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1.
《Applied Geochemistry》2000,15(1):117-132
Selenium deficiency (Keshan Disease) and toxicity diseases in humans occur within 20 km of each other in Enshi District in China and have been linked to environmental levels of Se. Low concentrations of Se are associated with Jurassic siltstones and sandstones, whereas high concentrations occur in areas underlain by Permian carbonaceous strata. Although these broad relationships between Se in the environment and the human population have been established previously, not all villages underlain by the carbonaceous strata suffer Se toxicity problems and the precise controls on Se distribution and availability have not been quantified. In the present study, soil, grain, drinking water and human hair samples are examined to determine the controls on Se availability in 3 Se environments in Enshi District. Five low-Se and Keshan Disease villages, 5 high-Se and no toxicity villages and 5 high-Se and toxicity villages were selected for the study. Results show that the majority of samples in the low-Se villages are deficient or marginal in Se, and that Se availability to plants is inhibited by adsorption onto organic matter and Fe oxyhydroxides in soil. Therefore, remediation strategies involving the application of Se fertiliser direct to the soil may not increase plant Se levels as expected. In the high-Se villages, localised lithological variations result in considerable ranges in Se concentrations in all sample types. Deficient and excessive levels of Se are recorded in samples from the same village. Selenium bioavailability in the high-Se toxicity villages is controlled by the total soil Se concentration and pH. A greater proportion of the Se is plant available in villages where the carbonaceous strata are interbedded with limestone. Villagers should be advised to avoid planting crops in these areas if possible. 相似文献
2.
广东省普宁市土壤硒的分布特征及影响因素研究 总被引：2，自引：0，他引：2
开展了广东省普宁市区域土壤硒调查研究,采集了413个表层土壤样品(0～20 cm)和103个深层土壤样品(> 150 cm),测定了土壤全硒含量,据此研究土壤硒分布特征及其影响因素。结果表明,普宁市土壤全硒含量变化于0. 16～2. 01 mg/kg,平均值为0. 63 mg/kg,总体上处于中硒及高硒水平,不存在缺硒和硒过剩土壤。砂页岩风化形成的赤红壤全硒含量较高,平均值达0. 86 mg/kg,以侏罗系页岩母质发育的土壤全硒含量最高,平均值达0. 89 mg/kg;三角洲第四系沉积物发育形成的水稻土全硒含量最低,平均值为0. 41 mg/kg。回归分析表明,土壤全硒含量与铁铝含量、有机碳含量具有极显著正相关,与p H呈极显著负相关。影响普宁市土壤硒含量的主要因素是成土母质,土壤p H、有机碳和铁铝含量及土地利用方式对土壤全硒含量分布与富集也有一定的影响。 相似文献
3.
Geochemical processes controlling the spatial distribution of selenium in soil and water,west central South Dakota,USA 总被引：8，自引：0，他引：8
Selenium (Se) is essential in the human diet, but has a low threshold for toxic concentration. It is recommended that nutrients
such as Se should be consumed through foods as part of a normal diet. Se concentrations in crops and meat depend on the amount
of labile Se in the soil where crops and forage are grown. Therefore, managing agriculture for optimal Se in grain crops and
forage requires an understanding of the distribution and mobility of Se. Elevated concentrations of Se occur in waters, soils,
and forage 120 km west of Pierre in west central South Dakota, USA. The research site lies in an elevated, dissected plain
where soils developed on gently dipping Pierre Shale. Soils were sampled along catena transects and waters collected from
soil, ponds, and shallow borings in areas of known elevated forage and crop Se. Soil extracts from saturated-paste extraction
and acid (aqua regia and hydrofluoric acid) extraction were analyzed. Selenate was the dominant Se species in both acid and
saturated-paste extracts; selenite and organic Se were below detection (<0.2 ppb) in the same soil extracts. On average, 98% of soil Se was not water-soluble. The distribution of total Se shows much less spatial variation than water-soluble
Se in the areas sampled. Se shows correlation with organic carbon in soils and waters, suggesting its association with organic
carbon. Ca shows some correlation to Se in acid extracts, but not in saturated-paste extracts or in waters. Total Se shows
no significant correlation to Na, Mg, and total S in the soils. Se in saturated-paste extracts and water samples shows good
correlations with Na, Mg, and SO4, suggesting that evaporitic Na–Mg–sulfate minerals may temporarily concentrate water-soluble Se in shallow soils. The dissolution
and precipitation of these Na–Mg–sulfate salts together with pH and oxidation–reduction conditions apparently control water-soluble
Se distribution and mobilization in shallow subsurface environments. 相似文献
4.
土壤、农作物中及家畜体内的微量营养元素 总被引：2，自引：0，他引：2
Umesh C.Gupta Wu Kening Liang Siyuan 《地学前缘》2008,15(5):110-125
微量营养元素通常富集在表层土壤中,其含量随土层深度递减。尽管土壤中大多数微量元素的含量很高,但只有一小部分能被植物吸收。微量营养元素,也被称为痕迹元素,所需数量微小,但其缺乏会对农作物生产和动物健康造成严重影响。农作物对不同微量营养元素有着不同的反应。芸苔和豆类对Mo和B有较高的响应度,而玉米和其他谷类对Zn和Cu较为敏感。在温润和湿热地区,由于强降雨和强淋溶作用,微量营养元素缺乏较为普遍。土壤pH值是影响微量营养元素对植物有效性的重要因素之一。除Mo以外,微量营养元素的有效性随pH的增加而减小,Mo的有效性随pH的增加而增加。对于大多数植物来说,叶片中的微量营养元素含量高于植物的其他部分。因此,可以用叶片作为样品来测定农作物中微量营养元素的含量。大多数微量营养元素缺乏表现在植物顶部的新叶上,而过量则表现在老叶上。根据Deckers和Steinnes的结论,土壤较为贫瘠的发展中国家与土壤肥沃的欧洲及北美地区相比,微量营养元素缺乏现象较为普遍。许多营养元素缺乏区位于潮湿的热带地区,土壤极度贫瘠、高度风化和/或强淋溶,营养元素十分匮乏。此类其他土壤分部于半干旱及毗邻地区,这些地区的碱性和石灰性土壤条件严重限制了微量营养素对植物的供给。通常,可以满足草料作物生长的Cu、 Fe、Mn、 Zn 、Se含量水平,却不能满足家畜的需要。Se是植物生长所不需要的微量元素,因此草料作物中Se的含量很少。然而,如果动物所食农作物和草料中Se含量偏低,会造成严重的肌肉异常和其他疾病。白肌病是最常见的由于Se缺乏造成的疾病,在牛犊和羔羊中都有发现。本文讨论了与动物需求相关的农作物微量营养元素充足度。 相似文献
5.
浙江省北部地区调查研究表明,受成土母质来源、土壤类型及其理化性质等因素的影响,土壤元素全量、有效量及其有效度表现为:1)低山丘陵岗地土壤中As,Cd,Mo,Pb和Se全量较高,As,Cd,Fe,Pb,Se和Zn有效量较高;而山前平原区土壤中Hg,Pb和Zn元素全量较高,由地表向深部的下降递度较小,显示为原始沉积成因特点。2)中酸性、富含有机质的红壤和水稻土中As,Cd,Cu,Fe,Mn,Pb,Se,Zn等元素有效度较高,水稻土Hg有效度最低;弱碱性或碱性、贫有机质的潮土和滨海盐砂土中As,Cd,Cu,Fe,Mn,Pb,Se,Zn等元素有效量较低,但B有效量及有效度均较高。3)统计分析表明,土壤中Mn,Cu,Zn,Mo,Cd,Pb,Se等元素全量与有效量间具显著正相关性,表明全量是有效量的重要影响控制因素;有机质含量与Fe,Cu,Zn,Cd,As和Pb有效度间为显著正相关,说明有机质较高有利于土壤元素活化;Fe,Cu,Zn,Cd,As,Pb和Se有效度与pH值为显著负相关,表明土壤酸性增强(酸化)会增加这类元素的生物有效性。 相似文献
6.
为了弄清楚长江三角洲土壤-水稻系统中Cd污染和迁移制约因素,采集了典型地区的水稻土壤、秸秆、籽实等样品共66组,测试了这些样品中重金属元素和常量元素的含量、土壤pH值和总有机碳含量等参数指标,并对这些参数进行相关性分析,评估水稻土壤与籽实中的Cd污染,探讨Cd空间分布,讨论土壤中pH值和有机质以及其他金属元素对Cd在水稻中积累的制约作用。结果表明：长江三角洲典型地区水稻土壤和籽实都存在Cd含量超标现象,土壤样品中Cd质量分数为（81.39～1 441.00）×10-9,平均值277.40×10-9,而水稻籽实样品中Cd质量分数为（10.44～692.40）×10-9,平均值55.63×10-9;根据土壤环境质量标准（GB 15618—1995）的二级标准,水稻土壤超标率为9.09%,超标样品主要分布在苏州、镇江和常州;根据食品中污染物的限量标准（GB 2762—2005）,水稻籽实Cd含量超标率为4.55%,超标样品集中在苏州和无锡;影响水稻积累Cd的因素有土壤中总有机碳、CaO、MgO、P的含量和pH值;水稻中S和Se含量与Cd含量关系密切,Cd与Zn表现为协同作用,土壤中S、Se和Zn的含量对水稻积累Cd无明显影响;提高土壤中pH值以及增加土壤总有机碳含量,能适当降低水稻中Cd的积累,适当增加土壤中Ca、Mg和P的含量能在一定程度上降低水稻对Cd的吸收。 相似文献
7.
《Applied Geochemistry》2001,16(11-12):1345-1351
The biogeochemical cycling and chemical transformation of Se in Chinese environments is reviewed, especially with regard to the formation of low-Se environments. The occurrence, distribution, concentration and flux of Se in Chinese environments are reported in comparison to those in the rest of the world. Low-Se regions in China can be classified into 4 categories. In the NE, organic matter in the soil affects bioavailability of Se in soil. In the Huabei plain, the concentration of soil Se is strongly influenced by leaching and hydrological transport processes and Se deficient regions are mostly located on the hill-slopes due to leaching. In the Loessial Plateau, low-Se soils have developed on the low-Se parent material with a very low flux of Se between soil and plants. Low-Se regions in the SW have soils derived from weathered materials of lower Se contents. Both the lowest and highest concentrations and the flux of Se in environments are reported for China. 相似文献
8.
Zinc availability in relation to selected soil properties in a crude oil polluted eutric tropofluvent 总被引：2，自引：2，他引：0
M. C. Chukwuma E. T. Eshett E. U. Onweremadu Ph.D. M. A. Okon 《International Journal of Environmental Science and Technology》2010,7(2):261-270
The study investigated zinc availability in relation to selected soil properties in a crude-oil-polluted Eutric Tropofluvent in Egbema, Southeastern Nigeria. For this purpose, three treatments have been applied: unpolluted soil, polluted without vegetation and polluted with vegetation with five replicates arranged in a randomized complete block design. Guided by transect sampling technique, soil sampling was carried out in June 2008. Soil samples were collected from the three different land units using soil auger at a depth of 0–20 cm. Standard laboratory procedures were adopted in analysing the soils. Soil generated data were subjected to analysis of variance and correlation analysis. Results showed highly significant variation (p = 0.01) in bulk density, porosity, silt: clay ratio, pH, effective cation exchange capacity, percent base saturation, total nitrogen, organic matter, available phosphorus, calcium: magnesium ratio and zinc. It was found that zinc was higher in crude oil polluted soils than in non-polluted soil and it was below critical limits. Zinc availability in relation to selected soil properties in the crude oil polluted soils indicated that clay and organic matter did not affect zinc availability, while pH and effective cation exchange capacity did. A study on zinc dynamics in crude-oil-polluted soils will certainly provide further information on the management of crude-oil-polluted soils since it is one of the key micronutrient for crop productivity. 相似文献
9.
农业土壤除了pH值、有机质、全氮、全磷、全钾有全量评价标准外,多目标地球化学调查提供的其他营养和有益元素均无全量评价标准。文章采用耕作地土壤的背景值和标准离差以及与全国土壤丰度的比值确定了其他13种营养和有益元素的丰缺分级评价标准。提出了土壤养分丰缺综合评价方法,将19种土壤养分指标分成土壤性质指标、一级营养元素指标、二级营养元素指标及微量营养和有益元素指标,其贡献总分值分别为30分、40分、15分和15分,组成类型的单指标总分值与该类型贡献总分值相同,根据丰缺分级评价标准和各单指标含量,计算单指标分值。采用算术平均值法计算4种类型指标的分值,以4种类型指标分值和的大小作为评价土壤全量养分丰缺的依据。应用该评价体系对福建沿海地区农业土壤养分状况进行评价,旨在为农业土壤区划提供参考依据。另外,文章还分析了影响土壤养分丰缺的因素,提出了土壤的pH值和SiO2含量是影响土壤养分丰缺的重要因素,其次还有地质背景因素、人类活动叠加因素、沉积作用环境因素和气候环境因素等。 相似文献
10.
Data on soils with six Neoglacial moraines of the Klutlan Glacier have been compared with those from moraines at the warm, moist coastal site of Glacier Bay, 160 km south. Percentage organic matter increases rapidly for the first 100 to 150 yr of soil development and then continues to rise gradually for the next 100 yr. Soil pH falls from 8.0 in recent till to approximately 6.0 in 200-yr-old soils. Nitrogen levels in the mineral soil increase from near zero in recent tills to 0.7% in soils 175–200 yr old; organic horizons of soils associated with spruce forests in later successional stages contain approximately 1% nitrogen. Concentrations of certain inorganic phosphate ions in the different-aged soils increase continually throughout the succession. Data for nine chemical variables were subjected to a principal components analysis; the major pattern in the data reflects the differences between soils of low organic content and high pH present in early successional stages, and nutrient-rich soils with high organic content and low pH present after succession has progressed toward the spruce forest. These trends in soil development with time are strikingly similar to those reported from Glacier Bay, except that the changes in soil properties appear to be delayed by 50–100 yr at the Klutlan terminus. Although numerous signs of nitrogen deficiency have been identified in plants growing on new soils at Glacier Bay, none was observed visually in living plants or in nutrients measured in samples of foliage from three plant taxa (Epilobium latifolium, Salix spp., and Populus balsamifera) taken from the Klutlan moraines. Concentrations of nitrogen and other nutrients (Ca, Mg, K, total P) in the foliage samples show no clear trends with increasing soil development. Low temperatures, a short growing season, and very low mean annual precipitation probably limit plant growth and account for the delayed soil development on the Klutlan moraines. 相似文献
11.
Christopher Oze Catherine Skinner Andrew W. Schroth Robert G. Coleman 《Applied Geochemistry》2008,23(12):3391-3403
Serpentine soils derived from the weathering of ultramafic rocks and their metamorphic derivatives (serpentinites) are chemically prohibitive for vegetative growth. Evaluating how serpentine vegetation is able to persist under these chemical conditions is difficult to ascertain due to the numerous factors (climate, relief, time, water availability, etc.) controlling and affecting plant growth. Here, the uptake, incorporation, and distribution of a wide variety of elements into the biomass of serpentine vegetation has been investigated relative to vegetation growing on an adjacent chert-derived soil. Soil pH, electrical conductivity, organic C, total N, soil extractable elements, total soil elemental compositions and plant digestions in conjunction with spider diagrams are utilized to determine the chemical relationships of these soil and plant systems. Plant available Mg and Ca in serpentine soils exceed values assessed in chert soils. Magnesium is nearly 3 times more abundant than Ca in the serpentine soils; however, the serpentine soils are not Ca deficient with Ca concentrations as high as 2235 mg kg−1. Calcium to Mg ratios (Ca:Mg) in both serpentine and chert vegetation are greater than one in both below and above ground tissues. Soil and plant chemistry analyses support that Ca is not a limiting factor for plant growth and that serpentine vegetation is actively moderating Mg uptake as well as tolerating elevated concentrations of bioavailable Mg. Additionally, results demonstrate that serpentine vegetation suppresses the uptake of Fe, Cr, Ni, Mn and Co into its biomass. The suppressed uptake of these metals mainly occurs in the plants’ roots as evident by the comparatively lower metal concentrations present in above ground tissues (twigs, leaves and shoots). This research supports earlier studies that have suggested that ion uptake discrimination and ion suppression in the roots are major mechanisms for serpentine vegetation to tolerate the chemistry of serpentine soils. 相似文献
12.
硒是重要的人体必需微量元素,对特色农业发展起着重要的助力作用。碧江区土壤硒元素含量平均值超过贵州省及全国硒含量均值。富硒耕地面积达29426 8万亩,具有较大的富硒资源开发潜力。成土母岩为炭质页岩所形成的土壤中硒元素含量高于其他类型成土母岩所形成的土壤,强酸性土壤中硒元素含量平均值高于其他酸碱度等级土壤,水田中硒元素含量平均值显著高于旱地、果园、水浇地等其他类型土地。成土母质是土壤中硒元素的主要来源及影响因素,pH值、有机质、土壤质地等理化条件对土壤硒元素有一定影响。 相似文献
13.
以拜泉地区1：5万土地质量地球化学调查数据为基础,开展硒地球化学特征及生态效应研究,探讨硒元素在土壤-植物系统中的迁移富集规律.研究表明：拜泉地区根系土硒含量均值为0.25×10-6,属中等富硒土壤,黄豆和水稻富硒占比相对较高;水溶态硒和离子交换态硒含量之和约为5%,一定程度上制约硒的有效量.土壤理化性质对硒全量、硒形态及其迁移富集具有重要影响：碱性-中性土壤硒含量基本不受pH制约,硒多以亚硒酸盐形式存在,不利于硒元素的转移和植物吸收;硒全量（有效量）与有机质呈显著正相关关系,但有机质含量超过某一界限后,有机质含量的增加虽然可以提高硒含量水平,但也抑制硒元素的迁移富集. 相似文献
14.
黑龙江省克山县是我国克山病区.通过分析土壤表层（0～20 cm）样品809件,深层（150～200 cm）样品205件,对不同类型土壤中微量元素Se的含量、有效态含量、农作物籽实Se含量特征进行了研究.结果显示：土壤表层Se元素含量平均为0.249×10-6,低于全国平均值,高于世界、和东北平原黑龙江省土壤平均值,土壤表层Se含量以足硒为主要特征,足硒土壤面积达93.95%;土壤深层Se含量平均为0.167×10-6,明显低于土壤表层,Se含量不足或缺Se土壤面积占62.62%;不同类型土壤表层Se含量由高到低顺序为黑钙土=草甸土 > 黑土 > 暗棕壤,深层Se含量由高到低依次为暗棕壤 > 黑土 > 草甸土 > 黑钙土,与土壤表层高低顺序相反;不同土地利用类型Se含量显示建设用地和耕地Se含量较高,林地和水利用地含量较低,反映Se含量受人类活动影响明显;玉米、大豆、水稻主要农作物籽实Se含量平均为0.033×10-6,呈低Se特征. 相似文献
15.
16.
晋北大同盆地土地生态安全评价中的土壤Se指标 总被引：2，自引：0，他引：2
通过对大同盆地土壤Se含量水平的调查和160组玉米籽实与根系土Se含量关系的研究发现:①大同盆地土壤Se含量一般在100～200 ng/g之间,平均值为152 ng/g;②玉米籽实Se含量对土壤Se全量、水溶态Se含量、离子交换态Se含量、碳酸盐态Se含量均具有很好的响应关系,在统计学上印证了植物中的矿质营养元素主要来自土壤和土壤溶液;③土壤全量Se可以作为土壤质量评价的重要指标之一,建议大同盆地土壤缺Se和土壤富Se的评价标准值分别为180 ng/g、360 ng/g;④大同盆地研究区内大面积缺Se和富Se的土壤仅分布在浑源县和朔州东部滋润一带。 相似文献
17.
Naser Hafezi Moghaddas Hadi Hajizadeh Namaghi Hadi Ghorbani Behnaz Dahrazma 《Environmental Earth Sciences》2013,68(2):487-497
Soil samples were collected from the agricultural lands of Golestan province, north of Iran and analyzed for 24 elements including eight toxic metals of As, Cd, Co, Cr, Cu, Pb, Se and Zn. Electrical conductivity, pH, organic matter, soil texture, calcium carbonate content as well as soil cation exchange capacity were also determined. The possible sources of metals are identified with multivariate analysis such as correlation analysis, principal component analysis (PCA), and cluster analysis. In addition, enrichment factors were used to quantitatively evaluate the influences of agricultural practice on metal loads to the surface soils. The PCA and cluster analysis studies revealed that natural geochemical background are the main source of most elements including Al, Co, Cr, Cs, Cu, Fe, K, Li, Ni, Pb, V and Zn in the arable soils of the province (more than 90 %), however, those soils which have been developed on the mafic and metamorphic rocks were considerably contributed on metal concentration (43 %). Calcium and Sr were constituents of calcareous rocks and Na and S were mainly controlled by saline soils in the north of the province. Loess deposits was also accounting for high levels of selenium concentration. Phosphorous was mostly related to application of P-fertilizers and organophosphate pesticides. The comparison of metal load and enrichment factor for dry and irrigated farmlands showed that Cd, Co, Pb, Se and Zn had higher concentrations in the irrigated lands where considerable amounts of agrochemicals had been applied. However, it also found that proximity of arable lands to urban and industrial areas resulted in higher Pb and Cd values in the irrigated agricultural sources relative to dry ones. 相似文献
18.
为了系统地探讨洞庭湖平原土壤铅(Pb)活动性特征及其影响因素,本次研究在常德市、益阳市、株洲市共采集了110件水稻根系土样品,讨论了土壤Pb活动态含量和活动系数与有机质、pH值、阳离子交换量(CEC)等土壤理化性质的相关性,并据此建立了Pb活动态含量和活动系数的预测模型。研究结果表明:土壤Pb含量、pH值、有机质含量、CEC和风化程度都是影响Pb活动态含量及活动系数的主要因素。pH值、CEC和有机质含量都会影响土壤缓冲能力,进而影响Pb的活动性。土壤Cd含量和Zn/Pb值也与Pb活动态含量有显著相关性;在不同的浓度梯度内,Cd与Pb的交互作用不同;土壤具有较高的Zn/Pb 值时,Pb活动态含量较低。采用逐步回归法建立了土壤Pb活动态含量以及活动系数的预测模型,土壤Pb活动态含量用土壤pH、Pb含量、CEC和Na2O/K2O值进行预测,活动态系数用pH、CEC、SiO2/Al2O3值进行预测,预测效果均较好。 相似文献
19.
土壤有机氮矿化是供应无机氮的主导过程，研究其变化对于认识土壤氮素有效性和指导氮肥施用具有重要意义。本研究分别在云南建水、蒙自和勐腊岩溶区选取脐橙地、玉米地和橡胶地作为研究对象，并以临近未受人为扰动的草地或原始林地作为对照，采用15N同位素标记方法，研究了岩溶区草地或原始林地开垦种植农作物后石灰土有机氮矿化(MNorg)速率变化，并区分了易分解有机氮矿化(MNlab)和难分解有机氮矿化(MNrec)对MNorg的贡献。结果表明，原始林地土壤MNorg (8.94 mg N?kg-1 d-1)显著高于草地(1.41~2.46 mg N?kg-1 d-1)，且均以MNlab为主。其中，草地MNlab对MNorg贡献率可达80.6%~93.1%，而在原始林地中该贡献率达到62.2%。岩溶区草地或林地开垦种植经济作物显著降低MNorg速率，其MNorg速率为0.53~0.89 mg N?kg-1 d-1，下降比例达62.5%~90.1%。这种差异主要受MNlab和MNrec影响，由草地开垦种植脐橙和玉米后土壤MNorg下降主要归于MNlab速率下降，而MNrec并未发生显著变化；原始林地开垦种植橡胶后土壤MNorg下降主要归于MNlab和MNrec速率的共同下降。岩溶区草地或原始林地开垦种植农作物后土壤有机碳、全氮、全磷、全钙和全镁含量及土壤田间持水量、pH、阳离子交换量均显著降低，且与土壤MNorg和MNlab呈显著正相关，表明农业种植对土壤理化性质的改变是影响矿化速率的重要因素。 相似文献
20.
Selenium fractionation and speciation in rocks, soils, waters and plants in polluted surface mine environment 总被引：1，自引：0，他引：1
A fractionation and speciation was performed to determine the distribution of selenium (Se) species in major components of quartzite surface mine environment (rocks, mine tailings, soils, stream sediments, surface waters and plants) in obov, Slovakia. A three-step sequential extraction procedure was utilised for the fractionation of Se in mine tailings and soils. The first extractant in order to evaluate the soluble and ligand exchangeable fraction of Se (0.1 mol/l K2HPO4 + KH2PO4 at pH 7.0) solubilized up to 15% of total Se content. The second step (0.1 mol/l K2S2O8 at 90°C) which extracted Se associated or occluded with organic matter released 13 – 45% of total selenium. The decomposition of the residue (HNO3 + H2SO4 1+1) was used to solubilize the remaining 35–88% of total Se as the final step. The recovery of the procedure was between 97 and 106%. Selenate predominated in natural river and lake waters about pH 7.0 (>95%) but in acid mine leakings up to 40% of selenite was found. In the plants (birch leaves, grass leaves and roots) collected from the area acidified by mine leakings no significant accumulation of selenium was observed. The correlation between total Se and S in the rocks from the mine gives an evidence of the common origin of these elements in the studied area. 相似文献