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1.
长江中下游地区地下水中化学元素的背景特征及形成 总被引：46，自引：0，他引：46
本文论证了长江中下游地区地下水中钾、钠、钙、镁、硅、铁、锰、铬、镍、钒、钴、钛、钼、铜、铅、锌、砷、汞、镉、铍、锂、锶、硼、氟、氯、溴、碘的背景特征、形成及分布规律,探讨其与地下水的含水介质成分,上覆岩土性质、氧化还原环境、地下水的径流条件和矿化度以及地下水的酸碱度之间的关系。 相似文献
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江西省鄱阳湖地区地下水环境背景的形成 总被引：8，自引：0，他引：8
本文以丰富的实际资料,论证了鄱阳湖地区地下水的Mg,Ca、Na、K、SiO_2、Fe、Mu、Cr、V、Co、Ni、Ti、Be、Li、Sn、Mo、Cu、Pb、Zu、A_5、Hg、Cd、Sr、F、Cl、Br、I等27项化学成分背景的形成。 相似文献
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流域上游基岩与下游冲积平原土壤化学组成的对比 总被引：2，自引：0，他引：2
对海河水系流域、鄱阳湖水系流域上游的基岩与下游的冲积平原土壤之间化学组成的对比研究显示,下游冲积物土壤的化学组成明显地受源岩成分、形成过程和形成环境的影响。流域上游基岩的一些特征元素在冲积物土壤中被明显地继承,如海河流域基岩和土壤中的CO2、CaO、MgO、FeO、Sr,鄱阳湖流域基岩和土壤中的W、Sn、Bi、U、Th、Pb、Rb、Tl、As、Sb、Se、Hg、Nb、Ta、Hf、B、Be、Ge、Pt、Pd、Y。受形成过程和形成环境的影响,处于暖温带半湿润季风气候下的海河流域冲积平原土壤以极富集CO2、CaO、Na2O、Cl,显著富集MgO、FeO、Sr,富集P、S为特征;而处于亚热带湿润季风气候下的鄱阳湖流域冲积平原土壤则以显著富集Hg、Se和富集Al2O3、Fe2O3H2O^＋、W、Sn、Bi、Mo、U、Th、Pb、Rb、Cs、Tl、Li、Be、B、Ga、Ge、Nb、Ta、Zr、Hf、As、Sb、Co、Cr、Ti、V、Zn、Pt、Pd、REE、Y为特征。无论是海河流域还是鄱阳湖流域的冲积平原土壤,均富集As、Sb、Hg、B、Cl、W、Sn、Bi、Pb、Se、Ge、Li、Cs、Cu、Au、Fe2O3、V、Cr、Ni、Zr、Hf、Y。 相似文献
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本文提供了不同成分的8大类主岩(偏铝质(超)基性岩、过碱性(超)基性岩、偏铝质中性岩、过碱性中性岩、偏铝质酸性岩、过碱性酸性岩、过铝质酸性岩、超酸性岩)中28个矿物(橄榄石、单斜辉石、斜方辉石、角闪石、黑云母、金云母、斜长石、钾长石、石英、磁铁矿、钛铁矿、石榴石、锆石、磷灰石、绿帘石、黄玉、榍石、堇青石、蓝方石、石榴石、霞石、白磷钙矿、镁铁钛矿、板钛矿、黄长石、钙钛矿、尖晶石、金红石)的69个化学元素(Li、Rb、Cs、K、Na、Ca、Sr、Ba、Mn、Fe、Mg、Cu、Pb、Zn、Co、Ni、Be、La、Ce、Nd、Sm、Eu、Gd、Tb、Dy、Ho、Er、Tm、Yb、Lu、Y、Sc、Cr、In、Ga、Al、B、Cd、Sb、Bi、U、Th、Zr、Hf、Si、Ti、Ge、Sn、Mo、Nb、Ta、W、V、P、F、Cl、S、N、O、C、As、Pu、Re、Os、He、Ne、Ar、Xe、Kr)和1个化学一价原子团OH的分配系数。综合分析对比表明,矿物、熔体的成分和结构是分配系数的最重要的控制因素。对前人未讨论过的矿物结构和熔体铝过饱和度这两个因素应引起重视。最后,本文分析了矿物-熔体间元素分配系数的研究现状、存在问题,指出了这一领域今后的研究方向。 相似文献
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高能偏振能量色散-X射线荧光光谱法测定PM10大气颗粒物的组成 总被引：2，自引：1，他引：1
为配合X射线衍射分析(XRD)方法对可吸入大气颗粒悬浮物(PM10)的结晶物相进行定性和定量分析的研究工作,本文应用高能偏振能量色散X射线荧光光谱(HE-P-EDXRF)对Whatman玻璃纤维滤膜采集的PM10颗粒物中主、次量元素进行定量分析,着重研究了空气滤膜空白值对测定PM10颗粒物中组成的影响。结果表明,当玻璃纤维滤膜空白值中元素的面密度大于0.1μg/cm2时,需使用玻璃纤维滤膜为载体的标准样品;元素的面密度小于0.1μg/cm2时,可用聚碳酸脂膜为载体的标准样品。对HE-P-EDXRF谱仪测定PM10颗粒物中痕量重元素进行探讨,将测定元素范围扩展到62个元素,其中Na、Mg、S、Y、Nd、Sm、Eu、Gd、Tb、Dy、Ho、Er、Tm、Yb、Lu的检岀限>0.1μg/cm2;Ca、Cr、Mn、Fe、Co、Ni、Cu、Zn、Br和Rb的检岀限<0.01μg/cm2;Cl、Al、Si、P、K、Sc、Ti、V、Ge、As、Br、Se、Sr、Zr、Mo、Pd、Rh、In、Nb、Ag、Cd、Te、Sb、Sn、Ba、Cs、La、Ce、Pr、Au、Pt、W、Tl、Pb、Bi、Th和U等元素检出限为0.1～0.01μg/cm2。 相似文献
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浙江省下寒武统荷塘组黑色页岩系地球化学特征 总被引：2，自引：0，他引：2
首次根据浙江省西北部荷塘组岩石样品的实测数据,提出了浙江省荷塘组黑色岩系6个岩性层的Pt、Pd、Au、Ag、Cu、As、Sb、Pb、Mo、Ni、V、P、U、B、Cd、Tl、Se、Zn元素的平均值,运用微量元素和稀土元素的配分模式探讨了成岩环境及元素高含量对环境的影响.荷塘组富集元素较多,富集程度高的有Mo、Se、Cd、Ag、Sb、U、As、P;较富集的有V、B、Cu、Tl、Zn,弱富集的为Au、Pt、Pb、Ni.综合地质地球化学特征研究认为,荷塘组黑色岩系具有寻找含钼、磷、矾和有色金属矿产的潜力. 相似文献
7.
李亮歌 《矿物岩石地球化学通报》1988,(1)
我所于1983年对台湾海峡中、北部进行了综合调查,首次测定了表层沉积物样品(120个)的有机碳、全氮、全磷、碳酸钙、可溶性硅酸盐、全硅、铝、钛、钒、铬、铁、锰、钴、镍、铜、锌、铌、锆、镧、铈、钇、铍、镁、钙、锶、钡等26个化学元素(成分)的含量;同时选择有代表性的柱状岩芯12个,进行了有机碳、全氮、全磷、碳酸钙等化学成分的测定。 相似文献
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中国29个省、市、自治区的土壤质量和农作物优质高产与土壤环境中化学元素N、P、K、S、Fe、Mn、Cu、Zn、B、Mo、V、Sr、Ti、Mg、La、Ce、Pr、Nd、Sm、Eu、Y、Gd、Tb、Dy、Ho、Er、Tm、Yb、Lu、Ca、Co、Ni、F、Tl、Si、Na、Cr、Ph、Cd、Hg、Se、Ba、Te、Ta及有机质、酸碱度、含盐量有密切的关系。土壤的质量为优质高产打下了基础,应充分地开发利用和保护。提出了生态农业地质研究的目的、内容、方法、管理及其前景。 相似文献
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边坡滚石运动轨迹分段循环算法 总被引：1，自引：0，他引：1
边坡滚石是在基本建设中常遇到的一种工程灾害。其防护结构的设计依据主要是边坡滚石的运动轨迹,因而要对这种灾害进行防治,首先要确定滚石的运动轨迹。根据落石运动全过程的三个阶段,即滚动(滑动)运动阶段、抛物运动阶段和与坡面碰撞阶段,利用分段循环算法分别得到了三个运动阶段的运动速度计算公式。以某岩质边坡构建相似模型,将该理论公式应用于落石运动轨迹预测,验证了公式的可行性和有效性。与现有方法相比,分段循环算法具有计算原理简单明确、易于使用等优点。该方法可用于斜坡区滚石运动特征的预测,并可作为斜坡区滚石灾害防治的依据。 相似文献
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Reaction of zoning of garnet 总被引：1，自引：0，他引：1
Timothy P. Loomis 《Contributions to Mineralogy and Petrology》1975,52(4):285-305
Compositional zoning of garnet in metamorphic or igneous rocks preserves evidence of the equilibration history of the sample and can be interpreted in terms of a growth-fractionation, diffusion-exchange, or diffusion-reaction model. Diffusion zoning is usually assumed to result from exchange reactions between garnet and other phases as the partitioning coefficient varies in response to changing environmental conditions, primarily temperature. However, in many natural environments where garnet grew originally in divariant equilibrium with other phases, changing conditions can promote continuous or “divariant” reactions and consequent compositional shifts of phases that can be much greater in some systems showing these reactions than those related to the small changes of partitioning. Diffusional zoning related to overstepping of these continuous reactions must be related to incongruent reaction and necessitates formulation of a kinetic diffusion-reaction model involving moving phase boundaries as well as solid-state diffusion. Three samples containing zoned garnets from the metamorphic aureole around the Ronda ultramafic intrusion in southern Spain are used to illustrate two possible models of diffusion-reaction processes. The examples are particularly informative because the reactions are demonstrably irreversible and evidence of the reaction system is preserved. Partitioning data indicates that compositions of product phases are not in equilibrium with the original garnet and do not vary with extent of reaction; therefore, exchange reactions with garnet were not possible and garnet changed composition only by incongruent reaction. After a small amount of reaction, Mg/Fe of the rim composition approaches a value apparently in equilibrium with product phases, but the garnets are zoned inward to the original garnet composition preserved in the interior. Grossularite content is approximately constant and spessartite content variable but small, thus, the rim composition of pyrope or almandine is assumed to be fixed by the external reaction process and is taken as a boundary condition in the following models. The zoning profile of pyrope or almandine component between the fixed rim and core compositions (assumed to extend to ∞) is described in semiinfinite, half-space models appropriate for large garnets with narrow rims. The first model corresponds to a reaction system in which all garnet compositions are metastable (case 1) and zoning depends on the independent variables of the diffusion constant, velocity of the interface between garnet and matrix, and time. The second model, corresponding to systems in which the initial garnet composition is metastable but an equilibrium composition is stable (case 2), depends on the independent variables diffusion constant, time, and a function of reaction compositions. In case 1 the consumption velocity is assumed constant and a steady state zoning profile is reached at large time, whereas, in case 2, the velocity decreases with the concentration gradient and steady state is not possible. The models were tested using a reaction time estimated from cooling models of the aureole, mass of garnet consumed, determined petrographically, and phase compositions. The two cases are somewhat independent in that different parameters are independent variables. The estimate of the diffusion constant of 10?18±2 cm2/sec (assumed to be a mutual or binary coefficient for almandine and pyrope) is considered reasonable for the temperature range of reaction (probably 600–900° C), and the two models are consistent considering the probable error and possible real temperature differences. It is obvious that details of the metamorphic reaction system must be known to successfully apply diffusion models. Kinetic models, involving consumption or growth of the phase as well as diffusion are probably necessary when dealing with natural rocks. Several possible and interesting complications, such as cross coupling between components, can be investigated if more data were available. Experimental determination of diffusion constants allow natural reaction rates to be estimated by this method. Diffusion zoning is an important consideration that could increase the efficiency of experimentation with chemically recalcitrant phases. 相似文献
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下扬子区三叠纪古地理演化 总被引：2，自引：2，他引：0
下扬子区在三叠纪期间接受了早-中三叠世海相碳酸盐沉积、中-晚三叠世海陆交互相和陆相湖沼沉积.沉积相带的空间分布和古地理格局的变迁明显地受到区域构造的控制.区内盆地发育与演化是在华南板块与扬子板块、扬子板块与华北板块相互作用的背景下进行的.早-中三叠世末期的印支运动是下扬子区构造-古地理格局改变的决定性因素,使下扬子海盆闭合,沉积类型由海相沉积变为陆相沉积.下扬子区三叠纪古地理的演化特征也为板块碰撞提供了沉积证据. 相似文献
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M. D. Sharma 《Journal of Earth System Science》2004,113(2):247-257
Three dimensional scattering of near-field is studied for dilatation and rotation in the time domain. The perturbation method
is applied to solve the equation of motion for the first order scattering from a weak inhomogeneity in an otherwise homogeneous
medium. The inhomogeneity is assumed close enough to the point source so that the near-field intermediate wave is dominating
over the far-field sphericalP andS pulses. The integral expressions are derived to relate dilatation and rotation of scattering to the radial fluctuations of
velocities and density in the inhomogeneity. These integrals are solved to calculate the strains of scattering from (a part
of) an inhomogeneous spherical shell of arbitrary curvature. Variable curvature may allow the shape of inhomogeneity volume
element to change uniformly from spherical to rectangular. Rotation of scattering from a spherical shell is independent ofP wave velocity inhomogeneity. Dilatation of scattering does not involveS wave velocity inhomogeneity but its gradient. The back scattering results are obtained as a special case. Strains are computed
numerically, for hypothetical models to study the effects of various parameters viz., velocity inhomogeneity, distance of
source from inhomogeneity and from receiver, and thickness of inhomogeneity. The curvature of the spherical shell is varied
to study the effects of the shape of inhomogeneous volume element on scattering. 相似文献
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A review of theories of mechanisms of induced seismicity 总被引：1，自引：0，他引：1
Carl Kisslinger 《Engineering Geology》1976,10(2-4):85-98
Theories of the physical processes leading to the stimulation of seismic activity by underground explosions, fluid injection, and reservoir impoundment are summarized. In all cases, the materials must be pre-stressed to a substantial fraction of their breaking strength in order for seismicity to be induced. Stress concentrations due to the presence of old faults or to inhomogeneities in the material properties play an important role in localizing induced seismicity.
For the few cases for which data are available, the stimulation of earthquakes by fluid injection in bore holes is adequately explained by a Coulomb-Mohr failure criterion and the concept of effective pressure in a water-filled porous mechanism. Reservoir-related earthquakes are most likely due to the same mechanism, but, in view of the low injection pressures, additional physical or chemical effects of the water on the materials may play an important role. There may be a weakening of the materials in old fault zones by the introduction of water or static fatigue in silicate rocks due to stress corrosion. 相似文献
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本文从拉长石晕彩色的空间分布特征研究出发,采用显微镜观察、粉晶X射线衍射及电子探针分析等手段,查明了拉长石不同晕彩区域的结构和成分特征,建立了晕彩拉长石的晕彩色与成分之间的耦合关系,并对拉长石晕彩成因进行了有效的约束。研究结果表明,拉长石的晕彩色是由层状结构对光的干涉所致,其结构单元层由贫钙和富钙两相长石共同组成,当结构层厚度处于128~292nm之间时出现可见光范围内的干涉色,但结构层表面并不绝对平坦,因而出现了有如地形图中等高线似的干涉色。结构层厚度与钙含量有关,随着钙含量的增加,结构层相应地增厚,晕彩色波长也随之增大。但由于产地和结晶环境的不同,干涉色相同的拉长石钙含量不一定相等,但对于同一产地的拉长石而言,干涉色波长与钙含量呈正相关关系。 相似文献
19.
Nowadays, in most of the advanced and developing countries, waste tires have caused serious environmental problems such as fire and environmental contamination. For reusing them in an appropriate and beneficial way, waste tires have been utilized as a lightweight fill material in geotechnical engineering applications such as highway embankments. In this study, Babolsar fine-grained sand and granulated rubber with sizes in the ranges of 1 to 4, 1 to 9, and 4 to 9 mm were used. A series of model footing tests on reinforced sand with different sizes of granulated rubber were carried out. According to the results, 4- to 9-mm granulated rubber had the highest effect on enhancement of bearing capacity and reduction of fine-grained sand settlement. The results showed that sand-granulated rubber mixtures with granulated rubber in the range of 4 to 9 mm and content of 10% by weight of mixture can increase the bearing capacity of sand up to 50%. In addition, for this mixture, a series of laboratory tests were conducted to determine the optimum width and depth of the reinforcement layer consisting of sand-granulated rubber mixture. The results indicate that the optimum width and the most effective depth of this mixture are 5B and 1B, respectively (where B is the footing width). 相似文献
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沉管隧道基槽爆破施工对既有堤岸稳定性影响的数值仿真分析 总被引：1，自引：0，他引：1
结合爆破数值模拟中爆破荷载的特点,分析了各种荷载施加方法的特点及爆破震动场模拟的要求,基于圣维南荷载等效原理,提出了爆破荷载的等效施加方法,即将作用在炮孔壁上的爆破荷载等效后,施加在同排炮孔中心线或者面上来模拟爆破荷载的作用。结果表明,等效施加方法在近区存在一定差异,但在中远区吻合得较好。利用该等效荷载施加方法,采用三维实体模型计算分析了某沉管隧道基槽爆破施工对既有堤岸稳定性影响,计算了周围不同位置、不同深度位置处的振动响应,并在此基础上,分析研究了减小爆破振动对既有结构物影响的减振措施,可为类似工程提供借鉴。 相似文献