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1.
天然气水合物广泛分布于陆地冻土带和深海地层,资源潜力巨大,其中Ⅱ类水合物藏占有重要地位。为加强对Ⅱ类水合物藏开采规律的认识,结合实际水合物藏参数,使用数值模拟方法研究了热水驱替开采Ⅱ类水合物藏的动态规律,并与降压法的开采效果进行了对比分析。结果表明:①热水驱替开采Ⅱ类水合物藏时,产气速率和分解气速率首先快速上升,然后以较快速度下降至趋于相对稳定;累产气和累分解气上升较快;气体采出程度和水合物分解程度均处于较高水平(>60%)。②热水驱替对Ⅱ类水合藏的开采具有一定的适应性,与降压法开采相比,热水驱替方式下储层水合物的分解更彻底,气体采出程度、水合物分解程度也更优,但具有较低的累积气水比,产水量较大。 相似文献
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天然气水合物超声和时域反射联合探测技术 总被引：9，自引：0，他引：9
首次将超声探测技术和时域反射技术集成于一个系统中,可实时探测沉积物中水合物饱和度和声学参数。进行了58个轮次的水合物生成与分解实验,超声、时域反射和温压异常3种方法所探测到的生成点、分解点吻合,这说明利用超声技术和时域反射技术联合探测沉积物中水合物的饱和度与声速是十分有效的,将有助于更好地了解含水合物沉积层的物理性质,为海洋天然气水合物的地球物理勘探和资源评价提供基础性参数。 相似文献
3.
Numerical studies of methane production from Class 1 gas hydrate accumulations enhanced with carbon dioxide injection 总被引：2，自引：0，他引：2
Class 1 gas hydrate accumulations are characterized by a permeable hydrate-bearing interval overlying a permeable interval with mobile gas, sandwiched between two impermeable intervals. Depressurization-induced dissociation is currently the favored technology for producing gas from Class 1 gas hydrate accumulations. The depressurization production technology requires heat transfer from the surrounding environment to sustain dissociation as the temperature drops toward the hydrate equilibrium point and leaves the reservoir void of gas hydrate. Production of gas hydrate accumulations by exchanging carbon dioxide with methane in the clathrate structure has been demonstrated in laboratory experiments and proposed as a field-scale technology. The carbon dioxide exchange technology has the potential for yielding higher production rates and mechanically stabilizing the reservoir by maintaining hydrate saturations. We used numerical simulation to investigate the advantages and disadvantages of using carbon dioxide injection to enhance the production of methane from Class 1 gas hydrate accumulations. Numerical simulations in this study were primarily concerned with the mechanisms and approaches of carbon dioxide injection to investigate whether methane production could be enhanced through this approach. To avoid excessive simulation execution times, a five-spot well pattern with a 500-m well spacing was approximated using a two-dimensional domain having well boundaries on the vertical sides and impermeable boundaries on the horizontal sides. Impermeable over- and under burden were included to account for heat transfer into the production interval. Simulation results indicate that low injection pressures can be used to reduce secondary hydrate formation and that direct contact of injected carbon dioxide with the methane hydrate present in the formation is limited due to bypass through the higher permeability gas zone. 相似文献
4.
刘金龙 王淑红 AsiriObeysekara XIANGJiansheng PabloSalinas ChristopherPain JonnyRutqvist 颜文 《热带海洋学报》2020,39(1):94-105
海洋天然气水合物稳定带气烟囱结构中存在被水合物充填的裂隙, 表明在自然条件下沉积物中曾发生过流体压裂以及相关的流体流动和水合物形成。在水合物稳定带内实施人为的流体压裂工程, 并联合其他方法(如降压或注热)进行水合物开采, 有望提高开采效率。水合物稳定带内, 无论是自然条件下发生的流体压裂过程, 还是人为实施的流体压裂工程, 都存在水合物反应和沉积物裂隙变形之间的耦合响应。当前, 已有不少数值程序对水合物反应与沉积物弹塑性变形的耦合过程进行了定量研究, 但尚没有数值程序能够计算水合物反应和离散裂隙变形之间的耦合过程。文章将TOUGH+Hydrate程序、IC-FERST和Solidity两者的耦合程序进行了进一步耦合, 为水合物稳定带内的流体压裂计算提供了一种耦合计算方法, 同时通过一个算例初步验证了该耦合计算方法的可行性。验证结果表明, 该耦合计算方法经进一步改进后有望应用于定量研究水合物稳定带内的裂隙变形和水合物反应过程。 相似文献
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Natural gas hydrate, as a potential energy resource, deposits in permafrost and marine sediment with large quantities. The current exploitation methods include depressurization, thermal stimulation, and inhibitor injection. However, many issues have to be resolved before the commercial production. In the present study, a 2-D axisymmetric simulator for gas production from hydrate reservoirs is developed. The simulator includes equations of conductive and convective heat transfer, kinetic of hydrate decomposition, and multiphase flow. These equations are discretized based on the finite difference method and are solved with the fully implicit simultaneous solution method. The process of laboratory-scale hydrate decomposition by depressurization is simulated. For different surrounding temperatures and outlet pressures, time evolutions of gas and water generations during hydrate dissociation are evaluated, and variations of temperature, pressure, and multiphase fluid flow conditions are analyzed. The results suggest that the rate of heat transfer plays an important role in the process. Furthermore, high surrounding temperature and low outlet valve pressure may increase the rate of hydrate dissociation with insignificant impact on final cumulative gas volume. 相似文献
6.
海洋天然气水合物的巨大储量刺激了世界各国能源部门努力研究如何从天然气水合物储层生产天然气。根据水合物形成的条件,只有当水合物处在其相平衡条件以外,水合物才能分解。因此,水合物的开采方法只能为热熔法、抑制剂刺激法、减压法和地面分解法。为了对天然气水合物储层中气体的生产有个定量的评估,本文以水合物开采井为例,运用数学方法推导了水合物井中气体的产生量。结果表明,在天然气水合物储层中,天然气释放量是井内水合物分解温度、压力及水合物层气体渗透性的敏感函数。该函数可以用于天然气水合物井气体开采量的计算及对水合物储层可开采性评价。 相似文献
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Hydro-thermo-chemo and mechanically coupled processes determine hydrate morphology and control gas production from hydrate-bearing sediments. Force balance, together with mass and energy conservation analyses anchored in published data provide robust asymptotic solutions that reflect governing processes in hydrate systems. Results demonstrate that hydrate segregation in clayey sediments results in a two-material system whereby hydrate lenses are surrounded by hydrate-free water-saturated clay. Hydrate saturation can reach ≈2% by concentrating the excess dissolved gas in the pore water and ≈20% from metabolizable carbon. Higher hydrate saturations are often found in natural sediments and imply methane transport by advection or diffusion processes. Hydrate dissociation is a strongly endothermic event; the available latent heat in a reservoir can sustain significant hydrate dissociation without triggering ice formation during depressurization. The volume of hydrate expands 2-to-4 times upon dissociation or CO2CH4 replacement. Volume expansion can be controlled to maintain lenses open and to create new open mode discontinuities that favor gas recovery. Pore size is the most critical sediment parameter for hydrate formation and gas recovery and is controlled by the smallest grains in a sediment. Therefore any characterization must carefully consider the amount of fines and their associated mineralogy. 相似文献
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2015~2016年在神狐新钻探区钻遇大量水合物岩心,证实南海北部神狐新钻探区具有较好的水合物成藏环境和勘探前景。结合2008~2009年该区采集的地震资料,我们对晚中新世以来细粒峡谷的沉积特征及其相应的水合物成藏模式进行了分析。通过对大量地震剖面进行解释,发现该区峡谷两侧的隆起上发育大量的滑塌体。本文通过岩心粒度分析,地震相识别分析和水合物测井响应分析等手段综合识别出对水合物成藏有控制作用的三种类型的滑塌体：原生滑塌体、峡谷切割滑塌体、和同生断裂滑塌体。结合沉积速率、流体流速分析和峡谷迁移等沉积学要素对滑塌体成因进行分析,认为峡谷切割滑塌体由于后期峡谷迁移对前期滑塌体切割形成的、同生断裂滑塌体是由于隆起区基底不平引起差异性沉降而形成的。不同类型的滑塌体发育位置不同：原生滑塌体常发育在隆起中坡度较缓的区域、峡谷切割成因滑塌体常发育在不定向迁移的峡谷两侧、同生断裂滑塌体常发育在隆起中坡度起伏较大的区域。三种类型滑塌及其相应的水合物成藏模式不同,其中原生滑塌体有利于水合物成藏,而另外两种类型的滑塌体由于其不能对自由气进行有效封堵而不利于水合物成藏。根据三种滑塌体对水合物成藏的响应指出在粗粒的含有孔虫粉砂岩储层上,覆盖细粒的泥岩对自由气进行封堵有利于水合物成藏,并且多层的泥岩覆盖是造成水合物稳定带中水合物多个分层成矿现象出现的原因。 相似文献
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天然气水合物注热水分解前缘热作用因素分析 总被引：2，自引：0，他引：2
为研究天然气水合物注热水分解前缘的热作用影响,建立了考虑孔隙介质中水合物饱和度的分解前缘数学模型,并进行迭代分析求解;实验测温前缘和电阻前缘与数学模型拟合前缘较好的吻合,误差控制在8%以内;分析了注热水温度和速率对分解前缘的热作用影响:温度对分解前缘影响的误差不超过8.71%,较大流速对分解前缘影响误差为4.53%,在提高注入热水温度的同时以较大注入速率能减小对水合物分解前缘的热作用影响。 相似文献
11.
TOUGH+HYDRATE 水合物模型参数敏感性分析 总被引：1，自引：0，他引：1
运用国际上较为先进的水合物开采模拟软件TOUGH+HYDRATE(T+H)对我国南海水合物藏竖井降压开采假设进行数值模拟,采用LH-OAT全局敏感性分析方法,对模型中19个普遍应用的水合物层参数进行了敏感性分析,并对参数敏感性从重到轻进行了极敏感、敏感、一般敏感和不敏感4个水平的等级划分。研究表明:T+H的参数敏感性随评价目标、时间和空间位置的不同而不同。对CH4气体累积产量有显著影响的参数有:Stone指数(n)、固相渗透率缩减指数(PRE)、绝对渗透率(Permeabilities)、流体临界饱和度(CMPS)。随着模拟时间的增加,参数对水合物饱和度的整体敏感度提高。在空间分布上,随着与井壁水平距离的增加,所有参数对水合物饱和度的敏感度降低。敏感参数的确定对提高模型的准确性有重大意义。在实际应用中要有针对性地调节参数,以获得最优效果。 相似文献
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ABSTRACTA model test program for studying soil stratum failure and pore pressure variation during tetrahydrofuran (THF) hydrate dissociation considering the effects of heating and drainage conditions is presented in this paper. The temperature and pore pressures are recorded during heating. Test results show that the THF hydrate would dissociate to be liquid and then gas when heating. Once pore pressure generated by the flow of released gas/water exceeded the strength of over layer, the layered fractures and soil-gas/water mixture outburst would occur. The high heating temperature and low permeability of over layer both cause excess pore pressure generation and more serious stratum failures. 相似文献
13.
To what extent methane liberated from marine hydrate will enter the ocean during a warmer world is unknown. Although methane release due to hydrate dissociation has been modelled, it is unclear whether or not methane will reach the seafloor during a warmer world and therefore contribute to oceanic and atmospheric budgets. Here we show, using a new three-dimensional (3-D) seismic dataset, that some hydrate deposits surround the gas chimneys passing through the HSZ. Bottom water warming since the last glacial maximum (LGM) is interpreted to cause hydrate dissociation but critically some of the released methane was not vented to the ocean. The released gas caused seal failure and free gas entered the hydrate stability zone (HSZ) through vertical gas chimneys to where new hydrate accumulations formed. This process is a new evidence for methane recycling and could account in part for the lack of methane in ice core records that cover warming events during the late Quaternary. This research provides new insight into how methane could be recycled rather than vented during a warmer world. 相似文献
14.
Downhole wireline log (DWL) data was acquired from eight drill sites during China's first gas hydrate drilling expedition (GMGS-1) in 2007. Initial analyses of the acquired well log data suggested that there were no significant gas hydrate occurrences at Site SH4. However, the re-examination of the DWL data from Site SH4 indicated that there are two intervals of high resistivity, which could be indicative of gas hydrate. One interval of high resistivity at depth of 171–175 m below seafloor (mbsf) is associated with a high compressional- wave (P-wave) velocities and low gamma ray log values, which suggests the presence of gas hydrate in a potentially sand-rich (low clay content) sedimentary section. The second high resistivity interval at depth of 175–180 mbsf is associated with low P-wave velocities and low gamma values, which suggests the presence of free gas in a potentially sand-rich (low clay content) sedimentary section. Because the occurrence of free gas is much shallower than the expected from the regional depth of the bottom simulating reflector (BSR), the free gas could be from the dissociation of gas hydrate during drilling or there may be a local anomaly in the depth to the base of the gas hydrate stability zone. In order to determine whether the low P-wave velocity with high resistivity is caused by in-situ free gas or dissociated free gas from the gas hydrate, the surface seismic data were also used in this analysis. The log analysis incorporating the surface seismic data through the construction of synthetic seismograms using various models indicated the presence of free gas directly in contact with an overlying gas hydrate-bearing section. The occurrence of the anomalous base of gas hydrate stability at Site SH4 could be caused by a local heat flow conditions. This paper documents the first observation of gas hydrate in what is believed to be a sand-rich sediment in Shenhu area of the South China Sea. 相似文献
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南海北部大陆边缘天然气水合物稳定带厚度的地热学研究 总被引：1，自引：1，他引：0
The exploration of unconventional and/or new energy resources has become the focus of energy research worldwide,given the shortage of fossil fuels.As a potential energy resource,gas hydrate exists only in the environment of high pressure and low temperature,mainly distributing in the sediments of the seafloor in the continental margins and the permafrost zones in land.The accurate determination of the thickness of gas hydrate stability zone is essential yet challenging in the assessment of the exploitation potential.The majority of previous studies obtain this thickness by detecting the bottom simulating reflectors(BSRs) layer on the seismic profiles.The phase equilibrium between gas hydrate stable state with its temperature and pressure provides an opportunity to derive the thickness with the geothermal method.Based on the latest geothermal dataset,we calculated the thickness of the gas hydrate stability zone(GHSZ) in the north continental margin of the South China Sea.Our results indicate that the thicknesses of gas hydrate stability zone vary greatly in different areas of the northern margin of the South China Sea.The thickness mainly concentrates on 200–300 m and distributes in the southwestern and eastern areas with belt-like shape.We further confirmed a certain relationship between the GHSZ thickness and factors such as heat flow and water depth.The thickness of gas hydrate stability zone is found to be large where the heat flow is relatively low.The GHSZ thickness increases with the increase of the water depth,but it tends to stay steady when the water depth deeper than 3 000 m.The findings would improve the assessment of gas hydrate resource potential in the South China Sea. 相似文献
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珠江口盆地神狐海域是天然气水合物钻探和试验开采的重点区域,大量钻探取心、测井与地震等综合分析表明不同站位水合物的饱和度、厚度与气源条件存在差异。本文利用天然气水合物调查及深水油气勘探所采集的测井和地震资料建立地质模型,利用PetroMod软件模拟地层的温度场、有机质成熟度、烃源岩生烃量、流体运移路径以及不同烃源岩影响下的水合物饱和度,结果表明:生物成因气分布在海底以下1500 m范围内的有机质未成熟地层,而热成因气分布在深度超过2300 m的成熟、过成熟地层。水合物稳定带内生烃量难以形成水合物,形成水合物气源主要来自于稳定带下方向上运移的生物与热成因气。模拟结果与测井结果对比分析表明,稳定带下部生物成因气能形成的水合物饱和度约为10%,在峡谷脊部的局部区域饱和度较高;相对高饱和度(>40%)水合物形成与文昌组、恩平组的热成因气沿断裂、气烟囱等流体运移通道幕式释放密切相关,W19井形成较高饱和度水合物的甲烷气体中热成因气占比达80%,W17井热成因气占比为73%,而SH2井主要以生物成因为主,因此,不同站位甲烷气体来源占比不同。 相似文献
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天然气水合物资源潜力评价 总被引：2，自引：0，他引：2
作为一种新型能源的天然气水合物越来越引起人们的重视。研究表明,在永冻区水合物主要存在于地下130～2000m,海洋中的水合物主要存在于海底以下100～1100m,水合物矿层的厚度可从几厘米到30m左右。目前海相和极地永冻区水合物资源量估计约为20000万亿m^3。近些年来,很多国家包括日本、印度和美国投入大量的资金进行水合物资源的研究。虽然在有些基础性问题的研究上,如对已证实的含水合物地层中水合物聚集的资源量的估算等方面存在差异,但这些研究项目的开展可以帮助我们了解水合物储层的属性、开采体系的设计以及更为重要的开采成本及经济效益等关键性问题。 相似文献
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用地球化学方法勘查中国南海的天然气水合物 总被引：7，自引：0，他引：7
天然气水合物是一种未来新型能源,赋存于低温高压环境下的海洋沉积物中,但也可形成于大陆永久冻土带中。天然气水合物资源量巨大,具有经济和环境上的研究意义。近年来,国际上己对天然气水合物的产况、分布和形成机理开展了大量研究,但国内这方面的工作还刚刚开展。对中国南海的调查表明该区存在天然气水合物赋存的有利地质条件、温压条件和富含有机质的沉积条件。在南海的许多海区还发现了指示天然气水合物存在的地震标志(BSR)。介绍了在南海天然气水合物勘查中的地球化学异常标志。这些地球化学异常的产生可能与天然气水合物的形成或分解过程有关。研究内容包括沉积物中气体含量(主要为甲烷和乙烷),甲烷的碳同位素,孔隙水中阴离子(Cl^-、SO4^2-等)、阳离子(Ca^2 、Mg^2 、Ba^2 、Sr^2 ,B^3 和NH4^ 等)浓度和δ^18,δD,δ^11B,及^87Sr／^86Sr等同位素组成,此外还对海底沉积物的热释光特征和紫外、可见、近红外反射光谱特征开展了探索性研究。通过进一步加强理论和实验研究,结合地球物理和地球化学资料,在不远的将来将会在南海发现和圈定天然气水合物矿藏。 相似文献
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Preliminary studies of Caspian Sea have shown the possibility of gas hydrate accumulations, because of suitable physicochemical conditions, existence of clayey deposits, and high concentrations of organic matter. Studies have indicated that gas hydrates are mainly composed of methane. Therefore, based on physicochemical equations for methane hydrate stability in different pressure, temperature, and salinity, this study was designed to calculate the potential of gas hydrate formation in the Caspian Sea basin. For this, data of more than 600 locations were analyzed and in each location, upper and lower limits of methane hydrate formation zone were calculated. Then, the zoning maps of upper and lower limits were prepared which can be useful for exploring the gas hydrate as an energy source or predicting gas hydrate hazards. According to the calculations and maps, methane hydrate formation in Caspian Sea, theoretically, can take place from near the seabed to 4000 and 2500 m beneath the sea surface when low and high geothermal gradient are supposed, respectively. By comparing the results with gas hydrate zones revealed in geophysical profiles, it has been shown that, in Caspian Sea, gas hydrates probably accumulate near the lower limit when a high geothermal gradient is assumed. 相似文献