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1.
The Hegenshan ophiolite in Inner Mongolia is a remnant of oceanic lithosphere of probable Devonian age. The ophiolite consists of several blocks composed chiefly of serpentinized ultramafic rocks with lesser amounts of troctolite and gabbro, and sparse lavas and dikes. The ultramafic rocks consist chiefly of depleted harzburgite and minor dunite and are interpreted as mantle tectonites. In the Hegenshan block dunite is relatively abundant and is typically associated with podiform chromitite. Both the chromite ore and the residual chromites in this body are relatively aluminous with average Cr numbers of 44–54. A few small chromite bodies and some of the residual chromites have much higher Cr numbers (72–76). Several blocks have well-layered cumulate sequences of gabbro and troctolite. Sheeted dikes are absent but small mafic dikes are common in some of the ultramafic sections. Most of the mafic dikes have flat chondrite-normalized REE patterns and are strongly depleted in incompatible elements, similar to depleted tholeiites from immature island arcs. The basaltic lavas of the Hegenshan ophiolite have two distinctly different chemical signatures—one similar to the mafic dikes and one similar to ocean island basalts. The entire complex was probably formed within an island arc–marginal basin system that was later accreted to the southern margin of the Siberian Altaids.  相似文献   

2.
《International Geology Review》2012,54(12):1145-1149
Evidence of “Upper Cretaceous” sediments above the melt rock/breccia assemblage at Chicxulub has been used to dispute the link between this large impact crater and the Cretaceous-Tertiary (KT) extinction horizon. We have evaluated core samples and well logs from the Petróleos Mexicanos (Pemex) Yucatan No. 6 exploratory well located ～50 km from ground zero. Despite previous reports to the contrary, the sequence of crystalline rocks and breccias located at depths exceeding 1000 m below sea level are characteristic of the upper lithological sequence observed at other large impact basins such as the 220 km Sudbury structure. Furthermore, the “Upper Cretaceous” sediments overlying the melt rocks and impact brecias at Chicxulub contain abundant glass shards and shocked minerals, demonstrating conclusively that these are reworked debris involved in the impact event, and not normal marine sediments. Core samples straddling the KT boundary indicate that the impact event created a basin several hundred meters deep.  相似文献   

3.
Spinellids showing unmixed intergrowths of chromite or chromian spinel (sensu stricto) and magnetite or chromian magnetite are not known in mafic or ultramafic igneous rocks. They do occur within metamorphosed rocks that attained temperatures sufficiently high (upper amphibolite facies) for the formation of homogeneous Al-Cr-Fe3+-Ti spinel phases with compositions not matched in slowly cooled igneous rocks. In the Tugela Rand intrusion complex intergrowths of chromian spinel, chromian magnetite, ulvöspinel, ilmenite and a transparent aluminous spinel are observed and interpreted in terms of the thermal history of the rocks. Compositional differences between the separate areas of chromian spinel and chromian magnetite in complex intergrowths exhibited by the metamorphosed Tugela Rand and Mambulu Complexes confirm the extension of the magnetite-hercynite solvus (Turnock and Eugster 1962) towards magnesium- and chromium-rich compositions. The Tugela Rand spinellids are compared with those from the Carr Boyd Complex (Purvis et al. 1972) and the ultramafic rocks of the Giant Nickel Mine (Muir and Naldrett 1973) and the Red Lodge district (Loferski and Lipin 1983). Significant differences between the spinels from the Red Lodge district compared to the other three occurrences may reflect the different metamorphic histories of these areas.  相似文献   

4.
Criteria allowing diagnostic identification of asteroid and comet impact fallout units (impactites), including fragmental ejecta, microtektites and microkrystite spherules (impact vapour condensates) comprise: (i) unique mineral fallout phases—shocked quartz grains, coesite and nano-diamonds; (ii) unique intra-microkrystite phases—Ni-chromite, Ni-nanonuggets and Ir-nanonuggets, condensed from vapour enriched in meteoritic components; (iii) geochemical features such as high abundance and unique ratios of the platinum group (PGE) and other siderophile elements (Ni, Co); (iv) meteoritic isotopic ratios including ε53Cr (53Cr/52Cr), ε54Cr (54Cr/52Cr), ε182W (182W/183W) or (182W/184W), εOs (187Os/188Os), ε17O (17O/16O), ε18O (18O/16O); and (v) cometary seeding of 3He/4He and racemic organic molecules (AIB) and possibly fullerenes (C60). Relic nickel chromites and metasomatically derived sulfides may contain PGE nanonuggets. Alteration, burial metamorphism and open-system mobility of uranium in hydrous terrestrial environments renders preservation of meteoritic ε207Pb (207Pb/204Pb) and ε206Pb (206Pb/204Pb) values unlikely. Where least affected, PGE patterns of microkrystites and microtektite-bearing impact fallout units (impactites) are the reverse of terrestrial PGE patterns, including low Pd/Pt ratios, which provide some of the more readily identified and analytically practical criteria for identifying a meteoritic component. εCr?–?εCr relations in Barberton Greenstone Belt impact fallout units (3.26?–?3.24 Ga) identify a carbonaceous chondrite composition of the parental asteroids. PGE abundances (Ir, Pt) and εCr isotope values allow mass-balance estimates of parental projectiles in the order of 20?–?30 km diameter. Ir and Pt mass-balance estimates correspond to projectiles ～20 km in diameter or larger in the Pilbara Craton for the JIL (>?2.63 Ga) and DGS4 (2.5?–?2.47 Ga) impact fallout units. The Ni, Co and Cr enriched composition of most Precambrian microkrystite spherules militates for mafic/ultramafic target crust which, coupled with the estimated diameter of the ensuing craters, implies the existence of maria-scale impact basins in oceanic-type crustal regions during the Archaean and Palaeoproterozoic.  相似文献   

5.
Petrological, geochemical and radiogenic isotopic data on ophiolitic‐type rocks from the Marlborough terrane, the largest (～700 km2) ultramafic‐mafic rock association in eastern Australia, argue strongly for a sea‐floor spreading centre origin. Chromium spinel from partially serpentinised mantle harzburgite record average Cr/(Cr + Al) = 0.4 with associated mafic rocks displaying depleted MORB‐like trace‐element characteristics. A Sm/Nd isochron defined by whole‐rock mafic samples yields a crystallisation age of 562 ± 22 Ma (2σ). These rocks are thus amongst the oldest rocks so far identified in the New England Fold Belt and suggest the presence of a late Neoproterozoic ocean basin to the east of the Tasman Line. The next oldest ultramafic rock association dated from the New England Fold Belt is ca530 Ma and is interpreted as backarc in origin. These data suggest that the New England Fold Belt may have developed on oceanic crust, following an oceanward migration of the subduction zone at ca540 Ma as recorded by deformation and metamorphism in the Anakie Inlier. Fragments of late Neoproterozoic oceanic lithosphere were accreted during progressive cratonisation of the east Australian margin.  相似文献   

6.
Aeromagnetic data of the Anti-Atlas Mountains show an important magnetic anomaly along the ‘Major Anti-Atlas Fault’, produced by different mafic and ultramafic rocks of a Neoproterozoic ophiolite complex. The magnetic modelling of Bou Azzer–El Graara ophiolitic suture shows a deep-seated anomaly through the upper continental crust corresponding to a north-dipping subduction. The polarity of the Pan-African subduction in the Anti-Atlas is therefore compatible with the contemporaneous Pan-African orogenic belts, where polarity of subduction dipped away from the West African Craton during the amalgamation of Western Gondwana. To cite this article: A. Soulaimani et al., C. R. Geoscience 338 (2006).  相似文献   

7.
This work presents isotopic data for the non-traditional isotope systems Fe, Cu, and Zn on a set of Chicxulub impactites and target lithologies with the aim of better documenting the dynamic processes taking place during hypervelocity impact events, as well as those affecting impact structures during the post-impact phase. The focus lies on material from the recent IODP-ICDP Expedition 364 Hole M0077A drill core obtained from the offshore Chicxulub peak ring. Two ejecta blanket samples from the UNAM 5 and 7 cores were used to compare the crater lithologies with those outside of the impact structure. The datasets of bulk Fe, Cu, and Zn isotope ratios are coupled with petrographic observations and bulk major and trace element compositions to disentangle equilibrium isotope fractionation effects from kinetic processes. The observed Fe and Cu isotopic signatures, with δ56/54Fe ranging from ?0.95‰ to 0.58‰ and δ65/63Cu from ?0.73‰ to 0.14‰, mostly reflect felsic, mafic, and carbonate target lithology mixing and secondary sulfide mineral formation, the latter associated to the extensive and long-lived (>105 years) hydrothermal system within Chicxulub structure. On the other hand, the stable Zn isotope ratios provide evidence for volatility-governed isotopic fractionation. The heavier Zn isotopic compositions observed for the uppermost part of the impactite sequence and a metamorphic clast (δ66/64Zn of up to 0.80‰ and 0.87‰, respectively) relative to most basement lithologies and impact melt rock units indicate partial vaporization of Zn, comparable to what has been observed for Cretaceous-Paleogene boundary layer sediments around the world, as well as for tektites from various strewn fields. In contrast to previous work, our data indicate that an isotopically light Zn reservoir (δ66/64Zn down to ?0.49‰), of which the existence has previously been suggested based on mass balance considerations, may reside within the upper impact melt rock (UIM) unit. This observation is restricted to a few UIM samples only and cannot be extended to other target or impact melt rock units. Light isotopic signatures of moderately volatile elements in tektites and microtektites have previously been linked to (back-)condensation under distinct kinetic regimes. Although some of the signatures observed may have been partially overprinted during post-impact processes, our bulk data confirm impact volatilization and condensation of Zn, which may be even more pronounced at the microscale, with variable degrees of mixing between isotopically distinct reservoirs, not only at proximal to distal ejecta sites, but also within the lithologies associated with the Chicxulub impact crater.  相似文献   

8.
The mineralized sublayer at the base of the Sudbury Igneous Complex (SIC) consists of two variants, the noritic contact sublayer and radial and concentric quartz dioritic offset dykes. Both are characterized by the presence of significant quantities of Ni–Cu–PGE sulphides and by a prominent population of recrystallized diabasic-textured and melanocratic to ultramafic fragments. The two variants of the sublayer contain compositionally distinct inclusion populations and inclusion-bearing matrices. Contact sublayer and offset dykes hosted by north range granitoid footwall can be distinguished from those hosted by south range basaltic and metasedimentary footwall environments. The compositional variation in SIC rocks can be described in terms of contributions from exposed crustal rocks and differentiation of the resultant melt(s).

The basaltic inclusion population is characterized by hornfels recrystallization of the plagioclase, and is geochemically and isotopically identified with Huronian basalts which comprise the south range footwall, with (Ce/Yb)N ratios of around 2.5 and Nd1850 between −2 to −5. The melanocratic inclusions in the sublayer are typically coarse-grained and undeformed, with incompatible element contents and radiogenic isotopic compositions intermediate between those of the basaltic inclusions and those of the melt sheet, which has (Ce/Yb)N ratios of around 10 and Nd1850 around −9. Calculated crystallization models are consistent with derivation of the ultramafic inclusions by crystallization from a magma produced by mixing of molten basaltic footwall with basal melt sheet. It is proposed that the sublayer appeared as the marginal facies of a meteorite impact melt sheet as a result of footwall melting following the impact. This basal layer was progressively enriched in sulphides and mafic cumulates from above through differentiation during cooling. Offset dykes were emplaced and the magmas effectively removed from the system. Subsequently, continued evolution of the marginal facies produced the more mafic inclusions in the contact sublayer. No extracrustal (e.g., mantle) component is envisioned in this model to explain the silicate compositional distributions in the SIC, and mafic crustal rocks in the target zone are implicated as the metal source for the SIC deposits.  相似文献   


9.
阿拉善地块北缘晚中生代(晚侏罗世-早白垩世)时期发育有广阔的伸展盆地体系,其形成可能与陆内伸展作用有关。本文首次在阿拉善地块西北缘北大山陶来地区识别出一套晚侏罗世镁铁质-超镁铁质岩,对其进行系统的岩石学、年代学和地球化学研究,从而为该地区陆内伸展提供岩浆作用方面的证据。LA-ICP-MS锆石U-Pb定年结果表明,北大山陶来地区角闪辉长岩形成时代为155.7±4.6Ma(MSWD=1.5),即晚侏罗世。角闪辉长岩显示出高铝基性岩的地化特征,如低SiO 2(48.0%~52.5%),高Al 2O 3(15.3%~18.2%)、MgO(8.78%~10.6%)和CaO(12.8%~16.7%)。此外,它们还显示出高的Mg#(72~82)、Cr(295×10^(-6)~960×10^(-6))和Ni(97.4×10^(-6)~186×10^(-6)),N-MORB型和平坦的HREE配分形式、Eu正异常,较高的Nb/La比值,这些都表明其可能为软流圈地幔减压熔融产生的原始岩浆与壳幔过渡带中含斜长石堆晶岩相互作用后分离结晶的产物。富铝和富钙源区以及岩浆中高的水含量抑制斜长石早期成核与生长共同控制了高铝角闪辉长岩的形成。辉长岩表现出N-MORB型全岩地球化学特征和板内成因岩浆锆石特征(高Nb/Hf及低Hf/Th、Th/Nb),均揭示了阿拉善西北缘陶来地区晚侏罗世镁铁质-超镁铁质岩体是板内岩石圈伸展作用的产物。在古亚洲洋最终碰撞闭合后伸展基础上,蒙古-鄂霍茨克洋闭合与古太平洋俯冲后撤叠加作用引发了岩石圈伸展,并沿中亚造山带南缘多个古生代缝合带产出了194~124Ma多期镁铁质-超镁铁质岩。  相似文献   

10.
The geodynamic setting of the Xigaze ophiolite has long been debated. Structural and geochemical evidence suggest the Xigaze ophiolite was formed at a slow‐spreading ridge (Nicolas et al., 1981; Liu et al., 2016). Based on incompatible element concentrations, the Xigaze ophiolite volcanics are consistent with the ubiquitous subduction signature in suprasubduction zone (Bedard et al., 2009; Hebert et al., 2012; Dai et al., 2013). It is noteworthy that the Xigaze ophiolite is different from the Geotimes and Lasail and Velly units from Oman ophiolite, respectively. The mafic rocks of the Xigaze ophiolite generally resemble typical N‐MORB and Geotimes volcanics in composition except for slight depletions of Th and Nb (Fig.1a). Although the Xigaze rocks have similar Th and Nb concentrations to Lasail and Velly rocks, most incompatible elements in the Xigaze rocks are comparable to N‐MORB. Petrography in gabbro of Xigaze ophiolite shows that euhedral plagioclases are enclosed by clinopyroxenes suggesting that these minerals have crystallized from an anhydrous magma (Sisson and Grove, 1993). Although the Xigaze volcanic rocks are slightly depleted in Th and Nb, they have MORB‐like trace element characteristics implying that they are derived from an anhydrous MORB magma at spreading centre. Godard et al. (2006) suggested that the mantle source of the Oman ophiolite have element and isotopic characteristics similar to Indian Ocean MORB, where the mantle preserved some older slab materials. A negative Nb anomaly of Oman Geotimes volcanic rocks may be resulted from contamination of the slab materials via decompression melting of the convecting mantle. Moreover, the Xigaze rocks have 1.27–3.18 of (Th/Nb)N ratios similar with those of Geotimes volcanics ((Th/Nb)N =0.51–2.77) and lower than those of Lasail and Velly units ((Th/Nb)N =2.12–6.35). These features suggest that the Xigaze ophiolite may have formed at the spreading centre.  相似文献   

11.
天然富勒烯的地质产状与成因   总被引：2，自引：2，他引：0  
天然富勒烯研究是富勒烯科学和地质科学相交叉的一个新兴研究领域,迄今为止已在桑加岩、闪电熔岩、陨石撞击坑中的含碳质角砾岩、古近系/白垩系地层界线(E/K)的含碳粘土岩、三叠系/二叠系(T/P)界线岩石(粘土岩、硅质岩)、恐龙蛋壳、煤、重质油、固体沥青以及半天然的烟灰、木炭、书墨等物质中检测到富勒烯的存在,但含量很低。多数天然富勒烯的地质分布、成因机制与陨石撞击、野火、闪电等有关,但部分天然富勒烯的成因尚不清楚。天然富勒烯研究扩展了人们对自然界碳结构及其演化的认识,在地质事件、事件地层如陨石撞击事件、E/K界线、T/P界线等的研究中充分显示了其独特的方法和应用价值。  相似文献   

12.
The Neoproterozoic Ougda magmatic complex occurs within platformal carbonate rocks in the western part of the Pan-African fold belt of the Tuareg shield (NW Africa). It is composed of - 800 Ma old, relatively high P-T (i.e., Grt + Cpx-bearing: P > 5 kbar; T≈900'Q, tholeiitic mafic/ultramafic cumulates and related rocks intruded by intermediate to mafic calcalkali plutons (e.g., Cpx+Hbl-bearing gabbro) and dikes. Apparent contrasts in structural level of crystallization indicate that the calc-alkali rocks are significantly younger than the tholeiites, which temporally correlate with a period of regional extension in this part of Africa. Intrusion of the calc-alkali rocks may have occurred during the formation of an arc after the tholeiitic rocks had been (diapirically?) emplaced within the shelf carbonates, and prior to (> 630 Ma) the Pan-African orogeny. Data reported herein indicate that the Ougda complex records the inception and demise of a Neoproterozoic ocean basin. Similar crustal sections have been described from collisional (e.g., Aleutian islands) and extensional (e.g., Ivreä-Verbano zone) settings, indicating that processes operating in both environments can generate nearly indistinguishable igneous suites; the prevalence of shallow-level calc-alkali rocks in both settings may mask the presence of more mafic, tholeiitic rocks at depth.  相似文献   

13.
青山群火山岩是华北克拉通破坏期间最具代表性的地幔或地壳熔融产物,记录了华北深部地质演化的重要信息。本文对胶东青山群基性火山岩进行了40Ar/39Ar定年和岩石地球化学分析,结合前人报道的胶东青山群酸性火山岩资料,发现:(1)基性火山岩喷发年龄为122～113Ma,早于青山群酸性火山岩(110～98Ma);(2)基性和酸性火山岩显示了不同的元素和同位素地球化学特征。岩石成因分析表明,基性火山岩为交代富集地幔部分熔融作用的产物,而酸性火山岩为古老下地壳和中生代底侵岩浆的熔融产物(Ling et al.,2009)。因此,胶东地区青山群火山岩记录了岩浆熔融源区从地幔向下地壳的转变。这与长时间尺度的岩石圈减薄过程中热能由地幔向地壳传递过程相吻合,而不同于地壳拆沉作用所预测的岩浆演化趋势。  相似文献   

14.
Evidence of mafic and ultramafic magmatism exists in many parts of the Dharwar craton which is divided into two blocks, the West Dharwar Craton (WDC) and the East Dharwar Craton (EDC). The mafic-ultramafic rocks occur in supracrustal/greenstone belts and in numerous enclaves and slivers in the WDC. The oldest recorded maficultramafic rocks, which are mainly komatiitic in nature, are preserved in the Sargur Group which is more than 3.3–3.4 Ga old, the youngest being manifested by 63–76 Ma old mafic dyke magmatism, possibly related to Deccan volcanism. In the Sargur Group, ultramafics rocks greatly dominate over mafic lithological units. Both extrusive and intrusive varieties, the latter in the form of differentiated layered complexes, occur. Mafic volcanics exists in all the greenstone belts of the eastern block and in the Bababudan and Western Ghats belts of the western block. In addition to the Sargur Group where stratigraphic sequences are unclear, mafic magmatism is recorded in three different formations of the Bababudan Group and two sub-divisions of the Shimoga and Chitradurga Groups where basaltic flows are conspicuous. In the well studied greenstone belts of Kolar and Hutti in the EDC, three to four different Formations of mafic volcanic rocks have been mapped. Isotopic dating has indicated that while mafic magmatism in the greenstone belts of the EDC covers only a short time span of between 2.65 to 2.75 Ga, those in the Dharwar Supergroup of the WDC cover a much longer time span from 3.35 to 2.5 Ga. Mafic dyke magmatism has taken place repeatedly from 2.45 Ga to about 1.0 Ga, but, the peak of emplacement was between 1.8 and 1.4 Ga when the densely developed swarms on the western and south western portions of the Cuddapah Basin and in the central part of Karnataka, were intruded. Emplacement of potassic ultramafic magma in the form of kimberlite-lamproite which is confined to the EDC, is a later magmatic event that took place between 1.4 Ga and 0.8 Ga. From a mineralization perspective, mafic magmatism of the supracrustal groups of the WDC and the greenstone belts of the EDC are the most important. V-Ti-magnetite bands constitute the most common deposit type recorded in the mafic-ultramafic complexes of the Sargur Group with commercially exploitable chromite deposits occurring in a number of belts. PGE mineralization of possible commercial value has so far been recorded in a single mafic-ultramafic complex, while copper-nickel mineralization occurs at certain localities in the Sargur and Chitradurga Groups. Gold mineralization hosted by mafic (occasionally ultramafic) rocks has been noted in many of the old workings located in supracrustal groups of rocks in the WDC and in the greenstone belts of EDC. Economically exploitable mineralization, however, occurs mainly in the greenstone belts of the Kolar, Ramagiri-Penkacherla and Hutti-Maski and along the eastern margin of the Chitradurga belt, where it is associated with a major N-S striking thrust zone separating the WDC from the EDC. Gold deposits of the eastern greenstone belts are comparable to those of the younger greenstone belts of Canada, Zimbabwe and Australia where the mineralization is associated with quartz carbonate veins often in iron-rich metabasic rocks. The gold was emplaced as hydrothermal fluids, derived from early komatiitic and tholeiitic magmas, and injected into suitable dilatent structures. The other common type of mineralization associated with the ultramafic rocks of the Sargur Group and supracrustal belts, particularly of the WDC, are asbestos and soapstone, related to autometamorphism/metasomatism. Ruby/sapphire deposits occur in places at the contacts of ultramafic rocks with the Peninsular Gneiss, and are related to contact metamorphism and metasomatism. Mineable magnesite deposits related to low-temperature hydrothermal/lateritic alteration exist in the zone of weathering, particularly in the more olivine-rich rocks. Recent spurt in diamond exploration is offering promise of discovering economically workable diamondiferous kimberlite/lamproite intrusions in the EDC.  相似文献   

15.
Systematic variations in 54Cr/52Cr ratios between meteorite classes ( [Trinquier et al., 2007] and [Qin et al., 2010a]) point to large scale spatial and/or temporal isotopic heterogeneity in the solar protoplanetary disk. Two explanations for these variations have been proposed, with important implications for the formation of the Solar System: heterogeneous seeding of the disk with dust from a supernova, or energetic-particle irradiation of dust in the disk. The key to differentiating between them is identification of the carrier(s) of the 54Cr anomalies. Here we report the results of our recent NanoSIMS imaging search for the 54Cr-rich carrier in the acid-resistant residue of the CI chondrite Orgueil. A total of 10 regions with extreme 54Cr-excesses (δ54Cr values up to 1500‰) were found. Comparison between SEM, Auger and NanoSIMS analyses showed that these 54Cr-rich regions are associated with one or more sub-micron (typically less than 200 nm) Cr oxide grains, most likely spinels. Because the size of the NanoSIMS primary O− ion beam is larger than the typical grain size on the sample mount, the measured anomalies are lower limits, and we estimate that the actual 54Cr enrichments in three grains are at least 11 times Solar and in one of these may be as high as 50 times Solar. Such compositions strongly favor a Type II supernova origin. The variability in bulk 54Cr/52Cr between meteorite classes argues for a heterogeneous distribution of the 54Cr carrier in the solar protoplanetary disk following a late supernova injection event. Such a scenario is also supported by the O-isotopic distribution and variable abundances in different planetary materials of other presolar oxide and silicate grains from supernovae.  相似文献   

16.
Contributors to chromium isotope variation of meteorites   总被引：3，自引：0，他引：3  
We report the results of a comprehensive, high precision survey of the Cr isotopic compositions of primitive chondrites, along with some differentiated meteorites. To ensure complete dissolution of our samples, they were first fused with lithium borate-tetraborate at 1050-1000 °C. Relative to the NIST Cr standard SRM 3112a, carbonaceous chondrites exhibit excesses in 54Cr/52Cr from 0.4 to 1.6ε (1ε = 1 part in 10,000), and ordinary chondrites display a common 54Cr/52Cr deficit of ∼0.4ε. Analyses of acid-digestion residues of chondrites show that carbonaceous and ordinary chondrites share a common 54Cr-enriched carrier, which is characterized by a large excess in 54Cr/52Cr (up to 200ε) associated with a very small deficit in 53Cr/52Cr (<2ε). We did not find 54Cr anomalies in either bulk enstatite chondrites or in leachates of their acid-digestion residues. This either requires that the enstatite chondrite parent bodies did not incorporate the 54Cr anomaly carrier phase during their accretion, or the phase was destroyed by parent body metamorphism. Chromium in the terrestrial rocks and lunar samples analyzed here show no deviation from the NIST SRM 3112a Cr standard. The eucrite and Martian meteorites studied exhibit small deficits in 54Cr/52Cr. The 54Cr/52Cr variations among different meteorite classes suggest that there was a spatial and/or temporal heterogeneity in the distribution of a 54Cr-rich component in the inner Solar System.We confirm the correlated excesses in 54Cr/52Cr and 53Cr/52Cr for bulk carbonaceous chondrites, but the new data yield a steeper slope (∼6.6) than that reported in Shukolyukov and Lugmair (2006). The correlated excesses may affect the use of the Mn-Cr chronometer in carbonaceous chondrites. We could not confirm the bulk carbonaceous chondrite Mn-Cr isochron reported by Shukolyukov and Lugmair (2006) and Moynier et al. (2007), mostly because we find much smaller total variations in ε53Cr (∼0.2). All bulk chondrites have small ε53Cr excesses (up to 0.3) relative to the Earth, most likely reflecting the sub-chondritic Mn/Cr ratio of the Earth. The ε53Cr variations in chondrites do seem to grossly correlate with Mn/Cr and yield an initial Solar System 53Mn/55Mn value of 5.4(±2.4) × 10−6, corresponding to an absolute age of 4566.4 (±2.2) Ma.Nuclear interactions with cosmic rays result in coupled excesses in ε54Cr and ε53Cr with a ∼4:1 ratio in phases with high Fe/Cr. These are most dramatically demonstrated in the iron meteorite Carbo, showing excesses in ε54Cr of up to 140ε. These new results show that the Mn-Cr chronometer should be used with caution in samples/minerals with high Fe/Cr and long cosmic ray exposure ages.  相似文献   

17.
A banded amphibolite sequence of alternating ultramafic, mafic (amphibolite) and silicic layers, tectonically enclosed within Variscan migmatites, outcrops at Monte Plebi (NE Sardinia) and shows similarities with leptyno-amphibolite complexes. The ultramafic layers consist of amphibole (75–98%), garnet (0–20%), opaque minerals (1–5%) and biotite (0–3%). The mafic rocks are made up of amphibole (65–80%), plagioclase (15–30%), quartz (0–15%), opaque minerals (2–3%) and biotite (0–2%). The silicic layers consist of plagioclase (60–75%), amphibole (15–30%) and quartz (10–15%). Alteration, metasomatic, metamorphic and hydrothermal processes did not significantly modify the original protolith chemistry, as proved by a lack of K2O-enrichment, Rb-enrichment, CaO-depletion, MgO-depletion and by no shift in the rare earth element (REE) patterns. Field, geochemical and isotopic data suggest that ultramafic, mafic and silicic layers represent repeated sequences of cumulates, basic and acidic rocks similar to macrorhythmic units of mafic silicic layered intrusions. The ultramafic layers recall the evolved cumulates of Skaergaard and Pleasant Bay mafic silicic layered intrusions. Mafic layers resemble Thingmuli tholeiites and chilled Pleasant Bay mafic rocks. Silicic layers with Na2O: 4–6 wt%, SiO2: 67–71 wt% were likely oligoclase-rich adcumulates common in many mafic silicic layered intrusions. Some amphibolite showing a strong Ti-, P-depletion and REE-depletion are interpreted as early cumulates nearly devoid of ilmenite and phosphates. All Monte Plebi rocks have extremely low Nb, Ta, Zr, Hf content and high LILE/HFSE ratios, a feature inherited from the original mantle sources. The mafic and ultramafic layers show slight and strong LREE enrichment respectively. Most mafic layer samples plot in the field of continental tholeiites in the TiO2–K2O–P2O5 diagram and are completely different from N-MORB, E-MORB and T-MORB as regards REE patterns and Nd, Sr isotope ratios but show analogies with Siberian, Deccan and proto-Atlantic rift tholeiites. Comparisons with Thingmuli, Skaergaard and Kiglapait rocks and with experimental data suggest that the Monte Plebi intrusion was an open-to-oxygen system with fO2 FMQ. Mafic and ultramafic samples yielded Nd(460)=+0.79 /+3.06 and 87Sr/86Sr=0.702934–0.703426, and four silicic samples Nd(460)=–0.53/–1.13; 87Sr/86Sr=0.703239–0.703653. Significant differences in Nd isotope ratios between mafic and silicic rocks prove that both groups evolved separately in deeper magma chambers, from different mantle sources, with negligible interaction with crustal material, and were later repeatedly injected within a shallower magma chamber. The spectrum of Sr and Nd isotope data is consistent with a slightly enriched mantle metasomatized during an event earlier than 460 Ma. The metasomatising component was represented by alkali-Th-rich fluids of crustal origin rather than by sedimentary materials, able to modify alkali and Sr–Nd isotope systematics. Monte Plebi layered amphibolites might represent the first example of a strongly metamorphosed fragment of an early Paleozoic mafic silicic layered intrusion emplaced in a thinning continental crust and then tectonically dismembered by Variscan orogeny.  相似文献   

18.
A regional soil and sediment geochemical study in northern California   总被引：7，自引：7，他引：0  
Regional-scale variations in soil geochemistry were investigated in a 20,000-km2 study area in northern California that includes the western slope of the Sierra Nevada, the southern Sacramento Valley and the northern Coast Ranges. Over 1300 archival soil samples collected from the late 1970s to 1980 in El Dorado, Placer, Sutter, Sacramento, Yolo and Solano counties were analyzed for 42 elements by inductively coupled plasma-atomic emission spectrometry and inductively coupled plasma-mass spectrometry following a near-total dissolution. These data were supplemented by analysis of more than 500 stream-sediment samples from higher elevations in the Sierra Nevada from the same study site. The relatively high-density data (1 sample per 15 km2 for much of the study area) allows the delineation of regional geochemical patterns and the identification of processes that produced these patterns. The geochemical results segregate broadly into distinct element groupings whose distribution reflects the interplay of geologic, hydrologic, geomorphic and anthropogenic factors. One such group includes elements associated with mafic and ultramafic rocks including Cr, Ni, V, Co, Cu and Mg. Using Cr as an example, elevated concentrations occur in soils overlying ultramafic rocks in the foothills of the Sierra Nevada (median Cr = 160 mg/kg) as well as in the northern Coast Ranges. Low concentrations of these elements occur in soils located further upslope in the Sierra Nevada overlying Tertiary volcanic, metasedimentary and plutonic rocks (granodiorite and diorite). Eastern Sacramento Valley soil samples, defined as those located east of the Sacramento River, are lower in Cr (median Cr = 84 mg/kg), and are systematically lower in this suite compared to soils from the west side of the Sacramento Valley (median Cr = 130 mg/kg). A second group of elements showing a coherent pattern, including Ca, K, Sr and REE, is derived from relatively silicic rocks types. This group occurs at elevated concentrations in soils overlying volcanic and plutonic rocks at higher elevations in the Sierras (e.g. median La = 28 mg/kg) and the east side of the Sacramento Valley (median 20 mg/kg) compared to soils overlying ultramafic rocks in the Sierra Nevada foothills (median 15 mg/kg) and the western Sacramento Valley (median 14 mg/kg). The segregation of soil geochemistry into distinctive groupings across the Sacramento River arises from the former presence of a natural levee (now replaced by an artificial one) along the banks of the river. This levee has been a barrier to sediment transport. Sediment transport to the Valley by glacial outwash from higher elevations in the Sierra Nevada and, more recently, debris from placer Au mining has dominated sediment transport to the eastern Valley. High content of mafic elements (and low content of silicic elements) in surface soil in the west side of the valley is due to a combination of lack of silicic source rocks, transport of ultramafic rock material from the Coast Ranges, and input of sediment from the late Mesozoic Great Valley Group, which is itself enriched in mafic elements. A third group of elements (Zn, Cd, As and Cu) reflect the impact of mining activity. Soil with elevated content of these elements occurs along the Sacramento River in both levee and adjacent flood basin settings. It is interpreted that transport of sediment down the Sacramento River from massive sulfide mines in the Klamath Mountains to the north has caused this pattern. The Pb, and to some extent Zn, distribution patterns are strongly impacted by anthropogenic inputs. Elevated Pb content is localized in major cites and along major highways due to inputs from leaded gasoline. Zinc has a similar distribution pattern but the source is tire wear.  相似文献   

19.
The Thetford Mines complex is a complete ophiolite which is part of an ultramafic-mafic belt within Québec Appalachians. These allochtonous bodies were emplaced during the Early Ordovician. The Thetford Mines complex comprises a lower unit of metamorphic harzburgite (in which tabular, dyke-like, dunitic bodies occur) overlain successively by ultramafic cumulates, mafic cumulates, ophitic gabbros, diabase sills and dykes, and basaltic volcanic rocks. Field evidence, petrography and chemical data indicate that the tabular dunitic bodies formed when fractures in the metamorphic harzburgite (which constituted the floor of the magma chamber) filled with early cumulates (i.e., olivine±chromite). Representative rocks from all units were analyzed for major and rare earth elements (REE). Metamorphic harzburgite samples from Thetford Mines complex have U-shaped chondrite-normalized REE patterns. Pyroxenites and wehrlites of the cumulate sequence are all strongly light-REE depleted and have heavy REE ranging from 0.4 to 1.5 times chondrite. REE data from ultramafic and volcanic rocks of Thetford Mines complex and geochemical modelling indicate that the metamorphic harzburgite has the chemical characteristics of depleted upper mantle residues with U-shaped patterns, and that the ultramafic cumulates crystallized from magmas having different La/Yb ratios.  相似文献   

20.
The Jacurici Complex, located in the NE part of the São Francisco Craton, hosts the largest chromite deposit in Brazil. The mineralized intrusion is considered to be a single N-S elongated layered body, disrupted into many segments by subsequent deformation. The ore is hosted in a thick, massive layer. Two segments, Ipueira and Medrado, have been previously studied. We provide new geological information, and chromite composition results from the Monte Alegre Sul and Várzea do Macaco segments located farther north, and integrate these with previous results. The aim of this study is to determine and discuss the magma chamber process that could explain the formation of the thick chromitite layer. All segments exhibit similar stratigraphic successions with an ultramafic zone (250 m thick) hosting a 5–8 m thick main chromitite layer (MCL), and a mafic zone (40 m thick). The chromite composition of the MCL, Mg-numbers (0.48–0.72) and Cr-numbers (0.59–0.68), is similar to chromites from layered intrusions and other thick chromitites. Previous work concluded that the parental magma of the mineralized intrusion was very primitive based on olivine composition (up to Fo93) and orthopyroxene composition (up to En94) from harzburgite samples, and that it originated from an old subcontinental lithospheric mantle. We estimate that the melt from which the massive chromitite layer crystallized was similar to a boninite, or low siliceous high-Mg basalt, with a higher Fe/Mg ratio. The petrologic evidence from the mafic-ultramafic rocks suggests that a high volume of magma flowed through the sill, which acted as a dynamic conduit. Crustal contamination has previously been considered as the trigger for the chromite crystallization, based on isotope studies, as the more radiogenic signatures correlate with an increase in the volumetric percentage of amphibole (up to 20%). The abundant inclusions of hydrous silicate phases in the chromites from the massive ore suggest that the magma was hydrated during chromite crystallization. Fluids may have played an important role in the chromite formation and/or accumulation. However, the trigger for chromite crystallization remains debatable. The anomalous thickness of the chromitite is a difficult feature to explain. We suggest a combined model where chromite crystallized along the margins of the magma conduit, producing a semi-consolidated chromite slurry that slumped through the conduit forming a thick chromitite layer in the magma chamber where layered ultramafic rocks were previously formed. Subsequently, the conduit was obstructed and the resident magma fractionated to produce a more evolved composition.  相似文献   

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