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1.
江西九瑞矿集区郎君山第三纪玄武岩的成因与岩浆演化:来自辉石和长石的矿物学证据 总被引：1，自引：0，他引：1
近期在江西九瑞矿集区朗君山地区通过钻探获取了新鲜的第三纪火山岩样品,本文对这些样品进行了系统的矿物学研究。结果表明:这些火山岩样品均为玄武岩,可明显分为两个喷发旋回,主要组成矿物为单斜辉石和斜长石,并有少量的磷灰石和铁钛氧化物等矿物。根据其矿物成分特征判断,早期旋回的玄武岩属于钾玄岩系列,晚期旋回的玄武岩属于拉斑玄武岩系列。对比两套玄武岩中单斜辉石的成分可以发现,早期玄武岩岩浆朝着富钙富锰和贫铝贫碱的方向演化,而晚期玄武岩岩浆则朝着富钛富锰和贫铝贫钙贫铬的方向演化。早期旋回玄武岩中斜长石斑晶发育反环带和韵律环带,辉石斑晶中发育正环带、反环带和韵律环带,且基质中斜长石普遍被碱性长石所交代,推测早期喷发的岩浆遭受过多次岩浆混合作用。早期旋回玄武岩中单斜辉石形成的温度为1124~1157℃,压力为1.23~1.42GPa,相应深度为41~47km,表明这套玄武岩可能是由相对原始岩浆上升到较浅部位分异形成的。根据单斜辉石F1-F2图解和Ti O2-Al Z图解判断,该区玄武岩具有明显的与弧有关的构造环境特征,推测应为弧后拉张盆地环境。 相似文献
2.
浙江嵊县—新昌盆地新生代玄武岩为橄榄拉斑玄武岩—碱性橄榄玄武岩—碧玄岩组合。根据124个矿物电子探针分析资料研究了橄榄石、单斜辉石和斜长石的种属、成分相关性及演化。根据矿物组合、单斜辉石化学成分和演化趋势以及岩石化学特征,认为本区玄武岩属于碱性玄武岩系列。 相似文献
3.
内蒙锡盟新生代玄武岩的岩石学研究 总被引：6，自引：4，他引：6
依照地层顺序和火山机构的完好程度,内蒙锡盟新生代玄武岩可粗略划分为三期。各期玄武岩又可分出若干层(次)。玄武岩由含量不等的橄榄石、单斜辉石和斜长石斑晶及基质组成。部分玄武岩含有二辉橄榄岩等深源包体。斑晶矿物均具有成分环带。矿物化学、岩石化学资料揭示出本区玄武岩从原生岩浆到进化岩浆的主要演化机制是以橄榄石为主的分离结晶作用,同时在部分进化岩浆中还存在岩浆混合作用。稀土元素资料还指出了一个形成本区原生岩浆以及派生岩浆的原生母岩浆的重要机制:上地幔渐进的部分熔融作用。 相似文献
4.
X射线衍射-X射线荧光光谱-电子探针等分析测试技术在玄武岩矿物鉴定中的应用 总被引：3，自引：3，他引：0
玄武岩的鉴定通常采用显微镜镜下判定,鉴定结果容易受到鉴定人员的专业水平和主观因素、切片方位的影响,光性特征有差异,再者颗粒细小的矿物还受到光学显微镜本身放大倍数的限制也很难准确鉴定。当前的鉴定方法已由传统的显微镜向现代分析仪器(X射线衍射仪、电子探针、X射线荧光光谱仪等)综合研究方向发展。本文采用X射线粉晶衍射(XRD)和显微镜镜下观测相结合的方法,对安徽女山玄武岩(未经蚀变)和团山玄武岩(经过蚀变)进行鉴定,并采用X射线荧光光谱仪(XRF)和电子探针对鉴定结果进行验证。结果表明:女山玄武岩用显微镜鉴定主要由基质(74%,斜长石44%+辉石30%)和斑晶(13%)组成,还含有少量金属矿物(8%)及较大颗粒石英捕掳晶(5%);其中,基质部分的斜长石经XRD分析可进一步确定为拉长石,辉石主要为普通辉石(单斜辉石),少量金属矿物为钛铁矿。团山玄武岩用显微镜鉴定主要由基质(75%,斜长石50%+辉石25%)和斑晶(9%)组成,还含有少量绿泥石充填的杏仁体;其中,基质部分的斜长石经XRD分析可进一步确定为微斜长石,蚀变矿物为蒙脱石而非薄片鉴定中的绿泥石。综合XRD和相关技术鉴定结果可确定,女山玄武岩主要矿物为拉长石、辉石、钛铁矿;团山玄武岩主要矿物为微斜长石、辉石、蒙脱石。研究显示,单独的显微鉴定技术在含蚀变矿物的玄武岩鉴定中会产生较大偏差,而结合XRD等多种分析测定技术可以快速鉴定出矿物种类,尤其对颗粒较小的矿物鉴定的准确度更高。 相似文献
5.
秦祁昆结合部夏河县八角城作海枕状玄武岩,不整合于中二叠统大关山组生物灰岩之上。枕状构造保存完好,气孔、杏仁构造发育,具斑状结构。斑晶主要为橄榄石,其次为斜长石和辉石;基质由板条状斜长石微晶、粒状辉石、橄榄石及钛铁矿等矿物组成。橄榄石斑晶发生伊丁石化、滑石化和绿泥石化,部分橄榄石完全被伊丁石化。TiO2质量分数为1.99%~2.24%,Mg#值为58~64,∑REE为（106~119）×10-6,LaN/YbN为5.6~7.1,富集Nb、Ta、Zr,以及Rb、Ba、Th、U、K等元素,高Nb/Y低Zr/Ti,并且呈现出与夏威夷、土耳其等地区OIB型碱性玄武岩相一致的稀土、微量元素配分模式曲线。橄榄石斑晶Fo值为82.73~84.57,w(CaO)均大于0.1%;斜长石斑晶An为64.72%~70.39%,基质中斜长石An为58.88%~61.53%,且斜长石斑晶较基质中斜长石呈现出低Si、Fe、Na、K、Ti和高Al、Ca特征。这些事实表明,形成该套岩石组合的原始岩浆曾经经历了橄榄石和斜长石等矿物的结晶分异作用。SHRIMP锆石U Pb测年结果表明,八角城作海玄武岩形成时代为晚三叠世Norian期（（220.5±4.2） Ma）。结合区域地质资料,在秦祁昆结合部古特提斯洋于晚三叠世俯冲消减结束并进入陆陆碰撞造山作用阶段,该时期陆陆碰撞作用引发的岩石圈拆沉作用导致岩石圈的减薄,进而形成八角城作海OIB型枕状玄武岩。 相似文献
6.
人们对超慢速扩张洋中脊深部岩浆过程的了解至今仍十分模糊。我们对西南印度洋洋中脊(Southwest Indian Ridge,SWIR) 63. 9°E处采集到的斜长石超斑状玄武岩(Plagioclase Ultra-Phyric Basalt,PUB)进行了岩石学和地球化学研究。样品具有以下几个特征:斜长石斑晶的体积分数高达～25%,而橄榄石斑晶的体积分数约1%;尽管该样品中玻璃的成分与同一洋脊段玄武岩的成分基本一致,但高Fo橄榄石斑晶与玻璃基质的成分不平衡;不同类型的斜长石晶体之间存在成分差异,单个斜长石大斑晶中的An值也呈现出与正常的结晶分异过程不符的环带;斜长石斑晶中发育溶蚀、筛状等不平衡结构。因此,我们认为,斜长石超斑状玄武岩经历了多期次熔体的作用,是由通过密度分选聚集在岩浆房顶部的斜长石斑晶被之后的火山喷发带出海底形成。尽管斜长石超斑状玄武岩与同一洋脊段的非斑状玄武岩之间并不存在母熔体成分上的差别,但超斑状玄武岩的出现进一步反映了超慢速扩张洋壳岩浆活动的多样性。 相似文献
7.
汉诺坝玄武岩中熔体-捕虏体相互作用初步研究 总被引：1，自引：0，他引：1
汉诺坝新生代玄武岩捕获的地幔橄榄岩及其解体矿物橄榄石、单斜辉石、斜方辉石捕虏晶,普遍发育反应边结构,提供了玄武岩浆在上升穿越岩石圈地幔过程中橄榄岩-熔体相互作用的重要信息。橄榄石和单斜辉石捕虏晶反应边的成分变化一致,由核部富镁向边部富铁变化,趋同于玄武岩中相应斑晶的成分。斜方辉石捕虏晶反应边一般由橄榄石+单斜辉石+玻璃构成,多为双层结构,反应边矿物橄榄石、单斜辉石较相应的地幔矿物富铁,其富硅、碱的中酸性玻璃成分,为中国东部地幔矿物包裹体中存在的富硅、碱熔体的来源提供了重要信息。同时发现橄榄岩捕虏体中尖晶石颜色、成分的变化与温度的关系。地幔矿物捕虏晶反应边结构(非平衡结构)得以保存,暗示了玄武岩浆的快速上升。而大规模的熔体-捕虏体相互作用,改变着岩石圈地幔的性质。 相似文献
8.
天和永地区南北向出露的小面积单层碱性玄武岩,岩石中出现至少三种矿物共生组合关系。所有岩石均以橄榄石作为主要斑晶矿物,大颗粒环带橄榄石斑晶中心镁值为89．5,边缘镁值为70．3,小颗粒环带橄榄石镁值46．2～78．9。粒径最小的橄榄石聚集体和散布的基质橄榄石均无明显环带,前者镁值67．4～68．1,后者镁值65．5—72．1;单斜辉石由相对高钛高铝贫硅的散布柱状辉石和相对低钛低铝富硅的聚集粒状辉石组成,前者形成于低压快速淬火环境,镁值65．1—77．1,后者形成于富含挥发份的低压低过冷度环境,镁值77．7～78．0。所有单斜辉石均以次透辉石为主,个别为深绿辉石;斜长石以包含结构产出为主,为相对偏酸性的中长石An=33．7～37．4,CaO含量低与早期大量单斜辉石结晶有关。由于残余岩浆内K,0和Na20含量富集且极不均一,晚期结晶的长石同时出现了高钠长石、K-高钠长石（歪长石）和K-透长石;钛铁氧化物多数为晚期结晶的细粒基质矿物,少量以0．3ram左右的斑晶和橄榄石斑晶中的包裹体形式存在,可归属为钛铁尖晶石（Usp）-磁铁矿（Mt）固溶体系列,晚期逐渐向贫铝、铬和富钛方向演化。由于以上各种造岩矿物的晶出,导致残余岩浆形成的火山玻璃向贫镁、铁、钙和富铝、钾方向演化,火山玻璃的全碱含量变异趋势与全岩类似,均和SiO2含量无明显相关性,火山玻璃具有响岩和粗面安山岩成分特征,K2O／Na2O值变化大0．68～1．61,均为钾玄岩系列,Na2O含量依然呈现宽区间特征,是天和永玄武岩由钾质过渡到钠质的主要原因。天和永玄武质岩浆从地幔运移到地表仅需5小时-5天,大颗粒斑晶橄榄石和小颗粒基质橄榄石生长仅需几小时到几天,前者形成无须深部岩浆房停留,后者近似晚期岩浆快速淬火时间。高镁橄榄石斑晶与残余岩浆的扩散平衡时间约42天～252天。深部结晶的橄榄石在运移途中和地表流动过程中缺乏足够的时间和适宜的动力学条件而无法离开岩浆体系。全岩与火山玻璃间缺少中间过渡成分,呈两个相对集中的端元组分存在亦由晶出矿物无法离开岩浆体系所致。天和永玄武岩的成岩时间尺度远小于同化混染和岩浆分异的时间尺度,是岩浆作用过程未能明显影响其不均一原生岩浆性质的主要原因。因此,岩浆作用的某些物理过程分析是认识岩浆起源与岩浆作用过程及其对火成岩多样性的贡献的重要方面,同时对于理解和约束岩浆作用的某些化学过程也是十分有益的。 相似文献
9.
《吉林大学学报(地球科学版)》2015,(Z1)
<正>一般我们都会选取一套玄武岩中成分最富镁的端元作为最为接近原生岩浆的成分,这种端元很可能发生了一定程度的分离结晶或堆晶作用,为此可以考察这样的火成岩中的斑晶组合和斑晶成分来获取原生岩浆成分。通常最为富镁的样品中主要是橄榄石为斑晶,其它斑晶矿物(如单斜辉石或斜长石)很少或无,而且一系列样品间显示主要是橄榄石控制全岩成分变化趋势。对于这样的样品通过添加橄榄石或减少橄榄石的含量,直到全岩成分与样品中最富镁的橄榄石斑晶平衡,此时的岩浆成分便可看做原生岩浆成分或者 相似文献
10.
松辽盆地早白垩世营城组火山岩系含有丰富的珍珠岩,为松辽盆地重要的油气勘探目的层位。在松辽盆地边缘东南隆起九台地区出露有比较新鲜的珍珠岩,内部斑晶保存完好,裂隙发育;斑晶矿物主要有斜长石、黑云母、角闪石,还有镁铁质的单斜辉石和斜方辉石。对含斑晶珍珠岩和剔除斑晶后的珍珠岩玻璃质分别进行地球化学分析,斑晶矿物进行单矿物电子探针成分研究。其结果表明：该珍珠岩属于酸性高钾钙-碱性系列,微量和稀土元素特征显示与上部地壳相似;斑晶矿物单斜辉石为斜紫苏辉石和次透辉石,斜方辉石为紫苏辉石,均显示变质成因,属于捕虏晶;与珍珠岩相邻层位玄武岩的斑晶斜长石为拉长石,单斜辉石为铁次透辉石,属于岩浆成因。这些特征表明,珍珠岩原岩可能来自于上部地壳,其辉石等捕虏晶为岩浆上侵运移过程与围岩发生混染作用的结果。 相似文献
11.
C. I. Mathison 《Australian Journal of Earth Sciences》2013,60(1):57-86
The Somerset Dam Layered Basic Intrusion is probably a sub‐volcanic magma chamber, and it consists of 20 saucer‐shaped layers composed of troctolites, olivine gabbros, ferrigabbros, and leucogabbros. The layered sequence is 1650 ft (500 m) thick, and comprises several repetitions of a standard pattern termed a zone. Each zone is generally composed of four layers, and successive mineral assemblages from the base upwards are: plagioclase‐olivine, plagioclase‐augite‐olivine, plagioclase‐augite‐magnetite‐ilmenite, and plagioclase‐uralite. Pronounced modal and textural changes define the boundaries between these layers. Within a zone, systematic variation in the proportions and compositions of minerals is thought to be the result of a slight decrease in temperature, and an increase in the partial pressures of water vapour and oxygen from the base to the top. Repetition of zones is explained by a mechanism involving periodic renewals of magma. Lack of progressive changes in mineral compositions and proportions from the base to the top of the layered sequence is also a consequence of the magma composition, the control of water vapour pressure, and the limited range of crystallisation temperatures. Gravitational settling of early minerals does not explain the variation within a zone, or the small‐scale rhythmic layering that is locally developed, and it is concluded that diffusion has been an important control. 相似文献
12.
《Geodinamica Acta》1998,11(5):205-215
We compared the disintegration processes and mineralogic and chemical evolution pathways of two Quaternary basalts at Bakrit and Ifrane, weathered in the same physiographic and hydrologic conditions, but differing in texture according to the quantity of glass present. At Bakrit, quite abundant glass favoured the formation of a microfissure network throughout the rock and its disintegration without any distinct weathering front. As a result, basaltic sand with polymineral grains and a clayey-silty matrix were produced. At Ifrane, weathering of a glass-poor basalt produced only a clayey-silty saprolite. In glass-rich basalts, secondary minerals formed in microfissures and were 2/1 clay-mineral rich. In glass-poor basalts, secondary minerals formed mainly within primary minerals and were 1/1 clay-mineral rich. Because glass could be easily dissolved, it protected the minerals of close chemical composition, especially the plagioclases. The order of basalt-mineral weathering (olivine, labrador, augite, Fe-Ti oxides) was modified when glass was abundant (glass, olivine, augite, labrador, Fe-Ti oxides). 相似文献
13.
Deccan volcanism with a tremendous burst of volcanic activity marks a unique episode in Indian geological history and covers
nearly two third of Peninsular India. Occurrences of mafic sill in the continental basalts are rather rare throughout the
flood basalt provinces and only few sporadic reports have been described from different Continental Flood Basalts of the world.
In the present article, petrology of mafic sill from the Narshingpur-Lakhnadon section of Eastern Deccan province of India
has been presented. The mafic sill in the field is found to occur in a relatively deep valley amidst Gondwana rocks, which
occur as the basement of the extrusion. The sill is spatially associated with three initial flows viz. flow I, II and III
of adjacent Narshingpur-Harrai-Amarwara section. The sill in its central part is a medium grained rock and petrographically
corresponds to dolerite containing augite, plagioclase and rare olivine grains; the chilled facies of the sill is characterized
by phenocrysts of olivine, plagioclase and augite that are set in groundmass consisting predominantly of plagioclase, olivine
and glass. Mineral chemistry indicates that olivine phenocrystal phase is magnesian (Fo61). Plagioclase phenocrystal composition
ranges from An 51 to An 71 whereas the same variation of the groundmass plagioclase composition corresponds to An 31 to An
62. The overlap in the compositions for groundmass and phenocrystal plagioclase may be explained due to fluctuating PH2O condition.
The pyroxene compositions (both groundmass and phenocryst) in majority of the cases are clubbed well within the augite field,
however, in a few cases, groundmass compositions are found to fall in the sub-calcic augite and pigeonite field. Some zoned
pyroxene phenocrysts, characteristically display different types of zoning patterns. Opaque minerals in the mafic sill are
found to be magnetite and ilmenite and this coexisting iron-oxide composition helps to constrain the prevalent fO2 condition
in the parent magma. The geochemistry of the mafic sill and associated basaltic lava flows indicates close genetic link amongst
them. Critical consideration of trace elements indicates a distinct enriched mantle source (EM-I/EM-II/HIMU) for the parental
magma. Trace element modeling indicates that equilibrium batch-melting of plume source followed by fractionation of olivine,
clinopyroxene and plagioclase and subsequent heterogeneous mixing of melt and settled crystals can very well explain the genesis
of the mafic sill and the associated basaltic flows. 相似文献
14.
Dimitrios Xirouchakis David S. DraperCraig S. Schwandt Antonio Lanzirotti 《Geochimica et cosmochimica acta》2002,66(10):1867-1880
The texture of Los Angeles (stone 1) is dominated by relatively large (0.5−2.0 mm) anhedral to subhedral grains of pyroxene, and generally subhedral to euhedral shocked plagioclase feldspar (maskelynite). Minor phases include subhedral titanomagnetite and ilmenite, Fe-rich olivine, olivine+augite-dominated symplectites [some of which include a Si-rich phase and some which do not], pyrrhotite, phosphate(s), and an impact shock-related alkali- and silica-rich glass closely associated with anhedral to euhedral silica grains. Observations and model calculations indicate that the initial crystallization of Mg-rich pigeonitic pyroxenes at ≤1150 °C, probably concomitantly with plagioclase, was followed by pigeonitic and augitic compositions between 1100 and 1050 °C whereas between 1050 and 920 to 905 °C pyroxene of single composition crystallized. Below 920 to 905 °C, single composition Fe-rich clinopyroxene exsolved to augite and pigeonite. Initial appearance of titanomagnetite probably occurred near 990 °C and FMQ-1.5 whereas at and below 990 °C and ≥FMQ-1.5 titanomagnetite and single composition Fe-rich clinopyroxene may have started to react, producing ilmenite and olivine. However, judging from the most common titanomagnetite compositions, we infer that most of this reaction likely occurred between 950 and 900 °C at FMQ-1.0±0.2 and nearly simultaneously with pyroxene exsolution, thus producing assemblages of pigeonite, titanomagnetite, olivine, ilmenite, and augite. We deem this reaction as the most plausible explanation for the formation of the olivine+augite-dominated symplectites in Los Angeles. But we cannot preclude possible contributions to the symplectites from the shock-related alkali- and silica-rich glass or shocked plagioclase, and the breakdown of Fe-rich pigeonite compositions to olivine+augite+silica below 900 °C. Reactions between Fe-Ti oxides and silicate minerals in Los Angeles and other similar basaltic Martian meteorites can control the T-fO2 equilibration path during cooling, which may better explain the relative differences in fO2 among the basaltic Martian meteorites. 相似文献
15.
AbstractWe compared the disintegration processes and mineralogic and chemical evolution pathways of two Quaternary basalts at Bakrit and Ifrane, weathered in the same physiographic and hydrologic conditions, but differing in texture according to the quantity of glass present. At Bakrit, quite abundant glass favoured the formation of a microfissure network throughout the rock and its disintegration without any distinct weathering front. As a result, basaltic sand with polymineral grains and a clayey-silty matrix were produced. At Ifrane, weathering of a glass-poor basalt produced only a clayey-silty saprolite. In glass-rich basalts, secondary minerals formed in microfissures and were 2/1 clay-mineral rich. In glass-poor basalts, secondary minerals formed mainly within primary minerals and were 1/1 clay-mineral rich. Because glass could be easily dissolved, it protected the minerals of close chemical composition, especially the plagioclases. The order of basalt-mineral weathering (olivine, labrador, augite, Fe-Ti oxides) was modified when glass was abundant (glass, olivine, augite, labrador, Fe-Ti oxides). © Elsevier, Paris 相似文献
16.
Ya. V. Bychkova E. V. Koptev-Dvornikov N. N. Kononkova E. E. Kameneva 《Geochemistry International》2007,45(2):131-151
Data obtained on the compositions of rock-forming minerals from the Kivakka layered intrusion indicate that the #Fe of olivine increases up the vertical section of the intrusion, and the #Mg of the pyroxenes and the anorthite contents of the plagioclase simultaneously decrease, which reflects the fractionation of the parental melt. Emphasis is placed onto the compositional variability of minerals in the layered unit. A method is developed for the reliable calculation of the composition of pyroxenes before their exoslution (separately for ortho-and clinopyroxene). The composition of minerals in the zone of intercalating melano-, meso-, and leucocratic norites remains practically unchanged, which is generally consistent with the results of mathematical simulations: compositional variations of the bronzite (#Mg) and plagioclase (An content) during the crystallization of the bronzite-plagioclase cotectic were no greater than 5 mol %. The variations in the concentrations of trace elements in the cumulus and intercumulus clinopyroxene occurred to be the most informative. It was determined that the Cr concentration in the cumulus augite is statistically significantly lower than that in the intercumulus augite, which is at variance with fractionation laws and led us to suggest that the rocks with cumulus pyroxenes were formed by a melt with a higher degree of fractionation than those of the intercumulus melts of the adjacent layers. 相似文献
17.
High pressure phase relations of primitive high-alumina basalts from Medicine Lake volcano,northern California 总被引：8，自引：1，他引：8
Karen S. Bartels Rosamond J. Kinzler Timothy L. Grove 《Contributions to Mineralogy and Petrology》1991,108(3):253-270
Anhydrous phase relations were determined at 1 atm and 10 to 15 kbar for primitive high-alumina basalts (79–35g and 82–72f)
from Giant Crater at Medicine Lake volcano. These compositions are multiply saturated with olivine+augite+plagioclase+spinel+/-orthopyroxene
near the liquidus at about 11 kbar. Experiments on mixtures of sample 79–35g with orthopyroxene and olivine determined the
location of the multiple saturation boundaries where liquid coexists with the assemblage olivine+augite+orthopyroxene+plagioclase
at 10 kbar and olivine+augite+orthopyroxene+spinel at 15 kbar. The mix experiments showed that primitive Medicine Lake high
alumina basalts (HABs) are close in composition to liquids in equilibrium with a mantle lherzolite source containing olivine+augite+
orthopyroxene+spinel+plagioclase at 11 kbar. Orthopyroxene observed as a near liquidus phase in an 11 kbar experiment on sample
82–72f supports this conclusion. The most primitive HABs from Medicine Lake are low in K2O (0.07 wt.%), high in MgO (>10 wt.%) and Ni (231 ppm), and have light-rare earth element depletions and large ion lithophile
element enrichments. A model for the origin of these near-primary high-alumina basalts is that they are partial melts of a
MORB-like mantle lherzolite source that has been enriched by a fluid component derived from the subducted slab. The HAB magma
segregated from its mantle residue just below the base of the crust near the crust-mantle boundary. 相似文献
18.
<正>GRV 020175 is an Antarctic mesosiderite,containing about 43 vol%silicates and 57 vol% metal.Metal occurs in a variety of textures from irregular large masses,to veins penetrating silicates, and to matrix fine grains.The metallic portion contains kamacite,troilite and minor taenite.Terrestrial weathering is evident as partial replacement of the metal and troilite veins by Fe oxides.Silicate phases exhibit a porphyritic texture with pyroxene,plagioclase,minor silica and rare olivine phenocrysts embedded in a fine-grained groundmass.The matrix is ophitic and consists mainly of pyroxene and plagioclase grains.Some orthopyroxene phenocrysts occur as euhedral crystals with chemical zoning from a magnesian core to a ferroan overgrowth;others are characterized by many fine inclusions of plagioclase composition.Pigeonite has almost inverted to its orthopyroxene host with augite lamellae, enclosed by more magnesian rims.Olivine occurs as subhedral crystals,surrounded by a necklace of tiny chromite grains(about 2-3μm).Plagioclase has a heterogeneous composition without zoning. Pyroxene geothermometry of GRV 020175 gives a peak metamorphic temperature(～1000℃) and a closure temperature(～875℃).Molar Fe/Mn ratios(19-32) of pyroxenes are consistent with mesosiderite pyroxenes(16-35) and most plagioclase compositions(An_(87.5_96.6)) are within the range of mesosiderite plagioclase grains(An_(88-95)).Olivine composition(Fo_(53.8)) is only slightly lower than the range of olivine compositions in mesosiderites(Fo_(55-90)).All petrographic characteristics and chemical compositions of GRV 020175 are consistent with those of mesosiderite and based on its matrix texture and relatively abundant plagioclase,it can be further classified as a type 3A mesosiderite.Mineralogical, penological,and geochemical studies of GRV 020175 imply a complex formation history starting as rapid crystallization from a magma in a lava flow on the surface or as a shallow intrusion.Following primary igneous crystallization,the silicate underwent varying degrees of reheating.It was reheated to 1000℃,followed by rapid cooling to 875℃.Subsequently,metal mixed with silicate,during or after which,reduction of silicates occurred;the reducing agent is likely to have been sulfur.After redox reaction,the sample underwent thermal metamorphism,which produced the corona on the olivine, rims on the inverted pigeonite phenocrysts and overgrowths on the orthopyroxene phenocrysts,and homogenized matrix pyroxenes.Nevertheless,metamorphism was not extensive enough to completely reequilibrate the GRV 020175 materials. 相似文献
19.
New data on the composition of minerals in corona textures around olivine and crystal-fluid inclusions in olivine from anorthosites of the Korosten’ pluton (sampled in the Golovino quarry), Ukrainian Shield were obtained using electron and ion microprobe analyses, Raman spectroscopy, scanning electron microscopy, and cryo- and thermometry. The corona textures developed around olivine grains in contact with plagioclase and consist of inner orthopyroxene rims around olivine and outer rims of orthopyroxene-clinopyroxene-orthoclase-plagioclase symplectites. The symplectites and orthopyroxene rims most probably developed nearly simultaneously and grew in the opposite directions from the original contact of the magmatic olivine and plagioclase and replaced both olivine and plagioclase. The Al2O3 and CaO concentrations in the symplectitic orthopyroxene increase toward the contact with magmatic plagioclase, whereas the Al2O3 and CaO concentrations in the symplectitic plagioclase simultaneously decrease and its Na2O and K2O increase. Optically discernible crystalline and fluid phases of crystal-fluid inclusions in olivine were identified as pyroxenes (orthopyroxene and clinopyroxene), actinolite, Ca-and Fe, Mg-carbonates, and magnetite, along with practically pure highdensity CO2. The mineral assemblages of corona texture in the Korsten’ anorthosites were produced by autometasomatic processes at a high CO2 activity, and the local variations in the chemistry of corona minerals were likely controlled by the content and chemistry of the interstitial fluid and primary minerals. The coronas developed under subsolidus conditions, via the reaction interaction of olivine and plagioclase under the effect of an integranular fluid, with the dissolution of olivine and plagioclase at T = 980–860°C and P > 5 kbar. Inasmuch as corona textures do not occur ubiquitously in the rocks, the origin of the former was most probably controlled by the amount of the intergranular fluid. 相似文献
20.
辽宁永宁地区发育一套闪长质火山岩，该岩石中曾选获金刚石及其指示矿物，因此成为辽宁省金刚石第Ⅳ成矿带。通过对该岩石矿物组成及其显微结构构造特征研究，表明：(1)闪长质岩石中的斑晶斜长石具有环带结构；(2)橄榄石及金云母具有多世代性，且目估橄榄石+金云母含量在10%以上，局部更为富集；(3)出现“橄榄石+金云母+石榴石”与“斜长石+辉石+角闪石”不平衡的矿物组合；(4)发现橄榄石有碎斑结构和金伯利岩角砾。初步认为，永宁地区的闪长质岩浆在上升过程中捕获了早先已形成的金伯利岩并与之发生熔融混合作用，金刚石来自于深部的金伯利岩。这一认识对该地区寻找金刚石原生矿具有启示意义。 相似文献