Soil carbon dioxide and weathering potentials in tropical karst terrain,peninsular Malaysia: A preliminary model     

J. Crowther 《地球表面变化过程与地形》1984,9(5):397-407

CO₂ concentrations at depths of 15,30, and 50 cm were determined over a one-year period in six karst soils in the Malay peninsula. Evidence suggests that the highest single CO₂ value (MAXCO₂, per cent) recorded at each site/depth provides the best estimate of conditions during groundwater recharge events. Soil depth (cm) and bulk density (BDEN) are the best predictors of MAXCO₂, with the equation loglo(MAXCO₂) = 1·146 (BDEN) + 0·00698 (DEPTH) - 1·227 accounting for 86 per cent of the variation. This equation is used to model MAXCO₂ at seven, more remote sites. Soil throughflow patterns and groundwater recharge points are estimated from slope pantometer and soil depth surveys in order to assess the CO₂ concentration with which soil waters ultimately equilibrate before entering the limestone. Limestone weathering seems to be predominantly of the open system type, the overall mean MAXCO₂ of 1·65 per cent corresponding with a weathering potential of 167 ppm CaCO₃. Weathering potentials vary markedly, ranging from 62–82 ppm on rocky hilltops to more than 280 ppm on certain tower karst footslopes in Selangor and the Kinta Valley and on moderate hillslopes developed in impure limestones in the Boundary Range.  相似文献   

A world model of soil carbon dioxide     

George A. Brook  Michael E. Folkoff  Elgene O. Box 《地球表面变化过程与地形》1983,8(1):79-88

Mean growing season soil PCO₂ data were obtained for 19 regions of the world in nine countries. Bivariate and multiple linear regression analysis with soil log(PCO₂) as the dependent variable and TEMP, PRECIP, log(AET), and log(PET) as the four climatic independent variables demonstrated that AET was the best independent predictor of soil PCO₂. An improved soil PCO₂-AET model was developed by assuming (1) that as AET approaches zero, soil PCO₂ approaches the atmospheric value and (2) that there is an upper limit to soil PCO₂ at very high AET. This model has the form log(PCO₂) = ?3·47 + 2·09 (1 ?e^{?0·0172 AET}) where AET is in mm. It explains 67 per cent of the initial variation in the soil PCO₂ data, predicts a soil log(PCO₂) of ? 3·47 at AET = 0, and an upper limit of 3·5 per cent (log(PCO₂) = ? 1·45) for mean growing season soil PCO₂ at AET values of 2000 mm and above. The results of this study suggest that soil PCO₂ levels in tropical areas are, on average, higher than those in temperate, alpine, and arctic regions.  相似文献   

Effect of intensity and duration of freezing on soil microbial biomass,extractable C and N pools,and N2O and CO2 emissions from forest soils in cold temperate region     

XingKai Xu  CunTao Duan  HaoHao Wu  TuanSheng Li  WeiGuo Cheng 《中国科学:地球科学(英文版)》2016,59(1):156-169

Freezing can increase the emissions of carbon dioxide(CO_2) and nitrous oxide(N_2O) and the release of labile carbon(C) and nitrogen(N) pools into the soil. However, there is limited knowledge about how both emissions respond differently to soil freezing and their relationships to soil properties. We evaluated the effect of intensity and duration of freezing on the emissions of CO_2 and N_2 O, net N mineralization, microbial biomass, and extractable C and N pools in soils from a mature broadleaf and Korean pine mixed forest and an adjacent secondary white birch forest in northeastern China. These soils had different contents of microbial biomass and bulk density. Intact soil cores of 0–5 cm and 5–10 cm depth sampled from the two temperate forest floors were subjected to -8, -18, and -80°C freezing treatments for a short(10 d) and long(145 d) duration, and then respectively incubated at 10°C for 21 d. Soil cores, incubated at 10°C for 21 d without a pretreatment of freezing, served as control. Emissions of N_2 O and CO_2 after thaw varied with forest type, soil depth, and freezing treatment. The difference could be induced by the soil water-filled pore space(WFPS) during incubation and availability of substrates for N_2 O and CO_2 production, which are released by freezing. A maximum N_2 O emission following thawing of frozen soils was observed at approximately 80% WFPS, whereas CO_2 emission from soils after thaw significantly increased with increasing WFPS. The soil dissolved organic C just after freezing treatment and CO_2 emission increased with increase of freezing duration, which paralleled with a decrease in soil microbial biomass C. The cumulative net N mineralization and net ammonification after freezing treatment as well as N_2 O emission were significantly affected by freezing temperature. The N_2 O emission was negatively correlated to soil p H and bulk density, but positively correlated to soil K_2SO_4-extractable NO_3~--N content and net ammonification. The CO_2 emission was positively correlated to the cumulative net N mineralization and net ammonification. From the above results, it can be reasonably concluded that for a wide range of freezing temperature and freezing duration, N_2 O and CO_2 emissions after thaw were associated mainly with the changes in soil net N mineralization and the availability of substrate liberated by freezing as well as other soil properties that influence porosity.  相似文献   

Diffuse CO2 efflux from Iwojima volcano,Izu-Ogasawara arc,Japan     

《Journal of Volcanology and Geothermal Research》2005,139(3-4):147-161

Iwojima volcano, located on the southernmost part of the Izu-Ogasawara arc, is characterized by the extrusion of trachyte or trachy andesite lavas and pyroclastic rocks of Holocene and surface thermal manifestations. Small phreatic explosions have been recorded frequently during the last 100 years with the most recent in 1999 and 2001. In order to elucidate the behavior of volcanic volatiles and to assess the potential activity of this volcano, diffuse CO₂ efflux, CO₂ content and δ¹³C–CO₂ in soil gas, and soil temperature at 30 cm depth were measured at 272 sites in March 2000, 112 sites in December 2000 and 40 sites in December 2001. We found that high CO₂ efflux values, of more than 100 g m⁻² day⁻¹, occurred at several locations on Motoyama volcano corresponding with high soil temperatures (more than 60 °C at 30 cm depth) region and with areas where CO₂ with magmatic δ¹³C was observed. Here, the magmatic δ¹³C determined for fumarolic CO₂ data ranged from −2‰ to +3‰, which is clearly higher than magmatic gas values (−8‰ to −2‰) typically found in island arc settings around the world. However, this can be explained in terms of carbon-isotope fractionation between calcite and CO₂ under subsurface temperature and pressure conditions at Iwojima. A total efflux of CO₂ for Iwojima volcano is estimated to be 760 t day⁻¹, with a magmatic contribution of about 450 t day⁻¹. This value is rather high compared with other volcanoes in island arc settings. Since Iwojima has no visible plume, almost all volcanic CO₂ is released as diffuse efflux through the volcanic edifice.  相似文献   

Seasonal dynamics of soil CO2 effluxes with responses to environmental factors in lower subtropical forests of China     

Zhang  Deqiang  Sun  Xiaomin  Zhou  Guoyi  Yan  Junhua  Wang  Yuesi  Liu  Shizhong  Zhou  Cunyu  Liu  Juxiu  Tang  Xuli  Li  Jiong  Zhang  Qianmei 《中国科学:地球科学(英文版)》2006,49(2):139-149

Seasonal metrics and environmental responses to forestry soil surface CO₂ emission effluxes among three types of lower subtropical forests were consistently monitored over two years with static chamber-gas chromatograph techniques among three types of lower subtropical forests. Results showed that annual CO₂ effluxes (S+L) reached 3942.20, 3422.36 and 2163.02 CO₂ g·m⁻²·a⁻¹, respectively in the monsoon evergreen broadleaf forest, mixed broadleaf-coniferous forest and coniferous forest. All the three types of forests revealed the same characteristics of seasonal changes with the CO₂ effluxes peaking throughout June to August. During this peaking period, the effluxes were 35.9%, 38.1% and 40.2% of the total annual effluxes, respectively. The CO₂ emission process responding to the environmental factors displayed significantly different patterns in forestry soils of the three types of forests. The coniferous forest (CF) was more sensitive to temperature than the other two types. The Q ₁₀ values were higher, along with greater seasonal variations of the CO₂ efflux, indicating that the structurally unique forestry ecosystem has disadvantage against interferences. All the three types of forestry CO₂ effluxes showed significant correlation with the soil temperature (T _s), soil water content (M _s) and air pressure (P _a). However, stepwise regression analysis indicated no significant correlation between air pressure and the soil CO₂ efflux. With an empirical model to measure soil temperature and water content in 5 cm beneath the soil surface, the CO₂ effluxes accounting for 75.7%, 77.8% and 86.5% of the efflux variability respectively in soils of BF, MF and PF were calculated. This model can be better used to evaluate the CO₂ emission of soils under water stress and arid or semi-arid conditions.

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Seasonal dynamics of soil CO<Subscript>2</Subscript> effluxes with responses to environmental factors in lower subtropical forests of China     

Zhang Deqiang  Sun Xiaomin  Zhou Guoyi  Yan Junhua  Wang Yuesi  Liu Shizhong  Zhou Cunyu  Liu Juxiu  Tang Xuli  Li Jiong  Zhang Qianmei 《中国科学D辑(英文版)》2006,49(2):139-149

Seasonal metrics and environmental responses to forestry soil surface CO₂ emission effluxes among three types of lower subtropical forests were consistently monitored over two years with static chamber-gas chromatograph techniques among three types of lower subtropical forests. Results showed that annual CO₂ effluxes (S+L) reached 3942.20, 3422.36 and 2163.02 CO₂ g·m^?2·a^?1, respectively in the monsoon evergreen broadleaf forest, mixed broadleaf-coniferous forest and coniferous forest. All the three types of forests revealed the same characteristics of seasonal changes with the CO₂ effluxes peaking throughout June to August. During this peaking period, the effluxes were 35.9%, 38.1% and 40.2% of the total annual effluxes, respectively. The CO₂ emission process responding to the environmental factors displayed significantly different patterns in forestry soils of the three types of forests. The coniferous forest (CF) was more sensitive to temperature than the other two types. The Q ₁₀ values were higher, along with greater seasonal variations of the CO₂ efflux, indicating that the structurally unique forestry ecosystem has disadvantage against interferences. All the three types of forestry CO₂ effluxes showed significant correlation with the soil temperature (T _s), soil water content (M _s) and air pressure (P _a). However, stepwise regression analysis indicated no significant correlation between air pressure and the soil CO₂ efflux. With an empirical model to measure soil temperature and water content in 5 cm beneath the soil surface, the CO₂ effluxes accounting for 75.7%, 77.8% and 86.5% of the efflux variability respectively in soils of BF, MF and PF were calculated. This model can be better used to evaluate the CO₂ emission of soils under water stress and arid or semi-arid conditions.  相似文献   

Variations in dissolved CO2 and CH4 in a first‐order stream and catchment: an investigation of soil–stream linkages     

Diane Hope  Sheila M. Palmer  Michael F. Billett  Julian J. C. Dawson 《水文研究》2004,18(17):3255-3275

Spatial and seasonal variations in CO₂ and CH₄ concentrations in streamwater and adjacent soils were studied at three sites on Brocky Burn, a headwater stream draining a peatland catchment in upland Britain. Concentrations of both gases in the soil atmosphere were significantly higher in peat and riparian soils than in mineral soils. Peat and riparian soil CO₂ concentrations varied seasonally, showing a positive correlation with air and soil temperature. Streamwater CO₂ concentrations at the upper sampling site, which mostly drained deep peats, varied from 2·8 to 9·8 mg l^?1 (2·5 to 11·9 times atmospheric saturation) and decreased markedly downstream. Temperature‐related seasonal variations in peat and riparian soil CO₂ were reflected in the stream at the upper site, where 77% of biweekly variation was explained by an autoregressive model based on: (i) a negative log‐linear relationship with stream flow; (ii) a positive linear relationship with soil CO₂ concentrations in the shallow riparian wells; and (iii) a negative linear relationship with soil CO₂ concentrations in the shallow peat wells, with a significant 2‐week lag term. These relationships changed markedly downstream, with an apparent decrease in the soil–stream linkage and a switch to a positive relationship between stream flow and stream CO₂. Streamwater CH₄ concentrations also declined sharply downstream, but were much lower (<0·01 to 0·12 mg l^?1) than those of CO₂ and showed no seasonal variation, nor any relationship with soil atmospheric CH₄ concentrations. However, stream CH₄ was significantly correlated with stream flow at the upper site, which explained 57% of biweekly variations in dissolved concentrations. We conclude that stream CO₂ can be a useful integrative measure of whole catchment respiration, but only at sites where the soil–stream linkage is strong. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

Effects of soil compaction,rain exposure and their interaction on soil carbon dioxide emission   总被引：2，自引：0，他引：2  

Agata Novara  Alona Armstrong  Luciano Gristina  Kirk T. Semple  John N. Quinton 《地球表面变化过程与地形》2012,37(9):994-999

Soils release more carbon, primarily as carbon dioxide (CO₂), per annum than current global anthropogenic emissions. Soils emit CO₂ through mineralization and decomposition of organic matter and respiration of roots and soil organisms. Given this, the evaluation of the effects of abiotic factors on microbial activity is of major importance when considering the mitigation of greenhouse gases emissions. Previous studies demonstrate that soil CO₂ emission is significantly affected by temperature and soil water content. A limited number of studies have illustrated the importance of bulk density and soil surface characteristics as a result of exposure to rain on CO₂ emission, however, none examine their relative importance. Therefore, this study investigated the effects of soil compaction and exposure of the soil surface to rainfall and their interaction on CO₂ release. We conducted a factorial laboratory experiment with three soil types after sieving (clay, silt and sand soil), three different bulk densities (1·1 g cm^–3, 1·3 g cm^–3, 1·5 g cm^–3) and three different exposures to rainfall (no rain, 30 minutes and 90 minutes of rainfall). The results demonstrated CO₂ release varied significantly with bulk density, exposure to rain and time. The relationship between rain exposure and CO₂ is positive: CO₂ emission was 53% and 42% greater for the 90 minutes and 30 minutes rainfall exposure, respectively, compared to those not exposed to rain. Bulk density exhibited a negative relationship with CO₂ emission: soil compacted to a bulk density of 1·1 g cm^–3 emitted 32% more CO₂ than soil compacted to 1·5 g cm^–3. Furthermore we found that the magnitude of CO₂ effluxes depended on the interaction of these two abiotic factors. Given these results, understanding the influence of soil compaction and raindrop impact on CO₂ emission could lead to modified soil management practices which promote carbon sequestration. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

Landscape structure,groundwater dynamics,and soil water content influence soil respiration across riparian–hillslope transitions in the Tenderfoot Creek Experimental Forest,Montana     

Vincent J. Pacific  Brian L. McGlynn  Diego A. Riveros‐Iregui  Daniel L. Welsch  Howard E. Epstein 《水文研究》2011,25(5):811-827

Variability in soil respiration at various spatial and temporal scales has been the focus of much research over the last decade aimed to improve our understanding and parameterization of physical and environmental controls on this flux. However, few studies have assessed the control of landscape position and groundwater table dynamics on the spatiotemporal variability of soil respiration. We investigated growing season soil respiration in a ～393 ha subalpine watershed in Montana across eight riparian–hillslope transitions that differed in slope, upslope accumulated area (UAA), aspect, and groundwater table dynamics. We collected daily‐to‐weekly measurements of soil water content (SWC), soil temperature, soil CO₂ concentrations, surface CO₂ efflux, and groundwater table depth, as well as soil C and N concentrations at 32 locations from June to August 2005. Instantaneous soil surface CO₂ efflux was not significantly different within or among riparian and hillslope zones at monthly timescales. However, cumulative integration of CO₂ efflux during the 83‐day growing season showed that efflux in the wetter riparian zones was ～25% greater than in the adjacent drier hillslopes. Furthermore, greater cumulative growing season efflux occurred in areas with high UAA and gentle slopes, where groundwater tables were higher and more persistent. Our findings reveal the influence of landscape position and groundwater table dynamics on riparian versus hillslope soil CO₂ efflux and the importance of time integration for assessment of soil CO₂ dynamics, which is critical for landscape‐scale simulation and modelling of soil CO₂ efflux in complex landscapes. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

Dynamics of seasonal recharge beneath a semiarid vegetation on the gnangara mound,Western Australia     

M. L. Sharma  M. Bari  J. Byrne 《水文研究》1991,5(4):383-398

To estimate seasonal changes in recharge to the underlying sandy aquifer, the soil water dynamics of the unsaturated zone was monitored down to a depth of 20 m over a period of three years (1985 to 1987). The measurements were made by a neutron probe at eight locations beneath a native vegetation in a semiarid region, Western Australia, receiving precipitation of 775 mm yr^?1. A relatively simple method, based on the analyses of sequentially measured soil water profiles involving utilization of zero flux plane in the unsaturated zone, is presented and used to compute seasonal recharge rates. Drainage fluxes (recharge rates) below two specified depths were estimated. These were: R₁ (water flux at a depth of 10 m, just below the maximum rooting depth) and R₂ (water flux at a depth of 18 m, just above the water table). These two estimates were significantly different both on a seasonal and annual basis, but their cumulative values for the three year period were very similar. While the annual precipitation varied from 525 to 850 mm yr^?1, the corresponding spatially averaged R₁ varied from 34 to 149 mm yr^?1, and R₂ varied from 65 to 80 mm yr^?1. A significant difference in recharge between the upslope and downslope positions on a hillslope was ascribed to differences in vegetation density of the understorey and differences in hydraulic properties of subsoils. For the three year period, the average R₁ and R₂ were 13 per cent and 10 per cent of the precipitation respectively. These values compare favourably with a long-term estimate based on an environmental tracer technique.  相似文献   

Measurement of Natural Losses of LNAPL Using CO2 Traps          下载免费PDF全文

Kevin McCoy  Julio Zimbron  Tom Sale  Mark Lyverse 《Ground water》2015,53(4):658-667

Efflux of CO₂ above releases of petroleum light nonaqueous phase liquids (LNAPLs) has emerged as a critical parameter for resolving natural losses of LNAPLs and managing LNAPL sites. Current approaches for resolving CO₂ efflux include gradient, flux chamber, and mass balance methods. Herein a new method for measuring CO₂ efflux above LNAPL bodies, referred to as CO₂ traps, is introduced. CO₂ traps involve an upper and a lower solid phase sorbent elements that convert CO₂ gas into solid phase carbonates. The sorbent is placed in an open vertical section of 10 cm ID polyvinyl chloride (PVC) pipe located at grade. The lower sorbent element captures CO₂ released from the subsurface via diffusion and advection. The upper sorbent element prevents atmospheric CO₂ from reaching the lower sorbent element. CO₂ traps provide integral measurement of CO₂ efflux based over the period of deployment, typically 2 to 4 weeks. Favorable attributes of CO₂ traps include simplicity, generation of integral (time averaged) measurement, and a simple means of capturing CO₂ for carbon isotope analysis. Results from open and closed laboratory experiments indicate that CO₂ traps quantitatively capture CO₂. Results from the deployment of 23 CO₂ traps at a former refinery indicate natural loss rates of LNAPL (measured in the fall, likely concurrent with high soil temperatures and consequently high degradation rates) ranging from 13,400 to 130,000 liters per hectare per year (L/Ha/year). A set of field triplicates indicates a coefficient of variation of 18% (resulting from local spatial variations and issues with measurement accuracy).  相似文献   

Comparison of the Penman‐Monteith method and regional calibration of the Hargreaves equation for actual evapotranspiration using SWAT-simulated results in the Seolma-cheon basin,South Korea     

Chung-Gil Jung  Dong-Ryul Lee 《水文科学杂志》2013,58(4):793-800

ABSTRACT

The Hargreaves method provides reference evapotranspiration (ET_o) estimates when only air temperature data are available, although it requires previous local calibration for an acceptable performance. This method was evaluated using the data from 71 meteorological stations in the Seolma-cheon basin (8.48 km²), South Korea, comparing daily estimates against those from the Penman‐Monteith (PM) method, which was used as the standard. To estimate reference ET_o more exactly, considering the climatological characteristics in South Korea, parameter regionalization of the Hargreaves equation is carried out. First, the modified Hargreaves equation is presented after an analysis of the relationship between solar radiation and temperature. Second, parameter (K_ET) optimization of the regional calibration of the Hargreaves equation (RCH) is performed using the PM method and the modified equation at 71 meteorological stations. Next, an application was carried out to evaluate the evapotranspiration methods (PM, original Hargreaves and RCH) in the SWAT (Soil and Water Assessment Tool) model by comparing these with the measured actual evapotranspiration (AET) in the basin. The SWAT model was calibrated using 3 years (2007–2009) of daily streamflow at the watershed outlet and 3 years (2007–2009) of daily AET measured at a mixed forest. The model was validated with 3 years (2010‐2012) of streamflow and AET. RCH will contribute to a better understanding of evapotranspiration of an ungauged watershed in areas where meteorological information is scarce.