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1.
Characterisation of a Natural Quartz Crystal as a Reference Material for Microanalytical Determination of Ti,Al, Li,Fe, Mn,Ga and Ge 总被引：2，自引：0，他引：2 
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下载免费PDF全文 Andreas Audétat Dieter Garbe‐Schönberg Andreas Kronz Thomas Pettke Brian Rusk John J. Donovan Heather A. Lowers 《Geostandards and Geoanalytical Research》2015,39(2):171-184
A natural smoky quartz crystal from Shandong province, China, was characterised by laser ablation ICP‐MS, electron probe microanalysis (EPMA) and solution ICP‐MS to determine the concentration of twenty‐four trace and ultra trace elements. Our main focus was on Ti quantification because of the increased use of this element for titanium‐in‐quartz (TitaniQ) thermobarometry. Pieces of a uniform growth zone of 9 mm thickness within the quartz crystal were analysed in four different LA‐ICP‐MS laboratories, three EPMA laboratories and one solution‐ICP‐MS laboratory. The results reveal reproducible concentrations of Ti (57 ± 4 μg g?1), Al (154 ± 15 μg g?1), Li (30 ± 2 μg g?1), Fe (2.2 ± 0.3 μg g?1), Mn (0.34 ± 0.04 μg g?1), Ge (1.7 ± 0.2 μg g?1) and Ga (0.020 ± 0.002 μg g?1) and detectable, but less reproducible, concentrations of Be, B, Na, Cu, Zr, Sn and Pb. Concentrations of K, Ca, Sr, Mo, Ag, Sb, Ba and Au were below the limits of detection of all three techniques. The uncertainties on the average concentration determinations by multiple techniques and laboratories for Ti, Al, Li, Fe, Mn, Ga and Ge are low; hence, this quartz can serve as a reference material or a secondary reference material for microanalytical applications involving the quantification of trace elements in quartz. 相似文献
2.
等离子体发射光谱法同时测定大洋富钴结壳中硅锰铁钙镁铝钛 总被引：3，自引：0，他引：3
大洋富钴结壳试样经ＨＣｌ＋ＨＮＯ３＋ＨＦ溶解,在０．２ｍｏｌ／ＬＨＦ和０．１３ｍｏｌ／ＬＨ３ＢＯ３介质中,用感耦等离子发射光谱法同时测定Ｓｉ、Ｍｎ、Ｆｅ、Ｃａ、Ｍｇ、Ａｌ、Ｔｉ元素的含量。方法经国家标准物质ＧＢＷ０７２４９大洋多金属结核验证,其结果与标准值相符,精密度ＲＳＤ〈３．２％（ｎ＝６）;已应用于太平洋富钴结壳中多元素分析。 相似文献
3.
A Comparison of In Situ Analytical Methods for Trace Element Measurement in Gold Samples from Various South African Gold Deposits 下载免费PDF全文
下载免费PDF全文 Christoph Gauert Mathias Schannor Lutz Hecht Martin Radtke Uwe Reinholz 《Geostandards and Geoanalytical Research》2016,40(2):267-289
Trace element concentrations in gold grains from various geological units in South Africa were measured in situ by field emission‐electron probe microanalysis (FE‐EPMA), laser ablation‐inductively coupled plasma‐mass spectrometry (LA‐ICP‐MS) and synchrotron micro X‐ray fluorescence spectroscopy (SR‐μ‐XRF). This study assesses the accuracy, precision and detection limits of these mostly non‐destructive analytical methods using certified reference materials and discusses their application in natural sample measurement. FE‐EPMA point analyses yielded reproducible and discernible concentrations for Au and trace concentrations of S, Cu, Ti, Hg, Fe and Ni, with detection limits well below the actual concentrations in the gold. LA‐ICP‐MS analyses required larger gold particles (> 60 μm) to avoid contamination during measurement. Elements that measured above detection limits included Ag, Cu, Ti, Fe, Pt, Pd, Mn, Cr, Ni, Sn, Hg, Pb, As and Te, which can be used for geochemical characterisation and gold fingerprinting. Although LA‐ICP‐MS measurements had lower detection limits, precision was lower than FE‐EPMA and SR‐μ‐XRF. The higher variability in absolute values measured by LA‐ICP‐MS, possibly due to micro‐inclusions, had to be critically assessed. Non‐destructive point analyses of gold alloys by SR‐μ‐XRF revealed Ag, Fe, Cu, Ni, Pb, Ti, Sb, U, Cr, Co, As, Y and Zr in the various gold samples. Detection limits were mostly lower than those for elements measured by FE‐EPMA, but higher than those for elements measured by LA‐ICP‐MS. 相似文献
4.
太平洋北部铁锰结核富集区沉积物的元素地球化学特征 总被引：2，自引：1，他引：2
本文对太平洋北部铁锰结核富集区沉积物的元素地球化学作了较为详细的研究。因子分析提供的信息表明,元素的分布主要受三个因子控制:（1）粘土及Fe、Mn氧化物水化物胶体的吸附作用;（2）生物化学作用过程有关的自生沉积作用;（3）海底页岩风化及附近海区的火山喷发作用。元素的来源:（1）Fe、Mn、Cu、Co、Ni、Zn、Cr、Cr、Mg、Al、Ti、K共生,主要来自粘土吸附;（2）C有机、N、Sr、Na及Si、Ca、Sr主要来自生物化学过程沉积;（3）Pb主要来源于岩石碎屑（火山喷发碎屑）。 相似文献
5.
Phytoplankton samples, collected in Monterey Bay, California, were analyzed for their Pb, Hg, Cd, Co, Ag, Cr, Ti, V, Mn, Ni, Cu, Fe, Zn, AI, Mo, Ba, Sr, K, Ca, Mg, Na and SiO2 content. The results of these analyses were categorized on a chemical basis and the sample data were placed in three groups: Group I, Ti not detected; Group II, Ti detected; and Group III, Sr concentrators present. Levels of most elements were higher in Groups II and III for a variety of reasons that are discussed in the text. The siliceous frustules, remaining after organic-matter digestion, were also analyzed for the elements listed above. Significant amounts of Al, Ti, Fe, Mn, Cu and Zn were found.Zooplankton and microplankton samples, collected in Monterey Bay, California; off the coast of Oregon; and on a transect between Hawaii and Monterey, were also analyzed for the elements listed above (except Si). In general, element levels in the inshore and offshore zoo-plankton were similar; however, the microplankton samples, in which strontium was highly concentrated, were almost always higher in Pb, Hg, Cu, Fe and Zn. 相似文献
6.
Trace Element Geochemistry of Magnetite from the Fe(-Cu) Deposits in the Hami Region, Eastern Tianshan Orogenic Belt, NW China 总被引：5，自引：0，他引：5
Laser ablation–inductively coupled plasma–mass spectrometry(LA–ICP–MS) was used to determine the trace element concentrations of magnetite from the Heifengshan, Shuangfengshan, and Shaquanzi Fe(–Cu) deposits in the Eastern Tianshan Orogenic Belt. The magnetite from these deposits typically contains detectable Mg, Al, Ti, V, Cr, Mn, Co, Ni, Zn and Ga. The trace element contents in magnetite generally vary less than one order of magnitude. The subtle variations of trace element concentrations within a magnetite grain and between the magnetite grains in the same sample probably indicate local inhomogeneity of ore–forming fluids. The variations of Co in magnetite between samples are probably due to the mineral proportion of magnetite and pyrite. Factor analysis has discriminated three types of magnetite: Ni–Mn–V–Ti(Factor 1), Mg–Al–Zn(Factor 2), and Ga– Co(Factor 3) magnetite. Magnetite from the Heifengshan and Shuangfengshan Fe deposits has similar normalized trace element spider patterns and cannot be discriminated according to these factors. However, magnetite from the Shaquanzi Fe–Cu deposit has affinity to Factor 2 with lower Mg and Al but higher Zn concentrations, indicating that the ore–forming fluids responsible for the Fe–Cu deposit are different from those for Fe deposits. Chemical composition of magnetite indicates that magnetite from these Fe(–Cu) deposits was formed by hydrothermal processes rather than magmatic differentiation. The formation of these Fe(–Cu) deposits may be related to felsic magmatism. 相似文献
7.
G. S. Lodha K. J. S. Sawhney H. Razdan D. P. Agrawal N. Juyal 《Journal of Earth System Science》1987,96(2):135-145
Major and trace element concentrations of a few representative loess profiles in Kashmir valley are studied using EDXRF spectroscopy.
Principal component analysis for pattern recognition has been employed to study association between elemental concentration
variations in various horizons. The present study reveals that elements related to clay illuviation (K, Rb, Fe, Ti, Mn) and
plant activity (Cu, Zn) are generally higher in B horizon of the palaeosols whereas Ca and Sr have a high concentration in
the loess layers. Such an elemental concentration variation provides us with an objective index for identification and confirmation
of palaeosols. There is further a close association in the movement of (i) K, Rb, (ii) Fe, Ti, Mn, (iii) Cu, Zn and (iv) Ca,
Sr. These clusters of elements are also present in modern soils, suggesting that the soil characteristics in palaeosols have
been preserved. Concentration of iron and titanium is also observed to be higher in loess profiles on Pir Panjal mountain
flank which is dominated by basic rocks, compared to profiles on Himalayan flank, suggesting that the loess in Kashmir might
have been derived from the nearby rocks in a localized way. 相似文献
8.
Kathryn L. Linge 《Geostandards and Geoanalytical Research》2008,32(4):453-468
This review describes developments in trace element determination using inductively coupled plasma‐atomic emission spectrometry (ICP‐AES) and inductively coupled plasma‐mass spectrometry (ICP‐MS) that were reported in 2006 and 2007. It focuses on the application of ICP techniques to geological and environmental samples; fundamental studies in ICP‐MS and ICP‐AES instrumentation have largely been ignored. New advances in ICP‐MS and ICP‐AES were incremental over this period, partly because both techniques are now well‐established. A continuing shift towards the hyphenation of low‐flow separation techniques has sparked activity in the development of appropriate low‐flow interfaces, and papers discussing interference removal also contribute significantly to the volume of research for both ICP‐AES and ICP‐MS. Whereas the majority of new ICP publications concerned advances in ICP‐MS analysis rather than ICP‐AES, development for ICP‐AES still occurs in almost all areas, particularly in sample introduction and hyphenated techniques. 相似文献
9.
Sediment samples at 10 locations in the mainstem of the Yellow River were taken in 1994. Five forms (exchangeable, carbonate, organic, Fe/Mn oxide and residual) of metals were extracted by the Tessier method. The total contents and contents of the five forms of 16 metal elements (Li, Na, K, Ca, Sr, Ba, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, and Al) were determined by ICP-AES. In sediments of the Yellow River, except for Na, mobile elements (such as K, Ca) do not show a negative correlation with the immobile elements. Alkaline metals (Li, Na, and K), Ti, and Al exist mainly in the residual form. The exchangeable forms of alkaline-earth elements (Ca, Sr, and Ba) are the highest, and their residual forms go up with the increase of the period in the periodic table of elements. Half of Mn exists in the residual form, and its non-residual forms exist mainly in carbonate and oxide forms. Except Mn, the iron group elements (Fe, Co, Ni, V, Cr) mainly exist in the residual and oxide forms. High carbonate content of Ca does not cause high contents of other elements in carbonate form, showing that chemical weathering is not strong in the area. 相似文献
10.
用质子探针和电子探针分别测定盘石山幔源橄揽岩包体中透辉石、橄榄石的微量元素和主量元素丰度;用X-射线荧光光谱法测定包体全岩的主量和微量元素丰度。定量讨论微量元素的分布和分配。其中绝大部分Sr、Zr、Ti、Na赋存在透辉石中,绝大部分Mn、Zn、Ni赋存在橄揽石中,在T=1194-1435K范围,分配系数变化如下:InDOl/CpxZn=1.44-2.19;InDOl/CpxMn=0.21-0.40,InDOl/CpxTi=4.76-5.61,InDOl/CpxNi(平均值)=2.20.透辉石中Ti/Zr=42-103,低于原始地幔值,由地幔隐性交代作用造成。 相似文献
11.
Valentina G. Batanova Jay M. Thompson Leonid V. Danyushevsky Maxim V. Portnyagin Dieter Garbe‐Schnberg Erik Hauri Jun‐Ichi Kimura Qing Chang Ryoko Senda Karsten Goemann Catherine Chauvel Sylvain Campillo Dmitri A. Ionov Alexander V. Sobolev 《Geostandards and Geoanalytical Research》2019,43(3):453-473
A new olivine reference material – MongOL Sh11‐2 – for in situ analysis has been prepared from the central portion of a large (20 × 20 × 10 cm) mantle peridotite xenolith from a ~ 0.5 My old basaltic breccia at Shavaryn‐Tsaram, Tariat region, central Mongolia. The xenolith is a fertile mantle lherzolite with minimal signs of alteration. Approximately 10 g of 0.5–2 mm gem quality olivine fragments were separated under binocular microscope and analysed by EPMA, LA‐ICP‐MS, SIMS and bulk analytical methods (ID‐ICP‐MS for Mg and Fe, XRF, ICP‐MS) for major, minor and trace elements at six institutions world‐wide. The results show that the olivine fragments are sufficiently homogeneous with respect to major (Mg, Fe, Si), minor and trace elements. Significant inhomogeneity was revealed only for phosphorus (homogeneity index of 12.4), whereas Li, Na, Al, Sc, Ti and Cr show minor inhomogeneity (homogeneity index of 1–2). The presence of some mineral and fluid‐melt micro‐inclusions may be responsible for the inconsistency in mass fractions obtained by in situ and bulk analytical methods for Al, Cu, Sr, Zr, Ga, Dy and Ho. Here we report reference and information values for twenty‐seven major, minor and trace elements. 相似文献
12.
沉积物的元素地球化学特征是对沉积盆地水体环境以及古气候条件变化的响应。本文根据元素（Al、Fe、Mg、Ca、K、Na、P、V、Ni、Co、Cr、Cu、Zn、Sr、Ba、Cd、Li、Mn、Pb、Ti）的含量及其比值（Al/Ti、Fe/Mn、Sr/Ba、Mg/Ca、Sr/Ca、Na/Ca、V/Cr、Ni/Co、Ni/V）的变化，对三水盆地古近系心组红岗段生油层的沉积条件进行了系统分析。心组红岗段下部（亚段A）表现为较稳定的地球化学特征。各元素丰度及其比值指示这一时期陆源输入持续较高、且物源组成变化不大。由于海水入侵的影响，湖盆水体盐度相对较高，底部水体以弱氧化条件为主，O2-H2S界面位于水/沉积物界面附近。红岗段中上部（亚段B、C）的元素地球化学特征变化较为频繁且幅度很大，反映古气候和湖盆沉积条件的迅速变迁。在潮湿气候条件下，沉积物的地球化学特征表现为以Al、Ti为代表的外源元素含量及其比值较高，而Mg、Ca等盆内化学沉积元素含量较低。古氧气指标指示底部水体为还原环境，有利于有机质保存。因而，相应于较高的有机碳含量。在间歇性干旱时期，陆源输入减少，外源元素含量及其比值显著降低。随着蒸发作用的加强，水体盐度加大，内源元素丰度以及Mg/Ca、Sr/Ba、Sr/Ca和Na/Ca比值大幅度上升。底部水体为氧化环境，O2-H2S界面多位于水/沉积物界面或沉积物中。上述两种气候条件在红岗段中上部沉积时期交替出现。红岗段沉积后期由于淡水的长期输入，湖水出现逐渐淡化趋势。 相似文献
13.
Four overbank profiles from the three terraces of different age were sampled in 10 to 20 cm intervals for the bulk content of major and minor (Ca, Mg, Fe, Ti, Al, Na, K and P) and trace (Mo, Cu, Pb, Zn, Ni, Co, Mn, As, U, Th, Sr, Cd, Sb, V, La, Cr, Ba, W, Zr, Ce, Sn, Y, Nb, Ta, Sc, Li, Rb and Hf) elements in the minus 0.125 mm fraction. Univariate statistics together with analysis of variance discriminated between the lower-lying carbonate (CA) population dominantly composed of carbonates and the overlying silicate (SI) population being dominantly of silicate mineralogy. This stratified pattern resulted from the intensive erosive action of melting glaciers exerted on limestones and dolomites in the alpine region, followed by local inputs mainly of silicate composition. Elements exhibiting the greatest between-population variability are Ca and Mg being enriched in the CA population and Fe, Mn, P, Sr, Al, Na, K, Li, Rb, Y, Zr, Ni, Cr and Ti being enriched in the SI population. Anomalously high Hg, Pb and Ba concentrations (maximum values: 6,500±2,860 ppb, 225±13 ppm and 1,519±91 ppm, respectively) in the lowermost part of the profile S7, which is nearest to the Croatian-Slovenian border, derive from the mineralized Slovenian catchment area. This profile also contains trimodal frequency distributions of Fe, Mn and P whose highest concentrations coincide with increased values of Zn and Cu which are bimodally distributed. Geochemical patterns of majority of elements in all four profiles consistently reflect the average compositions of the upstream drainage basins. 相似文献
14.
An Evaluation of the Effects of Primary and Cross‐Contamination during the Preparation of Rock Powders for Chemical Determinations 下载免费PDF全文
下载免费PDF全文 José P. Sertek Sandra Andrade Horstpeter H. Ulbrich 《Geostandards and Geoanalytical Research》2015,39(3):381-397
Quartz crystals from the Batatal site, Minas Gerais, southern Brazil, were used to determine quantitatively primary contamination when submitting the samples to milling processes. Crushing devices used were a primary steel jaw crusher (br1), a secondary tungsten carbide (WC) crusher (br2) and a hydraulic press with stainless steel plates (pr). Fragments with suitable sizes were then ground in different Fritsch planetary mills, equipped with agate, WC and chromium‐steel rings for 7, 4 and 3 min, respectively. Solutions of the powders were analysed initially with the TotalQuant? method in a quadrupole ICP‐MS instrument, providing semi‐quantitative results for seventy‐five elements. Contamination from crushers and mills was visible in major and minor elements such as Fe, Mn and Ti, and noticeable in trace elements such as Cr, Co, Ni, Cu and also V, Zr, Sc; significant contamination was observed from W, Mo, Co, Ta and Nb (mainly by use of the WC devices). Little or no contamination was observed for Pb, REE, Sr and Rb, elements that are important in routine isotopic determinations. Cross‐contamination was tested by grinding either a granite or a basalt sample, followed by conventional cleaning with mica‐free quartz sand, before the working quartz powder was prepared. 相似文献
15.
青藏铁路沱沱河取土场草本植物固土力学强度与化学元素含量特征 总被引：3，自引：0，他引：3
以青藏铁路沱沱河取土场草本植物种植区为例, 在野外和室内分别对生长期为5 a的6种草本做了原位拉拔试验、 室内拉伸试验和剪切试验, 分别得到了试验区梭罗草、 碱茅、 冷地早熟禾、 赖草、 垂穗披碱草、 星星草等6种草本根系抗拔力为187.34~57.89 N、 抗拉力为4.44~2.99 N, 抗剪力为4.33~3.85 N. 同时, 对取土场试验区6种草本地上茎叶、 地下根系15种化学元素进行了分析. 结果表明, 地上茎叶和地下根系主要含有Al、 Ca、 Mg、 K、 Fe、 Sr、 Zn、 Mn等8种元素, 其中Al、 Ca、 Mg、 K等4种元素较其余元素含量显著; 此外, 6种草本其根系所含Ca、 Fe、 Zn、 Sr、 Ni、 Cu等6种元素含量均显著大于相应草本种的茎叶部分. 试验区6种草本抗拔力由大至小依次为梭罗草、 赖草、 冷地早熟禾、 垂穗披碱草、 碱茅、 星星草, 6种草本其根系所含的其中前8种主要化学元素依次为Al、 Ca、 Mg、 K、 Fe 、 Zn、 Mn、 Sr等元素, 这说明了取土场试验区6种草本根系固土力学强度与根系所含化学元素具有一定的关系. 相似文献
16.
Factors affecting the distribution of potentially toxic elements in surface soils around an industrialized area of northwestern Greece 总被引：2，自引：0，他引：2
Alexandra Petrotou Konstantinos Skordas Georgios Papastergios Anestis Filippidis 《Environmental Earth Sciences》2012,65(3):823-833
In order to investigate the factors influencing the distribution of 32 potentially toxic elements in the Ptolemais–Kozani
basin, northwestern Greece, 38 soil samples were collected and analyzed. Concentrations of Al, Ca, Fe, K, Mg, Mn, Na, P, Ti,
Ba, Co, Cr, Cu, La, Li, Ni, Pb, Sc, Sr, V, Y, and Zn were determined by ICP-AES and concentrations of As, Bi, Cd, Cs, Mo,
Rb, Sb, Th, Tl, and U by ICP-MS. Bivariate analysis, principal component analysis, and geostatistical analysis were employed
to investigate the factors influencing the distribution of the elements determined in the study area. The results indicate
that the distribution of the majority of elements determined, especially for Cr, Ni, and associated elements, is greatly influenced
by the geology and geomorphology of the study area. Principal component analysis has yielded four factors that explain over
77% of the total variance in the data. These factors are as follows: lithophilic elements that are associated with Al silicates
minerals of K (factor I: 29.4%), ultramafic rocks (factor II: 20.5%), elements that are coprecipitated with Fe and Mn oxides
(factor III: 18.0%), and anthropogenic activities (factor IV: 9.3%). The anthropogenic activities that influence the distribution
of several potentially toxic elements (i.e., Cd, Cu, Pb, Zn) are agricultural practices and the deposition of fly ash in the
vicinity of the local power stations. 相似文献
17.
Doklady Earth Sciences - Published data and research results from the authors on the concentrations of dissolved trace elements (P, Si, Li, Rb, Cs, Sr, Ba, Mn, Fe, Co, Ni, Cu, Zn, Cd, Tl, Pb, Al,... 相似文献
18.
The specific chemical and mineral composition of discoid, cake-shaped, and platy ferromanganese nodules (FMNs) from the Chukchi Sea are considered. The main ore components of these FMNs are Fe, Mn, and P. The contents of trace elements (except for Ba and Sr) do not exceed hundredths of percent. Maximum concentrations of most of these elements are specific for the cake-shaped nodules. In general, Mn accumulates most intensely in FMNs. Next (in order of decrease) are Ag(?), Co, and Pb; Sr, Fe, P, Y, and Ca; and Ni, La, Zn, and Cu. As for Ba, Cr, Mg, and K, they do not accumulate in the FMNs. “Dilution” is typical of Si, Al, Na, and Ti. The main ore phases are strengite and amorphous Mn hydroxides. It has been revealed for the first time for the Chukchi Sea that Cu, Zn, Sn, Ni, Pb, W, Bi, Cr, Fe, Ti, Ag, Au, Y, Zr, and La–Nd lanthanides form individual mineral microphases in FMNs: native elements, intermetallic compounds, oxides, and, much more seldom, tungstates, silicates, and phosphates. Accessory ore mineralization is the best pronounced and most diverse in the platy nodules. Though the FMNs from the Chukchi Sea are diagenetic, high-temperature fluids are, most likely, the source of microinclusions of various accessory ore minerals. 相似文献
19.
Heye Freymuth Callum D. J. Reekie Helen M. Williams 《Geostandards and Geoanalytical Research》2020,44(3):407-420
We present a new procedure for the separation and purification of Cu and Zn from geological samples. Our procedure employed a single pass, triple‐stack column set‐up. The first column, filled with TRU resin (TrisKem International), quantitatively removed Fe and Ti from sample matrices. A second column, filled with pre‐filter resin (TrisKem International), removed organic compounds. Finally, a third column, filled with anion exchange resin (AG1‐X8, 200–400 mesh, Bio‐Rad), was used to separate Cu and Zn from the remaining matrix. Our procedure required about 50% less acid volume than previously reported methods for Cu and Zn separation, thereby minimising analytical blanks and column running times. Copper and Zn stable isotope ratios were determined by a Thermo Neptune Plus MC‐ICP‐MS using Zn and Cu external normalisation, respectively, in addition to sample‐standard bracketing to correct for instrumental mass bias. We explore the inter‐calibration of Cu and Zn isotope fractionation coefficients during analysis by measuring mixed Cu–Zn solutions with enhanced mass bias variation generated by varying sample gas flow rates. Our results demonstrate that this procedure is useful when variation in instrumental mass bias throughout analytical sequences is insufficient to inter‐calibrate Cu and Zn fractionation coefficients. 相似文献
20.
中太平洋YJA海山富钴结壳矿物组成与元素地球化学 总被引：4，自引：3，他引：1
研究样品采自马尔库斯（MARCUS）海脊YJA海山。利用等离子光谱、等离子质谱、X-射线衍射、红外光谱、场发射电镜等分析测试方法,对富钴结壳中不同构造层的矿物组成和元素地球化学进行了研究。该结壳为一大型板状新结壳,矿石矿物是水羟锰矿,脉石矿物是石英、斜长石、磷灰石等,微量矿物有蒙脱石、高岭石、钠沸石、水黑云母、片沸石等。从结壳的底部构造层到顶部构造层,TMn,Ni,Cu, Ba,Zn等元素的质量分数逐渐减少,TFe逐渐增加,Co变化不大;在相对疏松的构造层中,Si,Al,K,Na,Ca,Mg,Ti,P,Li,Rb等元素相对富集;结壳的稀土元素总量是1 982.27×10-6,Ce具明显的正异常。不同构造层稀土元素的演化趋势是：Ce与Mn等元素相同,其他稀土元素（Y除外）与Fe等相似。 相似文献