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1.
似层状铬铁矿床长期以来被认为是岩浆分异成因,但近年来有学者提出其中个别产在蛇绿岩中。本文选择北京放马峪似层状铬铁矿床中纯橄岩、辉橄岩和辉石岩中不同类型的含铬尖晶石进行了电子探针分析。研究表明,岩浆早期的纯橄岩和辉橄岩中的铬尖晶石富铬(Cr2O3平均43.32%),而岩浆晚期辉石的结晶消耗了大量Cr3+,由于氧逸度的升高,在辉石岩的单斜辉石中出溶贫铬的铬磁铁矿(Cr2O3平均10.32%)和富铝尖晶石(Cr2O3平均15.77%)。与世界上不同类型铬尖晶石的矿物化学特征进行对比,可以认为放马峪铬铁矿床是产在阿拉斯加型岩体中的早期岩浆矿床,而与蛇绿岩无关。本文对放马峪铬铁矿床成因和成矿专属性的限定,为这类镁铁-超镁铁岩体的铬、铜镍、铂族元素的找矿勘查提供了依据。  相似文献   

2.
Mantle xenoliths (lherzolites, clinopyroxene dunites, wehrlites, and clinopyroxenites) in the Early Cretaceous volcanic rocks of Makhtesh Ramon (alkali olivine basalts, basanites, and nephelinites) represent metasomatized mantle, which served as a source of basaltic melts. The xenoliths bear signs of partial melting and previous metasomatic transformations. The latter include the replacement of orthopyroxene by clinopyroxene in the lherzolites and, respectively, the wide development of wehrlites and olivine clinopyoroxenites. Metasomatic alteration of the peridotites is accompanied by a sharp decrease in Mg, Cr, and Ni, and increase of Ti, Al, Ca contents and 3+Fe/2+Fe ratio, as well as the growth of trace V, Sc, Zr, Nb, and Y contents. The compositional features of the rocks such as the growth of 3+Fe/2+Fe and the wide development of Ti-magnetite in combination with the complete absence of sulfides indicate the high oxygen fugacity during metasomatism and the low sulfur concentration, which is a distinctive signature of fluid mode during formation of the Makhtesh Ramon alkali basaltic magma. Partial melting of peridotites and clinopyroxenites is accompanied by the formation of basanite or alkali basaltic melt. Clino- and orthopyroxenes are subjected to melting. The crystallization products of melt preserved in the mantle rock are localized in the interstices and consist mainly of fine-grained clinopyroxene, which together with Ti-magnetite, ilmenite, amphibole, rhenite, feldspar, and nepheline, is cemented by glass corresponding to quartz–orthopyroxene, olivine–orthopyroxene, quartz–feldspar, or nepheline–feldspar mixtures of the corresponding normative minerals. The mineral assemblages of xenoliths correspond to high temperatures. The high-Al and high-Ti clinopyroxene, calcium olivine, feldspar, and feldspathoids, amphibole, Ti-magnetite, and ilmenite are formed at 900–1000°. The study of melt and fluid inclusions in minerals from xenoliths indicate liquidus temperatures of 1200–1250°C, solidus temperatures of 1000–1100°C, and pressure of 5.9–9.5 kbar. Based on the amphibole–plagioclase barometer, amphibole and coexisting plagioclase were crystallized in clinopyroxenites at 6.5–7.0 kbar.  相似文献   

3.
Some clinopyroxenes from ultramafic inclusions in Dreiser Weiher,Eifel   总被引：6，自引：1，他引：6  
Eight clinopyroxenes from wehrlites and clinopyroxenites and three clinopyroxenes of crystal lapilli in tuff of Dreiser Weiher in Eifel, Germany, have been separated and chemically analysed. One hornblende and two phlogopites from a wehrlite and clinopyroxenites have also been analysed. The rocks enclosing these inclusions are alkali basalts of basanite composition. The analysed clinopyroxenes contain considerable amounts of Al2O3 (3.87–10.84 wt%). The calculated Tschermak's component ranges from 5.9 to 18.4 mol per cent. All of the analysed clinopyroxenes are clearly different from chromian diopsides in lherzolite inclusions in basaltic rocks in Dreiser Weiher and other localities; the former has higher contents of total FeO, CaO and TiO2 and lower contents of MgO and Cr2O3 than the latter. Two clinopyroxenes separated from apatite-bearing clinopyroxenites show high contents of Fe2O3 with about 2 per cent of Na2O, indicating the presence of considerable amounts of acmite component in addition to Tschermak's component. The relative proportions of Al in the tetrahedral site and that in the octahedral site in the analysed clinopyroxenes are clearly different from those of the common igneous clinopyroxenes and eclogites, and similar to those of the clinopyroxenes from other inclusions in basaltic rocks and granulites. It is suggested that all the analysed clinopyroxenes and their host inclusions have crystallized from alkali basalt magmas in relatively deep levels of the continental crust.  相似文献   

4.
A suite of mafic pyroxenite xenoliths and clinopyroxene megacrysts was brought to the surface by Cenozoic nephelinites of the Jbel Saghro Volcanic Field (Anti-Atlas, Morocco). The large population of samples was subdivided into five groups: (i) clinopyroxenites sensu stricto; (ii) olivine clinopyroxenites; (iii) mica-bearing clinopyroxenites; (iv) kaersutite-bearing clinopyroxenites; (v) clinopyroxene megacrysts. These xenoliths display a cumulate texture (adcumulate, heteradcumulate with poikilitic clinopyroxene including olivine). The clinopyroxenes have the composition of augite and show an appreciable variation of MgO (7.02–14.80 wt.%), TiO2 (0.58–5.76 wt.%) and Al2O3 (2.81–12.38 wt.%) contents in grains. The clinopyroxenes are characterized by convex upward chondrite-normalized REE patterns, they display very similar trace element compositions with low contents of incompatible elements such as Rb (0−0.9 ppm), Ba (0.1–8.3 ppm), Th (0.1−0.3 ppm), U (0.01−0.04 ppm) and Nb (1.3–3.2 ppm). REE contents of the calculated melts in equilibrium with the clinopyroxene megacrysts and clinopyroxene from pyroxenite xenoliths are similar to those of the nephelinites exposed in Jbel Saghro. Crystallization temperatures of pyroxenite xenoliths and clinopyroxene megacrysts range from 950 °C to 1150 °C. Clinopyroxene barometry yielded pressure of crystallization ranging from 0.4 to 0.8 GPa for pyroxenite xenoliths and 0.3 to 0.7 GPa for clinopyroxene megacrysts. This pressure range is in agreement with pyroxenite xenoliths and clinopyroxene megacrysts being crystallized from their parental melts at the lower and upper crust.  相似文献   

5.
Here we present new data on the major and trace element compositions of silicate and oxide minerals from mantle xenoliths brought to the surface by the Carolina kimberlite, Pimenta Bueno Kimberlitic Field, which is located on the southwestern border of the Amazonian Craton. We also present Sr-Nd isotopic data of garnet xenocrysts and whole-rocks from the Carolina kimberlite. Mantle xenoliths are mainly clinopyroxenites and garnetites. Some of the clinopyroxenites were classified as GPP–PP–PKP (garnet-phlogopite peridotite, phlogopite-peridotite, phlogopite-K-richterite peridotite) suites, and two clinopyroxenites (eclogites) and two garnetites are relicts of an ancient subducted slab. Temperature and pressure estimates yield 855–1102 °C and 3.6–7.0 GPa, respectively. Clinopyroxenes are enriched in light rare earth elements (LREE) (LaN/YbN = 5–62; CeN/SmN = 1–3; where N = primitive mantle normalized values), they have high Ca/Al ratios (10–410), low to medium Ti/Eu ratios (742–2840), and low Zr/Hf ratios (13–26), which suggest they were formed by metasomatic reactions with CO2-rich silicate melts. Phlogopite with high TiO2 (>2.0 wt.%), Al2O3 (>12.0 wt.%), and FeOt (5.0–13.0 wt.%) resemble those found in the groundmass of kimberlites, lamproites and lamprophyres. Conversely, phlogopite with low TiO2 (<1.0 wt.%) and lower Al2O3 (<12.0 wt.%) are similar to those present in GPP-PP-PKP, and in MARID (mica-amphibole-rutile-ilmenite-diopside) and PIC (phlogopite-ilmenite-clinopyorxene) xenoliths. The GPP-PP-PKP suite of xenoliths, together with the clinopyroxene and phlogopite major and trace element signatures suggests that an intense proto-kimberlite melt metasomatism occurred in the deep cratonic lithosphere beneath the Amazonian Craton. The Sr-Nd isotopic ratios of pyrope xenocrysts (G3, G9 and G11) from the Carolina kimberlite are characterized by high 143Nd/144Nd (0.51287–0.51371) and εNd (+4.55 to +20.85) accompanied with enriched 87Sr/86Sr (0.70405–0.71098). These results suggest interaction with a proto-kimberlite melt compositionally similar with worldwide kimberlites. Based on Sr-Nd whole-rock compositions, the Carolina kimberlite has affinity with Group 1 kimberlites. The Sm-Nd isochron age calculated with selected eclogitic garnets yielded an age of 291.9 ± 5.4 Ma (2 σ), which represents the cooling age after the proto-kimberlite melt metasomatism. Therefore, we propose that the lithospheric mantle beneath the Amazonian Craton records the Paleozoic subduction with the attachment of an eclogitic slab into the cratonic mantle (garnetites and eclogites); with a later metasomatic event caused by proto-kimberlite melts shortly before the Carolina kimberlite erupted.  相似文献   

6.
Mineralogical data for xenoliths occurring as inclusions in the fissure erupted alkali basalts and the basanitic tuffs of Anjouan reveal three xenolith suites: 1) the lherzolites, 2) the dunites and wehrlites, 3) the gabbros and syenites. The dunite-wehrlite suite and the gabbro suite are shown to represent high-level cumulate sequences resulting from ankaramitic fractionation of the hy-normative shield-building lavas and cotecictic fractionation of the alkali basalt lavas respectively, whilst the syenitic xenoliths represent evolved high-level intrusions. Mineralogical and rare earth element (REE) data indicate that the most likely origin for the spinel lherzolite xenoliths is by extraction of a basaltic phase from spinel peridotite, leaving a light REE-poor spinel lherzolite residuum. REE models, constructed using model peridotite assemblages, imply that the hy-normative basalt lavas may be derived by partial melting of spinel peridotite at pressures of <20–25 kb leaving a residual lherzolite, and that the alkali basalt and basanite melts are formed by small degrees of melting of a garnet-peridotite source at pressures of >20–25 kb. The spinel lherzolite source for the hy-normative basalts has been accidentally sampled during explosive eruption of the alkali basalt and basanite magmas.  相似文献   

7.
Ultramafic xenoliths were found in recent alkali basalts from São Tomé Island. These include spinel peridotites (lherzolites, harzburgites and dunites) and pyroxenites (orthopyroxenites and clinopyroxenites). Textures and mineral compositions indicate that pyroxenites originated from crystal/liquid separation processes operating on magmas similar to those giving rise to their present host rocks whereas spinel peridotite xenoliths had an accidental origin; Fo (>89) and Ni (>0.36 wt.%) contents in olivines, Mg# (91–95) of orthopyroxenes and low Ti in clinopyroxene (primary crystals: TiO2<0.06 wt.%) and in spinel (TiO2<0.1 wt.%) are within the range reported for abyssal peridotites, indicating São Tomé spinel peridotites represent refractory residues of melting. Nevertheless, the lack of correlation between mineral chemistry and modal composition suggests that spinel peridotite xenoliths are not simple residues and were affected by infiltration of fluid/melts within the mantle. The wide temperature range obtained for spinel peridotites (700 to >1150 °C) is compatible with a long period of pre-entrainment cooling supporting Fitton's [Tectonophysics 94 (1983) 473] hypothesis that proposes oceanic lithosphere uprising in the Cameroon Volcanic Line prior to the initiation of the current thermal regime, related to São Tomé magmatism. The association of upper mantle (peridotite) xenoliths with igneous cumulates (pyroxenites) suggests that the spinel peridotite suite originated in the uppermost mantle above the São Tomé magma storage zone(s), probably in a region of high strain rate, near the boundary between the mantle and the overlying oceanic crust.  相似文献   

8.
Summary A suite of clinopyroxenite nodules, megacrysis and associated lavas from Somma-Vesuvius, Italy, has been investigated to establish its possible genetic relationships with the leucitebearing lavas of the Roman Region. The clinopyroxenites are essentially composed of clinopyroxene + mica and subordinate olivine, plagioclase, spinels, apatite and glass. The megacrysts are clinopyroxene fragments. The associated lavas are leucite-tephrites and a tephritic leucitite.The mineralogy of the clinopyroxenites is distinctive but gradational to that of the Somma-Vesuvius lavas and reflects subvolcanic crystallization of a silica-undersaturated, mafic magma. The megacrystic clinopyroxene is probably related to the clinopyroxenites.The chemical composition of the clinopyroxenites shows strong affinites to that of the Somma-Vesuvius lavas and corresponds to leucite basanite compositions. Interstitial glass in the clinopyroxenites represents a residual liquid from clinopyroxenite crystallization. This glass approaches the chemical composition of the Somma tephrites.The experimental melting of two clinopyroxenites at 1 atm demonstrates that the essential assemblage of the Somma-Vesuvius lava, leucite + clinopyroxene, may develop from basanite compositions where olivine disappears by reaction with the liquid to form clinopyroxene. It is concluded that the clinopyroxenites represent basanitic magma crystallized at depth and that the Somma-Vesuvius leucite-bearing lavas are potential derivatives of this magma.
Petrologie von Klinopyroxenit-Auswürflingen von Somma-Vesuv und ihre genetische Bedeutung
Zusammenfassung Leucit-Tephrite und tephritische Leucitite der Romana enthalten Klinopyroxenit-Einschlüsse sowie Kristalle von Klinopyroxen, Glimmer, und untergeordnet Olivin, Plagioklas, Spinell, Apatit und Glas. Die genetischen Beziehungen zwischen Laven und Einschlüssen wurden an Hand der Ergebnisse petrologischer und geochemischer Untersuchungen überprüft.Die Mineralogie der Klinopyroxenite kann mit der der Somma-Vesuv-Laven korreliert werden und weist auf subvulkanische Kristallisation eines Si-untersättigten, mafischen Magmas hin.Die chemische Zusammensetzung der Klinopyroxenite zeigt deutliche Beziehungen zu den Laven von Somma-Vesuv und entspricht einem leucit-basanitischen Typ. Restschmelze der Klinopyroxenit-Kristallisation ist als Glas auf der Intergranulare erhalten. Die Zusammensetzung dieser Gläser ähnelt der von Somma-Tephriten.Schmelzversuche an zwei Klinopyroxeniten bei 1 atm zeigen, daß die wichtigste Mineralassoziation der Somma-Vesuv-Laven, Leucit und Klinopyroxen, aus einer basanitischen Zusammensetzung abzuleiten sind. Olivin verschwindet dabei durch Reaktion mit der Schmelze und Klinopyroxen wird gebildet. Die Untersuchungen lassen erkennen, daß die Klinopyroxenite Kristallisationsprodukte in der Tiefe erstarrter basanitischer Magmen sind, und daß die leucitführenden Magmen von Somma-Vesuv als mögliche Abkömmlinge dieser Magmen zu sehen sind.

With 3 Figures  相似文献   

9.
Summary The Late Pleistocene Mt. Vulture strato-volcano developed at the intersection of NE-SW and NW-SE lithospheric fault systems, on the easternmost border of the Apennine compressional front overthrust onto the Apulian foreland. The initial phase of the volcanic activity is represented by pyroclastic deposits, including lava blocks, and subordinate eccentric domes, mostly phonolitic in composition. The later stages of activity formed the bulk of the strato-volcano (pyroclastic products and subordinate lavas), mostly tephritic in composition, with minor intercalations of basanite, mela-foidite and melilitite lavas and dikes. Variations in rock and mineral composition suggest that the volumetrically predominant basanite-tephrite (foidite)-phonotephrite-phonolite series can be accounted for by fractional crystallization processes starting from basanitic parental magmas, in agreement with the remarkably constant 87Sr/86Sr isotopes (0.70586–0.70581). Mass-balance calculations indicate that the variably differentiated magmas may have been produced by removal of wehrlite, clinopyroxenite and syenite cumulates, some of which are occasionally found as cognate xenoliths in the volcanics. Fractionation processes probably developed in multiple-zoned magma chambers, at depths of 3–5 km, corresponding to the tectonic discontinuity between the allochthonous Apennine formations and the underlying Apulian platform. Highly differentiated phonolitic magmas capping the magma chambers and their conduits thus appear to have fed the initial volcanic activity, whereas dominantly tephritic products were erupted in later stages. The least evolved mafic magmas, namely basanites, mela-foidites and melilitites, are characterized by diverse Na/K ratios and critical SiO2-undersaturation, which indicate their derivation as independent melts generated from distinct, heterogeneously enriched mantle sources and by variable partial melting degrees. Primitive mantle-normalized incompatible element patterns of Vulture mafic lavas invariably share analogies with both orogenic subduction-related magmas (high Low Field Strength Elements/High Field Strength Elements ratios, K, Rb and Th contents and marked Ti and Nb negative anomalies) and alkaline lavas from within-plate and rift settings (high Light Rare Earth Elements, P, Zr, Nb and Na). These geochemical features may be accounted for by magma generation from deep lithospheric mantle sources, enriched in Na-alkali silicate/carbonatite anorogenic components, subsequently affected by orogenic subduction-related K-metasomatism, analogous to that which modified magma sources of the Roman Magmatic Province along the internal Apennine Chain. Received April 12, 2000; revised version accepted June 7, 2001  相似文献   

10.
St. Kitts lies in the northern Lesser Antilles, a subduction-related intraoceanic volcanic arc known for its magmatic diversity and unusually abundant cognate xenoliths. We combine the geochemistry of xenoliths, melt inclusions and lavas with high pressure–temperature experiments to explore magma differentiation processes beneath St. Kitts. Lavas range from basalt to rhyolite, with predominant andesites and basaltic andesites. Xenoliths, dominated by calcic plagioclase and amphibole, typically in reaction relationship with pyroxenes and olivine, can be divided into plutonic and cumulate varieties based on mineral textures and compositions. Cumulate varieties, formed primarily by the accumulation of liquidus phases, comprise ensembles that represent instantaneous solid compositions from one or more magma batches; plutonic varieties have mineralogy and textures consistent with protracted solidification of magmatic mush. Mineral chemistry in lavas and xenoliths is subtly different. For example, plagioclase with unusually high anorthite content (An≤100) occurs in some plutonic xenoliths, whereas the most calcic plagioclase in cumulate xenoliths and lavas are An97 and An95, respectively. Fluid-saturated, equilibrium crystallisation experiments were performed on a St. Kitts basaltic andesite, with three different fluid compositions (XH2O = 1.0, 0.66 and 0.33) at 2.4 kbar, 950–1025 °C, and fO2 = NNO ? 0.6 to NNO + 1.2 log units. Experiments reproduce lava liquid lines of descent and many xenolith assemblages, but fail to match xenolith and lava phenocryst mineral compositions, notably the very An-rich plagioclase. The strong positive correlation between experimentally determined plagioclase-melt KdCa–Na and dissolved H2O in the melt, together with the occurrence of Al-rich mafic lavas, suggests that parental magmas were water-rich (> 9 wt% H2O) basaltic andesites that crystallised over a wide pressure range (1.5–6 kbar). Comparison of experimental and natural (lava, xenolith) mafic mineral composition reveals that whereas olivine in lavas is predominantly primocrysts precipitated at low-pressure, pyroxenes and spinel are predominantly xenocrysts formed by disaggregation of plutonic mushes. Overall, St. Kitts xenoliths and lavas testify to mid-crustal differentiation of low-MgO basalt and basaltic andesite magmas within a trans-crustal, magmatic mush system. Lower crustal ultramafic cumulates that relate parental low-MgO basalts to primary, mantle -derived melts are absent on St. Kitts.  相似文献   

11.
This paper presents new petrographic observations and geochemical and microprobe analyses for the Laomiaojishan, Xiaotongguanshan, and Tianebaodanshan intrusions in the Tongguanshan mineral district, East China. The plutons vary in composition from quartz monzonitic diorite to pyroxene monzonitic diorite, and contain gabbroic to dioritic xenoliths. The Xiaotongguanshan intrusion yields a SHRIMP zircon U–Pb age of 139.5±2.9 Ma, indicating Late Jurassic to Early Cretaceous magmatism in the Lower Yangtze River Valley. Relative to host rocks, the gabbro and diorite xenoliths are low in SiO2 (52.03–54.61 wt‐%), Al2O3 (12.87–14.43 wt‐%), and total alkalis (Na2O+K2O; 5.26–6.30 wt‐%), but high in MgO (5.41–11.66 wt‐%); the host rocks have high SiO2 (59.97–64.44 wt‐%), Al2O3 (16.43–17.59 wt‐%), and total alkalis (6.67–8.25 wt‐%), but are low in MgO (1.52–2.50 wt‐%). Concentrations of rare earth elements (REEs) in the xenoliths (165.70–190.40 ppm) are similar to those in the host rocks (166.12–185.95 ppm), although the ratio of light REEs to heavy REEs in the xenoliths (3.39–4.27) is lower than that in the host plutons (4.86–5.94). All of the analysed rocks show similar REE patterns, although the xenoliths display marked positive Eu anomalies and the host rocks show slightly negative Eu anomalies. Values of epsilon Nd (t) ranges from ?4.9 to ?9.9 in the gabbro xenoliths and from ?11.4 to ?11.9 in the host intrusives. Initial 87Sr/86Sr ratios are 0.7064–0.7073 in the xenoliths and 0.7072–0.7084 in the quartz monzonitic diorite host rocks. Crystallization temperatures of hornblende and plagioclase in the gabbro xenoliths, diorite xenoliths, and host rocks are 816, 773–790, and 664–725°C, respectively, based on an amphibole–plagioclase geothermometer. The pressures recorded by these phases indicate that they formed at depths of 26, 12–15, and 3–4 km, respectively, based on an aluminum‐in‐hornblende geobarometer. The petrological and geochemical features of the analysed intrusions and xenoliths are consistent with their derivation from basic to intermediate‐acidic magmas that possibly formed via a series of complex interactions between underplated, mantle‐derived basaltic magma and varying amounts of middle‐ to lower‐crustal material, followed by assimilation–fractional crystallization.  相似文献   

12.
Calcic diopside megacrysts, called Granny Smith nodules, in the Kimberley area and Jagersfontein kimberlites are sheared, commonly contain lenticles of ilmenite and intergrowths of phlogopite, and have a distinctive apple-green color. These diopsides have Ca(Ca + Mg) > 0.45, Mg(Mg + Fe) > 0.90, 0.2?0.4 wt% TiO2 and 0.5–3 wt% Cr2O3. They have Na > (Al + Cr), in contrast to diopsides in peridotite xenoliths and those that form subcalcic discrete nodules, but in this respect are similar to diopsides in amphibole-bearing MARID nodules and mica-rich glimmerites. Granny Smith megacrysts are not cognate (Kramers, 1979); their parental magmas (in an igneous or metasomatic sense) may have been parts of the spectrum between kimberlites and lamproites.  相似文献   

13.
We present petrography and mineral chemistry for both phlogopite,from mantle-derived xenoliths(garnet peridotite,eclogite and clinopyroxene-phlogopite rocks)and for megacryst,macrocryst and groundmass flakes from the Grib kimberlite in the Arkhangelsk diamond province of Russia to provide new insights into multi-stage metasomatism in the subcratonic lithospheric mantle(SCLM)and the origin of phlogopite in kimberlite.Based on the analysed xenoliths,phlogopite is characterized by several generations.The first generation(Phil)occurs as coarse,discrete grains within garnet peridotite and eclogite xenoliths and as a rock-forming mineral within clinopyroxene-phlogopite xenoliths.The second phlogopite generation(Phl2)occurs as rims and outer zones that surround the Phil grains and as fine flakes within kimberlite-related veinlets filled with carbonate,serpentine,chlorite and spinel.In garnet peridotite xenoliths,phlogopite occurs as overgrowths surrounding garnet porphyroblasts,within which phlogopite is associated with Cr-spinel and minor carbonate.In eclogite xenoliths,phlogopite occasionally associates with carbonate bearing veinlet networks.Phlogopite,from the kimberlite,occurs as megacrysts,macrocrysts,microcrysts and fine flakes in the groundmass and matrix of kimberlitic pyroclasts.Most phlogopite grains within the kimberlite are characterised by signs of deformation and form partly fragmented grains,which indicates that they are the disintegrated fragments of previously larger grains.Phil,within the garnet peridotite and clinopyroxene-phlogopite xenoliths,is characterised by low Ti and Cr contents(TiO_21 wt.%,Cr_2 O_31 wt.% and Mg# = 100 × Mg/(Mg+ Fe)92)typical of primary peridotite phlogopite in mantle peridotite xenoliths from global kimberlite occurrences.They formed during SCLM metasomatism that led to a transformation from garnet peridotite to clinopyroxene-phlogopite rocks and the crystallisation of phlogopite and high-Cr clinopyroxene megacrysts before the generation of host-kimberlite magmas.One of the possible processes to generate low-Ti-Cr phlogopite is via the replacement of garnet during its interaction with a metasomatic agent enriched in K and H_2O.Rb-Sr isotopic data indicates that the metasomatic agent had a contribution of more radiogenic source than the host-kimberlite magma.Compared with peridotite xenoliths,eclogite xenoliths feature low-Ti phlogopites that are depleted in Cr_2O_3 despite a wider range of TiO_2 concentrations.The presence of phlogopite in eclogite xenoliths indicates that metasomatic processes affected peridotite as well as eclogite within the SCLM beneath the Grib kimberlite.Phl2 has high Ti and Cr concentrations(TiO_22 wt.%,Cr_2O_31 wt.% and Mg# = 100× Mg/(Mg + Fe)92)and compositionally overlaps with phlogopite from polymict brecc:ia xenoliths that occur in global kimberlite formations.These phlogopites are the product of kimberlitic magma and mantle rock interaction at mantle depths where Phl2 overgrew Phil grains or crystallized directly from stalled batches of kimberlitic magmas.Megacrysts,most macrocrysts and microcrysts are disintegrated phlogopite fragments from metasomatised peridotite and eclogite xenoliths.Fine phlogopite flakes within kimberlite groundmass represent mixing of high-Ti-Cr phlogopite antecrysts and high-Ti and low-Cr kimberlitic phlogopite with high Al and Ba contents that may have formed individual grains or overgrown antecrysts.Based on the results of this study,we propose a schematic model of SCLM metasomatism involving phlogopite crystallization,megacryst formation,and genesis of kimberlite magmas as recorded by the Grib pipe.  相似文献   

14.
The mineralogy and geochemical characteristics of intermediate composition ferrolatites and related lavas from the Magic Reservoir eruptive center (central Snake River Plain) have been investigated to evaluate the origin and petrologic significance of these hybrid lavas. The ferrolatites are chemically uniform, but contain a disequilibrium phenocryst/xenocryst assemblage derived in part from mixed rhyolitic and basaltic magmas that are closely represented by extrusive units in the area. The hybrid lavas also contain xenoliths of Archean granulites and have high 87Sr/ 86Sr and low 143Nd/144Nd ratios, all of which suggest significant magma-crust interaction. Quantitative models including magma mixing, minor crystal fractionation, and crustal contamination very closely reproduce the observed compositions of these ferrolatites; closed system fractionation and (or) simple bulk contamination models are not as successful and can be ruled out. It appears that preexisting mafic and silicic magmas from distinct sources (e.g., mantle and crust) encounter one another in crustal-level magma chambers under conditions where intimate mixing may occur despite wide differences in the physical properties of these liquids.  相似文献   

15.
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16.
Volcán San Pedro in the Andean Southern Volcanic Zone(SVZ) Chile, comprises Holocene basaltic to dacitic lavas withtrace element and strontium isotope ratios more variable thanthose of most Pleistocene lavas of the underlying Tatara–SanPedro complex. Older Holocene activity built a composite coneof basaltic andesitic and silicic andesitic lavas with traceelement ratios distinct from those of younger lavas. Collapseof the ancestral volcano triggered the Younger Holocene eruptivephase including a sequence of lava flows zoned from high-K calc-alkalinehornblende–biotite dacite to two-pyroxene andesite. Notably,hornblende–phlogopite gabbroic xenoliths in the daciticlava have relatively low 87Sr/86Sr ratios identical to theirhost, whereas abundant quenched basaltic inclusions are moreradiogenic than any silicic lava. The latest volcanism rebuiltthe modern 3621 m high summit cone from basaltic andesite thatis also more radiogenic than the dacitic lavas. We propose thefollowing model for the zoned magma: (1) generation of hornblende–biotitedacite by dehydration partial melting of phlogopite-bearingrock similar to the gabbroic xenoliths; (2) forceful intrusionof basaltic magma into the dacite, producing quenched basalticinclusions and dispersion of olivine and plagioclase xenocryststhroughout the dacite; (3) cooling and crystallization–differentiationof the basalt to basaltic andesite; (4) mixing of the basalticandesite with dacite to form a small volume of two-pyroxenehybrid andesite. The modern volcano comprises basaltic andesitethat developed independently from the zoned magma reservoir.Evolution of dacitic and andesitic magma during the Holoceneand over the past 350 kyr reflects the intrusion of multiplemafic magmas that on occasion partially melted or assimilatedhydrous gabbro within the shallow crust. The chemical and isotopiczoning of Holocene magma at Volcán San Pedro is paralleledby that of historically erupted magma at neighboring VolcánQuizapu. Consequently, the role of young, unradiogenic hydrousgabbro in generating dacite and contaminating basalt may beunderappreciated in the SVZ. KEY WORDS: Andes; dacite; gabbro; Holocene; strontium isotopes  相似文献   

17.
《地学前缘(英文版)》2020,11(6):2157-2168
Mount Cameroon volcano has erupted several times in the 20th Century with documented eruptions in 1909, 1922, 1954, 1959, 1982, 1999 and 2000. Evidence of historic volcanism is represented by several older lava flows and lahar deposits around the flanks of the volcano. This study aims to assess the evolution of Mount Cameroon volcanism through its eruptive history via interpretation of mineralogical, whole rock geochemical and Pb, Sr, Nd isotope data generated from historic and recent lava flows. In this study, samples were collected from the 1959, 1982, 1999 and 2000 eruptions and from several historic eruption sites with unknown eruption dates.Evaluation of major and trace element data demonstrates that Mount Cameroon is geotectonically associated with within-plate Ocean Island Basalt Settings. More than 90% of the studied historic lavas (n ​= ​29) classify as tephrites and basanites whereas the modern lavas (n ​= ​38) are predominantly trachybasalts, demonstrating evolution from primitive to evolved lavas over time typically in response to fractional crystallization. Petrographically, the lavas are porphyritic with main mineral phases being olivine, clinopyroxene, plagioclase feldspars and Fe–Ti–Cr oxides. The 1982 lavas are predominantly aphyric and dominated by lath-shaped flow-aligned plagioclase in the groundmass. Olivine chemistry shows variable forsterite compositions from Fo60–89. Clinopyroxenes vary from diopside through augite to titanaugite with chemical composition ranges from Wo45En32Fs7 to Wo51En47Fs17. Plagioclase feldspars vary from labradorite (An56–70) to bytownite (An80–87). For the Fe–Ti–Cr oxides, calculated ulvöspinel component shows a wide variation from ulv38–87. CIPW-normative classification on the Di-Ol-Hy-Qz-Ne system shows that all Mount Cameroon lavas are nepheline-normative (Ne ranges from 4.20 wt.% to 11.45 ​wt.%).Radiogenic isotope data demonstrate that Mount Cameroon lavas are HIMU (or high μ ​= ​238U/204Pb), characterized by 206Pb/204Pb ​= ​20.19–20.46, 207Pb/204Pb ​= ​15.63–15.69, 208Pb/204Pb ​= ​40.01–40.30, 87Sr/86Sr ​= ​0.70322–0.70339 (εSr ​= ​−21.37 to −18.96) and 143Nd/144Nd ​= ​0.51276–0.51285 (εNd ​= ​+2.29 to +4.05). The historic lavas show stronger HIMU signature relative to the modern lavas, suggesting evolution towards less HIMU signatures over time. This study has revealed that Mount Cameroon volcanism has evolved from primitive magmas characterized by stronger HIMU signatures with high 206/204Pb and 208/204Pb isotopes, low SiO2 and high Mg, Ni, Cr content towards lower HIMU signatures with relatively higher SiO2, lower Mg, Cr and Ni compositions. The geochemical and isotopic changes, which account for the evolution of magmatism on Mount Cameroon occur over long periods of time because all the modern lavas erupted within the last 100 years are isotopically homogeneous, with very limited variation in SiO2 compositions.  相似文献   

18.
Basaltic lavas from the AMAR Valley and the Narrowgate region of the FAMOUS Valley on the Mid-Atlantic Ridge (36° to 37°?N) range in texture from aphyric to highly plagioclase phyric (>25% large plagioclase phenocrysts). Based on 87Sr/86Sr and 143Nd/144Nd ratios, most of these lavas can be subdivided into two distinct, isotopically homogeneous, groups: Group I has lower 87Sr/86Sr (0.70288±1) and higher 143Nd/144Nd (0.51312±1) ratios; Group II has higher 87Sr/86Sr (0.70296±1) and lower 143Nd/144Nd (0.51309±2) ratios. Most Group II lavas are aphyric, whereas Group I lavas are primarily plagioclase phyric. Lavas from both groups show a wide range in incompatible element abundance ratios (e.g., Zr/Nb =6–29; (La/Sm)n=0.6–1.7). Aphyric lavas have relatively constant Sc (40±1.5?ppm) abundances and CaO/Al2O3 ratios (0.80±0.02). Group I lavas are confined primarily to the AMAR rift valley floor whereas Group II lavas are found along the east and west marginal highs. We interpret the isotopic differences between the two groups as reflecting a temporal change in the upwelling mantle beneath this region of the Mid-Atlantic Ridge which is south of the Azore Islands. For each group, a petrogenetic model consistent with the geochemical data is multi-stage decompression melting of an initially enriched, homogeneous, mantle source region. If the early derived, incompatible-element enriched, melt increments are not always pooled with subsequent increments, the erupted magma batches may have the major element characteristics of melts derived by 10 to 20% melting, but with incompatible element abundance ratios reflecting the change from an enriched to depleted source during the incremental melting process. In this process an initially homogeneous source can generate primary magmas with the required range in incompatible element abundance ratios shown by each group. The nearly constant CaO/Al2O3 ratios and Sc contents of the aphyric lavas with decreasing Mg?? reflects subsequent polybaric fractionation of clinopyroxene, plagioclase and olivine over the pressure interval 8–6?kbar (24–18?km), followed by rapid transport to the surface and eruption. There is no geochemical evidence for a crustal magma chamber beneath this section of the Mid-Atlantic Ridge.  相似文献   

19.
The unaltered magmatic rocks of the Zadoi Massif were analyzed for Sr isotopic composition and concentrations of major oxides and trace elements by ICP MS. The evolution of the massif involved four phases: (i) perovskite and ilmenite clinopyroxenites, (ii) ijolites, (iii) nepheline syenites, and (iv) carbonatites. The perovskite clinopyroxenites have anomalously high Ce/Pb (223–1132) and Pr/Sr × 1000 (70–360) ratios at a low initial Sr isotopic ratio (87Sr/86Sr)0 = 0.70247–0.70285. The ilmenite clinopyroxenites have Ce/Pb and Pr/Sr × 1000 ratios approaching those in basalts of oceanic islands (OIB) (decreasing to 39 and 30, respectively) at a simultaneous increase in the (87Sr/86Sr)0 ratios (0.7030–0.7036). The ijolites and nepheline syenites have patterns of incompatible trace elements similar to those in OIB and the highest (87Sr/86Sr)0 ratios (0.70346–0.70414). The carbonatites are complementarily enriched in incompatible elements of the nepheline syenites and have (87Sr/86Sr)0 = 0.7029–0.7034, which is comparable with the range of analogous ratios for the ilmenite clinopyroxenites. Our geochemical data indicate that the carbonatites were formed as an immiscible liquid or fluid, which separated from the ijolite-nepheline syenite melt during its interaction with the source material of the perovskite and ilmenite clinopyroxenites.  相似文献   

20.
Alkali-bearing Ti oxides were identified in mantle xenoliths enclosed in kimberlite-like rocks from Limeira 1 alkaline intrusion from the Alto Paranaíba Igneous Province, southeastern Brazil. The metasomatic mineral assemblages include mathiasite-loveringite and priderite associated with clinopyroxene, phlogopite, ilmenite and rutile. Mathiasite-loveringite (55–60 wt.% TiO2; 5.2–6.7 wt.% ZrO2) occurs in peridotite xenoliths rimming chromite (～50 wt.% Cr2O3) and subordinate ilmenite (12–13.4 wt.% MgO) in double reaction rim coronas. Priderite (Ba/(K+Ba)< 0.05) occurs in phlogopite-rich xenoliths as lamellae within Mg-ilmenite (8.4–9.8 wt.% MgO) or as intergrowths in rutile crystals that may be included in sagenitic phlogopite. Mathiasite-loveringite was formed by reaction of peridotite primary minerals with alkaline melts. The priderite was formed by reaction of peridotite minerals with ultrapotassic melts. Disequilibrium textures and chemical zoning of associated minerals suggest that the metasomatic reactions responsible for the formation of the alkali-bearing Ti oxides took place shortly prior the entrainment of the xenoliths in the host magma, and is not connected to old (Proterozoic) mantle enrichment events.  相似文献   

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