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1.
The present study is on the aerosol optical and radiative properties in the short-wave radiation and its climate implications at the arid city of Abu Dhabi (24.42 °N, 54.61 °E, 4.5 m MSL), in the United Arab Emirates. The direct aerosol radiative forcings (ARF) in the short-wave region at the top (TOA) and bottom of the atmosphere (BOA) are estimated using a hybrid approach, making use of discrete ordinate radiative transfer method in conjunction with the short-wave flux and spectral aerosol optical depth (AOD) measurements, over a period of 3 years (June 2012–July 2015), at Abu Dhabi located at the south-west coast of the Arabian Gulf. The inferred microphysical properties of aerosols at the measurement site indicate strong seasonal variations from the dominance of coarse mode mineral dust aerosols during spring (March–May) and summer (June–September), to the abundance of fine/accumulation mode aerosols mainly from combustion of fossil-fuel and bio-fuel during autumn (October–November) and winter (December–February) seasons. The monthly mean diurnally averaged ARF at the BOA (TOA) varies from ?13.2 Wm?2 (～?0.96 Wm?2) in November to ?39.4 Wm?2 (?11.4 Wm?2) in August with higher magnitudes of the forcing values during spring/summer seasons and lower values during autumn/winter seasons. The atmospheric aerosol forcing varies from + 12.2 Wm?2 (November) to 28.2 Wm?2 (June) with higher values throughout the spring and summer seasons, suggesting the importance of mineral dust aerosols towards the solar dimming. Seasonally, highest values of the forcing efficiency at the surface are observed in spring (?85.0 ± 4.1 W m?2 τ ?1) followed closely by winter (?79.2 ± 7.1 W m?2 τ ?1) and the lowest values during autumn season (?54 ± 4.3 W m?2 τ ?1). The study concludes with the variations of the atmospheric heating rates induced by the forcing. Highest heating rate is observed in June (0.39 K day ?1) and the lowest in November (0.17 K day ?1) and the temporal variability of this parameter is linearly associated with the aerosol absorption index.  相似文献   

2.
E. N. Kairu 《GeoJournal》1993,29(4):351-358
This paper discusses the results of an experiment whereby all the major radiation and energy fluxes were measured/estimated for a mature tea canopy at Kericho, Kenya. The fluxes include incoming short-wave radiation, terrestrial radiation, latent heat flux and the sensible heat fluxes between the canopy and the air and that into and out of the soil. The pertinent data were simultaneously collected by use of 21X microloggers. Global radiation varied from 40 Wm–2 to 1160 Wm–2 depending on sky conditions. High values were observed early in the morning and late in the afternoon. Net radiation varied between — 100 Wm–2 at night and 600 Wm–2during the daytime. The largest proportion of net radiation was consumed by the latent heat flux. Advection was found to be minimal.  相似文献   

3.
《地学前缘(英文版)》2020,11(5):1755-1761
Thermal conductivity(k) of iron is measured up to about 134 GPa.The measurements are carried out using the single sided laser heated diamond anvil cell,where the power absorbed by a Fe metal foil at hotspot is calculated using a novel thermodynamical method.Thermal conductivity of fee(γ)-Fe increases up to a pressure of about46 GPa.We find thermal conductivity values in the range of 70-80 Wm~(-1)K~(-1)(with an uncertainty of 40%),almost constant with pressure,in the hcp(e) phase of Fe.We attribute the pressure independent k above 46 GPa to the strong electronic correlation effects driven by the electronic topological transition(ETT).We predict a value of thermal conductivity of ε-Fe of about 40±16 Wm~(-1)K~(-1) at the outer core of Earth.  相似文献   

4.

A 22-member ensemble from CMIP6 is used to analyze the projected changes and seasonal behavior in surface air temperature over South America during the twenty-first century. In the future projections, CMIP6 models shown a high dependency to the socioeconomic pathway over each country of South America. The multimodel ensemble projects a continuous increase in the annual mean temperature over South America during the twenty-first century under the three future scenarios (SSP1-2.6, SSP2-4.5 and SSP5-8.5). Besides, it was possible to identify consistent positive trends across all the models, with values between 0.45 ± 0.05 and 2.05 ± 0.31 °C cy−1 under the historical experiment, however largest trends occurs for the projection periods (near, mid and far future), with values between − 0.87 ± 0.84 to 2.88 ± 0.60 °C cy−1 (SSP1-2.6), 1.41 ± 0.88 to 5.32 ± 0.81 °C cy−1 (SSP2-4.5) and 4.75 ± 0.58 to 8.76 ± 0.74 °C cy−1 (SSP5-8.5) with maximum values at Bolivia, Brasil, Paraguay and Venezuela whilst minimum values for Argentina and Uruguay, regardless of the SSP scenario used. From the seasonal behavior analysis was possible to identify maximum values between January and March whilst minimum between June and July, except in Brasil, Venezuela and Guyana–Surinam–French Guayana, with annual range decreasing as the latidude decreases. By the end of the twenty-first century the annual mean temperature over South america is projected to increase between 0.92–2.11 °C, 0.97–3.37 °C and 1.27–6.14 °C under SSP1-2.6, SSP2-4.5 and SSP5-8.5 projection scenarios respectively. This projected increase of temperature across the continent will produce negative repercussions in the social, economic and political spheres. The results obtained in this study provide insights about the CMIP6 performance over this region, which can be used to develop adaptation strategies and might be useful for the adaptation to the climate change.

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5.
Celestite solubility measurements have been conducted in pure water at temperatures from 10 to 90°C. Equilibrium was achieved with respect to a crystalline solid phase from both undersaturated and supersaturated solutions. The measurements show that the solubility undergoes a maximum near 20°C. LogK values for the solubility reaction are adequately described by the following expression over the temperature range 283.15 to 363.15 K: −logK= −35.3106+0.00422837T+318312/T2+14.99586 logT.The following thennodynamic values for the dissolution reaction of SrSO4(s), at 25°C have been derived: ΔGR0 = 37852 ± 30 Jmol−1ΔHR0 = −1668±920Jmol−1ΔSR0= −132.6±3.2JK−1mol−1Celestite solubility measurements were also determined in NaCl solutions up to 5 m concentration and from 10 to 40°C. These data are in good agreement with the work of StrÜbel (1966), who reports solubility measurements to temperatures of 100°C.The application of the Pitzer relations and the solubility constants determined in this study to calculate celestite solubility in NaCl solutions yields excellent agreement between predicted values and experimental measurements over the entire range of temperature and NaCl concentration conditions. For the limited number of solubility measurements in seawater-type solutions and mixed-salt brines, the agreement using the Pitzer relations is within three percent of the measured solubility.  相似文献   

6.
Methods have been developed for solution calorimetry of hydrous phases in molten lead borate near 700°C. These involve thermochemical cycles using dissolution and decomposition reactions of hydrous silicates and hydroxides. Preliminary results suggest that H2O derived from the decomposition of hydroxides dissolves in molten 2PbO-B2O3 with an exothermic enthalpy of solution of −5.7 ±0.7 kcal mol−1. Hydroxyphologopite persists metastably at 714°C and its heat of solution in 2PbO·B2O3 has been measured. From these new data, the standard enthalpy of formation of phlogopite from the elements at 25°C is −1485.5 ±1.5 kcal mol−1. The standard free energy of formation is -1394.6 ±1.5 kcal mol−1, assuming complete tetrahedral Al-Si disorder.Two structural features complicate the thermodynamics of synthetic and natural micas. The first is a varying degree of tetrahedral Al-Si disorder. Raman spectroscopic study of phlogopite synthesized above 600°C suggests a disordered Al-Si distribution. Calculations of the P-T locus of the geologically important equilibrium: Phl + 3Qtz = 3En + Sa + H2O, using our thermochemical data, agree within experimental error with the results of calculations based on the best available phase equilibrium data only if a tetrahedrally disordered phlogopite is assumed. Such calculations are very sensitive to uncertainties in ΔH° and ΔG°, and reversed phase equilibrium experiments remain essential to obtaining reliable estimates of thermodynamic properties. In contrast to these Al-Si disordered phlogopites, some biotites of low temperature parageneses (<600°C) may have substantial Al-Si order. A variable Al-Si distribution has a substantial effect on the configurational entropy and therefore on the free energy of the mica in question. Because of these and other questions, applications of biotite equilibria to determining volatile fugacities in igneous and metamorphic petrogenesis are subject to large uncertainties.The second structural complication is stacking disorder, which is present in phlogopite synthesized at 650°C but not in the 850°C sample. The enthalpy difference between these two samples, determined by solution calorimetry, is smaller than the experimental uncertainty of ±1.0 kcal mol−1. Thus there appears to be little driving force for ordering, and micas with disordered stacking sequences may persist in many geologic environments. The effect of stacking disorder on thermodynamic properties is probably very small.  相似文献   

7.
《Geochimica et cosmochimica acta》1999,63(13-14):1969-1980
The solubility of ettringite (Ca6[Al(OH)6]2(SO4)3 · 26H2O) was measured in a series of dissolution and precipitation experiments at 5–75°C and at pH between 10.5 and 13.0 using synthesized material. Equilibrium was established within 4 to 6 days, with samples collected between 10 and 36 days. The log KSP for the reaction Ca6[Al(OH)6]2(SO4)3 · 26H2O ⇌ 6Ca2+ + 2Al(OH)4− + 3SO42− + 4OH− + 26H2O at 25°C calculated for dissolution experiments (−45.0 ± 0.2) is not significantly different from the log KSP calculated for precipitation experiments (−44.8 ± 0.4) at the 95% confidence level. There is no apparent trend in log KSP with pH and the mean log KSP,298 is −44.9 ± 0.3. The solubility product decreased linearly with the inverse of temperature indicating a constant enthalpy of reaction from 5 to 75°C. The enthalpy and entropy of reaction ΔH°r and ΔS°r, were determined from the linear regression to be 204.6 ± 0.6 kJ mol−1 and 170 ± 38 J mol−1 K−1. Using our values for log KSP, ΔH°r, and ΔS°r and published partial molal quantities for the constituent ions, we calculated the free energy of formation ΔG°f,298, the enthalpy of formation ΔH°f,298, and the entropy of formation ΔS°f,298 to be −15211 ± 20, −17550 ± 16 kJ mol−1, and 1867 ± 59 J mol−1 K−1. Assuming ΔCP,r is zero, the heat capacity of ettringite is 590 ± 140 J mol−1 K−1.  相似文献   

8.
《Applied Geochemistry》1998,13(6):707-714
The properties of fluorapatite, both a useful radiochronometer and a potential storage matrix specific for minor actinides produced by the reprocessing of spent nuclear fuel, have been investigated with emphasis to its response to alpha decay. Exfoliation, which occurs after implantation of high doses of 1.6-MeV He-ions (>1.4×1017 ions cm−2, corresponding to 5% atomic proportion), could set an upper limit to the concentration of imbedded actinides (about 2 atoms % corresponding to 20 wt. %) or storage age unless significant diffusion of radiogenic He intervenes. This process has been studied by combining He implantation, thermal treatments in the temperature range 124–250°C and measurement of the resulting He profile by an ion beam technique (ERDA) using 8.5-MeV C ions. The diffusion coefficient follows an Arrhenius' law with an activation energy of 120 (±2) KJ/mole and a frequency factor of 14.5 (±7)×10−3 cm2 sec−1 in agreement with literature data. The inferred closure temperature which validates the U,Th–He radiochronological method also fits previous values: 97 (±10)°C for grain size 165 μm. With respect to radwaste disposal. He volume diffusion is too small to exclude the occurrence of exfoliation unless diffusion at grain boundary is much higher and a fine-grain matrix is deliberately chosen.  相似文献   

9.
Measurements taken between July 2006 to May 2007 at the Maqu station in the Upper Yellow River area were used to study the surface radiation budget and soil water and heat content in this area. These data revealed distinct seasonal variations in downward shortwave radiation, downward longwave radiation, upward longwave radiation and net radiation, with larger values in the summer than in winter because of solar altitudinal angle. The upward shortwave radiation factor is not obvious because of albedo (or snow). Surface albedo in the summer was lower than in the winter and was directly associated with soil moisture and solar altitudinal angle. The annual averaged albedo was 0.26. Soil heat flux, soil temperature and soil water content changed substantially with time and depth. The soil temperature gradient was positive from August to February and was related to the surface net radiation and the heat condition of the soil itself. There was a negative correlation between soil temperature gradient and net radiation, and the correlation coefficient achieved a significance level of 0.01. Because of frozen state of the soil, the maximum soil thermal conductivity value was 1.21 W m−1°C−1 in January 2007. In May 2007, soil thermal conductivity was 0.23 W m−1°C−1, which is the lowest value measured in the study, likely due to the fact that the soil was drier then than in other months. The soil thermal conductivity values for the four seasons were 0.27, 0.38, 0.55 and 0.83 W m−1°C−1, respectively.  相似文献   

10.
《Applied Geochemistry》2000,15(8):1203-1218
Ca6[Al(OH)6]2(CrO4)3·26H2O, the chromate analog of the sulfate mineral ettringite, was synthesized and characterized by X-ray diffraction, Fourier transform infra-red spectroscopy, thermogravimetric analyses, energy dispersive X-ray spectrometry, and bulk chemical analyses. The solubility of the synthesized solid was measured in a series of dissolution and precipitation experiments conducted at 5–75°C and at initial pH values between 10.5 and 12.5. The ion activity product (IAP) for the reaction Ca6[Al(OH)6]2(CrO4)3·26H2O⇌6Ca2++2Al(OH)−4+3CrO2−4+4OH−+26H2O varies with pH unless a CaCrO4(aq) complex is included in the speciation model. The log K for the formation of this complex by the reaction Ca2++CrO2−4=CaCrO4(aq) was obtained by minimizing the variance in the IAP for Ca6[Al(OH)6]2(CrO4)3·26H2O. There is no significant trend in the formation constant with temperature and the average log K is 2.77±0.16 over the temperature range 5–75°C. The log solubility product (log KSP) of Ca6[Al(OH)6]2(CrO4)3·26H2O at 25°C is −41.46±0.30. The temperature dependence of the log KSP is log KSP=A−B/T+D log(T) where A=498.94±48.99, B=27,499±2257, and D=−181.11±16.74. The values of ΔG0r,298 and ΔH0r,298 for the dissolution reaction are 236.6±3.9 and 77.5±2.4 kJ mol−1. the values of ΔC0P,r,298 and ΔS0r,298 are −1506±140 and −534±83 J mol−1 K−1. Using these values and published standard state partial molal quantities for constituent ions, ΔG0f,298=−15,131±19 kJ mol−1, ΔH0f,298=−17,330±8.6 kJ mol−1, ΔS0298=2.19±0.10 kJ mol−1 K−1, and ΔC0Pf,298=2.12±0.53 kJ mol−1 K−1, were calculated.  相似文献   

11.
Variability of the ocean surface boundary layer characteristics on daily time-scale is studied utilizing the 3-hourly hydrographic data collected at a stationary location (20°N, 89°E) in the Bay of Bengal during August (18th–31st) and September (9th–19th), 1990 under MONTBLEX-90 field programme. The daily variations of temperature, salinity, σ0, mixed layer thickness, stability, heat content and rate of change of heat content in the upper 100 m are discussed in relation to prevailing weather (depressions) and hydrographic conditions (influx of fresh water, presence of eddies). The mixed layer thickness is examined through temperatureand σ0-based criteria considering also the surface salinity in the latter. TheT-based mixed layer thickness is always higher than that of σ0-based thickness. The rate of change of heat content is also computed up to the depth of 20°C and 14°C isotherms which takes into account the vertical motion and hence divergence. With the development of a low into a deep depression close to the study area, intense upwelling of subsurface cold waters is noticed from 100 m to the bottom of the surface mixed layer (20m) from 18th to 20th August. The upwelling is weakened by 21st August when the depression moved away from the study location. This variation of upwelling is supported by the variation of surface mixed layer thickness, static stability at 30 m depth, heat content in the upper 100 m and the heat content up to the depth of 20°C isotherm from 18th to 21st August. The rate of change of heat content in the upper 100 m and up to the depths of 20°C and 14°C isotherms leads to net heat storage during August and to net heat depletion during September. This together with the net surface heat gain lead to an import (197Wm?2) and export (233 Wm?2) of heat during August and September respectively through horizontal advective processes. These advective processes are attributed to the presence and movement of a warm core eddy through the study location.  相似文献   

12.
《Applied Geochemistry》2004,19(6):835-841
Experiments on dissolution kinetics of galena were performed in 1 mol l−1 NaCl solutions at pH 0.43–2.45 and 25–75 °C. When the dissolution reaction is far from equilibrium, a linear relation exits between the dissolution rate, r, and the H+ ion activity, [H+]. The rate law for galena dissolution is given by the following equation: r=k[H+]. With respect to H+, the dissolution reaction is in the first order. The apparent rate constant, k, has values of 2.34×10−7 mol m−2 s−1 at 25 °C, 1.38×10−6 mol m−2 s−1 at 50 °C, and 7.08×10−6 mol m−2 s−1 at 75 °C. The activation energy of dissolution reaction is 43.54 kJ mol−1. The mechanism of dissolution is suggested to be surface chemical reaction, and the rate determining step is the dissociation of the Pb–S bond of the surface complex, which releases Pb2+ into the solution.  相似文献   

13.
The Kaiparowits Formation contains an exceptionally rich history of tectonic, climatic, and biologic conditions within the Western Interior of North America during the Campanian. Here we reconstruct aspects of the southern Cordilleran foreland basin's paleohydrology using δ18O and δ13C values determined from unionoid bivalve shells and pedogenic carbonate nodules derived from a suite of lithofacies associations. Unionoid shells derived from fluvial deposits display average water δ18O estimates of −13.7‰ ± 2.1 (1σ) (VSMOW) and shell δ13C values of −4.0‰ ± 1.5 (VPDB), whereas pedogenic carbonate nodules display average values of −6.0‰ ± 0.5 and −8.7‰ ± 0.8, respectively. Unionoid shells derived from pond deposits fall in between the two other environments with average values of −9.5‰ ± 1.8 and −5.7‰ ± 2.1, in δ18O and δ13C values respectively. Water δ18O estimates are interpreted to represent high altitude runoff within river systems, low elevation precipitation within the basin onto floodplain soils, and varying degrees of mixing between these two components within floodplain ponds. δ13C values track the isotopic composition of dissolved inorganic carbon within river, soil, and pond waters with high values likely reflecting greater contribution from chemically weathered marine carbonates exposed in the hinterland and lower values reflecting greater contributions from the in situ degradation of plant matter. Up-section there is a shift to lower δ18O values and higher δ13C values in fluvially-derived unionoid shells that post-dates an incursion of the Western Interior Seaway, but coincides with a shift in sediment provenance, an increase in basin sedimentation rates, and a change to a more anastomosed-style channel morphology within the basin foredeep depocentre. By combining the isotopic patterns with previously published sedimentologic, climate model, and paleofloral records we find: 1) additional evidence for humid, wet, and potentially monsoonal conditions within the region, 2) support for a tectonic uplift event, potentially related to Laramide deformation, and 3) greater aggradation and overbank flooding within the alluvial system in response to the uplift event.  相似文献   

14.
《Applied Geochemistry》2005,20(5):961-972
The temperature dependence of the self-diffusion of HTO, 22Na+ and 36Cl− in Opalinus Clay (OPA) was studied using a through-diffusion technique, in which the temperature was gradually increased in the steady state phase of the diffusion. The measurements were done on samples from two different geological locations. The dependence of the effective diffusion coefficient on temperature was found to be of an Arrhenius type in the temperature range between 0 and 70 °C. A slight difference between the two locations could be observed. The average value of the activation energy of the self-diffusion of HTO in OPA was 21.1 ± 1.6 kJ mol−1, and 21.0 ± 3.5 and 19.4 ± 1.5 kJ mol−1 for 22Na+ and 36Cl−, respectively. The measured values for HTO are slightly higher than the values found for the bulk liquid water (HTO: 18.8 ± 0.4 kJ mol−1). This indicates that the structure of the confined water in OPA might be slightly different from that of bulk liquid water. Also for Na+ and Cl−, slightly higher values than in bulk liquid water (Na+: 18.4 kJ mol−1; Cl−: 17.4 kJ mol−1) were observed.The Stokes–Einstein relationship, based on the temperature dependency of the viscosity of bulk water, could not be used to describe the temperature dependence of the diffusion of HTO in OPA. This additionally indicates the slightly different structure of the pore water in OPA.  相似文献   

15.
《Geochimica et cosmochimica acta》1999,63(19-20):3417-3427
In order to verify Fe control by solution - mineral equilibria, soil solutions were sampled in hydromorphic soils on granites and shales, where the occurrence of Green Rusts had been demonstrated by Mössbauer and Raman spectroscopies. Eh and pH were measured in situ, and Fe(II) analyzed by colorimetry. Ionic Activity Products were computed from aqueous Fe(II) rather than total Fe in an attempt to avoid overestimation by including colloidal particles. Solid phases considered are Fe(II) and Fe(III) hydroxides and oxides, and the Green Rusts whose general formula is [FeII1−xFeIIIx(OH)2]+x· [x/z A−z]−x, where compensating interlayer anions, A−, can be Cl−, SO42−, CO32− or OH−, and where x ranges a priori from 0 to 1. In large ranges of variation of pH, pe and Fe(II) concentration, soil solutions are (i) oversaturated with respect to Fe(III) oxides; (ii) undersaturated with respect to Fe(II) oxides, chloride-, sulphate- and carbonate-Green Rusts; (iii) in equilibrium with hydroxy-Green Rusts, i.e., Fe(II)-Fe(III) mixed hydroxides. The ratios, x = Fe(III)/Fet, derived from the best fits for equilibrium between minerals and soil solutions are 1/3, 1/2 and 2/3, depending on the sampling site, and are in every case identical to the same ratios directly measured by Mössbauer spectroscopy. This implies reversible equilibrium between Green Rust and solution. Solubility products are proposed for the various hydroxy-Green Rusts as follows: log Ksp = 28.2 ± 0.8 for the reaction Fe3(OH)7 + e− + 7 H+ = 3 Fe2+ + 7 H2O; log Ksp = 25.4 ± 0.7 for the reaction Fe2(OH)5 + e− + 5 H+ = 2 Fe2+ + 5 H2O; log Ksp = 45.8 ± 0.9 for the reaction Fe3(OH)8 + 2e− + 8 H+ = 3 Fe2+ + 8 H2O at an average temperature of 9 ± 1°C, and 1 atm. pressure. Tentative values for the Gibbs free energies of formation of hydroxy-Green Rusts obtained are: ΔfG° (Fe3(OH)7, cr, 282.15 K) = −1799.7 ± 6 kJ mol−1, ΔfG° (Fe2(OH)5, cr, 282.15 K) = −1244.1 ± 6 kJ mol−1 and ΔfG° (Fe3(OH)8, cr, 282.15 K) = −1944.3 ± 6 kJ mol−1.  相似文献   

16.
This study describes time series analysis of snow-melt, radiation data and energy balance for a seasonal snow cover at Dhundi field station of SASE, which lies in Pir Panjal range of the N-W Himalaya, for a winter season from 13 January to 12 April 2005. The analysis shows that mean snow surface temperature remains very close to the melting temperature of snow. It was found close to −1°C for the complete observational period which makes the snow pack at Dhundi moist from its beginning. The average air temperature over this period was found to be 3.5°C with hourly average variation from −5.5°C to 13°C. The snow surface at this station received a mean short wave radiation of 430W m−2, out of which 298W m−2 was reflected back by the snow surface with mean albedo value of 0.70. The high average temperature and more absorption of solar radiation resulted in higher thermal state of the snowpack which was further responsible for faster and higher densification of the snowpack. Net radiation energy was the major component of surface energy budget with a mean value of 83W m−2. Bulk transfer model was used to calculate turbulent fluxes. The net energy was utilized for satisfying cold content and snow-melt by using measured snow surface temperature and density of snow pack. The mean square error between calculated and measured daily snow-melt was found to be approximately 6.6mm of water equivalent.  相似文献   

17.
《Applied Geochemistry》2003,18(10):1653-1662
The through- and out-diffusion of HTO, 36Cl− and 125I− in Opalinus Clay, an argillaceous rock from the northern part of Switzerland, was studied under different confining pressures between 4 and 15 MPa. The direction of diffusion and the confining pressure were perpendicular to the bedding. Confining pressure had only a small effect on diffusion. An increase in pressure from 4 to 15 MPa resulted in a decrease of the effective diffusion coefficient of ∼20%. Diffusion accessible porosities were not measurably affected. The values of the effective diffusion coefficients, De, ranged between (5.6±0.4)×10−12 and (6.7±0.4)×10−12 m2 s−1 for HTO, (7.1±0.5)×10−13 and (9.1±0.6)×10−13 m2 s−1 for 36Cl− and (4.5±0.3)×10−13 and (6.6±0.4)×10−13 m2 s−1 for 125I−. The rock capacity factors, α, measured were circa 0.14 for HTO, 0.040 for 36Cl− and 0.080 for 125I−. Because of anion exclusion effects, anions diffuse slower and exhibit smaller diffusion accessible porosities than the uncharged HTO. Unlike 36Cl−, 125I− sorbs weakly on Opalinus Clay resulting in a larger rock capacity factor. The sorption coefficient, Kd, for 125I− is of the order of 1–2×10−5 m3 kg−1. The effective diffusion coefficient for HTO is in good agreement with values measured in other sedimentary rocks and can be related to the porosity using Archie's Law with exponent m=2.5.  相似文献   

18.
We present the results of new multicolor photometry of the chromospherically active binary CG Cyg acquired in 2005–2009 (136 hours of observations). The light curves for each season reveal rotational brightness modulation due to spots that varies in amplitude and phase from season to season. We have determined the longitudes of spotted areas: for each season, they were located on the primary, close to the line joining the centers of the components. The longitude distribution of spots was analyzed for 44 years of observations of CG Cyg using all data available in the literature. The active longitudes of CG Cyg are not fixed at the quadratures, as was believed earlier: most of the time (1965–2003), the spots were concentrated at two active longitudes at the quadratures, at orbital phases 0.28±0.06 and 0.70±0.08, but, during a shorter time after 2004, they were located along the line joining the component centers, at orbital phases 0.50 ± 0.04 and 0.93 ± 0.03. We detected a switch of the active longitude by 180° during 1.5 months in 2008, accompanied by an increase in the amplitude of the rotational brightness modulation and only a slight increase in the star’s spotted area (by 5%). Our analysis of archive data reveals that switches of the active longitude during time intervals of 1–1.5 months were observed three times during the entire observational history of CG Cyg (in 1991, as well as in our observations of 2003 and 2008). All these switches were accompanied by similar phenomena: an increase in the amplitude of the rotational brightness modulation (by 0.06 m , 0.02 m , and 0.04 m ) and an increase in the spotted area (by 79%, 11%, and 5%). We used a zonal spot model to reconstruct the parameters of the spotted regions on CG Cyg. At all our observing epochs, the spots were located at low latitudes, in a region that was symmetric about the equator, 10° to 14° wide on either side. The spots are cooler than the surrounding photosphere by 2000 K. The spotted area varied only slightly from season to season, comprising 13%–15% of the surface area of the star, close to the historic spottedness maximum for the CG Cyg system.  相似文献   

19.
Benthic fluxes in two southern California borderland basins have been estimated by modeling water column property gradients, by modeling pore water gradients and by measuring changes in concentration in a benthic chamber. Results have been used to compare the different methods, to establish budgets for biogenic silica and carbon and to estimate rate constants for models of CaCO3 dissolution. In San Pedro Basin, a low oxygen, high sedimentation rate area, fluxes of radon-222 (86 ± 8 atoms m−2 s−1), SiO2 (0.7 ± 0.1 mmol m−2 d−1), alkalinity (1.7 ± 0.3 meq m−2 d−1), TCO2 (1.9 ± 0.3 mmol m−2 d−1) and nitrate (−0.8 ± 0.1 mmol m−2 d−1) measured in a benthic chamber agree within the measurement uncertainty with fluxes estimated from modeling profiles of nutrients and radon obtained in the water column. The diffusive fluxes of radon, SiO2 and TCO2 determined from modeling the sediment and pore water also agree with the other approaches. Approximately 33 ± 13% of the organic carbon and 37 ± 47% of the CaCO3 arriving at the sea floor are recycled. In San Nicolas Basin, which has larger oxygen concentrations and lower sedimentation rates than San Pedro, the fluxes of radon (490 ± 16 atoms m−2 s−1), SiO2 (0.7 ± 0.1 mmol m−2 d−1), alkalinity (1.7 ± 0.3 meq m−2 d−1), TCO2 (1.7 ± 0.2 mmol m−2 d−1), oxygen (−0.7 ± 0.1 mmol m−2 d−1) and nitrate (-0.4 ± 0.1 mmol m−2 d−1) determined from chamber measurements agree with the water column estimates given the uncertainty of the measurements and model estimates. Diffusion from the sediments matches the lander-measured SiO2 and PO43− (0.017 ± 0.002 mmol m−2 d−1) fluxes, but is not sufficient to supply the radon or TCO2 fluxes observed with the lander. In San Nicolas Basin 38 ± 9% of the organic carbon and 43 ± 22% of the CaCO3 are recycled. Approximately 90% of the biogenic silica arriving at the sea floor in each basin is recycled. The rates of CaCO3 dissolution determined from chamber flux measurements and material balances for protons and electrons are compared to those predicted by previously published models of CaCO3 dissolution and this comparison indicates that in situ rates are comparable to those observed in laboratory studies of bulk sediments, but orders of magnitude less than those observed in experiments done with suspended sediments.  相似文献   

20.
New data are presented on the distribution of oxygen isotopes and conditions of the local isotope equilibrium in high-Al rocks rocks of Khitostrov Island showing abnormally low δ18O values (below–25‰). The temperatures of isotope equilibrium are within 400–475°C. The minimum δ18O values have been registered in the in plagioclase, whereas the same phases in kyanite-bearing rocks lacking corundum demonstrate δ18O values usually 3–5‰ higher. The fluid δ18O value varies from–22 to–16‰ at 475 ± 15°C, from–18 to–23‰ at 425 ± 25°C, and from–17 to–22‰ at 380 ± 15°C. The results obtained do not require abnormal depletion of δ18O values owing to the infiltration of an external fluid under the Svecofennian transformations. The association of corundum-bearing rocks with the basic intrusions, the presence of zircon cores of older ages compared to these rocks, and the peculiarities of rock chemistry may be ascribed to the fact that lower crustal layers of ancient rocks depleted in δ18O before metamorphism were captured by basite melts.  相似文献   

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