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1.
Re-Os isotopes were used to constrain the source of the ore-forming elements of the Tharsis and Rio Tinto mines of the Iberian Pyrite Belt, and the timing of mineralization. The pyrite from both mines has simila]r Os and Re concentrations, ranging between 0.05–0.7 and 0.6–66 ppb, respectively. 187Re/188Os ratios range from about 14 to 5161. Pyrite-rich ore samples from the massive ore of Tharsis and two samples of stockwork ore from Rio Tinto yield an isochron with an age of 346 ± 26 Ma, and an initial 187Os/188Os ratio of about 0.69. Five samples from Tharsis yield an age of 353 ± 44 Ma with an initial 187Os/188Os ratio of about 0.37. A sample of massive sulfide ore from Tharsis and one from Rio Tinto lie well above both isochrons and could represent Re mobilization after mineralization. The pyrite Re-Os ages agree with the paleontological age of 350 Ma of the black shales in which the ores are disseminated. Our data do not permit us to determine whether the Re-Os isochron yields the original age of ore deposition or the age of the Hercynian metamorphism that affected the ores. However, the reasonable Re-Os age reported here indicates that the complex history of the ores that occurred after the severe metamorphic event that affected the Iberian Pyrite Belt massive sulfide deposits did not fundamentally disturb the Re-Os geochronologic system. The highly radiogenic initial Os isotopic ratio agrees with previous Pb isotopic studies. If the initial ratio is recording the initial and not the metamorphic conditions, then the data indicate that the source of the metals was largely crustal. The continental margin sediments that underlie the deposits (phyllite-quartzite group) or the volcanic rocks (volcanogenic-sedimentary complex) in which the ores occur are plausible sources for the ore-forming metals and should constrain the models for the genesis of these deposits. Received: 15 March 1999 / Accepted: 26 July 1999  相似文献   

2.
会泽超大型铅锌矿是滇东北铅锌多金属成矿域中典型的密西西比河谷型(MVT)或会泽型(HZT)矿床,因其独特的成矿系统以及矿床中富锗而被地质学者熟知,由于该类型矿床成矿温度较低且缺少合适的定年矿物,其成矿时代一直存在较大的争议。本文在会泽铅锌矿麒麟厂矿区1584中段0-11号穿脉坑道块状铅锌硫化物矿石中挑选了9件硫化物样品(黄铁矿、方铅矿和闪锌矿),采用负离子热表面电离质谱法进行Re-Os同位素分析,获得Re-Os等时线年龄为40.7±2.6 Ma(n=9),与模式年龄加权平均值40.0±2.6Ma(n=8)在误差内完全一致,闪锌矿和方铅矿模式年龄分别为38.24±0.41 Ma和36.57±0.40 Ma。上述同位素年龄揭示了会泽超大型铅锌矿的成矿时代可能为始新世。结合滇东北铅锌矿集区NE向逆冲断层和冲断褶皱控矿构造区域构造解析以及断裂、矿体构造-岩相蚀变特征,提出会泽超大型铅锌矿经历了燕山期、喜山期两阶段构造-流体贯入的成矿作用模型。  相似文献   

3.
湘西大溶溪钨矿床中辉钼矿Re-Os同位素定年及其地质意义   总被引：9，自引：2，他引：7  
湘西大溶溪钨矿床,为雪峰隆起区内的一个中型白钨矿矿床。文章对该矿床中穿插钨矿体的含辉钼矿石英脉进行了Re-Os同位素年代学研究。分析结果显示,该矿中辉钼矿的Re-Os同位素模式年龄为217.0~221.1 Ma,平均为（219.0±1.2） Ma,其对应的等时线年龄为（223.3±3.9） Ma,揭示其形成于晚三叠世。这些年龄数据与矿区内大神山花岗岩的侵位时间〔（224.3±1.0） Ma〕基本吻合,表明该区含辉钼矿石英脉的形成与花岗岩的侵位具有密切的时、空联系。考虑到该区钨矿体的形成时间介于花岗岩和含辉钼矿石英脉之间,因此,推断大溶溪钨矿床形成于223 Ma左右。该研究成果,不仅为湘西雪峰隆起区存在多期次的钨成矿事件提供了可靠证据,同时又进一步证实了华南地区确实存在一次区域性的与印支期花岗岩有关的成矿作用。  相似文献   

4.
The Yaogangxian deposit in the central Nanling region, South China consists of vein-type ore bodies hosted in Cambrian to Jurassic strata and Mesozoic granitic intrusions. Wolframite and molybdenite are the dominant ore minerals intergrown with gangue minerals of quartz, feldspar, phlogopite, and muscovite. We have carried out molybdenite Re–Os and phlogopite and muscovite 40Ar/39Ar dating to better understand the timing and genesis of mineralization. Re–Os dating of eight molybdenite samples yielded model ages ranging from 152.0±3.5 to 161.1±4.5 Ma, with an average of 156.0 Ma. The Re–Os analyses give a well-defined 187Re/187Os isochron with an age of 154.9±2.6 Ma (MSWD=2.4). Hydrothermal phlogopite and muscovite display extremely flat 40Ar/39Ar age spectra. Phlogopite yields a 40Ar/39Ar plateau age of 153.0±1.1 Ma, whereas muscovite yields a plateau age of 155.1±1.1 Ma. Both 40Ar/39Ar ages are in good agreement with the Re–Os ages, placing the timing of tungsten mineralization at about 154 Ma. This age is consistent with the field relationships. Our new data, when combined with published geochronological results from other major deposits in this region, suggest that large scale W–Sn mineralization occurred throughout the central Nanling region in the Late Jurassic.  相似文献   

5.
We present new Re–Os molybdenite age data on three porphyry Cu–Mo–Au deposits (Yulong, Machangqing, and Xifanping). These deposits are associated with the Himalayan adakitic magmatism that occurred in a continental collision environment, controlled by large-scale Cenozoic strike-slip faults in the eastern Indo–Asian collision zone. Three distinct episodes of Cu–Mo–Au mineralization are recognized. At Yulong, Re–Os isotopic data of four molybdenite samples from sulfide-quartz veins in the quartz–sericite alteration zone yield an isochron with an age of 40.1±1.8 Ma (2σ), coincident to a zircon sensitive high-mass resolution ion microprobe (SHRIMP) age of 40.9±0.1 Ma for the host monzogranite. The molybdenite Re–Os dates, together with K–Ar, Rb–Sr, U–Pb, and 40Ar/39Ar dates on the pre- and intra-ore porphyries, suggest that Cu–Mo–Au mineralization formed during the late stage (∼40 Ma) of regional porphyry magmatism, but hydrothermal activity probably lasted to at least ∼36 Ma. At Machangqing, molybdenite Re–Os data from the K–silicate and quartz–sericite alteration zones yield an isochron with an age of 35.8±1.6 Ma (2σ), which is identical to the zircon SHRIMP and bulk-rock Rb–Sr ages (35∼36 Ma) of the host granite, but older than bulk-rock K–Ar dates (31∼32 Ma) for associated Au-bearing quartz syenite with advanced argillic alteration. At Xifanping, five molybdenite samples from the K–silicate alteration zone yield the youngest Re–Os isochron age in the area, at 32.1±1.6 Ma (2σ). The Re–Os molybdenite dates here are younger than K–Ar ages (33.5∼34.6) for hydrothermal biotite and actinolite. There is a positive correlation between the absolute age of the deposits and their Cu and Au reserves in the eastern Indo–Asian collisional zone. Episodic stress relaxation probably caused multiple magmatic intrusions, which most likely resulted in three episodes of Cu–Mo–Au mineralization in the eastern Indo–Asian collision zone.  相似文献   

6.
新疆哈勒尕提铜铁矿床的成矿年代学研究   总被引：3，自引：0，他引：3  
首次采用锆石SHRIMP微区U-Pb测年技术,对新疆西天山哈勒尕提铜铁多金属矿床成矿岩体进行了年代学研究,通过对角闪石黑云母二长花岗岩中单颗粒锆石12个样品点的分析,获得206Pb/238U年龄介于362.7~381.7 Ma,加权平均值为（367.3±2.2）Ma,表明岩体的结晶年龄为晚泥盆世。通过ICP-MS法测定了哈勒尕提铜铁多金属矿床中的辉钼矿Re-Os同位素年龄,获得其模式年龄的加权平均值为（370.1±2.4）Ma,等时线年龄为（371±12）Ma,代表了哈勒尕提铜铁多金属矿床的成矿年龄。两种测年方法获得的年龄在误差范围内基本一致,因此该测试结果表明哈勒尕提铜铁多金属矿床与晚泥盆世角闪石黑云母二长花岗岩侵入作用密切相关,角闪石黑云母二长花岗岩为哈勒尕提铜铁多金属矿床的形成提供了成矿物质和热源。  相似文献   

7.
The large Jiguanshan porphyry Mo deposit, with more than 100 Mt of ore and grades ranging from 0.08% to 0.11%, is located in the newly identified Xilamulun metallogenic belt along the northern margin of the North China Craton. The Mo mineralization is predominantly disseminated in the host granite porphyry, but locally occurs as stockworks in lithic tuff and rhyolitic rocks. 40Ar/39Ar dates of samples from groundmass material in the host granite porphyry, post-ore diabase, and quartz porphyry dikes show plateau ages of 155.1 ± 1.9, 149.4 ± 0.9, and 147.6 ± 0.9 Ma, with inverse isochron ages of 156.0 ± 1.8, 149.3 ± 1.3, and 148.3 ± 1.2 Ma, respectively. Seven samples of disseminated molybdenite yielded a weighted average 187Re-187Os age of 155.3 ± 0.9 Ma, whereas six veinlet-type molybdenite samples yielded a weighted average 187Re-187Os age of 153.0 ± 0.9 Ma, providing direct timing constraints for the Mo mineralization at 153–155 Ma. The regional geological setting together with the emplacement of post-ore diabase and quartz porphyry dikes in the Jiguanshan deposit, are indicative of an extensional regime in Late Jurassic, which was probably linked to lithospheric extension in northeast China.  相似文献   

8.
The absolute timing of epigenetic mineralization, including most types of gold deposits, is difficult to resolve due to the absence of suitable minerals in veins and replacement zones. However, gold is commonly closely associated with pyrite and arsenopyrite, which may be amenable to Re–Os geochronology, providing sufficient Re and Os are present within them. This short paper outlines the use of this method to date two gold deposits in Newfoundland using pyrite. Although the Os contents of the pyrites are extremely low (≪0.1 ppb), the Os is almost exclusively radiogenic 187Os, and data are amenable to model age calculations, as used in Re–Os molybdenite dating. The pyrites from these deposits correspond to low-level highly radiogenic sulphides, as defined by other studies. The Stog’er Tight and Pine Cove gold deposits yield mean Re–Os model ages of 411 ± 7 Ma (n = 4) and 420 ± 7 Ma (n = 5), respectively, which agree with isochron regression of 187Os against 187Re. The Re–Os age for Stog’er Tight is within uncertainty of a previous U–Pb age from ‘hydrothermal’ zircon (420 ± 5 Ma) in spatially related alteration. A latest Silurian–earliest Devonian age for the mineralization is consistent with indirect age constraints from some other gold deposits in central Newfoundland and suggests a broad temporal link to the mid-Silurian Salinic Orogeny. However, the gold mineralization appears to be younger than most plutonic activity associated with this event. The results illustrate the potential value of Re–Os pyrite geochronology in understanding the temporal framework of epigenetic mineralization, especially if future improvements in analytical precision and reductions in procedural blanks allow wider application to material with similarly low Re and Os concentrations.  相似文献   

9.
陕西洛南县石家湾钼矿Re-Os同位素年龄及地质意义   总被引：1，自引：0，他引：1  
陕西石家湾钼矿床位于东秦岭成矿带西段黄龙铺地区,钼矿化呈细脉-网脉状分布于花岗斑岩体及其围岩中,与矿化有关的围岩蚀变有钾长石化、硅化、绢云母化,属斑岩型矿床.在矿床中选取不同矿化类型的辉钼矿样品,进行了Re～Os同位素定年,获得模式年龄变化范围为143.1±2.1～145.1±2.2 Ma之间,其加权平均年龄(144.0±1.1 Ma,MSWD=0.91)、等时线年龄(145.4±2.1 Ma,MSWD=0.83)与石家湾斑岩体的成岩年龄(141.4±0.6Ma)相近,说明成岩成矿作用发生在晚侏罗世一早白垩世.综合辉钼矿中Re的含量、硫同位素以及相关岩体的源区特征等多方面证据认为,石家湾斑岩型钼矿的成矿物质主要来自于下地壳,并混有少量幔源成分.  相似文献   

10.
Both stratiform/stratabound and granite-related models have been used to explain the genesis of W(Mo) deposits in the Okiep copper district in western Namaqualand, South Africa. Apparently, stratabound mineralization (Fe-rich wolframite with accessory molybdenite) occurs in foliation-parallel quartz veins in high-grade (∼750 °C, 5–6 kbar) metapelites of the Wolfram Formation, and less commonly in small bodies of silicified leucogranites and pegmatites. Six Re–Os ages for molybdenites from four deposits (Nababeep Tungsten Far West, Kliphoog, Narrap, Tweedam) range between 1000 ± 4 and 1026 ± 5 Ma. These molybdenites define a well-constrained 187Re–187Os isochron with an age of 1019 ± 6 Ma, which is interpreted as the age of W(Mo) mineralization. This age is significantly younger than Proterozoic protolith ages for supracrustal rocks and the emplacement ages for the main intrusive suites, but geologic evidence requires overlap with a period of high-grade metamorphism. We suggest that W(Mo) mineralization is genetically linked to intra-crustal magmatic processes at ∼1020 Ma, thereby precluding the ∼1060 Ma Concordia granite as the source for mineralizing fluids. A narrow range of positive δ34S compositions (+3.6 to +4.5‰) for eight molybdenites from five W(Mo) mines is consistent with a SO2-rich fluid and a granite-related genetic model. Post-peak metamorphic deformation and metamorphism of W(Mo) ores is most likely related to the retrograde stage of the Namaquan orogeny, which overlaps emplacement of late-orogenic, evolved granites and pegmatites, and the formation of W(Mo) deposits in western Namaqualand. Therefore, the effects of retrograde Namaquan metamorphism extend at least to ∼1020 Ma or, alternatively, these W(Mo) veins were affected by a poorly constrained later event (e.g. early Pan-African). Received: 12 September 1999 / Accepted: 20 April 2000  相似文献   

11.
Zijinshan is the largest high-sulfidation epithermal Cu–Au deposit on mainland China. The primary mineralization at the deposit is characterized by pyrite, digenite and covellite. Although some RbSr isochron ages of the fluid inclusions in quartz and the apparent K-Ar age of the Cu-bearing alunite alteration zone have been previously interpreted as the ore-forming age, the Rb-Sr and K-Ar dating systems are usually readily reset due to their closure temperature, and thus document the latest thermal event. In order to precisely determine the age of the Cu mineralization, eight-pyrite separates were Re-Os dated, and seven yielded an isochron age of 103 ± 4 Ma with an initial 187Os/188Os ratio of 0.45 ± 0.14. This date is interpreted as the age of Cu mineralization, which is in agreement with geochronological data from molybdenite and the porphyritic granodiorite that hosts Cu-Mo mineralization at Luoboling (located 2 km NE of Zijinshan), suggesting that these two deposits were formed during the same metallogenic event. The relatively low initial 187Os/188Os ratio indicates that the source of the Cu at Zijinshan is predominantly the crust with input from the mantle.  相似文献   

12.
通过对修水县莲花芯石英脉型Cu-Mo-W矿床的辉钼矿进行Re-Os同位素测年,获得的w(普Os)为0.0083×10-9~0.1535×10-9,加权的平均年龄为(157.7±2.8)Ma,计算得到辉钼矿Re-Os等时线年龄为(158.6±2.0)Ma(MSWD=0.63),与加权平均年龄在误差范围内一致,可代表辉钼矿的形成年龄,成矿作用时代晚于赋矿围岩晋宁期黑云母花岗岩的成岩时代。对比区域成岩成矿作用时代,认为该矿床可能与燕山期花岗岩岩浆活动有关,是赣北大规模钨多金属成矿序列演化的产物之一,属于华南中生代第二次大规模成矿作用(165~135 Ma)的产物。  相似文献   

13.
Reproducibility of Re-Os molybdenite ages depends on sample size and homogeneity, suggesting that Re and Os are decoupled within individual molybdenite crystals and do not remain spatially linked over time. In order to investigate the Re-Os systematics of molybdenite at the subgrain (micron) scale, we report LA-ICP-MS Re-Os ages for an Archean molybdenite crystal from Aittojärvi, Finland, analyzed in situ in a white aplite matrix. A related Aittojärvi molybdenite (A996D), in the form of a very fine-grained mineral separate, is used as one of our in-house NTIMS standards, and thus its age of 2760 ± 9 Ma is well established. Measurements of (187Re + 187Os)/185Re on micron scale spots along 200 μm traverses across the crystal yield a wide range of ages demonstrating that, in this case, microsampling of molybdenite does not produce geologically meaningful ages. Experimentation with mineral separations and sample size over a 7-yr period predicted that this would be the outcome. We suggest that 187Os is more likely to be the mobile species, based on its charge and ionic radius, and that 187Os becomes decoupled from parent 187Re with time on the micron and larger scale. Incompatible charge and ionic radius for Os ions formed during reduction of molybdenite-forming fluids may explain the widely observed absence of common (initial) Os in molybdenite. Geologically accurate ages for molybdenite can only be obtained for fully homogenized crystals (or crystal aggregates) so that any post-crystallization 187Re-187Os decoupling is overcome.A growing number of geologically accurate ID-NTIMS 187Re-187Os ages for homogenized molybdenite suggest that postcrystallization mobility of radiogenic 187Os must be limited to within the molybdenite mineral phase. We suggest that radiogenic 187Os may be stored in micron scale dislocations, kink bands, and delamination cracks produced by deformation, and that the unusual structure and deformation response of molybdenite results in an increased chemical stability in this mineral. Migration of 187Os into adjacent silicate phases is highly unlikely, but other contacting sulfides may take in Os. In an example from a Proterozoic skarn deposit at Pitkäranta (western Russia), we demonstrate minor loss of radiogenic 187Os from molybdenite and a corresponding gain in adjacent chalcopyrite such that the molybdenite age is not perceptibly disturbed, whereas the resulting chalcopyrite ages are impossibly old. Therefore, it is unadvisable to perform Re-Os analytical work on any sulfide in contact or intimate association with molybdenite. In addition to large errors in the age, if the isochron method is employed, initial 187Os/188Os ratios could be erroneously high, leading to seriously errant genetic interpretations.  相似文献   

14.
The Suwałki anorthosite massif, located in extreme northeast Poland beneath more than a kilometer of Phanerozoic cover, hosts major Fe-Ti-V deposits. These deposits, discovered in 1962, are contained in Fe and Ti oxide minerals that coexist with subordinate quantities of Fe, Cu, Ni, and Co sulfides in massif-style anorthosites, norites, and gabbronorites. Accessibility and other considerations preclude development of this natural resource in the present economic climate. Detailed work by Polish geologists during the last 35 years provides a sound geologic framework for this Re-Os study of the age and origin of oxide and sulfide deposits associated with a major, but lesser known anorthosite massif. Rhenium and osmium abundances and Os isotopic compositions were measured for nine sulfides and four titanomagnetites from the Suwałki anorthosite massif. The titanomagnetites are over an order of magnitude lower in Re (0.4–1.5 ppb) and Os (0.036–0.144 ppb) concentrations than co-precipitated pyrrhotite, pyrite, and chalcopyrite that yield consistent concentrations for Re (30–55 ppb) and Os (1–6 ppb). Parallel lines connecting co-existing titanomagnetite and sulfides have slopes of ∼1 on Re versus common Os concentration plots, indicating that both Re and Os behave similarly during crystallization in their high preference for any sulfide phase over magnetite. Samples from three deposits within the anorthosite massif were analyzed. An age of 1559 ± 37 Ma (n=10) with an initial 187Os/188Os of 1.16 ± 0.06 for the Jezioro Okrągłe and Krzemianka deposits is essentially identical to an age of 1556 ± 94 Ma (n=3) for the Udryń deposit. Udryń, however, yielded a marginally lower initial 187Os/188Os of 0.87 ± 0.20. The high initial 187Os/188Os combined with the Proterozoic Re-Os age indicates that the source for Suwałki oxides-sulfides is older crust, and hypothetically, could involve Archean rocks. An average crustal value of 50 for 187Re/188Os yields a 2777 Ma age for Suwałki source rocks. Widespread Phanerozoic cover severely limits knowledge of basement rocks in Poland, however, and no Archean rocks are known in the immediate region. More likely, 187Re/188Os ratios may be higher than average continental crust, reflecting mafic crust in the source, and may move the source age for Suwałki anorthosite and mineral deposits toward younger values that easily include ∼2.0 Ga Proterozoic rocks. This more favorable case also accommodates Paleoproterozoic Nd model ages. Regardless of Archean or Proterozoic source age, the high initial 187Os/188Os ratios derived from the Re-Os isochron indicate that the source for the oxide-sulfide mineral deposits is more likely the crust and not the mantle. Given that these deposits are clearly magmatic, the Re-Os results add a new dimension to the long-standing “origin of anorthosite” problem, implying a crustal source for the anorthosite as well. The 1559 Ma Suwałki age is compatible with a well-exposed east-west band of 1530-1660 Ma rapakivi granite-anorthosite magmatism to the immediate north, transecting western Russia, southern Finland, Estonia and Latvia, and central Sweden. In particular, the age and isotopic character of Suwałki are not unlike those of the well-studied Salmi rapakivi granite-anorthosite batholith in western Russia (Karelia). Received: 4 December 1998 / Accepted: 11 November 1999  相似文献   

15.
戴盼  吴胜华  丁成武 《岩石学报》2018,34(9):2598-2614
王坞斑岩型Mo-Cu矿床位于北武夷地区,地处钦杭构造岩浆成矿带北段。目前钻孔信息显示,该矿床的矿体主要由网脉状石英-辉钼矿-黄铜矿矿石组成,也含少量的浸染状和细脉浸染状Cu-Mo矿化,主要的蚀变作用包括硅化、绢英岩化和绿泥石化。矿区内隐伏燕山期的花岗斑岩脉及石英闪长玢岩脉。本文对该矿床的花岗斑岩进行了LA-ICP-MS锆石U-Pb测年,对主要矿石类型(网脉状石英-辉钼矿矿石)中的辉钼矿进行了Re-Os同位素测年。结果显示,花岗斑岩的锆石U-Pb年龄为136. 7±2. 2Ma,辉钼矿的Re-Os同位素模式年龄为132. 6±1. 8Ma~134. 5±2. 0Ma,加权平均值为133. 7±0. 94Ma,对应的Re-Os等时线年龄为134. 8±2. 1Ma。花岗斑岩的锆石U-Pb年龄和辉钼矿的Re-Os年龄在误差范围内基本一致,且花岗斑岩和矿体之间具有密切的空间关系,指示王坞Mo-Cu矿床的Mo矿化可能与矿区内的花岗斑岩存在密切的成因联系。北武夷地区主要的斑岩-矽卡岩和岩浆热液脉型Cu-Mo多金属矿床的成岩成矿年龄数据的统计结果显示,北武夷地区的Cu-Mo-Pb-ZnAg成矿作用主要集中在燕山期,可被划分为150~165Ma和140~125Ma两个阶段。结合区域构造背景资料,王坞Mo-Cu矿床形成于早白垩纪伸展的构造背景下。  相似文献   

16.
镰子沟金矿床位于小秦岭金矿集区西部,矿体受断裂和石英脉体控制,围岩蚀变以钾化和硅化为主。矿床浅部以金矿为主,深部发现金钼(共)伴生矿体。为了确定镰子沟金矿床成岩、成矿时代,选择镰子沟金矿床正长斑岩和金钼矿石分别进行了LA-ICP-MS锆石U-Pb和辉钼矿Re-Os同位素研究。获得正长斑岩的~(207)Pb/~(206)Pb年龄加权平均值为1802.9±9.9Ma,此年龄明显早于小秦岭地区金矿床的形成时代;获得辉钼矿Re-Os等时线年龄为128.8±6.5Ma,指示矿床形成于早白垩世,晚于区域已知花岗岩形成时代。综合研究认为,镰子沟金矿床的形成与区域花岗岩无关,可能与深部流体或隐伏岩浆有关。  相似文献   

17.
Summary Re–Os molybdenite ages from the exocontact of the Hnilec granite-greisen body provide temporal constraints for tin, tungsten and molybdenite mineralisation in the Gemeric Superunit, Slovakia. Two molybdenite separates were taken from a representative sample of the Sn–W–Mo mineralisation at Hnilec and their Re–Os ages of 262.2 ± 0.9 and 263.8 ± 0.8 Ma (2-sigma) are in excellent agreement. The obtained Re–Os molybdenite ages are similar to recent but less precise electron microprobe monazite (276 ± 13 Ma) and U–Pb single zircon (250 ± 18 Ma) ages from the Hnilec granite intrusion, supporting a granite-related greisen origin for the Sn–W–Mo mineralisation. Our precise Re–Os molybdenite ages resolve the long time controversy over the timing of high-temperature mineralisation in the Gemeric Superunit. These Permian ages eliminate suggestions of an Alpine age. The sulphur isotope composition of the studied molybdenite is δ34S(CDT) = 1.71 ± 0.2‰ and is consistent with a magmatic sulphur source. Field observations indicate the lack of a broad contact aureole in the vicinity of the Hnilec granite body. Shallow level granite emplacement in schistose host rocks was accompanied by alteration and formation of tin-tungsten greisen in the upper part of the granite and exocontact molybdenite mineralisation, both commonly lacking in other granite bodies within the Gemeric Superunit.  相似文献   

18.
Four of the major plutons in the vicinity of the Candelaria mine (470 Mt at 0.95% Cu, 0.22 g/t Au, 3.1 g/t Ag) and a dike–sill system exposed in the Candelaria open pit have been dated with the U–Pb zircon method. The new geochronological data indicate that dacite magmatism around 123 Ma preceded the crystallization of hornblende diorite (Khd) at 118 ± 1 Ma, quartz–monzonite porphyry (Kqm) at 116.3 ± 0.4 Ma, monzodiorite (Kmd) at 115.5 ± 0.4 Ma, and tonalite (Kt) at 110.7 ± 0.4 Ma. The new ages of the plutons are consistent with field relationships regarding the relative timing of emplacement. Plutonism temporally overlaps with the iron oxide Cu–Au mineralization (Re–Os molybdenite ages at ∼115 Ma) and silicate alteration (ages mainly from 114 to 116 and 110 to 112 Ma) in the Candelaria–Punta del Cobre district. The dated dacite porphyry and hornblende diorite intrusions preceded the ore formation. A genetic link of the metallic mineralization with the quartz–monzonite porphyry and/or the monzodiorite is likely. Both of these metaluminous, shoshonitic (high-K) intrusions could have provided energy and contributed fluids, metals, and sulfur to the hydrothermal system that caused the iron oxide Cu–Au mineralization. The age of the tonalite at 110.7 Ma falls in the same range as the late alteration at 110 to 112 Ma. Tonalite emplacement may have sustained existing or driven newly developed hydrothermal cells that caused this late alteration or modified 40Ar/39Ar and K/Ar systematic in some areas.  相似文献   

19.
The Karamay porphyry Mo–Cu deposit, discovered in 2010, is located in the West Junggar region of Xinjiang of northwest China. The deposit is hosted within the Karamay granodiorite porphyry that intruded into Early Carboniferous sedimentary strata and its exo‐contact zone. The LA‐ICPMS U–Pb method was used to date the zircons from the granodiorite samples of the porphyry. Analyses of 12 spots of zircons from the granodiorite samples yield a U–Pb weighted mean age of 300.8 ± 2.1 Ma (2σ). Re–Os dating for five molybdenite samples obtained from two prospecting trenches and three outcrops in the deposit yield a Re–Os isochron age of 294.6 ± 4.6 Ma (2σ), with an initial 187Os/188Os of 0.0 ± 1.1. The isochron age is within the error of the Re–Os model ages, demonstrating that the age result is reliable. The Re–Os isochron age of the molybdenite is consistent with the U–Pb age of the granodiorite porphyry, which indicates that the deposit is genetically related with an Early Permian porphyry system. The ages of the Karamay Mo–Cu deposit and the ore‐bearing porphyry are similar to the ages of intermediate‐acid intrusions and Cu–Mo–Au polymetallic deposits in the West Junggar region. This consistency suggests the same geodynamic process to the magmatism and related mineralization.  相似文献   

20.
滇西北红山铜钼矿床辉钼矿Re-Os同位素测年及其成矿意义   总被引：10，自引：7，他引：3  
红山铜钼矿床是义敦岛弧南端格咱火山-岩浆弧中已探明规模最大的夕卡岩型铜矿床,近年来在其深部勘探过程中又发现斑岩型铜钼矿体.利用辉钼矿Re-Os同位素测年技术,分别对红山铜钼矿床中5件夕卡岩型矿石和1件斑岩型矿石中辉钼矿进行定年,首次获得红山铜钼矿床高精度成矿年龄.夕卡岩型矿石中辉钼矿Re-Os模式年龄为77.90 ～ 81.05Ma,加权平均值为79.32±0.87Ma,斑岩型矿石中辉钼矿模式年龄为80.71Ma,两者在误差范围内相一致;6件样品辉钼矿等时线年龄为80.0±1.8Ma,代表了红山铜钼矿床的成矿时代.辉钼矿中Re的含量为(4.074±0.035) ×l0-6～(94.21±0.75)×10-6,指示其物质来源以壳源为主,有少量幔源物质混入.红山铜钼矿床与格咱火山-岩浆弧燕山晚期岩浆侵入作用的高峰期及相关斑岩-夕卡岩型多金属矿床的成矿年龄一致,表明它们是弧陆碰撞的后造山伸展背景下同一区域地质事件的产物,该期夕卡岩-斑岩型铜钼多金属具有较大成矿潜力.  相似文献   

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