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1.
A.O. Aweto 《Geoforum》1985,16(1):85-92
The trend of change in the cation exchange capacity of ferrallitic soils under bush fallow in south-western Nigeria was examined during the first 10 years following the cessation of cropping. The general trend is that the soil cation exchange capacity increases over time but this increase is largely restricted to the 0–10 cm layer of the soils. Three years of fallowing in the study area was generally inadequate to maintain soil cation exchange capacity at a level that would ensure continued high fertility. It is suggested that a short fallow of 3 years should be accompanied by the application of organic manures and inorganic fertilizers to increase the supply of plant nutrients. Soil percentage base saturation decreased with increasing length of the fallow period, presumably due to nutrient uptake from the soil by fallow vegetation. It is suggested that soils should be limed after a long fallow of >10 years in order to increase soil percentage base saturation and nutrient availability. Organic matter appears to be the main factor influencing the cation exchange capacity of soils under bush fallow in the study area. The effects of fallow vegetation on organic build-up in fallow soil and their implications for managing soil fertility during cropping are discussed.  相似文献   

2.
Plants play an important role in soil phosphorus nutrition. However, the effect of plants on phosphorus nutrition in soils of the Loess Plateau of China is not well understood. This study was conducted to reveal the relationships between plants and phosphorus’ fractions and availability in the Loess Plateau of China. Twenty-two plant communities were surveyed and soil samples under different plant canopies were collected for the determination of soil properties and inorganic phosphorus fractionation. The results showed that Leguminosae and Lilaceae reduced pH and increased organic matter, cation exchange capacity, total and Olsen phosphorus in soils under their canopies, while Labiatae and Rosaceae increased pH and decreased organic matter, cation exchange capacity, total and Olsen phosphorus in soils under their canopies. The contents of Ca2P, Ca8P, Al-P and Fe-P were highly related with soil Olsen phosphorus. They were all higher in soils under Leguminosae and Lilaceae and lower in soils under Labiatae and Rosaceae. The results of this study indicate that Leguminosae and Lilaceae improved phosphorus nutrition in soils, yet Labiatae and Rosaceae impeded the improvement of phosphorus nutrition in soils under their canopies, which will be of more help to instruct vegetation restoration in the region and provide information for soil development.  相似文献   

3.
A. M. A. Ismail 《GeoJournal》1991,23(3):233-237
This study is mainly about the relationship of the moisture holding and release capacity of soils with their texture, particularly the clay fraction. Soil samples collected from various sites in the Sudan Gezira were analysed for physical and chemical properties and moisture characteristics. Generally the soils were clayey except the recent alluvium which was loamy. The pH was alkaline and the electric conductivity < 1.0 dS m–1. The studied soils were calcareous and very poor in organic matter, their intermediate to high water holding capacity being due mainly to the presence of large quantities of clay. Matric potentials of –0.4 to –1.5 MPa reduced soil moisture for all types of soils but the effects were not necessarily quantitatively equal. Permanent wilting point — moisture content at – 1.5 MPa — varied widely (10.5 – 22.0%) amongst the different soils and this was mainly attributed to texture and mineralogy of the soil clays. Bulk density decreased with increase in clay content. Calcium carbonate content was found to have no apparent relationship with the moisture content of these soils. The amount of silt fraction seems to have an overriding effect on the relationship between soil moisture availability in the recent alluvium soil and its subsequent release to growing plants. The results are discussed in relation to the phenomenon of mid-day stress observed in all grown crops of the Sudan Gezira.  相似文献   

4.
为了系统地探讨洞庭湖平原土壤铅(Pb)活动性特征及其影响因素,本次研究在常德市、益阳市、株洲市共采集了110件水稻根系土样品,讨论了土壤Pb活动态含量和活动系数与有机质、pH值、阳离子交换量(CEC)等土壤理化性质的相关性,并据此建立了Pb活动态含量和活动系数的预测模型。研究结果表明:土壤Pb含量、pH值、有机质含量、CEC和风化程度都是影响Pb活动态含量及活动系数的主要因素。pH值、CEC和有机质含量都会影响土壤缓冲能力,进而影响Pb的活动性。土壤Cd含量和Zn/Pb值也与Pb活动态含量有显著相关性;在不同的浓度梯度内,Cd与Pb的交互作用不同;土壤具有较高的Zn/Pb 值时,Pb活动态含量较低。采用逐步回归法建立了土壤Pb活动态含量以及活动系数的预测模型,土壤Pb活动态含量用土壤pH、Pb含量、CEC和Na2O/K2O值进行预测,活动态系数用pH、CEC、SiO2/Al2O3值进行预测,预测效果均较好。  相似文献   

5.
广西壮族自治区碳酸盐岩分布面积为96 372 km2,约占全区陆地国土面积的407%。由碳酸盐岩风化形成的土壤中Cd、Pb、Hg等重金属元素普遍富集。初步评价发现,农作物籽实对Cd的吸收量与土壤Cd含量无对应关系,农作物Cd超标多出现在土壤Cd含量较低的地区。进一步研究发现,Cd高含量的土壤中普遍含有铝土矿、Fe Mn结核等颗粒。为了探索土壤中Cd存在形态及其影响因素,选择了含铝土矿和铁锰结核的横县土壤和无铝土矿与铁锰结核的象州土壤,系统研究了土壤Cd形态差异及其影响因素。结果表明：(1)象州土壤中Cd主要以活动态形式存在,生物可利用性高,横县土壤中Cd主要以稳定态形式存在,生物可利用性低。(2)pH值为60是象州土壤Cd活动态含量的突变点,pH值在60处含量达到最大值;而在横县,pH降低使活动态Cd比例增加。(3)象州土壤中活动态Cd随有机质增加而增加,表明Cd被有机质弱吸附;而横县土壤有机质含量与Cd形态无明显相关性。(4)由铝土矿导致的土壤高Cd含量,多以残渣态形式存在,不会对动植物造成危害。  相似文献   

6.
The adsorption properties in terms of cation exchange capacity and their relation to the soil and sediment constituents (clay minerals, Fe-, Mn-, and Al-oxyhydroxides, organic matter) were investigated in loess, soil-loess transition zone, and soil at four loess-soil sections in North-Western Croatia. Cation exchange capacity of the bulk samples, the samples after oxalate extraction of Fe, Mn and Al, and after removal of organic matter, as well as of the separated clay fraction, was determined using copper ethylenediamine. Cation exchange capacity (pH～7) of the bulk samples ranges from 5 to 12 cmol c /kg in soil, from 7 to 15 cmol c /kg in the soil-loess transition zone, and from 12 to 20 cmol c /kg in loess. Generally, CEC values increase with depth. Oxalate extraction of Fe, Mn, and Al, and removal of organic matter cause a CEC decrease of 3–38% and 8–55%, respectively, proving a considerable influence of these constituents to the bulk CEC values. In the separated clay fraction (<2 μm) CEC values are up to several times higher relative to those in the bulk samples. The measured CEC values of the bulk samples generally correspond to the clay mineral content identified. Also, a slight increase in muscovite/illite content with depth and the vermiculite occurrence in the loess horizon are concomitant with the CEC increase in deeper horizons, irrespective of the sample pretreatment.  相似文献   

7.
茶园土壤不同形态镍的含量及其影响因素   总被引：3，自引：2，他引：1  
通过自然茶园土壤采样和室内实验分析,探讨浙江、江苏和安徽13个茶园土壤镍的污染状况、形态分布规律以及不同形态镍的含量与土壤镍总量和土壤理化性质的关系。结果表明：部分茶园土壤受到不同程度的镍污染;茶园土壤镍的形态分布有一定差异,按镍的含量多少排序,一般为残渣态＞交换态＞铁锰氧化物结合态＞有机结合态＞碳酸盐结合态;除了交换态以外的所有其他形态的镍含量均随土壤镍含量的增加而显著增加;碳酸盐结合态、铁锰氧化物结合态和残渣态镍含量随土壤pH的升高呈显著增加趋势,而交换态镍则呈减少趋势,但不显著;随土壤有机质含量的增加,铁锰氧化物结合态镍显著减少,而其他形态增加或减少的趋势均不显著;碳酸盐结合态、有机结合态和残渣态的镍含量均随阳离子交换量的增加显著增加;随粘粒含量的增加所有形态中的镍呈增加趋势,但除了残渣态外增加趋势均不显著。  相似文献   

8.
为揭示冲积与湖积成因土壤镉的吸附特征,以安徽省当涂县冲积成因的江心洲和冲积、湖积成因的大陇乡根际土壤为研究对象,开展土壤镉的等温吸附实验和吸附动力学实验.等温吸附实验结果表明,冲积土壤镉的吸附量（S）、等温吸附常数（K）和固液分配系数（Kd）均较湖积土壤明显偏大,显示冲积土壤对镉的吸附能力较湖积土壤强;吸附动力学实验表明,冲积土壤的最大吸附量、平衡吸附量均较湖积土壤大,吸附速率也明显偏大,尤其在吸附实验早期更为显著;等温吸附常数K和平衡吸附速率Vb与土壤理化性质的分析表明,土壤pH是造成研究区土壤镉吸附能力差异的主要原因,其次为物理性粘粒含量;土壤pH是影响研究区冲积土壤镉吸附能力的主要因素;湖积土壤镉的吸附能力受土壤pH、有机质含量、Cd含量、物理性粘粒含量等因素的综合影响.研究对于揭示Cd在水土系统的迁移转化规律以及土壤Cd的污染防治具有重要的指导意义.   相似文献   

9.
A. O. Aweto Dr. 《GeoJournal》1985,10(4):409-415
The organic matter and nutrient contents of soils under four types of bush fallow in a part of the forest zone of SW Nigeria were analysed. The soils were formed from the same parent material of sandstone. The fallows studied were: 1) grass, 2) forb, 3) forb/woody and 4) woody fallows. The total nitrogen and organic matter contents and the cation exchange capacity values of soils under the forb/woody and woody fallow on the one hand were higher than those of the grass and forb fallow on the other. This is due to the greater age, biomass and greater capacity of the forb/woody and woody fallows to generate litter and to protect the soil against organic matter diminution through erosion and thermal decomposition. Of the four fallow types, the woody had the highest organic matter and nitrogen contents and cation exchange capacity. The fallows exert differential effects on soil mineral-nutrients. Compared to the woody fallow, there was a build-up of exchageable calcium in the topsoils of the grass and forb fallow. In contrast, there was a marked accumulation of exchageable sodium and potassium in the topsoils of the forb/woody and woody fallows. The woody and the grass or forb fallows appear to complement one another in restoring soil organic matter and nutrient content after cropping. It is suggested that the woody fallow should be alternated with grass or forb fallow in order to maintain the balance of soil nutrients over time.  相似文献   

10.
The mobility of toxic metals in soils or sediments is of great concern to scientists and environmentalists since it directly affects the bioavailability of metals and their movement to surface and ground waters. In this study, a multi-surface soil speciation model for Cd (II) and Pb (II) was developed to predict the partition of metals on various soil solid components (e.g. soil organic matter (SOM), oxide mineral, and clay mineral). In previous study, the sorption of metal cations on SOM and oxide minerals has been evaluated by thermodynamically based surface complexation model. However, metal binding to soil clay fractions was normally treated in a simplistic manner: only cation exchange reactions were considered and exchange coefficient was assumed unity. In this study, the binding of metals onto clays was described by a two-site surface sorption model (a basal surface site and an edge site). The model was checked by predicting the adsorption behavior of Cd (II) and Pb (II) onto three selected Chinese soils as a function of pH and ionic strengths. Results showed that the proposed model more accurately predicted the metal adsorption on soils under studied condition, especially in low ionic strength condition, suggesting that adsorption of metals to soil clay fractions need to be considered more carefully when modeling the partition of trace elements in soils. The developed soil speciation model will be useful when evaluating the movement and bioavailability of toxic metals in soil environment.  相似文献   

11.
A careful selection of waste dumpsites, particularly hazardous ones, is very important for sustainable water resources management. Several laboratory experiments were carried out on the field samples to study adsorption capacity using p-dichlorobenzene (a solvent used in various industrial processes) as the test contaminant. The effect of parameters such as organic matter, clay, and iron and aluminium oxides, which are known to influence the soil adsorption capacity, are studied in the present work. Several soil samples from the Patancheru Industrial Area (Hyderabad, India) were collected and characterized. Only three soils, which had a comparatively high percentage of organic matter, clay, iron and aluminium oxide contents were used for the adsorption studies. The results clearly indicated a decrease in the adsorption capacity of the soils by as much as 75% when organic matter was removed. The other parameters such as clay and iron and aluminium oxides also play an important role in adsorption (57 and 39.8% reduction respectively). It was observed that out of the selected factors organic matter in the soils has the maximum effect regarding the adsorption of p-dichlorobenzene. Since the selected soils contain comparatively more organic matter, clay and iron and aluminium oxides in the selected industrial area, these can be used as sites for dumping hazardous waste, which can be further treated by methods like bioremediation.  相似文献   

12.
Analysis of the spatial variability of soil properties is important to explain the site-specific ecosystems. Spatial patterns of some soil properties such as soil texture, exchangeable sodium percentage (ESP), electrical conductivity (ECe), soil pH and cation exchange capacity (CEC) were analyzed in salt and sodic affected soils in the south of the Ardabil province, in the northwest of Iran, to identify their spatial distribution for performance of a site-specific management. Soil samples were collected from 0 to 30, 30 to 60, 60 to 90, 90 to 120 and 120 to 150 cm soil depths at sampling sites. Data were investigated both statistically and geostatistically on the basis of the semivariogram. The spatial distribution model and spatial dependence level varied in the study area. Among the considered parameters, maximum and minimum spatial variability were observed in EC and pH parameters, respectively. Soil properties showed moderate to strong spatial dependence, except for a few. ECe was strongly spatially dependent in the total soil depth and clay was strongly spatially dependent at the first depth. Sand and pH were moderately spatially dependent for three of the five depths. ESP was strongly spatially dependent and silt was moderate in the total soil depths, except at 90–120 cm depth. Furthermore, CEC had strong spatial dependence for three of the five depths. All geostatistical range values were >1,389 m in this study. It was concluded that the strong spatial dependency of soil properties would lead to extrinsic factors such as bedrock, agricultural pollution, drainage and ground water level.  相似文献   

13.
通过对祁连山大野口流域的青海云杉林大样地进行土壤剖面取样, 分析了样地土壤有机碳与pH值、养分和阳离子交换量等基本化学性质的变化规律及其相互关系. 结果表明: 随土层深度不断增加, 土壤有机碳含量逐渐减小, 在20～30 cm以下趋于稳定(P > 0.05); 土壤pH值不断增大, 仅在0～10 cm与10～20 cm差异显著(P<0.05); 土壤全氮、速效氮、全磷和阳离子交换量不断减小, 全氮含量在30～40 cm以下趋于稳定(P > 0.05), 速效氮含量变化剧烈(P<0.05), 全磷含量差异性不显著(P > 0.05), 阳离子交换量与有机碳含量变化规律相同; 土壤速效磷、全钾和速效钾含量没有明显的变化规律, 速效磷和全钾含量差异性不显著(P > 0.05), 速效钾含量仅在0～10 cm与10～20 cm差异显著(P<0.05). 土壤有机碳与全氮、速效氮、全磷、速效磷、速效钾和阳离子交换量之间呈极显著和显著正相关, 与土壤pH值和全钾含量之间呈极显著和显著负相关. 土壤有机碳与其他基本化学性质的回归方程具有较高精度(R2=0.793), 影响土壤有机碳含量的主要化学因子依次为土壤阳离子交换量、速效钾和全磷含量.  相似文献   

14.
以珠江三角洲平原为研究区域,对其7个区县102件水稻根系土样品进行土壤理化参数及Pb形态分析,探讨在第四系分布区土壤Pb全量及Pb活动态含量的特征及影响因素。结果表明:全部供试土壤样品中Pb元素平均含量为46.47mg/kg,略高于广东省土壤Pb含量背景值(36mg/kg),表现出一定的累积趋势。研究区自西北陆相沉积区至南部海陆交互相沉积区,元素含量增高。Pb元素主要以残渣态和铁锰氧化物形态赋存在土壤中,迁移能力弱。影响土壤Pb全量的因素主要有Al2O3、K2O、Tl、Mo;影响土壤Pb活动态的因素有Pb全量、pH、有机质、CEC、P、TFe2O3、Mn;其中,p H是控制Pb元素活动性的最主要因素。  相似文献   

15.
吸附离子对粉质粘土及改良土特性的影响   总被引：1，自引：0，他引：1  
唐晓武  应丰  寇乃羽  王周庆 《岩土力学》2010,31(8):2519-2524
利用疏浚土有机质含量高、吸附能力强和低渗透性等特点,探讨将其作为填埋场黏土衬垫改性材料的可能性。针对粘土垫层所关心渗透性及强度两个基本问题,比较了粉质黏土、改良土（粉质黏土添加疏浚土）吸附离子前后的变化。吸附K+、Cu2+后粉质黏土、改良土的渗透系数随着土中离子含量的增加而增大,但对改良土渗透系数的影响要小于粉质黏土;吸附离子后,粉质黏土摩擦角增幅不大,黏聚力有较大增长,而改良土的黏聚力增长较少,摩擦角增长较快。总体而言,添加一定量的疏浚土能改善吸附离子对黏土垫层的影响。采用SEM电镜试验拍摄了离子吸附前后土体微观结构的变化,并从扩散双电层理论出发,解释了吸附离子对粉质黏土及改良土的影响。  相似文献   

16.
潮白河受水区再生水入渗盐污染模拟柱试验   总被引：1，自引：0，他引：1  
根据工程地质勘察及采样测试分析,选取北京市顺义潮白河再生水受水区3种典型代表性土壤介质(砾石含砂、细砂、粉质粘土)装柱,并采用受水区再生水进行淋溶模拟土柱试验。测试结果分析表明,在3种典型土壤介质中,阳离子交换吸附作用主要体现为K+与Ca2+之间的交换,且粉质粘土柱中阳离子的离子交换作用较砾石含砂柱和细砂柱更为显著。另外,试验结果还表明,随着土壤介质中粘粒含量、总有机碳含量、阳离子交换容量和粘土矿物总量的增加,典型介质淋溶模拟土柱试验中阳离子交换作用达到平衡时所需要的时间也就越长,分别为砾石含砂72 d、细砂80 d和粉质粘土86 d。定量结果计算也证明：粉质粘土介质的各阴、阳离子本底含量最高,单位质量粉质粘土介质硬度及溶解性总固体(TDS)的贡献量最大,分别为5 767 mg/g和6 952 mg/g。  相似文献   

17.
Urban soils, although crucial to defining urban vegetation types and strengthening the resilience of urban ecosystems, can be severely modified by human activities. Yet understanding of these modifications and their implications for soil properties is limited. This study examined the vertical and spatial variability of selected soil physicochemical properties (pH, SOM, OC, TN, and bulk density) in Kumasi, Ghana, using a stratified random sampling technique. Soil samples were collected at three depths (0–15, 15–30, and 30–60 cm) from 161 plots in eight green space types within two urban zones. Mean topsoil pH ranged between 5.0 in the natural forest and 6.5 in home gardens. Mean bulk density, nitrogen, and carbon concentrations differed among green space types and depths (p?<?0.0001). Soil nitrogen and carbon concentrations in the 0–15 cm depth were two times greater than those of the 30–60 cm depth. Soil pH and organic matter concentrations were higher in the core urban soils than in the peri-urban while the reverse was true for total soil N and bulk density. Canonical discriminant analysis showed considerable separation of green space types based on the soil physicochemical properties. Higher total nitrogen and C:N ratios separated natural forest and cemetery from the other UGS types, whereas higher pH and bulk densities separated plantations and home gardens from the rest of the UGS types. Furthermore, the subsoil layers were laden with undecomposed cloths, plastics, concrete, and metal parts which can obstruct root growth and water movement. Results generally demonstrate considerable variability in soil properties among urban green spaces and highlight the need for a better understanding of these patterns to ensure continued support for plant growth, green space sustenance and maintenance, and the ecosystem services derived from them.  相似文献   

18.
Aquifer vulnerability is frequently estimated through methodologies that don’t consider most physical and chemical soil parameters. A soil attenuation index is proposed to estimate groundwater chemical pollution risk, that takes into account organic carbon content, pH, cation exchange capacity, clay content, phreatic depth and landscape position. The attenuation index is constructed by a methodology similar to that developed for water quality index. P, Mn and Zn concentrations in groundwater from selected places were used to validate the proposed index.  相似文献   

19.
垃圾渗滤液污染地下环境介质岩性对pH缓冲能力的影响   总被引：1，自引：1，他引：0  
董军  马小兰  何正坤 《世界地质》2010,29(3):490-494
通过模拟实验研究垃圾渗滤液污染地下环境介质岩性对pH缓冲能力变化的影响。亚黏土和砂土的pH缓冲容量的本底值分别为440.20和324.93mmol/(kg·pH),其中阳离子交换缓冲、碳酸钙缓冲、硅酸盐缓冲和次级缓冲的本底值分别为206.18、88.43、75.79和69.80mmol/(kg·pH),149.31、86.53、47.33和41.77mmol/(kg·pH)。污染的亚黏土和砂土的交换性阳离子(CEC)和交换性盐基离子(BEC)均小于本底值;盐基饱和度随离污染源距离的增加呈先升高后降低的变化趋势。  相似文献   

20.
A study was made to determine the influence of pasture degradation on soil quality indicators that included physical, chemical, biological and micromorphological attributes, along the hillslope positions in Chaharmahal and Bakhtiari province, western Iran. Soil samples from different slope positions were collected from 0 to 30 cm depth for physical and chemical properties and from 0 to 15 cm depth for biological properties at two adjacent sites in the two ecosystems: natural pasture and cultivated land. Soil quality indicators including bulk density, mean weight diameter, soil organic carbon (SOC), particulate organic material (POM) in aggregate fractions, total nitrogen, available potassium, available phosphorus, cation exchange capacity, soil microbial respiration (SMR) and microbial biomass C and N were determined. The results showed that SOC decreased cultivation from 1.09 to 0.77 % following pasture degradation. The POM decreased by about 19.35 % in cultivated soils when compared to natural pasture; also, SMR and microbial biomass C and N decreased significantly following pasture degradation. Furthermore, aggregate stability and pore spaces decreased, and bulk density increased in the cultivated soils. Overall, our results showed that long-term cultivation following pasture degradation led to a decline in soil quality in all selected slope positions at the site studied in the semiarid region.  相似文献   

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