共查询到20条相似文献，搜索用时 566 毫秒
1.
在用离子色谱法测定温泉水样中F~-、Cl~-、Br~-、NO_2~-、NO_3~-、SO_4~(2-)、PO_4~(2-)等阴离子和Li~+、Na~+、K~+、Mg~(2+)、Ca~(2+)等阳离子过程中,研究了用油泵超声波池内脱气法处理H_2CO_3过饱和水样以排除HCO_3~-对阴离子检测干扰的方法.研究采用青岛普仁仪器有限公司生产的PIC-8型离子色谱仪,分离柱为TSK-GEL SuperIC-CationColumn(150 mm×4.5 mm)离子分离柱,以1.9 mmol/L碳酸钠-1.8mmol/L碳酸氢钠作为阴离子淋洗液,流量为1.5 Ml/min;以2 mmol/L HNO_3为阳离子淋洗液,流量为1.0 ml/min,测定了腾冲火山区叠水河、大滚锅两个温泉水中的阴阳离子的含量.研究结果表明:该方法简便、快速、准确可靠,可在火山和地震监测中推广使用. 相似文献
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Impact of environmental factors on water quality at multiple spatial scales and its spatial variation in Huai River Basin,China 总被引：1，自引：0，他引：1
XIA Jun WANG LongFeng YU JingJie ZHAN CheSheng ZHANG YongYong QIAO YunFeng WANG YueLing 《中国科学:地球科学(英文版)》2018,(1)
Quantitative assessment of water quality and its spatial variation identification, as well as the discernment of primary factors affecting water quality are in its urgent in water environment management. In this study, four key water quality indicators,namely, ammonia nitrogen(NH_4~+-N), permanganate index(COD_(Mn)), total phosphorus(TP) and total nitrogen(TN) at 71 sampling sites were selected to evaluate water quality and its spatial variation identification. More concerns were emphasized on the anthropogenic factors(land use pattern) and natural factors(river density, elevation and precipitation) to quantify the overall water quality variations at different spatial scales. Results showed that the Yi-Shu-Si River sub-basin had a better water quality status than the Huai River sub-basin. The moderate polluted area nearly distributed in the upper and middle reaches of the Shaying River and Guo River. The high cluster centers which were surrounded with COD_(Mn), NH_4~+-N, TN and TP mainly also distributed in the upper and middle reaches of the Shaying River and Guo River. Redundancy analysis showed that the 200 m buffer area acted as the most sensitive area, which was easily subjected to pollution. The precipitation was identified as the most important variables among all the studied hydrological units, followed by farmland, urban land or elevation. The point source pollution was still existed although the non-point source pollution was also identified. The urban surface runoff pollution was severer than farmland fertilizer loss at the sub-basin scale in flood season, while the farmland showed "small-scale" effects for explaining overall water quality variations. This research is helpful for identifying the overall water quality variations from the scale-process interactions and providing a scientific basis for pollution control and decision making for the Huai River Basin. 相似文献
3.
1950年以来青藏高原兹格塘错碳酸盐稳定碳同位素变化及其原因 总被引：1，自引：1，他引：0
兹格塘错是青藏高原中部一个典型的半混合型咸水湖泊。本文在~(210)Pb和~(137)Cs定年的基础上,研究了兹格塘错重力岩芯(ZGTC A-1)小于38.5μm细颗粒组分碳酸盐稳定碳同位素1950年以来的变化及其影响因素。对冬夏季湖水水化学特征的分析表明,夏季湖水溶解CO_2呈逸出状态,冬季湖水钙离子浓度是夏季湖水的10倍,据此可以得出兹格塘错碳酸盐矿物主要在夏季沉淀。通过与那曲气象站气象记录对比发现,1950年以来A-1岩芯碳酸盐碳同位素变化与年均温度有很好的相关性,表现出年均温度高时碳同位素偏重,而年均温度低时碳同位素偏轻的特征。兹格塘错1950年以来自生碳酸盐碳同位素的变化是由湖区及水体碳循环(如碳酸盐沉淀,有机质的沉淀与分解,有机碳和无机碳的转化等)的变化引起的,但各种因素的相互作用非常复杂。碳酸盐含量也与温度有关,温度越高,碳酸盐含量越高,同时降水量与碳酸盐含量也存在明显的相关关系。1950年以来有机质含量与温度呈反相关,可能与湖泊生产力的下降有关。 相似文献
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In this work, we test the hypothesis that the Mg~(2+)content in biogenic aragonite has a systematic relationship with biomolecules. A series of biomimetic experiments were conducted to show the dependence of Mg~(2+)in aragonite on the model organic molecules added to the mineralizing solution, including the concentration of various organics, mineralization temperature, Mg/Ca ratio and Mg~(2+)initial concentration. The mineralized products were characterized by powder X-ray diffraction(XRD), Fourier transform infrared spectroscopy(FT-IR), field emission scanning electron microscopy(FESEM), thermogravimetric analysis(TGA), and inductively coupled plasma-atomic emission spectrometry(ICP-AES). High Mg~(2+)is detected in aragonite obtained in the presence of organics, whereas the lowest Mg~(2+)is measured in aragonite without organics. Moreover, the concentration of Mg~(2+)in aragonite increases gradually with the amended organics. Mg K-edge NEXAFS spectra show that the magnesium microenvironment in aragonite is similar to the organic-associated environment, indicating that the Mg~(2+)ions are not on the aragonite lattices, but adhere to the intracrystalline organics. Furthermore, the mineralization temperature, Mg/Ca ratio and Mg~(2+)content in mineralization medium significantly influence Mg~(2+)content in aragonite, reiterating the effect of the microenvironment on aragonite biomineralization. 相似文献
5.
固定化氮循环细菌修复城市湖泊水体脱氮效果及N2O排放 总被引：4，自引：0，他引：4
利用从镇江金山湖天然水体中筛选分离出的土著氨化、亚硝化、硝化和反硝化细菌,将氮循环细菌固定化后在金山湖示范工程区进行水体脱氮净化效果研究.结果表明,运行一段时间后水质明显得到改善,氨氮、亚硝酸盐氮、硝酸盐氮以及总氮浓度均显著下降,氨氮浓度指标达到国家水质Ⅰ类标准,总氮浓度指标达到水质Ⅱ类标准.同时,对湖泊水体的N_2O气体排放通量进行了检测,结果显示,随着实验的进行,金山湖区的N_2O气体排放通量逐渐升高,4月份的平均值为23,51μg/(m~2·h)、5月份的平均值为29.52μg/(m~2·h)、6月份的平均值为59.10μg/(m~2·h).水质氮素指标以及N_2O气体排放通量数据说明利用微生物固定化载体强化净化技术对城市湖泊水质净化具有显著效果和重要意义. 相似文献
6.
改良型生物稳定塘对滇池流域受污染河流净化效果 总被引：5，自引：1，他引：4
对滇池流域大清河生物稳定塘系统中的水质净化效果进行了分析,同时对各塘中的浮游藻类种类组成、细胞密度和多样性进行了调查。结果表明,当污水流经预处理塘、好氧塘、水生植物塘、养殖塘的过程中,pH、DO、叶绿素a浓度呈逐渐上升趋势,TN、TP、NH_4~+-N、BOD_5和COD浓度呈逐渐下降趋势,生物稳定塘系统对TN、TP、NH_4~+-N、BOD_5和COD的去除率分别达29.29%,48.68%,33.68%,68.14%和71.25%。叶绿素a浓度和pH(r=0.955,P0.05)、DO(r=0.992,P0.01)显著正相关,而和TN(r=-0.936,P0.05)、TP(r=-0.925,P0.05)以及NH_4~+-N(r=-0.927,P0.05)等显著负相关。在塘系统中,共出现浮游藻类53种,藻类种类数和生物多样性呈增加趋势,总细胞密度呈下降趋势;塘系统中共出现6种藻类优势种,其中绿色微囊藻和惠氏微囊藻细胞密度呈现出逐渐下降的趋势,梅尼小环藻、啮蚀隐藻、美丽网球藻和球囊藻细胞密度呈现出逐渐上升的趋势。 相似文献
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三峡水库典型支流上游区和回水区营养状态分析 总被引：10，自引：3，他引：7
2006年3、5、8月,对三峡水库成库后5条支流的上游区和回水区水质参数及营养因子分布进行了初步研究.研究结果表明,支流高锰酸盐指数范围在1.00-2.50mg/L、COD范围为6.00-26.5mg/L,上游区与回水区有机物含量差异不大,支流目前未受到有机物污染影响.NH_4~+-N范围为0.039-0.367mg/L,各支流含量均为丰水期最大.TN范围在0.58-1.67mg/L,TP范围在0.005-0.133mg/L,支流回水区TN和TP含量均远高于水体发生富营养化的最低限制值,水体存在发生富营养化的风险.大多支流N/P比值处于适宜藻类生长范围.Chl.a浓度范围为0.94-28.9mg/m~3,各支流回水区Chl.a浓度均为5月最大河流回水区Chl.a浓度高于上游区,上游区、回水区Chl.a含量有显著差异.选用修正的Carlson营养状态指数(Trophic State Index)TSI_M法,评价了支流水体营养状态,TSI_M指数范围在36.0-64.2,上游区除龙河、澎溪河5月达到富营养水平外,其余支流均为贫-中营养水平.回水区各支流均达到中-富营养水平.支流回水区营养状态指数均高于上游区,但各支流增加幅度不同.支流回水区水体营养状态明显受三峡水库蓄水水体流速减缓的影响.Chl.a与COD(n=15,P0.01)呈极显著正相关,与其它营养因子无明显相关关系.三峡水库完工后,支流回水区水体流速减缓,富营养化趋势可能加重. 相似文献
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《Acta Geochimica》2021,(3)
The aim of this study was to evaluate groundwater fitness for domestic and irrigational use in Unnao district of Uttar Pradesh,India.For this study,block wise(n=16) groundwater samples were collected,and measured parameters were analyzed using the pollution index of groundwater(PIG),various irrigational indices,and graphical techniques.The results of this study suggested that most of the parameters were within the prescribed limits of WHO and BIS,excluding F~-(0.4 to 2.6 mg L~(-1))and Fe~(2+)(0.1 to 1.7 mg L~(-1)).Concentrations of total dissolved solids(TDS) were exceeded the desirable limit( 500 mg L~(-1)) in 43.75% of samples at some sites.The Gibbs plot revealed that groundwater chemistry was governed by rock-water interaction in the region,especially silicate weathering.The Piper plot suggested that Ca~(2+)-HCO_3~-is dominant hydrochemical facies in the area followed by mixed Ca~(2+)-Na~+-HCO_3~-type,Na~+-Cl~-type,and Na~+-HCO_3~-type.PIG evaluation revealed that the contribution of F~-and Fe~(2+) in groundwater degradation is high in comparison to other elements in the region,about 18.75% samples showed low pollution,while about 6.25% samples shows moderate pollution,and 6.25%samples reflected high pollution.The human health risk(HHR) assessment finding suggested that children(mean:1.36) are more vulnerable than adults(mean:1.01).Sodium absorption ration(SAR),Residual sodium carbonate(RSC),and Permeability index(PI) indicated that most of the groundwater was suitable for irrigation,whereas,Magnesium hazard ration(MHR) and Potential salinity(PS) indices suggested that only 37.5% and 56.25%of the samples were suitable for irrigational use,respectively.This regional study would help in decision making for stakeholders and relevant authorities in the execution of groundwater management and remediation plans in the area. 相似文献
9.
《Acta Geochimica》2021,(1)
Trace elements(and their isotopes) in carbonates are commonly used to reconstruct paleoenvironment and paleoclimate.Understanding the processes and mechanisms of element incorporation into carbonates is thus crucial for using such geochemical parameters as paleoclimate proxies.In contrast to laboratory-based experimental results,the partitioning of trace metals between solid and solution phases in natural carbonate precipitation systems has rarely been reported.In this study,we investigated the partition coefficients of metal ions between solid and solution in the channel of the natural Baishuitai travertine system,Yunnan,China.Our results show that the partition coefficients of Li~+,Na~+,Mg~(2+),Sr~(2+) and Ba~(2+)are 1,that of Ni~(2+) is approximately 1,and those of Co~(2+),Mn~(2+),Zn~(2+) and Cu~(2+) are 1,consistent with the results found in previous experimental studies.Although the substitution for Ca~(2+) is likely the main uptake process of these metals into calcite,depending on their ionic radius and charge,trace elements may also be incorporated by adsorption or physical entrapment.Our study shows that unlike laboratory experiments performed under specific conditions,the partitioning of metals between two phases in the natural travertine system could be controlled by several,even multiple,environmental factors(e.g.,carbonate deposition rate,temperature,and pH),which should be taken into account when using trace metals(and their isotopes) in carbonate archives as a paleoclimate proxy. 相似文献
10.
沉水植物生长对沉积物间隙水中的氮磷分布及界面释放的影响 总被引：16，自引：2，他引：14
采集未破坏沉积物结构的柱状沉积物样品,通过室内41 d的培养实验,研究了沉水植物生长过程对间隙水中NH_4~ -N和PO_4~(3-)-P的浓度的动态影响,分析了沉水植物生物量与沉积物中氮磷释放通量的对应关系．结果表明：随沉水植物生长和生物量增加,上部0-5 cm沉积物垂向各层间隙水中NH_4~ -N含量呈逐步降低,表现出沉积物-水界面氮的释放通量与沉水植物生物量存在负相关性;而间隙水PO_4~(3 )-P含量则随沉水植物生长呈单峰型变化,磷释放通量与生物量相关性不明显．初步反映沉水植物在沉积物的生长过程中对氮磷吸收的生物地球化学机制是不同的． 相似文献
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Nasir Ahmed Md.Bodrud-Doza S.M.Didar-Ul Islam Manzoor Ahmad Choudhry Md.Iftakharul Muhib Anwar Zahid Shahadat Hossain Md.Moniruzzaman Nipa Deb Md.Abdul Quaiyum Bhuiyan 《Acta Geochimica》2019,(3):440-455
To investigate the hydrogeochemical characteristics of groundwater 23 shallow, 30 intermediate and 38 deep wells samples were collected from Sylhet district of Bangladesh, and analyzed for temperature, pH, Eh, EC,DO, DOC, Na^+, K^+, Ca2+, Mg2+, Cl^-, SO_42-, NO_3^-,HCO_3^-, SiO_2^-, Fe, Mn and As. Besides, 12 surface water samples from Surma and Kushiyara Rivers were also collected and analyzed to understand the influence into aquifers. Results revealed that, most of the groundwater samples are acidic in nature, and Na–HCO_3 is the dominant groundwater type. The mean value of temperature, EC,Na^+, K^+, Ca2+, Mg2+, Cl^-, NO_3^- and SO_42- were found within the range of permissible limits, while most of the samples exceeds the allowable limits of Fe, Mn and As concentrations. However, relatively higher concentration of Fe and Mn were found in deep water samples and reverse trend was found in case of As. The mean concentrations of As in shallow, intermediate and deep wells were 39.3, 25.3and 21.4 lg/L respectively, which varied from 0.03 to148 lg/L. From spatial distribution, it was found that Fe,Mn and As concentrations are high but patchy in northern,north-western, and south-western part of Sylhet region. The most influential geochemical process in study area were identified as silicate weathering, characterized by active cation exchange process and carbonate weathering, which thereby can enhance the elemental concentrations in groundwater. Pearson's correlation matrix, principal component analysis and cluster analysis were also employed to evaluate the controlling factors, and it was found that, both natural and anthropogenic sources were influencing the groundwater chemistry of the aquifers. However, surface water has no significant role to contaminate the aquifers,rather geogenic factors affecting the trace elemental contamination. Thus it is expected that, outcomes of this study will provide useful insights for future groundwater monitoring and management of the study area. 相似文献
14.
南极洲万达盐湖为饱和方解石湖水。计算出的方解石饱和指数随水深增加而变化。在Ca~(2+)及HCO_3~-活度值均一的上部氧化环境湖水中,pH及溶解氧(DO)是控制该变化的主要因素,在下部还原环境湖水中,Ca~(2+)及HCO_3~-的活度对方解石的饱和指数SI的变化起主要作用。这充分揭示了湖底部近代沉积物中分布较多方解石矿物的原因。 相似文献
15.
《Acta Geochimica》2017,(4)
While it is critical to accurately understand the sources and transformation of sulfate based on time-series analysis, there are limited studies on temporal variation of sulfate in rivers and on rock weathering by sulfuric acids.We conducted a monthly sampling campaign in the Beipan, Nanpan, and Hongshui Rivers over the course of one hydrological year. This study examined seasonal variations in riverine sulfate impacted by the monsoon climate in the upper reaches of the Xijiang River basin. In general, the SO_4~(2-) contents in these rivers dropped from relatively high levels to low values during the high-flow season, in response to increasing discharge. The sulfate was generally enriched in heavy isotopes during the low-flow season compared to the high-flow season. The calculated results indicate that the riverine sulfate was mainly derived from sulfide oxidation, but that evaporite dissolution could be an important source during the low-flow season, based on isotopic evidence. Mine drainage is likely an important source of sulfate to these rivers during the high-flow season due to contributions from fast surface flow, which responds to frequent heavy rain in monsoonal climate regions. Arelatively high proportion of HCO_3~- was found to be derived from rock weathering by sulfuric acid during the high-flow season when compared to that observed during the low-flow season. The results suggest that approximately one quarter of the HCO_3~- in the Hongshui River originated from carbonate weathering by sulfuric acid derived from the oxidation of sulfide. Such information on the specific dual isotopic characteristics of riverine sulfate throughout a hydrological year can provide unique evidence for understanding the temporal variability of sulfate concentrations and weathering processes in rivers. 相似文献
16.
藏南普莫雍错流域水体离子组成与空间分布及其环境意义 总被引：18，自引：3，他引：15
对藏南普莫雍错湖水及其周围人湖河流水体进行了离子化学成分分析,对部分湖泊和河流水样作氧同位紊分析.结果显示,不同入湖河流离子组成与湖水本身离子组成有较大差异.湖水的主要离子组合是Mg2 -Ca2 -HCO3-SO42-,而主要补给河流加曲为Ca2 -Mg2 -HCO3-.加曲人湖河口2m水深以内水化学性质差异大,湖泊其他地区差异小.加曲对河口三角洲之上湖水影响显著.其他河流对河口处湖水影响较小.Gibbs图显示湖水离子的组成主要与流域内的岩石风化有关.离子比例和三角图分析说明控制入湖河水离子主要过程是碳酸盐、黄铁矿和硅酸盐风化.湖泊与河流水体离子的组成差异较大,原因可能是蒸发浓缩导致的CaCO3的沉淀.其结果有助于正确理解湖泊沉积碳酸盐的环境指示意义. 相似文献
17.
藏南羊卓雍错流域水化学主离子特征及其控制因素 总被引：14，自引：1，他引：13
水化学主离子特征是流域湖泊的一个重要特征,对气候以及河流所经地区的环境具有指示作用.本文对藏南羊卓雍错流域水化学主离子组成特征及其控制因素进行分析,结果显示流域内不同水体(湖水、河水、地下水)之间的主离子组成以及水化学类型差异显著.其中,羊卓雍错的水化学类型为SO24--HCO3--Mg2+-Na+,巴纠错为SO24--Mg2+-Na+,沉错为SO24--Na+-Mg2+-Ca2+,普莫雍错为HCO3--SO24--Mg2+-Ca2+,空姆错为HCO3--SO24--Ca2+;流域河水中主要阴离子为HCO3-和SO24-,Ca2+为绝对优势阳离子;流域地下水化学类型则为HCO3--Ca2+.究其原因,流域水体化学组成主要受岩石风化作用控制;除此,羊卓雍错、巴纠错和沉错水化学组成亦受自身蒸发-结晶作用的影响.就入湖河水而言,羊卓雍错入湖河水整体受碳酸盐岩石风化的影响较大,蒸发岩溶解的影响次之;沉错和空姆错入湖河流(卡鲁雄曲)的蒸发岩来源则略大于碳酸盐岩来源;而硅酸盐对流域内河水的水化学性质影响较小.与入湖河水相比,羊卓雍错和沉错湖水的Mg2+、Na+和SO24-含量较高,而Ca2+和HCO3-含量较低.这应该与湖水蒸发强烈使得湖水中Ca2+和HCO3-析出并沉积到湖底有关.而空姆错由于湖泊面积小、入湖河水流量大,致使其湖水与入湖河水的主离子组成差异不显著. 相似文献
18.
《Acta Geochimica》2015,(2)
Phosphorus(P) species in surface sediments from a shallow,hypertrophic lake,Lake Dianchi,China,were investigated by P fractionation and ~(31)P nuclear magnetic resonance(NMR) spectroscopy during a regional algal bloom.In addition,their potential contributions to the overlying water were also evaluated.Labile fractions of P extracted by NH_4C1,bicarbonate dithionite and NaOH ranged from 340.6 to 1,725.8 mg kg~(-1),accounting for20.5%-67.2%of the total P.A two-step extraction method refinement of P recovery was performed before the~(31)P NMR analysis.Recovery rates of sedimentary TP and organic P,by combining EDTA pretreatment and NaOH or mixed reagents,ranged from 31.8%to 69.3%and from19.8%to 51.7%.~(31)P NMR results showed that ortho-P and monoester-P were the most abundant P components in the sediment extractable P of sediments,followed by diester-P and pyro-P.Spatial distribution of the sum of ortho-P,diester-P and pyro-P detected by P NMR corresponded well with the labile P concentration determined by fractionation.Both exhibited a significant positive correlation with the total P in the water column,suggesting that internal loading may be an important source of P for the lake ecosystem.Biogenic P other than ortho-P may contribute to phytoplankton growth,with the relative proportion being 4.4%-18.7%.The release of labile P fractions fueled algal bloom,and the decay of organic matter,following the bloom events,consumed oxygen and elevated the pH value.This co-dependence might lead to a vicious cycle.Transformation mechanisms of various P species remain ambiguous and are worthy of further investigation. 相似文献
19.
本文根据OMNI、TC-2卫星、LANL系列卫星、Cluster星簇卫星(C1-C4)以及加拿大的8个中高纬地磁台站的观测数据,研究了2005年8月24日强磁暴(SYM-Hmin~ -179 nT)主相期间的强亚暴(ALmin~ -4046 nT)事件特征.该强磁暴在大振幅(IMF Bz min~ -55.57 nT)、短持续时间(~90 min)的行星际磁场条件下产生,有明显的磁暴急始(SSC),强度较大且持续时间较短.发生在磁暴主相期间的亚暴发展的主要特征如下:亚暴增长相期间,C1-C4卫星先后穿越中心等离子体片;亚暴膨胀相触发后,在近地磁尾(X~-6RE)可观测到磁场偶极化现象;等离子体无色散注入区在亚暴onset开始后迅速沿经向扩展,但被限制在有限的经度范围;磁纬60°附近,Pi2地磁脉动振幅超过了100 nT.膨胀相开始后,在中、高磁纬地磁台站可观测到负湾扰,近地磁尾可观测到Pi2空间脉动,中磁尾区域可观测到尾向流、磁重联以及O+/H+数密度比值在亚暴onset之后增大等现象.分析表明该强磁暴主相期间的强亚暴现象发生时序是自内向外:X~-6RE处TC-2观测到磁场偶极化(~09:42:30 UT),同步轨道卫星LANL1994-084观测到等离子体无色散注入(~09:44:30 UT),X~-17.8RE处C1观测到磁场重联(~09:45:30 UT),由此推断该亚暴事件很可能是近地磁尾不稳定性触发产生,其发生区域距离地球很近. 相似文献
20.
松花江哈尔滨段水域硅藻植物群落及其水质的初步评价 总被引：5，自引：2，他引：3
2005-2006年5-9月、12月的两年间,在松花江哈尔滨段水域进行了硅藻植物的调查采集,经观察鉴定,共发现硅藻植物72种43变种3变型,分别隶属于2纲6目9科23属,共计118个分类单位。本文对松花江哈尔滨段水域的环境特征,硅藻植物群落组成、种类丰度的季节性变化进行了研究,利用硅藻植物与环境相关性特点对水质进行了初步评价。研究结果表明松花江段哈尔滨水域的硅藻植物群落,总体来说以普生种类(共计86个分类单位)为每年的常见种类,还有一些嗜碱种类和冷水种类出现;硅藻种类的丰度随季节变化明显,从夏季到秋季逐渐增多。硅藻的群落结构变化主要受pH,温度,TN,BOD_5,氨氮的影响,从优势种的组成来看,β-中污以上的污水指示种类数量最多,一些富营养化种类和耐污种类也有出现,说明2005-2006年松花江流域水质污染呈中度至重度污染。 相似文献