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1.
《Advances in water resources》2002,25(4):417-426
This paper presents a complete analytical solution to describe tidal groundwater level fluctuations in a coastal subsurface system. The system consists of two aquifers and a leaky layer between them. Previous solutions of Jacob [Flow of groundwater, in: H. Rouse (Ed.), Engineering Hydraulics, Wiley, New York, 1950, pp. 321–386], Jiao and Tang [Water Resour. Res. 35 (3) (1999) 747], Li and Jiao [Adv. Water Resour. 24 (5) (2001a) 565], Li et al. [Water Resour. Res. 37 (2001) 1095] and Jeng et al. [Adv. Water Resour. (in press)] are special cases of the new solution. The present solution differs from previous work in that both the effects of the leaky layer's elastic storage and the tidal wave interference between the two aquifers are considered. If the upper and lower aquifers have the same storativities and transimissivities, the system can be simplified into an equivalent double-layered, aquifer–aquitard system bounded by impermeable layers from up and down. It is found that the leaky layer's elastic storage behaves as a buffer to the tidal wave interference between the two aquifers. The buffer capacity increases with the leaky layer's thickness, specific storage, and decreases with the leaky layer's vertical permeability. Great buffer capacity can result in negligible tidal wave interference between the upper and lower aquifers so that the Li and Jiao (loc. cit.) solution applies. 相似文献
2.
Tide-induced airflow is commonly seen in coastal lands and affects ground stability especially with a less permeable pavement on the ground surface. A tide-induced airflow model in a two-layered unsaturated zone consisting of a highly permeable layer underneath a less permeable layer was established by Li and Jiao [Li HL, JJ Jiao. One-dimensional airflow in unsaturated zone induced by periodic water table fluctuation. Water Resour Res 2005;41:W04007. doi:10.1029/2004WR003916] to describe the one-dimensional airflow with constant atmospheric pressure at the ground surface. In this study, we expand the Li and Jiao model by considering the realistic atmospheric pressure fluctuations and the initial condition. A new transient solution to the airflow model is developed for an initial boundary value problem (IBVP). The transient solution can be used not only to calculate the subsurface air pressure at a future time with a known initial condition, but also to evaluate the asymptotic air pressure variations when time becomes long. The amplitude ratio and phase lag of the subsurface air pressure relative to the tide-induced hydraulic head variations inside the unconfined aquifer below the unsaturated zone are investigated. The results reveal that effect on the subsurface pressure due to changes of atmospheric pressure amplitude depends on the configurations of air resistance in the less permeable layer and the air-filled porosity difference in the two layers. The introduction of atmospheric pressure fluctuations into the airflow model leads to insignificant influence on water table level. A field application of the new solution at Hong Kong International Airport in Hong Kong, China is demonstrated. It indicates that the new transient solution can be conveniently used to evaluate the subsurface air pressure with discrete atmospheric pressure data at the ground surface. 相似文献
3.
This paper presents an analytical case study to explore one‐dimensional subsurface air pressure variation in a coastal three‐layered unsaturated zone. The upper layer is thin and much less permeable than the middle layer, and water table is located in the very permeable lower layer. An analytical solution was derived to describe the air pressure variation caused by tide‐induced water table fluctuations. We revisited the case study at Hong Kong International Airport conducted by Jiao and Li (2004) who used a two‐dimensional numerical model. The analytical prediction using the parameter values equivalent to the two‐dimensional numerical model agreed very well with the observed air pressure, indicating the validity and applicability of our one‐dimensional model in approximating the actual situation in this coastal zone with adequate accuracy. The analysis revealed that the asphalt pavement played an important role in causing air pressure fluctuations below it. Abnormally high air pressure can be caused beneath the surface pavement when the air permeability decreases due to rainfall infiltration, which may lead to heaving problems during rising tides. 相似文献
4.
Numerical Analysis of Groundwater Ridging Processes Considering Water‐Air Flow in a Hillslope 
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下载免费PDF全文 In this study, a water‐air two‐phase flow model was employed to investigate the formation, extension, and dissipation of groundwater ridging induced by recharge events in a hypothetical hillslope‐riparian zone, considering interactions between the liquid and gas phases in soil voids. The simulation results show that, after a rain begins, the groundwater table near the stream is elevated instantaneously and significantly, thereby generating a pressure gradient driving water toward both the stream (the discharge of groundwater to the stream) and upslope (the extension of groundwater ridging into upslope). Meanwhile, the airflow upslope triggered by the advancing wetting front moves downward gradually. Therefore, the extension of groundwater ridging into upslope and the downward airflow interact within a certain region. After the rain stops, groundwater ridging near the stream declines quickly while the airflow in the lower part of upslope is still moving into the hillslope. Thus, the airflow upslope mitigates the dissipation of groundwater ridging. Additionally, the development of groundwater ridging under different conditions, including rain intensity, intrinsic permeability, capillary fringe height, and initial groundwater table, was analyzed. Changes in intrinsic permeability affect the magnitude of groundwater ridging near the stream, as well as the downward speed of airflow, thereby generating highly complex responses. The capillary fringe is not a controlling factor but an influence factor on the formation of groundwater ridging, which is mainly related to the antecedent moisture. It was demonstrated that groundwater ridging also occurs where an unsaturated zone occurs above the capillary fringe with a subsurface lateral flow. 相似文献
5.
This study employed a coupled water-air two-phase flow and salt water transport model to analyze the behaviors of generated airflow in unsaturated zones and the fluctuations of salinity at the salt–fresh water interface in a two-layered unconfined aquifer with a sloping beach surface subjected to tidal oscillations. The simulation results show that as the new dynamic steady state including effects of tidal fluctuations is reached through multiple tidal cycles, the dispersion zone in the lower salt water wedge is broadened because fresh water/salt water therein flows continuously landward or seaward during tidal cycles. The upper salt–fresh water interface exhibits more vulnerable to the tidal fluctuations, and the variation of salinity therein is periodic, which is irrelevant to the hydraulic head but is influenced by the direction and velocity of surrounding water-flow. With the tidal level fluctuating, airflow is mainly concentrated in the lower permeable layer due to the restraint of the upper semi-permeable layer, and the time-lag between the pore-air pressure and the tidal level increases with distance from the coastline. The effect of airflow in unsaturated zones can be transmitted downward, causing both the magnitude of salinity and its amplitude in the upper salt–fresh water interface to be smaller for the case with airflow than without airflow due to the resistance of airflow to water-flow. Sensitivity analysis reveal that distributions of airflow in unsaturated zones are affected by the permeability of the upper/lower layer and the van Genuchten parameter of the lower layer, not by the van Genuchten parameter of the upper layer, whereas the salinity fluctuations in the salt–fresh water interface are affected only by soil parameters of the lower layer. 相似文献
6.
When an open well is installed in an unsaturated zone, gas will flow to/from the well depending on the pressure difference between the well and the surrounding media. This process is called barometric pumping and the well is called a barometric pumping well (BPW). Understanding subsurface gas pressure distribution and gas flow rate to/from a BPW is indispensable to optimize passive soil vapor extraction. This study presents a 2-D semi-analytical solution to calculate the subsurface gas pressure and gas flow rate to/from a BPW with and without a check valve. The problem is conceptualized as a mixed-type boundary value problem. The solution for pumping without a check valve is used to analyze the behavior of the radius of influence (ROI). Results show that ROI is time-dependent. It increases with radial gas permeability and decreases with vertical gas permeability. Field application of the solution without a check valve demonstrates the high accuracy of the developed solution. 相似文献
7.
A hydrographic method was proposed to separate out the hourly scaled groundwater level changes caused by net recharge, barometric effects and evapotranspiration from a semidiurnal water table fluctuation. A characteristic midnight time, with a turning point of the barometric pressure change and high relative air humidity, which meant that neither the barometric effect nor groundwater evapotranspiration occurred, was proposed for determining the net recharge rate rnet. Then, the barometric efficiency fbar was estimated using the other time period without evapotranspiration, and the evapotranspiration rate rETG was finally obtained using the remainder of the water level changes. A case example illustrated that estimation of fbar using the proposed method was more accurate than that using the traditional error analysis method, which may result in a significant underestimation under the condition of the present water level changes. Additionally, the abnormal semidiurnal fluctuations, more specifically, two step-down fluctuations, which may be a common pattern when the groundwater level is controlled by net recharge, barometric effects and evapotranspiration, can be well understood using the three components separated out. The results also showed that nighttime groundwater evapotranspiration, accounting for an average of 23% of that during the daytime, cannot be ignored. 相似文献
8.
Hydrologic precursors to earthquakes: A review 总被引：4，自引：0，他引：4
Evelyn A. Roeloffs 《Pure and Applied Geophysics》1988,126(2-4):177-209
This review summarizes reports of anomalous flow rates or pressures of groundwater, oil, or gas that have been interpreted as earthquake precursors. Both increases and decreases of pressure and flow rate have been observed, at distances up to several hundred kilometers from the earthquake epicenter, with precursor times ranging from less than one day to more than one year. Although information that might rule out nontectonic causes does not appear in many published accounts of hydrologic anomalies, several recent studies have critically evaluated the possible influences of barometric pressure, rainfall, and groundwater or oil exploitation. Anomalies preceding the 1976 Tangshan, China, and the 1978 Izu-Oshima-Kinkai, Japan, earthquakes are especially well-documented and worthy of further examination.Among hydrologic precursors, pressure head changes in confined subsurface reservoirs are those most amenable to quantitative interpretation in terms of crustal strain. The response of pressure head to earth tides determines coefficients of proportionality between pressure head and crustal strain. The same coefficients of proportionality should govern the fluid pressure response to any crustal strain field in which fluid flow in the reservoir is unimportant. Water level changes in response to independently recorded tectonic events, such as earthquakes and aseismic fault creep, provide evidence that a calibration based on response to earth tides may be applied to crustal strains of tectonic origin.Several models of earthquake generation predict accelerating stable slip on part of the future rupture plane. If precursory slip has moment less than or equal to that of the impending earthquake, then the coseismic volume strain is an upper bound for precursory volume strain. Although crustal strain can be only crudely estimated from most reported pressure head anomalies, the sizes of many anomalies within 150 kilometers of earthquake epicenters appear consistent with this upper bound. In contrast, water level anomalies at greater epicentral distances appear to be larger than this bound by several orders of magnitude.It is clear that water level monitoring can yield information about the earthquake generation process, but progress higes on better documentation of the data. 相似文献
9.
An investigation of groundwater table fluctuations induced by rainfall should consider interactions between the liquid and gas phases in soils. In this study, a water‐air two‐phase flow model was initially verified by simulating an infiltration experiment. It was then employed to model the interactions between liquid and gas phases regarding actions of airflow on the groundwater table and the fluctuations of the phreatic level and water level in the well induced by rainfall. The effects of airflo7w caused by rainfall on phreatic level fluctuations were also studied quantitatively by comparing the results obtained using the proposed model with those obtained from a water single‐phase flow model. The simulation results show that in addition to actual recharge, compressed airflow in unsaturated zones causes the phreatic level to increase, but the rise in the phreatic level is lower than that in the pore‐air pressure head in unsaturated zones due to the mitigation of capillary fringe. The existence of airflow enhances the phreatic level rise during and after rainfall. In addition, the water level in the well, pushed by the phreatic level fluctuations, varies similarly to the phreatic level, but it experiences somewhat delayed and slightly attenuated. The Lisse effect precisely reflects the phreatic level fluctuations before actual recharge. Furthermore, the fluctuations in the phreatic level and water level in the well and the contributions of airflow to phreatic level fluctuations are affected by many factors: rain intensity, initial moisture, overlying aquitard, groundwater table depths, and screen depths of the well. 相似文献
10.
液相渗透率描述了岩石的渗流特性,是评价储层与预测油气产能的重要参数.液相渗透率是指盐水溶液在岩石孔隙中流动且与岩石孔隙表面黏土矿物发生物理化学作用时所测得的渗透率;液相渗透率的实验测量条件更加接近实际地层泥质砂岩的条件,使得液相渗透率更能反映地层条件下泥质砂岩的渗流特性;然而,现有的液相渗透率评价模型较少,且模型未能揭示液相渗透率与溶液矿化度之间的关系.基于此,开展了液相渗透模型推导与计算方法研究;文中首先将岩石等效为毛管束模型,推导建立了液相渗透率与比表面、喉道曲折度、总孔隙度、黏土束缚水孔隙度等参数之间的关系;其次,根据岩石物理体积模型,推导建立了黏土束缚水孔隙度与阳离子交换容量、溶液矿化度等参数的关系;最终,将黏土束缚水孔隙度引入液相渗透率计算公式,建立了基于总孔隙度、阳离子交换容量、溶液矿化度、比表面、喉道曲折度等参数的液相渗透率理论计算模型.液相渗透率计算模型与两组实验数据均表明,液相渗透率随阳离子交换容量的增大而降低,随溶液矿化度的增大而增大.然而,液相渗透率理论计算模型的实际应用中喉道曲折度、比表面等参数求取困难,直接利用理论模型计算液相渗透率受到限制.在分析液相渗透率与孔隙渗透率模型的基础上,建立了液相渗透率与空气渗透率之间的转换模型,形成了利用转化模型计算液相渗透率的新方法.为进一步验证液相渗透率与空气渗透率转化模型的准确性,基于两组实验数据,利用转换模型计算了液相渗透率;液相渗透率计算结果与岩心测量液相渗透率实验结果对比显示,液相渗透率计算结果与实际岩心测量结果吻合较好,文中建立的液相渗透率与空气渗透率转化模型合理可靠. 相似文献
11.
Groundwater level fluctuations are affected by surface properties due to complex correlations of groundwater-surface water interaction and/or other surface processes, which are usually hard to be accurately quantified. Previous studies have assessed the relationship between groundwater level fluctuations and specific controlling factors. However, few studies have been conducted to explore the impact of the combination of multiple factors on the groundwater system. Hence, this paper tries to explore the localized and scale-specific multivariate relationships between the groundwater level and controlling factors (such as hydrologic and meteorological factors) using bivariate wavelet coherence and multiple wavelet coherence. The groundwater level fluctuations of two wells in areas covered by different plant densities (i.e., the riparian zone of the Colorado River, USA) are analyzed. Main findings include three parts. First, barometric pressure and river stage are the best factors to interpret the groundwater level fluctuations at small scales (<1 day) and large scales (>1 day) at the well of low-density plants stand, respectively. Second, at the well of high-density plants stand, the best predictors to control the groundwater level fluctuations include barometric pressure (<1 day), the combination of barometric pressure and temperature (1-7 days), temperature (7-30 days), and the combination of barometric pressure, temperature, and river stage (>30 days). The best predictor of groundwater head fluctuations depends on the variance of the vegetation coverage and hydrological processes. Third, these results provide a suite of factors to explain the groundwater level variations, which is an important topic in water-resource prediction and management. 相似文献
12.
Mart Oostrom Michael J. Truex Guzel D. Tartakovsky Tom W. Wietsma 《Ground Water Monitoring & Remediation》2010,30(3):45-56
Low-permeability layers of the vadose zone containing volatile organic compounds (VOCs) may persist as source zones for long time periods and may provide contamination to groundwater. At sites with low recharge rates, where vapor migration is the dominant transport process, the impact of vadose zone sources on groundwater may be difficult to assess. Typical assessment methods include one-dimensional numerical and analytical techniques. The one-dimensional approaches only consider groundwater coupling options through boundary conditions at the water table and may yield artificially high mass flux results when transport is assumed to occur by gas-phase diffusion between a source and an interface with a zero concentration boundary condition. Improvements in mass flux assessments for VOCs originating from vadose zone sources may be obtained by coupling vadose zone gas transport and dissolved contaminant transport in the saturated zone and by incorporating the inherent three-dimensional nature of gas-phase transport, including the potential of density-driven advection. This paper describes a series of three-dimensional simulations using data from the U.S. Department of Energy's Hanford site, where carbon tetrachloride is present in a low-permeability zone about 30 m above the groundwater. Results show that, for most cases, only a relatively small amount of the contaminant emanating from the source zone partitions into the groundwater and that density-driven advection is only important when relatively high source concentrations are considered. 相似文献
13.
Groundwater in coastal areas is commonly disturbed by tidal fluctuations. A two‐dimensional analytical solution is derived to describe the groundwater fluctuation in a leaky confined aquifer system near open tidal water under the assumption that the groundwater head in the confined aquifer fluctuates in response to sea tide whereas that of the overlying unconfined aquifer remains constant. The analytical solution presented here is an extension of the solution by Sun for two‐dimensional groundwater flow in a confined aquifer and the solution by Jiao and Tang for one‐dimensional groundwater flow in a leaky confined aquifer. The analytical solution is compared with a two‐dimensional finite difference solution. On the basis of the analytical solution, the groundwater head distribution in a leaky confined aquifer in response to tidal boundaries is examined and the influence of leakage on groundwater fluctuation is discussed. Copyright © 2001 John Wiley & Sons, Ltd. 相似文献
14.
Soil air permeability plays a decisive role in the effectiveness of soil vapour extraction (SVE) for the removal of volatile organic contaminants (VOCs) from soil. The objective of this work is to study the change of the soil air permeability during continuous venting and removal of contaminant from a polluted soil. SVE pilot experiments were conducted to investigate the interaction of soil air permeability with total liquids saturation. Oppositely to previous studies, air permeability was measured by fitting pressure data measured in a 3D laboratory venting pilot to an analytical airflow solution. The experimental correlation was compared with two different correlations published previously. A difference was observed between measured and calculated air relative air permeabilities especially for low water saturation degrees. The importance of the correct estimate of relative permeability was then illustrated by comparing vacuums and streamlines calculated using measured permeability and permeability values estimated with the two correlations tested here. Results show that an inappropriate assessment of relative permeability may engender significant errors in designing an SVE system. The second part of this work reports on the influence of air permeability change on the prediction capability of an SVE mathematical model. A significant difference between simulated breakthrough curves, estimated using firstly the relationship established experimentally and secondly the two other correlations, was observed. These results lead us to say that inadequate characterization of the air permeability change may generate significant errors in removal rate and closure time estimates. 相似文献
15.
A general solution for groundwater flow in an estuarine's leaky aquifer system after considering aquifer anisotropy 下载免费PDF全文
下载免费PDF全文 This paper presents an analytical model for describing the tidal effects in a two‐dimensional leaky confined aquifer system in an estuarine delta where ocean and river meet. This system has an unconfined aquifer on top and a confined aquifer on the bottom with an aquitard in between the two. The unconfined and confined aquifers interact with each other through leakage. It was assumed that the aquitard storage was negligible and that the leakage was linearly proportional to the head difference between the unconfined and confined aquifers. This model's solution was based on the separation of variables method. Two existing solutions that deal with the head fluctuation in one‐dimensional or two‐dimensional leaky confined aquifers are shown as special cases in the present solution. Based on this new solution, the dynamic effect of the water table's fluctuations can be clearly explored, as well as the influence of leakage on the behaviour of fluctuations in groundwater levels in the leaky aquifer system. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
16.
L. Li D. A. Barry C. Cunningham F. Stagnitti J. -Y. Parlange 《Advances in water resources》2000,23(8):176
Previous studies on tidal dynamics of coastal aquifers have focussed on the inland propagation of oceanic tides in the cross-shore direction, a configuration that is essentially one-dimensional. Aquifers at natural coasts can also be influenced by tidal waves in nearby estuaries, resulting in a more complex behaviour of head fluctuations in the aquifers. We present an analytical solution to the two-dimensional depth-averaged groundwater flow equation for a semi-infinite aquifer subject to oscillating head conditions at the boundaries. The solution describes the tidal dynamics of a coastal aquifer that is adjacent to a cross-shore estuary. Both the effects of oceanic and estuarine tides on the aquifer are included in the solution. The analytical prediction of the head fluctuations is verified by comparison with numerical solutions computed using a standard finite-difference method. An essential feature of the present analytical solution is the interaction between the cross- and along-shore tidal waves in the aquifer area near the estuary’s entry. As the distance from the estuary or coastline increases, the wave interaction is weakened and the aquifer response is reduced, respectively, to the one-dimensional solution for oceanic tides or the solution of Sun (Sun H. A two-dimensional analytical solution of groundwater response to tidal loading in an estuary, Water Resour Res 1997;33:1429–35) for two-dimensional non-interacting tidal waves. 相似文献
17.
The distributions of permeability and porosity are key factors that control airflow and gas phase transport in unsaturated formations. To understand the behavior of flow and transport in such formations, characterization procedure is a typical approach that has been widely applied to laboratories and fields. As is recognized by most investigations, this approach relies on accurate measurements, and more importantly, an adequate tool to interpret those measurements from experiments. This study presents a pneumatic inverse model that is capable to estimate the distributions of permeability (k) and porosity () with high resolution in heterogeneous unsaturated formations. Based on the concept of sequential successive linear estimator (SSLE), the developed model accounts for compressibility and density of air and estimates the geologic parameters using air pressure measurements from sequential cross-hole pneumatic pumping or injection tests. Four synthetic examples, including a one-dimensional well-posed, a horizontally two-dimensional, and two three-dimensional problems, are used to evaluate the developed model in estimating the distributions of permeability and porosity in unsaturated formations. Results of the numerical experiments are promising. The developed pneumatic inverse model can reconstruct the property (i.e., permeability and porosity) fields if the well-defined conditions are met. With a relatively small number of available measurements, the proposed model can accurately capture the patterns and the magnitudes of estimated properties for unsaturated formations. Results of two complex three-dimensional examples show that the proposed model can map the fracture connectivity using a small number of subsurface pressure measurements and estimate k and in shallow soil layers using spatial variations of barometric pressure. 相似文献
18.
Abstract Submarine springs play an important role in submarine groundwater discharge (SGD). To investigate the effects of these springs on the propagation of tidal signals in coastal confined aquifers, this paper considers a general coastal aquifer system with a submarine spring on the seabed where the length of the aquifer's offshore extent is finite and its submarine outlet is covered by an impermeable outlet-capping. An approximate analytical solution is obtained for describing the tidal head fluctuations in the aquifer. Solution analyses indicate that the error of the approximate analytical solution is negligible when both distances from the spring hole to the coastline and to the submarine outlet-capping are much greater than the radius of the spring hole. Sensitivity tests are conducted to investigate the effects of hydraulic properties, tidal and spring geometric configuration parameters on the tidal signal propagation in the inland aquifer. For aquifers with infinite offshore length, or without submarine springs, existing solutions in the literature are obtained. The comparison of groundwater head fluctuations for the cases with and without a submarine spring demonstrate the enhancing effect of the submarine spring on tidal signal propagation in the inland aquifer. Three situations that fit our model assumptions are given for future potential applications. A hypothetical example is used to show the possibility of identifying a spring's location using the present analytical solution together with tidal signals observed from inland wells. Editor D. Koutsoyiannis; Associate editor Y. Guttmann Citation Xia, Y.Q., Li, H.L., Yang, Y., and Huang, W., 2012. Enhancing effect on tidal signals of a submarine spring related to a semi-infinite confined aquifer. Hydrological Sciences Journal, 57 (6), 1231–1248. 相似文献
19.
Groundwater temperature is an important water quality parameter that affects species distributions in subsurface and surface environments. To investigate the response of subsurface temperature to atmospheric climate change, an analytical solution is derived for a one‐dimensional, transient conduction–advection equation and verified with numerical methods using the finite element code SUTRA. The solution can be directly applied to forward model the impact of future climate change on subsurface temperature profiles or inversely applied to produce a surface temperature history from measured borehole profiles. The initial conditions are represented using superimposed linear and exponential functions, and the boundary condition is expressed as an exponential function. This solution expands on a classic solution in which the initial and boundary conditions were restricted to linear functions. The exponential functions allow more flexibility in matching climate model projections (boundary conditions) and measured temperature–depth profiles (initial conditions). For example, measured borehole temperature data from the Sendai Plain and Tokyo, Japan, were used to demonstrate the improved accuracy of the exponential function for replicating temperature–depth profiles. Also, the improved accuracy of the exponential boundary condition was demonstrated using air temperature anomaly data from the Intergovernmental Panel on Climate Change. These air temperature anomalies were then used to forward model the effect of surficial thermal perturbations in subsurface environments with significant groundwater flow. The simulation results indicate that recharge can accelerate shallow subsurface warming, whereas upward groundwater discharge can enhance deeper subsurface warming. Additionally, the simulation results demonstrate that future groundwater temperatures obtained from the proposed analytical solution can deviate significantly from those produced with the classic solution. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
20.
Knowing little about how porosity and permeability are distributed at depth, we commonly develop models of groundwater by treating the subsurface as a homogeneous black box even though porosity and permeability vary with depth. One reason for this depth variation is that infiltrating meteoric water reacts with minerals to affect porosity in localized zones called reaction fronts. We are beginning to learn to map and model these fronts beneath headwater catchments and show how they are distributed. The subsurface landscapes defined by these fronts lie subparallel to the soil-air interface but with lower relief. They can be situated above, below, or at the water table. These subsurface landscapes of reaction are important because porosity developed from weathering can control subsurface water storage. In addition, porosity often changes at the weathering fronts, and when this affects permeability significantly, the front can act like a valve that re-orients water flowing through the subsurface. We explore controls on the positions of reaction fronts under headwater landscapes by accounting for the timescales of erosion, chemical equilibration, and solute transport. One strong control on the landscape of subsurface reaction is the land surface geometry, which is in turn a function of the erosion rate. In addition, the reaction fronts, like the water table, are strongly affected by the lithology and water infiltration rate. We hypothesize that relationships among the land surface, reaction fronts, and the water table are controlled by feedbacks that can push landscapes towards an ‘ideal hill’. In this steady state, reaction-front valves partition water volumes into shallow and deep flowpaths. These flows dissolve low- and high-solubility minerals, respectively, allowing their reaction fronts to advance at the erosion rate. This conceptualization could inform better models of subsurface porosity and permeability, replacing the black box. 相似文献