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1.
Metal levels (cadmium, cobalt, chromium, copper, iron, nickel, lead and zinc) of seventeen different edible wild fungi species (Agaricus campestris, Calocybe gambosa, Coprinus comatus, Hericium coralloides, Hydnum repandum, H. repandum var. rufescens, Lactarius deliciosus, L. salminocolor, Macrolepiota procera, Pleurotus ostreatus, P. ostreatus var. columbinus, Ramaria aurea, R. stricta, Rhizopogon luteolus, Sparassis crispa, Suillus bovinus, Tricholoma terreum) growing in Bolu-Turkey were measured by inductively coupled plasma optical emission spectrocopy. The obtained data were analyzed with “statistical package for the social sciences” statistics program. In addition, relation between metal concentrations in both soil and fungi samples were investigated. The highest metal concentrations in Bolu District, Turkey were measured in A. campestris (cadmium 0.270, chromium 2.735 and zinc 7.683), C. comatus (iron 160.12), M. procera (copper 15.990, cobalt 0.352 and nickel 3.645), R. luteolus (Pb 4.756) mg/kg dw (dry weight). As a result of the measurements, it was observed that metal uptake is related with the species of fungi and is also affected by pH and organic contents of the soil.  相似文献   

2.
The purpose of this study was to determine and assess the concentrations of trace metals in surface seawaters and sediments from different coastal habitats of the Red Sea coast of Yemen. Surface seawater and sediment samples were collected, treated and analyzed for cadmium, cobalt, manganese, chromium, lead, iron, nickel, copper, zinc and vanadium by the atomic absorption spectrometric analysis. The concentrations were high for cadmium, cobalt and lead and low or consistent with the natural background concentrations for the rest of the metals. However, the coastal habitats of the Red Sea coast of Yemen are still considered unpolluted, it is concluded that the cadmium cobalt and lead levels in surface seawaters are high and could have negative effects on marine life of the sites. Further studies are needed to characterize the sources fate, biogeochemical processes and impacts of these trace metals on coastal habitats and marine life of the region.  相似文献   

3.
In the present study sediment and water samples collected from Kowsar Dam reservoir in Kohkiluye and Boyerahmad Province, southwest of Iran, are subjected to bulk digestion and chemical partitioning. The concentrations of nickel, lead, zinc, copper, cobalt, cadmium, manganese and iron in water and bed sediment were determined by atomic absorption spectrometry. The concentrations of metals bounded to five sedimentary phases were estimated. On this basis, the proportions of natural and anthropogenic elements were calculated.The anthropogenic portion of elements are as follows: zinc (96 %)> cobalt (88 %)> iron (78 %)> magnesium (78 %)> nickel (78 %)> copper (66 %)> lead (63 %)> cadmium (59 %). The results show sediment contamination by nickel, cadmium and lead, according to the world aquatic sediments and mean earth crust values. Manganese and copper have strong association with organic matter and are of high portion of sulfide bounded ions. Finally, The degree of sediment contamination was evaluated using enrichment factor, geo-accumulation index (Igeo) and pollution index (IPoll). The sediments were identified to be of high cadmium and lead pollution index. The pattern of pollution intensity according to enrichment factor is as follows; manganese (1.25) < copper (1.63) < zinc (1.93) < cobalt (2.35) < nickel (3.83) < lead (12.63) < cadmium (78.32). Cluster analysis was performed in order to assess heavy metal interactions between water and sediment. Accordingly, nickel, cadmium and copper are earth originated. Zinc, copper and manganese are dominated by pH. All the elemental concentrations in water and sediment are correlated except for sedimental copper.  相似文献   

4.
The remobilization of iron, manganese, cobalt, cadmium, copper and zinc in the pore water of estuarine sediment cores at Yingkou was assessed using diffusive equilibrium in thin films and diffusive gradients in thin films techniques. A relatively anoxic system (+33.7 to ?224.1 mV) in the sediment cores might cause the reductive release of iron, manganese and cobalt into pore water from the estuarine sediment. High-average concentrations of iron (47.85 μg ml?1) and manganese (3.81 μg ml?1) were observed using diffusive equilibrium in thin films on the sediment core, but the concentration of cobalt (18.02 ng ml?1) was relatively low. A strong correlation between iron and cobalt was observed based on the vertical profiles of the metals. Manganese and iron were more readily released from the solid phase to the solution. The peak cobalt, copper and zinc concentrations were observed in the upper layer (2–4 cm) measured using diffusive gradients in thin films. However, the peak iron, manganese and cobalt concentrations were located in the deeper layer (≥7 cm). In addition, the concentration profiles measured using diffusive gradients in thin films of cobalt, copper and zinc were independent of the iron, manganese and cobalt distribution with respect to depth.  相似文献   

5.
Sediment and interstitial water from four cores in Saanich Inlet were analyzed for total iron, manganese, nickel, cobalt, copper, molybdenum, zinc, lithium and strontium. In addition, three separate sediment fractions were analyzed:
1.
(i) dilute acid soluble  相似文献   

6.
In the study, the relationship between some aquatic insect species (Ephemeroptera, Plecoptera, Trichoptera and Odonata) and some heavy metals (cadmium, lead, copper, zinc, nickel, iron and manganese) and boron were assessed using data obtained from the Ankara Stream, which flows through Ankara, the capital city of Turkey and receives high organic and industrial wastes. Sampling was carried out monthly along the Ankara Stream in 1991. environmental data were used to explain biological variation using multivariate techniques provided by the program canonical correspondence analysis ordination. The ordination method canonical correspondence analysis was applied to evaluate the relationships between environmental variables and distribution of aquatic insect larvae. Data sets were classified by two way indicator species analysis. In this study, aquatic insecta communities have been shown by canonical correspondence analysis ordination as related to total hardness, pH, cadmium, lead, copper, zinc, nickel, iron, manganese and boron. Cadmium, lead, copper and boron exceeded limits of the United States Environmental Protection Agency criteria for aquatic life. Trichopteran, Dinarthrum iranicum was an indicator of two way indicator species analysis and was placed close to the arrow representing copper. Odonate, Aeschna juncea was an indicator of two way indicator species analysis in site 10 and was placed close to the arrows representing manganese, lead, and nickel. Trichopteran, Cheumatopsyche lepida and odonate, Platycnemis pennipes were indicators of two way indicator species analysis for sites 6, 7, 11, 14, 15, 18 and were placed close to the arrows representing cadmium, boron, iron and total hardness.  相似文献   

7.
Earthquakes in the Gulf of Aqaba were compiled from the Jordan Seismological Observatory bulletins, Saudi Arabia (SNSN, King Abdulaziz City for Science and Technology), and Egypt (National Research Institute of Astronomy and Geophysics, Helwan) sources and were relocated after reexamining the P and S arrival times, testing the efficiency of stations used to determine the location of Aqaba events, calculating the average value of V p/V s, and choosing the best crustal model for the study area. The earthquake epicenters are distributed along the eastern side of the Gulf of Aqaba.  相似文献   

8.
The purpose of this study is to determine the present levels of atmospheric trace element pollution in the Murat Mountain of Aegean Region in the western part of Turkey. Therefore, 29 different plants were selected as potential biomonitors of trace elements including nickel, zinc, iron, lead, cadmium and manganese (??g/g, dry weight). The samples were collected from two different heights of Murat Mountain. Atomic absorption spectrometry was used to determine the concentrations of trace elements. The mean concentrations determined at 1,000?m altitude ranged from 0.139 to 4.518, 0.223 to 0.986, 0.359 to 6.930, 0.443 to 0.727 and 0.077 to 3.222???g/g, dry weight, for nickel, zinc, iron, lead and manganese, respectively. At 1,600?m altitude, the values ranged from 0.191 to 6.248, 0.302 to 1.008, 2.387 to 8.896, 0.345 to 0.570 and 0.195 to 3.502???g/g, dry weight, for nickel, zinc, iron, lead and manganese, respectively. No cadmium was found at both altitudes. For determination of existence of any differences between the averages of the herbaceous and woody plants, comparisons were made by the independent sample t test. In the statistical analysis, comparison of trace element pollution values of herbaceous and woody plants for nickel, lead and manganese was significant (P?<?0.05), while it was not for iron and zinc.  相似文献   

9.
This paper presents one of the first investigations into the geochemical enrichment of the middle and lower Mvoti river system. Chemical elements are naturally present in aquatic sediments, but their concentrations tend to rise to potentially toxic levels via both natural and anthropogenic processes. This study evaluated the concentrations of aluminum, arsenic, boron, barium, cadmium, calcium, cobalt, chromium, copper, iron, lead, magnesium, manganese, molybdenum, nickel, phosphorous, selenium, silicon, strontium, titanium, vanadium and zinc, using inductively coupled plasma optical emission spectroscopy. The levels of elements present were used to assess their spatial distribution within the river and to determine the contamination factors and enrichment factors for each element. The pollution load index (PLi) is another contributing parameter that was calculated to determine the degree of pollution at each site. The results indicate that the sediments of the Mvoti are low to moderately polluted and deteriorating with time (average PLi value of 5.19), and that a major contributing factor to this contamination is natural sources.  相似文献   

10.
Four sediment cores representing adjacent mudflat and mangrove sub-environments of middle estuary (Shastri) were analyzed for sand, silt, clay, and organic carbon. Total metal concentration of iron (Fe), manganese (Mn), nickel (Ni), zinc (Zn), chromium (Cr), copper (Cu), cobalt (Co), and lead (Pb) and chemical speciation of Fe, Mn, and Co on selected samples was also carried out on mudflat cores. The sediments in the upper middle estuary were found to be deposited under highly varying hydrodynamic energy conditions; whereas lower middle estuary experienced relatively stable hydrodynamic energy conditions with time. The tributary joining the river near the upper middle estuary is found to be responsible for the addition of enhanced organic carbon and metal concentrations. Speciation study indicated Fe and Co are from natural lithogenic origin while Mn is derived from anthropogenic sources. Higher Mn and Co than apparent effects threshold can pose a high risk of toxicity to organisms associated with these sediments.  相似文献   

11.
We measured the amount of arsenic, chromium, copper, lead, nickel, vanadium, and zinc accumulated over a five-year period from 1997 to 2002 in surface sediments of seven salt marshes along the New Brunswick coast of the Bay of Fundy, Canada. Study sites extended from outer to inner Bay, spanning a gradient in tidal range (6–12 m) and mean sediment deposition rate (0.27–1.76 cm yr−1). In each study site, metal concentrations were measured in low and high marsh areas. Concentrations of chromium, nickel, and zinc appear to be within their natural range, while arsenic, lead, and vanadium are enriched in some sites. Calculated sediment metal loadings rates showed variability among marsh sites that closely followed sediment deposition patterns, suggesting sediment deposition rate is the driving factor of short-term metal accumulation in Fundy marshes. The value of salt marshes as a sink for metals may be enhanced by high sedimentation rates.  相似文献   

12.
Chemical speciation of fine particle bound trace metals   总被引：5，自引：4，他引：1  
This study reported quantifications of fine particle bound trace metals and their potential health risks for residents in Guangzhou, a rapidly developing and most populated city in South China. The fine particle samples were collected from October 29th. to November 8th. of 2006 at two different elevations in a mainly residential area and analyzed for the total concentration of aluminum, iron, zinc, lead, manganese, copper, arsenic, chromium, nickel, cadmium, molybdenum and cobalt. Results showed that the fine particle concentrations ranged from 95.8μg/m3to 194.7 μg/m3 at the ground and 83.3-190.0 μg/m3 on the roof, which were much higher than the 24 h fine particle standard (35 μg/m3) recommended by USEPA. The total concentrations of zinc, lead, arsenic, chromium and cadmium in fine particle were 504.8, 201.6, 24.3, 7.7 and 4.4 ng/m3, respectively, which were comparable to other major cities of China, but much higher than major cities outside of China. A sequential extraction procedure was used to fractionate these fine particle bound metals into four different fractions. Results indicated that most toxic metals were mainly distributed in bioavailable fractions. For instance, about 91 % of cadmium, 85 % of lead and 74 % of arsenic were in bioavailable forms. Risk calculations with a simple exposure assessment model showed that the cancer risks of the bioavailable fractions of arsenic, chromium and cadmium were 3 to 33 times greater than usual goal, indicating serious health risks to the residents in this urban area.  相似文献   

13.
论述了最近５０年来世界矿产资源供求关系的变化和现状,着重讨论了独联体国家、北美地区西欧国家、中欧和东欧国家、日本、澳大利亚和南非共和国、欧佩克国家的矿产资源情况。俄罗斯仍是矿产资源大国,但矿山开采工业每况愈下,许多矿种没有清楚的探明储量。独联体一些国家某些矿种储量大,但没有维持经济正常发展的其它矿种。美国的某些矿种储量大,但其它矿种不足,例如石油、天然气、煤、铝、铜、铅、锌、锡、镍、钴、钨等需求量  相似文献   

14.
Water and sediment samples were collected from 20 location of the Buriganga river of Bangladesh during Summer and Winter 2009 to determine the spatial distribution, seasonal and temporal variation of different heavy metal contents. Sequential extraction procedure was employed in sediment samples for the geochemical partitioning of the metals. Total trace metal content in water and sediment samples were analyzed and compared with different standard and reference values. Concentration of total chromium, lead, cadmium, zinc, copper, nickel, cobalt and arsenic in water samples were greatly exceeded the toxicity reference values in both season. Concentration of chromium, lead, copper and nickel in sediment samples were mostly higher than that of severe effect level values, at which the sediment is considered heavily polluted. On average 72 % chromium, 92 % lead, 88 % zinc, 73 % copper, 63 % nickel and 68 % of total cobalt were associated with the first three labile sequential extraction phases, which portion is readily bioavailable and might be associated with frequent negative biological effects. Enrichment factor values demonstrated that the lead, cadmium, zinc, chromium and copper in most of the sediment samples were enriched sever to very severely. The pollution load index value for the total area was as high as 21.1 in Summer and 24.6 in Winter season; while values above one indicates progressive deterioration of the sites and estuarine quality. The extent of heavy metals pollution in the Buriganga river system implies that the condition is much frightening and may severely affect the aquatic ecology of the river.  相似文献   

15.
The concentrations of potential toxic elements (PTEs) such as cadmium (Cd), copper (Cu), lead (Pb) and zinc (Zn) were measured in five different stations of Rameswaram (RM) coast, Gulf of Mannar (GoM), India, in coastal waters in sediments and tissues of Adocia pigmentifera. Concentration of PTEs (Cd, Cu, Pb and Zn) was found to be highest in sediments followed by A. pigmentifera and seawater samples collected from the different stations of RM coast. The pattern of accumulation of PTEs in the three sample types is of the following order Zn < Pb < Cu < Cd. The seasonal variation of these PTEs also followed the same pattern. One-way analysis of variance (ANOVA) with Tukey’s HSD post hoc test has revealed significant differences among stations S1–S4 when compared with the station S5 which is considered as the reference site. Correlation coefficient study showed no significant correlation in the concentration of PTEs in A. pigmentifera, seawater and sediment samples. The concentration of all the PTEs in different sample types has exceeded the FAO/WHO/sediment background values, except for the concentration of Zn in A. pigmentifera and sediment sample, which did not exceed the limits. The contamination factor (CF) and geoaccumulation index (I geo) values indicated significant contamination of PTEs in the sediments from different stations of RM coast, India. Variations found between the sample types during the studies could be due to changes in levels of pollution discharge over time, availability of PTEs for adsorption as well as variations in the sampling season. Increasing urban sprawl and release of effluents both from domestic and industrial sources are the main sources of pollution at RM coast and are the prime reasons for the loss of existing diverse ecosystem.  相似文献   

16.
The concentrations of six heavy metals were studied in five living coral species and their fossil counterparts collected along the Jordanian Coast of the Gulf of Aqaba. The study aimed at investigating the validity of using coral skeletons as bioindicators for environmental pollution by heavy metals in the Gulf of Aqaba, Red Sea. The skeletal samples of the collected corals were acid digested and analyzed for Cd, Cu, Fe, Mn, Pb, and Zn content using flame atomic absorption spectrophotometer. The results obtained have shown that higher concentrations of heavy metals were found in coral skeletons from areas hosting intense developments and human activities. The massive Porites sp. coral tended to accumulate the highest metal concentrations among the other species (except for Mn). This was due to interspecific differences or selectivity of heavy metals between different coral species. It was noteworthy that fossil coral species recorded higher average metal concentrations than their living counterparts; this was attributed to surface contamination due to prolonged burial of the fossil corals in sediment over the years. The study concluded that corals (specially the massive Porites species) are vulnerable to the accumulation of high concentrations of heavy metals in their skeletons and therefore can serve as proxies to monitor environmental pollution.  相似文献   

17.
The granites of the Ukrainian shield are secondary; the “shield,” in the first instance, is a segment of a fold belt which extends from the Black Sea, via the Voronezh Arch, to the Kola Peninsula. The metamorphic ungranitized anticlines are narrow folds in which are found iron, copper, zirconium and precious metals. Iron, titanium, copper, graphite and mica deposits are found in the folds of granitized gneisses, migmatites, anatektites and granites. The crystalline metal ores are associated with metamorphosed elastics and evaporites; the titanium, copper, cobalt, gold, vanadium, mercury, chromium and nickel deposits – associated with sedimentary volcanics and evaporites. The high-grade metamorphics Contained the deposits of titanium, iron, calcium, magnesium, copper, vanadiuta, lead and zinc. The chromites and nickel silicates are associated with the intrusives. In short, metamorphic history and mineralogy exercised a direct control over the size and grade of ore deposits.  相似文献   

18.
Exudates from conifer trees, presumably consisting largely of volatile materials, were sampled at 19 subalpine localitites in Colorado and Idaho where anomalous amounts of several metals were determined in vegetation and mull during previous geochemical testing. The trees sampled were lodgepole pine (Pinus contorta), Engelmann spruce (Picea engelmannii) and Douglas fir (Pseudotsuga menziesii). The condensed exudates were passed through No. 40 Whatman filters, and through 5-micron, 0.45-micron, and 0.05-micron average-pore-diameter membrane filters, evaporated to dryness, and each residue was ashed and analyzed by a semiquantitative spectrographic method.The ashed residues of the exudates contain lithium, beryllium, boron, sodium, magnesium, titanium, vanadium, chromium, manganese, iron, cobalt, nickel, copper, zinc, gallium, arsenic, strontium, yttrium, zirconium, molybdenum, silver, lead, bismuth, cadmium, tin, antimony, barium, and lanthanum.The presence of these elements suggests that volatile exudates from vegetation are a medium for the transport of elements in the biogeochemical cycle in subalpine environments. Thus, air sampling and analysis of aerosols derived from volatile exudates may be a useful tool in geochemical exploration.  相似文献   

19.
锰的氧化物和氢氧化物在污染水体净化中的应用研究现状   总被引：17，自引：1，他引：17  
经过对锰的氧化物和氢氧化物在净化污染水体中的应用综合研究，发现该氧化物和氢氧化物样品能有效去除污染水体中的有毒有害金属离子和 氧化降解苯酚、2－丙醇、苯及印染废水等有机物，其污染净化能力主要是基于表面络合反应、表面离子交换作用和变价元素的氧化还原作用。同时介绍了锰氧化物和氢氧化物所具有的4个环境属性；离子交换、氧化还原、粒径效应和孔道效应，提出将结构特征与环境化学有机结合，深入探讨其环境属性与污染净化能力之间的关系是目前主要的研究方向。  相似文献   

20.
Foraminifers, being sensitive to minute changes, either undergo morphological changes or even disappear from the area completely due to pollution or under unfavourable conditions. The characteristics of foraminifers to incorporate the signature of presence of pollutants are considered to be an effective tool for temporal pollution monitoring studies. Totally, 12 offshore samples (both sediment and water) were taken along a normal profile along the coast of Cuddalore for pollution studies. Apart from foraminiferal studies, geochemical studies of the sediments collected are also undertaken to correlate and substantiate the findings. The near-shore area has a higher concentration of trace elements. If these concentrations exceed or go below permissible limits, it is collateral for the marine community and for those who consume these marine resources. The concentration of trace elements like lead, zinc, manganese, copper, chromium and nickel was illustrated to give an idea of the trace element concentration of the study area. The sedimentological studies reveal the organic matter and calcium carbonate content of the samples, and the bottom water measurements reveal the temperature, salinity and dissolved oxygen of sample locations. These are used to determine whether the conditions prevailing could sustain life. The ratio of living to dead species is also determined and correlated with sedimentological and geochemical parameters. Pollution studies have given way to identify morphological abnormalities in the species mainly in Spiroloculina, Quinqueloculina, Elphidium, etc. but we could not find many effects among the faunal assemblages because of the nature of the sediments found in that area.  相似文献   

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