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1.
Accelerated erosion of fine‐grained sediment is an environmental problem of international dimensions. Erosion control strategies and targeting of mitigation measures require robust and quantitative identification of sediment sources. Here, we use magnetic ‘fingerprinting’ to characterize soils, and examine their affinity with and contribution to suspended sediments transported within two subcatchments feeding Bassenthwaite Lake, northwest England. A high‐resolution soil magnetic susceptibility survey was made using a field susceptometer (ZH Instruments, SM400 probe). Combining the spatial and vertical (down‐profile) soil magnetic data, a subset of soil profiles was selected for detailed, laboratory‐based magnetic remanence analyses. The magnetic properties of the catchment soils are highly particle size‐dependent. Magnetic analyses were performed on the 31–63 µm fraction, for particle size‐specific comparison both with the suspended sediments and lake sediments. Fuzzy cluster analysis groups the soil magnetic data into six clusters, apparently reflecting variations in parent material and horizon type, with three magnetically hard soils as unclassified outliers. Examination of the cluster affinity of the soils, suspended sediments and lake sediments indicates that topsoils of the upper Newlands Valley and subsoils around Keskadale Beck are a major source of the Newlands Beck suspended load, and the recent (post‐nineteenth century) sediments in the deep lake basin. Older lake sediments show strong affinity with a small number of the Derwent suspended sediments and one of the Glenderamackin soils. A large number of Derwent suspended sediments show no affinity with any of the soils or lake sediments, instead forming a coherent, discrete and statistically unclassified group, possibly resulting from mixing between the magnetically hard subsoils of the medium to high‐altitude Glenderamackin and Troutbeck areas and softer, lower altitude Glenderamackin soils. The lack of any affinity of these suspended sediments with the lake sediments may indicate deposition along the Derwent flood plain and/or in the shallow delta of Lake Bassenthwaite. Particle size‐specific magnetic fingerprinting is thus shown to be both highly discriminatory and quantitatively robust even within the homogeneous geological units of this catchment area. Such a methodological approach has important implications for small–large scale catchment management where sources of sediment arising from areas with uniform geology have been difficult to determine using other approaches, such as geochemical or radionuclide analyses. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

2.
Critical load calculations have suggested that groundwater at depth of 2 m in Sweden is very sensitive to acid load. As environmental isotope studies have shown that most of the runoff in streams has passed through the soil, there is a risk in the near future of accelerated acidification of surface waters.

To assess the importance of the last soil horizon of contact before discharge, the upper 0–0.2m of soils in seven discharge zones were analysed for pools of base cations, acidity and base saturation. The sites were about 3–4 m2 in size and selected from two catchments exposed to different levels of acid deposition.

The soils in the seven sites had high concentrations of exchangeable base cations and consequently high base saturation. The high correlation (r2 = 0.74) between base saturation in the soils of the discharge zones and mean pH of the runoff waters suggested that the discharge zone is important for surface water acidification. The high pool of exchangeable base cations will buffer initially against the acid load. As the cation exchange capacity (meq dm−3) and base saturation were lower in the sites from the catchment receiving lower deposition, these streams may be more vulnerable to acidification in the near future. The high concentration of base cations in non-exchangeable fractions may also buffer against acidification as it is likely that some of these pools will become exchangeable with time.  相似文献   


3.
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4.
亚热带富铁土的磁学性质及其磁性矿物学   总被引：7，自引：3，他引：4  
通过５５个亚热带富铁土的磁化率（χ）、频率磁化率(χｆｄ)、非滞后剩磁（ＡＲＭ）和饱 和等温剩磁（ＳＩＲＭ）等磁性参数测定,结合氧化铁化学形态分析和矿物鉴定,初步明确了亚热 带富铁土的磁学特征及其磁性矿物．磁测数据表明富铁土中存在强磁性的矿物,其磁化率χ 与土壤游离氧化铁（Ｆｅｄ）含量呈极显著指数正相关（Ｒ２＝０．５９７１）,频率磁化率χｆｄ与土壤游离氧 化铁含量呈极显著直线正相关（Ｒ２＝０．４２８９）．富铁土的χｆｄ和非滞后磁化率χＡＲＭ。值表明土壤 中的磁性矿物以超顺磁性（ＳＰ）和稳定单畴（ＳＳＤ）颗粒为主,富铁上的χ和χＡＲＭ呈极显著直线 正相关（Ｒ＝ ０．９４２９）,证明富铁土的磁性是由风化成土过程产生的 ＳＰ和 ＳＳＤ磁性颗粒贡献 的．矿物磁测结合Ｘ－衍射证明富铁土中的氧化铁矿物由赤铁矿、磁赤铁矿和针铁矿组成。  相似文献   

5.
New measurements of high field magnetisation (Is), remanence (Is), and coercive force (Hc) are presented between 4 and 300 K for x = 0.4, 0.5, 0.6 and 0.8 (Fe3−xTixO4). For x = 0.4 a pronounced minimum is found at T100 K and for X = 0.5 and 0.6 broad minima occur around T200 K, apparently coinciding with the temperature for K10. The magnetic properties below T60 K ar complex and were found to be significantly changed by cooling in the presence of a high magnetic field. With no applied field during cooling, a distinct decrease in Is is observed for T60 K, at which temperature there is a peak in the value of Irs. The effe cooling is to eliminate the sharp decrease in Is, reduce Hc and to increase Irs below 60 K to a value the peak value, giving essentially a square hysteresis loop. The results are interpreted in terms of a form of crystallographic phase transition coupled to the magnetisation direction, possibly by the magnetostriction. Square hysteresis loops in ferrites have been explained by the presence of Jahn-Teller ions and, in the present case, the low temperature of the observed effect may be a consequence of the weak Fe2+ Jahn-Teller ion coupled to other effects such as spin-lattice coupling.

Details of this work can be found in Schmidbauer, E. and Readman, P.W., 1982. Low temperature magnetic properties of Ti-rich Fe---Ti spinels. J. Magn. Magn. Mat., 27: 114–118. A paper reporting further work on Fe2.4Ti0.6O0.4 is in preparation.  相似文献   


6.
We report new metal-silicate partition coefficients for Ni, Co and P at 7.0 GPa (1650–1750°C), and Ni, Co, Mo, W and P at 0.8, 1.0 and 1.5 GPa (1300–1400°C). Guided by thermodynamics, all available metal-silicate partition coefficients, D(i), where i is Ni, Co, P, Mo and W, are regressed against 1/T, P/T, lnf(O2), ln(1 − Xs) (XS is mole fraction of S in metallic liquid) and nbo/t (non-bridging oxygen/tetrahedral cation ratio, a silicate melt compositional-structural parameter) to derive equations of the following form: ln D(i) = aln f(O2) + (b/T) + (cP/T) + d(nbo/t) + eln(1 − XS) + f. Expressions for solid metal-liquid silicate and liquid metal-liquid silicate partition coefficients are derived for S-free and S-bearing systems.

We investigate whether Earth's upper-mantle siderophile element abundances can be reconciled with simple metal-silicate equilibrium. Sulfur-free metallic compositions do not allow a good fit. However, Ni, Co, Mo, W and P abundances in the upper mantle are consistent with simple metal-silicate equilibrium at mantle pressures and temperatures (27 GPa, 2200 K, ΔIW(iron-wüstite) = −0.15, nbo/t = 2.7; XS = 0.15). Although these conditions are near the anhydrous peridotite solidus, they are well above the hydrous solidus and probably closer to the liquidus. A hydrous magma ocean and early mantle are consistent with predicted planetary accretion models. These results suggest that siderophile element abundances in Earth's upper mantle were established by liquid metal-liquid silicate equilibrium near the upper-mantle-lower-mantle boundary.  相似文献   


7.
Paleomagnetic measurements have been made on a continuously sampled, 5-m section of a core from Clear Lake, California. The sediments studied span an 8000-year interval centered at 25,000 years B.P., the approximate date of the large-scale, counterclockwise loop of the magnetic vector recorded in sediments from Mono Lake, California. The data from Mono Lake have been interpreted as a geomagnetic excursion with a duration of 600–1000 years. Because Clear Lake is only 320 km from Mono Lake and since each sample from Clear Lake represents 26 years of sedimentation, the magnetic signature of the Mono Lake geomagnetic excursion should be recorded in detail in the Clear Lake samples. Aside from a generally uniform shallowing of inclinations due to compaction, the paleomagnetic record from Clear Lake contains no anomalous features which would correspond to the Mono Lake excursion. Thus it has yet to be shown that the Mono Lake excursion was recorded anywhere besides Mono Lake. Even if the existence of the excursion is ultimately confirmed, its usefulness as a magnetostratigraphic horizon is limited.  相似文献   

8.
巢湖沉积物磁性特征及其对沉积动力的响应   总被引：10，自引：2，他引：8  
对巢湖西部柱样以及杭埠河流域土壤的环境磁学研究表明,磁铁矿是决定磁性特征的主要磁性矿物,杭埠河流域是巢湖西部沉积物的主要来源．靠近巢湖西岸的柱样AC1砂含量较高,X、SIRM值较大而xARM／SIRM较低,说明磁铁矿含量较高、颗粒较粗．距岸稍远的柱样AC2砂含量较低,X、SIRM值也较低,其变化与XARM较相似,与粘土含量变化也有一定程度的相似,AC2沉积物X、SIRM值较ACI小,但XARM／SIRM较高,说明磁铁矿含量较低且颗粒较细．杭埠河流域土壤的磁性测量结果表明,砂、砾含量高的粗骨土磁性最强,富含粗颗粒磁铁矿．巢湖柱样沉积物砂的含量随踞岸远近而不同, 反映了沉积环境的水动力不同,由此产生明显的磁性特征差异,实质是对沉积动力的响应．研究表明磁性参数XARM／SIRM 可以间接反映沉积物中粘土含量的高低变化．  相似文献   

9.
蛇绿岩中枕状玄武岩的古地磁学研究可为古海洋的恢复与演化提供定量化依据.黑龙江省饶河地区中侏罗世枕状玄武岩的岩石学、岩石磁学研究表明,该岩石具备水下喷出特点,发育辉长结构,载磁矿物为磁铁矿.17个采点181块样品的热退磁实验表明,中侏罗世枕状玄武岩记录了高温分量和中温分量,前者为熔岩喷发记录的原生剩磁方向,平均方向D/I=59.4°/46.3°,α95=6.8°,对应的极位置为40.3°N,224.6°E,A95=7°;后者可能为晚侏罗世—早白垩世岩浆热事件的叠加,平均方向D/I=55.4°/60.6°,α95=3.9°,对应的极位置为50.8°N,210.6°E,A95=5.2°.综合考虑区域地质背景,将这一结果与邻区同时代的古地磁数据对比,推测在中侏罗世之前,在饶河杂岩与佳木斯地体之间存在一定规模的海域,与现今日本海相似;早白垩世时期,该海域封闭,饶河杂岩与华北、西伯利亚板块在动力学上已成为整体.  相似文献   

10.
Spatial and temporal measurements of shallow sub-surface soil physical properties were made within a 1 km2 upland catchment. The surface soil layer of the catchment was organic rich (>70% organic matter) with a corresponding total porosity of 81%. Monthly point observations of volumetric water content (θ) were combined with point estimates of total porosity () and the porosity <50 μm (residual), to define the ratio of water filled pore volume:pore volume in pores <50 μm (=θ/residual). Values of θ/residual were compared with discharge to test whether mass flow occurred when θ/residual>1. A correlation between water content and discharge was found, with discharge increasing rapidly when θ/residual approached unity. Similar relationships between water content and catchment discharge were identified for soil units adjacent to the stream when θ/residual approached unity. These data suggest that soil pores >50 μm are of crucial importance in determining catchment discharge. Spatial and temporal variations in soil properties related to moisture content of the soil were also observed. Under dry conditions, a clear division based on aspect was noted, the west-facing side of the catchment being wettest. In wetter months, total porosity and soil water content were significantly affected by soil type and the spatial pattern of soil water content was more variable than in the dryer months. The physical quantification of soil properties in the shallow sub-surface layer proved important in explaining different initial changes in discharge from the catchment in response to a rainfall event.  相似文献   

11.
Factors controlling acidity were studied in the acidic River Lillån in the coastal zone of central northern Sweden. The stream drains the hilly wave-washed terrain and the sediment-covered coastal plain which are the dominating types of landscape in the region. A synoptic study of 38 small streams, representing both types of landscape was also made. Acidity in all streams is caused by organic acids in combination with catchment sources of sulfate. The most acidic streams occur in the hilly terrain because of a high terrestrial export of organic acids and low buffering capacity. Acidic episodes during snowmelt were associated with strongly decreased base cation concentrations, decreased SO2−4 and slightly increased organic acids concentrations. Frequently occurring acid episodes caused by rainstorms and associated outwash of organic acids from forest soils are typical for events in late summer and autumn. It is suggested that, in all essential aspects, the acidity in surface waters in this part of Sweden is of natural origin.  相似文献   

12.
末次冰期时,在雅鲁藏布大峡谷入口处发育了一个古冰川堰塞湖,称为格嘎古堰塞湖.该堰塞湖是认识冰川阻江地貌效应的重要地质证据.古冰川堰塞湖可能会发生多次溃决洪水,通过堰塞湖沉积的分析可以获取堰塞期间的水文事件的信息.本文通过对古堰塞湖沉积39个样品多种磁学参数的详细分析发现,湖相沉积中的砂层低频磁化率（Xlf）为291×10-8m3/kg,泥质沉积的Xlf仅为42×10-8m3/kg;而非磁滞剩磁磁化率（XARM）和饱和等温剩磁（SIRM）的差别则较小.进一步的X-T、Loop和IRM研究以及XARM/Xlf表明,砂层中包含较多的粗颗粒磁铁矿是Xlf较高的主要原因,说明砂层中的磁性矿物没有经过风化破坏,应为近源沉积,并且快速埋藏,指示了溃决事件.本文的结果表明,利用岩石磁学性质以检测古堰塞湖溃决事件是一种可行的新方法.  相似文献   

13.
The spatial distribution of source areas and associated residence times of water in the catchment are significant factors controlling the annual cycles of dissolved organic carbon (DOC) concentration in Deer Creek (Summit County, Colorado). During spring snowmelt (April–August 1992), stream DOC concentrations increased with the rising limb of the hydrograph, peaked before maximum discharge, then declined rapidly as melting continued. We investigated catchment sources of DOC to streamflow, measuring DOC in tension lysimeters, groundwater wells, snow and streamflow. Lysimeter data indicate that near-surface soil horizons are a primary contributor of DOC to streamflow during spring snowmelt. Concentrations of DOC in the lysimeters decrease rapidly during the melt period, supporting the hypothesis that hydrological flushing of catchment soils is the primary mechanism affecting the temporal variation of DOC in Deer Creek. Time constants of DOC flushing, characterizing the exponential decay of DOC concentration in the upper soil horizon, ranged from 10 to 30 days for the 10 lysimeter sites. Differences in the rate of flushing are influenced by topographical position, with near-stream riparian soils flushed more quickly than soils located further upslope. Variation in the amount of distribution of accumulated snow, and asynchronous melting of the snowpack across the landscape, staggered the onset of the spring flush throughout the catchment, prolonging the period of increased concentrations of DOC in the stream. Streamflow integrates the catchment-scale flushing responses, yielding a time constant associated with the recession of DOC in the stream channel (84 days) that is significantly longer than the time constants observed for particular locations in the upper soil. © 1997 John Wiley & Sons, Ltd.  相似文献   

14.
The paper deals with continuous-state reservoirs in discrete time, in terms of the (continuous) Moran transform Ut = Zt + Xt of the (discontinuous) storage levels Zt. In the non-seasonal case, if the inflows Xt have a first-order Markov structure, the modified storage levels Ut have a second-order Markov structure. It is shown that, for each value of u, the limit p(u,v) as t → ∞ of the joint density pt + 1 (u, v) of Ut+ 1 at u and Ut at v satisfies a certain non-standard first-order linear integral equation of the form
or, equivalently, a standard second-order equation of the form
In the seasonal case, with two seasons, the corresponding bivariate density p(u,v) for consecutive seasons satisfies a second-order integral equation of the form
the kernel being a function of the season-to-season inflow transition densities.  相似文献   

15.
本文利用信使号飞船2011-2015年期间在轨磁场数据对水星磁尾电流片的磁场结构分布特征进行了统计分析.为探究磁场结构分布随水星径向距离的变化,电流片划分为近磁尾（-1.5RM > X > -2.0RM）和远磁尾（-2.0RM > X > -2.5RM）两个区域.所得结果表明：（1）无论是近磁尾还是远磁尾,电流片中的磁场都以+Bz分量为主,磁场方向几乎与磁赤道面垂直.（2）相比近磁尾,远磁尾电流片中磁场强度、Bz分量较弱,By分量较强,而且-Bz信号出现概率相对较大,这表明电流片中磁活动相对容易在远磁尾中发生.（3）磁场强度以及Bz分量在晨昏方向上的分布存在晨昏不对称性——在方位角120°~190°范围内相对较弱.弱Bz数据点（Bz<5 nT）也在昏侧（Y>0）发生较为频繁.（4）与Bz分布相反,磁场强By分量（|By|>5 nT）倾向于在晨侧（Y<0）发生.统计分析还表明,磁场By分量与行星际磁场By分量并无明显的相关性.对比地球磁尾电流片,我们对水星磁尾电流片Bz分量、强By分量的晨昏不对称起源机制作了探讨分析.  相似文献   

16.
根据河套盆地周缘断裂带泉水的氢、氧同位素组成和水化学组分,讨论了该区地下水的化学类型、成因及其与地震活动的关系。于2014年9月下旬和2015年4月15日MS5.8阿左旗地震震后在河套盆地周缘的乌拉山断裂带、色尔腾断裂带、狼山断裂带以及桌子山断裂带采集了17个泉水和井水样品,测得水样的TDS分布在143.8~42 553.0mg/L范围内,δD和δ18O值分别在-83.6‰~66.56‰和-11.16‰~8.2‰的范围内,来源为大气降水。根据舒卡列夫分类法,震前水样可划分为13种水化学类型,震后西山咀、圐圙朴隆等5个点采样点泉水的水化学类型发生变化。其中,乌拉山断裂带的水样以HCO3-Ca型低矿化度地表水为主;色尔腾断裂带、狼山断裂带泉水受白垩系含水层影响,矿化度较高,富含HCO-3及SO2-4;桌子山一带受煤矿开采影响,水样以富SO2-4和Cl-的高矿化度水为特征。地震前后TDS、阴、阳离子以及γNa/γCl、γ(SO4+Cl)/γHCO3、γHCO3/γCl等毫克当量比值能够较好地反映地震。2015年4月15日阿左旗MS5.8地震后,呼鲁斯太、迪延阿贵庙及八一井的水化学组成变化较大,对地震响应较为敏感。呼鲁斯太地区泉水的TDS稍有降低,但HCO-3在阴离子中所占比例有所增加,表明震后该地区含水层的泉水与较低矿化度的含碳酸盐岩含水层水发生了混合;八一井的TDS值有所增加,γNa/γCl比值有所降低,表明深部高矿化度水的混入;迪延阿贵庙水样的TDS稍有下降,但NaCl的相对含量较震前有所升高,表明有低矿化度NaCl水的混入。本工作不仅确定了该区水文地球化学背景,而且对地震监测和预测具有一定参考价值。  相似文献   

17.
《Journal of Hydrology》2005,300(1-4):1-19
  相似文献   

18.
Concentrations of suspended particulate matter (SPM), NO3-N and P fractions: PO4-P, dissolved organic P (DOP), particulate P (PP) and bioavailable exchangeable P were examined over 5 storm events in two nested agricultural catchments in NE Scotland: a (51 km2) catchment and its headwater (4 km2). NO3-N showed anticlockwise hysteresis for all storms in both catchments. In contrast, the headwater showed strong clockwise hysteresis of SPM, dissolved and particulate P concentrations, but which weakened through summer to spring. Less pronounced hysteresis of P forms in the larger catchment was attributed to a combination of factors: a less energetic system, nutrient leaching from the floodplain, a point source of a small sewage treatment works and the occurrence of coarser soil and sediment parent materials with less P adsorption and transport capacity. The headwater exhibited a strong ‘first flush’ effect of sediment and dissolved P, particularly following dry conditions, received a significant transfer of readily-solubilized organic P from the surrounding soils in late summer and after manure applications in winter, and was the likely cause of large sediment associated P signals observed in the 51 km2 catchment. Our results suggest that steeper gradient headwaters should be targeted for riparian improvements to mitigate soil erosion from headwater fields. The efficiency of riparian erosion controls is also dependant on the size of the store of fine sediment material within the stream channel and this may be large.  相似文献   

19.
In 1995–1998, Han 11 km terrestrial surge of Kuannersuit Glacier, an outlet glacier of the largest ice cap on Disko Island, West Greenland, affected the catchment dramatically. In order to estimate solute fluxes and provenances, bulk meltwaters were sampled at the main subglacial outlet during the initial part of the quiescent phase. The hydrochemistry is significantly influenced by a subglacial basaltic weathering regime with absence of carbonate minerals. The results show that marine and aerosol derived solutes have minimal contribution to the total ion content, whereas sequestration of atmospheric CO2 associated with carbonation of Ca-rich feldspar and reactive volcanic glass is more dominant than previously reported from glacierized catchments. Application of a sampling strategy dividing water samples into four groups to determine the content of dissolved HCO3− and CO32− shows that the cationic equivalent weathering rate range is 683–860 Σmeq+ m−2 a−1 and solute flux ranges between 76 and 98 t km−2 a−1. The crustal denudation rate is estimated to 26 t km−2 a−1, and the transient CO2 drawdown amounts to 8500–13700 kg C km−2 a−1.  相似文献   

20.
Different opinions exist regarding the specific effect of Mg on soil physical and chemical properties. We hypothesized that Mg2+, compared with Ca2+, reduces saturated hydraulic conductivity (Ks) via promoting clay swelling, disaggregation, and clay dispersion. Two soils (mixed, mesic Typic Hapludalfs) in packed soil columns were leached with either Ca- or Mg-containing solutions at the successive concentrations of 250, 10, 2, 0.5, and 0 mM. Critical flocculation concentration (CFC) in either Ca or Mg systems was determined with flocculation series tests. Aggregate stability and mean weight diameter (MWD) were assessed by wet-sieving. The CFCs were higher in Mg than in Ca for both soils, indicating that Mg is more dispersive than Ca. The MWDs measured using 1–2 mm aggregates of both soils were significantly larger for Ca-soils than for Mg-soils (P=0.05). The Ksr (normalized with initial Ks) started to decline at higher concentrations for Mg than for Ca, and the reduction was much greater in Mg than in Ca above 0.5 mM. The Ksr and percent transmittance (inversely related to turbidity) of leachate at a given eluted pore volume following ‘steady state’ were higher in Ca than in Mg for both soils (P=0.1), indicating lower permeability and more clay dispersion with the Mg treatment. Swelling and disaggregation, which reduced large pores, appeared to be the dominant process causing the rapid initial decline of Ksr. Clay dispersion and subsequent pore plugging became progressively important when electrolyte concentration was reduced to below CFCs.  相似文献   

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