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1.
Geochemical subsoil data obtained from China and European laboratories have been
compared in this study. 787 C horizon subsoil samples from FOREGS (Forum of European Geological
Surveys) geochemical baselines mapping project were sent to China’s IGGE (Institute of Geophysical
and Geochemical Exploration) laboratory and composited to 190 samples according to the
160 km 160 km GNT (Global Terrestrial Network) cells. In addition to the FOREGS elemental analysis
package, Au, Pt, Pd, B, Ge, Br, Cl, Se, N, Li and F were also analyzed by using the IGGE’s 76 element
analytical scheme. Geochemical data statistics, scatter plotting, and geochemical map compilation techniques
have been employed to investigate differences between FOREGS and IGGE analytical results.
The results of two datasets, the IGGE’s analysis data for composited samples, and the FOREGS
average data of samples in each GNT cell, agree extremely well for about 23 elements, viz: SiO2, Sr,
Al2O3, Zr, Ba, Fe2O3, Ti, Rb, Mn, Gd, CaO, Ga, MgO, P, Pb, Na2O, Y, Th, As, U Sc, Cr, and Co. There
are slight differences between-laboratory biases shown as proportional errors between the datasets for Ni,
K2O, Tb, Tl, Cu, S, Sm, La, Ce, Pr, Nd, Eu, Ho, Er, Tm, Yb, Lu, Ta, Nb, Hf, and Dy. For Cd, Cs, Be, Sb,
In, Mo, I, Sn, and Te, the correlation of the two datasets and the similarity of the geochemical maps are
fairly good, but obvious biases exist between the two datasets at values near detection limits. Sensitivities of FOREGS analytical methods for W, Bi, Sn, Te, Be, and I are insufficient to produce
reportable values in at least 80% of the samples. Although the detection limits of Ag for both FOREGS
and IGGE are sufficient to provide reportable values, a large bias was found between the two datasets.
This study demonstrates that consistent analytical data for certain elements of global geochemical
mapping samples can be achieved by different qualified laboratories, such as China’s IGGE laboratory
and some European laboratories. For some elements, such as Ag, further research on the selection of the
proper analytical methods and on the development of quality control methods should be undertakendwith
final recommendations adhered to by all participants of the global geochemical mapping program. 相似文献
2.
Geochemical Constraints of Sediments on the Provenance, Depositional Environment and Tectonic Setting of the Songliao Prototype Basin 总被引：1，自引：0，他引：1
YAN Quanren GAO Shanling WANG Zongqi LI Jiliang XIAO Wenjiao HOU Quanling YAN Zhen CHEN HaihongInstitute of Geology & Geophysics Chinese Academy of Science Beijing Institute of Geology Chinese Academy of Geological Sciences Beijing 《《地质学报》英文版》2002,76(4):455-462
The geochemistry of sediments is primarily controlled by their provenances, and different tectonic settings have distinctive provenance characteristics and sedimentary processes. So, it is possible to discriminate provenances, depositional environments and tectonic settings in the development of a sedimentary basin with the geochemistry of the clastic rocks. The analytical results of the present paper demonstrate that sediments in the Songliao prototype basin are enriched in silica (SiO2=66.48-80.51 %), and their ΣREE are 30-130 dmes of that of chondrite with remarkable Eu anomalies. In discriminating diagrams of Eu/Eu vs eeeeeREE and (La/Yb)N vs ΣREE, most samples locate above the line Eu/ Eu=l, on the right of the line Eu/Eu/ΣREE=1 and under the line La/Yb)N/eeeeeREE=1/8, which indicates that the depositional environment of sediments in the basin was oxidizing. In addition, variations of MgO, TiO2, A12O3, FeO+Fe2O3, Na2O and CaO vs SiO2 reflect a tendency of increasing mineral maturity of sediments 相似文献
3.
通过高温固相反应制备了Er3+掺杂的nEr2O3:K2La2Ti3O10系列光催化剂,对样品进行了X射线衍射、扫描电镜、紫外可见吸收光谱和比表面积分析,并以染料降解考察了样品的光催化活性.研究表明.Er3+的适量掺杂抑制了K2La2Ti3O10粒径生长,增加了K2La2Ti3O10对太阳光的利用率.提高了K2La2Ti3O10的光催化活性.当n=0.003时,K2La2Ti3O10的光催化活性最大,在可见光和紫外光辎照下,可将多种染料水溶液降解.在可见光辐照下,其光催化活性优于市售的光催化剂TiO2(P25). 相似文献
4.
金伯利岩的岩石化学特征与含金刚石程度的判别 总被引：4，自引：0，他引：4
There has been found a distinct directional trend of kimberlites differring in orebearing capability with changing chemical composition. The contents of MgO, NiO and Cr2O3 decrease gradually while Na2O3. K2O and Al2O3, as well as P2O3 increase eonsiderably in the order of diamond-rich- diamond-poor-diamond-absent kimberlites. In general, Fe2O3, FeO and TiO2 also show an increasing tendency. Therefore, the variation in chemical composition may be used as a petrochemical index for calculating the ore-bearing capability of kimberlites. Based upon discriminant analysis, it is possible to make a distinction between diamond-bearing and diamond-free, or between diamondrich and diamond-poor kimberlites. 相似文献
5.
本文对青藏高原羌北-昌都地块阿布日阿加措地区的晚二叠世那益雄组火山岩进行了年代学和地球化学研究。该火山岩主要由玄武岩、安山玄武岩、安山岩、流纹岩、凝灰岩组成,具有碱性玄武岩到酸性熔岩的特征。锆石U-Pb年代学研究表明该火山岩的形成时代为251. 1±4. 8～249. 6±1. 3 Ma之间。地球化学分析结果表明,该地区的流纹岩具有高的Si O2(74. 85%～77. 55%)和Na2O+K2O(5. 40%～6. 61%)含量,较低的MgO、K2O和Ca O含量,Al2O3含量低且稳定,里特曼指数平均为1. 15,小于3. 3。安山岩Si O2含量55. 13%～56. 28%,Na2O+K2O含量4. 13%～6. 15%,里特曼指数平均为2. 20,小于3. 3,属于钙碱性安山岩。碱性玄武岩Si O2含量51. 49%,Na2O+K2O含量6. 34%,里特曼指数为4. 73,属于碱性系列。稀土元素配分曲线为富集LREE的右倾型。另外,富集大离子亲石元素(LILE) Th、U,亏损高场强元素(HFSE) Nb、Ta等特征,均说明羌北-昌都地块阿布日阿加措地区的火山岩形成于陆缘岛弧环境。 相似文献
6.
采用等温蒸发法研究简单四元体系Na+//CI-,CO32-,B4O72---H2O 273 K时的介稳相平衡,并测定该体系273 K平衡液相中各组分的溶解度及密度,该体系的介稳相图和密度组成图显示:该四元体系在273 K时的相图由3条溶解度单变量线、3个结晶区及1个共饱和点组成.体系属简单共饱型,无复盐或固溶体形成,3个结晶区分别对应单盐Na2CO3?10H2O,NaCI和Na2B4O7?10H2O.共饱点E处于Na2CO3?10H2O,NaCI及Na2B4O,?10H2O3盐共饱和,所对应的平衡液相组成为ω(Na2CO3)=6.81%,ω(NaCl)=21.69%,ω(Na2B4O7)=0.65%.ω(H20)=70.85%.研究体系在273 K下,Na2CO3?10H2O是碳酸钠盐的唯一析出形式,且硼酸钠对碳酸钠有盐析作用. 相似文献
7.
Exsolutions of Diopside and Magnetite in Olivine from Mantle Dunite, Luobusa Ophiolite, Tibet, China 总被引：1，自引：0，他引：1
The exsolutious of diopside and magnetite occur as intergrowth and orient within olivine from the mantle dunite, Luobusa ophiolite, Tibet. The dunite is very fresh with a mineral assemblage of olivine （〉95%） ＋ chromite （1%-4%） ＋ diopside （〈1%）. Two types of olivine are found in thin sections： one （Fo = 94） is coarse-grained, elongated with development of kink bands, wavy extinction and irregular margins; and the other （Fo = 96） is fine-grained and poly-angied. Some of the olivine grains contain minor Ca, Cr and Ni. Besides the exsolutions in olivine, three micron-size inclusions are also discovered. Analyzed through energy dispersive system （EDS） with unitary analytical method, the average compositions of the inclusions are： Na20, 3.12%-3.84%; MgO, 19.51%-23.79%; Al2O3, 9.33%-11.31%; SiO2, 44.89%-46.29%; CaO, 11.46%-12.90%; Cr2O3, 0.74%-2.29%; FeO, 4.26%- 5.27%, which is quite similar to those of amphibole. Diopside is anhedral f＇dling between olivines, or as micro-inclusions oriented in olivines. Chromite appears euhedral distributed between olivines, sometimes with apparent compositional zone. From core to rim of the chromite, Fe content increases and Cr decreases; and A! and Mg drop greatly on the rim. There is always incomplete magnetite zone around the chromite. Compared with the nodular chromite in the same section, the euhedral chromite has higher Fe3O4 and lower MgCr2O4 and MgAI2O4 end member contents, which means it formed under higher oxygen fugacity environment. With a geothermometer estimation, the equilibrium crystalline temperature is 820℃-960℃ for olivine and nodular chromite, 630℃-770℃ for olivine and euhedral chromite, and 350℃-550℃ for olivine and exsoluted magnetite, showing that the exsolutions occurred late at low temperature. Thus we propose that previously depleted mantle harzburgite reacted with the melt containing Na, Al and Ca, and produced an olivine solid solution added with Na^＋, Al^3＋, Ca^2＋, Fe^3＋, Cr^3＋. With temperature d 相似文献
8.
TiO2, Al2O3, Fe2O3, FeO, MnO, MgO, CaO, Na2O, K2O, P2O3, and H2O have been calculated as a function of SiO2 in ealc-alkaline granites on a statistic basis from 128 samples of world-wide occurrence. Results of this regression calculation can be used as compositional representatives for the normal evolutionary series of calc-alkaline granites,tbus providing criteria against which the deviation from normal trend can be judged with respect to granitic rocks in a particular area. 相似文献
9.
煤矸石提铝与溶胶凝胶法合成纳米α-Al2O3的研究 总被引：5，自引：0，他引：5
随着科学与技术的发展,我国的煤炭消费量逐年增加.在煤炭采掘的同时,伴随开采的煤矸石不仅占用了大量土地,而且污染了环境.煤矸石中含有约35%的Al2O3和45%的SiO2以及大量农作物生长必需的微量元素,而α-Al2O3是用于制作精细瓷器、耐火材料和其他纳米功能材料的主要原料.有文献报道用(NH4)2SO4提取煤矸石中的Al2O3,制备纳米α-Al2O3. 相似文献
10.
11.
奇尔古斯套组硅质岩SiO2含量较高,Al2O3、TiO2含量变化较大,反映出较多的外来物质的加入;Si/ (Al+Fe+Mn)、Al/ (Al+ Fe+ Mn)、MnO/TiO2、Al2 O3/(Al2 O3+ Fe3 O2)值较高,反映其为生物化学成因,形成于大陆边缘环境;Fe2O3/TiO2对Al2O3/(Al2 O3+ Fe2O3)图解同样说明其形成于大陆边缘环境.REE较高,HREE富集不明显,北美页岩标准化后的稀土配分模式曲线较为平坦,向左倾斜不明显,(La/Ce)shale值较低,δCeshale值较高,无明显Ce负异常,反映奇尔古斯套组硅质岩属生物化学成因硅质岩,形成于大陆边缘环境; (La/Ce)shale对Al2 O3/(Al2 O3+Fe2 O3)图解亦说明其形成于大陆边缘环境.微量元素中Hf含量高,而Be、Li、Nb、Rb、Sr、Ta、Th、U、V、Zr含量低;Ba元素含量低;Co、Ni贫富相当,Co/Ni值较高,U/Th值低,说明奇尔古斯套组硅质岩属于正常的生物化学成因的硅质岩. 相似文献
12.
氟铁云母——“姑苏城外”发现的新矿物 总被引：2，自引：0，他引：2
氟铁云母是三八面体云母类矿物新种 ,属铁云母的富氟类似物。新矿物产于“姑苏城外”近郊苏州A型花岗岩上部氟铁云母分异岩中。矿物呈自形 -半自形板片状 ;铁黑色 ,半透明。密度 3.18g/cm3(实测 )和 3.2 3g/cm3(计算 )。二轴负晶 ;钠光下测得折光率 :Ng =Nm =1.648,Np =1.596;2V(实测 )≈ 0° ,2V(计算 ) =0° ;Y =b =Nm。矿物多色性强 :Ng棕褐色 ,Nm暗绿色 ,Np浅棕色。由电子探针、湿法和原子吸收分析等手段提供的氟铁云母化学成分均值(wB% ) :SiO2 34 .12 ,Al2 O313.89,FeO 2 6.19,Fe2 O37.86,MgO 1.4 9,MnO 0 .68,Li2 O 0 .4 7,TiO21.2 9,ZnO 0 .2 7,NiO 0 .0 1,K2 O 8.73,Na2 O 0 .19,Rb2 O 0 .4 2 ,CaO 0 .0 2 ,BaO 0 .4 4 ,SrO 0 .0 1,H2 O 0 .91,F 3.91,Cl痕量 ,S 0 .0 0 ,O =F 1.65,总量 99.2 5。按O OH F Cl S =12及四面体阳离子数之和为 4计算的氟铁云母经验化学式为 :(K0 .92 Na0 .0 3 Rb0 .0 2 Ba0 .0 1) 0 .98(Fe2 1.82 Fe3 0 .4 9Al0 .19Mg0 .18Li0 .16Ti0 .0 8Mn0 .0 5Zn0 .0 2 ) 2 .99(Al1.17Si2 .83) 4 .0 0 O10 (F1.0 3OH0 .50 O0 .4 7) 2 .0 0 。其理想化学式为 :KFe2 3 AlSi3O10 F2 。氟铁云母属单斜晶系 1M型 ,空间群C2 /m。晶胞参数 :a =0 .5369( 8)nm、b =0 .92 89( 3)nm、 相似文献
13.
固体酸催化剂的无腐蚀、环境友好和可循环使用等特点使其成为无机液体酸的最佳替代物.磁性纳米固体酸具有优于常规固体酸催化剂的催化活性及分离简单的特性.用共沉淀法分别合成了一系列三组分TiO2-Al2O3-Fe3O4(TAF)和CeO2-Al2O3-Fe3O4(CAF)及四组分ZrO2--Al2O3-Fe3O4(ZACF)磁性纳米复合氧化物固体酸催化剂,通过电感耦合等离子体原子发射光谱、比表面积测定、X射线衍射、透射电镜、热重分析和红外光谱等对其进行了表征,并利用酯化反应作为探针反应评价了其催化性能.结果表明,合成的磁性纳米固体酸催化剂在酯化反应中表现出很好的催化活性. 相似文献
14.
根据超高压岩石的退变质反应20Jd 3Di H2O=12Ab 2An Tar 3Na2O和18Jd 3Di 2Aeg H2O=12Ab 2An Fe-Tar 3Na2O,利用拟合的绿闪石和铁质绿闪石的热力学数据,在平衡热力学原理的基础上,建立了两个反应的压力计表达式:p=0.001 6(t 273)-0.028lnK 0.321K = (aPlNaAlSi3O8)12·(aPlCaAl2Si2O8)2·(aTarNa2CaMg3Al2[Si6Al2O22](OH)2·(aSodNa2O)3/aNCpxNaAlSi2O6)20·(aCpxCaMgSi2O6)3·aWatH2O经中国安徽省潜山县双河和西阿尔卑斯高压超高压变质带的验证及与角闪石-斜长石温度计的对比,其计算结果基本合理,表明这一新的压力计具有较好的应用价值. 相似文献
15.
南海北部沉积物常量元素变化、碳酸盐旋回及其古环境意义 总被引：1，自引：0，他引：1
通过对南海北部ODP1145站沉积物的常量元素和碳酸盐分析,探讨了早更新世南海北部沉积物常量元素和碳酸盐含量变化特征及其古环境意义.结果表明,南海北部沉积物中主量元素CaO、Fe2O3、K2O、Na2O、MnO和P2O5受碳酸盐含量影响相对较小,而SiO2、MgO、Al2O3和TiO2受到碳酸盐含量影响相对较大.碳酸盐校正后的常量元素变化可以划分为3种类型,即PC1、PC2和PC3,它们的主要特点有:PC1元素组合包括了SiO2、CaO、Na2O、P2O5、Fe2O3和K2O,主要反映了与季风强度有关的生源物质产率变化,指示了距今2.5～1.5Ma时段生产力的逐渐降低;PC2元素组合(Al2O3、TiO2)代表了陆源物质的输入,指示了在约2Ma开始陆源物质输入的明显增加;PC3元素组合(MgO、MnO)可能与海洋自生作用有关,反映了海底氧化/还原环境的相对变化.早更新世南海北部CaCO3含量呈阶段性降低,一方面受陆源物质稀释作用的影响,另一方面可能更与生物生产力逐渐降低有关.主量元素组合及碳酸盐含量在约2Ma和1.7Ma左右均发生显著变化,可能指示了早更新世时期东亚冬季风的两次增强. 相似文献
16.
镜铁山铁（铜）矿床是我国西北地区发现和勘探最早的大型铁（铜）矿床。对于铁矿床的成因,目前还存在不同的观点。本文对镜铁山铁铜矿床赋矿地层开展了岩石学和岩石化学成分分析,结果显示：变质石英砂岩的SiO2平均含量为96. 95%、Al2O3平均为1. 36%、Fe2O3平均为0. 31%,SiO2/Al2O3平均值为73. 26,K2O/Na2O平均值为12. 54;除Sn以外,其他微量元素平均含量均低于后太古宙澳大利亚页岩(PAAS) 值,稀土元素总量显著低于PAAS值,具有弱的Eu正异常,Ce异常不明显;铁碧玉岩SiO2平均含量为85. 67%、Fe2O3平均含量为10. 19%、SiO2/Al2O3平均为430. 47、K2O/Na2O平均为0. 79;除Cu、Ba和Pb平均含量显著高于PAAS外,其他微量元素平均含量均低于PAAS,具有极低的稀土总量、较明显的Eu正异常和不明显的Ce异常;千枚岩SiO2平均为63. 56%、Al2O3平均为14. 35%、Fe2O3平均为5. 04%,K2O平均为5. 08%,MgO平均为2. 46%,SiO2/Al2O3=4. 2~4. 95,平均为4. 44,除了Cu、Sr和U外,其他微量元素均高于PAAS,尤其是Sn和Ba显著高于PAAS。稀土元素总量与PAAS相当,Ce和Eu异常不明显。认为镜铁山群下岩组千枚岩和变质石英砂岩为陆源石英质沉积岩和中—中酸性火成岩在半干旱—潮湿的气候条件下经历了中等—强烈的风化并在被动大陆边缘的氧化—贫氧—次氧化水体环境沉积而成,铁碧玉岩源岩主要为火成岩,形成于氧化的水体环境,为典型的热水成因。镜铁山铁矿为SEDEX型矿床,其形成与哥伦比亚超大陆裂解有关。 相似文献
17.
采用无机盐溶胶-凝胶法制备了颗粒均匀的形态为针状的(Eu2+,Dy3+)SrAl2O4纳米粉体.通过TG-DTA分析和X射线衍射和扫描电镜分析方法,对样品进行了微观结构和表面形态的表征.研究了纳米(Eu2+,Dy3+)SrAl2O4粉体在不同烧结温度下固相反应过程和成相规律.实验结果表明,当样品的烧结温度为500 ℃时是单一的Sr(NO3)2晶相;750 ℃左右生成了Sr3Al2O6,并伴有少量SrAl2O4晶体;1 100 ℃是生成了结晶度良好的针状纳米(Eu2+,Dy3+)SrAl2O4粉体.通过计算,样品粉体晶粒平均为80～100 nm.该晶体粒度随烧结温度升高而逐渐变大. 相似文献
18.
150ka B.P.以来萨拉乌苏河流域主元素变动旋回 总被引：5，自引：1，他引：5
萨拉乌苏河流域米浪沟湾剖面150kaB.P.以来存在27个由风成砂与河湖相和古土壤构成的沉积旋回。通常后两者的Al2O3、TFe、Mn、TiO2、K2O、MgO、CaO和Na2O含量明显高于前者,而SiO2则相反,构成了与沉积旋回相应的150kaB.P.以来27个元素变化旋回。结合各元素的化学迁移特性、研究区所在的鄂尔多斯高原东南部洼地地貌特征以及季风沙区位置,论证了风成砂中SiO2含量增高,Al2O3、TFe、Mn、TiO2、K2O、MgO、CaO和Na2O相对降低,与干寒多风气候及其影响下石英的大量迁入有关,而河湖相和古土壤中SiO2相对迁移、Al2O3等呈聚集的势态,与暖湿气候作用下稳定性元素Al2O3、TFe、Mn、TiO2和非稳定性元素K2O、MgO、CaO、Na2O都能够从四周地表汇集于本区这种特殊的比较封闭的低地有关。研究表明,萨拉乌苏河流域150kaB.P.以来27个元素变化旋回与该时期北半球冰期-间冰期气候波动诱发的亚洲冬夏季风在毛乌素沙漠的多次更迭具有成因上的联系。 相似文献
19.
采用浸渍法制备了用于常温常压下催化Fenton法的负载型Fe2O3/凹凸棒石催化剂,并将其用于处理十二烷基苯磺酸钠废水.采用BET,SEM,FT-IR对其进行了表征,并考察了Fe2O3/凹凸棒石催化剂的催化活性和稳定性.对于初始浓度为40 mg/L的十二烷基苯磺酸钠模拟废水,当Fe2O3/凹凸棒石催化剂和H2O2氧化剂的投加量分别为20 g/L和0.392 mol/L时,pH为5时,反应温度为80℃时,处理1h时染料的十二烷基苯磺酸钠的去除率可达到99.99％.与传统Fenton试剂法相比,以Fe2O3/凹凸棒石为催化剂的Fenton法,具有pH范围广(2～10),降解程度高和催化剂易回收再用的优点. 相似文献