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1.
本文根据核爆炸岩石熔融玻璃的地球化学研究结果,与超速陨石撞击坑的熔岩进行比较,获得在远离热力学平衡条件下,各种玻璃和熔岩在化学成分上分布十分均匀的重要结论。岩石玻璃和熔岩是由基岩各组成岩石按一定比例混合熔融形成的。它们的主量元素和痕量元素丰度受基岩元素背景值制约。文中根据熔体和靶岩的化学成分,计算了熔岩各组成岩石的百分比。玻璃陨石是地壳岩石受撞击熔融形成的。同一撒布区的玻璃陨石化学成分相近,说明起源于同一源坑;而玻璃陨石化学成分的不同,则说明母岩组成分量的差异。因此,文中通过模拟计算,得出各玻璃陨石的组成源岩。澳大利亚撒布区的玻璃陨石,Al2O3,K2O 和Na2O 与 SiO2及 K2O/Na2O 比值不完全相同,说明澳大利亚撒布区存在着几个不同的源岩和源坑,至少有印支、爪哇、菲律宾和澳大利亚四个相应撞击坑。 相似文献
2.
古代玻璃材料LA-ICP-MS组分分析及产源研究 总被引：1，自引：1，他引：0
古代玻璃及玻璃质材料的定量分析对于研究其制作年代及产地、原料的来源以及制作工艺有着重要的参考意义。与电子探针(EMPA)、能谱扫描-电子显微镜(EDX-SEM)等分析方法相比,LA-ICP-MS能够快速且准确地提供样品主次量及微量元素信息。本文对LA-ICP-MS古代玻璃元素定量分析中的影响因素进行研究认为:在193nm激光下玻璃标准NIST610和康宁玻璃标准之间基体差异造成的影响较小,而采用玻璃标准NIST610为外标结合基体归一化法的校正策略测定康宁标准结果表明,该策略能够准确反映不同类型古代玻璃材料中成分组成;实验中不同剥蚀模式的研究,有助于不同实验条件的建立,从而满足不同研究的需要。本次研究对出土样品进行了分析,为该制品的产源研究提供了数据支持。 相似文献
3.
中基性火山作用喷出物类型、特征与成因 总被引：5，自引：0，他引：5
基于松辽盆地中生代和准噶尔盆地古生代火山岩研究资料与长白山、五大连池等现代火山考察,结合国外典型实例,将火山作用喷出物分为熔岩、碎屑熔岩、火山碎屑岩和沉火山碎屑岩4类;前两类岩石冷凝固结,后两类压实固结。按成分-组构-岩相分类方案划分出34种岩相。详细论述了各岩相的成岩方式、成分、组构、成因和产状,并给出各岩相类型的实例和典型照片。建造-改造和继承-变异分析对比显示,现代火山与古火山都常见的岩相包括厚层熔岩、熔结结构碎屑熔岩、柱状节理熔岩、枕状熔岩和玻璃质熔岩。现代火山常见而古火山少见或未见的有浮岩、渣状熔岩、绳状和块状熔岩。火山穹窿垮塌是常见的同生改造作用。裂隙式与中心式喷发往往相伴而生,常表现为沿着深大断裂的一系列中心式喷发。 相似文献
4.
火山灰地层学主要依靠火山玻璃的成分进行源区的识别,然而,当火山玻璃成分不均一时就会对源区识别造成影响.四海龙湾玛珥湖位于东北新生代龙岗火山区内,其湖泊沉积物可以记录周边的火山喷发,电子探针等方法得到的火山玻璃成分可以揭示其喷发来源.同时,玛珥湖的纹层年龄可以限定其喷发年龄.在四海龙湾沉积物(钻孔2008) 的78~79 cm岩芯处出现一层火山灰层,其纹层年龄为AD 308 a,电子探针结果显示火山玻璃具有不均一的主量元素组成,为玄武质粗安岩到碱玄质响岩.FeO、TiO2及Al2O3等与MgO协变图解更清楚地显示了此次火山喷发的火山玻璃成分的不均一性.火山玻璃与火山灰全岩对比分析显示,全岩分析在火山灰地层学应用中容易造成对比偏差. 相似文献
5.
三、火山熔岩的某些特征结构 火山熔岩或称喷发溢流熔岩。它们是在地壳内一定深度的岩浆,沿某些裂隙上升,涌出或溢出地表而形成。火山熔岩有如下一些特征: 1.当岩浆还处于地壳深部时,部分矿物可能结晶(即后来岩石中的斑晶),随着岩浆沿通道上升过程中与围岩中某些物质反应,就影响和改选了岩浆的成分和已结晶的矿物; 相似文献
6.
通过描述一种利用LA-ICP-MS准确测定含水硅酸盐矿物主量元素和微量元素含量的多外标、无内标分析方法.总结出该方法基于矿物化学计量式计算含水硅酸盐矿物中挥发分的相对含量,再将全部分析元素归一化到总金属氧化物含量(100%减含水量)的原理,利用多种天然成分的岩石标准玻璃(如MPI-DING玻璃和USGS玻璃)作为外标进行校正计算.利用该方法对角闪石、绿帘石、电气石和透闪石等含水硅酸盐矿物进行了分析,并与利用电子探针和微钻(直径300 μm)取样溶液-ICP-MS分析的结果进行了对比研究.研究结果表明:对于组成均一的主量元素的分析结果与电子探针分析数据一致,相对偏差集中在5%以内.除了那些分布异常不均一的元素(在300 μm尺度上),对微量元素的分析结果与溶液-ICP-MS分析结果具有很好的一致性,二者之间的相对偏差大部分集中在10%以内.研究结论为采用归一化校正策略,选择MPI-DING和USGS玻璃作为外标,利用LA-ICP-MS微区分析方法可以准确测定含水硅酸盐矿物中的主、微量元素含量. 相似文献
7.
黑龙江省五大连池钾质火山岩石中普遍含有壳源捕虏体和捕虏晶,并多赋存于火山集块、浮岩砾、火山渣等各级火山碎屑物及盾状台地的表皮相到内部相火山熔岩中。花岗岩质捕虏体一般大小为5～50cm,捕虏晶一般为0.2～5mm,成分以二长花岗岩为主,少见花岗闪长岩及黑云母英云闪长岩和少量砂岩捕虏体。石英、斜长石、少数钾长石捕虏晶见于各期火山碎屑(物)和熔岩中,其中以石英捕虏晶最为常见。壳源捕虏体中的代表性矿物及浅色玻璃电子探针分析结果表明,火山岩SiO2偏高是岩浆上涌喷发过程中捕获了大量壳源物质的结果。五大连池火山群富钾火山岩岩石化学、地球化学长期保持均一,说明其岩浆直接来自EMⅠ型钾质地幔,岩浆在上升过程中遭受了地壳物质的明显混染。 相似文献
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9.
内蒙古赤峰双胜地区早白垩世多斑流纹斑岩,发育气孔构造,具多斑状结构,斑晶含量高达70%,成分为透长石（30%）、石英（35%）及斜长石（5%）. 斑晶透长石呈半自形宽板状且具有梳状反应边,反应边成分为Na-正长石,反应边中含针柱状矿物雏晶. 斑晶石英边缘或内部被强烈熔蚀,并发育碎斑结构,具有“裂而不离”或“离而不散”的特点,碎斑石英之间被基质成分充填. 岩石兼具熔岩及碎斑熔岩的双重结构. 岩石中含气孔. 岩石结构特征反映岩浆经历了绝热-减压快速上升过程,可能指示成岩时期区域伸展构造背景的开始. 相似文献
10.
赣杭构造带相山火山侵入杂岩的岩浆演化特征——来自斜长石和黑云母的化学成分研究 总被引：4，自引：4，他引：0
黑云母、斜长石等矿物可作为寄主岩石的岩浆演化的指示剂。本文借助电子探针微区分析技术,通过对赣杭构造带中相山盆地火山侵入杂岩中这些矿物的化学组成进行定量分析发现:碎斑熔岩、花岗斑岩及石英二长斑岩的斜长石环带不明显,并且主要是中长石;石英二长斑岩中黑云母矿物成分为镁质黑云母和铁质黑云母,化学成分更为接近研究区镁铁质微粒包体中黑云母的成分,而碎斑熔岩及花岗斑岩中黑云母的镁含量较低。结合黑云母、斜长石矿物的化学特征及前人的工作研究,相山碎斑熔岩和花岗斑岩的物质来源主要是壳源,没有明显地幔物质的加入,而石英二长斑岩有一定量的地幔物质的加入,并且这个地幔物质的加入发生在石英二长斑岩的黑云母开始结晶之前。 相似文献
11.
A. A. Plyashkevich P. S. Minyuk T. V. Subbotnikova A. V. Alshevsky 《Doklady Earth Sciences》2016,467(2):380-383
Newly obtained data from microscopic, geochemical, and thermomagnetic studies of the large Kolyma fulgurite are presented here: the fulgurite was formed in the Holocene as a result of lightning affected black shale alluvium. The composition is very close to that of glass formed from a melt. The glass has elevated concentrations of Y, Zr, Nb, and REEs. The newly formed mineral phases have been identified: those are Al–Si glass, α-cristobalite, moissanite, native iron with a phosphorus admixture, nickel-less shreibersite (?), troilite, and possibly cohenite. The formation of these minerals is related to the melt fractionation and the effects of element concentration and segregation of ore components under conditions of the rock melting caused by the effect of high-energy plasma (lightning strike). 相似文献
12.
Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) has been applied to determine the elemental composition of the surface layer, as well as of the first interior layer, of quartz grains from the mine tailings from Kristineberg (northern Sweden) in order to determine concentration gradients between these two layers. The quartz grains were collected from the oxidized and unoxidized zones within the tailings. The aim of this study is to assess the role of quartz surfaces as sites for the attenuation of solutes from the mine-tailings porewater. Concentrations of Cu, Ag, Sb, Pb and Bi are highest near the surface of each grain and decrease towards the interior. The surface concentration of Cu, Zn and Pb is more pronounced within the unoxidized than within the oxidized zone of the tailings. Cu exhibits a distinct concentration peak at the surface of the quartz grains below the pre-remediation oxidation front. For Zn and Ce the trend of high surface concentration is less pronounced than for Cu or Pb. Silver, Bi and As are preferably adsorbed within the uppermost layers of the oxidized zone where the pH is as high as 6.2. The conversion of intensity signals of the elements to concentration values in ppm was done by using external standards (NIST silicate glass). 相似文献
13.
松辽盆地白垩系营城组流纹岩中石泡构造类型、特征及成因 总被引：1，自引：0，他引：1
通过大比例尺平面地质填图、剖面测量和显微组构分析,九台营城煤矿区流纹岩中石泡构造发育。根据成因、产状、宏观形态和显微特征,石泡构造可分为3类:膨润土中的独立石泡、层状流纹岩表面贴附的石泡和块状流纹岩内部的石泡。独立石泡大小不等,直径由几厘米至几十厘米,表面似葡萄状,平面上呈环带状分布于珍珠岩四周蚀变膨润土中,为富含挥发物质的岩浆遇水淬碎成球体,经结晶分异作用形成。层状流纹岩表面贴附的石泡,直径由几毫米至几厘米,表面形态与独立石泡相似,平面上呈环带状分布于独立石泡带外侧,形成机理与独立石泡相似,由于遇水量减少和岩浆喷发强度增大形成差别。块状流纹岩内部的石泡,直径由几毫米至几厘米,内部具多圈层结构,为含气液混合物的岩浆,气体逸出,液体中的矿物成分随温度下降,由外至内依次结晶形成。3类石泡赋存于喷溢相上部亚相,形成机理为等容降温、冷凝收缩。 相似文献
14.
本文将全球洋中脊系统作为研究整体,根据洋中脊的全球分布、运动学特征及其初始形成时与泛大陆的构造几何关系,将全球现今的洋中脊系统划分为内、外支洋中脊。外支洋中脊为探索者洋中脊-太平洋洋隆-东南印度洋中脊-西北印度洋中脊,起源于泛大洋及冈瓦纳大陆内部;内支洋中脊为西南印度洋中脊-大西洋中脊-北冰洋加科尔洋中脊,起源于泛大陆内部。两者之间通过俯冲带、转换断层以及弥散性板块边界实现全球板块构造在运动上的平衡,并保持地球的球形几何形态恒定。外支洋中脊在全球板块构造上造成泛大洋缩减,并持续被太平洋取代,直接推动了环太平洋俯冲带的形成;内支洋中脊造成大西洋盆、印度洋盆中生代以来持续扩张。中生代以来,外支洋中脊和内支洋中脊共同作用引起非洲板块、印度澳大利亚板块向北运动,新特提斯洋盆关闭,形成特提斯(阿尔卑斯山-喀尔巴阡山-扎格罗斯山-喜马拉雅山)碰撞造山带,并通过洋中脊扩张平衡了相关的岩石圈缩短。 相似文献
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16.
W. v. Engelhardt 《Contributions to Mineralogy and Petrology》1972,36(4):265-292
In the suevite breccia of the Ries impact crater, Germany, glasses occur as bombs, and small particles in the groundmass. These glasses were formed from melt produced by shock fusion of crystalline basement rocks. Ejection from the crater resulted in the formation of aerodynamically shaped bombs, a few homogeneous spherules and a large mass of small glass particles which were deposited in the suevite breccia. Bombs and small particles included within chilled bottom and top layers of suevite deposits have been preserved in vitreous state, whereas glasses within the interior of the suevite devitrified, due to slower cooling rates.This paper summarizes the results of petrographical and chemical investigations of suevite glasses and their devitrification products. Conclusions are derived on origin and history of bombs and glass particles.Vitreous bombs and glass particles consist of schlieren-rich glass, mineral fragments (mainly quartz), rock fragments and vesicles. Wet chemical, trace element and microprobe analyses reveal that a primary melt was formed by shock fusion of a basement complex, consisting of about 80% biotite granite and 20% amphibolite. The, originally, more than 1800° C hot melt then incorporated shocked and desintegrated rocks of outer zones of the impact. Partial fusion of the rock debris resulted in a polyphase mixture consisting of melts, different in composition, accumulations of refractory mineral fragments and vesicles.Devitrified bombs and glass particles which are found in the interior of suevite deposits show alterations of texture and composition, due to microcrystallite growth and action of hydrothermal and weathering solutions. Incipient devitrification is indicated by brown staining of the glasses, originating, probably, by exsolution of minute magnetite particles. By optical microscopy and X-ray analysis, plagioclase and pyroxenes have been identified as main devitrification products. Shapes and textures of microcrystallites indicate fast crystal growth in a viscous and supercooled medium. Hot fluids permeating the suevite deposited microcrystalline quartz in vesicles and cracks. Later, montmorillonite was precipitated by solutions corroding the glass. Action of solutions on glasses which were weakened in coherence by devitrification resulted in oxidation of iron, leaching of iron and magnesium, and enrichment in alkalis. 相似文献
17.
In order to reveal the temperature variation mechanism of a small and relatively closed cave, the surface temperature, the cave air temperature and the drip water temperatures were monitored with high-resolution recorders for a 7-year period. The results indicated that the cave temperature is mainly affected by the external seasonal oscillations. The temperature curve of the inner cave area (with standard deviation between 0.59 and 0.87) was much smoother in comparison with that of the surface (with SD as high as 8.46). However, the cave reacted to the temperature drifts with some delay, for example, at VP3 in 2006, the internal temperature increased for additional 49 days after the surface temperature dropped colder than inside of the cave. This seasonal variation and delayed response of the internal temperature were mainly affected by conduction from the epikarst rock mass. Air convection also occurred in the cave, especially when the surface temperature dropped lower than that of the inside cave (during the winter time) and in the outer section (close to the entrance), which caused an abrupt and irregular variation of the outer section. In addition, the influence from the percolating water was ephemeral and depended on its supplementary amount and temperature difference, e.g., there were more apparent responses at VP1 and VP3 when the intensive rain fell. The percolating water temperature could be a good indicator for water flow in epikarst. 相似文献
18.
The Adamello gabbro exposed on the summit of Cornone di Blumone, Western Alps, Italy, has been fused by lightning strikes to form magnetite-rich fulgurites produced by melting of magnetite, hornblende, calcic plagioclase and minor clinopyroxene. The composition of quench magnetite in the fulgurite is 44.4 Fe3O4; 27.5 MgFe2O4; 15.1 FeAl2O4; 7.9 Fe2TiO4; 2.5 Fe2SiO4; 1.9 CaFe2O4; 0.8 MnFe2O4 and is inferred to have crystallized from a low-Si, Fe-rich melt under high oxidation conditions of about 1 log unit below the log10?O2 of hematite–magnetite. The low Si, Fe-rich melt is considered to have been produced from fusion of magnetite + hornblende-rich areas of the host gabbro and/or possible separation of an immiscible high Fe2O3/FeO Fe-rich, low-Si melt from a more siliceous glass during superheating. Skeletal-dendritic morphologies of magnetite in the fulgurite indicate crystallization under conditions of extreme supercooling. Juxtaposition of areas exhibiting different growth habits and crystal sizes of magnetite may reflect compositionally different local melt domains and/or small differences in the delicate balance between nucleation and growth in domains that had slightly different, although ultrafast, cooling rates. 相似文献
19.
In an external vacuum and at temperatures between 900° C and 1650° C internal graphitisation takes place on or around mineral inclusions in diamond, and appears to be responsible for similar features previously reported in diamond from several localities. Several mechanisms are proposed and discussed for internal graphitisation at temperatures as low as 900° C: it is proposed that at low external pressures CO2 exsolves from inclusions and causes internal graphitisation. The results also indicate that immediately after pressure release arising from volcanic breakthrough of kimberlites of different geological ages at several localities in West and South Africa, the temperature was not in excess of 800° C to 900° C in certain regions of the diatremes. 相似文献
20.
Henner Busemann Silvio Lorenzetti Otto Eugster 《Geochimica et cosmochimica acta》2006,70(21):5403-5425
We analyzed the spallogenic, trapped, fissiogenic and radiogenic noble gas components in various bulk samples of the angrites D’Orbigny and Sahara 99555 as well as in glass separates of D’Orbigny. The D’Orbigny glass samples show hints of solar-like noble gases, as deduced from the trapped elemental and Ne isotopic compositions; the bulk samples do not contain detectable amounts of trapped gases. These observations indicate that D’Orbigny experienced a complex history shortly after its formation 4.56 Ga ago. The glass of D’Orbigny most likely represents magma that rose from the interior of the angrite parent body (APB) and was quenched near the surface. Hence, the APB may contain—similar to the interior of Earth and Mars—solar noble gases. This would call into question the suggested trapping mechanism for solar noble gases in the Earth and Mars, which involves the solution of early atmospheres into magma oceans, due to the APB’s inability to retain a primordial atmosphere. The first detection of—possibly parentless—radiogenic excess 129Xe and solar noble gases in the glass of D’Orbigny indicates that the interior of APB degassed to a lesser degree than the outer regions. Therefore primordially trapped, fossil 129I was kept. The APB was not completely devolatilized. Sahara 99555 yields a cosmic-ray exposure age of 6.8 ± 0.3 Ma, while D’Orbigny was exposed to cosmic rays for 11.9 ± 1.2 Ma. Both ages are different than those found in the other angrites. Hence, the angrites analyzed so far sampled surface material from the APB that was ejected in at least five events. In contrast to the bulk sample, the D’Orbigny glass separates yield concordant ages of only 3.0 ± 1.1 Ma, apparently suggesting a pre-exposure of the host material. However, such a scenario is unlikely, due to very similar Mn-Cr ages found in the bulk and glass of D’Orbigny. Most likely, this discrepancy is the result of additional, secondary gas-free glass. Such glass might have been formed during the meteorite’s entry into the Earth’s atmosphere. Isotopically anomalous Xe due to the decay of 247Cm has not been found. The presence of 247Cm in glass of D’Orbigny has been suggested based on Pb isotope constraints. 相似文献