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1.
Caprock has the most important role in the long term safety of formation gas storage. The caprocks trap fluid accumulated beneath, contribute to lateral migration of this fluid and impede its upward migration. The rapid upward passage of invasive plumes due to buoyancy pressure is prevented by capillary pressure within these seal rocks. In the present study, two main seal rocks, from the Zagros basin in the southwest of Iran, a shale core sample of Asmari formation and an anhydrite core sample of Gachsaran formation, were provided. Absolute permeabilities of shale and anhydrite cores, considering the Klinkenberg effect, were measured as 6.09 × 10−18 and 0.89 × 10−18 m2, respectively. Capillary sealing efficiency of the cores was investigated using gas breakthrough experiments. To do so, two distinct techniques including step by step and residual capillary pressure approaches were performed, using carbon dioxide, nitrogen and methane gases at temperatures of 70 and 90 °C, under confining pressures in the range 24.13–37.92 MPa. In the first technique, it was found that capillary breakthrough pressure of the cores varies in the range from 2.76 to 34.34 MPa. Moreover, the measurements indicated that after capillary breakthrough, gas effective permeabilities lie in range 1.85 × 10−21 – 1.66 × 10−19 m2. In the second technique, the minimum capillary displacement pressure of shale varied from 0.66 to 1.45 MPa with the maximum effective permeability around 7.76 × 10−21 – 6.69 × 10−20 m2. The results indicate that anhydrite caprock of the Gachsaran formation provides proper capillary sealing efficacy, suitable for long term storage of the injected CO2 plumes, due to its higher capillary breakthrough pressure and lower gas effective permeability.  相似文献   

2.
Offshore oil & gas industry is moving exploration and production activities into Arctic and deep water regions. Governmental regulations require environmental impact assessments before operations to evaluate the possible effects of accidental oil releases. These are often performed by numerical fate models, like the Oil Spill Contingency and Response (OSCAR) model, which has become an industry standard in Norway. In this model, biodegradation rates are adjusted to local conditions by temperature compensation according to a Q10 approach. Q10 is the multiplier by which rates of enzymatic reactions increase at a 10 °C temperature rise. Herein, this Q10 approach implemented in the OSCAR model is investigated based on published data and novel obtained results. Overall, biodegradation rate predictions calculated by temperature compensation are found to be questionable, and choosing one universal Q10 value is considered not feasible. The high variation in Q10 values is herein attributed to indirect effects of temperature.  相似文献   

3.
Organic contaminant and total mercury concentrations were compared in four species of lamniform sharks over several age classes to examine bioaccumulation patterns and gain insights into trophic ecology. Contaminants found in young of the year (YOY) sharks were assumed to be derived from maternal sources and used as a proxy to investigate factors that influence maternal offloading processes. YOY white (Carcharodon carcharias) and mako (Isurus oxyrinchus) sharks had comparable and significantly higher concentrations of PCBs, DDTs, pesticides, and mercury than YOY thresher (Alopias vulpinus) or salmon (Lamna ditropis) sharks. A significant positive relationship was found between YOY contaminant loads and maternal trophic position, suggesting that trophic ecology is one factor that plays an important role in maternal offloading. Differences in organic contaminant signatures and contaminant concentration magnitudes among species corroborated what is known about species habitat use and may be used to provide insights into the feeding ecology of these animals.  相似文献   

4.
Transition to low carbon sea transport is a logical response to the extreme dependency of the Pacific Islands region on imported fossil fuel, its significant vulnerability to the effects of climate change and the critical shipping needs of Pacific Island countries (PICs). Building on previous work in low carbon sea transport in the Pacific, this paper further considers the barriers to achieving such transition by assessing, through a ‘post-Paris Agreement’ lens, the Intended Nationally Determined Contributions (INDCs) submitted by PICs and contrasting these to the near total lack of investment and planning for low carbon transition in the transport sector with the parallel occurrence in the electricity sector where ~USD 2 billion of donor investment is deployed or queued despite electricity using only ~20% of fossil fuel across the region. Consistent with recent international studies, inadequate and inappropriate financing and policy have been identified as dominant transition barriers for low carbon sea transport development in PICs. This paper further examines the regional level barriers to policy development, and finds them inhibited by the silo nature of the major regional actors. The implications that the Paris Agreement has for climate financing to support the essential research and capacity development needed to underpin a successful low carbon sea transport transition strategy at any useful scale and speed are also considered in this paper.  相似文献   

5.
The central part of the Zagros Fold-Thrust Belt is characterized by a series of right-lateral and left-lateral transverse tear fault systems, some of them being ornamented by salt diapirs of the Late Precambrian–Early Cambrian Hormuz evaporitic series. Many deep-seated extensional faults, mainly along N–S and few along NW–SE and NE–SW, were formed or reactivated during the Late Precambrian–Early Cambrian and generated horsts and grabens. The extensional faults controlled deposition, distribution and thickness of the Hormuz series. Salt walls and diapirs initiated by the Early Paleozoic especially along the extensional faults. Long-term halokinesis gave rise to thin sedimentary cover above the salt diapirs and aggregated considerable volume of salt into the salt stocks. They created weak zones in the sedimentary cover, located approximately above the former and inactive deep-seated extensional faults. The N–S to NNE–SSW direction of tectonic shortening during the Neogene Zagros folding was sub-parallel with the strikes of the salt walls and rows of diapirs. Variations in thickness of the Hormuz series prepared differences in the basal friction on both sides of the Precambrian–Cambrian extensional faults, which facilitated the Zagros deformation front to advance faster wherever the salt layer was thicker. Consequently, a series of tear fault systems developed along the rows of salt diapirs approximately above the Precambrian–Cambrian extensional faults. Therefore, the present surface expressions of the tear fault systems developed within the sedimentary cover during the Zagros orogeny. Although the direction of the Zagros shortening could also potentially reactivate the basement faults as strike-slip structures, subsurface data and majority of the moderate-large earthquakes do not support basement involvement. This suggests that the tear fault systems are detached on top of the Hormuz series from the deep-seated Precambrian–Cambrian extensional faults in the basement.  相似文献   

6.
Ancient lacustrine storm-deposits that act as petroleum reservoirs are seldom reported. The Lijin Sag, which is located in the southeastern corner of the Bohai Bay Basin in East China, is a NE–SW trending Cenozoic half-graben basin. Some of its Eocene deposits (Bindong deposits) were interpreted as lacustrine tempestites. The Bindong tempestites, which developed in the lower part of the upper fourth member of the Shahejie Formation (Es41), constitute a new kind of petroleum reservoir and are novel petroleum exploration targets in the Bindong Area. However, the characteristics of the Es41 Bindong tempestite reservoirs and their controlling factors are poorly understood. Point-count analyses of thin sections, scanning electron microscope image analyses, X-ray diffractometry data, and the petrophysical parameters of the Bindong tempestite reservoirs were utilized to estimate the reservoir quality. The reservoirs have undergone significant diagenetic alteration, which can be divided into negative and positive aspects. The negative alteration includes compaction, authigenic minerals, and cementation such as carbonates, clay minerals and overgrowths of quartz and feldspar. The uneven distribution of carbonate cement increased the reservoir’s heterogeneity, with carbonate cement commonly precipitating along the sandstone-mudstone contacts. The primary porosity was severely reduced because of compaction and extensive carbonate cementation. Positive alteration includes dissolution, carbonate cementation, undercompaction and fractures. Carbonate cementation exhibited both positive and negative effects on the reservoir quality. Overall, the objective reservoir quality is quite poor. A quantitative evaluation of the reservoirs’ potential was conducted. The cutoff values of several of the reservoir’s parameters were calculated. The lower limits of the porosity and permeability are 8.35–5.85% and 1.2587–0.2753 × 10–3 μm2, respectively, depending on the depth. The upper limits of the carbonate and mud content are approximately 18.5% and 9–10%, respectively. A fundamental understanding of these characteristics will provide necessary information for extracting hydrocarbons from analogous subsurface reservoirs.  相似文献   

7.
Military sonar has the potential to negatively impact marine mammals. To investigate factors affecting behavioral disruption in California sea lions (Zalophus californianus), fifteen sea lions participated in a controlled exposure study using a simulated tactical sonar signal (1 s duration, 3250–3450 Hz) as a stimulus. Subjects were placed into groups of three and each group received a stimulus exposure of 125, 140, 155, 170, or 185 dB re: 1 μPa (rms). Each subject was trained to swim across an enclosure, touch a paddle, and return to the start location. Sound exposures occurred at the mid-point of the enclosure. Control and exposure sessions were run consecutively and each consisted of ten, 30-s trials. The occurrence and severity of behavioral responses were used to create acoustic dose–response and dose–severity functions. Age of the subject significantly affected the dose–response relationship, but not the dose–severity relationship. Repetitive exposures did not affect the dose–response relationship.  相似文献   

8.
Deep water fold and thrust belts (DWFTBs) are sedimentary wedges that accommodate plate-scale deformation on both active and passive continental margins. Internally, these wedges consist of individual structures that strongly influence sediment dispersal, bathymetry and fluid migration. Most DWFTB studies investigate basin- and intra-wedge- scale processes using seismic reflection profiles, yet are inherently limited by seismic resolution. Of critical importance is strain distribution and its accommodation on discrete faults compared to distributed deformation. Recent studies have considered strain distribution by investigating regional reflection DWFTBs profiles within coupled systems, which contain down-dip compression and up-dip extension. There is broad agreement of a mis-balance in compression versus extension, with ∼5% excess in the latter associated with horizontal compaction, yet this remains unproven.Using two exceptionally well exposed outcrops in the Spanish Pyrenees we consider deformation of DWFTB at a scale comparable to, and beyond, seismic resolution for the first time. By coupling outcrop observations (decametre to hectometre scale) with a re-evaluation of seismic profiles from the Orange Basin, South Africa, which contains one of the best imaged DWFTBs globally, we provide a unique insight into the deformation from metre to margin scale. Our observations reveal hitherto unrecognised second order structures that account for the majority of the previously recognised missing strain. This re-evaluation implies that ∼5% missing strain should be accounted for in all DWFTBs, therefore existing studies using restorations of the sediment wedge will have underestimated crustal shortening in active margins, or sedimentary shortening in gravity driven systems by this amount. In contrast to previous studies, our observations imply that the majority of this strain is accommodated on discrete fault surfaces and this can explain the occurrence and location of a range of intra-wedge processes that are intimately linked to structures including sediment dispersal, fluid migration pathways and reservoir compartmentalisation.  相似文献   

9.
Using photomosaics and measured sections, this outcrop study characterizes facies- to sandbody-scale heterogeneity in the fluvial and coastal-plain deposits of the Blackhawk Formation of the Wasatch Plateau, Utah, USA, as an outcrop analog for the fluvial tight-gas reservoirs of the adjacent greater western Rocky Mountain basins as well as for conventional fluvial reservoirs elsewhere. Analysis on eight contiguous, vertical cliff-faces comprising both depositional-dip- and -strike-oriented segments provides field-validation and calibration of the entire range of fluvial heterogeneity, where: 1) large-scale heterogeneity (10's of m vertically and 100's of m laterally) is associated with stacking of channelized fluvial sandbodies encased within coastal-plain fines, 2) intermediate-scale heterogeneity (1's of m vertically and 10's of m laterally) is related to type and distribution of architectural elements like bar-accretion and crevasse-splay units within individual sandbodies, and 3) small-scale heterogeneity (10's of cm vertically and 1's of m laterally) is attributed to facies spatial variability within individual architectural elements.At a reservoir-scale (∼6 km strike-transect), impact of these heterogeneities has resulted in potential stratigraphic compartmentalization in varied patterns and scales within and among three zones, which have similar lateral extents. Distinct vertical or lateral compartmentalization, contrasting net-to-gross pattern, width-constraint by either large- or intermediate-scale heterogeneity, disparity in communication between principal reservoir compartments by intermediate-scale heterogeneity, and reservoir-quality segregation to barrier styles rendered by small-scale heterogeneity are documented in an array of trends. These intriguing trends are challenging to correlate across the reservoir-scale dataset, contributing to multiple, analogous exploration and production uncertainties. For improved tight-gas exploration and production strategy of the western Rocky Mountain basins, study results were also used in developing potential predictive tools: 1) thickness threshold of individual channelized sandbody favoring multiple well intersection, 2) aspect ratio in performing probabilistic sandbody-width estimation, and 3) prediction of sandbody amalgamation using underlying coal thickness.  相似文献   

10.
11.
以 CG2 0潜山为例 ,从建立地质模型入手 ,包括地层模型、构造模型、储集模型、储盖组合模型、速度模型等 ,认识到各套地层分布和储层物性的差异均与地震响应密切相关 ,因此可以利用地震波的信息 ,预测潜山储层的发育及分布情况。在对 CG2 0潜山进行精细全三维构造解释的基础上 ,探讨性地应用了测井约束反演、吸收系数、相干分析及三维模式识别等技术 ,对潜山储层进行了预测 ,从而提高了潜山勘探的效益 ,并为类似断阶型潜山带的勘探提供了成功的经验 ,具有一定的指导意义。  相似文献   

12.
The study of many slope channel systems has led to the development of rules in the form of observations, measurements, and hypotheses. For example, we hypothesize that high abandonment relief can strongly influence the location of the subsequent channel element and will result in an organized channel stacking pattern in which the path of the younger channel element approximates the path of the former element. The rules were developed with the objective of constructing forward models of petroleum reservoirs that are internally consistent, reproducible, and quantifiable. Channelized turbidite deposits can be interpreted to be the product of multiple cycles of waxing-waning flow energy at multiple scales. Systematic changes in the volume and caliber of turbidity flows through time trigger a fall of the equilibrium profile, which drives erosion and sediment bypass across the slope, followed by a rise of the equilibrium profile, which allows deposition on the slope of increasingly mud-rich sediments through time. In most turbidite successions, at least three scales of waxing-waning cyclicity can be interpreted: element, complex set, and sequence. The stacking pattern of channel elements within a complex set-scale cycle tends to be sequential: (1) erosion and sediment bypass; (2) amalgamation of channel elements associated with a low rate of aggradation; (3) a disorganized stacking pattern of channel elements associated with a moderate rate of aggradation; and (4) an organized stacking pattern of channel elements associated with a high rate of aggradation. Stages 1 and 2 may be absent or minor in mud-rich systems but prominent in sand-rich systems. Conversely, stage 4 may be prominent in mud-rich systems but absent in sand-rich systems. Event-based forward modeling, utilizing rules, can produce realistic architectures, such as the four stages described above. Multiple realizations and multiple alternative models can be constructed to quantitatively examine the probability of specific parameters of interest such as pore volume and connectivity.  相似文献   

13.
With over 30 years’ experience of managing Marine Protected Areas (MPAs), China has established more than 250 MPAs in its coastal and marine areas, but the overall management effectiveness is unimpressive [46]. Recently, China has made commitments to expand the MPA coverage in its waters ([7,52,53]) and develop an “ecological barrier” along the coast by connecting MPAs and islands by 2020 (The State Council 2015). In this context, this study reviews major challenges in current MPA practices in China, including the lack of systematic and scientific approaches, inadequate laws and regulations, ineffective governance mechanisms, conflicts between conservation and exploitation, limited funding, and inadequate monitoring programs. Four scenarios for developing China's MPA networks are developed and analyzed based on a literature review of experience in the United States, Canada, Australia, New Zealand, the European Union and the Philippines, as well as a set of interviews with Chinese MPA experts. These scenarios include: 1) creating a national system with an inventory of MPAs, 2) developing social networks, 3) developing regional ecological networks, and 4) developing a national representative network. The first two scenarios focus on the enhancement of the governance system through connecting individual MPAs as a social, institutional, and learning network, which could provide opportunities for creating an ecologically coherent network, while the latter two emphasized ecological connectivity and representativeness. Given different focuses, they can be applied at different stages of implementation and combinations of scenarios can be used depending on China's needs.  相似文献   

14.
海洋石油开发过程中面临着复杂多样的储层环境,对油套管的强度、密封性等性能提出了严格要求,合理选择适合的油套管对油气钻采至关重要。本文首先对渤海、东海、南海东部、南海西部海域进行了基础数据的收集,主要包括油田分布情况、油气藏特点;并进行双变量相关性分析,明确了海况参数与油套管技术参数的相关性。在此基础上,根据不同储层地质特点和差异建立了适用于各海域的海上油田油套管推荐体系;采用Django+MySQL为开发工具进行开发,形成一套基于Web前端的海上油田油套管数据库管理系统;最后通过渤海海域埕北油田M1井应用案例测试,获得合适的油套管推荐方案,验证了该海上油田油套管数据库的实用性。海上油田油套管管理系统的建立能够高效、科学的管理油套管的应用信息,有利于未来海上油田的开发。  相似文献   

15.
The recent major discoveries of petroleum in Pre-Salt carbonate reservoirs, of mainly lacustrine origin, offshore Brazil has increased interest in studying these complex non-marine reservoirs, which present many production-development challenges, largely due to their heterogeneous nature. Some of the reservoir carbonate rock-types present in Brazil are limestones composed predominantly of bivalve shells, which are known as ‘coquinas’.The coquinas show a variety of pore types, pore sizes, pore shapes and pore connectivity which define their porosity and strongly influence the permeability and resulting electrical resistivity but this aspect of these relationships in these carbonates has been relatively poorly characterised (particularly in a quantitative manner) in the literature. The petrophysical characterisation of the coquinas of the Morro de Chaves Formation (Barremian-Aptian), exposed in a quarry in NE Brazil, was carried out using the outcrop-selected samples, plugs and petrographic thin-sections to investigate these aspects. Porosity, permeability, grain density and porosity exponent (m) measurements were carried out on the plugs. X-ray microtomography was performed to identify key characteristics of the pore system and for the basis of 3-D modelling.Significant variation in m was observed across the plug data set, which is not unexpected in carbonates, but it suggested that a range of fabrics and pore topology were present in these rocks, which are described only as calcirudites. Modelling of the resistivity using 3D pore scale models was used to understand the role of disconnected macro-pores and dissolution seams in controlling the more extreme variation in petrophysical properties observed in the coquinas. This understanding of the controls on resistivity pathways in this outcrop coquina will help in understanding the pore types in the subsurface and the estimation of saturations in these complex rocks where they are found to be oil-bearing.  相似文献   

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