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1.
The Cretaceous Banhad?o alkaline complex in southeastern Brazil presents two potassic SiO2-undersaturated series. The high-Ca magmatic series consist of initially fractionated olivine (Fo92-91) + diopside (Wo48-43En49-35Ae0-7), as evidenced by the presence of xenocrysts and xenoliths. In that sequence, diopside (Wo47-38En46-37Ae0-8) + phlogopite + apatite + perovskite (Prv>92) crystallized to form the phlogopite melteigite and led to the Ca enrichment of the magma. Diopside (Wo47-41En32-24 Ae3-14) continued to crystallize as an early mafic mineral, followed by nepheline (Ne74.8-70.1Ks26.3-21.2Qz7.6-0.9) and leucite (Lc65-56) and subsequently by melanite and potassic feldspar (Or85-99Ab1-7) to form melanite ijolites, wollastonite-melanite urtites and melanite-nepheline syenites. Melanite-pseudoleucite-nepheline syenites are interpreted to be a leucite accumulation. Melanite nephelinite dykes are believed to represent some of the magmatic differentiation steps. The low-Ca magmatic series is representative of a typical fractionation of aegirine-augite (Wo36-29En25-4Ae39-18) + alkali feldspar (Or57-96Ab3-43) + nepheline (Ne76.5-69.0Ks19.9-14.4Qz15.1-7.7) + titanite from phonolite magma. The evolution of this series from potassic nepheline syenites to sodic sodalite syenites and sodalitolites is attributed to an extensive fractionation of potassic feldspar, which led to an increase of the NaCl activity in the melt during the final stages forming sodalite-rich rocks. Phonolite dykes followed a similar evolutionary process and also registered some crustal assimilation. The mesocratic nepheline syenites showed interactions with phlogopite melteigites, such as compatible trace element enrichments and the presence of diopside xenocrysts, which were interpreted to be due to a mixing/mingling process of phonolite and nephelinite magmas. The geochemical data show higher TiO2 and P2O5 contents and lower SiO2 contents for the high-Ca series and different LILE evolution trends and REE chondrite-normalized patterns as compared to the low-Ca series. The 87Sr/86Sr, 143Nd/144Nd, 206Pb/204Pb and 208Pb/204Pb initial ratios for the high-Ca series (0.70407–0.70526, 0.51242–0.51251, 17.782–19.266 and 38.051–39.521, respectively) were slightly different from those of the low-Ca series (0.70542–0.70583, 0.51232–0.51240, 17.758–17.772 and 38.021–38.061, respectively). For both series, a CO2-rich potassic metasomatized lithospheric mantle enriched the source with rutile-bearing phlogopite clinopyroxenite veins. Kamafugite-like parental magma is attributed to the high-Ca series with major contributions from the melting of the veins. Potassic nephelinite-like parental magma is assigned to the low-Ca series, where the metasomatized wall-rock played a more significant role in the melting process.  相似文献   

2.
The Larkman Nunatak (LAR) 06319 olivine-phyric shergottite is composed of zoned megacrysts of olivine (Fo76-55 from core to rim), pyroxene (from core to rim En70Fs25Wo5, En50Fs25Wo25, and En45Fs45Wo10), and Cr-rich spinel in a matrix of maskelynite (An52Ab45), pyroxene (En30-40Fs40-55Wo10-25,), olivine (Fo50), Fe-Ti oxides, sulfides, phosphates, Si-rich glass, and baddeleyite. LAR 06319 experienced equilibration shock pressures of 30-35 GPa based on the presence of localized shock melts, mechanical deformation of olivine and pyroxene, and complete transformation of plagioclase to maskelynite with no relict birefringence. The various phases and textures of this picritic basalt can be explained by closed system differentiation of a shergottitic melt. Recalculated parent melt compositions obtained from melt inclusions located in the core of the olivine megacrysts (Fo>72) resemble those of other shergottite parent melts and whole-rock compositions, albeit with a lower Ca content. These compositions were used in the MELTS software to reproduce the crystallization sequence. Four types of spinel and two types of ilmenite reflect changes in oxygen fugacity during igneous differentiation. Detailed oxybarometry using olivine-pyroxene-spinel and ilmenite-titanomagnetite assemblages indicates initial crystallization of the megacrysts at 2 log units below the Fayalite-Magnetite-Quartz buffer (FMQ - 2), followed by crystallization of the groundmass over a range of FMQ - 1 to FMQ + 0.3. Variation is nearly continuous throughout the differentiation sequence.LAR 06319 is the first member of the enriched shergottite subgroup whose bulk composition, and that of melt inclusions in its most primitive olivines, approximates that of the parental melt. The study of this picritic basalt indicates that oxidation of more than two log units of FMQ can occur during magmatic fractional crystallization and ascent. Some part of the wide range of oxygen fugacities recorded in shergottites may consequently be due to this process. The relatively reduced conditions at the beginning of the crystallization sequence of LAR 06319 may imply that the enriched shergottite mantle reservoir is slightly more reduced than previously thought. As a result, the total range of Martian mantle oxygen fugacities is probably limited to FMQ − 4 to − 2. This narrow range could have been generated during the slow crystallization of a magma ocean, a process favored to explain the origin of shergottite mantle reservoirs.  相似文献   

3.
Lunar meteorite Northwest Africa 773 (herein referred to as NWA773) is a breccia composed predominantly of mafic volcanic components, including a prominent igneous clast lithology. The clast lithology is an olivine-gabbro cumulate, which, on the basis of mineral and bulk compositions, is a hypabyssal igneous rock related compositionally to volcanic components in the meteorite. The olivine-gabbro lithology exhibits cumulus textures and, in our largest section of it, includes some 48% olivine (Fo64 to Fo70, average Fo67), 27% pigeonite (En60Fs24Wo16 to En67Fs27Wo6), 11% augite (En50Fs17Wo33 to En47Fs13Wo40), 2% orthopyroxene (En70Fs26Wo4), 11% plagioclase (An80 to An94), and trace barian K-feldspar, ilmenite, Cr-spinel, RE-merrillite, troilite, and Fe-Ni metal. The Mg/Fe ratios of the mafic silicates indicate equilibration of Fe and Mg; however, the silicates retain compositional variations in minor and trace elements that are consistent with intercumulus crystallization. Accessory mineralogy reflects crystallization of late-stage residual melt. Both lithologies (breccia and olivine cumulate) of the meteorite have very-low-Ti (VLT) major-element compositions, but with an unusual trace-element signature compared to most lunar VLT volcanic compositions, i.e., relative enrichment in light REE and large-ion-lithophile elements, and greater depletion in Eu than almost all other known lunar volcanic rocks. The calculated composition of the melt that was in equilibrium with pyroxene and plagioclase of the cumulate lithology exhibits a KREEP-like REE pattern, but at lower concentrations. Melt of a composition calculated to have been in equilibrium with the cumulate assemblage, plus excess olivine, yields a major-element composition that is similar to known green volcanic glasses. One volcanic glass type from Apollo 14 in particular, green glass B, type 1, has a very low Ti concentration and REE characteristics, including extremely low Eu concentration, that make it a candidate parent melt for the olivine-gabbro cumulate. We infer an origin for the parent melt of NWA773 volcanic components by assimilation of a trace-element-rich partial or residual melt by a magnesian, VLT magma deep in the lunar crust or in the mantle prior to transportation to the near-surface, accumulation of olivine and pyroxene in a shallow chamber, eruption onto a volcanic surface, and incorporation of components into local, predominantly volcanic regolith, prior to impact mixing of the volcanic terrain and related hypabyssal setting, and ejection from the surface of the Moon. Volcanic components such as these probably occur in the Oceanus Procellarum region near the site of origin of the green volcanic glasses found in the Apollo 14 regolith.  相似文献   

4.
Ca-rich and Ca-poor pyroxenes present in the Bushveld rocksof the Bethal area display well developed exsolution texturestypical of slowly cooled mafic intrusions. This gave rise topoor reproducibility in electron microprobe analyses of thesame pyroxene grain, as well as results which departed fromthe bulk composition of the original homogeneous mineral. EMMA-4was used together with the electron microprobe to establishthe composition of the constituent phases in exsolved pyroxenes.The data showed that microprobe analyses carried out with adefocused beam were equivalent to the bulk composition of thepyroxenes. Microprobe analyses obtained using a focused beamwere found to approach closely the bulk composition of pyroxenesonly when the exsolution density reached 90 lamellae per millimetre. Transmission electron microscope examination of microstructuresin ion-thinned samples of pyroxenes at 100 kV and 1000 kV showedthat the exsolution mechanism in Ca-rich and Ca-poor pyroxeneswas one of heterogeneous nucleation. Subsequent growth tookplace by means of the migration of ledges along the (100) plane.Pigeonite inversion was also shown to occur in iron-rich Ca-poorpyroxene exsolution lamellae in augite. Fractionation trends established for the Bethal pyroxenes frommicroprobe analyses indicated an overall range from Fs14En84Wo2to Fs60En31Wo9 in the Ca-poor pyroxene and Fs7En50Wo43 to Fs36En27Wo37in the Ca-rich pyroxene. Comparison of pyroxene fractionationtrends from the western, eastern and Bethal areas of the Bushveldsuggests that crystallization took place under different conditionsof pressure and temperature.  相似文献   

5.
河北武安坦岭多斑斜长斑岩的成因:冻结岩浆房活化机制   总被引：5，自引：3，他引：2  
流变学实验表明,当岩浆中晶体体积分数达到约50vol%时,岩浆体实际上处于冻结状态,不再具有整体迁移的能力。但在自然界中仍存在含大量斑晶的浅成火成岩和火山岩。因此,富晶体岩浆的上升过程和侵位机制是近年来地球科学领域关注的热点之一。目前,冻结岩浆房的活化机制主要有二种:升温活化机制和流体活化机制。河北武安坦岭地区新发现的多斑斜长斑岩为揭示冻结岩浆房的活化提供了契机。野外观察和晶体粒度分布(CSD)分析表明,坦岭斜长斑岩中斜长石斑晶高达70vol%,基质为显微晶质结构。斜长石斑晶粒径分布均一,大小约为3.1×1.7mm;显微镜观察和背散射图像揭示,斜长石斑晶具环带结构,由宽广的斜长石核部+宽度可变的条纹长石边部组成,且无熔蚀现象;电子探针成分剖面分析表明,斑晶核部成分为更长石(An_(27)Ab_(71)Or_2),幔部为更长石(An_(13)Ab_(83)Or_4),边部为条纹长石。边部条纹长石的成分有一定变化,从内侧到外侧,主晶钠长石成分由Ab_(53)Or_(47)变为Ab_(99)Or_1,客晶钾长石成分由Ab_(48)Or_(51)变为Ab3Or97。斑晶斜长石核部存在细长条状或斑点状钾长石,且越靠近中心,钾长石斑点的数量越少。这些特点表明,边部条纹长石为交代成因。稀土和微量元素分析则显示,边部条纹长石具弱正Eu异常,相对富集LREE和K、Rb、Ba、Sr等大离子亲石元素,亏损Th、Zr、Nb的特点。CSD相关图解及以上特征表明,斜长石斑晶形成于稳定,封闭的结晶环境,并受到晚期碱交代作用的改造。基质主要由微粒钙质角闪石,条纹长石,石英,钾长石和钠长石组成,含少量自形-半自形磁铁矿和钛铁矿、磷灰石、榍石、金红石和锆石等11种矿物组成。11种矿物相和结构特征暗示基质形成于极端不稳定的结晶环境,与斜长石斑晶形成条件鲜明对照。根据基质的矿物组成,推测形成基质的岩浆具有富含K、Na、Fe、Si和挥发分的特征。这种特征与上述关于条纹长石环边形成条件的判断一致。据此,本文认为:产生斜长石斑晶的岩浆曾经在地壳深部作过长时间滞留,导致了斜长石的稳定结晶,增加了岩浆的粘度和密度,使岩浆处于冻结状态;富碱高铁熔体-流体流的注入大幅降低了岩浆的总粘度,并提高了岩浆的浮力,从而促使冻结岩浆房迅速活化和上升侵位;同时,富碱高铁熔体-流体流强烈交代了先存的斜长石斑晶,使其边部形成条纹长石;这种熔体-流体流则在快速排气,冷却过程中迅速结晶,形成了具有不平衡矿物组合的显微晶质基质。在岩浆侵入体较深部位,富碱高铁熔体-流体经历了很缓慢的固结过程,而相分离产生的流体有可能萃取携带岩浆中的铁质,形成富Fe流体流,后者可能对区内"铁矿浆"型铁矿的形成具有重要的贡献。  相似文献   

6.
The Precambrian Sierra Ancha sill complex, more than 700 feet thick, is a multiple intrusion with a central layer of feldspathic olivine-rich diabase, and upper and lower layers of olivine diabase derived from a high-alumina basalt magma. Minor rock types include albite diabase and albite-diabase pegmatite. Deuteric alteration was extensive. Principal primary minerals are plagioclase (An72 to An16), augite (Wo43En44Fs13 to Wo40En38Fs22), olivine (Fo74 to Fo54), orthopyroxene (En77 to En44), magnetite (Mgt66Usp34 to Mgt89Usp11), and ilmenite (Ilm86Hem14 to Ilm96Hem4). Ilmenite formed by reaction-exsolution from magnetitess is consistently different in compositon from primary ilmenite. Primary ilmenite became enriched in Mn and depleted in Mg as crystallization proceded. A systematic Fe-Mg partition between contacting olivine and orthopyroxene suggests that equilibrium prevailed on an extremely local scale during crystallization. Albite-diabase pegmatite contains a mineral assemblage including augite, ferrosalite (Wo49En28Fs23 to Wo49En14Fs37), albite (An2 to An0), and iron-rich chlorite. Altered diabase and albite diabase also have unusually calcium-rich pyroxenes. The calcium-rich pyroxenes, which occur in assemblages like those characterizing some spilites, are richer in calcium and lower in aluminum and titanium than basaltic augite.Contribution No. 1712 of the Division of Geological Sciences, California Institute of Technology, Pasadena, California.  相似文献   

7.
Diffuse streaks in diffraction patterns of synthetic pyroxene single crystals at elevated temperatures are used to determine which reactions are initiated and how they proceed. The samples investigated are a) a host orthopyroxene (Wo4En83Fs13) containing oriented pigeonite (Wo6En78Fs16) parallel to (100) and b) a pigeonite (Wo8En75Fs17). The maximum temperatures were 820° C and 1,015° C, respectively. No partial melting occurs at these temperatures, all reactions are in the subsolidus. In case a) augite is formed parallel to the (001) plane of pigeonite, but the augite is not exsolved by the pigeonite. This is proved by the absence of the obligatory streaks between corresponding reflections in highly resolved precession photographs. Instead, there are streaks from augite to the corresponding reflections of the host orthopyroxene. Example b) demonstrates that the temperature of the high-low transformation of pigeonite is very sensitive to the Ca content and clearly depends on the exsolution of augite. This augite is oriented parallel to (100) of pigeonite, not to (001). Both the high and the low pigeonite are present over a range of ～150° C, while the exsolution of augite continues. Simultaneously, orthopyroxene is also formed sharing (100) of pigeonite. There seems to be an indication that only low pigeonite inverts to orthopyroxene.  相似文献   

8.
The electrical conductivities of alkali feldspar solid solutions ranging in chemical composition from albite (NaAlSi3O8) to K-feldspar (KAlSi3O8) were measured at 1.0 GPa and temperatures of 873–1,173 K in a multi-anvil apparatus. The complex impedance was determined by the AC impedance spectroscopy technique in the frequency range of 0.1–106 Hz. Our experimental results revealed that the electrical conductivities of alkali feldspar solid solutions increase with increasing temperature, and the linear relationship between electrical conductivity and temperature fits the Arrhenius formula. The electrical conductivities of solid solutions increase with the increasing Na content at constant temperature. At 1.0 GPa, the activation enthalpy of solid solution series shows strong dependency on the composition, and there is an abrupt increase from the composition of Or40Ab60 to Or60Ab40, where it reaches a value of 0.96 eV. According to these results in this study, it is proposed that the dominant conduction mechanism in alkali feldspar solid solutions under high temperature and high pressure is ionic conduction. Furthermore, since the activation enthalpy is less than 1.0 eV for the alkali feldspar solid solutions, it is suggested to be a model where Na+ and K+ transport involves an interstitial mechanism for electrical conduction. The change of main charge carriers can be responsible for the abrupt increase in the activation energy for Or60Ab40. All electrical conductivity data were fitted by a general formula in order to show the dependence of activation enthalpy and pre-exponential factor on chemical composition. Combining our experimental results with the effective medium theory, we theoretically calculated the electrical conductivity of alkali feldspar granite, alkali feldspar quartz syenite, and alkali feldspar syenite with different mineral content and variable chemical composition of alkali feldspar at high temperatures at 1.0 GPa, and the calculated results are almost in agreement with previous experimental studies on silicate rocks.  相似文献   

9.
The Johnstown meteorite is a brecciated orthopyroxenite (diogenite) containing coarsegrained centimeter-sized clasts of cumulate origin that have undergone subsolidus recrystallization. The brecciated portion is dominated by subangular fragments of orthopyroxene (Wo2–3En72–74Fs23–25) in a variably comminuted matrix of the same material. Minor and accessory phases include plagioclase (An82–90Ab10–18Or0–1), diopside (Wo44–45En46–47Fs9–10), olivine (Fo71–72), tridymite, troilite, metallic Ni-Fe (~3% Ni), and chromite (Cm71–80Hc1–8Sp11–19Mt2–4Uv1–3).The clastic component is parental to the brecciated matrix which contains no foreign lithic or mineralogic components. Siderophile trace element studies, however, reveal the presence of meteoritic (chondritic) contamination in the brecciated portion using unbrecciated clasts for indigenous values. Rare earth element abundances show a wide range of values for the light REE in different samples, although all samples exhibit a strong negative Eu anomaly, indicative of earlier plagioclase fractionation. Two pairs of adjacent brecciated and unbrecciated samples from different portions of the meteorite show, respectively, the most enriched and the most depleted light REE patterns. The variability in La content is over a factor of 100. However, in each case the REE pattern for the brecciated portion is very similar to that of the unbrecciated portion. These differences are attributed to sampling of variable amounts of residual, REE-enriched, trapped liquid. The most representative REE pattern for the bulk meteorite has an intermediate composition and was obtained from the largest sample. The data presented here indicate that Johnstown is a monomict breccia, in contrast to several other diogenites which may be considered to be polymict on the basis of their mineral compositions and/or clast populations.  相似文献   

10.
Abstract A suite of granulites including a meta-ironstone, pyroxenites, and spinel-lherzolites from East Tonagh Island, Enderby Land, Antarctica, preserve exsolution-recry-stallization features consistent with a shared metamorphic evolution that involves marked cooling from initial metamorphic temperatures of nearly 1000°C. Reintegrated pre-exsolution and pre-reaction grain compositions in the meta-ironstone indicate the former coexistence of metamorphic pigeonite (Wo12En38Fs50) and ferroaugite (Wo35En31Fs34) at temperatures in excess of 980°C for pressures of 7 kbar (0.7 GPa) using pyroxene quadrilateral thermometry (Lindsley, 1983). Intra-grain lamellae relationships indicate the exsolution of a second pigeonite (Wo12En35Fs53) from the ferroaugite at temperatures in the range 930–970°C, prior to the c. 720–600°C exsolution of orthopyroxene and clinopyroxene (100) lamellae and later partial recrystallization at similar temperatures. Although pyroxenitic and iherzolitic granulites preserve a much less complete history, reintegrated porphyroclast compositions in these yield temperature estimates which approach those inferred from the metaironstone. Pyroxene thermometry based on neoblast compositions suggests that recrystallization post-dating a late, low intensity, deformation phase (D3) occurred at temperatures greater than 600°C. These results are consistent with the independent evidence obtained from studies of metapelitic and felsic rock types for very high temperature metamorphism throughout the Napier Complex followed by near-isobaric cooling and later deformation under lower-grade granulite facies conditions. Comparison with similar pyroxene data from Fyfe Hills (Sandiford & Powell, 1986) demonstrates further the regional significance of these high temperatures, and implies broadly isothermal metamorphic conditions over a large area (～ 5000 km2) and thickness (6–9 km) of lower crust at c. 3070 Ma.  相似文献   

11.
Miocene volcanism of the Oglakci region (Sivrihisar, Eskisehir) in northwestern Central Anatolia, Turkey, is represented by basaltic and trachytic groups of rocks. Samples of both groups have been investigated using mineral-chemical data together with whole-rock major-, trace-element, and radiogenic Sr-Nd isotopic data. The basaltic volcanic rocks consist of mugearites and shoshonites, whereas the trachytic rocks include trachytes, latite, and rhyolite. Both groups are of alkaline character. The basaltic rocks contain plagioclase (An29-63), alkali feldspar (Or12-74), olivine, orthopyroxene (En64-67), clinopyroxene (Wo43-48), biotite (Mg#82-88), and Fe-Ti oxide phenocrysts, whereas the trachytic rocks contain plagioclase (An21-64), alkali feldspar (Or10-53), clinopyroxene (Wo41-49), amphibole (Mg#64-83), biotite (Mg#79-85), Fe-Ti oxide, titanite, apatite, and quartz phenocrysts. The measured 87Sr/86Sr ratios of basaltic samples range from 0.7045 to 0.7048, and those of trachytic samples from 0.7054 to 0.7056. The basaltic samples have 143Nd/144Nd ratios ranging from 0.512753 to 0.512737, and those of trachytic samples are 0.512713 to 0.512674. Isotopic, major-, and trace-element data suggest that the Oglakci volcanic rocks are products of postcollisional magmatism and originated from a complex interplay of crustal assimilation, magma mixing, and fractional crystallization processes following the demise of Neotethys. Trace-element characters also are consistent with an OIB-like mantle source. These volcanic rocks probably were associated with extensional tectonics, which occurred within the Anatolian plate as a result of collision of the Eurasian and Afro-Arabian plates during the neotectonic evolution of Turkey.  相似文献   

12.
Orthopyroxene-magnetite intergrowths (symplectites), partly or completely surrounding olivine, are described from the Wateranga layered mafic intrusion, Queensland, Australia. The texture occurs in unmetamorphosed plagioclase-rich norites, olivine gabbros and troctolites in which the primary minerals are olivine (Fo63–69) orthopyroxene (En66–72), clinopyroxene (Wo42En42Fs16), plagioclase (An49–65), hornblende, ilmenite, magnetite and sulphides. Symplectites range from incipient fine grained developments around corroded olivine grains to intricately formed pseudomorphs after olivine and slow a consistent orthopyroxene/magnetite ratio. Orthopyroxene in symplectites is commonly in optical continuity with surrounding magnetite-free orthopyroxene rims. Later intercumulus hornblended has replaced orthopyroxene. There is marked chemical similarity between primary and simplectite, orthopyroxenes and magnetites. Textures similar to those described here are considered elsewhere to have formed at a late magmatic stage or by solid state reactions involving subsolidus oxidation of olivine. In the Wateranga intrusion textural relations, the chemical similarity between primary and symplectite phases, and the consistent volume proportions of magnetite and orthopyroxene in the intergrowths suggest that they developed during late magmatic crystallization.  相似文献   

13.
We report on the petrology and geochemistry of the Northwest Africa 2737 (NWA 2737) meteorite that was recovered from the Morrocan Sahara in 2000. It is the second member of the chassignite subclass of the SNC (Shergotitte-Nakhlite-Chassignite) group of meteorites that are thought to have originated on Mars. It consists of black olivine- and spinel-cumulate crystals (89.7 and 4.6 wt%, respectively), with intercumulus pyroxenes (augite 3.1 wt% and pigeonite-orthopyroxene 1.0 wt%), analbite glass (1.6 wt%) and apatite (0.2 wt%). Unlike Chassigny, plagioclase has not been observed in NWA 2737. Olivine crystals are rich in Mg, and highly equilibrated (Fo = 78.7 ± 0.5 mol%). The black color of olivine grains may be related to the strong shock experienced by the meteorite as revealed by the deformation features observed on the macroscopic to the atomic scale. Chromite is zoned from core to rim from Cr83.4Uv3.6Sp13.0 to Cr72.0Uv6.9Sp21.1. Pyroxene compositional trends are similar to those described for Chassigny except that they are richer in Mg. Compositions range from En78.5Wo2.7Fs18.8 to En76.6Wo3.2Fs20.2 for the orthopyroxene, from En73.5Wo8.0Fs18.5 to En64.0Wo22.1Fs13.9for pigeonite, and from En54.6Wo32.8Fs12.6 to En46.7Wo44.1Fs9.2 for augite. Bulk rock oxygen isotope compositions confirm that NWA 2737 is a new member of the martian meteorite clan (Δ17O = 0.305 ± 0.02‰, n = 2). REE abundances measured in NWA 2737 mineral phases are similar to those in Chassigny and suggest a genetic relationship between these two rocks. However, the parent melt of NWA 2737 was less evolved and had a lower Al abundance.  相似文献   

14.
Ultramafic-mafic rocks from Makrirrakhi, Central Greece exhibit features of an original ophiolite sequence which contains depleted mantle material, ultramafic containing partial melt textures and possibly the mafic pluton which resulted from the coalescing of these partial melt segregations. Considerable mineralogical variation exists: unzoned olivine crystals range in composition from Fo78–84 (mafics) to Fo88–92 (ultramafics), plagioclases An64–79 (mafics) to An80–90 (ultramafics) and spinel varies from a chromian spinel (ultramafics) to a more aluminous-titaniferous spinel (mafics). Pyroxenes from the ultramafics display a limited range: En89–92 Fs9–8 Wo0–2 (orthopyroxene) and En48–54 Fs1–10 Wo38–50 (clinopyroxene). Mafic rocks display a greater range being richer in ferrosilite En36–65 Fs3–20 Wo33–51. Pyroxenes from within the partial melt segregations have chemical affinities with those from the gabbrotroctolite series. A model of partial melt within the upper mantle, and, a set of criteria to distinguish partial melt textures from cumulate textures, are developed from analytical data and textural evidence.  相似文献   

15.
南极月球陨石MIL05035矿物学、岩石学及演化历史   总被引：1，自引：0，他引：1  
月球陨石MIL05035岩石类型上属于普通辉石低钛玄武岩,粗粒辉长结构,无角砾化。主要矿物为辉石(60.2%)、斜长石(27.3%)和橄榄石(6.05%),次要矿物为石英(4.36%)、钛铁矿(1.25%)和陨硫铁(0.84%),含极少量富Ti、Fe尖晶石和磷灰石,广泛发育由钙铁辉石+铁橄榄石+石英组成的后成合晶三相集合体。辉石颗粒具有明显的化学成分不均匀性和出溶片晶,核部相对贫铁钙富镁(Fs30.2-60.8Wo14.2-35.0),边部富铁钙贫镁(Fs47.5-64.9Wo22.8-44.3)。熔长石化斜长石具有微弱的成分环带,边部相对富碱金属元素(Ab9.3-12.3,Or0.31-1.03),核部则相反(Ab7.6-10.6,Or0.12-0.36),含有未熔长石化的残留斜长石。橄榄石具有粗晶橄榄石(Fa95.5-96.6)和后成合晶中细粒橄榄石(Fa88.9-93.5)两种产状。石英具有脉状、团块状和蠕虫状等产状:脉状石英大部分转变为二氧化硅玻璃,核部石英具有较宽的拉曼谱特征峰(448~502cm-1),证明其经历了冲击变质与退变质作用;团块状石英分布于粗粒橄榄石颗粒间或橄榄石与斜长石和辉石接触边界上,与斜长石构成充填结构;蠕虫状石英分布于细粒后成合晶中。粗粒辉石边部铁辉石和后成合晶中辉石成分的继承性、结构上的延续性、光学特征上的冲击暗化现象、与冲击熔脉结构上的相关性和后成合晶中发育与粗粒辉石方向几乎一致的解理等方面的证据,认为后成合晶可能由于铁辉石在冲击压力释放与温度降低后的退变质作用下分解形成。根据岩石矿物结构观察、成分分析和MELTS模拟表明该陨石母岩的岩浆演化过程可能为:母岩浆在温度降低后首先产生极少量钛铁尖晶石、其次是普通辉石和钙长石先后结晶;随着温度下降,贫钙铁普通辉石、铁钙铁辉石和铁普通辉石等在普通辉石边部大量结晶,钙长石边部分异结晶少量培长石或拉长石;随着温度继续下降,早期结晶的普通辉石析出易变辉石等出溶片晶,橄榄石在辉石和斜长石边部结晶;其后,钛铁矿和陨硫铁析出,石英沿橄榄石和钙长石等先结晶矿物裂隙充填。出露月表后强烈的冲击变质作用使斜长石几乎全部转变为熔长石、石英大部分转变为二氧化硅玻璃,并具有一系列面状变形,冲击熔脉发育,冲击变质程度至少为S5。本研究为月球的岩浆演化和冲击变质过程提供了重要证据。  相似文献   

16.
A unique clinopyroxene (En19Fs78Wo3), clinoeulite, space group P21/c, $${\text{(Fe}}_{{\text{1}}{\text{.48}}} {\text{Mg}}_{{\text{0}}{\text{.37}}} {\text{Mn}}_{{\text{0}}{\text{.08}}}^{{\text{2 + }}} {\text{Ca}}_{{\text{0}}{\text{.05}}} {\text{Al}}_{{\text{0}}{\text{.01}}} {\text{)}}_{{\text{1}}{\text{.99}}} {\text{ [Si}}_{{\text{2}}{\text{.01}}} {\text{O6],}}$$ contains sharp exsolution lamellae of ferroaugite (En17Fs43Wo40) from which the former presence of a ferropigeonite near En17Fs70Wo13 can be calculated. This two-pyroxene intergrowth is the main component of a eulysite containing also magnetite, olivine (Fo9Fa86Te5), quartz, oligoclase-K feldspar inter-growth, and retrograde cummingtonite with about 76 % grunerite end member. The occurrence of this most unusual rock type in the center of the Vredefort structure is attributed to a period of high-temperature metamorphism (at least 800 °–850 °C) which was followed by hot deformation of the rock during the Vredefort event thus probably preventing the common formation of orthopyroxene through pigeonite exsolution and inversion upon cooling. After this tectonic deformation, the rock recrystallized within the low-temperature stability range of clinoeulite to yield fine annealing textures. Late-stage equilibria at temperatures well below 500 °C include the complete unmixing of a former high-temperature anorthoclase, a Mg/Fe redistribution in the clinoeulite and olivine and, with the introduction of water, the partial formation of cummingtonite through reaction of clinoeulite, olivine, and quartz. During weathering the olivine was transformed to a nearly opaque, anhydrous ferrisilicate which, except for the change of Fe2+ to Fe3+ and the oxygen introduction, largely retained its original chemistry.  相似文献   

17.
Spinel-lherzolite xenoliths in alkali basalts from eastern China have porphyroclastic to equigranular textures displaying varying degrees of deformation and subsolidus re-equilibration. The proportions of minerals in these xenoliths vary from 52 to 72% homogeneous olivine (Fo88-91); 11 to 26% orthopyroxene (Wo0.9.1.6; En88-90; Fs8.7.10.7), with minor discontinuous variations of Al2O3, FeO, and CaO; 6 to 19% clinopyroxene (Wo43.47; En49.51; Fs3.7.6.7); and 1 to 5% spinel, with similar Mg# (79.6 to 82.6), but wider variations of Al2O3 and Cr2O3 (100Cr/(Cr + Al + Fe3+) = 8.1 to 23.6). Although previous trace-element and isotopic studies have shown that at least two distinctly different mantle sources were sampled by Cenozoic basalts, mineralogical heterogeneities seem to be minor within the spinel-peridotite-facies lithosphere beneath eastern China.

These xenoliths experienced limited interaction with the host basaltic magma during eruption. Symplectites of secondary, minute silicates, titanomagnetite, and sulfide have replaced orthopyroxene—and to a lesser extent olivine—at the contact with the basalt. The spinel in the margin of the xenolith is continuously zoned by substitutions of Fe3O4 (magnetite) and Fe2TiO4 (ulvospinel) for MgAl2O3 (spinel), and is rimmed by titanomagnetite with a sharp boundary. However, the compositions of the interior clinopyroxenes were commonly modified by metasomatic partial melting, which resulted in “spongy-textured” rinds on primary clinopyroxene. This secondary assemblage is composed mainly of a refractory, jadeite-poor clinopyroxene, which is largely in optica! continuity with the primary clinopyroxene in addition to interstitial feldspars, with minor titanomagnetite and Fe-Ni sulfides. This assemblage was produced by the introduction of K-rich fluids from the enclosing basaltic magma. The intensity of these secondary reactions appears to have been a function of the residence time of the xenolith in the host basalt. Therefore, all secondary alteration of both external and internal primary minerals in these xenoliths are the result of near-surface metasomatic processes, rather than of mantle phenomena.  相似文献   

18.
The occurrence of a rare mantle-derived chrome-diopside megacryst (～8 mm), containing inclusions of olivine, in a lamprophyre dyke from the late Cretaceous polychronous (～100 – 68 Ma) Mundwara alkaline complex of NW India is reported. The olivine inclusions are forsteritic (Fo: 85.23) in composition, and their NiO (0.09 wt%) and CaO (0.13 wt%) contents imply derivation from a peridotitic mantle source. The composition of the chrome diopside (Cr2O3: 0.93 wt ) (Wo45.27 En48.47 Fs5.07 and Ac1.18) megacryst is comparable to that occurring in the garnet peridotite xenoliths found in diamondiferous kimberlites from Archaean cratons. Single pyroxene thermobarometry revealed that this chrome diopside megacryst was derived from a depth range of ～100 km, which is relatively much deeper than that of the chrome-diopside megacrysts (～40–50 km) reported in spinellherzolite xenoliths from the alkali basalts of Deccan age (ca. 66–67 Ma) from the Kutch, NW India. This study highlights that pre- Deccan lithosphere, below the Mundwara alkaline complex, was at least ～100 km thick and, likely, similar in composition to that of the cratonic lithosphere.  相似文献   

19.
Two suites of felsic eruptives and intrusives are represented in a set of samples from the summit region of the Plio-Pleistocene volcano, Mt. Kenya. Most of the samples are moderately or strongly undersaturated and have 87Sr/86Sr initial ratios in the range 0.70360–0.70368 (mean=0.70362). Members of this phonolitic suite are phonolites, nepheline syenites or kenytes and as a group they show a wide variation in TiO2, FeO, P2O5, Sr, Ba, Zr and Nb. The minor and trace element geochemistry reflect variation in the nature of the parental basaltic magmas from which the phonolitic rocks evolved and variation in the crystal fractionation process in individual cases. Crystal fractionation involving plagioclase, alkali feldspar, clinopyroxene, olivine and magnetite is the process by which most of the phonolitic rocks evolved and variation in the relative proportions of these phases in individual cases has led to a broad spectrum of trace and minor element behaviour. The second suite of felsic samples is critically saturated and consists of trachytes showing either slight oversaturation or slight undersaturation with respect to SiO2. This trachyte suite has lower initial 87Sr/86Sr ratios (mean=0.70355) and is derived from transitional alkalic basalts by low pressure (crustal) crystal fractionation involving feldspar, clinopyroxene, magnetite and olivine. The range in minor and trace element chemistry observed among the felsic rocks is a consequence of variation in the parental basalts which is related to mantle source variation and to the specific nature of the crystal fractionation process.  相似文献   

20.
The late-stage basanite (～12–1 Ma) of the NNW-SSE extending Gharyan Cenozoic volcanics (Northern West Libya) contains numerous fresh lherzolite xenoliths. These xenoliths display magmatic protogranular and porphyroclastic textures. Chemistry of olivine (forsterite content –90–91, NiO = 0.26–0.39 wt %), orthopyroxene (Mg# = 0.91–0.92, Cr# = 0.03–0.07, Al2O3 = 3.64–4.43 wt %), clinopyroxene ((Wo45.59–48.61, En45.89–48.80, Fs4.47–5.81), Mg# = 0.82–0.92, Al2O3 = 5.14–6.58 wt % and Cr2O3 = 0.5–0.95 wt %) and spinel (hercynite–picotite–Al-rich chromite spinels with Cr# = 0.08–0.11) refer to the fertile nature of Gharyan peridotites. Mantle source region was close to the primitive composition with low degrees of melting and depletion in melt (1.5% in average). However, it underwent metasomatism as illustrated by formation of secondary clinopyroxene (Wo37.96–44.77, En47.44–54.18, Fs7.59–8.03) with high contents of Na2O, and enrichment of the Al-spinel in TiO2. The estimated pre-eruptive temperature ranges from 1066 to 837°C. Despite the Gharyan peridotite is similar to mantle components in many districts in Saharan belt of North Africa, it represents juvenile mantle source with minor refractory residues. This compositional heterogeneity is mainly attributed to the local effect of the interaction of the Gharyan mantle with the host basanite magma that may be related to the Cenozoic rifting of the Pan-African basement.  相似文献   

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