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1.
Acadian (Late Silurian to Early Devonian) metamorphism in the Central Maine Terrane (CMT) in central Massachusetts is characterized by an early low-P, high-T (Buchan-type) metamorphism followed by thickening at high temperature (>650d? C) and then by cooling to 100-200d? C below peak recorded temperatures before eventual unroofing. Mineralogical and textural evidence for this path includes sillimanite pseudomorphs after early andalusite, abundant cordierite in pelitic lithologies, replacement of low-P cordierite-bearing assemblages by high-P garnet-bearing assemblages, and recrystallization of mylonites associated with late shear zones to form lower-T and higher-P assemblages. Peak conditions in the highest grade rocks were 685-780d? C and 5-6 kbar; the cooling path passed through 550d? C at about 6.5 kbar. The well-constrained P-T path documented from geological and mineralogical evidence for the CMT offers an unusual opportunity to examine characteristics of fluid inclusions that have experienced a long-lived metamorphic event spanning a broad range of P-T conditions. Fluid inclusion data from the CMT document a range of fluid compositions (CO2-rich, mixed CO2-N2-rich, N2-rich and H2O-rich) and densities during metamorphism. Densities of CO2 fluid inclusions range from 0.20 to 1.03 g cm-3. Medium-density CO2 fluid inclusions are contained in quartz inclusions within garnets in partial melt leucosomes, and in quartz grains within migmatites. Fluid inclusions within the quartz inclusions indicate trapping conditions of 650-700d? C at pressures below 5 kbar. Other CO2 fluid inclusions from matrix quartz yield isochores which pass through 700d? C and 5.2 kbar. The highest density inclusions associated with rocks containing the late high-P assemblages have isochores which pass below the estimated P-T conditions for recrystallization of the mylonite. Fluid inclusion evidence suggests an early low-P heating event, followed by thickening at high temperature, and then by nearly isobaric cooling to about 500d? C with later decompression. This interpretation is also consistent with previously published petrological models and supports an anticlockwise P-T path for the CMT of south-central Massachusetts.  相似文献   

2.
The Seiland Igneous Province of the North Norwegian Caledonides consists of a suite of deep-seated rift-related magmatic rocks emplaced into paragneisses during late Precambrian to Ordovician time. In the south-eastern part of the province, contact metamorphism of the paragneisses and later reworking of intrusives and associated contact aureoles have resulted in the development of three successive metamorphic stages. The contact metamorphic assemblage (M1) Opx + Grt + Qtz + Pl + Kfs + Hc + Ilm ± Crd is preserved in xenolithic rafts of paragneiss within metagabbro. Geothermobarometric calculations yield 930-960d? C and 5-6.5 kbar for the contact metamorphism. M1 was followed by cooling, accompanied by strong shearing, formation of the gneiss foliation and recrystallization at intermediate-P granulite facies conditions (M2). Stable M2 phases are Cpx + Opx + Pl +Ilm ± Hbl in metagabbro and Grt ± Sil ± Opx + Kfs + Qtz + Pl ± Bt + Ilm in host paragneiss. The M2 conditions are estimated to 700-750d? C and 5-7 kbar. A subsequent pressure increase is recorded in the M3 episode, which is associated with recrystallization in narrow ductile shear zones and secondary growth on M2 minerals. M3 is defined by the assemblages Grt + Cpx ± Opx + Pl + Ru + Qtz in metagabbro, and Grt ± Ky + Qtz + Pl ± Kfs + Bt + Ru in host paragneiss. M3 conditions are estimated to 650-700d? C and 8-10 kbar. The substantial pressure increase related to the M2 → M3 transition is interpreted to be a result of (early?) Caledonian overthrusting. Chemical zoning in cordierite and biotite suggest rapid cooling following the M3 event. The proposed P-T-t evolution implies that the tectonic evolution of the Seiland Igneous Province was long (at least 330 Ma) and complex and involved initial rifting and extension followed by crustal thickening and compression.  相似文献   

3.
Representative diamond-bearing gneisses and dolomitic marble, eclogite and Ti-clinohumite-bearing garnet peridotite from Unit I at Kumdy Kol and whiteschist from Unit II at Kulet, eastern Kokchetav Massif, northern Kazakhstan, were studied. Diamond-bearing gneisses contain variable assemblages, including Grt+Bt+Qtz±Pl±Kfs±Zo±Chl±Tur±Cal and minor Ap, Rt and Zrn; abundant inclusions of diamond, graphite+chlorite (or calcite), phengite, clinopyroxene, K-feldspar, biotite, rutile, titanite, calcite and zircon occur in garnet. Diamond-bearing dolomitic marbles consist of Dol+Di±Grt+Phl; inclusions of diamond, dolomite±graphite, biotite, and clinopyroxene were identified in garnet. Whiteschists carry the assemblage Ky+Tlc+Grt+Rt; garnet shows compositional zoning, and contains abundant inclusions of talc, kyanite and rutile with minor phlogopite, chlorite, margarite and zoisite. Inclusions and zoning patterns of garnet delineate the prograde P–T path. Inclusions of quartz pseudomorphs after coesite were identified in garnet from both eclogite and gneiss. Other ultrahigh-pressure (UHP) indicators include Na-bearing garnet (up to 0.14 wt% Na2O) with omphacitic Cpx in eclogite, occurrence of high-K diopside (up to 1.56 wt% K2O) and phlogopite in diamond-bearing dolomitic marble, and Cr-bearing kyanite in whiteschist. These UHP rocks exhibit at least three stages of metamorphic recrystallization. The Fe-Mg partitioning between clinopyroxene and garnet yields a peak temperature of 800–1000 °C at P >40 kbar for diamond-bearing rocks, and about 740–780 °C at >28–35 kbar for eclogite, whiteschist and Ti-bearing garnet peridotite. The formation of symplectitic plagioclase+amphibole after clinopyroxene, and replacement of garnet by biotite, amphibole, or plagioclase mark retrograde amphibolite facies recrystallization at 650–680 °C and pressure less than about 10 kbar. The exsolution of calcite from dolomite, and development of matrix chlorite and actinolite imply an even lower grade greenschist facies overprint at c. 420 °C and 2–3 kbar. A clockwise P–T path suggests that supracrustal sediments together with basaltic and ultramafic lenses apparently were subjected to UHP subduction-zone metamorphism within the diamond stability field. Tectonic mixing may have occurred prior to UHP metamorphism at mantle depths. During subsequent exhumation and juxtaposition of many other tectonic units, intense deformation chaotically mixed and mylonitized these lithotectonic assemblages.  相似文献   

4.
Calc-silicate rocks occur as elliptical bands and boudins intimately interlayered with eclogites and high-pressure gneisses in the Münchberg gneiss complex of NE Bavaria. Core assemblages of the boudins consist of grossular-rich garnet, diopside, quartz, zoisite, clinozoisite, calcite, rutile and titanite. The polygonal granoblastic texture commonly displays mineral relics and reaction textures such as post kinematic grossular-rich garnet coronas. Reactions between these mineral phases have been modelled in the CaO-Al2O3-SiO2-CO2-H2O system with an internally consistent thermodynamic data base. High-pressure metamorphism in the calc-silicate rocks has been estimated at a minimum pressure of 31 kbar at a temperature of 630d? C with XH2, O ≥ 0.03. Small volumes of a CO2-N2-rich fluid whose composition was buffered on a local scale were present at peak-metamorphic conditions. The P-T conditions for the onset of the amphibolite facies overprint are about 10 kbar at the same temperature. XCo2 of the H2O-rich fluid phase is regarded to have been <0.03 during amphibolite facies conditions. These P-T estimates are interpreted as representing different stages of recrystallization during isothermal decompression. The presence of multiple generations of mineral phases and the preservation of very high-pressure relics in single thin sections preclude pervasive post-peak metamorphic fluid flow as a cause of a re-equilibration within the calc-silicates. The preservation of eclogite facies, very high-pressure relics as well as amphibolite facies reactions textures in the presence of a fluid phase is in agreement with fast, tectonically driven unroofing of these rocks.  相似文献   

5.
Near 68° N the Scandinavian Caledonides are composed of 3 tectonic domains each of which has a different tectonostratigraphy. The lower 2 domains can be related stratigraphically to Scandinavia prior to Caledonian deformation, whereas the highest domain, the Middle Köli Nappe Complex (MKNC) represents a fore-arc accretionary complex that was accreted to Scandinavia during Caledonian deformation. Subsequent to accretion, the flyschoid sediments that dominate the MKNC were metamorphosed to the amphibolite facies. In the area covered by this study, the MKNC is composed of two nappes, a lower Langvatn nappe and an upper Marko nappe, each of which has a unique early metamorphic history. Pelitic mineral assemblages in the Marko nappe constrain the peak P-T to be: 625°<T<775° C and P>7.0 kbars whereas ultramafic mineral assemblages in the lower Langvatn nappe constrain its peak temperature to be <580° C. P-T estimates from garnet-biotite and garnet-plagioclase geothermobarometry for both nappes overlap; ranging from 528° C and 6.6 kbars to 620° C and 8.8 kbars, with an average of 567±32° C and 8.0±0.9 kbar.Analysis of garnet zonation profiles from low variance pelitic assemblages from the Marko nappe using the Gibbs method of Spear and Selverstone (1983) suggests that P-T paths showing cooling (37–125° C) and decompression (20–1700 bars) were followed during the development of the outer part of garnet zonation profiles. The slope of these retrograde P-T paths is approximately 15 bars/° C. Because of the high variance of pelitic assemblages from the Langvatn nappe P-T paths have not been determined.The retrograde cooling rate of the Marko nappe has been estimated by numerical modeling of garnet zonation profiles that are interpreted to have formed by volume diffusion during retrograde cooling. This modeling suggests that the Marko nappe cooled very rapidly (25–100° C/m.y.) between the metamorphic peak and the temperature at which cation-exchange reactions closed. The form of Langvatn nappe garnet zonation profiles suggests that it did not undergo this rapid cooling.The cooling rate estimated for the Marko nappe is probably too high to be produced by unroofing alone and may be the result of late metamorphic thrusting and imbrication within the MKNC during which the cooler Langvatn nappe was underthrust beneath the warmer Marko nappe. The metamorphic peak of the Marko nappe therefore predates the peak of the Langvatn nappe. The peak P-T of the Langvatn nappe and the P-T recorded by geothermobarometry (570° C, 8.0 kbar) approximates the conditions under which the two nappes were juxtaposed.  相似文献   

6.
The metamorphic sequences of the Saxonian Erzgebirge were thoroughly overprinted by a Variscan medium-pressure event under amphibolite facies conditions. However, eclogitic relics documenting an older high-pressure event are widespread. P-T conditions of the eclogite-facies metamorphism systematically decrease, over a distance of 50 km, from about >29 kbar/850°C, in the central part, to 20–24 kbar/650°C, in the westernmost part of the Erzgebirge crystalline complex. A distinct gap in P-T conditions exists between the central and the western Erzgebirge coinciding with the fault zone of the Flöha syncline. Therefore, the eclogitebearing sequences are assumed to represent at least two different nappe units. The lower-grade eclogite assemblages in the western Erzgebirge display a continuous metamorphic zonation with a gradual decrease of peak metamorphic temperatures towards the west. Assemblages formed in the stability field of coesite and thus indicating a regional ultra-high pressure metamorphism, are restricted to the central Erzgebirge, where they are widespread in the eclogites, but also present in metaacidic country rocks. The same high-temperature/high-pressure conditions, testifying to a burial of at least 100 km, were independently recorded for the ultramafic garnet pyroxenites associated with the eclogites of the central Erzgebirge. Mineral relics included in the eclogite phases and mineral assemblages formed by retrograde reactions permit reconstruction of the prograde and retrograde P-T paths in the different parts of the Erzgebirge crystalline complex.  相似文献   

7.
ABSTRACT A suite of garnet-wollastonite-scapolite-bearing calcsilicate granulites from the Eastern Ghats has been investigated to document the controls of mineral reactions during the metamorphic evolution of the deep continental crust. The rocks studied show heterogeneity in modal mineralogy and phase compositions in millimetre-sized domains. Textural relations, and the compositional plots of the phases, established that the clinopyroxene exerts a strong influence on the formation and composition of garnet in the complex natural system. P-T estimates using the vapour-independent equilibria involving garnet define a near isobaric cooling path from c. 850C at c. 5.5–5.2 kbar. The deduced trajectory tallies well with the terminal segment of the overall retrograde P-T path construed from the associated rocks using well-calibrated thermobarometers. The ubiquitous occurrence of wollastonite and scapolite in the main calcsilicate body suggests low aCO2 during peak metamorphic condition. Fluid compositions constrained from mineral-fluid equilibria of the garnet-bearing assemblages show domainal variations as a function of the compositions of the solid phases, e.g. garnet and clinopyroxene. A quantitative log/CO2-log/O2 diagram has been constructed to depict the stability of the different calcsilicate assemblages as functions of the compositions and the behaviour of these fugitive species. The results of the mineral-fluid equilibria and the quantitative fluid/rock ratio calculations, in conjunction with the topological constraints, imply vapour-deficient meta-morphism in the rocks studied. It is argued that fO2 during peak metamorphism was monitored by the ambient fO2. Subsequently, during retrogression, different domains evolved independently, whereas the fluid composition was controlled by the mineral-fluid equilibria.  相似文献   

8.
In the Orlica–?nie?nik Dome (NE Bohemian massif), alternating belts of orthogneiss with high‐pressure rocks and belts of mid‐crustal metasedimentary–metavolcanic rocks commonly display a dominant subvertical fabric deformed into a subhorizontal foliation. The first macroscopic foliation is subvertical, strikes NE–SW and is heterogeneously folded by open to isoclinal folds with subhorizontal axial planes parallel to the heterogeneously developed flat‐lying foliation. The metamorphic evolution of the mid‐crustal metasedimentary rocks involved successive crystallization of chlorite–muscovite–ilmenite–plagioclase–garnet, followed by staurolite‐bearing and then kyanite‐bearing assemblages in the subvertical fabric. This was followed by garnet retrogression, with syntectonic crystallization of sillimanite and andalusite parallel to the shallow‐dipping foliation. Elsewhere, andalusite and cordierite statically overgrew the flat‐lying fabric. With reference to a P–T pseudosection for a representative sample, the prograde succession of mineral assemblages and the garnet zoning pattern with decreasing grossular, spessartine and XFe are compatible with a P–T path from 3.5–5 kbar/490–520 °C to peak conditions of 6–7 kbar/～630 °C suggesting burial from 12 to 25 km with increasing temperature. Using the same pseudosection, the retrograde succession of minerals shows decompression to sillimanite stability at ～4 kbar/～630 °C and to andalusite–cordierite stability at 2–3 kbar indicating exhumation from 25 km to around 9–12 km. Subsequent exhumation to ～6 km occurred without apparent formation of a deformation fabric. The structure and petrology together with the spatial distribution of the metasedimentary–metavolcanic rocks, and gneissic and high‐pressure belts are compatible with a model of burial of limited parts of the upper and middle crust in narrow cusp‐like synclines, synchronous with the exhumation of orogenic lower crust represented by the gneissic and high‐pressure rocks in lobe‐shaped and volumetrically more important anticlines. Converging P–T–D paths for the metasedimentary rocks and the adjacent high‐pressure rocks are due to vertical exchanges between cold and hot vertically moving masses. Finally, the retrograde shallow‐dipping fabric affects both the metasedimentary–metavolcanic rocks and the gneissic and high‐pressure rocks, and indicates that the ～15‐km exhumation was mostly accommodated by heterogeneous ductile thinning associated with unroofing of a buoyant crustal root.  相似文献   

9.
Abstract

Combined in situ monazite dating, mineral equilibria modelling and zircon U–Pb detrital zircon analysis provide insight into the pressure–temperature–time (P–T–t) evolution of the western Gawler Craton. In the Nawa Domain, pelitic and quartzo-feldspathic gneisses were deposited after ca 1760?Ma and record high-grade metamorphic conditions of ～7.5?kbar and 850?°C at ca 1730?Ma. Post-peak microstructures, including partial plagioclase coronae and late biotite around garnet, and subtle retrograde garnet compositional zoning, suggest that these rocks cooled along a shallow down-pressure trajectory across an elevated dry solidus. In the northwest Fowler Domain (Colona Block), monazite grains from pelitic gneisses record two stages of growth/recrystallisation interpreted to represent discrete parts of the P–T path: (1) ca 1710?Ma monazite growth during prograde to peak conditions, and (2) ca 1690?Ma Y-enriched monazite growth/recrystallisation during partial garnet breakdown and cooling towards the solidus. Relict prograde growth zoning in garnet suggests rocks underwent a steep up-P path to peak conditions of ～8?kbar at 800?°C. The new P–T–t results suggest basement rocks of the southwestern Nawa and northwestern Fowler were buried to depths of 20–25?km during the Kimban Orogeny, ca 10 Myrs after the sedimentary precursors were deposited. The P–T path for the Kimban Orogeny is broadly anti-clockwise, suggesting that at least the early phase of this event was associated with extension. Exhumation of rocks from both the southwestern Nawa and northwestern Fowler domains may have occurred during the waning stages of the Kimban Orogeny (<ca 1690?Ma). The limited low-grade overprint in these rocks may be explained by a mid-to-upper crustal position for these rocks during the subsequent Kararan Orogeny. Aluminous quartz-feldspathic gneiss of the Nundroo Block in the eastern Fowler Domain records peak conditions of ～7?kbar at 800?°C. Monazite grains from the Nundroo Block are dominated by an age peak at ca 1590?Ma, although the presence of some older ages up to ca 1690?Ma, possibly reflect partial resetting of older monazite domains. The P–T–t conditions suggest these rocks were buried to 20–25?km at ca 1590?Ma during the Kararan Orogeny. This high-grade metamorphism in the Nundroo Block is a mid-crustal expression of the same thermal anomaly that caused magmatism in the central-eastern Gawler Craton. Juxtaposition of rocks affected by the Kimban and Kararan orogenic events in the western Gawler Craton was controlled by lithospheric-scale shear zones, some of which have facilitated ～20 kilometres of exhumation.  相似文献   

10.
The gneisses of the Makuti Group in north-west Zimbabwe are characterized by complex geometries that resulted from intense non-coaxial deformation in a crustal scale high-strain zone that accommodated extensional deformation along the axis of the Zambezi Belt at c. 800 Ma. Within low-strain domains in the Makuti gneisses, undeformed metagabbroic lenses preserve eclogite and granulite facies assemblages, which record a part of the metamorphic history that predates Pan-African events. Eclogitic rocks can be subdivided into: (1) corona-textured metagabbros that preserve igneous textures, and (2) garnet–omphacite rocks in which primary textures are destroyed. The lenses of eclogitic rocks are enveloped in a mantle of garnet–clinopyroxene–hornblende gneiss, which is a common rock type in the Makuti gneisses. The eclogites preserve multi-staged, domainal, symplectic reaction textures that developed progressively as the rocks experienced loading followed by decompression–heating. In the metagabbros, the original clinopyroxene, plagioclase and olivine domains acted separately during the peak of metamorphism, with plagioclase being replaced by garnet and kyanite, and olivine being replaced by orthopyroxene and possibly omphacite. The peak assemblage was overprinted by: (1) the multi-mineralic corona assemblage pargasite–orthopyroxene–spinel–plagioclase replacing garnet–kyanite–clinopyroxene (possibly at c. 19 kbar, 760±25 °C); (2) orthopyroxene–pargasite–plagioclase–scapolite coronas replacing orthopyroxene (15±1.5 kbar, 750±50 °C); and (3) moats of orthopyroxene–plagioclase replacing garnet (10±1 kbar, 760±50 °C). The garnet–omphacite rocks record similar peak conditions (15±1.1 kbar, 760±60 °C). Garnet–clinopyroxene–hornblende–plagioclase gneisses envelop the eclogites and record matrix conditions of 11±1.5 kbar at 730±50 °C using assemblages that are oriented in the regional fabric. These rocks are characterized by decompression-heating textures, reflecting temperature increases during exhumation of the Makuti gneisses. The eclogite facies rocks formed during a collisional event prior to 850 Ma. Their formation could be related to a suture zone that developed along the axis of the Zambezi Belt during the formation of Rodinia (between 1400 and 850 Ma). The main deformation-metamorphism in the Makuti gneisses occurred around 800 Ma and involved extension and exhumation of the high-P rocks (break-up of Rodinia), which experienced a high-T metamorphic overprint. Around 550–500 Ma, a collisional event associated with the formation of Gondwana resulted in renewed burial and metamorphic recrystallization of the Makuti gneisses.  相似文献   

11.
假蓝宝石是Mg-Al质麻粒岩中一种特殊的高温矿物,对超高温变质作用的研究有重要的意义。本文通过对全球66个超高温麻粒岩中47个含假蓝宝石麻粒岩地区的文献调研,总结了几种最常见的含假蓝宝石矿物组合产出的结构位置和变质反应关系,以及假蓝宝石的矿物化学特征。假蓝宝石的化学成分一般位于7∶9∶3端元左右,X_(Mg)大于0. 7,XFe_(3+)变化范围很宽,为0～0. 7。含假蓝宝石矿物组合的形成和演化指示了岩石经历的P-T轨迹。岩石中保留的假蓝宝石取代尖晶石、Grt/Opx+Sil取代Spr+Qz组合,以及随后的Spr+Crd±Opx后成合晶取代Grt/Opx+Sil组合的结构,一般可能指示了逆时针P-T轨迹中冷却和随后减压的部分;岩石中Grt/Opx+Sil/Ky或富Mg十字石反应形成Spr+Qz组合的结构可能指示了顺时针P-T轨迹中减压升温的部分。超高温变质岩不同的P-T轨迹暗示着它们的成因机制并不单一,前者可能是幔源基性岩浆底侵或增生作用的结果,后者可能与长期的热造山作用相关。  相似文献   

12.
Granulite facies metasedimentary gneiss exposed on Jetty Peninsula, east Antarctica, contains assemblages involving garnet-sillimanite-biotite-cordierite-spinel-ilmenite-rutile and garnet-orthopyroxene-cordierite-biotite, as well as quartz and K-feldspar. Peak assemblages involve garnet + sillimanite + ilmenite (±rutile) and garnet + orthopyroxene. P-T calculations suggest formation conditions of approximately 800d? C at 7-7.5 kbar. Cooling from peak conditions is suggested by biotite + garnet (±sillimanite) overprinting some peak assemblages. A subsequent increase in temperature is inferred from the formation of cordierite + garnet + biotite + ilmenite, garnet + sillimanite + cordierite + ilmenite and cordierite + orthopyroxene assemblages during D2. In slightly zincian bulk compositions, hercynitic spinel + cordierite + sillimanite constitutes the peak D2 assemblage. Average pressure calculations indicate peak pressures of 5.9 ±0.4 kbar at 700d? C for the cordierite-bearing D2 assemblages. Available radiometric data suggest that peak metamorphism occurred at c. 1000 Ma and D2 occurred after 940 ± 20 Ma. The following two possibilities exist for the metamorphic evolution. (1) The formation of the lower pressure cordierite-bearing assemblages is associated with a separate metamorphic event (M2), unrelated to the peak assemblage (M1), and the lower pressure assemblages have no relevance in terms of a single tectonothermal event. (2) The cordierite-bearing assemblages formed during a progression from peak conditions. In this case, the lower pressure assemblages reflect a broadly decompressional metamorphic evolution, during which temperatures fluctuated. Comparison with P-T paths from granulites of similar age in adjacent areas suggests that the second possibility should be preferred. The cooling interval between peak conditions and the development of cordierite-bearing coronas and symplectites suggests affinities with isobarically cooled granulites of similar age immediately to the west, and the low-P/high-T post-peak conditions are similar to the later stages of decompressional paths recognized in much of east Antarctica.  相似文献   

13.
The sapphirine granulites from G. Madugula, Eastern Ghats preserve a variety of mineral textures and reactions. Corona and reaction textures are used in conjunction with mineral compositions to construct a sequence of metamorphic reactions describing the mineralogical evolution of sapphirine granulites. An early stage is characterized by the development of sapphirine + quartz, spinel + quartz in textural equilibrium, and possible relicts after osumilite during peak metamorphic conditions. Sapphirine/spinel crystals were later detached from quartz in the form of mineral coronas. During a subsequent sapphirine-cordierite stage, several cordierite forming reactions reflect decreasingP-T conditions. Finally during the late stage, a few samples show evidence of retrogressive hydration. Sapphirine is rather iron-rich (12.8 wt%) and the Mg number in the analysed minerals varies in the order: cordierite > phlogopite > sapphirine > orthopyroxene > spinel > garnet.P-T conditions of metamorphism have been constrained through the application of geothermobarometry and thermodynamically calibrated MAS equilibria.P-T vectors from granulite facies rocks in the G. Madugula area indicate that the rocks experienced substantial decompression (up to 3 kbar) and moderate cooling (150–200°C) subsequent to peak conditions of metamorphism (8.4 kbar, > 900°C). The decompressionalP-T history of sapphirine granulites interpreted from textural features and thermobarometric estimates suggest that they may have eventually resulted from exhumation of thickened crust.  相似文献   

14.
Ultramafic blocks that themselves contain eclogite lenses in the Triassic Su-Lu ultrahigh-P terrane of eastern China range in size from hundreds of metres to kilometres. The ultramafic blocks are enclosed in quartzofeldspathic gneiss of early Proterozoic age. Ultramafic rocks include garnetiferous lherzolite, wehrlite, pyroxenite, and hornblende peridotite. Garnet lherzolites are relatively depleted in Al2O3 (<3.8wt%), CaO (<3.2%) and TiO2 (<0.11 wt%), and are low in total REE contents (several p.p.m.), suggesting that the rocks are residual mantle material that was subjected to low degrees of partial melting. The eclogite lenses or layers within the ultramafic rocks are characterized by higher MgO and CaO, lower Al2O3 and TiO2 contents, and a higher CaO/Al2O3 ratio compared to eclogites enclosed in the quartzofeldspathic gneiss. Scatter in the plots of major and trace elements vs. MgO, REE patterns and La, Sm and Lu contents suggest that some eclogites were derived from melts formed by various degrees (0.05–0.20) of partial melting of peridotite, and that other eclogites formed by accumulation of garnet and clinopyroxene ± trapped melt in the upper mantle. Both ultramafic and eclogitic rocks have experienced a complex metamorphic history. At least six stages of recrystallization occurred in the ultramafic rocks based on an analysis of reaction textures and mineral compositions. Stage I is a high temperature protolith assemblage of Ol + Opx + Cpx + Spl. Stage II consists of the ultrahigh-pressure assemblage Ol + Cpx + Opx + Grt. Stage III is manifested by the appearance of fine-grained garnet after coarse-grained garnet. Stage IV is characterized by formation of kelyphitic rims of fibrous Opx and Cpx around garnet, and replacement of garnet by spinel and pargasitic-hornblende. Stage V is represented by the assemblage Ol + Opx + Prg-Hbl + Spl. The mineral assemblages of stages VIA and VIB are Ol + Tr-Amp + Chl and Serp + Chl ± talc, respectively. Garnet and orthopyroxene all show a decrease in MgO with retrogressive recrystallization and Na2O in clinopyroxene also decreases throughout this history. Eclogites enclosed within ultramafic blocks consist of Grt + Omp + Rt ± Qtz ± Phn. A few quartz-bearing eclogites contain rounded and oval inclusion of polycrystalline quartz aggregates after coesite in garnet and omphacite. Minor retrograde features include thin symplectic rims or secondary amphiboles after Cpx, and ilmenite after rutile. P-T estimates indicate that the ultrahigh-metamorphism (stage II) of ultramafic rocks occurred at 820-900d? C and 36-41 kbar and that peak metamorphism of eclogites occurred at 730-900d? C and >28 kbar. Consonant with earlier plate tectonic models, we suggest that these rocks were underplated at the base of the continental crust. The rocks then underwent ultrahigh-pressure metamorphism and were tectonically emplaced into thickened continental crust during the Triassic collision between the Sino-Korean and Yangtze cratons.  相似文献   

15.
Garnet amphibolites can provide valuable insights into geological processes of orogenic belts, but their metamorphic evolution is still poorly constrained. Garnet amphibolites from the Wutai–Hengshan area of the North China Craton mainly consist of garnet, hornblende, plagioclase, quartz, rutile and ilmenite, with or without titanite and epidote. Four samples selected in a south–north profile were studied by the pseudosection approach in order to elucidate the characteristics of their metamorphic evolution, and to better reveal the northwards prograde change in P–T conditions as established previously. For the sample from the lower Wutai Subgroup, garnet exhibits obvious two‐substage growth zoning characteristic of pyrope (Xpy) increasing but grossular (Xgr) decreasing outwards in the core, and both Xpy and Xgr increasing outwards in the rim. Phase modelling using thermocalc suggests that the garnet cores were formed by chlorite breakdown over 7–9 kbar at 530–600 °C, and rims grew from hornblende and epidote breakdown over 9.5–11.5 kbar at 600–670 °C. The isopleths of the minimum An in plagioclase and maximum Xpy in garnet were used to constrain the peak P–T conditions of ~11.5 kbar/670 °C. The modelled peak assemblage garnet + hornblende + epidote+ plagioclase + rutile + quartz matches well the observed one. Plagioclase–hornblende coronae around garnet indicate post‐peak decompression and fluid ingress. For the samples from the south Hengshan Complex, the garnet zoning weaken gradually, reflecting modifications during decompression of the rocks. Using the same approach, the rocks are inferred to have suprasolidus peak conditions, increasing northwards from 11.5 kbar/745 °C, 12.5 kbar/780 °C to 13 kbar/800 °C. Their modelled peak assemblages involve diopside, garnet, hornblende, plagioclase, rutile and quartz, yet diopside is not observed petrographically. The post‐peak decompression is characterized by diopside + garnet + quartz + melt = hornblende + plagioclase, causing the diopside consumption and garnet compositions to be largely modified. Thus, the pesudosection approach is expected to provide better pressure results than conventional thermobarometry, because the later approach cannot be applied with confidence to rocks with multi‐generation assemblages. U–Pb dating of zircon in the Wutai sample records a protolith age of c. 2.50 Ga, and a metamorphic age of c. 1.95 Ga, while zircon in the Hengshan samples records metamorphic ages of c. 1.92 Ga. The c. 1.95 Ga is interpreted to represent the pre‐peak or peak metamorphic stages, and the ages of c. 1.92 Ga are assigned to represent the cooling stages. All rocks in the Wutai–Hengshan area share similar clockwise P–T morphologies. They may represent metamorphic products at different crustal depths in one orogenic event, which included a main thickening stage at c. 1.95 Ga followed by a prolonged uplift and cooling after 1.92 Ga.  相似文献   

16.
The north-west Turkish blueschists represent a subducted passive continental margin sequence dominated by metaclastic rocks and marble. The depositional age of the blueschist protoliths are probably Palaeozoic to Mesozoic, while the age of the high-pressure/low-temperature metamorphism is Late Cretaceous. Blueschists are tectonically overlain by a volcanosedimentary sequence made up of accreted oceanic crustal material that locally shows incipient blueschist metamorphism and by spinel peridotite slices. The metaclastic rocks with regional jadeite and glaucophane, which comprise the lower part of the blueschist unit, make up an over 1000-m-thick coherent sequence in the Kocasu region of north-west Turkey. Rare metabasic horizons in the upper parts of the metaclastic sequence with sodic amphibole + Iawsonite but no garnet indicate lawsonite blueschist facies metamorphism. The blueschist metaclastics in the Kocasu region are practically free of calcium and ferric iron and closely approximate the NFMASH system in bulk composition. Two low-variance mineral assemblages (with quartz and phengite) are jadeite + glaucophane + chlorite + paragonite and chloritoid + glaucophane + paragonite. The metaclastics comprise up to several-metres-thick layers of jadeite schist with quartz, phengite and nearly 100 mol% jadeite. Phase relations in the metaclastics show that the chloritoid + glaucophane assemblage, even in Fe2+-rich compositions, is stable in the jadeite stability field. In the NFASH system the above assemblage without the accompanying garnet has a narrow thermal stability field. Mineral equilibria in the metaclastics involving chloritoid, glaucophane, jadeite, paragonite and chlorite indicate metamorphic P-T conditions of 20 ± 2 kbar and 430 ± 30 d? C, yielding geothermal gradients close to 5d? C km-1, one of the lowest geotherms recorded. Blueschists in the Kocasu region, which have been buried to 70 km depth, are tectonically overlain by the volcanosedimentary sequence and by peridotite buried not deeper than 30 km. Phengites from two jadeite schists were dated by Ar/Ar laser probe; they give an age of 88.5 ± 0.5 Ma, interpreted as the age of metamorphism. Blueschists and the overlying peridotite bodies are intruded by 48-53-Ma-old granodiorite bodies that were emplaced at 10 km depth. This suggests that the exhumation of blueschists by underplating of cold continental crust, and normal faulting at the blueschist-peridotite, interface occurred during the Late Cretaceous to Palaeocene (88-53 Ma).  相似文献   

17.
The Flinton Group is a greenschist to upper amphibolite facies package of metasediments in southeastern Ontario that was metamorphosed during the Ottawan Orogeny. Thermodynamic modeling of metapelitic mineral assemblages suggests an increase in peak conditions of metamorphism across the 40 km wide study area from 3.5 to 7.9 kbar and 540 to 715 °C. Garnet isopleth thermobarometry applied to the cores of compositionally zoned porphyroblasts reveals remarkably similar P-T conditions of initial crystallization at approximately 3.7–4.0 kbar and 512–520 °C, corresponding to a relatively high geothermal gradient of ca. 34–45 °C km?1. It is inferred from modeling and reaction textures that metamorphism was along Barrovian P-T paths. Major and trace element zoning in garnet from one sample records a complex growth history as evidenced by major and trace element zoning and the distribution of xenotime, allanite and monazite inclusions. High-resolution (6 μm) LA-ICP-MS U-Pb geochronology performed on monazite in the rock matrix and included in the outer 150 μm of garnet rim-ward of a Y annulus revealed an age of 976?±?4 Ma. The age is interpreted to reflect monazite growth at the expense of allanite and apatite late in garnet’s growth history over the P-T interval 4.5–6.8 kbar and 540–640 °C. This new age estimate for near peak metamorphism fits well into the regional framework but is significantly younger than previously reported ages for Ottawan metamorphism. Based on microstructures this new age suggests that compressional tectonics were operating much later in the history of the Grenville of southeastern Ontario than previously thought.  相似文献   

18.
Textural relations, thermobarometry and petrogenetic grid considerations in the syn-tectonic granitoid massif and the enveloping metasedimentary gneisses at Salur are consistent with a counter-clockwise P–T –t path for the rocks. The low-P/high-T prograde sector is documented by the pre- to syn-D1 cordierite±orthopyroxene±garnet±spinel–bearing metatexite leucosomes in metapelites. Heating and loading of the rocks (syn- to post-D1) resulted in the formation of garnet+orthopyroxene± cordierite-bearing diatexites, and decomposition of cordierite in metatexite leucosomes to orthopyroxene+sillimanite+biotite+quartz symplectites. Near-peak temperature, 850 °C at 8.0 kbar, was reached syn- to post-D2. Post-peak cooling resulted in the stabilization of coronal grossular and anorthite+calcite symplectites at the expense of scapolite+wollastonite+calcite assemblages in calc-silicate gneisses, and the resetting of cation exchange temperatures at 700–750 °C. Near-isothermal decompression at c. 700–750 °C is manifested by the decomposition of garnet porphyroblasts in the granitoid gneisses to plagioclase+orthopyroxene/ilmenite/biotite two-phase coronas and restabilization of cordierite at garnet margins in metapelites. Subsequent low-P, near-isobaric cooling led to the overprinting of granulite facies assemblages by muscovite+calcite assemblages, and further resetting of cation exchange thermometers to lower temperatures c. 600 °C. The tectonothermal evolution of the Salur gneiss complex vis-a-vis the Eastern Ghats Belt is therefore consistent with high degrees of lower crustal melting, followed by prograde heating of the cover rocks due to magma invasion synchronous with crustal compression, and finally thermal relaxation over a protracted period punctuated by tectonic/erosional denudation of the thickened crust.  相似文献   

19.
Pressure–temperature pseudosections for ‘greyschist’ (metamorphosed greywacke and argillite) from the Alpine Schist (Haast Schist group) near Hokitika (Southern Alps, New Zealand) are used to gain new insights into its metamorphic history. The rocks were metamorphosed at relatively low‐grade conditions associated with the first appearance and initial growth of garnet in the stability field of albite. The measured and predicted garnet compositional zoning data are used to construct an overall P–T path by combining P–T path results from nearby rocks that have a range of MnO contents. The P–T path obtained is steep from ～380 °C/2.5 kbar up to ～490 °C/8.5 kbar, then recurves sharply with garnet growth continuing during early decompression to ～500 °C/6.5 kbar. Most garnet growth in the study area took place in the stability field of albite, with oligoclase appearing only during decompression, when the peristerite gap was entered. On appearance of oligoclase, there is a marked decrease in the CaO content of garnet. The preservation of mineral assemblages from near‐peak temperature conditions can be understood in terms of the P–T path subsequently becoming tangential to water content contours, during cooling with further decompression.  相似文献   

20.
The sequential growth of biotite, garnet, staurolite, kyanite, andalusite, cordierite and fibrolitic sillimanite, their microstructural relationships, foliation intersection axes preserved in porphyroblasts (FIAs), geochronology, P–T pseudosection (MnNCKFMASH system) modelling and geothermobarometry provide evidence for a P–T–t–D path that changes from clockwise to anticlockwise with time for the Balcooma Metamorphic Group. Growth of garnet at ～530 °C and 4.6 kbar during the N–S‐shortening event that formed FIA 1 was followed by staurolite, plagioclase and kyanite growth. The inclusions of garnet in staurolite porphyroblasts that formed during the development of FIAs 2 and 3 plus kyanite growth during FIA 3 reflect continuous crustal thickening from c. 443 to 425 Ma during an Early Silurian Benambran Orogenic event. The temperature and pressure increased during this time from ～530 °C and 4.6 kbar to ～630 °C and 6.2 kbar. The overprinting of garnet‐, staurolite‐ and kyanite‐bearing mineral assemblages by low‐pressure andalusite and cordierite assemblages implies ～4‐kbar decompression during Early Devonian exhumation of the Greenvale Province.  相似文献   

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