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1.
The geochemical evolution of groundwater in the Ordovician-Cambrian aquifer system in the northern part of the Baltic Artesian Basin (BAB) illustrates how continental glaciations have influenced groundwater systems in proglacial areas. The aquifer system contains water that has originated from various end-members: recent meteoric water, glacial meltwater and relict Na-Cl brine. The saline formation water that occupied the aquifer system prior to the glacial meltwater intrusion has been diluted by meltwaters of advancing-retreating ice sheets. The diversity in the origin of groundwater in the aquifer system is illustrated by a wide variety in δ18O values that range from −11‰ to −22.5‰. These values are mostly depleted with respect to values found in modern precipitation in the area. The chemical and isotopic composition of groundwater has been influenced by mixing between waters originating from different end-members. In addition, the freshening of a previously saline water aquifer due to glacial meltwater intrusion has initiated various types of water-rock interaction (e.g. ion exchange, carbonate mineral dissolution).  相似文献   

2.
Spatial variations of δD and δ18O among seven tributaries and their water sources were investigated in the Heishui Valley of the Yangtze River, China during the dry-season in 2004. A one-way ANOVA (analysis of variation) test showed that both δD (p?18O (p?=?0.045) spatially varied among the seven tributaries. The plot of δ18O versus δD for the river water collected at different locations showed that isotopic fractionation occurred during the snow and glacial melting process. The depleted δ18O and δD in the tributary waters distributed above the local meteoric water line (LMWL) suggested that the glacial and early snowpack meltwater largely recharged these streams during the early spring. The meltwater was isotopically distinguishable from the precipitation and river water, which had been evaporated during warmer and drier times. If glaciers and snow accumulation diminish with future climate warming, the recharge of these tributaries’ baseflow will decline and the security of the water resource in this watershed will be threatened.  相似文献   

3.
The chemistry of water in the Cambrian-Ordovician aquifer in six midwestern states has been studied as part of the Northern Midwest Regional Aquifer-System Analysis of the U.S. Geological Survey. Dissolved-solids concentrations generally increase perpendicular to the direction of regional groundwater flow, from less than 400 mg/liter in southeast Minnesota, southwest Wisconsin, and northeast Iowa to more than 10,000 mg/liter in northwest Missouri. Isotopic ratios of hydrogen and oxygen are significantly depleted from north to south, with an areal distribution approximately parallel to the distribution of dissolved solids. For example, δ18O in southern Iowa and northern Missouri is about 6 parts per thousand lighter than δ18O of modern recharge water in Minnesota and Wisconsin. Covariance between δ18O and δD of the groundwater, similar to that of modern precipitation, suggests that the differences in isotopic ratios between groundwater and modern recharge water reflect meteoric signatures of water during past recharge events rather than geochemical processes such as isotopic exchange with aquifer materials. The pronounced parallelism between the distribution of isotopes and dissolved solids over large areas probably reflects largescale recharge of Pleistocene glacial meltwater into the aquifer system, which probably had a paleoflow system with a gradient from northeast to southwest rather than from northwest to southeast.  相似文献   

4.
中国北方第四系地下水同位素分层及其指示意义   总被引：11，自引：0，他引：11  
中国北方第四系地下水中的D, 18O, 3H和14C含量存在明显的分层现象, 这种现象与末次冰期以来的古气候变化有着较好的对应性, 反映了全新世和末次冰期气候条件的差别以及地下水不同的形成机制.深层地下水为晚更新世末次冰期时期形成, 其δ(D) 和δ(18O) 值与全新世补给形成的浅层地下水相比, 分别贫4× 10-3~ 16× 10-3和1× 10-3~ 2× 10-3, 说明末次冰期时期年均气温较低.古地下水中D和18O的大陆梯度与全新世以来地下水中的梯度基本相同, 说明在过去30000a来尽管气温发生变化, 但中国北方大陆的大气循环模式没有发生实质性的改变.地下水同位素分层现象反映了3种不同的补给机制及参与现代水循环程度.这些信息对大陆尺度上的水循环研究和地下水的可持续开发利用有着重要的意义.   相似文献   

5.
The groundwater flow pattern of the western part of the Guarani Aquifer System (GAS), Brazil, is characterized by three regional recharge areas in the north, and a potentiometric divide in the south, which trends north–south approximately. Groundwater flow is radial from these regional recharge areas toward the center of Paraná Sedimentary Basin and toward the western outcrop areas at the border of the Pantanal Matogrossense, because of the potentiometric divide. The isotopic composition of GAS groundwater leads to understanding the paleoclimatic conditions in the regional recharge areas. The δ18O and δ2H isotopic ratios of GAS groundwaters vary, respectively, from –9.1 to –4.8‰ V-SMOW and –58.4 to –21.7‰ V-SMOW. In the recharge zones, enriched δ18O values are observed, while in the confined zone lighter δ18O values are observed. These suggest that climatic conditions were 10°C cooler than the present during the recharge of these waters. The δ13C ratios in groundwater of GAS, in the study area, vary from –19.5 to –6.5‰ VPDB, increasing along the regional flow lines toward the confined zone. This variation is related to dissolution of carbonate cement in the sandstones.  相似文献   

6.
The recharge and origin of groundwater and its residence time were studied using environmental isotopic measurements in samples from the Heihe River Basin, China. δ18O and δD values of both river water and groundwater were within the same ranges as those found in the alluvial fan zone, and lay slightly above the local meteoric water line (δD=6.87δ18O+3.54). This finding indicated that mountain rivers substantially and rapidly contribute to the water resources in the southern and northern sub-basins. δ18O and δD values of groundwater in the unconfined aquifers of these sub-basins were close to each other. There was evidence of enrichment of heavy isotopes in groundwater due to evaporation. The most pronounced increase in the δ18O value occurred in agricultural areas, reflecting the admixture of irrigation return flow. Tritium results in groundwater samples from the unconfined aquifers gave evidence for ongoing recharge, with mean residence times of: less than 36 years in the alluvial fan zone; about 12–16 years in agricultural areas; and about 26 years in the Ejina oasis. In contrast, groundwater in the confined aquifers had 14C ages between 0 and 10 ka BP.  相似文献   

7.
Climatic instability during the late Pleistocene has been reflected in the pattern of groundwater recharge. This report summarizes palaeoclimate knowledge during the late Weichselian in Europe. During this period the majority of northern Europe was covered by thick ice sheets and permafrost, preventing aquifers from recharging. In contrast, southern Europe was generally free of these palaeoclimatic features. Palaeoclimatic information has been combined with isotope data to better understand the palaeorecharge conditions and recharge timing across the European continent. The 18O and 2H relationship shows latitudinal plus climatic influences. Radiocarbon data show that while southern European aquifers have generally been recharged continuously during the last 40,000 years, northern European aquifers typically show a recharge gap during the Last Glacial Maximum. Areas that underwent continuous recharge during the entire late Pleistocene period can also be distinguished from areas where recharge to aquifers was prevented during the Last Glacial Maximum. Finally, several examples are presented of melt-water recharge or subglacial recharge. The identification of such diversity in the groundwater palaeorecharge in Europe is of great importance for modellers developing management schemes for groundwater resources.  相似文献   

8.
Hydrological systems have been seriously affected by changes of glaciations and snow covers in Mount Gongga, Sichuan, China, but the relevance of ice-snow melt for alpine river basin hydrology is so far not well known. To better understand hydrological features of the Hailuogou River, changes of δ18O and δ2H were investigated by analyzing 117 water samples collected from May 2008 to November 2009. Our results show that the stream water contains a relatively intermediate magnitude of isotopic variations, with δ18O ranging from ?18.09 to ?13.08 ‰ and δ2H from ?126.5 to ?88.8 ‰. The average values are both higher than those of ice-snow meltwater, but lower than those of meteoric water. These data also show a gradually increasing trend from upstream to downstream, and these changes might document the fingerprint of ice-snow melt in the headwater region and indicate the increasing recharge of heavy isotope-enriched waters with flow distance. The similarity in slopes of δ2H and δ18O relationship for meteoric waters and stream waters suggests that the isotopic signature of precipitation is well preserved in stream flow, and during the rainfall and stream flow the evaporation is only minor. Based on δ18O model, the results suggested that the fraction of ice-snow meltwater input over the total stream flow ranged from 84.50 to 86.52 % in the headwater region, but the fraction of ice-snow meltwater input from upper basin downward was significantly decreased. The study demonstrates that ice-snow meltwater is a substantially important water source in alpine regions on the edge of Tibetan Plateau.  相似文献   

9.
With the aim of evaluating the influence of glacial meltwater signature on tree‐ring stable isotopes, we analysed δ18O and δ13C in the tree rings of Larix decidua Mill. specimens growing in the area of an ice‐contact lake (Lago Verde, at Miage Glacier, European Alps). Additionally, we analysed δ18O in the glacial meltwater of the lake and of the glacier stream and compared it with the δ18O of precipitation predicted by a spatial model. We found that tree‐ring cellulose of trees fed by glacial meltwaters (LVW site) is significantly more depleted in δ18O than at a control site LVM (?0.91‰) fed only by precipitation, thus reflecting the measured higher depletion of glacial meltwaters with respect to local precipitation. δ13C values did not show significant differences in mean values between the two sites but an anomalous correlation with summer temperature was found at the LVW site, probably due to the different responses of trees stomatal conductance. Over the 30‐year period of analysis, four years at LVW (1992, 1995, 2003 and 2009) were markedly depleted in δ18O. These years are those when the highest summer temperatures were recorded in the area (the ones during which glacier ablation usually increases and more depleted meltwaters fill the lake), with the exception of 1995 during which high water levels occurred following the year with the second highest summer temperature (1994). Overall, our analysis demonstrates that tree‐ring δ18O, driven by the glacial meltwater signature in the lake, can be used for detecting past major glacier runoff events. The proposed approach could also be used for quantifying past glacier runoff and for defining past distribution areas of glacial meltwaters in glacier forefields, thus contributing to past environmental reconstructions and to hazard assessment.  相似文献   

10.
Groundwater recharge and evolution in the Quaternary aquifer beneath the Dunhuang Basin was investigated using chemical indicators, stable isotopes, and radiocarbon data to provide guidance for regional water management. The quality of groundwater and surface water is generally good with low salinity and it is unpolluted. The dissolution of halite and sylvite from fine-grained sediments controls concentrations of Na+ and K+ in the groundwater, but Na+/Cl− molar ratios >1 in all samples are also indicative of weathering of feldspar contributing to excess Na+. The dissolution of carbonate minerals yields Ca2+ to the groundwater, thereby exerting a strong influence on groundwater salinity. The δ18O and δ2H values in unconfined groundwater are enriched along the groundwater flow path from SW to NE. In contrast, confined groundwater was depleted in heavy isotopes, with mean values of −10.4‰ δ18O and −74.4‰ δ2H. Compared with the precipitation values, all of the groundwater samples were strongly depleted in heavy isotopes, indicating that modern direct recharge to the groundwater aquifers in the plains area is quite limited. The unconfined water is generally young with radiocarbon values of 64.9–79.6 pmc. In the northern basin, radiocarbon content in the confined groundwater is less than 15 pmc and an uncorrected age of ∼15 ka, indicates that this groundwater was recharged during a humid climatic phases of the late Pleistocence or early Holocene. The results have important implications for inter-basin water allocation programmes and groundwater management in the Dunhuang Basin.  相似文献   

11.
The Ledo‐Paniselian Aquifer in Belgium offers unique opportunities to study periglacial groundwater recharge during the Last Glacial Maximum (LGM), as it was located close to the southern boundary of the ice sheets at that time. Groundwater residence times determined by 14C and 4He reveal a sequence of Holocene and Pleistocene groundwaters and a gap between about 14 and 21 ka, indicating permafrost conditions which inhibited groundwater recharge. In this paper, a dataset of noble gas measurements is used to study the climatic evolution of the region. The derived recharge temperatures indicate that soil temperatures in the periods just before and after the recharge gap were only slightly above freezing, supporting the hypothesis that permafrost caused the recharge gap. The inferred glacial cooling of 9.5°C is the largest found so far by the noble gas method. Yet, compared to other palaeoclimate reconstructions for the region, recharge temperatures deduced from noble gases for the cold periods tend to be rather high. Most likely, this is due to soil temperatures being several degrees higher than air temperatures during periods with extended snow cover. Thus the noble‐gas‐derived glacial cooling of 9.5°C is only a lower limit of the maximum cooling during the LGM. Some samples younger than the recharge gap are affected by degassing, possibly related to gas production during recharge in part of the recharge area, especially during times of melting permafrost. The findings of this study, such as the occurrence of a recharge gap and degassing related to permafrost and its melting, are significant for groundwater dynamics and geochemistry in periglacial areas. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

12.
The oxygen isotopic composition of land-snail shells may provide insight into the source region and trajectory of precipitation. Last glacial maximum (LGM) gastropod shells were sampled from loess from Belgium to Serbia and modern land-snail shells both record δ18O values between 0‰ and − 5‰. There are significant differences in mean fossil shell δ18O between sites but not among genera at a single location. Therefore, we group δ18O values from different genera together to map the spatial distribution of δ18O in shell carbonate. Shell δ18O values reflect the spatial variation in the isotopic composition of precipitation and incorporate the snails' preferential sampling of precipitation during the warm season. Modern shell δ18O decreases in Europe along a N-S gradient from the North Sea inland toward the Alps. Modern observed data of isotopes in precipitation (GNIP) demonstrate a similar trend for low-altitude sites. LGM shell δ18O data show a different gradient with δ18O declining toward the ENE, implying a mid-Atlantic source due to increased sea ice and a possible southern displacement of the westerly jet stream. Balkan LGM samples show the influence of a Mediterranean source, with δ18O values decreasing northward.  相似文献   

13.
Ayadi  Rahma  Trabelsi  Rim  Zouari  Kamel  Saibi  Hakim  Itoi  Ryuichi  Khanfir  Hafedh 《Hydrogeology Journal》2018,26(4):983-1007

Major element concentrations and stable (δ18O and δ2H) and radiogenic (3H and 14C) isotopes in groundwater have proved useful tracers for understanding the geochemical processes that control groundwater mineralization and for identifying recharge sources in the semi-arid region of Sfax (southeastern Tunisia). Major-ion chemical data indicate that the origins of the salinity in the groundwater are the water–rock interactions, mainly the dissolution of evaporitic minerals, as well as the cation exchange with clay minerals. The δ18O and δ2H relationships suggest variations in groundwater recharge mechanisms. Strong evaporation during recharge with limited rapid water infiltration is evident in the groundwater of the intermediate aquifer. The mixing with old groundwater in some areas explains the low stable isotope values of some groundwater samples. Groundwaters from the intermediate aquifer are classified into two main water types: Ca-Na-SO4 and Ca-Na-Cl-SO4. The high nitrate concentrations suggest an anthropogenic source of nitrogen contamination caused by intensive agricultural activities in the area. The stable isotopic signatures reveal three water groups: non-evaporated waters that indicate recharge by recent infiltrated water; evaporated waters that are characterized by relatively enriched δ18O and δ2H contents; and mixed groundwater (old/recent) or ancient groundwater, characterized by their depleted isotopic composition. Tritium data support the existence of recent limited recharge; however, other low tritium values are indicative of pre-nuclear recharge and/or mixing between pre-nuclear and contemporaneous recharge. The carbon-14 activities indicate that the groundwaters were mostly recharged under different climatic conditions during the cooler periods of the late Pleistocene and Holocene.

  相似文献   

14.
The stable isotopic characteristics were used together with the total chloride to assess changes in groundwater from recharge zones into the carbonate aquifer in an arid environment. The aquifer under study represents a major source of groundwater and thermal springs in Al-Ain city, which are located at the northern part of Jabal Hafit in the United Arab Emirates (UAE). The relationship between oxygen and hydrogen isotopic composition of groundwater is established and is described by δD?=?2.2δ18O???9.96. The lower slope and y-intercept of groundwater samples relative to the local meteoric waterline suggests that the isotopic enrichment is due to the evaporation of shallow groundwater after recharge occurs. The majority of the shallow groundwater samples have a negative deuterium excess (d-excess) which might be ascribed to high a degree of evaporation, while most of the groundwater samples from deep wells, have a positive value of d-excess which may be related to a low degree of evaporation. The δ18O values of the thermal waters suggest enrichment towards δ18O of the carbonate rocks because of the exchange with oxygen at higher temperatures. A possible mixing between thermal or hot water and shallow groundwater is evident in some samples as reflected by δD vs. Cl and d-excess vs. δ18O plots.  相似文献   

15.
Recent analysis of a sediment core in the eastern Arabian Sea revealed a negative pulse of about 1% in the δ18O value of the planktonic Foraminifera around the last glacial maximum (LGM). This pulse has been attributed to (i) increased runoff into the Bay of Bengal from the east-flowing south Indian rivers due to enhancement of the northeast winter monsoon, and (ii) an increase in Arabian sea-surface temperature caused by the weakening of the southwest monsoon at the LGM. We show that the speculation on which the latter hypothesis is based, is not supported by observational data and cannot fully account for the observed magnitude of the spike. With a view to assessing the validity of the first mechanism, we have modelled the mixed layer of the Bay of Bengal as a well-mixed box. The model calculations show that to account for the pulse requires a change of about 10% in either the annual rate of river input or its isotopic composition. For the northeast monsoon to account for the pulse it would mean that the rainfall should have increased by a factor of five to ten during the LGM. No evidence for such an increase is indicated in the available palaeoclimatic data. We explain the freshwater spike by invoking increased discharge of glacial meltwater from the Tibetan plateau into the Bay of Bengal. We show that the proxy climate data from the Indo-Tibetan region that has become available recently provides substantial evidence for the occurrence of a warming event around the LGM, which supports our mechanism.  相似文献   

16.
The environmental isotopes such as deuterium and oxygen-18 and the deuterium excess values have been used to assess groundwater recharge sources and their dynamics in Khan Younis City in the Gaza Strip in Palestine. Three isotopic lines for the relationship between δ2H and δ18O were used in the assessment. These lines are the global meteoric water line, the local meteoric water line and the groundwater evaporation line. The δ2H, δ18O and D-excess values indicate that deuterium and oxygen-18 isotopes originated in the groundwater from groundwater mixing with rainfall and other water sources; the groundwater in the area recharged from rainfall from a distant source that came from the Mediterranean Sea and from other sources such as wastewater, irrigation return flow and saline water.  相似文献   

17.
An investigation was conducted in Beijing to identify the groundwater evolution and recharge in the quaternary aquifers. Water samples were collected from precipitation, rivers, wells, and springs for hydrochemical and isotopic measurements. The recharge and the origin of groundwater and its residence time were further studied. The groundwater in the upper aquifer is characterized by Ca-Mg-HCO3 type in the upstream area and Na-HCO3 type in the downstream area of the groundwater flow field. The groundwater in the lower aquifer is mainly characterized by Ca-Mg-HCO3 type in the upstream area and Ca-Na-Mg-HCO3 and Na-Ca-Mg-HCO3 type in the downstream area. The δD and δ18O in precipitation are linearly correlated, which is similar to WMWL. The δD and δ18O values of river, well and spring water are within the same ranges as those found in the alluvial fan zone, and lay slightly above or below LMWL. The δD and δ18O values have a decreasing trend generally following the precipitation → surface water → shallow groundwater → spring water → deep groundwater direction. There is evidence of enrichment of heavy isotopes in groundwater due to evaporation. Tritium values of unconfined groundwater give evidence for ongoing recharge in modern times with mean residence times <50 a. It shows a clear renewal evolution along the groundwater flow paths and represents modern recharge locally from precipitation and surface water to the shallow aquifers (<150 m). In contrast, according to 14C ages in the confined aquifers and residence time of groundwater flow lines, the deep groundwater is approximately or older than 10 ka, and was recharged during a period when the climate was wetter and colder mainly from the piedmont surrounding the plain. The groundwater exploitation is considered to be “mined unsustainably” because more water is withdrawn than it is replenished.  相似文献   

18.
ＩＮＴＲＯＤＵＣＴＩＯＮＭａｎｙｓｔｕｄｉｅｓｏｆｇｌｏｂａｌｃｈａｎｇｅｓｓｈｏｗｔｈａｔｔｈｅｈｙｄｒｏｌｏｇｉｃａｌｃｙｃｌｅｏｆａｃｏｎｔｉｎｅｎｔａｌｓｃａｌｅｃａｎｂｅｒｅｌａｔｅｄｔｏｃｌｉｍａｔｉｃｃｈａｎｇｅｓ(Ａｎｄｅｒｓｏｎｅｔａｌ.,2 0 0 1;ＫａｒｅｎａｎｄＤａｒａ,2 0 0 1;ＭｉｃｈａｅｌａｎｄＭｉｃｈａｅｌ,1999;Ｈｕｇｏｅｔａｌ.,1996 ;Ｌａｒｒｙｅｔａｌ.,1996 ) .Ｃｕｒ ｒｅｎｔｄｉｓｔｒｉｂｕｔｉｏｎｐａｔｔｅｒｎｓｏｆｄｅｕｔｅｒｉｕｍａｎｄｏｘｙｇｅｎ 18ｃｏｎｃｅｎ …  相似文献   

19.
Aquifers within the Pampa del Tamarugal Basin (Atacama Desert, northern Chile) are the sole source of water for the coastal city of Iquique and the economically important mining industry. Despite this, the regional groundwater system remains poorly understood. Although it is widely accepted that aquifer recharge originates as precipitation in the Altiplano and Andean Cordillera to the east, there remains debate on whether recharge is driven primarily by near-surface groundwater flow in response to periodic flood events or by basal groundwater flux through deep-seated basin fractures. In addressing this debate, the present study quantifies spatial and temporal variability in regional-scale groundwater flow paths at 20.5°S latitude by combining a two-dimensional model of groundwater and heat flow with field observations and δ18O isotope values in surface water and groundwater. Results suggest that both previously proposed aquifer recharge mechanisms are likely influencing aquifers within the Pampa del Tamarugal Basin; however, each mechanism is operating on different spatial and temporal scales. Storm-driven flood events in the Altiplano readily transmit groundwater to the eastern Pampa del Tamarugal Basin through near-surface groundwater flow on short time scales, e.g., 100–101 years, but these effects are likely isolated to aquifers in the eastern third of the basin. In addition, this study illustrates a physical mechanism for groundwater originating in the eastern highlands to recharge aquifers and salars in the western Pampa del Tamarugal Basin over timescales of 104–105 years.  相似文献   

20.
The effect of seasonally reversing monsoons in the northern Indian Ocean is to impart significant changes in surface salinity (SS). Here, we report SS changes during the last 32 kyr in the Lakshadweep Sea (southeastern Arabian Sea) estimated from paired measurements of d18O and sea surface temperature (SST) using Globigerinoides sacculifer, an upper mixed layer dwelling foraminifera. The heaviest d18OG.sacculifer (–0.07±0.08‰) is recorded between 23 and 15 ka, which could be defined as the last glacial maximum (LGM). The d18OG.sacculifer shift between the LGM and Holocene is 2.07‰. The SST shows an overall warming of 2°C from the LGM to Holocene (28°C to 30°C). However, coldest SSTs are observed prior to LGM, i.e., ~27 ka. The SS was higher (~38 psu) throughout most of the recorded last glacial period (32.5–15 ka). This high salinity together with generally lower SSTs suggests a period of sustained weaker summer or stronger winter monsoons. The deglacial warming is associated with rapid reorganization of monsoons and is reflected in decreased salinity to a modern level of ~ 36.5 psu, within a period of ~5 kyr. This indicates intensification of summer monsoons during cold to warm climate transition.  相似文献   

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