共查询到20条相似文献，搜索用时 31 毫秒
1.
A. V. Volkov N. E. Savva A. A. Sidorov V. Yu. Prokof’ev N. A. Goryachev S. D. Voznesensky A. V. Al’shevsky A. D. Chernova 《Geology of Ore Deposits》2011,53(1):1-26
The Shkol’noe deposit is localized in a small granitoid stock, the root portion of which is traced using geophysical data
to a depth of 5–8 km. The high-grade gold ore (33 gpt Au) is enriched in silver and principally differs in ore composition
from the previously studied mesothermal gold-quartz and epithermal gold-silver deposits in the Russian Northeast. The main
reserves of the Shkol’noe deposit concentrate in bonanzas (20% of the total volume of orebodies). The internal deformation
is related to the rearrangement of matter in freibergite; exsolution structures in fahlore and native gold are related to
postmineral metamorphism. It is suggested that the ore of the Shkol’noe deposit occupies a transitional position between porphyrytype
and epithermal levels of ore deposition. 相似文献
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Simulating experiment on the hydrothermal superimposing metallogenesis of the Dongguashan strata-bound copper deposit 总被引：1，自引：0，他引：1
Series of sedimentary hydrothermal-diplogenetic copper deposits have been found scattering in the region along the middle-lower reaches of the Yangtze River, and their metallogenetic mechanism is still in hot debate. In order to reveal the ore-forming kinetics of sedimentary process and hydrothermal superimposition, and evaluate the role of sedimentary pyrite in the enrichment and precipitation of copper, a set of simulating experiments on the reaction between pyrite and CuCl2 solution were conducted. According to the physicochemical characteristics of the ore-forming fluid of the Dongguashan copper deposit, Anhui Province, 100 MPa was selected as the experimental pressure, and the experimental temperatures were set at 450, 350, 250 and 150°C, respectively. The reactions between pyrite grains isolated from the Shimenkou strata-bound pyrite deposit and the solution with 0.2 mol/L CuCl2 and 1.0 mol/L NaCl were experimentally simulated. Then, variations in surface topography and surface chemistry of the experimental pyrite grains were documented using scanning electronic microscopy (SEM), atomic force microscopy (AFM), Auger electron spectrometry (AES) and X-ray photoelectron spectroscopy (XPS), and the solution and newly formed minerals were analyzed using inductively coupled plasma (ICP-AES) and X-ray diffraction (XRD) techniques. Desulphurization of pyrite surface was observed and new copper minerals were detected. It is proposed that pyrite can act as a geochemical barrier for the enrichment and precipitation of copper from the solution under the experimental conditions. Furthermore, the ore-forming mechanism of sedimentary hydrothermal-diplogenetic copper deposits was discussed. 相似文献
4.
The Zijinshan high-sulfidation epithermal Cu–Au deposit is located in the Zijinshan ore field of South China, comprising porphyry–epithermal Cu–Au–Mo–Ag ore systems. The Cu ore body is more than 1000 m thick and is characterized by an assemblage of digenite–covellite–enargite–alunite. Digenite is the dominant Cu-bearing mineral, which makes this deposit unique, although the mechanisms of digenite formation remain controversial. To elucidate the genesis of digenite, this paper presents the Cu isotopic compositions of Cu-sulfides in the Zijinshan high-sulfidation Cu–Au deposit. The Cu isotopic values (65Cu relative to NIST 976) of all samples range from −2.97‰ to +0.34‰, and most values fall in a narrow range from −0.49‰ to +0.34‰, which is similar to the Cu isotopic signature of typical porphyry systems. Copper isotope ratios of each mineral decrease with increasing depth, a trend that is also typical of porphyry deposits. The variation tendency of δ65Cu values between sulfides is consistent with the sequence of mineral formation. These observations suggest that the Cu-sulfides in the Zijinshan Cu–Au deposit have a hypogene origin. 相似文献
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The Palaeoproterozoic (1.9 Ga) Rytky and Kotalahti mafic-ultramafic intrusions are located in the contact zone between the Archaean craton and Proterozoic supracrustal rocks. During the second deformation event (D2) the surrounding country rocks were subjected to intensive metamorphism and deformation associated with the Svecofennian orogeny; the Archaean/Proterozoic boundary controlled both D2 thrusting and magma ascent. Emplacement of the Rytky and Kotalahti intrusions took place at the culmination of D2, as shown by the gneiss inclusions with S2 schistosity within the intrusions. Overthrusting continued after emplacement, with detached fragments of the bodies incorporated into the Archaean gneisses. During the third deformation event (D3) the originally subhorizontal intrusions were rotated into a subvertical position, so that they now have their stratigraphic top towards the west. The Rytky intrusion is composed mainly of medium- and coarse-grained lherzolite, websterite and gabbronorite. The nickel deposit with pentlandite as the main nickel mineral is associated with the lherzolite and websterite. The coarse-grained lherzolite, websterite and melagabbro represent the first rocks to form, and they contain the nickel sulphide mineralisation. Country rock contamination, as indicated by high TiO2, P2O5, Rb, Zr and light rare earth element contents (LREE), is most pronounced in the marginal part of the intrusion, which was the first to form. The variation in olivine composition (Fo 78.6-84.77 mole %; Ni 630–2386 ppm) and the metal ratio of the sulphide (Ni/Co 19.3 – 50.3) along with the internal stratigraphy of the intrusion indicate an in-situ process of sulphide ore formation.Editorial handling: P. LightfootAn erratum to this article can be found at 相似文献
6.
G. N. Gamyanin N. A. Goryachev O. V. Vikentieva 《Russian Journal of Pacific Geology》2016,10(3):206-217
The paper reports the mineralogical and geochemical features of the Kysylga gold deposit located in the hornfelsed Norian sedimentary rocks and classified with low-sulfide gold–quartz type of deposits typical of the Verkhoyansk–Kolyma metallogenic province. Detailed typomorphic study of the major minerals (quartz, arsenopyrite, and gold) of the ore veins shows that the deposit is assigned to the gold–silver type. Mineralogical and geochemical data substantiate this conclusion. 相似文献
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Placer gold particles derived from epithermal deposits display distinct morphological and compositional features compared with particles from mesothermal systems. Here, it is hypothesized that the chemical composition of primary gold derived from different deposit types is a principle factor affecting the composition of resident biofilm communities as well as the transformation of placer particles. Gold particles were collected from placers originating from the epithermal system at the Eisenberg, Germany's largest primary gold deposit. For comparison, placer gold from mesothermal sources was studied. Morphological differences due to mechanical transport and physical reshaping were not observed. Biogeochemical gold/silver dissolution and gold re-precipitation were evident on epithermal particles and they accentuate the silver-fabrics and gold-rich clusters. In contrast, on mesothermally derived gold particles these processes led to the development of gold-rich rims via the formation of nano-porous secondary gold. Microprobe- and laser ablation mass spectrometric analyses of polished whole particle mounts confirmed differences in gold/silver content/distribution and trace metal content between particles from epi- and mesothermal sources, respectively. On particles from all sites nano- and micro-particulate gold is associated with polymorphic layers. These are composed of microbial cells, extracellular polymeric substances (EPS) and clay-sized minerals. Multivariate statistical analyses shows a significant difference between biofilm communities from epi- vs. mesothermally derived particles, which is linked to the chemical composition of the primary gold. While a number of key-species capable of gold transformation, e.g., Cupriavidus sp., Geobacter sp. and Rhodoferax sp., were detected on particles from both sources, higher numbers of organisms with the potential for gold solubilization, precipitation and detoxification were associated with particles from the epithermal sources. A range of species involved in gold transformation, i.e., Arthrobacter spp., Delftia sp., Shewanella sp., and Stenotrophomonas spp., were detected only on epithermally derived placer gold. This indicates the communities are sensitive to differences in gold/silver and possibly trace metal-cycling, resulting from differences in their content, distribution and mobilization behaviour in epi- vs. mesothermally derived particles. Ultimately, this study shows that the chemical composition of the primary deposit strongly influences the biogeochemical transformation of placer gold and the composition of associated biofilms, whereas physical transformations appear to be largely unaffected. 相似文献
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1 Introduction Alunite [KAl3(SO4)2(OH)6] is a very important non-ferrous metal resource, so many countries throughout the world have made great investments in research on the mechanism of its formation, its geological characteristics and applications. O… 相似文献
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K. R. Kovalev O. N. Kuzmina B. A. Dyachkov A. G. Vladimirov Yu. A. Kalinin E. A. Naumov M. V. Kirillov I. Yu. Annikova 《Geology of Ore Deposits》2016,58(2):116-133
The Zhaima gold–sulfide deposit is located in the northwestern part of the West Kalba gold belt in eastern Kazakhstan. The mineralization is hosted in Lower Carboniferous volcanic and carbonate rocks formed under conditions of marginal-sea and island-arc volcanic activity. The paper considers the mineralogy and geochemistry of primary gold–sulfide ore and Au-bearing weathering crusts. Au-bearing arsenopyrite–pyrite mineralization formed during only one productive stage. Disseminated, stringer–disseminated, and massive rocks are enriched in Ti, Cr, V, Cu, and Ni, which correspond to the mafic profile of basement. The main ores minerals are represented by finely acicular arsenopyrite containing Au (up to few tens of ppm) and cubic and pentagonal dodecahedral pyrite with sporadic submicroscopic inclusions of native gold. The sulfur isotopic composition of sulfides is close to that of the meteoritic standard (δ34S =–0.2 to +0.2). The 40Ar/39Ar age of three sericite samples from ore veinlets corresponds to the Early Permian: 279 ± 3.3, 275.6 ± 2.9, and 272.2 ± 2.9 Ma. The mantle source of sulfur, ore geochemistry, and spatial compatibility of mineralization with basic dikes allow us to speak about the existence of deep fluid–magmatic systems apparently conjugate with the Tarim plume. 相似文献
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近来南岭地区加里东期钨锡找矿勘查取得较大突破,但其成因机制研究仍相对缺乏。湘西南苗儿山岩体西北部的落家冲矿床是近年新发现的加里东期钨锡矿床,具有良好的钨锡多金属矿找矿前景,其成矿流体的特征和成矿机制有待查明。在详细的野外地质调查基础上,落家冲矿床的成矿过程可划分为四个阶段:蚀变花岗岩-白钨矿阶段(Ⅰ)、云英岩-白钨矿-锡石阶段(Ⅱ)、石英脉-白钨矿阶段(Ⅲ)和石英脉-硫化物阶段(Ⅳ)。本文选取第Ⅰ阶段的锆石和锡石开展了U-Pb定年和锆石Hf同位素分析,对四个成矿阶段的石英矿物进行了流体包裹体以及H-O同位素的研究。获得的锡石U-Pb反等时线年龄(433.0±11Ma)与蚀变花岗岩锆石U-Pb年龄(430.7±2.3Ma)在误差范围内一致,表明矿区的成岩成矿作用均发生于加里东晚期。流体包裹体研究显示第Ⅰ阶段到第Ⅳ阶段,均一温度分别集中在260-380℃、260-320℃、200-320℃和180-220℃之间,呈逐渐降低的趋势,盐度则表现为由第Ⅰ阶段到第Ⅱ阶段陡降,第Ⅱ阶段到第Ⅳ阶段总体变化不大的特点(平均值分别为16.9%、3.9%、4.8%和3.7%NaCleqv)。成岩成矿定年结果、各成矿阶段的成矿流体特征,结合锆石εHf(t)=-7.6--5.0、tDM2=1565-1711Ma,和石英矿物的δ18OH_(2)O值从第Ⅰ阶段(3.97‰-5.34‰)到第Ⅳ阶段(-4.99‰--5.10‰)逐渐降低的特点,以及区域岩体的地球化学特征,本文认为落家冲钨锡矿床是加里东期起源于元古宙地壳重熔的岩浆在经历了高分异演化作用后,流体的沸腾作用以及温度下降造成成矿流体中钨锡等矿质的沉淀所形成。 相似文献
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TheHuizelarge sizedPb ZndepositinYunnan ProvinceislocatedinthecenteroftheSichuan Yun nan GuizhouPb Zn Agpolymetalmineralizationzone(SYGPb ZnMMD)inwesternYangtzePlateandis oneofthefamousPb Zn GebasesinChina(Wang Jiangzhenetal.,2003;WangXiaochunetal.,2000).Thisdeposit,whichischaracterizedbylarge scale(Pb+Znmetallicreservesarehigherthan5mil liontons),highPb+Zngrade(thePb+Zngradesof mostoresare25%-35%),highabundanceofuseful associatedelements(Ag,Ge,Cd,Ga,etc.)and someimportantbreakt… 相似文献
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Soroush Modabberi Farid Moore 《中国地球化学学报》2006,25(B08):46-46
The Zarshuran arsenic deposit has been exploited for more than one thousand years. During this period of time, trace element pollutants have been transported downstream via natural agents, however this process has been exacerbated by human interferences, such as mining activities, especially in recent years. Geochemical study of metallic contaminants revealed a high concentration of elements especially of As, Sb, Hg, and TI in ore, waste piles, water and stream sediments, so that the arsenic concentration ranges between 40-0.028 mg/L in water samples of the Zarshuran Stream. In order to investigate the mechanism of contaminant transport downstream the mine, the concentrations of arsenic and other trace elements detected in ore-waste assemblage were measured in water samples taken from 11 stations. Also, the pH and Eh values have been measured in the same waster samples. The arsenic ore mainly consists of orpiment and realgar, associated with a small amount of Sb, Hg, Tl, minerals. Weathering of this assemblage gives rise to a mine water having an arsenic concentration of 22 mg/L. As concentrations are reduced to 4.272, 3.069, 0.421, 0.083, and 0.036 mg/L at distances of about 1, 1.3, 3.3, 7 and 15.2 km down the mine, respectively. The water samples have been passed through the 0.45μ filters to determine the fraction of contaminants transported in dissolved phase and also in particulate phase. The geochemical study of contaminant transport indicates that contaminants are transported mainly as colloidal and particulate phases in the upstream and only 13% of arsenic is transported as the dissolved phase. The milky appearance of stream is evidence for colloidal transport. From 6 km downward the mine, particulate phase is not the significant carrier of contaminants and more than 90% of the arsenic is transported as dissolved phase. The very positive correlation between trace element concentrations and Fe, colloidal deposition evidence as an ocher-colored precipitate on stream bed sediments accompanied by a decrease in contaminant concentrations in stream water, the physicochemical （Eh and pH） conditions, near neutral pH values, considerable difference in concentration of Fe in dissolved and total phases, weathering of iron sulfides in the ore-waste assemblage, XRD analysis of precipitates, indicate strongly that HFO is the main carrier and transporting agent in this area. 相似文献
16.
《中国地球化学学报》2006,(Z1)
The Zarshuran arsenic deposit has been exploited for more than one thousand years. During this period of time, trace element pollutants have been transported downstream via natural agents, however this process has been exacerbated by human interferences, … 相似文献
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NIU Shuyin SUN Aiqun WANG Baode LIU Jianming GUO Lijun HU Huabin XU Chuanshi 《中国地球化学学报》2007,26(4):394-401
The Dajing Cu-Sn-polymetallic ore deposit is famous for its large scale, abundant associated elements, narrow and closely-spaced development of ore veins and high grade, but exploration within the mining district and its deeper parts has revealed no Yanshanian rockbody. Therefore, there have been proposed a diversity of hypotheses on the genesis of the deposit. The authors, from the angle of mantle-branch structure, provided evidence showing that the mining district is located in the core of the Da Hinggan Ling mantle-branch structure, the multi-stage evolution of mantle plume paved the way for the ascending of deep-source ore fluids and these fluids extracted part of the ore-forming materials. Then, these ore-forming materials were concentrated in the favorable structural loci (e.g. structural fissures) to form ores. The orientation of ore-forming and ore-controlling fissures is closely related to the regionally structural stress field at the metallogenic stage. The zonation of Sn, Cu, Au, Ag, Pb, and Zn within the mining district appears to be related to metallogenesis and the crystallization temperature of ore-forming materials. Mineralization of Sn, Cu, Au, etc. which require relatively high crystallization temperature and pressure is in most cases recognized in the central part of the mining district, while that of Ag, Pb, Zn, etc. which require relatively low crystallization temperature and pressure is, for the most part, produced in the periphery of the mining district. 相似文献
18.
The ore body “T” is the newly discovered massive-pyrite type one which is located in the central part of the Bor copper mine. The main copper minerals are chalcocite-digenite, covellite and enargite. Small amounts of colusite are frequently present in the ore-body. It mostly occurs as the distinct exsolutions in digenite and, associating with enargite and covellite. Composition of the studied colusite shows enriched Sn content, giving an empirical formula from Cu24.7V1.8Fe0.2As5.1Sb0.2Sn0.8S32 to Cu26.7V2.0Fe0.3As3.0Sb0.3Sn3.5S32. This colusite represents a solid solution between colusite and nekrasovite within a range of 14–54 mol % nekrasovite. Most of the analyses show content of <50 mol % nekrasovite corresponding to the Sn-bearing colusite variety, while one analysis shows content of 54 mol % nekrasovite corresponding to the As-bearing nekrasovite. 相似文献
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Life spans and thermal evolution of hydrothermal systems are of fundamental metallogenic importance. We were able to establish
the chronology and cooling history of the Zaldívar porphyry copper deposit (Northern Chile) by applying a combination of different
isotopic dating methods in minerals with different closure temperatures, including 40Ar/39Ar geochronology and zircon fission track thermochronology, together with fluid inclusion thermometry and previous published
U–Pb zircon geochronology. The hydrothermal mineralization in the Zaldívar deposit is genetically related to the Llamo Porphyry
unit. Samples of igneous biotites from this intrusion yielded 40Ar/39Ar plateau ages between 35.5 ± 0.7 and 37.7 ± 0.4 Ma defining a weighted average of 36.6 ± 0.5 Ma (2σ). In contrast, one sample from the Zaldívar porphyry, one from the andesites, and two from the Llamo porphyry yielded considerably
younger fission track ages of approximately 29 Ma with a weighted mean for all ages of 29.1 ± 1.7 Ma (2σ). Thermal and compositional constraints for the hydrothermal system in the Zaldívar deposit from fluid inclusions thermometry
show that at least three fluid types broadly characterize two main hydrothermal episodes during the evolution of the deposit.
The main mineralization and alteration event is characterized by high temperature (above 320°C) hypersaline fluids (salinity
between 30 and 56 wt.% NaCl equivalents) coexisting with low-density gas-rich inclusions (salinity less than 17 wt.% NaCl
equivalents) that homogenizing into the gas phase at temperatures above 350°C. The second episode corresponds to a low-temperature
event which is characterized by liquid-rich fluid inclusions that homogenize into the liquid phase at temperatures ranging
from 200°C to 300°C with salinities lower than 10 wt.% NaCl equivalents. The 40Ar/39Ar data (36.6 ± 0.5 Ma, weighted average) obtained from igneous biotites represent the minimum age for the last high-temperature
(above 300°C) hydrothermal pulse. When compared with previously published U–Pb ages (38.7 ± 1.3 Ma) in zircons from the Llamo
porphyry, a close temporal relationship between crystallization of the parental intrusion and the thermal collapse of the
last high-temperature hydrothermal event is evident. Cooling took place from approximately 800°C (crystallization of the intrusive
complex defined by zircon U–Pb ages) to below 300 ± 50°C (biotite 40Ar/39Ar closure temperature) within approximately 1.5 m.y. Because the thermal annealing of fission tracks in zircons occurs at
temperatures of 240 ± 30°, the zircon fission track (ZFT) ages of 29.1 ± 1.7 Ma (2σ) mark the end of the thermal activity in the Zaldívar area, specifically the time when the whole area cooled below this temperature,
well after the collapse of the main hydrothermal event in the Zaldívar porphyry copper deposit. This cooling age roughly coincides
with the age defined for the emplacement of dacitic dikes at 31 ± 2.8 Ma (2σ) (published K–Ar whole rock), 5 km south of the Zaldívar deposit, in the Escondida area. This late magmatic pulse probably
is responsible for high heat flow in the Zaldívar deposit as late as 29 Ma. There is no evidence that the low temperature
hydrothermal pulse recognized by fluid inclusion studies is related to this thermal event. The zircon fission track cooling
ages are interpreted to be related to the time lag required for complete relaxation of the perturbation of the isotherms in
the geothermal field imposed by the intrusion of magmatic bodies, with or without any association with low temperature hydrothermal
activity. 相似文献
20.
Isotope geochemistry of ore fluids for the Dongsheng sandstone-type uranium deposit, China 总被引：2，自引：1，他引：2
The Dongsheng sandstone-type uranium deposit is one of the large-sized sandstone-type uranium deposits discovered in the northern part of the Ordos Basin of China in recent years. Geochemical characteristics of the Dongsheng uranium deposit are significantly different from those of the typical interlayered oxidized sandstone-type uranium ore deposits in the region of Middle Asia. Fluid inclusion studies of the uranium deposit showed that the uranium ore-forming temperatures are within the range of 150–160℃. Their 3He/4He ratios are within the range of 0.02–1.00 R/Ra, about 5–40 times those of the crust. Their 40Ar/36Ar ratios vary from 584 to 1243, much higher than the values of atmospheric argon. The δ18OH2O and δD values of fluid inclusions from the uranium deposit are -3.0‰– -8.75‰ and -55.8‰– -71.3‰, respectively, reflecting the characteristics of mixed fluid of meteoric water and magmatic water. The δ18OH2O and δD values of kaolinite layer at the bottom of the uranium ore deposit are 6.1‰ and -77‰, respectively, showing the characteristics of magmatic water. The δ13CV-PDB and δ18OH2O values of calcite veins in uranium ores are -8.0‰ and 5.76‰, respectively, showing the characteristics of mantle source. Geochemical characteristics of fluid inclusions indicated that the ore-formation fluid for the Dongsheng uranium deposit was a mixed fluid of meteoric water and deep-source fluid from the crust. It was proposed that the Jurassic-Cretaceous U-rich metamorphic rocks and granites widespread in the northern uplift area of the Ordos Basin had been weathered and denudated and the ore-forming elements, mainly uranium, were transported by meteoric waters to the Dongsheng region, where uranium ores were formed. Tectonothermal events and magmatic activities in the Ordos Basin during the Mesozoic made fluids in the deep interior and oil/gas at shallow levels upwarp along the fault zone and activated fractures, filling into U-bearing clastic sandstones, thus providing necessary energy for the formation of uranium ores. 相似文献