomatized peridotite. The incompatible trace element signatures of Western Rift lavas indicate that the
source area is typically homogeneous on the scale of individual volcanoes, although lavas from each volcano reflect a range
in degree of melting. Significantly, volcanoes with distinct geochemistry are always separated by major rift faults, suggesting
that volcanic and tectonic surface features may correspond to metasomatic provinces within the subcontinental lithospheric
mantle.
Received: 30 May 1994 / Accepted: 5 April 1995 相似文献
15.
万宝沟群位于柴达木地块南缘、东昆仑造山带中段,主要由溢流相玄武岩、火山和陆源碎屑岩以及灰岩组成。万宝沟玄武岩可以分为两类:高Ti碱性玄武岩和低Ti拉斑玄武岩,前者具有高的Ti/Y(502~660)、Nb/Y(0.8~1.6)值和Ti O2含量(2.76%~4.97%),与OIB类似;后者具有相对低的Ti/Y(383~439)、Nb/Y(0.3~0.4)值和Ti O2含量(1.80%~2.49%),与E-MORB类似。SIMS锆石年代学结果表明万宝沟玄武岩形成于新元古代(762±2 Ma)。野外地层和地球化学特征显示万宝沟玄武岩可能形成于大陆裂谷或者初始洋盆环境,代表Rodinia超大陆裂解的峰期阶段。 相似文献
16.
Constraints on the Mantle Sources of the Deccan Traps from the Petrology and Geochemistry of the Basalts of Gujarat State (Western India) 总被引：6，自引：3，他引：3
MELLUSO L.; BECCALUVA L.; BROTZU P.; GREGNANIN A.; GUPTA A. K.; MORBIDELLI L.; TRAVERSA G. 《Journal of Petrology》1995,36(5):1393-1432
The late Cretaceous-early Tertiary flood basalts in the Gujaratarea of the northwestern Deccan Traps (Kathiawar peninsula,Pavagadh hills and Rajpipla) exhibit a wide range of compositions,from picrite basalts to rhyolites; moreover, the basaltic rockshave clearly distinct TiO2 contents at any given degree of differentiationand strongly resemble the low-titanium and hightitanium basaltsfound in most of the Gondwana continental flood basalt (CFB)suites. Four magma groups are petrologically and geochemicallydistinguished: (1) A low-Ti group, characterized by rocks with varying SiO2saturation, and with TiO2 <1•8 wt%, extremely low incompatibletrace element abundances, low Zr/ (av- 3•8), Ti/ V (av.27), and a very slight large ion lithophile element (LJLE) enrichmentover high field strength elements (HFSE). These rocks sharesome features with the Bushe Formation of the Western Ghatsfarther south, but have distinct geochemical characters, inparticular the strong depletion in most incompatible trace elements. (2) A high-Ti group, characterized by a more K-rich characterthan the low-Ti rocks, and with a strong enrichment in incompatibleelements, similar to average ocean island basalt (OIB), e.g.high TiO2 (>1•8 wt% in picrites), Nb (>19 p.p.m.)Zr/ (av. 6•5) and Tt/V (av. 47). (3) An intermediate-Ti group, with TiO2 contents slightly lowerthan the high-Ti rocks at the same degree of evolution, andwith correspondingly lower incompatible trace element contentsand ratios, in particular K2O, Nb, Ba and Zr/Y (av. 5•2). (4) A potassium-rich group (KT), broadly similar in geochemicalcharacter to the high-Ti group but showing more extreme K, Rband Ba enrichment (av. K20/Na20l; Ba/Y20). The most primitive low-Ti and high-Ti picrites, when correctedfor low-pressure olivine fractionation, show distinct major(and trace) element geochemistry, in particular for CaO/AI2O3,CaO/TiO2 and Al2O3/TiO2, and moderate but significant variationsin their SiO2 and Fe2Ost contents; these characteristics stronglysuggest the involvement of different mantle sources, more depletedfor the low-Ti picrites, and richer in cpxfor the high-Ti picrites,but with broadly the same pressures of equilibration (27–14kbar). This, in turn, suggests a strong lateral heterogeneityin the Gujarat Trap mantle. Low-Ti picrites and related differentiatesin Kathiawar are reported systematically for the first timehere, and suggest the existence of HFSE-depleted mantle in thenorthwestern Deccan Traps, with extension at least to the SeychellesIslands and to the area of the Bushe Formation near Bombay inthe pre-drift position, before the development of the CarlsbergRidge. The absence of correlations between LILE/HFSE ratiosand SiO2 argues against crustal contamination processes actingon the low-Ti picrites, possibly owing to their probably rapiduprise to the surface. Consequently, the mantle region of thisrock group was probably re-enriched by small amounts of ULE-richmaterials. The substantially higher, trace element enrichmentof the least differentiated high-Ti picrites, relative to thebasalts of the Ambe-noli and Mahableshwar Formations of theWestern Ghats, testifies also to the presence of more incompatibleelement rich, OIB4ike mantle sources in northern and northwesternGujarat. These sources were geochemicaily similar to the present-dayReunion mantle sources. KEY WORDS: Deccan Traps; geochemistry; petrology; picrite basalts; western India
*Corresponding author, e-mail: mellujo{at}ds.cued.unina.it 相似文献
17.
In this paper, we present data on major and trace elements in highly metamorphosed mafic rocks from the granulite-gneiss complex of the Angara-Kan block (southwestern Siberian craton), identify igneous protoliths of the metabasites, and assess the mobility of elements during metamorphism. Two types of rocks with different geologic relations and compositions were recognized. Garnet-bearing two-pyroxene granulites (Cpx + Pl + Grt + Opx) occur as sheet- and boudin-like bodies, which were folded and deformed with their host paragneisses. Dikes, which in most cases underwent only brittle deformation, are composed of metabasites characterized by the assemblage Cpx + Hbl + Pl + Grt. The major element compositions of igneous protoliths for the mafic granulites and metabasite dykes correspond to variously differentiated basaltic magmas. The protoliths of the metabasites are depleted in K2O, LILE, Zr, Nb, and LREE and were derived from a depleted mantle source. The major and trace element compositions of the dike metabasites are similar to those of low-K tholeiitic basalts of oceanic island arcs. Continental intraplate basalts derived from an enriched mantle source are possible igneous protoliths for the mafic granulites enriched in Ba, LREE, Nb, Ta, Zr, and Hf. It is assumed that lower Rb, Th, and U contents in the mafic granulites compared with continental flood basalts, high K/Rb and La/Th, and moderate Th/U ratios reflect the loss of Rb, Th and U during granulite-facies metamorphism. 相似文献
18.
Recent work on the Panzhihua intrusion has produced two separate models for the crystallisation of the intrusion:（1） low-Ti,high CaO and low H2O（0.5 wt.%） parent magma（equivalent to Emeishan low-Ti basalt） at FMQ;and（2） high-Ti,low CaO and higher H2O（>1.5 wt.%） parent magma（equivalent to Emeishan high-Ti basalt） at FMQ + 1.5.Modelling of these parent magma compositions produces significantly different results. We present here detailed f（O2） and H2O modelling for average compositions of both Emeishan high-Ti and low-Ti ferrobasalts in order to constrain the effects on crystallisation sequences for Emeishan ultra-mafic -mafic layered intrusions.Modelling is consistent with numerous experimental studies on ferro-basaltic magmas from other localities（e.g.Skaergaard intrusion）.Modelling is compared with the geology of the Panzhihua intrusion in order to constrain the crystallisation of the gabbroic rocks and the Fe-Ti oxides ore layers.We suggest that the gabbroic rocks at the Panzhihua intrusion can be best explained by crystallisation from a parent magma similar to that of the high-Ti Emeishan basalt at moderate H2O contents（0.5-1 wt.%） but at the lower end of TiO2 content for typical high-Ti basalts（2.5 wt.%TiO2）. Distinct silicate disequilibrium textures in the Fe-Ti oxide ore layers suggest that an influx of H2O may be responsible for changing the crystallisation path.An increase in H2O during crystallisation of gabbroic rocks will result in the depression of silicate liquidus temperatures and resultant disequilibrium with the liquid.Continued cooling of the magma with high H2O then results in precipitation of Mt-Uv alone. The H2O content of parent magmas for mafic layered intrusions associated with the ELIP is an important variable.H2O alters the crystallisation sequence of the basaltic magmas so that at high H2O and f（O2） Mt -Uv crystallises earlier than plagioclase and clinopyroxene.Furthermore,the addition of H2O to an anhydrous magma can explain silicate disequilibrium texture observed in the Fe-Ti oxide ore layers. 相似文献
19.
Neoproterozoic zirconium-depleted boninite and tholeiitic series rocks from Adola, southern Ethiopia 总被引：1，自引：0，他引：1
In Adola, southern Ethiopia, mafic and ultramafic igneous rocks occur in narrow, 4–10 km wide, north-south-trending belts bounded by high-grade gneisses and migmatites. The mafic/ultramafic rocks are complexly deformed and metamorphosed in greenschist to lower amphibolite facies and are thought to be tectonically dismembered parts of an ophiolite complex. Preliminary geochemical and geochronological data highlight that the high-grade rocks in southern Ethiopia and northern Kenya include a significant portion of juvenile rocks that were accreted at the same time as ophiolitic rocks at 885-765 Ma. This is also the time of widespread oceanic magmatism and closure in the Arabian-Nubian Shield to the north.The Adola mafic rocks were previously described as island arc tholeiites and mid-ocean ridge basalts (MORB). New chemical analyses on the Megado belt rocks reveal the presence of boninites and related dacites interspersed with tholeiitic rocks. The Adola boninites are similar to the Cambrian boninites in western Tasmania in having relatively low Zr/Sm (≤32). Boninites with similarly low ratios have not been reported from elsewhere.The Adola tholeiites have high Ti/Zr (150–300). Mixing between tholeiite and boninite magmas may have resulted in elevated Ti/Zr (80–126) in some Adola boninites. Otherwise, Ti/Zr in the latter is low (20–40). Low Ti/Zr is characteristic of Tertiary boninites in the west Pacific. The fact that both Ti/Eu and Zr/Sm increase from the Adola and Tasmania type to the Tertiary boninites at constant Ti/Zr suggests that Ti might be an element that is also metasomatically added to the source of boninites and raises doubts about the role of amphibole in boninite petrogenesis. 相似文献
20.
《Gondwana Research》2001,4(3):455-463
Incompatible high-field strength element geochemistry divides mafic intrusive rocks of Garhwal Himalaya, exposed in the Bhagirathi and Yamuna valleys, into two distinct types, viz. older Garhwal Mafic Intrusive Rocks (GMIR1) and younger Garhwal Mafic Intrusive Rocks (GMIR2). GMIR1 is mainly associated with the Central Crystallines, whereas, GMIR2 belongs to the Garhwal Group. They outcrop close to the Main Central Thrust (MCT) Zone and extend in a NW-SE direction, following the strike direction. Both types are metamorphosed to amphibolite facies and classified as sub-alkaline, high-Fe tholeiitic basalts. They are enriched in large-ion lithophile and high-field strength elements relative to a primitive mantle source. GMIR2 has higher concentrations of incompatible high-field strength elements than the GMIR1. Further, on multi-element spidergrams, GMIR1 samples do not show any elemental anomaly but GMIR2 samples show distinct negative Nb and Sr anomalies. GMIR1 multi-element and rare-earth element trends are similar to N-MORB, whereas, GMIR2 follows trends observed in the within plate basalts (continental flood basalts type). Discrimination diagrams, based on incompatible trace elements, corroborate the N-MORB nature of GMIR1 and CFB (WPB) nature of GMIR2. Geochemical modeling indicates that these mafic intrusive rocks were derived by close-system fractional crystallization of depleted (for GMIR1) to variably enriched parental basalts (for GMIR2). Probably these two contrasting mafic rock types have been juxtaposed during the Himalayan orogeny. Proterozoic mafic rocks of similar geochemical characteristics have been reported from different parts of the northern Indian lithosphere. Observed composition suggests its genetic association with the sub-continental lithosphere rather than effect of crustal contamination. 相似文献