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1.
Results are presented for gallium in six South African primary rock standards (NIMROCS) and in twelve secondary rock standards (SAROCS). A selective ion exchange procedure is used to separate gallium completely from all other elements, except remaining traces of thorium. It is followed by a determination of gallium with flame atomic absorption spectrometry using the nitrous oxide-acetylene flame, after the addition of 2000 ppm lanthanum as ionization suppressor. 相似文献
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Joyce K. FROST 《Geostandards and Geoanalytical Research》1991,15(1):43-50
Data for as many as 31 elements were determined by instrumental thermal neutron activation analysis for nine European Council for Mutual Economic Assistance (CMEA) rock and ore standards. The National Bureau of Standards plastic clay 98 and the University of Gent fired clay FCG were also analyzed. Synthetic, multielement standards were used and USGS rock standards provided reference samples. Correction factors for uranium fission products on cerium and molybdenum, and also for less commonly encountered spectral interferences, such as those due to the 213 ppm tantalum in granitoid 2B, were evaluated. 相似文献
3.
Results are presented for the determination of trace quantities of cobalt in three South African primary rock standards and in four secondary rock standards. Cohalt is separated from all other elements using a selective ion exchange separation procedure and determined by electrothermal atomic absorption spectrophotometry. 相似文献
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Most trace elements in ultrabasic rock samples are very often present in concentration levels of less than 10 ppm. In these cases, neutron activation analysis (NAA) is very useful. We have applied two different NAA procedures for the determination of 19 trace elements and CaO in two ultrabasic rock standards. Our values are compared with the preferred and published values, although the latter are not very abundant. 相似文献
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The errors in the chemical analyses of a granodiorite rock powder for 6 constituents (K 2O, Na2O, CaO,∑Fe2O3, MgO, and MnO) have been determined by replicate analyses of the whole rock and of a series of different sieved fractions. Sample inhomogeneity is indicated. This is confirmed by analyses of the fused rock powder. Fusion to a glass is therefore recommended for the preparation of geochemical rock standards. 相似文献
6.
同一岩石试样的Lu-Hf和Sm-Nd快速分离及国家岩石标准物质的Hf-Nd同位素比值精确测定 总被引：1，自引：2，他引：1
本文报道基于Li_2B_4O_7熔融样品、采用AG50W-X8和HDEHP组合或RE和HDEHP组合色谱交换柱,对同一岩石试样快速分离Sm-Nd-Lu-Hf的方法。用这两种方法对国际岩石标准BHVO-2、GSP-2和JB-1进行了Lu-Hf、Sm-Nd分离和~(143) Nd/~(144)Nd、~(176)Hf/~(177)Hf测定,并测定了BHVO-2、JB-1和JB-3的Lu/Hf和Sm/Nd比值,获得的结果在误差范围内与这些样品的参考值一致。同时,我们对国家岩石标准物质GBW07109、GBW07110和GBW07113进行了多次平行分析,首次获得了这些岩石标准的Nd-Hf同位素结果。 相似文献
7.
Spectrographic determinations for twenty trace elements in the six new U.S.G.S. silicate rock standards along with the rock standards G-1, W-1, SR-1, GR and BR are given. Most of the results represent the average of triplicate determinations on each of five splits of the portions of the standards available to the authors. Thus, the preferred values represent, in most cases, the average of fifteen replicate determinations. 相似文献
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SIMULTANEOUS DETERMINATION OF THIRTY-SEVEN TRACE ELEMENTS IN TWENTY-EIGHT INTERNATIONAL ROCK STANDARDS BY ICP-MS 总被引：15，自引：0，他引：15
Carl-Dieter GARBE-SCHÖNBERG 《Geostandards and Geoanalytical Research》1993,17(1):81-97
Thirty-seven trace elements, including rare-earth elements, have been determined by ICP-MS in twenty-eight international rock standards using routine sample preparation techniques. Samples were decomposed by either pressurized HF-HCIO4 -aqua regia attack, or by lithium borate fusion. Generally, the ICP-MS data for geological rock standards presented here agree well with certified values. However, the results for light rare earth elements appear to be systematically low in comparison with the published working values. 相似文献
13.
Erik J. Oerter George H Brimhall Jr. Jennifer Redmond Bruce Walker 《Applied Geochemistry》2007,22(12):2907
The abundance of pyrite and other sulfide minerals in mine rock piles is a potentially significant if not a determinative factor in terms of the geochemical and geomechanical evolution of the dumps as oxidation produces acid solutions that drive hydrolysis reactions. A technique is presented here that supports the quantitative determination of pyrite abundance in mine rock dumps by heavy liquid mineral separation to concentrate pyrite for powder X-ray diffraction and then Rietveld method refinement of the diffraction data on a large number of samples using commonly available laboratory equipment. In order to improve and constrain the accuracy of XRD results, binary (pyrite-quartz) and 6-part mineral mixtures (pyrite and rock-forming andesite minerals) spanning a wide range of pyrite concentrations were prepared gravimetrically and run as standards. These standards were then used to minimize errors in pyrite abundance data by constraining key input parameters in the Rietveld refinement. A new polynomial relationship was derived between diffracting crystallite size and the Brindley microabsorption correction input size. This method provides a means to determine uncertainties in pyrite abundance, whereas conventional Rietveld refinement techniques done without the use of standards yield only statistical measures of the least-squares fit, rather than absolute uncertainties in mineral constituent weight percentages. The technique was applied to a number of mine rock pile samples and the uncertainty in the results determined by applying the relationship derived from the 6-part gravimetric standards to the results of the Brindley corrected Rietveld refinements. Uncertainties determined by this method are found to be on the order of ±10% for samples with pyrite content greater than 10 wt% and ±30% for samples with pyrite content less than 10 wt%. In order to evaluate the technique’s improvement upon traditional visual mineral abundance estimation the quantitative results are compared to manual volumetric estimates. 相似文献
14.
Ten U.S. Geological Survey rock standards have been analyzed for trace elements by instrumental neutron activation using a low flux reactor and Ge detectors. Results compare favorably with the current working values for all elements except Mo. REE values that have been determined are generally slightly lower than accepted values. Data obtained for rocks that have very low trace element concentrations (e.g., BIR-1) will aid in refining the working values for these standards. 相似文献
15.
Hisayoshi YURIMOTO Isao SAKAGUCHI Norimasa NISHIDA Shigeho SUENO 《Geostandards and Geoanalytical Research》1991,15(1):155-159
Trace level determination of nickel in silicate rock samples has been achieved using secondary ion mass spectrometry (SIMS) with kinetic energy filtering. Standard rock references, issued by the Geological Survey of Japan, were fused into glass and used as standards for the SIMS analysis. Due to interferences from the glass matrix, the secondary ion of mass 60 was only useful for Ni, although the secondary ion was interfered mainly by CaO+. The contributions of these molecular ions were deconvolved by a least squares regression. Good linear correlation between results after the deconvolution and the Ni concentration in the glass standards was obtained. The uncertainties of the SIMS analysis depend strongly on the degree of contribution of CaO+ molecular ion. Such a method of SIMS analysis is especially useful to study the detailed behavior of Ni on a micro-scale in Ca-poor materials. 相似文献
16.
软岩三轴加-卸载试验的破坏特征及抗压强度取值方法研究 总被引：1，自引：0，他引：1
软岩三轴加、卸载试验中的抗压强度参数取值是一个非常关键的问题,目前还没有比较确定的方法,通常根据经验或工程要求确定。基于此,结合一组砂质泥岩的三轴加、卸载试验进行了详细研究,试验结果表明:(1)当围压大于10 MPa时,不论是三轴加载试验还是卸载试验,砂质泥岩均表现出明显的应变硬化特性;(2)砂质泥岩在三轴压缩和三轴卸荷两种应力路径的力学响应差别明显,在卸荷条件下通常只存在一条完整的剪切破坏面,而压缩条件下岩样没有明显的控制破裂面,并且剪胀效应明显;(3)将半对数法引入到软岩三轴加、卸载试验数据分析中,可以比较方便地确定软岩三轴加、卸载试验的抗压强度;(4)基于三轴加、卸载试验过程中的应力、应变增量分析,将软岩变形破坏过程分为3个阶段:平滑阶段、规则跳跃阶段和急剧跳跃阶段,各阶段划分的意义明确,可以作为抗压强度确定时的重要参考,因此,在软岩三轴试验数据分析时,可以综合采用这两种方法。研究提出的抗压强度确定方法可操作性强,在其他软岩三轴试验数据分析中值得参考借鉴。 相似文献
17.
Robert M. St. LOUIS 《Geostandards and Geoanalytical Research》1987,11(2):151-157
Four mafic USGS rock standards (BHVO-1, BIR-1, DNC-1, BCR-1) were analyzed at three sample sizes (1, 5, and 10 g) for gold by neutron activation analysis subsequent to fire-assay concentration. The results indicate that large samples, in the order of 10 g, are required to produce consistent results, although analyses of variance indicate that sample sizes of 5 g may be used effectively. The analysis of 1 g samples resulted in a large range of values and high standard deviations. BCR-1 was found to be the most homogeneous of the four standards for gold, followed in decreasing order by BIR-1, DNC-1, and BHVO-1. Data for Ir in BIR-1 and DNC-1 are also presented. 相似文献
18.
高盖山隧道岩爆预测采用工程岩体分级标准判别法、Russenes岩爆判别法、Turchaninov岩爆判别法和Hoek岩爆判别法等4种综合评定判别。当硬质脆性岩类隧道埋深小于240 m时,不会产生岩爆;埋深240~368 m时,可能产生轻微岩爆;埋深368~650 m时,会发生中等规模岩爆;埋深大于650 m时会发生较强岩爆。 相似文献
19.
USCS reference sample marine mud MAG-1 has been analyzed for 12 trace elements by flame atomic absorption spectrophotometry (11 elements) and graphite furnace (Cd). Individual and mean values are given and compared to published data. Precision as % coefficient of variation is given and the relative accuracy of the method assessed in relation to established rock standards. 相似文献
20.
Mercury inhomogeneity was found between bottles of the same standard for each of the six U.S.G.S. rock standards tested. Variations between bottles amounted to at least a factor of 2 for four of the six standards. Caution is suggested when using these standards as mercury accuracy checks and as estimators of mercury geochemical abundances or cycles. 相似文献