共查询到20条相似文献，搜索用时 46 毫秒
1.
Within the hydrologic balance of the River Arno catchment (northern Tuscany), the Rivers Elsa and Era are important tributaries entering the main river from the left bank in the lower part of the watershed. Waters and bed sediments were sampled in June 2000 during low discharges in the Rivers Elsa and Era, as well as in major tributary streams. Water samples were analysed for major chemistry and sulphur isotope composition of sulphate, and sediment samples were analysed for major composition and selected trace elements of environmental concern (Zn, Cu, Pb, Cr and Ni). The main results for the waters are: (1) Na and Cl in solution show consistent downstream positive trends in the main rivers, thus supporting progressive contributions of anthropogenic salts; the highest concentration values are observed in tributaries; (2) as shown by sulphur isotopes, sulphate in solution is mainly controlled by dissolution of evaporites (Elsa basin) or oxidation of reduced organic/biogenic sulphur (Era basin), with anthropogenic contributions in most streams not higher than 10% in both the basins. A δ34S signature in the range ?2 to +3‰ is estimated for pollutant sulphate in the basins studied. The main results for the sediments are: (1) major chemistry is essentially controlled by the lithotypes drained by the waters; (2) pollution by heavy metals does not reach high levels; (3) compared with local fine‐grained rocks, copper is more frequently anomalous, whereas lead and zinc show only occasional anomalies; (4) local high concentrations of chromium and nickel can be attributed to upstream occurrences of ophiolites. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
2.
Polycyclic aromatic hydrocarbons (PAHs) and organochlorine pesticides (OCPs) were measured in suspended particles and dissolved phase from the Baiertang water column and the Macao water column samples as collected from the Guangzhou channel of the Pearl River and the Macao harbor, where the sediments were heavily contaminated with organic pollutants. Total OCPs concentration varies from 23.4 to 61.7 ng/l in Baiertang water column and from 25.2 to 67.8 ng/l in Macao column, while total PAHs concentration varies from 987.1 to 2878.5 ng/l in the Baiertang water column and from 944.0 to 6654.6 ng/l in the Macao column. The vertical distribution profiles of pollutants and the partition of pollutants between particles and dissolved phases indicate that the sediments in Baiertang act as an important source of selected pollutants, and the pollutants in water of this region were mainly originated from the release and re-suspension of contaminants residing in the sediments. The sediments in Macao harbor act as a reservoir for organochlorine pesticides, such as DDTs mainly introduced by river inflow from Xijiang and PAHs input by brackish water from the Lingdingyang estuary. Combustion of fossil fuels and petroleum input are the main sources of PAHs in the Macao water column, while combustion of fossil fuels and coal is responsible for the PAHs in the Baiertang water column. The ratios of DDT/(DDD+DDE) for the Macao water column samples demonstrate that such chemicals were input into this region in recent times. 相似文献
3.
为了揭示湖库内源性污染物的分布、来源、组成及垂向分布特征,以新建人工深水湖泊龙景湖为研究对象,采用紫外-可见光谱和三维荧光光谱技术,研究了该湖泊以成湖前用途划分的3个特征区域(原河道底部、新淹没区底部和新淹没区边坡)的沉积物上覆水和孔隙水中的溶解性有机质(DOM)的光谱特征.结果表明,孔隙水中的DOM芳香性和腐殖化程度高于上覆水;孔隙水中疏水组分含量大于上覆水,且水体中可能存在内源孔隙水释放的低分子量DOM.龙景湖上覆水和孔隙水中的DOM主要源于水体自身的微生物,自生源特征明显,且可能存在新近释放到水体的有机质.龙景湖沉积物上覆水和孔隙水中的DOM以类腐殖酸和类蛋白质为主,且随着深度增加,类腐殖酸峰强度增强,与龙景湖的建湖背景有明显联系. 相似文献
4.
From 1998 to 2002 investigations were carried out to estimate both the quantity and quality (heavy metal contents) of suspended matter loads discharged into a floodplain area measuring approx. 5 km2 of the Central German river Weiße Elster, a tributary of the river Saale in the Elbe river basin. Flood sediments, suspended particulate matter, and floodplain soils were investigated especially for the main pollutants Cd, Zn, Cu, Pb, Cr, and Hg. Supplementary gamma spectroscopy examinations were performed to help to identify the age of deposits in order to estimate sedimentation rates for last decades. The recent flood sediments are contaminated by up to 33 times the geogenic background (Cd). Up to 55% of the total annual SPM load of the river Weiße Elster is relocated into the investigated retention area in the flood‐stricken year 2002. The sedimentation rates for the last 50 years vary between 0.5 mm/a and 1 mm/a in far away and rarely flooded parts and between 1 mm/a and 2 mm/a in the frequently flooded parts of the inflow of the retention area. 相似文献
5.
The rare earth element compositions of the Changjiang (Yangtze) and Huanghe (Yellow) river sediments 总被引：5，自引：0，他引：5
Thirty-four samples from the Changjiang and Huanghe were analyzed to characterize their rare earth element (REE) compositions. Although REE concentrations in the Changjiang sediments are higher than those of the Huanghe sediments, the former are less variable. Bulk samples and acid-leachable fractions have convex REE patterns and middle REE enrichments relative to upper continental crust, whereas flat patterns are present in the residual fractions. Source rock composition is the primary control on REE composition, and weathering processes play a minor role. Grain size exerts some influence on REE composition, as demonstrated by the higher REE contents of clay minerals in sediments from both rivers. Heavy minerals contribute about 10-20% of the total REE in the sediments. Apatite is rare in the river sediments, and contributes less than 2% of the REE content, but other heavy minerals such as sphene, allanite and zircon are important reservoirs of residual REE fractions. The Fe-Mn oxides phase accounts for about 14% of bulk REE content in the Changjiang sediments, which could be one of the more important factors controlling REE fractionation in the leachable fraction. 相似文献
6.
Immediately after the flood event in summer 1997 at the Odra river, samples of flood sediments were taken for a complex phase analysis. The realized investigations show that the sampled flood sediments are very inhomogeneous. The main reasons for this substantial condition are surely different states of flow during the flood event. It is possible to characterize the investigated material as middle to fine sands with variable phase compositions. The mineral content of the fraction <2 μm shows a complex composition of amorphous matter, quartz, feldspars, and a different composed clay mineral matter. A high distribution of several mixed layers in the clay mineral phase is detectable. Within the scope of the taken analyses the following minerals were detected: kaolinite (disordered), kaolinite/smectite-mixed layer, chlorite/smectite-mixed layer, montmorillonite, illite/smectite-mixed layer, celadonite. The investigation of the heavy fraction shows heavy minerals and heavy particles of different geneses. Mainly these are geogenic, transparent heavy minerals like zircon, amphibole, garnet, pyroxene, apatite, rutile, and epidote. Furthermore there were analysed geogenic, opaque heavy minerals (magnetite and ilmenite), anthropogenic, opaque heavy particles (fly ashes and slags), and biogenic components (pyrite framboids). The substantial character of the investigated flood sediments (e.g. content of organic matter, content of clay minerals) shows that this material is able to act as a fixation medium of contaminants. 相似文献
7.
筑坝拦截对黑河河道沉积物粒度空间分布的影响 总被引：2，自引：1，他引：1
河流沉积物对流域环境变化具有敏感响应,其粒度参数能反映沉积环境中物质来源和水动力环境.本文以黑河流域上中游为研究区域,探究河流沉积物粒度对流域环境变化的响应.从黑河上中游干流22个主要控制断面采集河床沉积物样品,采用筛分法和吸管法对沉积物样品粒度参数进行测定,并分析其空间分布规律对筑坝拦截为主的环境改变响应.研究结果表明：受梯级水库建设影响,黑河上中游泥沙粒径大小差异显著.干流库区泥沙粒径较自然河段明显减小,分选很好,呈正偏或极正偏尖锐分布,而且在库区不同沉积高度上表现出分层沉积特征;坝下游河段因遭受强烈冲刷,较自然河段泥沙粒径粗化显著,分选变差,偏态趋向极正偏,峰态尖锐化;水库回水区受水库壅水及下泄清水的双重制约,泥沙粒度参数介于自然河段和坝下游河段之间,整体分选中等,呈极正偏尖锐分布;沉积环境分析表明,上游支流河段沉积物粒度特征受泥沙供给和物源特征的影响较水动力条件显著,干流河段沉积物粒度特征主要受水动力条件控制.研究结果既符合河流上中游沉积物粒度分布规律,也反映了河流环境变化对沉积物粒度组成的影响. 相似文献
8.
Sediment samples were collected from the lower channel of the Yangtze River and the Yellow River and the contents of rare
earth elements (REEs) were measured. In addition, some historical REEs data were collected from published literatures. Based
on the δ EuN-ΣREEs plot, a clear boundary was found between the sediments from the two rivers. The boundary can be described as an orthogonal
polynomial equation by ordinary linear regression with sediments from the Yangtze River located above the curve and sediments
from the Yellow River located below the curve. To validate this method, the REEs contents of sediments collected from the
estuaries of the Yangtze River and the Yellow River were measured. In addition, the REEs data of sediment Core 255 from the
Yangtze River and Core YA01 from the Yellow River were collected. Results show that the samples from the Yangtze River estuary
and Core 255 almost are above the curve and most samples from the Yellow River estuary and Core YA01 are below the curve in
the δEuN-ΣREEs plot. The plot and the regression equation can be used to distinguish sediments from the Yangtze River and the Yellow
River intuitively and quantitatively, and to trace the sediment provenance of the eastern seas of China. The difference between
the sediments from two rivers in the δEuN-ΣREEs plot is caused by different mineral compositions and regional climate patterns of the source areas. The relationship
between δEuN and ΣREEs is changed little during the transport from the source area to the river, and from river to the sea. Thus the original
information on mineral compositions and climate of the source area was preserved.
Supported by National Natural Science Foundation of China (Grant Nos. 40506016, 40576032, and 90411014) 相似文献
9.
Juan Liu Jin Wang Yongheng Chen Jianying Qi Holger Lippold Chunlin Wang 《洁净——土壤、空气、水》2010,38(10):909-915
Thallium (Tl) is a rare element of high toxicity. Sediments sampled in three representative locations near industries utilizing Tl‐containing raw materials from the Pearl River Basin, China were analyzed for their total Tl contents and the Tl contents in four sequentially extracted fractions (i.e., weak acid exchangeable, reducible, oxidizable, and residual fraction). The results reveal that the total Tl contents (1.25–19.1 µg/g) in the studied sediments were slightly high to quite high compared with those in the Chinese background sediments. This indicates the apparent Tl contamination of the investigated sediments. However, with respect to the chemical fractions, Tl is mainly associated with the residual fraction (>60%) of the sediments, especially of those from the mining area of Tl‐bearing pyrite minerals, indicating the relatively low mobility, and low bioavailability of Tl in these sediments. This obviously contrasts with the previous findings that Tl is mainly entrapped in the first three labile fractions of the contaminated samples. Possible reasons were given for the dominating association of Tl with the residual fraction (>95%) of the mining area sediments. The significant role of certain K‐containing silicates or minerals of these sediments on retaining Tl in the residual fraction, discovered by this study, provides a special field of research opportunity for the Tl‐containing wastewater treatment. 相似文献
10.
Recent developments have opened up the possibilities of using potassium feldspar for dating Pleistocene sediments; a stable (less-fading) part of the infrared stimulated luminescence (IRSL) signal can be selected by largely depleting the unstable part of the IR signal, using a combination of thermal and IR stimulation: post IR-IRSL dating (pIR-IRSL).This study aims to test the validity of pIR-IRSL dating on feldspars. We obtained pIR-IRSL ages on a large suite of samples from several locations in the Netherlands area, covering a wide range of depositional environments and ages. Age control was provided by quartz optically stimulated luminescence (OSL) ages on the same samples; these ages were shown to accord with geological age constraints. Comparison with IRSL ages enabled us to evaluate the improvement that pIR-IRSL dating provides over conventional IRSL methods.The majority of feldspar ages obtained with pIR-IRSL showed good agreement with both the quartz OSL ages and the geological age constraints. Our study demonstrates that pIR-IRSL dating is more robust than conventional IRSL and should be the method of choice in feldspar luminescence dating of Pleistocene sediments. 相似文献
11.
武汉市东湖沉积物重金属与城市污染环境的关系 总被引：2，自引：1，他引：1
应用主成份分析原理,按照主成份提取的信息超过原始信息84％的原则,对武汉市东湖的主体湖区(郭郑湖和塘林湖)的0 cm-7 cm的沉积物30个代表性样品12种元素进行分析,确定其沉积物的重金属的污染源的主要类型．结果表明,郭郑湖第一污染源(占56％)为湖区周围的工业燃煤尘埃,其次(占16％)为交通尾气、生活污水和雨水片流,再次 (占12％)为电镀、印刷等行业的工业污水．塘林湖第一污染源(占65％)为湖区周围的生产性煤燃烧的粉尘,其次(17％) 为生活污水、医院污水和周围土壤的淋溶作用,再次(占9％)为废旧电池、报章杂志和农用物资等．采用均方根综合污染指数法评价分析东湖主体湖区的沉积物的污染程度为轻度污染,其中郭郑湖的污染程度高于塘林湖． 相似文献
12.
Luis de Los Santos Valladares Juan Luis Ccamapaza Renato Arturo Valencia-Bedregal Luis Enrique Borja-Castro Jose Velazquez-Garcia Dehiwalage Harshani Nimalika Perera Adrian Ionescu David Arvidsson Eustace Peregrine Barnes Peter Newton Hugo Lepage Patrick Byrne Angel Guillermo Bustamante Dominguez Crispin H.W.Barnes 《国际泥沙研究》2022,37(6):780-793
This study presents an analysis of sediments in an Andean river impacted by both natural conditions and anthropogenic activities. Fifty samples were collected from selected sites throughout the Moquegua River drainage basin, and Tambo River headwaters at Pasto Grande, in Peru, and analysed with X-ray diffraction, energy dispersive X-ray spectroscopy, scanning electron microscopy, Fourier-transform infrared spectroscopy and thermogravimetric analysis. Si, Ca, Al, Fe, and O, common constituents of... 相似文献
13.
洱海沉积物有色可溶性有机物(CDOM)三维荧光空间分布特性及指示意义 总被引：1，自引：0，他引：1
采用荧光光谱区域体积积分法定量研究洱海沉积物有色可溶性有机物（CDOM）三维荧光空间分布特性,结果表明,洱海沉积物CDOM中类腐殖酸组分占比最高（44.5%~74.2%）,其次为溶解性微生物代谢产物（10.7%~20.4%）和类富里酸物质（8.19%~19.7%）,而类蛋白组分占比最低,类腐殖酸占比与H/C和N/C均呈显著负相关;南部湖心平台区域沉积物类富里酸和类蛋白组分占比较高,其CDOM自生源占比较高;北部水生植物分布区溶解性微生物代谢产物占比较高,CDOM陆源性较强;中部深水区及南北湖湾区域类腐殖酸占比较高,随水深增加沉积物CDOM自生源特征增强.随沉积物深度增加类腐殖酸和溶解性微生物代谢产物占比呈下降趋势,类富里酸占比呈上升趋势,CDOM自生源特征增强,脂肪化程度增高.随湖泊富营养化程度增加沉积物CDOM受微生物代谢产物影响增强,陆源性增加,而自生源性降低,湖泊沉积物CDOM具有富营养化指示意义. 相似文献
14.
S. Santiago R. L. Thomas L. McCarthy J. L. Loizeau G. Larbaigt C. Corvi D. Rossel J. Tarradellas J. P. Vernet 《水文研究》1992,6(2):227-240
Ten large volume water samples were taken from the Rhône River (Switzerland-France) in November, 1989 for recovery of total suspended sediment by continuous flow centrifugation. the samples were freeze-dried and analysed for particle size, organic carbon, total nitrogen, and carbonate. for comparative purposes, four bed sediments collected in July, 1989 are also described. the Rhône can be subdivided into three sections on the basis of the origins of the water. the first section is the Upper Rhône River draining into Lake Geneva. Waters are derived from glaciers, with low temperature and conductivity and high turbidity. Suspended sediment is coarse, has a bimodal distribution, and is low in both organic matter and carbonate. the second reach is from Lake Geneva to the confluence with the Saône at Lyon and has warmer water with higher conductivity and very low turbidity. Suspended sediment is higher in organic matter, with high carbonate originating from the lake. the final section is from Lyon to Arles, with warmer water and higher conductivity and turbidity due to modification by the Saône. Sediment is rich in organic matter, which May, account for an observed decline in oxygen in the river waters downstream from Lyon. Carbonate in these sediments also decreases due to increased turbidity from the Saône. Suspended sediments other than from the Upper Rhône show a remarkable consistency in grain size, predominantly in the fine silts (mode 9-11 μm). This consistency indicates a high degree of suitability for geochemical analysis. Bed sediments were bimodal throughout, with a dominant coarse population in two out of the four samples. Grain size statistical parameters could be easily explained by application of the theory of mixing of two major populations in the sand size (bed traction load) and the fine silt/clay size (suspended sediment load). 相似文献
15.
S. Santiago R. L. Thomas G. Larbaigt C. Corvi D. Rossel J. Tarradellas D. J. Gregor L. McCarthy J. P. Vernet 《Aquatic Sciences - Research Across Boundaries》1994,56(3):220-242
The environmental quality of the Rhone River (Switzerland-France) has been assessed with a geochemical survey of the pollutants bound to suspended sediments. Ten samples were collected between Lake Geneva and the Mediterranean Sea in Nobember 1989 by continuous flow centrifugation and analysed for grain size distribution, carbonate, organic C, N, forms of particulate P, trace metals, and organic compounds (chlorobenzenes, organochlorine pesticides, PCBs, and PAHs). Four bed sediment samples were also studied for comparative purposes. The suspended solids provide lower variance by parameter than the bed sediments and are clearly most suitable for synoptic monitoring.The Upper Rhone River carries a glacial derived sediment with a low nutrient content, the stretch from Geneva to Lyon provides a sediment dominated by carbonate, and in the Lower Rhone the organic matter and phosphorus are relatively increased, mainly due to wastewater effluents and to an industrial P source. High concentrations of metals and organic micropollutants downstream of Lyon indicate a multiple contamination in the Lower Rhone, whereas more specific inputs are located downstream of Geneva and Arles.The comparison with data from other polluted major systems, the Rhine, the Niagara and the Detroit rivers, shows on overall similarity confirming that the Rhone quality is degraded downstream of Lyon. The levels of particular concern are for Hg, DDT metabolites which reveal a recent release in the basin, PCBs with a likely high chlorine content, and PAHs.The statistical evaluation of the compositional variables indicates a limited number of well defined associations, suggesting that the contamination of the suspended sediments results from the combination of numerous and intermittent point and diffuse sources in the Rhone River basin. 相似文献
16.
Modern and known-age Pleistocene fluvial sediments were investigated by optical dating of quartz to test the suitability of the approach for dating deposits from the deeply incised Middle Rhine Valley. Samples from modern flood sediments revealed skewed distributions indicating different residual levels of equivalent dose (De) within the different aliquots. Nevertheless, a substantial number of aliquots from the modern deposits reflect De values close to zero. For the Pleistocene samples, optical ages are in general consistent with age control given by the presence of the Laacher See Tephra and radiocarbon dating. However, some samples overestimate the known age by a few thousand years when using the arithmetic mean. This is apparently explained by including aliquots in the determination of mean De where the optical signal was incompletely bleached at deposition. The most difficult issue in this context is identifying a suitable approach that can distinguish between the variability of De due to partial bleaching and microdosimetry. However, even when considering these limitations it appears that optical dating will by a quite suitable method to date Pleistocene sediments from such a complex fluvial environment, especially when focusing on a precision scale beyond a few thousand years. 相似文献
17.
V. Hatje S.M. Macedo R.M. de Jesus G. Cotrim K.S. Garcia A.F. de Queiroz S.L.C. Ferreira 《Marine pollution bulletin》2010,60(12):2225-2232
The spatial distribution of As (total As, As (III) and As (V)) in estuarine sediments from the main tributaries of Todos os Santos Bay, BA, Brazil, was evaluated under high and low flow conditions. The concentrations of As were determined using a slurry sampling procedure with hydride generation atomic absorption spectrometry (HG-AAS). The highest concentrations were observed at estuary mouths, and exceeded conservative lower threshold value (Threshold Effects Level; TEL). Due to the oxic conditions and abundance of Mn and Fe (oxyhydr)oxides in the sediments, most inorganic arsenic in the Subaé and Paraguaçu estuaries was present as As (V). Nevertheless, the concentration of As (III) at several locations along the Jaguaripe River were also above the TEL value, suggesting that As may be toxic to biota. In the Subaé estuary, antropogenic activities are the main source of As. At the Jaguaripe and at Paraguaçu estuaries, nevertheless, natural sources of As need to be considered to explain the distribution patterns. 相似文献
18.
太湖流域上游东苕溪干流沉积物和悬浮物的氮形态分布及影响因素 总被引：1，自引：0，他引：1
氮是影响和控制水体富营养化的重要因素,不同形态的氮对水体富营养化贡献不同.使用连续提取法对东苕溪干流悬浮物、表层沉积物样品中各形态氮含量进行测定,探讨各形态氮的分布特征及其影响因素.结果表明,东苕溪水体氮污染严重,总氮浓度均值为4.48 mg/L.悬浮物中各形态氮含量均高于沉积物,其中悬浮物中铁锰氧化态氮(IMOF-N)含量所占比例最大,均值为1506.94 mg/kg;沉积物中有机硫化物结合态氮(OSF-N)含量最高,均值为625.31 mg/kg.IMOFN、OSF-N含量受阳离子交换量、粒径影响显著,均与总氮浓度显著相关.相关性分析表明水体的性质对IMOF-N及OSF-N含量影响较显著,并且总体上对悬浮物的影响强于沉积物.另外,悬浮物有助于水体中的氮发生硝化反应向硝态氮转化,沉积物则有助于水体的氮发生还原作用向氨氮转化.在一定程度上,水体中的悬浮物对藻类具有抑制作用. 相似文献
19.
