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1.
The circulation of methane-rich fluids at cold seeps often leads to the precipitation of seep carbonates close to the seafloor along continental margins, which can be used as records of past fluid seepage. Rare earth element (REE) concentrations in seep carbonates have been used to trace fluid sources and provide information on associated biogeochemical processes at cold seeps. The REE concentrations of a series of carbonates collected from cold seeps in the southwestern Dongsha area of the northern South China Sea are analyzed in this study. The total REE contents (ΣREE) of the seep carbonates analyzed show a wide variation from 17 ppm to 523 ppm with an average ΣREE value of 54 ppm, which are higher than the typical marine carbonate values of ∼28 ppm commonly reported and also higher than those of the carbonates from other cold seep areas. A positive correlation between Fe–Mn content and ΣREE was observed. These results suggest that the seep carbonates of this study were primarily controlled by the methane-derived fluid from which they precipitated. The Fe-rich dolomite and siderite, which are the main components of the carbonates, are responsible for the enrichment of the REE. A slight positive Ce anomaly observed in the shale-normalized REE patterns of the studied seep carbonates suggests that they formed in anoxic conditions, and the correlations between Ce/Ce* and LaN/SmN, Ce/Ce* and DyN/SmN, Ce/Ce* and ΣREE further reveal that the REE characteristics of most seep carbonate samples preserve the original redox conditions in which they precipitated and late diagenesis has had little effect on the REE. However, the REE characteristics of sub-samples DS2-2B, DS1-6A and DS1-7A are very different from those of the other sub-samples, indicating a greater impact of late diagenesis and post-oxidation favored REE enrichment.  相似文献   

2.
Authigenic carbonates were collected from methane seeps at Hydrate Hole at 3113 m water depth and Diapir Field at 2417 m water depth on the northern Congo deep-sea fan during RV Meteor cruise M56. The carbonate samples analyzed here are nodules, mainly composed of aragonite and high-Mg calcite. Abundant putative microbial carbonate rods and associated pyrite framboids were recognized within the carbonate matrix. The δ13C values of the Hydrate Hole carbonates range from ?62.5‰ to ?46.3‰ PDB, while the δ13C values of the Diapir Field carbonate are somewhat higher, ranging from ?40.7‰ to ?30.7‰ PDB, indicating that methane is the predominant carbon source at both locations. Relative enrichment of 18O (δ18O values as high as 5.2‰ PDB) are probably related to localized destabilization of gas hydrate. The total content of rare earth elements (REE) of 5% HNO3-treated solutions derived from carbonate samples varies from 1.6 ppm to 42.5 ppm. The shale-normalized REE patterns all display positive Ce anomalies (Ce/Ce* > 1.3), revealing that the carbonates precipitated under anoxic conditions. A sample from Hydrate Hole shows a concentric lamination, corresponding to fluctuations in δ13C values as well as trace elements contents. These fluctuations are presumed to reflect changes of seepage flux.  相似文献   

3.
Multidisciplinary study of seep-related structures on Southern Vøring Plateau has been performed during several UNESCO/IOC TTR cruises on R/V Professor Logachev. High-resolution sidescan sonar and subbottom profiler data suggest that most of the studied fluid discharge structures have a positive relief at their central part surrounded by depression. Our data shows that the present day fluid activity is concentrated on the top of these “seep mounds”. Number of high hydrocarbon (HC) gas saturated sediment cores and 5 cores with gas hydrate presence have been recovered from these structures. δ13C of methane (between −68 and −94.6‰ VPDB) and dry composition of the gas points to its biogenic origin. The sulfate depletion generally occurs within the upper 30–200 cm bsf and usually coincides with an increase of methane concentration. Pore water δ18O ranges from 0.29 to 1.14‰ showing an overall gradual increase from bottom water values (δ18O ∼ 0.35‰). Although no obvious evidence of fluid seepage was observed during the TV surveys, coring data revealed a broad distribution of living Pogonophora and bacterial colonies on sea bottom inside seep structures. These evidences point to ongoing fluid activity (continuous seepage of methane) through these structures. From other side, considerable number and variety of chemosynthetic macro fauna with complete absence of living species suggest that present day level of fluid activity is significantly lower than it was in past. Dead and subfossil fauna recovered from various seep sites consist of solemyid (Acharax sp.), thyasirid and vesicomyid (cf. Calyptogena sp.) bivalves belonging to chemosymbiotic families. Significant variations in δ13C (−31.6‰ to −59.2‰) and δ18O (0.42‰ and 6.4‰) of methane-derived carbonates collected from these structures most probably related to changes in gas composition and bottom water temperature between periods of their precipitation. This led us to ideas that: (1) seep activity on the Southern Vøring Plateau was started with large input of the deep thermogenic gas and gradually decries in time with increasing of biogenic constituent; (2) authigenic carbonate precipitation started at the near normal deep sea environments with bottom water temperature around +5 °C and continues with gradual cooling up to negative temperatures recording at present time.  相似文献   

4.
The Coal Oil Point seep field located offshore Santa Barbara, CA, consists of dozens of named seeps, including a peripheral ~200 m2 area known as Brian Seep, located in 10 m water depth. A single comprehensive survey of gas flux at Brian Seep yielded a methane release rate of ~450 moles of CH4 per day, originating from 68 persistent gas vents and 23 intermittent vents, with gas flux among persistent vents displaying a log normal frequency distribution. A subsequent series of 33 repeat surveys conducted over a period of 6 months tracked eight persistent vents, and revealed substantial temporal variability in gas venting, with flux from each individual vent varying by more than a factor of 4. During wintertime surveys sediment was largely absent from the site, and carbonate concretions were exposed at the seafloor. The presence of the carbonates was unexpected, as the thermogenic seep gas contains 6.7% CO2, which should act to dissolve carbonates. The average δ13C of the carbonates was ?29.2?±?2.8‰ VPDB, compared to a range of ?1.0 to +7.8‰ for CO2 in the seep gas, indicating that CO2 from the seep gas is quantitatively not as important as 13C-depleted bicarbonate derived from methane oxidation. Methane, with a δ13C of approximately ?43‰, is oxidized and the resulting inorganic carbon precipitates as high-magnesium calcite and other carbonate minerals. This finding is supported by 13C-depleted biomarkers typically associated with anaerobic methanotrophic archaea and their bacterial syntrophic partners in the carbonates (lipid biomarker δ13C ranged from ?84 to ?25‰). The inconsistency in δ13C between the carbonates and the seeping CO2 was resolved by discovering pockets of gas trapped near the base of the sediment column with δ13C-CO2 values ranging from ?26.9 to ?11.6‰. A mechanism of carbonate formation is proposed in which carbonates form near the sediment–bedrock interface during times of sufficient sediment coverage, in which anaerobic oxidation of methane is favored. Precipitation occurs at a sufficient distance from active venting for the molecular and isotopic composition of seep gas to be masked by the generation of carbonate alkalinity from anaerobic methane oxidation.
Figure
Processes modulating carbonate formation at Brian Seep (California) during times of high and low sediment burden  相似文献   

5.
Several hundred hydrothermal vent complexes were formed in the Vøring Basin as a consequence of magmatic sill emplacement in the late Palaeocene. The 6607/12-1 exploration well was drilled through a 220-m-thick sequence of Eocene–Miocene diatomites with carbonate nodules above the apex of one of these vent complexes. Analysed calcites and dolomites from this interval have isotopic signatures typical for methane seep carbonates, with low 13C signatures of –28 to –54 PDB. The data suggest that the vent complex acted as a fluid migration pathway for about 50×106 years after its formation, leading to near-surface microbial activity and seep carbonate formation.  相似文献   

6.
Authigenic carbonates from outcrops of the northern Apennines consist of small and irregular lenses and exhibit numerous features indicative of cold-seep settings. Detailed petrographic, mineralogical and geochemical studies from two Miocene deposits are presented. The first carbonate outcrop, named Fosso Riconi, is located in the foredeep basin of the Apenninic chain, whereas the second deposit represents a satellite basin called Sarsetta. The stable isotope data from specific carbonate minerals show a wide range of values well known from other palaeoseeps of the Apennine Mountains. The majority of seep carbonates are formed by low-Mg calcite and ankerite. Those minerals have δ13C values between ?7 and ?23‰ V-PDB, suggesting variable amounts of carbonate derived from oxidized methane, seawater (dissolved inorganic carbon) and sedimentary organic matter. Dolomite samples have the lowest δ13C values (?30.8 to ?39.0‰ V-PDB), indicating methane as the main carbon source. The findings suggest an evolutionary formation of the seeps and development of authigenic carbonates influenced by the activity of chemosynthetic organisms, of which large lucinid clams are preserved. Bioirrigation by the clams controlled the sediment–water exchange, and is here considered as an explanation for the anomalous Mg content of the calcite. We hypothesize that the seep carbonates were formed during periods of active methane-rich seepage, whereas during periods of slow seepage carbonate formation was reduced. Despite different geological settings, the two examined deposits of Sarsetta and Fosso Riconi show similar features, suggesting that a common pattern of fluid circulation played a major role in carbonate formation at both seep sites.  相似文献   

7.
Systematic analyses have been carried out on two gas hydrate-bearing sediment core samples, HYPV4, which was preserved by CH4 gas pressurization, and HYLN7, which was preserved in liquid-nitrogen, recovered from the BPXA-DOE-USGS Mount Elbert Stratigraphic Test Well. Gas hydrate in the studied core samples was found by observation to have developed in sediment pores, and the distribution of hydrate saturation in the cores imply that gas hydrate had experienced stepwise dissociation before it was stabilized by either liquid nitrogen or pressurizing gas. The gas hydrates were determined to be structure Type I hydrate with hydration numbers of approximately 6.1 by instrumentation methods such as powder X-ray diffraction, Raman spectroscopy and solid state 13C NMR. The hydrate gas composition was predominantly methane, and isotopic analysis showed that the methane was of thermogenic origin (mean δ13C = −48.6‰ and δD = −248‰ for sample HYLN7). Isotopic analysis of methane from sample HYPV4 revealed secondary hydrate formation from the pressurizing methane gas during storage.  相似文献   

8.
The lower Ordovician St. George Group in Western Newfoundland consists of a sequence of subtidal and peritidal carbonates, which are extensively dolomitized. The current study investigates the diagenetic evolution of the Catoche Formation from the Port aux Choix and Port au Port peninsulas in order to study the controls on reservoir quality in western Newfoundland. The Catoche Formation dolomites are classified into three main generations. Early and pervasive replacement dolomite (D1) indicates that dolomitization began during early stages of diagenesis. Stable isotope and trace element data indicate significant variations between D1 dolomite on the Port aux Choix and Port au Port peninsulas. The depleted δ18O signature of D1 dolomite fluids (−8.7 ± 1.3‰ VPBD) on the Port aux Choix Peninsula is consistent with partial dolomitization associated with mixing of seawater and meteoric waters on the flanks of structural highs. In contrast δ18O values (−6.1 ± 0.7‰ VPBD) and trace element data from the Port au Port Peninsula indicate that pervasive D1 was associated with mixing of possibly post evaporitic brines with meteoric waters.Later-stage replacement dolomites (D2) are associated with enhancement in porosity through the development of intercrystalline pores, while latest stage saddle dolomite (D3), significantly occluded the pores in some horizons. D2 dolomite formed due to the influx of warm (>100 °C), saline (>15 eq. wt% NaCl) fluids. Intercrystalline porosity in D2 formed due to the dolomitization of precursor calcite, due to the lower molar volume of dolomite compared to calcite. Therefore porosity development is lower on the Port au Port Peninsula, with no significant volume change during the recrystallization of the pervasive early (D1) dolomicrite. Similarly, extensive porous horizons on the Port aux Choix Peninsula are related to the limited extent of D1 dolomitization. This suggests that the quality of a potential dolomite reservoir is strongly controlled by tectonic and diagenetic history of host carbonates.  相似文献   

9.
The aim of this study was to distinguish between sources of the complex variety of Marennes-Oléron Bay suspended particulate organic matter (SPOM) contributing to the tropho-dynamics of the Marennes-Oléron oyster farming bay. Basic biomarkers (Chl a, C/N and POC/Chl a ratios), carbon and nitrogen stable isotopes from SPOM were analyzed and the microalgae community was characterized. The sampling strategy was bimonthly from March 2002 to December 2003; samples were taken from an intertidal mudflat. Four main sources contributed to the SPOM pool: terrigenous input from rivers, neritic phytoplankton, resuspended microphytobenthos and periodic inputs from intertidal Zostera noltii meadows. Seasonal fluctuations were observed in both years of the study period: (1) SPOM collected in the spring of 2002 (δ13C = −25‰ to −23‰) was mainly composed of fresh estuarine inputs; (2) SPOM from the summer and fall of 2002 and 2003 was predominantly neritic phytoplankton (δ13C = − 22‰ to −19‰); (3) SPOM from the winter of 2002, spring of 2003 and winter of 2003 (δ13C = −21 to −23‰) was composed of a mixture of decayed terrigenous river inputs and pelagic phytoplankton, which was predominantly resuspended microphytobenthos. In the summer of 2003—the warmest summer on record in southern France and Europe—SPOM was particularly enriched for 13C, with δ13C values ranging from −14‰ to −12‰. Pulses in δ13C values, indicative of 13C-enriched decaying materials, extended into the fall. These were attributed to benthic intertidal inputs, including both resuspended microphytobenthos and Z. noltii detritus. Changes in SPOM sources in Marennes-Oléron Bay may lead to differences in the quality of the trophic environment available for reared oysters.  相似文献   

10.
The worlds >1500 mud volcanoes are normally in a dormant stage due to the short duration of eruptions. Their dormant stage activity is often characterized by vigorous seepage of water, gas, and petroleum. However, the source of the fluids and the fluid–rock interactions within the mud volcano conduit remain poorly understood. In order to investigate this type of activity, we have combined satellite images with fieldwork and extensive sampling of water and gas at seeping gryphons, pools and salsa lakes at the Dashgil mud volcano in Azerbaijan. We find that caldera collapse faults and E–W oriented faults determine the location of the seeps. The seeping gas is dominated by methane (94.9–99.6%), with a δ13C (‰ V-PDB) in the −43.9 to −40.4‰ range, consistent throughout the 12 analysed seeps. Ethane and carbon dioxide occur in minor amounts. Seventeen samples of seeping water show a wide range in solute content and isotopic composition. Pools and salsa lakes have the highest salinities (up to 101,043 ppm Cl) and the lowest δ18O (‰ V-SMOW) values (1–4‰). The mud-rich gryphons have low salinities (<18,000 ppm Cl) and are enriched in 18O (δ18O = 4–6‰).  相似文献   

11.
Interlinked mangrove–seagrass ecosystems are characteristic features of many tropical coastal areas, where they act as feeding and nursery grounds for a variety of fishes and invertebrates. The autotrophic carbon sources supporting fisheries in Gazi bay (Kenya) were studied in three sites, two located in the tidal creeks flowing through extensive mangrove forests, another site located in the subtidal seagrass meadows, approximately 2.5 km away from the forest. Carbon and nitrogen stable isotope composition of 42 fish species, 2 crustacean species and a range of potential primary food sources (e.g., mangroves, seagrasses and epiphytes, macroalgae) were analysed. There was considerable overlap in the δ13C signatures between fish (−16.1 ± 2.1‰), seagrasses (−15.1 ± 3.0‰), seagrass epiphytes (−13.6 ± 3.3‰), and macroalgae (−20.4 ± 3.1‰). Nevertheless, the signatures for most primary producers were sufficiently distinct to indicate that the dominant carbon sources for fish were mainly derived from the seagrass and their associated epiphytic community, and possibly macroalgae. Mangrove-derived organic matter contributes only marginally to the overall fish food web. Carbon supporting these fish communities was derived directly through grazing by herbivorous and some omnivorous fishes, or indirectly through the benthic food web. Fishes from the mangrove creeks had distinctly lower δ13C signatures (−16.8 ± 2.0‰) compared to those collected in the adjacent seagrass beds (−14.7 ± 1.7‰). This indicated that these habitats were used as distinct sheltering and feeding zones for the fishes collected, with minimal degree of exchange within the fish communities despite their regular movement pattern.  相似文献   

12.
Vodyanitskii mud volcano is located at a depth of about 2070 m in the Sorokin Trough, Black sea. It is a 500-m wide and 20-m high cone surrounded by a depression, which is typical of many mud volcanoes in the Black Sea. 75 kHz sidescan sonar show different generations of mud flows that include mud breccia, authigenic carbonates, and gas hydrates that were sampled by gravity coring. The fluids that flow through or erupt with the mud are enriched in chloride (up to ∼650 mmol L−1 at ∼150-cm sediment depth) suggesting a deep source, which is similar to the fluids of the close-by Dvurechenskii mud volcano. Direct observation with the remotely operated vehicle Quest revealed gas bubbles emanating at two distinct sites at the crest of the mud volcano, which confirms earlier observations of bubble-induced hydroacoustic anomalies in echosounder records. The sediments at the main bubble emission site show a thermal anomaly with temperatures at ∼60 cm sediment depth that were 0.9 °C warmer than the bottom water. Chemical and isotopic analyses of the emanated gas revealed that it consisted primarily of methane (99.8%) and was of microbial origin (δD-CH4 = −170.8‰ (SMOW), δ13C-CH4 = −61.0‰ (V-PDB), δ13C-C2H6 = −44.0‰ (V-PDB)). The gas flux was estimated using the video observations of the ROV. Assuming that the flux is constant with time, about 0.9 ± 0.5 × 106 mol of methane is released every year. This value is of the same order-of-magnitude as reported fluxes of dissolved methane released with pore water at other mud volcanoes. This suggests that bubble emanation is a significant pathway transporting methane from the sediments into the water column.  相似文献   

13.
Paola Ridge, along the NW Calabrian margin (southern Tyrrhenian Sea), is one of the few reported deep sea sites of precipitation of authigenic carbonates in the Tyrrhenian Sea. Here, the changing composition of the seeping fluids and the dynamic nature of the seepage induced the precipitation of pyrite, siderite and other carbonate phases. The occurrence of this array of authigenic precipitates is thought to be related to fluctuation of the sulfate-methane transition zone (SMTZ).Concretions of authigenic minerals formed in the near sub-bottom sediments of the Paola Ridge were investigated for their geochemical and isotopic composition. These concretions were collected in an area characterized by the presence of two alleged mud volcanoes and three mud diapirs. The mud diapirs are dotted by pockmarks and dissected by normal faults, and are known for having been a site of fluid seepage for at least the past 40 kyrs. Present-day venting activity occurs alongside the two alleged mud volcanoes and is dominated by CO2-rich discharging fluids. This discover led us to question the hypothesis of the mud volcanoes and investigate the origin of the fluids in each different domed structure of the study area.In this study, we used stable isotopes (carbon and oxygen) of carbonates coupled with rare earth element (REE) composition of different carbonate and non-carbonate phases for tracing fluid composition and early diagenesis of authigenic precipitates. The analyses on authigenic precipitates were coupled with chemical investigation of venting gas and sea-water.Authigenic calcite/aragonite concretions, from surficial sediments on diapiric structures, have depleted 13C isotopic composition and slightly positive δ18O values. By contrast, siderite concretions, generally found within the first 6 m of sediments on the alleged mud volcanoes, yielded positive δ13C and δ18O values. The siderite REE pattern shows consistent LREE (light REE) fractionation, MREE (medium REE) enrichment and positive Gd and La anomalies. As shown by the REE distribution, the 13C-depleted composition and their association with chemosymbiotic fauna, calcite/aragonite precipitated at time of moderate to high methane flux close to the seafloor, under the influence of bottom seawater. Authigenic siderite, on the other hand, formed in the subseafloor, during periods of lower gas discharges under prolonged anoxic conditions within sediments in equilibrium with 13C-rich dissolved inorganic carbon (DIC) and 18O-rich water, likely related to methanogenesis and intermittent venting of deep-sourced CO2.  相似文献   

14.
Carbon and Nitrogen stable isotopes and stomach contents analyses were used to investigate an estuarine fish food web and identify the contribution of these two methods to the knowledge and understanding of the food web's structure and its functioning. The nine most abundant fish species during the warm period in the Gironde estuary (southwest France, Europe) are examined. Observation of the stomach contents reflects a variety of feeding modes between fish species that consume a diverse assortment of prey, with limited dietary overlap. Nevertheless, when regarding the whole fish community, few prey species dominate the stomach contents. Nitrogen isotope ratios indicate a high intraspecific variability inducing an interspecific covering of the signatures. However, a tendency to δ15N enrichment according to the trophic position of the species studied was observed. Fish assemblages show a trend towards enrichment of their carbon isotopic signatures from the upper estuary (−20.8 ± 1.8‰) towards the lower estuary (−18.3 ± 1.6‰). But whatever the capture zone considered, most of the individual δ13C values for each fish analysed are comprised between −22 and −16‰. Only few specimens, belonging to migratory amphihaline species, have significantly lighter values.  相似文献   

15.
We investigated the distribution of δ13C and δ15N of organic matter among benthic communities from the upper estuary of Yura River to offshore of Tango Sea, Japan, to determine spatial variation in utilization of organic matter by benthic communities. The δ13C values of benthic animals ranged from −27 to −15‰ in the upper estuary, −21 to −15‰ in the lower estuary, −20 to −16‰ in the shallow coast (5–10 m depths), −18 to −16‰ in the deep coast (30–60 m depths) and −19 to −15‰ in offshore (100–150 m depths) stations. Adapting the dual isotope values to mixing models, we estimated the relative contributions of potential food sources to the benthos diet. Phytoplankton and macroalgae that intruded the estuary in summer were utilized as alternative food aside from the terrestrial-origin organic matter assimilated by the estuarine benthic consumers. Resuspended benthic microalgae were important source of energy in the shallow coastal stations, while abundant supply of phytodetritus fueled the deep coastal and offshore benthic food webs. Spatial difference in the diet of benthic communities depends largely on the shifts in the primary carbon source. Thus, benthic communities are important link of autochthonous/allochthonous production and secondary production in the continuous river–estuary–marine system.  相似文献   

16.
Nearly 2000 pockmarks with diameters ranging from a few tens of meters up to 700 m are present on the seafloor of the St. Lawrence Estuary in eastern Canada. Coring of some pockmarks resulted in the recovery of various-sized and shaped carbonate concretions in a predominantly silty mud matrix. Petrographic and geochemical data on four authigenic carbonate concretions are reported as well as data from shell material in the unconsolidated sediment. Video observations and echo-sounder images indicate that the sampled pockmarks are actively gas venting. The video images show significant look-alike microbial mats in areas where gas is venting. The carbonate concretions are primarily made up of carbonate cements with varying percentage of shell fragments, micrite particles and fine-grained clastics. Orthorhombic crystal morphology and diagenetic fabrics including isopachous layers and botryoids characterize the aragonite cement. Oxygen isotopes ratios for the cement crusts do not record any thermal anomaly at the site of precipitation with δ18OVPDB ratios (+3) in equilibrium with cold (5 °C) deep marine waters, whereas significant negative δ13CVPDB ratios (−9.9 to −33.5) for cement and shell material within concretions indicate that the carbonates largely derive from the microbial oxidation of methane. The δ13CVPDB ratios of aragonite shells (−2.7 to −5.6) taken from unconsolidated sediments at some distance from the concretions/vents show variable dilution of HCO3 with negative δ13CVPDB ratios derived from microbial oxidation of methane with isotopically normal (0) marine bicarbonate. These results are in agreement with other lines of evidence suggesting that pockmarks formed through the recent and still active release of gas from a reservoir within the Paleozoic sedimentary succession.  相似文献   

17.
One hundred and ten carbon and nineteen strontium isotopic values of outcropping Cambrian Series 2 and Series 3 carbonate rocks in the Penglaiba section of the Keping area were analyzed. Effective isotopic data with little influence of diagenesis were used to address the global correlation. The δ13C values exhibit two major positive excursions (peaking at 3.1‰ and 3.3‰) and three major negative excursions (peaking at −3.0‰, −4.2‰ and −3.2‰). The carbon isotope excursions (peaking at −3.0‰ and −4.2‰) across the Cambrian Series 2-Series 3 boundary show good correlations with similar variations reported in Siberia, Laurentia, North China and South China. In contrast, the other three carbon isotope excursions (peaking at 3.1‰, 3.3‰ and −3.2‰) do not have a fairly good global correlation because of the lack of biostratigraphic data. With respect to the 87Sr/86Sr ratios, they show good correlation with those reported for Laurentia, and further support the global δ13C comparison. On the basis of these new data, it is showed that the combination of δ13C curves and 87Sr/86Sr variations serves as a powerful tool for correlation and subdivision of Cambrian strata in the Tarim Basin of northwest China, and provides new data for global correlation.  相似文献   

18.
Authigenic minerals were studied in Holocene shelf sediments of the Laptev Sea (cold methane seep site, water depth 71 m). The study presents the first finds of large hard carbonate concretions with Mg-calcite cement in recent sediments of the Arctic shelf seas. These concretions differ from previously reported glendonites and concretions from bottom sediments of the White Sea, Kara Sea, Sea of Okhotsk, etc. A study of the morphology, microstructure, and composition of these newly reported concretions revealed the multistage formation of carbonates (structural varieties of Mg-calcite and aragonite). It was shown that organic matter played an important role in the formation of authigenic carbonates, i.e., in the formation of sedimentary–diagenetic Mg-calcite. The role of methane as a possible source for authigenic carbonate formation was estimated. It was found that methane-derived Mg-calcite accounts for 17–35% of concretion materials. Mg-calcite had δ13С-Сcarb values between–24 and–23‰ and δ13С-Сorg values between–44.5 and–88.5‰.  相似文献   

19.
Two newly developed coring devices, the Multi-Autoclave-Corer and the Dynamic Autoclave Piston Corer were deployed in shallow gas hydrate-bearing sediments in the northern Gulf of Mexico during research cruise SO174 (Oct–Nov 2003). For the first time, they enable the retrieval of near-surface sediment cores under ambient pressure. This enables the determination of in situ methane concentrations and amounts of gas hydrate in sediment depths where bottom water temperature and pressure changes most strongly influence gas/hydrate relationships. At seep sites of GC185 (Bush Hill) and the newly discovered sites at GC415, we determined the volume of low-weight hydrocarbons (C1 through C5) from nine pressurized cores via controlled degassing. The resulting in situ methane concentrations vary by two orders of magnitudes between 0.031 and 0.985 mol kg− 1 pore water below the zone of sulfate depletion. This includes dissolved, free, and hydrate-bound CH4. Combined with results from conventional cores, this establishes a variability of methane concentrations in close proximity to seep sites of five orders of magnitude. In total four out of nine pressure cores had CH4 concentrations above equilibrium with gas hydrates. Two of them contain gas hydrate volumes of 15% (GC185) and 18% (GC415) of pore space. The measurements prove that the highest methane concentrations are not necessarily related to the highest advection rates. Brine advection inhibits gas hydrate stability a few centimeters below the sediment surface at the depth of anaerobic oxidation of methane and thus inhibits the storage of enhanced methane volumes. Here, computerized tomography (CT) of the pressure cores detected small amounts of free gas. This finding has major implications for methane distribution, possible consumption, and escape into the bottom water in fluid flow systems related to halokinesis.  相似文献   

20.
A cross-system analysis of bulk sediment composition, total organic carbon (TOC), atomic C/N ratio, and carbon isotope composition (δ13C) in 82 surface sediment samples from natural and planted mangrove forests, bank and bottom of tidal creeks, tidal flat, and the subtidal habitat was conducted to examine the roles of mangroves in sedimentation and organic carbon (OC) accumulation processes, and to characterize sources of sedimentary OC of the mangrove ecosystem of Xuan Thuy National Park, Vietnam. Sediment grain sizes varied widely from 5.4 to 170.2 μm (mean 71.5 μm), with the fine sediment grain size fraction (< 63 μm) ranging from 11 to 99.3% (mean 72.5%). Bulk sediment composition suggested that mangroves play an important role in trapping fine sediments from river outflows and tidal water by the mechanisms of tidal current attenuation by vegetation and the ability of fine roots to bind sediments. The TOC content ranged from 0.08 to 2.18% (mean 0.78%), and was higher within mangrove forests compared to those of banks and bottoms of tidal creeks, tidal flat, and subtidal sediments. The sedimentary δ13C ranged from − 27.7 to − 20.4‰ (mean − 24.1‰), and mirrored the trend observed in TOC variation. The TOC and δ13C relationship showed that the factors of microbial remineralization and OC sources controlled the TOC pool of mangrove sediments. The comparison of δ13C and C/N ratio of sedimentary OC with those of mangrove and marine phytoplankton sources indicated that the sedimentary OC within mangrove forests and the subtidal habitat was mainly composed of mangrove and marine phytoplankton sources, respectively. The application of a simple mixing model showed that the mangrove contribution to sedimentary OC decreased as follows: natural mangrove forest > planted mangrove forest > tidal flat > creek bank > creek bottom > subtidal habitat.  相似文献   

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