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1.
岩石脆延性转化 (brittle ductiletransition)和脆塑性转化 (brittle plastictransition)是不同的概念。脆延性转化指从岩石的局部变形破坏到宏观均匀流动变形的转化 ,它与宏观结构和力学行为的变化相关。脆塑性转化指脆性向晶体塑性变形的转化 ,它与力学行为和微观机制的变化相关。通过地壳中最主要的石英、长石的实验室和野外变形温压条件对比发现 ,达到相同的变形特征 ,在实验室和野外所需温压条件不同。建立变形机制图使解决这一矛盾成为可能。但受实验资料的限制 ,目前几种主要岩石的变形机制图还无法建立。因此 ,通过对实验与自然环境下变形特征及微观机制对比 ,找出两者温压条件的差别 ,就成为将实验研究结果外推解决实际地质问题的有效途径 相似文献
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3.
DEFORMATION OF THE BRITTLE-PLASTIC TRANSITION ZONE AT THE POST-SEISMIC RELAXATION PERIOD: A CASE STUDY OF THE RED RIVER FAULT 
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下载免费PDF全文 The transition from microscopic brittle deformation to microscopic plastic deformation is called brittle-plastic transition, which is considered as a key layer for determining the limit of lower continental crust seismicity. The depth and deformation mechanism of the brittle-plastic transition zone is controlled mainly by temperature. Besides, the strain rate and fluid pore pressure also affect the transition during the different deformation stages at the seismic cycle.
In this paper, microstructure observation of catalcastic samples collected from the Red River Fault was carried out using optical polarized microscopy and scanning electron microscopy. The morphology, microstructures of deformation characteristics, mineral composition, water-rock reaction, pressure solution, exsolution, crack healing in the samples were systematically observed. The mineral components quantitative analyses were examined using the EDS. Water-rock reaction and pressure solution were systematically observed under SEM. The fabric of the main minerals in the samples was measured using electron backscattered diffraction(EBSD). Based on these analyses, the deformation mode was setup for the brittle-plastic transition zone of the fault during the post-seismic relaxation period.
Both brittle deformation and plastic deformation were developed in the cataclastic samples. EBSD data shows that the c axial fabrics of quartz present low-temperature plastic deformation characteristics. The feldspar deformed as cataclastic rock, and the micro-fracture in feldspar was healed by static recrystallized quartz and calcite veins. The calcite vein underwent plastic deformation, which represents the post-seismic relaxation deformation.
Based on the analysis of deformation mechanism of cataclastic samples in brittle-plastic transition zone of the Red River Fault, and combined with previous studies, we concluded that the brittle fracture and fracture healing is the main deformation mode at brittle-plastic transition zone in the post-seismic relaxation. High stress and high strain rate at post-seismic relaxation lead to brittle fracture of high-strength minerals such as feldspar in rocks. Plastic deformation occurs in low-strength minerals such as quartz and mica. Under the fluid condition, micro-fractures were healed by quartz and calcite. The minerals such as quartz and calcite in the fracture transformed from static recrystallization to dynamic recrystallization with stress gradually accumulating. With fracture healing and stress accumulation, the fault strength gradually increases which could accumulate energy for the next earthquake. 相似文献
4.
We present a formulation for mechanical modeling of the interaction between fracture and fluid flow. Our model combines the
classic Biot poroelastic theory and a damage rheology model. The model provides an internally consistent framework for simulating
coupled evolution of fractures and fluid flow together with gradual transition from brittle fracture to cataclastic flow in
high-porosity rocks. The theoretical analysis, based on thermodynamic principles, leads to a system of coupled kinetic equations
for the evolution of damage and porosity. A significant advantage of the model is the ability to reproduce the entire yield
curve, including positive and negative slopes, in high-porosity rocks by a unified formulation. A transition from positive
to negative values in the yield curve, referred to as a yield cap, is determined by the competition between the two thermodynamic
forces associated with damage and porosity evolution. Numerical simulations of triaxial compression tests reproduce the gradual
transition from localized brittle failure to distributed cataclastic flow with increasing pressure in high-porosity rocks
and fit well experimentally measured yield stress for Berea sandstone samples. We modified a widely used permeability porosity
relation by accounting for the effect of damage intensity on the connectivity. The new damage-permeability relation, together
with the coupled kinetics of damage and porosity evolution, reproduces a wide range of realistic features of rock behavior.
We constrain the model variables by comparisons of the theoretical predictions with laboratory results reporting porosity
and permeability variation in rock samples during isotropic and anisotropic loading. The new damage-porosity-permeability
relation enables simulation of coupled evolution of fractures and fluid flow and provides a possible explanation for permeability
measurements in high-porosity rocks, referred to as the “apparent permeability paradox.”
The text was submitted by the authors in English. 相似文献
5.
The Rauðafell composite complex is part of the Neogene Breiðdalur volcano, eastern Iceland and is composed of a composite feeder dyke, a vent structure and a composite flow. The two end-members of the composite complex are rhyolite and basalt, and both are rich in plagioclase macrocrysts: bytownite in basalt and oligoclase in rhyolite. The rhyolite also includes ferroaugite macrocrysts. The mixed rocks are separated in three textural groups related to mixing proportions. When the basaltic end-member is dominant, a hybrid texture with a homogeneous matrix is observed and the only evidence of mixing is the presence of antecrysts of both end-members. When the basaltic end-member represents c. 65 to 30 % of the mixture, we observe emulsion textures composed of finely co-mingled basalt and rhyolite. The difference between these two textural expressions of mixing is due to effects of diffusion. The third texture shows mafic enclaves suspended in a rhyolitic matrix. In these rocks, the proportion of the basaltic end-member is inferior to 30 %, implying that the basalt froze solid in contact with the rhyolite. Zoning of plagioclase shows that the mixing processes are driven initially by highly efficient micro-mingling; the emulsification is possibly a result of compositional gradient stresses (Korteweg stress) between miscible basalt and rhyolite. This is followed by chemical diffusion (hybridisation) and tend to protect antecrysts from reaction with the primitive magmas. When antecrysts originated in the evolved magma, they undergo dissolution due to thermal disequilibrium during mingling and chemical disequilibrium during hybridisation. We argue that such mixing processes are important in producing intermediate rocks in Iceland and elsewhere that shows only the chemical attributes of an origin by mixing. The preservation of emulsion textures is rare and highly dependent on cooling history. 相似文献
6.
Acoustic Emissions Monitoring during Inelastic Deformation of Porous Sandstone: Comparison of Three Modes of Deformation 总被引：4，自引：0，他引：4
Jerome Fortin Sergei Stanchits Georg Dresen Yves Gueguen 《Pure and Applied Geophysics》2009,166(5-7):823-841
In some reservoirs, large deformations can occur during oil or gas production because of the effective stress change. For very porous rocks, these production operations can be sufficient to cause inelastic deformation and irreversible damage. Rock formations can undergo deformation by different mechanisms, including dilatancy or pore collapse. In the laboratory, it has been shown that the inelastic deformation and failure mode of porous rocks are pressure sensitive. Indeed, when subjected to an overall compressive loading, a porous rock may fail by shear localization, compaction localization, or by cataclastic compaction. Acoustic emission (AE) records provide important information to understand the failure mode of rocks: the spatial evolution of damage as well as the source mechanisms can be followed using this technique. In this paper, we present three different laboratory axisymmetric compression experiments, performed on Bleurswiller sandstone, which enable us to compare the acoustic emission signature of these three modes of deformation. Our data show that compaction localization and cataclastic compaction are characterized by similar acoustic signatures (in terms of AE sources characteristics and evolution of AE number), in comparison to the acoustic signature from shear localization. This implies similar micromechanisms involved during compaction bands formation and cataclastic compaction. 相似文献
7.
Hidemi Tanaka Shin-Ichiro Hinoki Kazuo Kosaka Aiming Lin Keiji Takemura Akihiro Murata Takao Miyata 《Island Arc》2001,10(3-4):381-391
Abstract This paper describes the results of petrographical and meso- to microstructural observations of brittle fault rocks in cores obtained by drilling through the Nojima Fault at a drilling depth of 389.52 m. The zonation of deformation and alteration in the central zone of the fault is clearly seen in cores of granite from the hanging wall, in the following order: (i) host rock, which is characterized by some intragranular microcracks and in situ alteration of mafic minerals and feldspars; (ii) weakly deformed and altered rocks, which are characterized by transgranular cracks and the dissolution of mafic minerals, and by the precipitation of zeolites and iron hydroxide materials; (iii) random fabric fault breccia, which is characterized by fragmentation, by anastomosing networks of transgranular cracks, and by the precipitation of zeolites and iron hydroxide materials; and (iv) fault gouge, which is characterized by the precipitation of smectite and localized cataclastic flow. This zonation implies that the fault has been weakened gradually by fluid-related fracturing over time. In the footwall, a gouge layer measuring only 15 mm thick is present just below the surface of the Nojima Fault. These observations are the basis for a model of fluid behavior along the Nojima Fault. The model invokes the percolation of meteoric fluids through cracks in the hanging wall fault zone during interseismic periods, resulting in chemical reactions in the fault gouge layer to form smectite. The low permeability clay-rich gouge layer sealed the footwall. The fault gouge was brecciated during coseismic or postseismic periods, breaking the seal and allowing fluids to readily flow into the footwall, thus causing a slight alteration. Chemical reactions between fluids and the fault breccia and gouge generated new fault gouge, which resealed the footwall, resulting in a low fluid condition in the footwall during interseismic periods. 相似文献
8.
A general constitutive equation for viscoelastic behaviour of rocks and minerals with fractional-order derivative is investigated. This constitutive law is derived based on differential geometry and thermodynamics of rheology, and the fractional order of derivative represents the degree of time delay. Analyzing some laboratory experimental data of high temperature deformation of rocks and minerals such as halite, marble and orthopyroxene, we propose how to determine the orders of fractional derivative for viscoelastic behaviours of rocks and minerals. The order is related to the exponents for the temporal scaling in the relaxation modulus and the stress power-law of strain rate, i.e., the non-Newtonian flow law, and considered as an indicator representing the macroscopic behaviour and microscopic dynamics of rocks. 相似文献
9.
Jafar Hadizadeh 《Pure and Applied Geophysics》1994,143(1-3):255-280
The mineralogical and elemental variations across the main shear zone of the Saltville thrust at Sharp Gap in Knoxville, Tennessee, U.S.A., were studied in a suite of deformed and undefromed carbonate rock samples using X-ray diffraction and electron microprobe methods. An examination of the samples for deformation effects at mesoscopic scale and under the optical microscope reveals familiar cataclastic deformation features including foliated cataclasites and microbreccias occurring in a well-defined, 1–2 m wide zone of intense deformation, plus evidence of hydrofracturing and extensive syndeformational pressure solution. There exists a clear correlation between the observed cataclastic deformation and mineral and elemental distribution which we interpret to result from a deformation-induced dolomite to calcite transformation in the shear zone. The transformation has resulted in removal of Mg from the shear zone, selective deposition of calcite as an intergranular cement in cataclasite/microbreccia units and a relative increase in the concentration of detrital quartz and feldspars.The compositional difference between the shear zone and wall rocks is explained in connection with cataclastic deformation features in terms of a model in which a dual pressure-solution/cataclastic flow mechanism leads to a gradual cementation-hardening of segments of the shear zone. Instabilities could occur via permeability reduction and increased pore pressure within these segments. Hydrofracturing of the hardened segments along with high strain rate reordering of the shear zone materials reset the ruptured zone back to the dual deformation mechanism regime. As a long-term effect, the compositional transformation of the shear zone is expected to prolong periods of creep and cause smaller coseismic stress drops since under the imposed conditions calcite is more ductile and soluble than dolomite. 相似文献
10.
T. Weiss S. Siegesmund W. Rabbel T. Bohlen M. Pohl 《Pure and Applied Geophysics》1999,156(1-2):97-122
—Seismic anisotropy is often neglected in seismic studies of the earth’s crust. Since anisotropy is a common property of many typically deep crustal rocks, its potential contribution to solving questions of the deep crust is evaluated. The anisotropic seismic velocities obtained from laboratory measurements can be verified by computations based on the elastic constants and on numerical data pertaining to the texture of rock-forming minerals. For typical lower crustal rocks the influence of layering is significantly less important than the influence of rock texture. Surprisingly, most natural lower crustal rocks show a hexagonal type of anisotropy. Maximum anisotropy is observed for rocks with a high content of aligned mica. It seems possible to distinguish between layered intrusives and metasediments on the basis of in situ measurements of anisotropy, which can thus be used to validate different scenarios of crustal evolution. 相似文献
11.
在总结岩石变形机制与岩石流变学实验进展的基础上,讨论了岩石流变学数据的重复性。虽然高温高压流变学实验积累了大量的数据,但中、上地壳长英质岩石和早期获得的石英集合体的流变实验数据重复性比较差,而近年来发表的石英、长石的流变学实验数据重复性相对较好。虽然利用经验理论模型,根据端元组分可以拟合两相矿物集合体的流变律,但并不能满足定量确定复杂组分和特殊流变性的长英质岩石流变参数的需要。因此,利用长英质岩石流变参数估计大陆地壳流变强度剖面时,即使在相同地温和应变速率条件下,给出的流变曲线、脆-塑性转化带深度也有一定差别,还需要通过大量实验给出更精细的长英质岩石流变学实验数据。根据近年来流变学实验研究的新进展,讨论了在实验室条件下影响长英质岩石流变的各种因素,重点分析了流体、岩石成分、样品粒度和组构对流变的影响。微量结构水对岩石流变有显著的弱化作用,而熔体对流变的影响与熔体含量和分布相关,只有熔体呈薄膜状湿润颗粒边界时,熔体的弱化作用才显著。成分对岩石流变的影响不仅体现在样品的应力指数等流变参数的变化方面,还体现在样品从半脆性变形向塑性变形的转化温度方面。粒度主要影响岩石的变形机制,其中,细粒样品在扩散蠕变域具有应力与粒度线性负相关特性,是理想的应力计,可以用来定量确定韧性剪切带的流变强度;而在位错蠕变域,应力与粒度没有依存关系,这为将实验室条件得出的流变数据外推估计地壳流变提供了重要依据。组构和各向异性是地壳中岩石存在的普遍现象,但关于层状组构对多相矿物组成的岩石流变影响的研究非常少,需要通过新的实验来深入研究。 相似文献
12.
在沂沭断裂带中段的泰山群结晶基底中,存在着一系列北东、北北东走向的左行韧性剪切带。对其中发育糜棱岩的韧性剪切带的结构构造、应变测量、变形岩石的显微构造、显微组构以及长石粒度和含量的变化规律进行了观测分析。讨论了韧性剪切带的变形条件和机制。及其递进发展的趋势。指出基底韧性剪切带是沂沭断裂带元古宙时期断裂活动时在地壳较深层次上形成的构造表象。在此基础上,讨论了地壳不同层次上的断裂变形及断裂岩石的综合分类问题 相似文献
13.
Koichiro Fujimoto Hidemi Tanaka Takayuki Higuchi Naoto Tomida Tomoyuki Ohtani Hisao Ito 《Island Arc》2001,10(3-4):401-410
Abstract Mineralogical and geochemical studies on the fault rocks from the Nojima–Hirabayashi borehole, south-west Japan, are performed to clarify the alteration and mass transfer in the Nojima Fault Zone at shallow depths. A complete sequence from the hornblende–biotite granodiorite protolith to the fault core can be observed without serious disorganization by surface weathering. The parts deeper than 426.2 m are in the fault zone where rocks have suffered fault-related deformation and alteration. Characteristic alteration minerals in the fault zone are smectite, zeolites (laumontite, stilbite), and carbonate minerals (calcite and siderite). It is inferred that laumontite veins formed at temperatures higher than approximately 100°C during the fault activity. A reverse component in the movement of the Nojima Fault influences the distribution of zeolites. Zeolite is the main sealing mineral in relatively deep parts, whereas carbonate is the main sealing mineral at shallower depths. Several shear zones are recognized in the fault zone. Intense alteration is localized in the gouge zones. Rock chemistry changes in a different manner between different shear zones in the fault zone. The main shear zone (MSZ), which corresponds to the core of the Nojima Fault, shows increased concentration of most elements except Si, Al, Na, and K. However, a lower shear zone (LSZ-2), which is characterized by intense alteration rather than cataclastic deformation, shows a decreased concentration of most elements including Ti and Zr. A simple volume change analysis based on Ti and Zr immobility, commonly used to examine the changes in fault rock chemistry, cannot account fully for the different behaviors of Ti and Zr among the two gouge zones. 相似文献
14.
Hans-Joachim Massonne 《Earth and Planetary Science Letters》2003,216(3):347-364
The petrography and chemical composition of minerals of quartz-rich diamondiferous rocks from the Kokchetav Massif, especially the zonation of garnet, were studied and compared with diamondiferous quartzofeldspathic rocks from the Saxonian Erzgebirge. Many compositional and textural features were found to be similar. For instance, microdiamonds are enclosed systematically in a specific intermediate growth zone of garnet in these rocks. On the basis of experimental data, a magmatic scenario was constructed to check if the quartz-rich diamondiferous rocks are of magmatic origin. By this, the P-T paths, derived here for the Kokchetav rocks, and the textural observations it is concluded that the minerals of the diamondiferous rocks have crystallized from silicate melts. These melts originated by anatexis of deeply submerged metasediments (Erzgebirge: at T as high as 1200°C, Kokchetav Massif: at 50-100°C lower T) and ascended from at least 200 km depth. Relics of the pre-anatectic evolution are still present, for instance, as garnet cores. After ascent and emplacement of the magma in deep portions of thickened continental crust (Kokchetav Massif: 45-50 km close to 800°C, Erzgebirge: 55-60 km at 30-50°C lower T) considerable quantities of (white and/or dark) micas formed by peritectic reactions from melt. For instance, garnets could be resorbed at this stage and biotite grew instead. After the magmatic stage, retrogression took place much stronger in the Kokchetav Massif. This was accompanied by deformation transforming broadly the magmatic texture of quartz-rich diamondiferous rocks from the Kokchetav Massif to a gneissic texture. 相似文献
15.
A. A. Guseinov 《Izvestiya Physics of the Solid Earth》2012,48(9-10):751-758
The electrical properties of magmatic rocks (diabase and granite porphyry) from the complex dike located in the Main Caucasian (Akhtychaisk) fault zone are examined at temperatures of 100?C1000°C. It is established that the increase in the electrical conductivity from granite porphyry to diabase is caused by the decreased quartz content, increased total content of iron oxides FeO and Fe2O3, as well as the fine-grained texture of diabases and their secondary alterations. The pattern of temperature dependence of specific electrical conductivity observed in granite porphyry and diabases reflects the polymorphic transformation of the monoclinic structure to the triclinic structure (the MT-transformation), which occurs in the feldspar component of the rock. Another factor responsible for the shape of the mentioned temperature dependence is that the formation of an extrinsic mechanism of conduction is dominated by the defects (associated into complexes) in the crystal lattices of the minerals. This allows determining the energy of formation and migration of lattice defects and the energy of association of the lattice defects into complexes, which play an important role in the natural metamorphic processes. The AC measurements for the granite porphyry revealed frequency dispersion of the electrical conductivity, which decreases with increasing temperature. 相似文献
16.
When one end of an air-dry igneous rock block was uniaxially loaded in laboratory, there appeared an electromotive force that made electric currents flow from the stressed volume to the unstressed volume. Quartz-free rocks such as gabbro also generated this force, stronger than quartz-bearing rocks such as granite. This indicates that the piezoelectric effect of quartz and the electrokinetic effect of pore water do not make a large contribution toward generating the electromotive force. We focus on peroxy bond that is one of the abundant lattice defects in igneous rock-forming minerals. When mechanical loading deforms the lattice structure around this defect and breaks its bond, its energy levels change and act like an accepter. As an electron is trapped at this defect from a neighbor O2- site, a positive hole is activated there. They attempt to diffuse toward the unstressed volume through the valence band and are simultaneously affected by the attractive electric force with the electrons trapped in peroxy bonds. This leads to a polarization in the stressed volume and the generation of electromotive force between the stressed and unstressed volumes. Similar electromotive force may be generated in the Earth's crust where inhomogeneous stress/strain is changing. 相似文献
17.
E. I. Demonterova A. V. Ivanov N. S. Karmanov 《Journal of Volcanology and Seismology》2009,3(4):260-268
Rocks having a pseudofluidal ignimbrite texture have been found on Saikhan Volcano in northeastern Khangai, Mongolia. The
rocks have a typically nodular banded texture. The fiamme and the bands vary in width between a few millimeters to a few centimeters.
These rocks have the same bulk composition as trachybasalts and do not differ from the ordinary trachybasalts found on this
volcano in the form of dikes and lavas. The difference consists in the composition of glasses and minerals, as well as in
the concentration of CO2 (which is higher in the ignimbrite-like rocks). The glasses in the ignimbrite-like rocks show a trend from basaltic trachyandesites
to tephriphonolites and foidites, thus indicating the liquidus crystallization of clinopyroxene. The glasses in the lavas
and dikes have a trachyte composition, indicating a residual origin following the crystallization of olivine and Ti-magnetite.
Much of the pyroxenes (∼20%) in the ignimbrite-like rocks show calculated pressures during their generation to have been in
the range of 6.5–14 kbars, while all pyroxenes in the ordinary lavas and dikes crystallized at pressures below 0.3 kbars.
It thus follows that the magmas that have produced the ignimbrite-like rocks began crystallizing in the subcrustal magma chamber
under fluid-saturated conditions, whence they were rapidly transported to the surface. 相似文献
18.
Thermal expansion during the first heating cycle at atmospheric pressure was measured in several directions in seven igneous rocks between 25° and 400°C at slow heating rates. The coefficient of thermal expansion measured under these conditions increases more rapidly as temperature is increased than the average thermal expansion coefficient of the constituent minerals. The “extra” expansion is attributed to the formation of cracks by differential expansion of mineral grains. The presence of such cracks in the rocks during the cooling part of the cycle and during any subsequent heating and cooling cycles will result in a substantial decrease in the coefficient of thermal expansion as compared to that measured during the first heating cycles. The effect of cracks initially present in a rock was studied by measuring the full tensor of the coefficient of thermal expansion on two rocks with anisotropic crack distributions. In these two rocks the coefficient of thermal expansion is least in the direction perpendicular to the plane of greatest crack concentration. The implication of our data is that thermal expansion depends greatly on the fracture state of the rock. Both the fractures in the rock and the boundary conditions on the rock are significant for the interpretation of thermal expansion measurements and for their application to other problems. 相似文献
19.
Recently obtained data on oxygen diffusion in feldspars, quartz, and hornblende permit the prediction of the apparent18O16O temperatures that would be measured in a rock that consisted only of those three minerals, and cooled slowly from high temperature. The computed temperatures would be based on the differences in the18O16O ratios between coexisting pairs of minerals. The present calculation takes into account the diffusion rates for oxygen as a function of temperature, the cooling rate of the rock, the mineral grain sizes, and the mode of the rock. For mineral grains 1 mm in radius, and a cooling rate of 10°C/m.y., the minimum difference in apparent temperature between quartz-feldspar and feldspar-hornblende pairs will be 115°C, despite the assumption of a normal, uneventful, slow cooling history to room temperature. Further, the apparent quartz-hornblende temperature will range over 30°C (590–620°C) depending on the mode of the rock. For a cooling rate of 1000°C/m.y., the apparent difference in temperature can be as much as 400°C. Consequently, consistency in temperatures obtained by oxygen isotope analysis should not be expected in most high-grade metamorphic rocks or igneous rocks which are cooled slowly. Departures from the pattern of temperatures obtained in this model would imply a very rapid quench from high temperature, or a complex history for the rock. For some minerals, including hornblende, the relation between temperature and the equilibrium fractionation of oxygen isotopes between coexisting phases has been derived from observed relations in natural specimens. The choice of the specimens used for such calibrations needs to be re-evaluated in light of these findings. This may result in a change in the equilibrium equation constants.An example from the literature, the San Jose tonalite, Baja California, Mexico, was modelled and yieldsδ18O concentrations in the minerals that correspond closely with the measured values. This suggests that the model used is appropriate, that the rock has had a simple thermal history, and that it cooled at 100–200°C/m.y. over the temperature range 800–500°C. The set of paleotemperatures obtained for a rock will, in general, yield neither the mineral closure temperatures nor the formation or crystallization temperatures. On the other hand, the cooling rate of the rock may be derived from the data. This, in turn, may have important tectonic implications with regard to denudation and uplift rates. 相似文献
20.
Thermodynamic conditions (first of all, temperature) are the main dynamic factors in the transformation process of ferrous
to ferric iron (TFFI). TFFI usually takes place within a temperature range of 473–843 K (most active at temperatures above
673 K) and does not require presence of the oxidizing agents above 673 K. Analysis of the chemical composition of different
rocks and minerals indicates that only for some sedimentary rocks is the relative content of ferrous iron oxide less than
its value in magnetite, and this value is minimal for oceanic sediments. The relative content of ferrous iron oxide in oceanic
magmatic rocks exceeds this value in continental magmatic rocks and depends on the rate of rock cooling. An investigation
of the role of the titanium oxide content of different rocks on stability of ferrous iron oxide against its transformation
to ferric iron oxide shows that a significant correlation (r = 0.79) does exist between the relative content of ferrous iron oxide and ratio of TiO2/Fe2O3. Temperature within the solar nebula at location of the Earth was within the temperature range of the TFFI. During the Earth
accretion and its early evolution, ferric iron oxide was unstable and most likely did not exist. The first magnetic minerals
containing ferric iron could have appeared only after the Earth’s surface had cooled below ∼843 K. The formation of the first
Algoma-type banded iron formations could be used as a marker of the Earth’s surface cooling below ∼843 K. 相似文献