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1.
Two petrographic settings of carbonaceous components, mainly filling open fractures and occasionally enclosed in shock‐melt veins, were found in the recently fallen Tissint Martian meteorite. The presence in shock‐melt veins and the deuterium enrichments (δD up to +1183‰) of these components clearly indicate a pristine Martian origin. The carbonaceous components are kerogen‐like, based on micro‐Raman spectra and multielemental ratios, and were probably deposited from fluids in shock‐induced fractures in the parent rock of Tissint. After precipitation of the organic matter, the rock experienced another severe shock event, producing the melt veins that encapsulated a part of the organic matter. The C isotopic compositions of the organic matter (δ13C = ?12.8 to ?33.1‰) are significantly lighter than Martian atmospheric CO2 and carbonate, providing a tantalizing hint for a possible biotic process. Alternatively, the organic matter could be derived from carbonaceous chondrites, as insoluble organic matter from the latter has similar chemical and isotopic compositions. The presence of organic‐rich fluids that infiltrated rocks near the surface of Mars has significant implications for the study of Martian paleoenvironment and perhaps to search for possible ancient biological activities on Mars.  相似文献   

2.
Abstract— Reflectance spectra of splits 92 and 271 from the Martian meteorite Allan Hills (ALH) 84001 are presented and analyzed in this paper. Although the visible and infrared spectra of both chips show that the dominant mineralogy is low-Ca pyroxene, the focus here is on identification of the minor constituents. Infrared spectra measured at multiple spots along the surface of chips 92 and 271 show subtle spectroscopic variations due to changes in the low-Ca pyroxene texture and composition and to the presence of secondary minerals. Absorption bands observed near 0.93 and 1.95 μm are characteristic of low-Ca pyroxene. Strong mid-infrared reststrahlen bands are observed near 9 and 19.5 μm in all surface spectra, and additional bands near 7, 10.5, 11.4, 17.8, 20.5 and 23 μm are variable depending on the low-Ca pyroxene texture and the presence of secondary minerals. Selected spectra exhibit carbonate features near 4, 6.4–7.1 and 11.3 μm. Detailed analysis of these carbonate features indicates the presence of Mg-Fe carbonate, which is consistent with petrographic studies. Many of these spectra with strong carbonate features exhibit a magnetite feature near 17.9 μm and a shoulder near 20.5 μm that cannot be uniquely ascribed to one mineral. Spectroscopic identification of the minor carbonate and magnetite minerals in this probable piece of Mars indicates that detection of small amounts of these minerals of possible biological significance will be possible using infrared hyperspectral analyses of the Martian surface. Also of importance for remote sensing on Mars is the result that Mg, Fe and Mg-Fe carbonates in a low-Ca pyroxene matrix should be distinguishable from one another in the spectral region measured by the thermal emmitance spectrometer (TES).  相似文献   

3.
Abstract— The origin of hematite detected in Martian surface materials is commonly attributed to weathering processes or aqueous precipitation. Here, we present a new hematite formation mechanism that requires neither water nor weathering. Glass‐rich basalts with Martian meteorite‐like chemistry (high FeO, low Al2O3) oxidized at high (700 and 900 °C) temperatures in air and CO2, respectively, form thin (<1 μm) hematite coatings on their outermost surfaces. Hematite is manifested macroscopically by development of magnetism and a gray, metallic sheen on the glass surface and microscopically by Fe enrichment at the glass surface observed in element maps. Visible and near‐infrared, thermal infrared, and Raman spectroscopy confirm that the Fe enrichment at the oxidized glass surfaces corresponds to hematite mineralization. Hematite formation on basaltic glass is enabled by a mechanism that induces migration of Fe2+ to the surface of an oxidizing glass and subsequent oxidation to form hematite. A natural example of the hematite formation mechanism is provided by a Hawaiian basalt hosting a gray, metallic sheen that corresponds to a thin hematite coating. Hematite coating development on the Hawaiian basalt demonstrates that Martian meteorite‐like FeO contents are not required for hematite coating formation on basalt glass and that such coatings form during initial extrusion of the glassy basalt flows. If gray hematite originating as coatings on glassy basalt flows is an important source of Martian hematite, which is feasible given the predominance of igneous features on Mars, then the requirement of water as an agent of hematite formation is eliminated.  相似文献   

4.
《Planetary and Space Science》1999,47(3-4):353-362
The Raman microspectra of the Nakhla SNC meteorite, which probably originates from Mars, are reported here for the first time. The specimen is shown to be heterogeneous, even at a sampling level of 2 μm, but several important mineralogical features have been identified, including clinopyroxene, olivine and plagioclase. In some sampling regions, α-quartz particles are evident and in one sample region the ν(CO2−3) mode of calcite at 1086 cm−1 is found. There is no evidence for organic chemical content detectable in this meteorite specimen, based on an absence of ν(CH) and δ(CH2) modes near 3000 and 1400 cm−1, respectively. Comparative Raman spectroscopic analyses were made on epilithic examples of Xanthoria elegans from Crater Cirque, northern Victoria Land, Antarctica, and cryptoendoliths from East Beacon, McMurdo Dry Valleys, as positive controls for microbial organics in cold, arid habitats analogous to former Martian conditions. Finally, an assessment is made of the potential role of Raman spectroscopy for extra-terrestrial characterisation of geological specimens.  相似文献   

5.
Multiple datasets have demonstrated that the crust of Mars is fundamentally basaltic. However, spectral libraries used to interrogate thermal infrared spectra of Martian dark regions through spectral deconvolution have heretofore lacked mafic glasses despite the importance of amorphous phases (or phases with amorphous-like spectral signatures) in Martian mineralogy. To establish the presence and importance of basaltic-to-intermediate glasses in Martian lithologies, we created five such glasses, obtained their thermal infrared spectra and included the spectra in a library used to deconvolve nine regional Thermal Emission Spectrometer spectra from Mars. We employed the nonnegative least squares (NNLS) deconvolution method, which yields deconvolved phase abundances and the uncertainties associated with those abundances. The basaltic-to-intermediate glasses do not appear in the deconvolution solutions, indicating they are not globally or regionally important phases. Because Martian igneous or impact processes are capable of basaltic-to-intermediate glass formation, the lack of such glasses in the deconvolved mineralogies suggests either the glasses did not form in detectable quantities or they (or their signatures) have been removed. The masking or replacement of basaltic-to-intermediate glasses through alteration is supported by the appearance in the deconvolution solutions of amorphous phases (e.g., silica-rich glasses, opal) or phases with amorphous-like spectral signatures (e.g., clays, zeolites) that commonly form through aqueous alteration of mafic glasses. The glasses may still be important to local-scale thermal infrared studies given the basaltic nature of Mars and the variety of local-scale lithologies detected by various missions. The regional mineralogies derived from the NNLS deconvolution analysis divide into five statistically separable groups, which provide insight into regional trends in mineralogy.  相似文献   

6.
Abstract— A database of magnetic susceptibility measurements of stony achondrites (acapulcoite‐lodranite clan, winonaites, ureilites, angrites, aubrites, brachinites, howardite‐eucrite‐diogenite (HED) clan, and Martian meteorites, except lunar meteorites) is presented and compared to our previous work on chondrites. This database provides an exhaustive study of the amount of iron‐nickel magnetic phases (essentially metal and more rarely pyrrhotite and titanomagnetite) in these meteorites. Except for ureilites, achondrites appear much more heterogeneous than chondrites in metal content, both at the meteorite scale and at the parent body scale. We propose a model to explain the lack of or inefficient metal segregation in a low gravity context. The relationship between grain density and magnetic susceptibility is discussed. Saturation remanence appears quite weak in most metal‐bearing achondrites (HED and aubrites) compared to Martian meteorites. Ureilites are a notable exception and can carry a strong remanence, similar to most chondrites.  相似文献   

7.
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8.
The hydrogen isotopic composition of planetary reservoirs can provide key constraints on the origin and history of water on planets. The sources of water and the hydrological evolution of Mars may be inferred from the hydrogen isotopic compositions of mineral phases in Martian meteorites, which are currently the only samples of Mars available for Earth‐based laboratory investigations. Previous studies have shown that δD values in minerals in the Martian meteorites span a large range of ?250 to +6000‰. The highest hydrogen isotope ratios likely represent a Martian atmospheric component: either interaction with a reservoir in equilibrium with the Martian atmosphere (such as crustal water), or direct incorporation of the Martian atmosphere due to shock processes. The lowest δD values may represent those of the Martian mantle, but it has also been suggested that these values may represent terrestrial contamination in Martian meteorites. Here we report the hydrogen isotopic compositions and water contents of a variety of phases (merrillites, maskelynites, olivines, and an olivine‐hosted melt inclusion) in Tissint, the latest Martian meteorite fall that was minimally exposed to the terrestrial environment. We compared traditional sample preparation techniques with anhydrous sample preparation methods, to evaluate their effects on hydrogen isotopes, and find that for severely shocked meteorites like Tissint, the traditional sample preparation techniques increase water content and alter the D/H ratios toward more terrestrial‐like values. In the anhydrously prepared Tissint sample, we see a large range of δD values, most likely resulting from a combination of processes including magmatic degassing, secondary alteration by crustal fluids, shock‐related fractionation, and implantation of Martian atmosphere. Based on these data, our best estimate of the δD value for the Martian depleted mantle is ?116 ± 94‰, which is the lowest value measured in a phase in the anhydrously prepared section of Tissint. This value is similar to that of the terrestrial upper mantle, suggesting that water on Mars and Earth was derived from similar sources. The water contents of phases in Tissint are highly variable, and have been affected by secondary processes. Considering the H2O abundances reported here in the driest phases (most likely representing primary igneous compositions) and appropriate partition coefficients, we estimate the H2O content of the Tissint parent magma to be ≤0.2 wt%.  相似文献   

9.
Abstract— Zagami and Nakhla are achondrites and belong to the Shergotty-Nakhla-Chassigny (SNC) meteorite group. It is generally accepted that Mars is their parent body. Mineralogical and chemical analyses have revealed that the major mineral phases of these two meteorites are pyroxene, olivine, maskelynite, and plagioclase. In this work, near-infrared biconical reflectance measurements were performed on sawed surfaces of chips from Zagami and Nakhla. Spectra obtained with an analytical spot diameter on the order of the mineral grain size reflect the heterogeneous distribution of different mineral phases. The characteristic absorption bands of the pyroxenes are numerically evaluated in terms of the modified Gaussian model. Spectra with overlapping absorption features are resolved into the basic absorption bands. From these results, it can be estimated what kind of clinopyroxenes belong to the investigated mineral assemblages. As a result, the major clinopyroxene phase in Nakhla is Ca-rich augite, whereas in Zagami both Ca-rich and Ca-poor pyroxenes are present. By means of such a procedure, laboratory spectra of minerals become more informative and may help in discussing Martian remote sensing data in the near-infrared region.  相似文献   

10.
Abstract— The objective of this study was to identify and map possible source regions for all 5 known martian meteorite lithologies (basalt, lherzolite, clinopyroxenite, orthopyroxenite, and dunite) using data from the Mars Global Surveyor Thermal Emission Spectrometer (MGS TES). We deconvolved the TES data set using laboratory spectra of 6 martian meteorites (Los Angeles, Zagami, ALH A77005, Nakhla, ALH 84001, and Chassigny) as end members, along with atmospheric and surface spectra previously derived from TES data. Global maps (16 pixels/degree) of the distribution of each meteorite end member show that meteorite‐like compositions are not present at or above TES detectability limits over most of the planet's dust‐free regions. However, we have confidently identified local‐scale (100s‐1000s km2) concentrations of olivine‐ and orthopyroxene‐bearing materials similar to ALH A77005, Chassigny, and ALH 84001 in Nili Fossae, in and near Ganges Chasma, in the Argyre and Hellas basin rims, and in Eos Chasma. Nakhla‐like materials are identified near the detection limit throughout the eastern Valles Marineris region and portions of Syrtis Major. Basaltic shergottites were not detected in any spatially coherent areas at the scale of this study. Martian meteorite‐like lithologies represent only a minor portion of the dust‐free surface and, thus, are not representative of the bulk composition of the ancient crust. Meteorite‐like spectral signatures identified above TES detectability limits in more spatially restricted areas (<tens of km) are targets of ongoing analysis.  相似文献   

11.
Mössbauer spectra of equilibrated ordinary chondrites consist of two doublets due to paramagnetic iron present in olivines and pyroxenes and two sextets due to magnetically ordered iron present in metallic phases and troilite. The spectral areas of the different mineralogical phases found by Mössbauer spectroscopy in meteorites are proportional to the number of iron atoms in this mineralogical phase. This property of Mössbauer spectra can be the basis for constructing a method for the classification of ordinary chondrites. This idea was first explored at the Mössbauer Laboratory in Kanpur. This group suggested a qualitative method based on 2‐dimensional plots of Mössbauer spectral areas and thus classified properly some meteorites. We constructed a quantitative method using Mössbauer spectral areas, multidimensional discriminant analysis, and Mahalanobis distance (4M method) to determine the probability of a meteorite to be of type H, L, or LL. Based on 59 Mössbauer spectra, we calculated by the 4M method, S cluster , the level of similarity of the Goronyo meteorite to the clusters. On the plot of ferrosilite versus fayalite, the point representing Goronyo is located on the border between H and L areas. Calculated by the 4M method, the meteorite Goronyo is 32% similar to type H, 75% to type L, and 11% to type LL. Additional mineralogical analyses suggested that the Goronyo meteorite would be classified as type L, although it was originally reported as type H in the Meteoritical Bulletin Database.  相似文献   

12.
The isotopic composition of the noble gases of the new Martian meteorite, the Dhofar 019 shergottite, found in the desert in the territory of the Sultanate of Oman on January 24, 2001, was investigated. Stepwise thermal annealing with isotopic analysis of each of the noble-gas temperature fractions was employed to determine the component composition. The concentration of the trapped noble gases in the new Martian meteorite Dhofar 019 is relatively high, although it lies within the range of concentrations in known SNC meteorites. A characteristic feature of all the trapped noble gases is the presence of two main components: a low-temperature, probably terrestrial atmospheric, component, trapped during the weathering of the meteorite on Earth, and a high-temperature trapped Martian component. Owing to the different ratios of the quantities of the two components, the trapped neon, argon, krypton, and xenon differ markedly in the kinetics of their release. The isotopic composition of the noble gases varies accordingly. The trapped xenon was found to contain two Martian components. One of them, with typical ratios of 129Xe/132Xe and 132Xe/84Kr, is representative of xenon and krypton of the Martian atmosphere; the other, of gases of the Martian mantle. Variations of the isotopic compositions of helium, neon, and argon (and also, to a lesser extent, of krypton and xenon) during the thermal annealing of the Dhofar 019 meteorite clearly point to a large proportion of cosmogenic as well as trapped components. The concentration of cosmogenic neon and argon in the meteorite is unusually high. This corresponds to a maximum exposure age among other SNC meteorites: 20 million years. Estimates of the potassium–argon age (gas-retention age) yielded the figure of 560 million years, which is within the range of values obtained for SNC meteorites by other authors, who used the rubidium–strontium and the potassium–argon technique.  相似文献   

13.
Abstract— The Martian meteorite Yamato (Y‐) 980459 is an olivine‐phyric shergottite. It has a very primitive character and may be a primary melt of the Martian mantle. We have conducted crystallization experiments on a synthetic Y‐980459 composition at Martian upper mantle conditions in order to test the primary mantle melt hypothesis. Results of these experiments indicate that the cores of the olivine megacrysts in Y‐980459 are in equilibrium with a melt of bulk rock composition, suggesting that these megacrysts are in fact phenocrysts that grew from a magma of the bulk rock composition. Multiple saturation of the melt with olivine and a low‐calcium pyroxene occurs at approximately 12 ± 0.5 kbar and 1540 ± 10°C, suggesting that the meteorite represents a primary melt that separated from its mantle source at a depth of ?100 km. Several lines of evidence suggest that the Y‐980459 source underwent extensive melting prior to and/or during the magmatic event that produced the Y‐980459 parent magma. When factored into convective models of the Martian interior, the high temperature indicated for the upper Martian mantle and possibly high melt fraction for the Y‐980459 magmatic event suggests a significantly higher temperature at the core‐mantle boundary than previously estimated.  相似文献   

14.
Abstract— Previous Raman investigations on experimentally shocked ingle‐crystal olivine indicated that the olivine Raman bands seemingly shift to a higher wave number with increasing shock pressure. If this effect could be confirmed, Raman analysis of natural shock‐metamorphosed minerals could potentially provide an important shock barometric tool. We carried out a Raman spectroscopic study on olivine in a series of natural dunite samples experimentally shocked to pressures between 5 and 59 GPa. In addition, we analyzed olivine grains in a sample of the Cold Bokkeveld C1 meteorite. We studied samples of several dunites with olivine of 90.64–92.00 mole% Fo to determine Raman effects in the region from 200 to 900 cm?1. Several olivine grains per sample/shock pressure stage were analyzed. Raman analysis, however, showed little or no shift with increasing shock pressure. The shifts to higher or lower frequencies observed were not specific for a given pressure stage, with some grains within a sample showing more shift than others. This finding is unrelated to the crystallographic orientation of analyzed grains and cannot be related systematically to the different degrees of optically determined shock metamorphism of the analyzed grains. We identified an increase in full width at half maximum (FWHM) for the 824 cm?1 band with increased shock pressure in the shocked Åheim samples above 45 GPa and, to a lesser extent, for the 856 cm?1 band. Evaluation of band broadening of olivine in the Cold Bokkeveld meteorite showed FWHM values that were much greater (9–20 cm?1) than those of olivine in the shocked dunite samples (7–12 cm?1). We concluded that these differences in FWHM are due to differences in chemical composition between the meteoritic and the experimentally shocked olivine. Therefore, using Raman spectroscopy to detect small shifts in wave numbers to higher frequencies with increased shock pressure does not yield consistent effects for polycrystalline dunite. An extra band at 650 cm?1 was identified in the Raman spectra of the unshocked Mooihoek dunite and the Åheim dunite samples shocked to 5, 29.3, and 59 GPa, as well as another at 696 cm?1 in all the spectra of the 59 GPa Åheim sample. The cause of these extra bands is not known. Comparison of these results with Raman spectra of olivine from the Cold Bokkeveld C1 meteorite did not allow us to determine shock pressures for the meteoritic olivine.  相似文献   

15.
The Martian meteorites comprise mantle‐derived mafic to ultramafic rocks that formed in shallow intrusions and/or lava flows. This study reports the first in situ platinum‐group element data on chromite and ulvöspinel from a series of dunitic chassignites and olivine‐phyric shergottites, determined using laser‐ablation ICP‐MS. As recent studies have shown that Ru has strongly contrasting affinities for coexisting sulfide and spinel phases, the precise in situ analysis of this element in spinel can provide important insights into the sulfide saturation history of Martian mantle‐derived melts. The new data reveal distinctive differences between the two meteorite groups. Chromite from the chassignites Northwest Africa 2737 (NWA 2737) and Chassigny contained detectable concentrations of Ru (up to ~160 ppb Ru) in solid solution, whereas chromite and ulvöspinel from the olivine‐phyric shergottites Yamato‐980459 (Y‐980459), Tissint, and Dhofar 019 displayed Ru concentrations consistently below detection limit (<42 ppb). The relatively elevated Ru signatures of chromite from the chassignites suggest a Ru‐rich (~1–4 ppb) parental melt for this meteorite group, which presumably did not experience segregation of immiscible sulfide liquids over the interval of mantle melting, melt ascent, and chromite crystallization. The relatively Ru‐depleted signature of chromite and ulvöspinel from the olivine‐phyric shergottites may be the consequence of relatively lower Ru contents (<1 ppb) in the parental melts, and/or the presence of sulfides during the crystallization of the spinel phases. The results of this study illustrate the significance of platinum‐group element in situ analysis on spinel phases to decipher the sulfide saturation history of magmatic systems.  相似文献   

16.
The Carancas meteorite fell on 15 September 2007 approximately 10 km south of Desaguadero, near Lake Titicaca, Peru, producing bright lights, clouds of dust in the sky and intense detonations. The Carancas meteorite is classified as a H4–5 ordinary chondrite with shock stage S3 and a degree of weathering W0. The Carancas meteorite is characterized by well defined chondrules composed either of olivine or pyroxene. The Mössbauer spectra show an overlapping of paramagnetic and magnetic phases. The spectra show two quadrupole doublets associated to olivine and pyroxene; and two magnetic sextets, associated with the primary phases kamacite/taenite and Troilite (Fe2+). Metal particles were extracted from the bulk powdered samples exhibit only kamacite and small amounts of the intergrowth tetrataenite/antitaenite. X-Ray diffractogram shows the primary phases olivine, pyroxene, troilite, kamacite, diopside and albite. Iron oxides has not been detected by Mössbauer spectroscopy or XRD as can be expected for a meteorite immediately recovered after its fall.  相似文献   

17.
Abstract— We report new 39Ar‐40Ar measurements on 15 plagioclase, pyroxene, and/or whole rock samples of 8 Martian shergottites. All age spectra suggest ages older than the meteorite formation ages, as defined by Sm‐Nd and Rb‐Sr isochrons. Employing isochron plots, only Los Angeles plagioclase and possibly Northwest Africa (NWA) 3171 plagioclase give ages in agreement with their formation ages. Isochrons for all shergottite samples reveal the presence of trapped Martian 40Ar (40Arxs), which exists in variable amounts in different lattice locations. Some 40Arxs is uniformly distributed throughout the lattice, resulting in a positive isochron intercept, and other 40Arxs occurs in association with K‐bearing minerals and increases the isochron slope. These samples demonstrate situations where linear Ar isochrons give false ages that are too old. After subtracting 40Ar*that would accumulate by 40K decay since meteorite formation and small amounts of terrestrial 40Ar, all young age samples give similar 40Arxs concentrations of ?1–2 × 10?6cm3/g, but a variation in K content by a factor of ?80. Previously reported NASA Johnson Space Center data for Zagami, Shergotty, Yamato (Y‐) 000097, Y‐793605, and Queen Alexandra Range (QUE) 94201 shergottites show similar concentrations of 40Arxs to the new meteorite data reported here. Similar 40Arxs in different minerals and meteorites cannot be explained as arising from Martian atmosphere carried in strongly shocked phases such as melt veins. We invoke the explanation given by Bogard and Park (2008) for Zagami, that this 40Arxs in shergottites was acquired from the magma. Similarity in 40Arxs among shergottites may reveal common magma sources and/or similar magma generation and emplacement processes.  相似文献   

18.
This study advances curve-fitting modeling of absorption bands of reflectance spectra and applies this new model to spectra of Martian meteorites ALH 84001 and EETA 79001 and data from the Compact Reconnaissance Imaging Spectrometer for Mars (CRISM). This study also details a recently introduced automated parameter initialization technique. We assess the performance of this automated procedure by comparing it to the currently available initialization method and perform a sensitivity analysis of the fit results to variation in initial guesses. We explore the issues related to the removal of the continuum, offer guidelines for continuum removal when modeling the absorptions and explore different continuum-removal techniques. We further evaluate the suitability of curve fitting techniques using Gaussians/Modified Gaussians to decompose spectra into individual end-member bands. We show that nonlinear least squares techniques such as the Levenberg–Marquardt algorithm achieve comparable results to the MGM model (Sunshine and Pieters, 1993, Sunshine et al., 1990) for meteorite spectra. Finally we use Gaussian modeling to fit CRISM spectra of pyroxene and olivine-rich terrains on Mars. Analysis of CRISM spectra of two regions show that the pyroxene-dominated rock spectra measured at Juventae Chasma were modeled well with low Ca pyroxene, while the pyroxene-rich spectra acquired at Libya Montes required both low-Ca and high-Ca pyroxene for a good fit.  相似文献   

19.
Abstract— Understanding the origin of carbonate minerals in the Martian meteorite Allan Hills (ALH) 84001 is crucial to evaluating the hypothesis that they contain traces of ancient Martian life. Using arguments based on chemical equilibria among carbonates and fluids, an origin at >650 °C (inimical to life) has been proposed. However, the bulk and stable isotopic compositions of the carbonate minerals are open to multiple interpretations and so lend no particular support to a high-temperature origin. Other methods (possibly less direct) will have to be used to determine the formation temperature of the carbonates in ALH 84001.  相似文献   

20.
Several olivine‐phyric shergottites contain enough olivine that they could conceivably represent the products of closed‐system crystallization of primary melts derived from partial melting of the Martian mantle. Larkman Nunatak (LAR) 06319 has been suggested to represent a close approach to a Martian primary liquid composition based on approximate equilibrium between its olivine and groundmass. To better understand the olivine–melt relationship and the evolution of this meteorite, we report the results of new petrographic and chemical analyses. We find that olivine megacryst cores are generally not in equilibrium with the groundmass, but rather have been homogenized by diffusion to Mg# 72. We have identified two unique grain types: an olivine glomerocryst and an olivine grain preserving a primary magmatic boundary that constrains the time scale of eruption to be on the order of hours. We also report the presence of trace oxide phases and phosphate compositions that suggest that the melt contained approximately 1.1% H2O and lost volatiles during cooling, also associated with an increase in oxygen fugacity upon degassing. We additionally report in situ rare earth element measurements of the various mineral phases in LAR 06319. Based on these reported trace element abundances, we estimate the oxygen fugacity in the LAR 06319 parent melt early in its crystallization sequence (i.e., at the time of crystallization of the low‐Ca and high‐Ca pyroxenes), the rare earth element composition of the parent melt, and those of melts in equilibrium with later formed phases. We suggest that LAR 06319 represents the product of closed‐system crystallization within a shallow magma chamber, with additional olivine accumulated from a cumulate pile. We infer that the olivine megacrysts are antecrysts, derived from a single magma chamber, but not directly related to the host magma, and suggest that mixing of antecrysts within magma chambers may be a common process in Martian magmatic systems.  相似文献   

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