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1.
贵州稀土矿及成矿地质特征 总被引：1，自引：0，他引：1
本文简要介绍了稀土元素地球化学性质和成矿作用特点,结合贵州主要以重稀土元素为主,矿床类型属稀土作为副产品的伴生沉积矿床,从含矿沉积建造,岩相古地理环境,稀土元素的矿化富集特征等方面,较为详细地阐述了贵州稀土元素的成矿地质特征。 相似文献
2.
Shilpa Vuba Sadia Farnaaz Netramani Sagar S. Masood Ahmad 《Journal of the Geological Society of India》2013,82(3):217-226
The major, trace and rare earth elements geochemistry and clay mineral compositions in the river bed sediments from lower reaches of Godavari river suggest that they are derived from weathering of felsic rocks. Trace and rare earth elemental compositions indicate evidence of sedimentary sorting during transportation and deposition. Lower concentrations of transition elements, such as V, Ni and Cr imply enrichment of felsic minerals in these bed sediments. The REE pattern in lower Godavari sediments is influenced by the degree of source rock weathering. The light rare earth elements (LREE) content are indicating greater fractionation compared to the heavy rare earth elements (HREE). A striking relationship is observed between TiO2 and gZREE content suggesting a strong control by LREE-enriched titaniferous minerals on REE chemistry. Shale-normalized REE pattern demonstrate a positive Eu anomaly, suggesting weathering of feldspar and their secondary products, which are enriched in Eu. Chondrite-normalised REE pattern is characteristic of felsic volcanic, granites and gnessic source rocks. Trace elemental compositions in sediments located near urban areas suggest influence of anthropogenic activity. Chemical Index of Alteration (CIA) is high (avg. 65.76), suggesting a moderate chemical weathering environment. X-ray diffraction analysis of clay fraction shows predominance of clay minerals that are formed because of the chemical weathering of felsic rocks. 相似文献
3.
沉积岩的微量、稀土元素对沉积环境的水介质变化有着较高的敏感度,对于研究古环境、沉积物源性质和构造背景方面具有重要的意义。前人对于东台坳陷元素地球化学方面的研究相对薄弱,利用元素地球化学资料解释古环境和源区性质方面的研究尚属空白。本文以苏北东台坳陷古新统阜宁组三段20件泥岩样品为研究对象,对其进行微量、稀土元素测定,并分析其地球化学特征及所揭示的地质意义。结果表明:(1)Sr含量、Sr/Cu、Rb/Sr、La_n/Yb_n比值指示干热气候;Li、Sr、Ni、Ga微量元素含量和Sr/Ba比值均指示淡水—半咸水的水体环境,整体以淡水环境为主,偶有咸水注入盆地,局部为半咸水环境;而V/(V+Ni)、V/Cr、Ni/Co、U/Th、δCe指示氧化—弱还原的水体环境。(2)Co/Th—La/Sc、La/Th—Hf判别图解和稀土元素配分模式,表明阜宁组三段沉积岩应来自于上地壳的长英质物质。(3)La—Th—Sc、Th—Co—Zr/10和Th—Sc—Zr/10构造背景判别图解反映了大陆岛弧与活动大陆边缘的构造背景,且与Bhatia不同构造背景杂砂岩的微量、稀土元素特征值的对比分析结果一致。 相似文献
4.
马尼特金矿床位于东昆仑木孜塔格-布青山蛇绿混杂岩带,是近年来在东昆仑发现的与马尔争组地层有关的构造蚀变岩型小型金矿床,矿体主要赋存于晚三叠世花岗闪长岩与围岩的接触部位。本次研究通过对赋矿花岗闪长岩体的LA-ICP-MS锆石U-Pb定年,全岩主量元素、微量元素的研究,探讨了该岩体的形成时代,成因类型及其形成构造环境。结果显示:该花岗闪长岩的锆石U-Pb年龄为213.25 Ma±0.62 Ma(MSWD=0.99),代表其侵入时代为晚三叠世。岩石w(SiO2)在66.96%~68.3%之间,K2O/Na2O=0.54~0.63,相对富钠,贫w(MnO)(平均0.03%),w(P2O5)(0.14%~0.16%)和w(TiO2)(0.4%~0.46%),A/CNK值为1.05~1.16,平均1.106,w(Al2O3)介于15.37%~15.72%之间,里特曼指数δ值为1.43%~1.89%,TFeO/MgO为1.72~1.84,DI为74.19~79.94,表明其为过铝质、钙碱性系列的I型花岗岩。岩石稀土总量较低(ΣREE=110.67×10^-6~121.36×10^-6),表现出轻稀土富集而重稀土亏损的右倾曲线,LREE/HREE=13.54~15.12,[(La/Yb)N=20.42~20.7],轻重稀土分馏明显,负Eu异常中等(δEu介于0.94~0.99之间),大离子亲石元素Rb,Ba,Sr以及U,Th相对富集,高场强元素Nb,Ta及K,P,Ti相对亏损,具有火山弧花岗岩特征。结合其形成时代及区域构造背景,认为其形成于早-中生代巴颜喀拉地块和东昆仑地块后碰撞构造环境。 相似文献
5.
为了解由早期(伟晶、巨晶)斑状二长花岗岩、中期(细粒)花岗岩和晚期花岗(斑)岩脉组成的马鞍山杂岩体的成因, 采用SHRIMP和LA-ICP-MS锆石U-Pb法厘定其侵入时代, 年龄显示伟晶斑状二长花岗岩为132.2±1.6 Ma, 巨晶斑状二长花岗岩为127. 7±1.2 Ma, 细粒花岗岩为128.3±1.1 Ma, 花岗斑岩脉为127.4±1.8 Ma.岩石地球化学研究结果表明岩体从早到晚具有从钾玄岩系列向高钾钙碱系列演变特征, 分异演化程度逐渐变高; 斑状二长花岗岩具有高REE含量, 轻重稀土分异较为明显, 具较强负铕异常和弱右倾的配分曲线特征, 富集K、Th、U、Rb等元素, 弱亏损Ba、Sr、P、Nb、Ta、Ti等元素; 细粒花岗岩及花岗(斑)岩脉具有较低REE含量, 轻重稀土分异不明显, 具强负铕异常和"V"型配分曲线特征, 富集K、Th、U、Rb等元素, 强亏损Ba、Sr、P、Nb、Ti等元素.马鞍山岩体为浙西北-皖南地区早白垩世俯冲造山后陆内拉张作用环境下下地壳部分熔融的同源岩浆侵位结晶分异作用形成的产物, 具有高分异I型花岗岩的特征. 相似文献
6.
中国大陆架海底沉积物中的稀土元素 总被引：32，自引：2，他引：30
选择渤海、黄海、东海和南海有代表性的大陆架沉积物样品,利用X射张荧光光谱法测定了15个稀土元素。中国大陆架沉积物稀土元素的丰度为156ppm,相对接近于中国黄土和花岗岩的丰度,而与太平洋沉积物的丰度相差较远,具有明显的“亲陆性”。稀土的配分模式旦显著的负斜率,属陆壳稀土的典型特征。稀土含量受沉积物粒度控制。实验表明稀土主要以类质同像存在于粘土矿物之晶体构造中。根据数理统计,稀土与亲陆源粘土矿物的元素为一类,彼此呈正相关;与亲海洋生物的元素为负相关。事实说明中国大陆岩石的风化和搬运,是中国海大陆架沉积物中稀土的主要物质来源。 相似文献
7.
文章报道了一种在川滇黔相邻区新发现的古陆相沉积型稀土矿床。稀土矿体赋存在二叠系峨眉山玄武岩之上,上二叠统宣威组底部,含矿建造为一套以高岭石及伊利石为主的黏土岩建造,分布广泛,连续性好,稀土氧化物TREO平均品位0.39%,最高可达1.60%。岩相古地理条件及地球化学特征显示,稀土元素源自西侧剥蚀区,经搬运-沉积-改造后富集;赋存状态方面,古陆相沉积型稀土除独立矿物态（<1%）,类质同象态（<1%）和离子吸附态（0.02%~24%）外,75%以上的稀土元素以纳米矿物颗粒的形态被“束缚”在黏土矿物层状结构中;稀土元素配分曲线图显示其高价值关键稀土元素镨、钕、铽、镝占比累计达23.34%;通过短流程的选冶一体化工艺技术,全元素稀土浸出率达到90%以上,综合回收率达80%以上。这一新类型稀土资源具有极大的开发利用前景,有望成为中国新的关键稀土元素来源。 相似文献
8.
地质样品痕量元素分析中的基体校正,前人作过大量工作。但是对于主元素(主要指铁)吸收限长波侧的基体校正还未很好解决。本文利用相对吸收的概念,计算了主 相似文献
9.
钨矿的稀土元素地球化学可以反映成矿作用的条件和过程,为矿床成因提供有效的信息。中国钨矿床稀土元素地球化学的研究硕果累累,从单矿种角度进行全国性的系统总结十分必要。本文统计了1990年至2016年间不同类型钨矿床钨矿石矿物及与成矿有关岩体的稀土元素300多组数据。通过总结可知,不同类型钨矿床钨矿石矿物及与成矿有关花岗岩中稀土元素的总量和稀土配分曲线不同,这与成矿原始物质及成矿时物理化学条件的不同有关。不同类型钨矿床大部分具有Eu负异常的特征,显示成矿条件为较高温的还原环境;黑钨矿及其成矿岩体的稀土分配模式之间存在一定的依从关系,但是,黑钨矿中的稀土元素并没有随着岩浆-流体的结晶分异而富集。 相似文献
10.
F.Q. Zhang H.L. Chen X. Yu C.W. Dong S.F. Yang Y.M. Pang G.E. Batt 《Gondwana Research》2011,19(1):163-176
The Songliao Basin is characterized by episodic rifting and intense volcanism during its early development, and forms a key concealed part of the Late Mesozoic magmatic province of NE China. Few precise geochronological and geochemical data were previously available for the volcanic elements of this basin, restricting understanding of its geodynamic setting and evolution. We present new SHRIMP U–Pb zircon ages and geochemical data for the volcanic rocks from the northern Songliao Basin, which limit this volcanism to the Early Cretaceous period (115–109 Ma). Although dominated by rhyolite, the rocks cover a wide compositional spectrum encompassing trachyandesite, basaltic trachyandesite, trachyte and dacite. This suite exhibits a range of geochemical signatures characteristic of subduction-related genesis, falling into a high-K calc-alkaline series, with enrichment in large ion lithophile elements (LILE) and light rare earth elements (LREE), and weak depletion in high field strength elements (HFSE) and heavy rare earth elements (HREE). The suite also shares a common isotopic composition, consistent with derivation from partial melting of a single depleted mantle source. This Early Cretaceous volcanism occurred in an extensional back-arc setting associated with the subduction of the Paleo-Pacific plate, large scale upwelling of the asthenosphere, and intensive lithospheric thinning of the eastern continental margin of NE China which may have lasted until ca. 109 Ma. 相似文献
11.
为了解桂东北伟晶岩岩浆的形成环境及演化过程,对桂东北茅安塘Nb-Ta-Be-Rb稀有金属矿床周围伟晶岩中的石榴子石进行了镜下观察、电子探针（EPMA）和LA-ICP-MS原位微区主微量元素研究,探讨石榴子石的成因及其对成岩及成矿作用的指示.结果表明,桂东北茅安塘地区伟晶岩中的石榴子石为岩浆成因石榴子石,属于铁铝榴石-锰铝榴石（平均Alm49.28-Sps47.09）固溶体系列,可分为早期形成的Ⅰ型石榴子石（GrtⅠ）和晚期形成的Ⅱ型子石（GrtⅡ）.两期石榴子石均以富集重稀土（HREE）、高场强元素（HFSE）,亏损轻稀土（LREE）和缺乏大离子亲石元素（LILE）为特征,∑REE配分模式呈明显左倾趋势,显著的Eu负异常.石榴子石生长过程中的界面反应速率小于物质迁移速率,水岩作用较弱,∑REE主要以表面吸附或吸收的形式进入石榴子石中,是导致其重稀土（HREE）元素富集,轻稀土元素亏损的主要原因.随着岩浆分异演化程度的不断提高,∑REE逐渐进入并赋存于石榴子石中,促进岩浆从早期的低分馏（未分馏）的岩浆熔体逐渐向晚期的高分馏的岩浆熔体演化.石榴子石中HREE含量随岩浆演化程度逐渐增加表明,晚期分异演化的岩浆-热液中逐渐富集稀土及稀有金属元素.这些晚期富含成矿元素的热液流体交代原生矿物,导致外侧带及核部花岗伟晶岩中发育大量交代成因的稀土和稀有金属矿物. 相似文献
12.
Abstract: The black shales of the Lower Cambrian Niutitang Formation in Weng’an, on the Yangtze platform of south China, contain voluminous polymetallic sulfide deposits. A comprehensive geochemical investigation of trace, rare earth, and platinum group elements (PGE) has been undertaken in order to discuss its ore genesis and correlation with the tectono-depositional setting. The ore-bearing layers enrich molybdenum (Mo), nickel (Ni), vanadium (V), lead (Pb), strontium (Sr), barium (Ba) , uranium (U) , arsenic (As), and rare earth elements (REE) in abundance. High uranium/thorium (U/Th) ratios (U/Th>1) indicated that mineralization was mainly influenced by the hydrothermal process. The dU value was above 1.9, showing a reducing sedimentary condition. The REE patterns showed high enrichment in light rare earth elements (LREE) (heavy rare earth elements (HREE) (LREE/HREE=5–17), slightly negative europium (Eu) and cerium (Ce) anomalies (dEu=0.81–0.93), and positive Ce anomalies (dCe=0.76–1.12). PGE abundance was characterized by the PGE-type distribution patterns, enriching platinum (Pt), palladium (Pd), ruthenium (Ru) and osmium (Os). The Pt/Pd ratio was 0.8, which is close to the ratios of seawater and ultramafic rocks. All of these geochemical features suggest that the mineralization was triggered by hydrothermal activity in an extensional setting in the context of break-up of the Rodinian supercontinent. 相似文献
13.
《International Geology Review》2012,54(10):1144-1153
The geochemical features of hydrothermal-pneumatolytic rare element deposits are discussed on the basis of a natural connection between high temperature metasomatism phenomena and concentration processes of some rare elements. Two kinds of metasomatic processes are most interesting from the view-point of rare elements (albitization and greisenization). Li and Rb are concentrated in zinnwaldite-bearingalbitized granites and greisens. Nb, Ta (in columbite, pyrochlore, microlite, hatchettolite), Zr (in malacone zyrtolite), Be (beryl) are concentrated in albitized and greisenized granites. The beryllium deposits are closely connected with greisens of different composition, and quartz-greisen veins. The fluorite-bearing metasomatic rocks among carbonate rocks are characterizedby accumulations of Be (chrysoberyl, phenacite, taateite, sianhualite), Li (Li - margarite), Sn (cassiterite). The character of postmagmatic alterations of intrusive and wall rocks is a valuable indicator of the possibility of concentration of different rare elements.—Auth. English Summary. 相似文献
14.
The black shales of the Lower Cambrian Niutitang Formation in Weng'an.on the Yangtze platform of south China,contain voluminous polymetallic sulfide deposits.A comprehensive geochemical investigation of trace,rare earth,and platinum group elements(PGE)has been undertaken in order to discuss its ore genesis and correlation with the tectono.depositional setting.The ore-bearing layers enrich molybdenum(Mo),nickeI(Ni),vanadium(V),lead(Pb),strontium(Sr), bariam(Ba),uranium(U),arsenic(As),and rare earth elements(REE)in abundance.High uranium/thorium(U/Th)ratios(U/Th>1)indicated that mineralization was mainly influenced by the hydrothermal process.The δU value Was above 1.9.showing a reducing sedimentary condition.The REE patterns showed high enrichment in Iight rare earth elements (LREE)(heavy rare earth elements (HREE)(LREE/HREE=5-17),slightly negative europium(EU)and cerium(Ce)anomalies(δEu=0.81-0.93).and positive Ce anomalies(δCe=0.76-1.12).PGE abundance was characterized by the PGE-type distribution patterns,enriching platinum(Pt),palladium(Pd),ruthenium(RuJ and osmium(Os).The Pt,Pd ratio was 0.8.which is close to the ratios of seawater and ultramafic rocks.AII of these geochemical features suggest that the mineralization was triggered by hydrothermal activity in an extensionai setting in the context of break-up of the Rodinian supercontinent. 相似文献
15.
应用LA-ICP-MS对马厂箐岩体中(似)斑状花岗岩的锆石进行了U-Pb定年和微量元素分析。在CL图像上,(似)斑状花岗岩中锆石均发育有典型的振荡环带,锆石的稀土元素配分模式表现为亏损轻稀土,富集重稀土,具有强烈正Ce异常和中度负Eu异常,且呈现出较高的Th/U比值等特征,表明所测锆石均为典型的岩浆锆石。马厂箐岩体(似)斑状花岗岩锆石U-Pb加权平均年龄为(33.78±0.21)Ma(MSWD=0.71),累计概率统计得到正长斑岩锆石U-Th-Pb年龄为(35.6±0.3)Ma、花岗斑岩锆石U-Th-Pb年龄为(35.0±0.2)Ma,宝兴厂矿段铜钼矿辉钼矿Re-Os等时线年龄分别为(35.8±1.6)Ma和(33.9±1.1)Ma,乱硐山矿段接触交代型金矿白云母40Ar/39Ar年龄为(35.25±0.36)Ma,人头箐—金厂箐矿段热液脉型金成矿白云母40Ar/39Ar年龄为(35.35±0.32)Ma,反映斑岩型铜钼矿化、接触交代型金矿化和热液脉型金矿化为同一个构造-岩浆-热液成矿系统的产物,Ⅱ期(33～37Ma)正长斑岩+二长斑岩+花岗斑岩+(似)斑状花岗岩岩性组合是成矿的地质体,为成矿提供了物质、流体和热动力条件,这期斑岩-热液-成矿系统的持续时间约为4Ma,铜、钼、金的成矿主要发生在Ⅱ期岩浆活动的早-中期。 相似文献
16.
竹山和马鞍山绿松石微量元素和稀土元素特征 总被引：2，自引：1，他引：1
对竹山和马鞍山两地绿松石的微量元素和稀土元素特征作了对比研究,同时分析了两地绿松石矿物特征和结构特征。采用X射线能谱、电感耦合等离子体质谱、X射线衍射、红外吸收光谱和扫描电镜等测试技术对竹山和马鞍山地区的绿松石样品进行岩石矿物学特征分析。结果表明,竹山与马鞍山地区绿松石在微量元素的含量上存在较大的差别,但主成分含量基本一致;两地区绿松石的稀土元素均富集重稀土,二者的稀土配分模式图出现镨反向,马鞍山地区的绿松石表现出铕负异常;马鞍山绿松石的结晶程度优于竹山县绿松石。该方法对绿松石产地划分的研究具有应用价值。 相似文献
17.
吉南张三沟岩组和金银别岩组发育一套高镁安山岩类,SHRIMP锆石U-Pb定年为（2 493±12）Ma,形成于新太古代。高镁安山岩类属于钙碱性系列,w(SiO2)为 53.93%～57.90%,富MgO(w(MgO)为6.54%～8.82%）,高Mg#值(0.68～0.71, 平均0.69),高铬(w(Cr)为(270.66～1 117.30)×10－6,平均443.62×10－6）,高镍(w(Ni) 为(141.74～542.98)×10－6,平均250.50×10－6）,这种高MgO、Cr、Ni的特征表明其成因与地幔部分熔融有关。另一方面,该岩石富集大离子亲石元素（如Sr、Cs、K、Pb、Rb和Ba）,亏损高场强元素（如Nb、Ta、Ti、P）,富集LREE（w(Ce)为(38.34～59.34)×10－6）,亏损HREE（w(Yb)为(1.38～1.57)×10－6）,显示弧火山岩的特点。上述地球化学特征表明,岩石可能是消减板片脱水流体或者消减板片部分熔融的熔体与地幔橄榄岩相互作用的结果,揭示它们形成于消减带的构造环境,表明新太古代已经存在现代类型的板块构造。 相似文献
18.
沙溪铜（金）矿床是目前长江中下游成矿带中已探明储量最大的斑岩型铜矿床。文章通过对沙溪矿区内闪长斑岩的年代学、全岩化学成分、同位素地球化学等综合研究,探讨了闪长斑岩的形成机制。闪长斑岩的LA-ICP-MS锆石U-Pb加权平均年龄为128.3±1.5 Ma,属于早白垩世岩浆活动产物。岩石具有富碱（ALK=6.12~7.53 wt%）、富钾、富镁（Mg#=38.99~51.53）、准铝质（A/CNK=0.90~0.99）等特征,属于钙碱性—高钾钙碱性系列岩石;岩石轻稀土元素富集,重稀土元素亏损（LaN/YbN=12.63~17.63）,无明显的Eu异常（δEu=0.84~1.14）;大离子亲石元素（Ba、Sr）和Pb等富集,高场强元素（Nb、Ta、Ti等）亏损。闪长斑岩的全岩(87Sr/86Sr)t值为0.7052~0.7056,εNd(t )值为-6.09~-3.42,(206Pb/204Pb)t值为17.51~18.16、(207Pb/204Pb)t值为15.49~15.63、(208Pb/204Pb)t值为37.57~38.45,表明成岩物质源于壳幔混合。130 Ma左右,平移的郯庐断裂的伸展引发了大规模岩浆作用,来自深部的岩浆沿着郯庐断裂带上侵,并混染了大量的地壳物质,形成了沙溪闪长斑岩及与铜矿有关的石英闪长斑岩。 相似文献
19.
贵阳花溪燕楼剖面下三叠统大冶组微量元素及稀土元素地球化学特征分析表明: U、V、Mo的含量及U/Th、V/Th、Mo/Th的比值,大于澳大利亚后太古代页岩(PAAS)的含量和比值。V/(V+Ni)、V/Cr、Ni/Co、V/Sc以及MoEF/UEF等氧化还原敏感元素的参数特征及其含量显示,大冶组一段处于缺氧-贫氧环境,大冶组二段处于贫氧—氧化环境。研究区经PAAS标准化的稀土配分模式比较平坦,根据大冶组的δCe及Ce/La的参数特征,认为早三叠世整体处于海洋环境;大冶组底部呈现明显Eu正异常,表明受火山热液作用影响明显;可见早三叠世贫氧环境可能与火山作用频发有关。大冶组上部表现微弱Eu正异常,说明火山作用的影响减弱。基于双壳类化石的结构及生活方式分析认为Claraia营外栖足丝固着的生活方式,属于贫氧生物,壳类化石结构只表现棱柱状外壳层和复杂交错纹层状珍珠层,其生活环境应为水动力条件较弱的浅水区。 相似文献
20.
本文介绍了敦化稀有矿泉水出露的地质环境条件,矿泉水的赋存条件和形成机理,分析了矿泉水的动态特征与稀有化学元素的特征指标,对敦化秋梨沟稀有矿泉水水源地合理开发利用、保护及开发利用战略提出合理化建议。 相似文献