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1.
江西省鄱阳湖地区地下水环境背景的形成 总被引：8，自引：0，他引：8
本文以丰富的实际资料,论证了鄱阳湖地区地下水的Mg,Ca、Na、K、SiO_2、Fe、Mu、Cr、V、Co、Ni、Ti、Be、Li、Sn、Mo、Cu、Pb、Zu、A_5、Hg、Cd、Sr、F、Cl、Br、I等27项化学成分背景的形成。 相似文献
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长江中下游地区地下水中化学元素的背景特征及形成 总被引：46，自引：0，他引：46
本文论证了长江中下游地区地下水中钾、钠、钙、镁、硅、铁、锰、铬、镍、钒、钴、钛、钼、铜、铅、锌、砷、汞、镉、铍、锂、锶、硼、氟、氯、溴、碘的背景特征、形成及分布规律,探讨其与地下水的含水介质成分,上覆岩土性质、氧化还原环境、地下水的径流条件和矿化度以及地下水的酸碱度之间的关系。 相似文献
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浙江省下寒武统荷塘组黑色页岩系地球化学特征 总被引：2，自引：0，他引：2
首次根据浙江省西北部荷塘组岩石样品的实测数据,提出了浙江省荷塘组黑色岩系6个岩性层的Pt、Pd、Au、Ag、Cu、As、Sb、Pb、Mo、Ni、V、P、U、B、Cd、Tl、Se、Zn元素的平均值,运用微量元素和稀土元素的配分模式探讨了成岩环境及元素高含量对环境的影响.荷塘组富集元素较多,富集程度高的有Mo、Se、Cd、Ag、Sb、U、As、P;较富集的有V、B、Cu、Tl、Zn,弱富集的为Au、Pt、Pb、Ni.综合地质地球化学特征研究认为,荷塘组黑色岩系具有寻找含钼、磷、矾和有色金属矿产的潜力. 相似文献
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中国东部岩石地球化学图 总被引：10，自引：2，他引：8
1986～1995年开展的中国东部地壳与岩石化学组成研究在中国东部(105°E以东)约330万km2的范围内系统采集了500余条标准地层剖面、800多个有代表性的火成岩体和变质杂岩体,总计28253件岩石样品,组合成2718件分析样品,对每个岩石组合样品的63种元素含量进行了准确测定,积累了大量的高质量的元素含量分析结果.选择60种元素SiO2、Al2O3、Fe2O3、FeO、MgO、CaO、Na2O、K2O、CO2、Ag、As、Au、B、Ba、Be、Bi、Cd、Cl、Co、Cr、Cs、Cu、F、Ga、Ge、Hf、Hg、Li、Mn、Mo、Nb、Ni、P、Pb、Pd、Pt、Rb、S、Sb、Sc、Se、Sn、Sr、Ta、Th、Ti、Tl、U、V、W、Zn、Zr、Y、La、Ce、Nd、Sm、Eu、Tb、Yb和Lu制作了中国东部岩石地球化学图.根据中国东部各省区区域地质志和1:50万地质图首次编制的中国东部岩石地球化学图基本反映了与特定岩石性有关的岩石地球化学元素含量分布特征、与大地构造单元有关的区域地球化学元素含量的宏观分布特征及不同大地构造单元元素含量背景的变化趋势.例如,CaO、(MgO) 、CO2和Cl的高背景反映地是碳酸盐岩地区,铁族元素Fe2O3、FeO、Mn、Ti、V、Cr、Co、Ni及MgO、Cu、Zn、P、Ga、Nb、Ta、Zr、Hf、Sc和Eu的高背景反映了基性火山岩地区,SiO2和K2O的高背景反映地是大面积分布的酸性岩石地区的地球化学特征.内蒙古兴安褶皱带为SiO2、K2O、Ag、As和Be的高背景分布区域,华北地台边缘、大别造山带和苏鲁造山带为Sr和Ba高背景分布区域,豫西台隆为Cu、Pb、W和Sc的高背景分布区域.南秦岭、西秦岭造山带以挥发性元素Hg、As、Sb、B以及Cd、Se、S的高背景显著特点.对于整个华南褶皱系而言,W、Sn、Bi、Mo、Rb、Cs、Tl、U、Th、Pb、Y和REE(Eu除外)为高背景,此外东南沿海火山岩带有是SiO2、K2O的高背景,而赣南闽西褶皱带还是碱金属Li,稀有元素Be、Nb、Ta,分散元素Cd及F的高背景. 相似文献
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据地质工作者目前已探明的储量表明,我国西北地区有28种矿产占全国等一。这些矿产当中,有甘肃的镍、铂、钴、钯、锇、铱、钌、铑、硒和铸型粘土;青海的锂、钾盐、镁盐、池盐、化工石灰岩、溴、硅石和石棉;新疆的铍、白云母、钠硝石、长石、陶士、蛇纹石和蛭石;陕西的铼、钾长石以及宁夏的石膏。 相似文献
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我国矿产资源丰富,已有探明储量的矿种达132个.其中储量占世界首位的有钨、锑、稀土、锌、锂、钒、钛、硼、硫铁矿、菱铁矿等,居世界第二位的有钖、铅、铌、汞、磷等,位列世界前茅的还有铁、锰、铜、铝、钼、镍、煤、铀及许多非金属矿 相似文献
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随着我国对生态文明建设的重视,自然资源综合调查势在必行,对生物标准物质亦提出了新的需求。当前相关调研工作已经大面积开展,自然资源综合调查、农产品与食品安全评价都需要对生物样品元素组成进行准确测试,需要以生物标准物质作为生物成分测试量值比对和溯源的基础,因此对生物基体标准物质的需求量大幅增加。大米作为主要粮食之一,其食品安全日益受到重视,对大米中的化学成分进行准确的分析测试具有重要的现实意义,因而对大米标准物质的需求量尤为突出,但目前大米成分分析标准物质已供不应求。本文严格按照《标准物质定值的通用原则及统计学原理》（JJF 1343—2012）和《地质分析标准物质的研制》（JJF 1646—2017）等相关规范要求,开展了GBW10010a大米成分分析标准物质的复（研）制工作,包括样品采集、加工制备、均匀性检验、稳定性检验、多家实验室协作定值测试及不确定度评定等关键环节。结果表明：本次复（研）制的大米标准物质定值成分多样、量值准确可靠,符合国家一级标准物质的要求。GBW10010a共定值54项主微量元素,包括Ag、Al、As、B、Ba、Be、Bi、Ca、Cd、Ce、Co、Cr、Cs、Cu、Dy、Er、Eu、Fe、Gd、Ge、Hg、Ho、K、La、Li、Ho、Mg、Mn、Mo、N、Na、Nb、Nd、Ni、P、Pb、Pr、Rb、S、Sb、Sc、Se、Si、Sm、Sr、Tb、Th、Tl、Tm、U、V、Y、Yb、Zn,其中的39项元素给出了标准值及不确定度,包括Ag、Al、As、B、Ba、Ca、Cd、Ce、Co、Cs、Cu、Dy、Er、Fe、Hg、K、Li、Mg、Mn、Mo、N、Na、Nd、Ni、P、Pb、Pr、Rb、S、Sb、Se、Si、Sm、Sr、Tb、Tl、Y、Yb、Zn;15项元素提供参考值,包括Be、Bi、Cr、Eu、Gd、Ge、Ho、Ho、La、Nb、Sc、Th、Tm、U、V。与原有GBW10010大米标准物质相比较,GBW10010a中As、Cd、Co、Cr、Cu、Hg、Mn、Mo、Ni、Zn等重金属元素含量显著下降,其中Cd、Cu、Zn降幅较大,分别下降约39%、43%、38.7%,一定程度上反映了农田生态环境的改善。本批标准物质定值元素总数量增加了6项,新增定值元素Ag、Nb（Nb给出参考值）,并且各项元素不确定度范围整体上有所缩小,如Al、Cd、Cu、Fe、K、Mg、Mo、Na、P、Pb、Se、Zn等对生物易有影响的重要元素,表明了地质分析测试方法技术的进步及定值水平的提高。本批标准物质定值元素涵盖了具有生物效应的大部分主微量元素,适用于农业生态环境地球化学调查与评价、生物样品测试、农产品质量与食品安全评价样品测试时的分析仪器校正、分析方法评价和分析质量监控等多个领域。 相似文献
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采用粉末压片法制样,使用新型X射线荧光光谱仪,对土壤样品中的C、N、S、Cl、Na、Mg、Al、Si、K、Ca、Fe、As、Ba、Br、Ce、Co、Cr、Cu、Ga、Hf、La、Mn、Nb、Ni、P、Pb、Rb、Sc、Sr、Th、Ti、U、V、Y、Zn、Zr等36种组分的直接同时测试进行了探讨测试。研究了测试中各种分析条件及存在问题。结果表明,方法的检出限、精密度和准确度大多数满足多目标地球化学调查样品分析质量的要求,标准物质的测定值与其标准值相吻合,适合土壤样品中多组分的同时直接测定。 相似文献
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TCLP法评价泉州市大气降尘重金属的生态环境风险 总被引：3，自引：0，他引：3
对泉州市不同功能区大气降尘中的重金属(Cu、Zn、Pb、Cd、Cr、As、Fe、Mn、Co、Ni、V)含量进行了分析测定,采用由美国环保署(USEPA)提出并被广泛推荐采用的TCLP法对泉州市不同功能区大气降尘中的重金属元素(Cu、Zn、Pb、Cd、Cr)的生态环境风险进行评价。以TCLP法提取的泉州市大气降尘重金属Cu、Cd、Zn、Pb、Cr、As、Fe、Mn、Co、Ni和V含量分别在2.592～63.20、0.084～2.978、9.276～3141、0.147～345.0、0.628～9.696、0.019-5.152、5.037-248.9、55.00-1261、0.040-63.56、0.735-37.43和0.020-24.07 mg/kg之间。根据TCLP法测定项目的法定阈值,泉州市大气降尘不同程度地受到Cu、Zn、Pb、Cd、Cr的污染,其中以Pb、Zn污染最为严重,其次为Cu、Cd、Cr。相关性分析结果显示,Fe、Mn、Ni、Cr、V的TCLP法提取量受样品pH值的显著影响;Pb、Cd、Mn、Co、Ni、As提取量除了受金属本身的总量影响外,还受到其它元素总量和TCLP提取量的影响。主成分分析结果表明,交通尾气尘、燃油尘、装饰材料尘、地面土壤尘、工业粉尘、建筑尘和燃煤烟尘等是泉州市大气降尘的主要来源,占总贡献率的86.01%。 相似文献
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A review of theories of mechanisms of induced seismicity 总被引：1，自引：0，他引：1
Carl Kisslinger 《Engineering Geology》1976,10(2-4):85-98
Theories of the physical processes leading to the stimulation of seismic activity by underground explosions, fluid injection, and reservoir impoundment are summarized. In all cases, the materials must be pre-stressed to a substantial fraction of their breaking strength in order for seismicity to be induced. Stress concentrations due to the presence of old faults or to inhomogeneities in the material properties play an important role in localizing induced seismicity.
For the few cases for which data are available, the stimulation of earthquakes by fluid injection in bore holes is adequately explained by a Coulomb-Mohr failure criterion and the concept of effective pressure in a water-filled porous mechanism. Reservoir-related earthquakes are most likely due to the same mechanism, but, in view of the low injection pressures, additional physical or chemical effects of the water on the materials may play an important role. There may be a weakening of the materials in old fault zones by the introduction of water or static fatigue in silicate rocks due to stress corrosion. 相似文献
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边坡滚石运动轨迹分段循环算法 总被引：1，自引：0，他引：1
边坡滚石是在基本建设中常遇到的一种工程灾害。其防护结构的设计依据主要是边坡滚石的运动轨迹,因而要对这种灾害进行防治,首先要确定滚石的运动轨迹。根据落石运动全过程的三个阶段,即滚动(滑动)运动阶段、抛物运动阶段和与坡面碰撞阶段,利用分段循环算法分别得到了三个运动阶段的运动速度计算公式。以某岩质边坡构建相似模型,将该理论公式应用于落石运动轨迹预测,验证了公式的可行性和有效性。与现有方法相比,分段循环算法具有计算原理简单明确、易于使用等优点。该方法可用于斜坡区滚石运动特征的预测,并可作为斜坡区滚石灾害防治的依据。 相似文献
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沉管隧道基槽爆破施工对既有堤岸稳定性影响的数值仿真分析 总被引：1，自引：0，他引：1
结合爆破数值模拟中爆破荷载的特点,分析了各种荷载施加方法的特点及爆破震动场模拟的要求,基于圣维南荷载等效原理,提出了爆破荷载的等效施加方法,即将作用在炮孔壁上的爆破荷载等效后,施加在同排炮孔中心线或者面上来模拟爆破荷载的作用。结果表明,等效施加方法在近区存在一定差异,但在中远区吻合得较好。利用该等效荷载施加方法,采用三维实体模型计算分析了某沉管隧道基槽爆破施工对既有堤岸稳定性影响,计算了周围不同位置、不同深度位置处的振动响应,并在此基础上,分析研究了减小爆破振动对既有结构物影响的减振措施,可为类似工程提供借鉴。 相似文献
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Nowadays, in most of the advanced and developing countries, waste tires have caused serious environmental problems such as fire and environmental contamination. For reusing them in an appropriate and beneficial way, waste tires have been utilized as a lightweight fill material in geotechnical engineering applications such as highway embankments. In this study, Babolsar fine-grained sand and granulated rubber with sizes in the ranges of 1 to 4, 1 to 9, and 4 to 9 mm were used. A series of model footing tests on reinforced sand with different sizes of granulated rubber were carried out. According to the results, 4- to 9-mm granulated rubber had the highest effect on enhancement of bearing capacity and reduction of fine-grained sand settlement. The results showed that sand-granulated rubber mixtures with granulated rubber in the range of 4 to 9 mm and content of 10% by weight of mixture can increase the bearing capacity of sand up to 50%. In addition, for this mixture, a series of laboratory tests were conducted to determine the optimum width and depth of the reinforcement layer consisting of sand-granulated rubber mixture. The results indicate that the optimum width and the most effective depth of this mixture are 5B and 1B, respectively (where B is the footing width). 相似文献
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群桩沉降计算理论分析 总被引：4，自引：0，他引：4
基于Geddes应力解,并根据叠加原理计算群桩内任意点处的三向应力,采用基于Duncen-Chang本构模型的修正分层总和法计算群桩内任意点处的沉降量,最后,根据基点法[1]和群桩基础荷载、变形协调关系建立方程,从而,最终获得群桩的沉降计算。该理论较常规弹性理论方法计算群桩沉降有较大地改进,具体体现在以下几个方面：（1）考虑了群桩中地基土的三向应力分布对群桩沉降计算的影响;（2）考虑了土体本构模型（Duncen-Chang弹性非线性本构模型）,因而,能计及土体非线性特性对群桩沉降的影响;（3）采用修正分层总和法理论,能考虑土体成层分布特性以及侧向变形对单桩沉降计算的影响。 相似文献
18.
Reaction of zoning of garnet 总被引：1，自引：0，他引：1
Timothy P. Loomis 《Contributions to Mineralogy and Petrology》1975,52(4):285-305
Compositional zoning of garnet in metamorphic or igneous rocks preserves evidence of the equilibration history of the sample and can be interpreted in terms of a growth-fractionation, diffusion-exchange, or diffusion-reaction model. Diffusion zoning is usually assumed to result from exchange reactions between garnet and other phases as the partitioning coefficient varies in response to changing environmental conditions, primarily temperature. However, in many natural environments where garnet grew originally in divariant equilibrium with other phases, changing conditions can promote continuous or “divariant” reactions and consequent compositional shifts of phases that can be much greater in some systems showing these reactions than those related to the small changes of partitioning. Diffusional zoning related to overstepping of these continuous reactions must be related to incongruent reaction and necessitates formulation of a kinetic diffusion-reaction model involving moving phase boundaries as well as solid-state diffusion. Three samples containing zoned garnets from the metamorphic aureole around the Ronda ultramafic intrusion in southern Spain are used to illustrate two possible models of diffusion-reaction processes. The examples are particularly informative because the reactions are demonstrably irreversible and evidence of the reaction system is preserved. Partitioning data indicates that compositions of product phases are not in equilibrium with the original garnet and do not vary with extent of reaction; therefore, exchange reactions with garnet were not possible and garnet changed composition only by incongruent reaction. After a small amount of reaction, Mg/Fe of the rim composition approaches a value apparently in equilibrium with product phases, but the garnets are zoned inward to the original garnet composition preserved in the interior. Grossularite content is approximately constant and spessartite content variable but small, thus, the rim composition of pyrope or almandine is assumed to be fixed by the external reaction process and is taken as a boundary condition in the following models. The zoning profile of pyrope or almandine component between the fixed rim and core compositions (assumed to extend to ∞) is described in semiinfinite, half-space models appropriate for large garnets with narrow rims. The first model corresponds to a reaction system in which all garnet compositions are metastable (case 1) and zoning depends on the independent variables of the diffusion constant, velocity of the interface between garnet and matrix, and time. The second model, corresponding to systems in which the initial garnet composition is metastable but an equilibrium composition is stable (case 2), depends on the independent variables diffusion constant, time, and a function of reaction compositions. In case 1 the consumption velocity is assumed constant and a steady state zoning profile is reached at large time, whereas, in case 2, the velocity decreases with the concentration gradient and steady state is not possible. The models were tested using a reaction time estimated from cooling models of the aureole, mass of garnet consumed, determined petrographically, and phase compositions. The two cases are somewhat independent in that different parameters are independent variables. The estimate of the diffusion constant of 10?18±2 cm2/sec (assumed to be a mutual or binary coefficient for almandine and pyrope) is considered reasonable for the temperature range of reaction (probably 600–900° C), and the two models are consistent considering the probable error and possible real temperature differences. It is obvious that details of the metamorphic reaction system must be known to successfully apply diffusion models. Kinetic models, involving consumption or growth of the phase as well as diffusion are probably necessary when dealing with natural rocks. Several possible and interesting complications, such as cross coupling between components, can be investigated if more data were available. Experimental determination of diffusion constants allow natural reaction rates to be estimated by this method. Diffusion zoning is an important consideration that could increase the efficiency of experimentation with chemically recalcitrant phases. 相似文献
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河流相是我国陆相盆地重要的油气储集层系类型之一,开发阶段应用高分辨率层序地层学进行河流相高精度小层划分,对于指导河道砂体的精细划分对比有重要意义。由于受到河流相地层自旋回沉积、沉积间歇面的作用、河型和砂体叠置样式的变化以及基准面旋回的级次的划分等复杂因素的影响,在开发阶段进行高精度层序对比时,难度更大。运用高分辨率层序地层学原理和方法,综合分析河流相模式的特点,充分利用河流相岩相、相序的组合特征随空容纳空间规律性变化,结合各种关键面的约束控制、油水界面在小层内部空间的分布位置以及河道的切割充填作用,进行精细河流相小层划分对比。旨在摸索一套油田开发中后期河流相高精度层序划分的思路和方法,以指导油田的生产开发。并以渤海Q油田明化镇组为例,在实际应用中取得了较好的效果。 相似文献
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Shales play important roles in various civil, energy and environmental engineering applications. Shales are categorized as poroelastic materials due to their tight and very stiff structure, and reliable poroelastic properties are required when dealing with shales. This paper presents simple procedures to determine the poroelastic properties of rocks using oedometer and triaxial consolidation tests. The procedures, which avoid the difficulty to perform determination of the unjacketed bulk modulus of the rock minerals, are demonstrated on a North Sea shale. The experimentally obtained Biot coefficient α and the drained bulk modulus K of the shale range from 0.95 to 0.99, and from 0.17 to 2.00 GPa, respectively. The Biot coefficient α and the drained bulk modulus K values determined from the oedometer and triaxial tests are compared and show good agreement and consistency between the two test procedures. The Skempton’s coefficient B-value of the triaxial samples was also experimentally measured prior to the triaxial consolidation tests. The theoretically predicted B-value varies from 0.81 to 0.96 which is, on the average, only about 10% higher than the experimentally obtained B-value which range from 0.80 to 0.85.
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