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1.
To promote the rational development and use of clean coal resources in China,data on the regional and age distribution of sulfur,arsenic and other harmful elements in Chinese coal was broadly collected,tested for content,and analyzed.Coal in northwestern China is characterized by low to extremely low levels of sulfur;the coal of the Taiyuan Formation in northern China mainly has high-sulfur content;that of the Shanxi Formation is mainly characterized by low sulfur coal;and the Late Permian coal in southern China has overall higher sulfur content;other regions have low sulfur coal.The average content of harmful trace elements in the bulk of China's coal is similar to the corresponding content in the coal of the North America and the rest of the world,whereas the content of various elements(Hg,Sb and Se)is different in magnitude to the corresponding percentage in the crust.The average content of the elements Cr,Se,Co,Be,U,Br in Late Permian coal in S China ranks first in the country whereas the average content of Hg and Cl in the coals of Late Carboniferous to Early Permian age in N China are the highest.The average content of Mn in Early and Middle Jurassic coal is higher in NW China.The high content of harmful elements in some coal should cause particular concern both in the development and utilization of coal.  相似文献   

2.
The determined results of the sulfur contents and isotopic composition of coal samples from major coal mines in 15 provinces and regions of China show that the coal mined in the north of China is characterized by higher ^34S and lower sulfur content, but that in the south of China has lower ^34S and higher sulfur content.During the coal-burning process in both indrstrial and daily use of coal as fuel the released sulfur dioxide is always enriched in lighter sulfur isotope relative to the corresponding coal;the particles are always enriched in heavier sulfur isotope.The discussion on the environmental geochemical significance of the above-mentioned results also has been made.  相似文献   

3.
The Longtan Formation was originally thought to belong to the Late Permian, but this study reveals that the lower part of this formation belongs to the Middle Permian. The study proposes the corresponding chro-nostratigraphic boundary and new schemes for the correlation of geological sections. Based on these schemes a new understanding on the accumulation regularity of Permian coal measures in South China is reached.  相似文献   

4.
Well-preserved and diversified spores, cryptospores, and acritarchs have been recorded from a relatively continuous sequence that encompasses the Silurian–Devonian boundary in Qujing, Yunnan, southwest China. Four spore assemblage zones from Late Silurian to Early Devonian in age are proposed based on the first appearance datum (FAD) of characteristic spore species. In ascending stratigraphic order, they are Ambitisporites dilutus–Apiculiretusispora synorea (DS; Late Ludfordian to Early Pridoli), Synorisporites verrucatus–Apiculiretusispora plicata (VP; Pridoli), Apiculiretusispora minuta–Leiotriletes ornatus (MO; Lochkovian), and Verrucosisporites polygonalis–Dibolisporites wetteldorfensis (PW; Pragian). The acritarch assemblage from the upper part of the Yulongsi Formation, the Xiaxishancun Formation, and the lower–middle parts of the Xitun Formation indicates an age of Late Silurian. Based on palynological evidence, the upper part of the Yulongsi Formation is considered Late Ludfordian to Early Pridoli in age; the Xiaxishancun Formation is believed to be Pridoli in age; the Xitun Formation is considered Late Pridoli to Early Lochkovian in age; the Guijiatun Formation is considered Lochkovian in age; and the Xujiachong Formation is Late Lochkovian to Pragian in age. The Silurian-Devonian boundary is recognized between the VP and the MO spore biozones, and occurs within the middle part of the Xitun Formation.  相似文献   

5.
During the Late Carboniferous to Early Permian, a rift was formed by post-collisional extension after ocean closure or an island arc-related basin formed by Paleo-Asian Ocean (PAO) subduction in the Xi Ujimqin area. Nevertheless, the closure time of the PAO is still under debate. Thus, to identify the origin of the PAO, the geochemistry and U-Pb age of zircons were analyzed for the extra-large deep marine, polymict clastic boulders and sandstones in the Shoushangou Formation within the basin. The analyses revealed magmatic activity and tectonic evolution. The conglomerates include megaclasts of granite (298.8 ± 9.1?Ma) and granodiorite porphyry (297.1 ± 3.1?Ma), which were deposited by muddy debris flow. Results of this study demonstrated that the boulders of granitoids have the geochemistry of typical I-type granite, characterized by low Zr + Nb + Ce + Y and low Ga/Al values. The granitoid boulders were formed in island arc setting, indicating the presence of arc magmatism in the area that is composed of the Late Carboniferous to Early Permian subduction-related granitoid in southern Xi Ujimqin. Multiple diagrams for determining sedimentary provenance using major and trace elements indicate that Shoushangou sediments originated from continental island arc-related felsic rocks. Detrital zircon U-Pb age cluster of 330–280?Ma was obtained, indicating input from granite, ophiolite, Xilin Gol complex, and Carboniferous sources to the south. The basin was geographically developed behind the arc during the Early Permian period because the outcropped intrusive rocks in the Late Carboniferous to Early Permian form a volcanic arc. The comprehensive analyses of source areas suggest that Shoushangou sediments developed in a backarc basin in response to the northward subduction of the PAO. The backarc basin and intrusive rocks, in addition to previously published Late Carboniferous to Early Permian magmatic rocks of arc unit in Xilin Gol, confirm the presence of an Early Permian trench-arc-basin system in the region, represented by the Baolidao arc and Xi Ujimqin backarc basin. This study highlights the importance and potential of combined geochemical and geochronological studies of conglomerates and sandstone for reconstructing the geodynamic setting of a basin.  相似文献   

6.
Affinity between Palaeozoic Blocks of Xinjiang and Their Suturing Ages   总被引：1，自引：0，他引：1  
The Kazakhstanian plate was near the Tarim, Sino-Korean and South China-Southeast Asian plates in the Middle-Late Cambrian and Late Ordovician, and approached the Siberian plate in the other periods of the Early Palaeozoic. The Hi and Toksun-Yamansu terranes had been split from the Tarim plate before the Middle Devonian and then went close to Angaraland in the late Early Permian. The Beishan area on the northeastern margin of the Tarim plate came close to Angaraland first in the early Early Permian. The suturing age between the Tarim and Ka-zakhstanian-Siberian plates is generally the same as that between the Turkey-Central Iran-Gangdise and South China-Southeast Asian plates. The suturing event took place in the early Early Permian, while the corresponding tectogeny occurred between the Early and Late Permian.  相似文献   

7.
Central Asian Orogenic Belt(CAOB) is one of the largest accretionary orogenic belts in the world. The eastern segment of CAOB is dominated by Paleozoic Paleo Asian Ocean tectonic regime, Mesozoic Paleo-Pacific tectonic regime and Mongolian-Okhotsk tectonic regime. The Songliao and Jiamusi blocks are located in the easternmost part of the CAOB and are the key region to solve the problem about overprinting processes of multiple tectonic regimes. It is generally believed that the Mudanjiang Ocean between the two blocks was finally closed in the Mesozoic, but the Paleozoic magmatism also developed along the Mudanjiang suture zone, while on both sides of the suture zone, there were comparable Paleozoic strata, indicating that the two blocks had converged during the Paleozoic, and the evolution history of the two blocks in the Late Paleozoic remains controversial. The Carboniferous-Permian terrestrial strata mainly developed in Binxian, Wuchang and Tieli on Songliao Block, Baoqing and Mishan on Jiamusi Block. Samples from the Songliao and Jiamusi blocks in the Late Carboniferous-Early Permian and Late Permian are collected for comparative analysis. The LAICP-MS zircon U-Pb dating results show that the maximum depositional age of Middle Permian Tumenling Formation and Late Permian Hongshan Formation in Songliao Block is ～260 Ma, while that of Tatouhe Formation and Carboniferous strata in Jiamusi Block are ～290 Ma and ～300 Ma, respectively, which supports the previous stratigraphic division scheme. The age peaks of ～290–300 Ma, ～400 Ma, ～500 Ma appeared in the Late Carboniferous to Early Permian strata of Jiamusi Block and the Middle Permian strata of Songliao Block. The age peak of ～500 Ma in the Middle Permian strata of Songliao Block may come from the Cambrian basement, Mashan Complex, of Jiamusi Block, while the age peaks of ～420–440 Ma in the Carboniferous strata of Jiamusi Block may come from the Silurian magmatic arc in Zhangguangcai Range in the eastern margin of Songliao Block, reflects the history that they had been potential sources of each other, indicating that they may have combined in the Paleozoic. The Hongshan Formation of Songliao Block in the Late Permian lacks the age peak of ～500 Ma, which indicate that Jiamusi Block was not the provenance of Songliao Block in the Late Permian, that is, there was a palaeogeographic isolation between the two blocks. Combined with the ～210 Ma bimodal volcanic rocks developed along the Mudanjiang suture zone reported previously, we believe that the oceanic basin between the Songliao and Jiamusi blocks should have been connected in Late Permian and reopened during Late Permian to Late Triassic.  相似文献   

8.
Leping coal (including barkinite-rich coal) is a unique kind of coal,which is widely distrbuted in the Late Permian Longan Formation,South China,In this paper,ROck-Eval,Py-GC and simulation experiment via an open-system were used to study the hydrocarbon-generating potential,hydrocarbon composition.and hydrocarbon-generating model of barkiniterich coals from the shuicheng coal field of Guizhou Province,Southwest China.The results show that barkinite-rich coals have high hydrocarbon-generating potential,with S1 S2 being 211-311mg/g,and can produce large amounts of hydrocorbon at the high-maturity stage,mostly within the temperature range of 420-450℃(corresponding to VR0 1.1-1.5%);barkinite-rich coal is one of the better oil sources and light hydrocarbon and wet gas are the major hydrocarbon components,which account for 45% and 33% of the total hydrocarbons.respectively.These characteristics are of importance for exploring oil and gas resources in the Late permian Longtan Formation coals,southwest China.  相似文献   

9.
Laser ablation-inductively coupled plasma mass spectrometry (LA-ICP-MS) zircon U-Pb dating and geochemical data for the Permian gabbros and diorites in the Hunchun area are presented to constrain the regional tectonic evolution in the study area. Zircons from gabbro and diorite are euhedral-subhedral in shape and display fine-scale oscillatory zoning as well as high Th/U ratios (0.26–1.22), implying their magmatic origin. The dating results indicate that the gabbro and diorite formed in the Early Permian (282±2 Ma) and in the Late Permian (255±3 Ma), respectively. In addition, the captured zircons with the weighted mean age of 279±4 Ma are also found in the diorite, consistent with the formation age of the gabbro within uncertainty. The gabbros belong chemically to low-K tholeiitic series, and are characterized by low rare earth element (REE) abundances, flat REE pattern, weak positive Eu anomalies (δEu), and depletion in high field strength elements (HFSEs, Nb, Ta, and Ti), similar to the high-aluminum basalts from island arc setting. Initial Hf isotopic ratios of zircons from the gabbro range from +7.63 to +14.6, suggesting that its primary magma could be mainly derived from partial melting of a depleted lithospheric mantle. The diorites belong to middle K calc-alkaline series. Compared with the gabbros, the diorites have higher REE abundance, weak negative Eu anomalies, and more depletion in HFSEs (Nb, Ta, and Ti), similar chemically to the volcanic rocks from an active continental margin setting. Initial Hf isotopic ratios and Hf two-stage model ages of zircons from the diorite range from +11.22 to +14.17 and from 424 to 692 Ma, respectively, suggesting that its primary magma could be mainly derived from partial melting of the Early Paleozoic and/or Neoproterozoic accretted lower crust. Taken together, it is suggested that geochemical variations from the Early Permian gabbros to the Late Permian diorites reveal that the subduction of the Paleo-Asian oceanic plate beneath the Khanka Massif and collision between the arc and continent (Khanka Massif) happened in the late stage of the Late Paleozoic.  相似文献   

10.
The pollen and spores found in the Early Cretaceous strata of two cores from the Shuangliao Fault Depression were studied systematically, and two palynological assemblages have been recognized. Assemblage Ⅰ from the Yingcheng Formation is named Paleoconiferus-Pinuspollenites; the assemblage is characterized by an extremely high content of Paleoconifer pollen. Assemblage Ⅱ from Member 1 of the Denglouku Formation is named Cicatricosisporites-Cyathidites-Pinuspollenites; the assemblage is characterized by the abundant presence of Laevigati spores, but less Paleoconifer pollen. According to the palynological data and zircon U-Pb dating, the geological age of the Yingcheng Formation is thought to be Aptian-Albian, and that of the Denglouku Formation is thought to be Early Albian. On the basis of the composition of each assemblage, we can infer that during the depositional period of the Yingcheng Formation, the paleovegetation was mainly conifer forest, the paleoclimate was consistent with the temperate climate of today, and the paleoenvironment was humid feature. During the depositional period of Member 1 of the Denglouku Formation, the paleovegetation was mainly conifer forest and shrubs, the paleoclimate was consistent with the subtropical climate of today, and the paleoenvironment was humid. The results significantly improve our understanding of the stratigraphy in the Shuangliao Fault Depression, provide biostratigraphic evidence for the division and correlation of Early Cretaceous strata in the Shuangliao Fault Depression, and provide new data for analyzing paleovegetation and paleoclimate in the Songliao Basin.  相似文献   

11.
From a fresh field investigation, it has been ascertained that the Late Palaeozoic Yu'erhong (Yuernhung) flora from Yu'erhong, Yumen, Gansu, northwestern China, studied by Bohlin in 1971 includes plants from the Westphalian Yangfukou Formation and the Stephanian to Sakmarian Taiyuan Formation. The Yu'erhong flora from the Yanghukou Formation is dominated by Euramerican elements with a few elements of the Cathaysian flora. No Angarian elements have be found in this section for lack of Late Permian strata. The specimens studied by Bohlin might possibly come from the upper part of the Upper Permian at tne southeastern corner . of the Yu'erhong basin. Those fossils from different horizons and localities might be mixed with each other during collection ;so they fail to reflect the exact horizon of certain plant fossils.  相似文献   

12.
Four great second-order transgressions occurred during the Late Carboniferous to early Early Permian and they came from both the eastern and western sea areas in the North China Platform. As time went on, depocentres, depositional extent, transgression directions, coastline position and distribution of minable coal seams were changing continuously. The third great second-order transgression occurring at the beginning of the early Early Permian marks the maximum transgression period and before its arrival, i.e. at the close of the late Late Carboniferous, there was the super-regional coal-forming environment. During the second, third and fourth transgressions, the northern North China Platform was all along situated on the transgressive margin of the epicontinental sea and became the major distribution area of thick coal belts because it maintained a coal-forming environment for a long period of time from the close of the late Late Carboniferous to the Early Permian.  相似文献   

13.
Inductively coupled plasma mass spectrometry, inductively coupled plasma optical emission spectroscopy, hydride generation-atomic fluorescence spectrometry, emission spectrometry, X fluorescence spectrometry, and X-ray diffraction were employed to study the geochemistry and mineralogy of coal gangues from Nos. 2, 3, and 8 coal seams of the Du’erping coal mine, Xishan coalfield, Taiyuan, Shanxi Province. The study revealed that compared with the sedimentary cover, upper continent crust, Carboniferous-Permian coal from North China, as well as most coal in China, coal gangues from Nos. 2 and 3 coal seams are rich in Li, Be, Sc, Cr, Cu, Ga, Ba, Th, Nb, Cd, Pb, Ta and rare-earth elements, and coal gangues from No. 8 coal seam are rich in Li, Sc, V, Cr, Ga, U, and rare-earth elements. Compared with the Carboniferous-Permian coal from North China and most coal in China, coal gangues from Nos. 2, 3 and 8 seams are rich in Rb, V, Cs and Sr. Therefore, The Du’erping coal gangues in the Xishan coalfield are rich in most hazardous trace elements and rare-earth elements, wherein the contents of Ga and Li reach the industrial grade and have significance for industrial utilization. On the whole, coal gangues of the Shanxi Formation from the Permian are rich in more trace elements than those of the Carboniferous Taiyuan Formation. The distributions of REE show obviously dipping rightwards with negative Eu anomalies. The contents of rare-earth elements in the three seams are quite different. All of the above indicate that the source of the rare-earth elements is terrigenous debris. Minerals in No. 2 seam identified by X-ray diffraction mainly include quartz, kaolinite, in addition to calcite, pyrite, apatite, epidote, and epsomite. No. 3 seam mainly contains quartz, kaolinite, in addition to a small amount of sodium feldspar, calcium nitrate, iron ore, gypsum, and vivianite. No. 8 seam mainly contains kaolinite, dickite, quartz, illite, and a small amount of hematite and U. The correlations between major elements and trace elements in coal gangues of the Du’erping coal mine analyzed by using SPSS (Statistical Product and Service Solutions) indicate that the trace alkali elements and rare-earth elements occur mainly in such clay minerals as kaolinite.  相似文献   

14.
According to the latest International Chronostratigraphic Scheme (ICS, 2000), the Permian in the Middle-Lower Yangtze region of South China can e divided into three series and nine stages relevant to the traditional six stages of South China. From Assellian to Changxingian of Permian, 44 Main age range, the strata are composed of 14 third-order sequences, each of which is 3.14 Ma in average age range. There is one third-order sequence of Zisongian, equivalent to middle and upper Chuanshan Formation or equal to Asselian and two thirds of Sakmarian. There are two third-order sequences, corresponding to Liang-shan Formation or Zhenjiang Formation and upper Chuanshan Formation, which are assigned to Longlingian, coinciding with Artinskian and one third of Sakmarian. In addition, three third-order sequences, equal to Qixia Formation, are attributed to Chhsian, corresponding to Kubergandian and one third of Roadian. Four third-order sequences, comprising Gufeng, Maokou, Yanqiao,Yinping and Wuxue formations, are assigned to Maokouan, equivalent to two thirds of Roadian, Wordian and Capitanian. Two third-order sequences, equal to Longtan Formation or Wujiaping Formation, are included in Wuchiapingian. Other two third-order sequences, corresponding to changxing Formation or Dalong Formation, are assigned to Changhsingian. In brief, these above third-order sequences can be incorporated into 4 sequences sets.  相似文献   

15.
During the Late Paleozoic, West Junggar(Xinjiang, NW China) experienced a shift in tectonic setting from compression to extension. Ha'erjiao is an important area for investigating collisional structures, post–collisional structures, and magmatic activities. Based on the petrological and geochemical characteristics of pyroclastic and other volcanic rocks in the Permian Kalagang Formation from the borehole ZKH1205 in the Jimunai Basin, the main types of source rock for the pyroclastic rocks deposited in the basin are identified and their implications for the Early Permian tectonic setting examined. The abundance of basalt and andesite lithic fragments in the pyroclastic rocks, together with the REE characteristics and the contents of transition and high field strength elements show that the source rocks were chiefly intermediate–basic volcanic rocks. High ICV values, low CIA values, low Rb/Sr ratios, low Th/U ratios and the mineralogical features suggest weak chemical weathering of the source rocks; the geochemical patterns of the pyroclastic rocks might not only have been impacted by crustal contamination but also might be related to the nature of the magma from the source area. The geochemical properties of the pyroclastic rocks distinguish them from arc-related ones, and such samples plot in the within-plate basalt(WPB) field in some diagrams. This is consistent with the formation background of the Early Permian volcanic rocks in this region.  相似文献   

16.
The Honggang member of the early Paleogene Buxin Formation is the main source rock in the Sanshui Basin, characterized by organic-rich black shales with the cyclic recurrence of organic- poor sediments. The geochemical characteristics of the Honggang member have been documented to determine the organic matter types and depositional environments in this paper. The organic matter of the black shales mainly consists of a mixture of land plant-derived and phytoplankton-derived organic matter. Total organic carbon content (TOC)–sulfur–iron (Fe) relationships suggest that the organic- rich black shales were deposited under dysoxic-to-euxinic water conditions. The time that iron minerals remained in contact with H2S in anoxic waters possibly influenced the formation of syngenetic pyrite, and organic carbon controlled the formation of diagenetic pyrite. Organic-poor intervals usually show pyrite sulfur enrichment and higher degree of pyritization values relative to low organic carbon contents. This resulted from HS– diffusing downward from overlying organic-rich sediments and formed Fe sulfides through reactions with sufficient Fe. Trace elements generally exhibit low concentrations and little TOC dependence, suggesting some degree of depletion in these elements in the early Paleogene sediments of the Sanshui Basin. This probably resulted from cyclic recurrences of oxic benthic conditions, which promoted the remobilization of trace elements and caused the low concentration of trace elements.  相似文献   

17.
Concentrations of seventeen hazardous trace elements including As, Pb, Hg, Se, Cd, Cr, Co, Mo, Mn, Ni, U, V, Th, Be, Sb, Br and Zn in the No.ll coal seam, Antaibao surface mine, Shanxi Province were determined using Instrumental Neutron Activation Analysis （INAA）, Inductively Coupled Plasma Atomic Emission Spectrometry （ICP-AES）, Cold-Vapor Atomic Absorption Spectrometry （CV-AAS） and Graphite Furnace Atomic Absorption Spectrometry （GF-AAS）. Comparisons with average concentrations of trace elements in Chinese coal show that the concentrations of Hg and Cd in the No. 11 coal seam, Antaibao surface mine are much higher. They may be harmful to the environment in the process of utilization. The variations of the trace elements contents and pyritic suffur in vertical section indicated that： （a） the concentrations of As, Pb, Mn, and pyritic sulfur decrease from roof to floor; （b） the concentrations of Cr, Zn and Mo are higher in roof, floor and lower in coal seam; （c） the concentration of Br, Sb, and Hg are higher in coal seam and lower in roof and floor; （d） the concentrations of Mo, V, Th and AI vary consistently with the ash yield. Cluster analysis of trace elements, pyritic sulfur, ash yield and major elements, such as AI, Fe, P, Ca shows that： （a） pyritic sulfur, Fe, As, Mn, Ni, Be are closely associated and reflect the influence of pyrite; （b） Mo, Se, Pb, Cr, Th, Co, Ca and A! are related to clay mineral, which is the main source of ash; （c） U, Zn, V, Na, P maybe controlled by phosphate or halite; （d） Hg, Br, Sb and Cd may be mainly organic-associated elements which fall outside the three main groups. The concentration distribution characteristics of trace elements in coal seam and the cluster analysis of major and trace elements showed that the contents of trace elements in the No. 11 coal seam, Antaibao surface mine, are mainly controlled by detrital input and migration from roof and floor.  相似文献   

18.
The occurrence and geological genesis of pyrites in Late Paleozoic colas of North china have been systematically studied in terms of coal petrology,coal chemistry,elemental geochemistry and sulfur isotope geochemistry.The results suggest that eight types of pyrite,i.e.,framboidal,automorphic graular,oolitic,massive,homogeneous spherical,allotriomorphic,nodular,joint-and fisure-filling pyrintes can be subdivided under the microscope,Four generations of pyrite are also reconized according to the shape,size,coexisting assemblage,spacial distribution relationship with macerals,the contents of sulfur and iron.atomic S/Fe ratios and associated elements in pryites.Sulfur in Late Palozoic colas of North China is of diverse source as evidenced by sulfur isotope variations in the pyrites.The δ34S values of pyrite generated at the early stage ted to be negative,and at the late stage,positive.  相似文献   

19.
Beryllium was determined from more than 40 granite bodies of different ages in southern China. Results show that it tends to increase with geologie age. The average beryllium contents for granites of various ages are (%): Hsuehfeng Period, 0.00016;Early Caledonian, 0.00034; Late Caledonian, 0.00035 ; Indosinian, 0.00055; Early Yenshanian, 0.00111; Late Yenshanian, 0.00032. The overall average content of beryllium of granite in this area is 0.00052%, 0.00047% and 0.00137% for biotite-granites and two-mica granites respectively. There seems to he a close relationship between Bemineralization and Yenshanian granites.  相似文献   

20.
Hazardous air pollutants, including compounds of sulfur and toxic trace elements, are emitted during coal combustion. Geochemical studies of these constituents in coals provide information about their species, regional distribution and origins. The data are useful in understanding the cause and scope of human health problems related to these hazardous elements and in designing preventive or remedial measures. Sulfur in coal is a problem because sulfur dioxide emitted during coal combustion is a main source of acid rain. The sulfur isotopic evidence shows that sulfur in low-sulfur coal is derived primarily from parent plant materials. Sulfur enrichment in medium- and high-sulfur coals is caused by the sulfate in seawater that flooded the peat swamp during coal formation. The sulfur content of a coal is controlled primarily by the depositional environment of coal seams. Only pyritic sulfur can be removed by physical coal cleaning processes （coal preparation）. Sulfur dioxide emission can be reduced using clean coal technologies, such as flue-gas desulfurization, fluidized-bed combustion, and integrated gasification and combined cycle.  相似文献   

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