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1.
报道了山东昌乐地区新生代王家大山玄武岩的全岩主元素、微量元素,橄榄石斑晶及被其捕获的熔体包裹体主元素和铅同位素组成。王家大山玄武岩为弱碱性-拉斑玄武岩。全岩主元素成分和熔体包裹体的SiO_2、TiO_2、Al_2O_3、CaO、Na_2O、K_2O和P_2O_5含量均与MgO含量呈负相关关系,CaO/Al_2O_3值基本不变;在微量元素原始地幔标准化蛛网图上与EMI洋岛玄武岩(OIB)相似,表现为明显的Ba、K和Sr正异常,Th和Pb负异常,无Nb-Ta和Ti异常。熔体包裹体铅同位素组成为208Pb/206Pb=2.091~2.166和207Pb/206Pb=0.846~0.899,其变化范围覆盖了山东地区新生代强碱性玄武岩到弱碱性-拉斑玄武岩的铅同位素范围;根据铅同位素组成,熔体包裹体可以分为低铅同位素组(207Pb/206Pb0.86)和高Pb同位素组(207Pb/206Pb0.87)。橄榄石斑晶Ni、Fe/Mn和Ca分别为1312~2417μg/g、71~92和745~2068μg/g,与典型辉石岩熔体结晶的橄榄石斑晶成分相当,但是,比橄榄岩熔体结晶的橄榄石成分高Ni和Fe/Mn,低Ca。全岩和熔体包裹体主元素的成分变化,结合岩相学和MELTS软件模拟结果,指示王家大山玄武岩主要经历了橄榄石结晶分离作用。橄榄石斑晶高Ni和Fe/Mn,低Ca,结合全岩高Fe/MnO值和低CaO,说明其源区岩石为辉石岩。全岩微量元素和熔体包裹体铅同位素指示源区有EMI组分,可能和再循环洋壳辉长岩有关。熔体包裹体两组铅同位素组成指示王家大山玄武岩源区是不均一的,暗示山东地区新生代玄武岩的源区是高度不均一的。  相似文献   

2.
山东地区新生代玄武岩主要分布在郯庐断裂带及其以东地区,在鲁西地区分布较少。本文报道了鲁西地区周村玄武岩的全岩主、微量元素组成、橄榄石斑晶及其熔体包裹体Pb同位素组成。结果表明,周村玄武岩为弱碱性玄武岩,其主量元素具有较高SiO_2和Al_2O_3,较低碱(Na_2O+K_2O)、CaO/Al_2O_3、Fe_2O_3~T(Fe_2O_3~T=Fe O/0.8998+Fe_2O_3)的特征;微量元素在原始地幔标准化蛛网图上与EMI洋岛玄武岩(OIB)相似,表现为明显的Ba、K和Sr正异常,Th和Pb负异常,无Nb、Ta和Ti异常;熔体包裹体~(207)Pb/~(206)Pb和~(208)Pb/~(206)Pb分别为0.894~0.921和2.166~2.213,略高于EMI-OIB。这些特征和鲁西地区无棣大山玄武岩有明显区别,但与山东其它地区的弱碱性-拉斑玄武岩相似。周村玄武岩的橄榄石斑晶Ni、Fe/Mn和Ca分别为1403~2611μg/g,70~93和824~2003μg/g。与橄榄岩熔体结晶的橄榄石成分相比,给定橄榄石Fo值,周村玄武岩橄榄石斑晶具有高Ni和Fe/Mn比值,低Ca的特征。结合全岩低CaO和高FeO/MnO比值,橄榄石成分指示周村玄武岩的源区岩性为辉石岩,其形成需要高比例的来自再循环地壳的英安质熔体交代地幔橄榄岩。高比例的英安质熔体和周村玄武岩的微量元素特征,进一步说明该再循环地壳为含辉长岩洋壳。本文的研究结果暗示山东地区弱碱性-拉斑玄武岩的源区辉石岩,主要与再循环洋壳有关。  相似文献   

3.
作为华北克拉通破坏的响应,华北地区广泛发育新生代玄武岩。尽管前人对这些玄武岩做了大量的研究,但是对其地幔源区性质及成因机制仍存在激烈争论。本文首次报道山东山旺新生代玄武岩中橄榄石斑晶捕获的熔体包裹体的研究结果。相对于全岩成分,熔体包裹体的成分更加复杂,碱性玄武岩中熔体包裹体不仅有碱性玄武质,碱性粗面玄武质成分,同时还有拉斑玄武质成分。这指示新生代玄武岩的形成主要是受控于贫硅与富硅熔体的混合。碱性玄武岩中的熔体包裹体中存在拉斑玄武质熔体意味着在山东地区新生代玄武岩中首次发现拉斑玄武质组分,暗示新生代玄武岩地幔源区比之前认识的更加复杂和不均一,碱性玄武岩地幔源区同样存在富硅组分。综合华北、东北新生代玄武岩数据,可以把这些玄武岩划分为三类:低硅,高硅以及中间类型。低硅玄武岩具有高的~(176)Hf/~(177)Hf,~(143)Nd/~(144)Nd,~(206)Pb/~(204)Pb,FeO,Na_2O+K_2O和Sm/Yb,低的SiO2_和Ba/Th比值;高硅玄武岩具有低的~(176)Hf/~(177)Hf,~(143)Nd/~(144)Nd,~(206)Pb/~(204)Pb,FeO,Na_2O+K_2O和Sm/Yb,高SiO_2和Ba/Th比值,(Th/La)_N1和(Th/Ba)_N1。结合实验岩石学数据推断低硅玄武岩形成于贫硅辉石岩和富含角闪石的岩石的部分熔融,这些辉石岩和富含角闪石的岩石形成于近期的岩石圈地幔交代事件;高硅玄武岩的地幔源区含有富硅的古老大洋下地壳组分,结合实验岩石学数据推断高硅玄武岩形成于富硅辉石岩和橄榄岩的部分熔融。  相似文献   

4.
玄武岩斑晶中熔体包裹体成分特征可以推断玄武岩源区物质组成,反映岩浆形成演化过程。利用LA—ICPMS对四合屯义县组玄武岩橄榄石、单斜辉石斑晶中单个熔体包裹体的元素组成进行了分析测试。研究结果表明,橄榄石、单斜辉石斑晶中的熔体包裹体在主、微量元素含量上表现出了比全岩更大的变化范围,但微量元素分配特征总体和全岩一致。单斜辉石斑晶中包裹体的CaO含量、CaO/Al2O3比值和Cr2O3含量随着单斜辉石Mg#值的降低而降低,反映了单斜辉石结晶分离的影响,Al2O3与Sr之间的显著相关关系则记录了斜长石结晶分离作用的影响,MgO—Ni和MgO—CaO/Al2O3的变化则反映了橄榄石的分离结晶作用。包裹体元素组成变化总体受橄榄石、单斜辉石和斜长石的结晶分离作用控制。结合前人研究成果,认为四合屯玄武岩在微量元素和同位素组成上的壳源组分特征可能部分地继承自原岩(即橄榄岩+榴辉岩部分熔融体反应形成的(橄榄)辉石岩),而不是岩浆上升过程中受地壳岩石混染的结果。高Mg#值单斜辉石斑晶中少量高Mg馆、高Si含量,低CaO、TiO2、Al2O3和微量元素含量的熔体包裹体反映玄武岩浆上升过程中受到了S1质岩石的混染,这与义县组玄武岩下伏地层为长城系大红裕组石英岩、石英砂岩的地质特征一致。因此,高Fo橄榄石斑晶中的熔体包裹体比采用向全岩中简单添加橄榄石方式计算出的原始熔体可能更能真实反映原始熔体组成。  相似文献   

5.
笔架山东基性—超基性岩体位于塔里木板块东北部的新疆北山地区,是笔架山岩带中最东边的一个岩体,岩体形态为椭圆状,出露面积约5 km2.由含长单辉橄榄岩、橄榄辉长岩、含橄辉长岩、辉长岩以及辉绿岩组成.含橄榄石较多的岩石属拉斑玄武岩系列,而辉长岩属钙碱性系列.岩相学、岩石化学和微量元素地球化学特征表明岩浆演化过程中经历了橄榄石、辉石、斜长石的分离结晶作用.Nd、Sr、Pb同位素组成和岩石地球化学特征反映出岩浆与围岩之间存在物质交换.笔架山东岩体的岩浆源区为OIB型地幔源区,原生岩浆为高镁拉斑玄武岩浆[w(MgO)=11.2%],这些性质与塔里木板块东北部其他基性-超基性岩体的特征相似,表明塔里木板块东北部二叠纪基性—超基性岩体的源区主要为OIB型地幔,可能与地幔柱有关.  相似文献   

6.
王梦玺  陈炳龙  焦建刚 《岩石学报》2018,34(8):2223-2244
坡北杂岩体位于塔里木板块东北缘北山裂谷带,主要由橄榄岩相、单辉辉石岩相、二辉岩相、辉长岩相、苏长岩相和辉长苏长岩相组成。坡一岩体中硫化物矿体赋存于超镁铁质岩中,而坡东岩体中硫化物矿体赋存于辉长苏长岩相中。坡一和坡东岩体不同岩相中单斜辉石的MgO和CaO含量、斜长石的An值和SiO_2含量连续变化且呈负相关,说明二者可能是同一原始岩浆分离结晶的产物。根据前人计算的原始岩浆成分,我们利用MELTS软件模拟了坡北杂岩体的分离结晶过程。结果表明矿物结晶顺序为:橄榄石→橄榄石+单斜辉石→橄榄石+单斜辉石+斜长石→单斜辉石+斜长石+斜方辉石,与岩相观察一致。坡北杂岩体原始岩浆经过20%分离结晶达到S饱和而发生早期硫化物熔离,形成坡一岩体中矿体。因此,在利用具有最高Fo值(90.9mol%)的橄榄石成分进行的模拟中,坡一岩体早期结晶的纯橄榄岩中橄榄石成分与分离结晶趋势线一致,而斜长橄榄岩中橄榄石成分低于趋势线,可能形成于早期硫化物熔离之后。随后岩浆中S再一次不饱和,但坡一岩体橄榄单辉辉石岩和辉长岩中橄榄石Fo和Ni含量在分离结晶趋势线之下,同时坡东岩体不含矿岩石中铂族元素总量主要在8.9×10~(-9)~29.0×10~(-9)之间,且相对于Ni和Cu明显亏损,说明在岩浆分离结晶晚期再次发生硫化物熔离,而且可能是地壳混染引起的,并形成了坡东岩体中的硫化物矿体。坡东岩体橄榄二辉岩和橄榄辉长苏长岩中橄榄石Fo值(74.5mol%~81.0mol%)较低,但变化范围较大,且Fo和Ni呈负相关关系,这可能是由于橄榄石和硫化物熔体在不平衡状态下发生成分交换造成的。坡北杂岩体超镁铁质岩石中单斜辉石Ti O2含量为0.21%~0.83%,阳离子中呈四次配位的Al(AlZ)为0.8mol%~7.8mol%,与裂谷环境堆晶岩中单斜辉石成分相似。因此,坡北杂岩体可能形成于和塔里木二叠纪地幔柱活动相关的裂谷环境。然而,超镁铁质岩石全岩Nd同位素指示其来源于亏损地幔,并不是地幔柱物质熔融的直接产物。纯橄榄岩和异剥橄榄岩La/Sm,Sm/Yb和La/Yb比值指示其源区为尖晶石二辉橄榄岩地幔。因此,坡北杂岩体源区应为浅部以尖晶石二辉橄榄岩为主的亏损岩石圈地幔,地幔柱在源区部分熔融过程中提供了大量的热。  相似文献   

7.
昌乐方山新生代玄武岩中携带有大量深源捕虏岩,其岩石类型以二辉辉石岩、二辉橄榄岩为主,方辉橄榄岩、单斜辉石岩、单辉橄榄岩少见,未见纯橄岩。二辉辉石岩、二辉橄榄岩、方辉橄榄岩的矿物岩石、地球化学特征和平衡温度压力计算显示为地幔来源,采用地质温度压力计进行计算,获取三者都源于岩石圈地幔,形成的深度范围为41~66.7 km。根据单辉橄榄岩和单斜辉石岩的矿物化学分析,单斜辉石岩和单辉橄榄岩形成深度要低于前三者,且与前三者有密切成因联系。"熔体—岩石"反应在各类深源捕虏岩中广泛存在,除方辉橄榄岩样品不存在明显的"熔体—岩石"反应外,二辉辉石岩、单斜辉石岩、二辉橄榄岩中不同的矿物边缘与玄武质熔体接触部位有着不同类型的反应边和反应矿物出现:橄榄石边部发生(Mg,Fe)_2SiO_4(镁橄榄石)+熔体(原始岩浆)=(Mg,Fe)_2SiO_4(贵橄榄石)+熔体(演化岩浆)反应,使得边部富铁贫镁;单斜辉石与玄武质熔体反应,多具有粉红色反应边,具有富Ti、Al、Fe,贫Si、Mg,较玄武岩基质中单斜辉石斑晶更低Mg~#的特征。斜方辉石与玄武质熔体反应生成复杂的反应带,存在斜方辉石+熔体=橄榄石+SiO_2(熔体)+单斜辉石的反应,反应带内新生成的矿物由内向外具有明显趋向玄武质熔体成分的变化;尖晶石与玄武质熔体反应边缘具有富Fe、Ti,贫Mg、Al,以及更高的Cr~#,趋向于形成钛铁矿的变化特征。二辉橄榄岩中熔体囊和单辉橄榄岩中筛状单斜辉石以及粉红色的反应边都暗示了二者至少经历了两个期次的熔体作用。随着岩石圈地幔的演化,熔体的再富集作用使得难熔的方辉橄榄岩逐渐转变为相对富集的二辉橄榄岩,后期二辉橄榄岩又与玄武质熔体反应,生成更加富集的单辉橄榄岩,而方山方辉橄榄岩也受到了熔体的轻度改造,已不具有难熔古老岩石圈地幔岩石的显著特征,鲁西新生代玄武岩中深源捕虏体与熔体的反应广泛存在,熔体成分以玄武质为主,这可能是华北克拉通岩石圈置换的重要方式之一,导致古老岩石圈地幔的消失。  相似文献   

8.
腾冲和保山地块之间的高黎贡—瑞丽断裂带西侧出露潞西三台山地幔橄榄岩,该岩体与围岩均呈断层接触共同构成增生杂岩,主要由纯橄榄岩和方辉橄榄岩组成,主要造岩矿物为橄榄石和斜方辉石,副矿物尖晶石发育。橄榄石为镁橄榄石(Fo为90~93);斜方辉石为顽火辉石(En为89~92),以低铝(0.47%~1%)和高Mg#值(91~96)为特征;尖晶石主要为富铬型尖晶石(Cr#值为54~78)。三台山纯橄榄岩和方辉橄榄岩具有相似的稀土配分模式曲线,为轻稀土元素富集且右倾平坦型曲线;在微量元素原始地幔标准化图解中,相对富集大离子亲石元素Rb、Cs和高场强元素Pb、U。矿物地球化学和全岩组分表明,三台山橄榄岩主要矿物与全岩地球化学成分特征具有深海橄榄岩和弧前橄榄岩的特征,为经历了25%~35%部分熔融后的残余。结合与不同蛇绿岩体构造环境的对比,笔者认为三台山橄榄岩与雅鲁藏布江缝合带的蛇绿岩体具有相似的源区特征,兼具亏损地幔源区特征和俯冲带熔/流体交代特征,表明其可能经历了快速扩张大洋中脊(MOR)和俯冲带仰冲板片(SSZ)两种构造环境。  相似文献   

9.
大兴安岭地幔橄榄岩中熔体的多样性及其成因   总被引:1,自引:1,他引:0  
本文报道了大兴安岭第四纪火山岩中的地幔橄榄岩中橄榄石、单斜辉石和斜方辉石颗粒内部熔体产状(囊体、包裹体和反应边)和成分(低硅熔体和高硅熔体)的多样性,初步讨论了不同熔体的成因。低硅熔体囊体是在地幔深部玄武岩浆与橄榄岩中单斜辉石发生交代反应的产物,斜方辉石反应边的高硅熔体是橄榄岩被捕获上升过程中玄武岩浆与斜方辉石反应的产物,高硅熔体包裹体是地幔中存在的交代熔体。  相似文献   

10.
利用橄榄石和熔体包裹体,结合全岩的方法对辽西地区早白垩世义县组黄半吉沟火山岩的成因进行了研究。黄半吉沟火山岩SiO_2=53.41%~53.74%,MgO=8.15%~8.23%,Mg#=~70(Mg#=mol Mg/(Mg+Fe2+)),为高镁安山岩;全岩在TAS图解上,落在玄武安山岩范围内,属于亚碱性系列;它们具有较高Ni(119×10-6~125×10-6)和高Cr(467×10-6~521×10-6),显示幔源岩浆特征;在微量元素组成上,黄半吉沟高镁安山岩Sr=920×10-6~930×10-6,Y=16.1×10-6~16.4×10-6,Sr/Y=57~58;在微量元素原始地幔标准化蛛网图上,黄半吉沟高镁安山岩显示轻重稀土分异,明显的Nb-Ta-Ti和弱的Zr-Hf负异常,Ba、Sr和Pb正异常,这些特征与大陆下地壳非常相似。熔体包裹体MgO为6.5%~9.7%,SiO_2为51%~53%,不符合典型高镁安山岩的定义;在TAS图解上它们落在玄武粗安岩内,属于碱性系列;MgO与其它主量元素成分呈明显或者弱的负相关关系,说明它们的成分主要受控于橄榄石结晶分离过程。黄半吉沟高镁安山岩的橄榄石Fo值为75~91;CaO含量为0.10%~0.18%,NiO为0.05%~0.41%,Fe/Mn比值为60~80。黄半吉沟高镁安山岩的全岩和熔体包裹体成分存在显著差异,如熔体包裹体具有更高的Al2O3和更低的SiO_2。结合全岩微量元素特征,我们认为黄半吉沟高镁安山岩在地壳深度的岩浆演化过程中加入了来自下地壳的酸性熔体,是壳幔相互作用的结果。全岩较低Ni高Mg#,熔体包裹体低CaO并落在CATS-Olivine-Quartz相图的热障碍边界线富硅一侧,以及橄榄石低Ca和陡倾的Fo-Ni关系,指示黄半吉沟高镁安山岩的幔源岩浆是来自以斜方辉石为主辉石岩的源区。我们认为广泛发育于辽西地区的早白垩世义县组高镁安山岩可能经历了壳幔相互作用,因而不能作为拆沉作用导致岩石圈大规模减薄的重要证据。  相似文献   

11.
对鲁西晚中生代济南和邹平辉长岩的Pb-Sr-Nd同位素和元素组成的研究,给出(87Sr/86Sr)i=0.7041~0.7056,εNd(t )=-6.0~-13.0,( 206Pb/204Pb)i=16.545~16.998,(207Pb/204Pb)i=15.242~15.350,(208Pb/204Pb)i=36.488~36.944(除SD792表现出高放射成因Pb外)。由于辉长岩的堆晶性质,其微量元素组成不能用于指示其物质来源。与EMⅠ型大洋和大陆玄武岩对比,表明济南和邹平辉长岩的源区具有与EMⅠ地幔端元一致的同位素特征,但在Pb同位素图解上有明显的下地壳物质的贡献。下地壳物质的参与可能与拆沉有关。  相似文献   

12.
橄榄石是基性岩浆中最早期结晶的硅酸盐矿物之一,其主量、微量元素特征可以反映出岩浆演化环境、岩浆源区岩性和再循环组分性质等重要信息.本次研究通过对峨眉山大火成岩省平川苦橄岩中橄榄石主量和微量元素分析,以及橄榄石内尖晶石包裹体分析,并与大理苦橄岩中橄榄石和尖晶石成分进行对比,来探讨不同苦橄岩母岩浆氧逸度及源区性质的异同.橄...  相似文献   

13.
The geochemical characteristics of melt inclusions and their host olivines provide important information on the processes that create magmas and the nature of their mantle and crustal source regions. We report chemical compositions of melt inclusions, their host olivines and bulk rocks of Xindian basalts in Chifeng area, North China Craton. Compositions of both bulk rocks and melt inclusions are tholeiitic. Based on petrographic observations and compositional variation of melt inclusions, the crystallizing sequence of Xindian basalts is as follows: olivine (at MgO > ~5.5 wt%), plagioclase (beginning at MgO = ~5.5 wt%), clinopyroxene and ilmenite (at MgO < 5.0 wt%). High Ni contents and Fe/Mn ratios, and low Ca and Mn contents in olivine phenocrysts, combining with low CaO contents of relatively high MgO melt inclusions (MgO > 6 wt%), indicate that Xindian basalts are possibly derived from a pyroxenite source rather than a peridotite source. In the CS-MS-A diagram, all the high MgO melt inclusions (MgO > 6.0 wt%) project in the field between garnet + clinopyroxene + liquid and garnet + clinopyroxene + orthopyroxene + liquid near 3.0 GPa, further suggesting that residual minerals are mainly garnet and clinopyroxene, with possible presence of orthopyroxene, but without olivine. Modeling calculations using MELTS show that the water content of Xindian basalts is 0.3–0.7 wt% at MgO = 8.13 wt%. Using 20–25 % of partial melting estimated by moderately incompatible element ratios, the water content in the source of Xindian basalts is inferred to be ≥450 ppm, much higher than 6–85 ppm in dry lithospheric mantle. The melting depth is inferred to be ~3.0 GPa, much deeper than that of tholeiitic lavas (<2.0 GPa), assuming a peridotite source with a normal mantle potential temperature. Such melting depth is virtually equal to the thickness of lithosphere beneath Chifeng area (~100 km), suggesting that Xindian basalts are derived from the asthenospheric mantle, if the lithospheric lid effect model is assumed.  相似文献   

14.
Young (6 Ma) alkali-basalts were collected from the toe of the oceanward slope of the northern Japan Trench. Two types of olivine are present in these lavas, xenocrysts with reaction rims and magmatic. The forsterite (Fo) (no. 91–92) values and NiO contents (0.3–0.5 wt%) of the xenocrysts are similar in composition to those of the depleted mantle peridotite. The groundmass olivines have relatively lower Fo values (no. 81–88) and NiO contents (0.1–0.5 wt%). Reaction rims and the vicinity of the silicate inclusion in xenocrysts show the intermediate compositions between the xenocryst and magmatic olivines. Chromian spinel inclusions in the xenocrysts also show the depleted composition in the range of abyssal peridotite. CO2 fluid inclusions in the xenocryst records pressures before entrainment into the host magma up to 0.4 GPa, which corresponds to a depth of up to 14 km of lithospheric mantle. These data indicate that the xenocrysts originate from MORB-depleted mantle.  相似文献   

15.
The isotopic compositions of Pb and Sr in Pleistocene basalt, high-silica rhyolite, and andesitic inclusions in rhyolite of the Coso volcanic field indicate that these rocks were derived from different levels of compositionally zoned magmatic systems. The 2 earliest rhyolites probably were tapped from short-lived silicic reservoirs, in contrast to the other 36 rhyolite domes and lava flows which the isotopic data suggest may have been leaked from the top of a single, long-lived magmatic system. Most Coso basalts show isotopic, geochemical, and mineralogic evidence of interaction with crustal rocks, but one analyzed flow has isotopic ratios that may represent mantle values (87Sr/86Sr=0.7036,206Pb/204Pb=19.05,207Pb/204Pb=15.62,208Pb/204Pb= 38.63). The (initial) isotopic composition of typical rhyolite (87Sr/86Sr=0.7053,206Pb/204Pb=19.29,207Pb/204Pb= 15.68,208Pb/204Pb=39.00) is representative of the middle or upper crust. Andesitic inclusions in the rhyolites are evidently samples of hybrid magmas from the silicic/mafic interface in vertically zoned magma reservoirs. Silicic end-member compositions inferred for these mixed magmas, however, are not those of erupted rhyolite but reflect the zonation within the silicic part of the magma reservoir. The compositional contrast at the interface between mafic and silicic parts of these systems apparently was greater for the earlier, smaller reservoirs.  相似文献   

16.
Upper mantle xenoliths from Wikieup, AZ, provide abundant evidence for magmatic modification of the uppermost mantle beneath the Transition Zone between the Colorado Plateau and the southern Basin and Range province. Upper mantle lithologies in this xenolith suite are represented by spinel peridotite, wehrlite, plagioclase peridotite, and Al-augite group pyroxenites. Isotopic data for these xenoliths yield relatively uniform values and suggest a common petrogenesis. Al-augite-bearing gabbro and pyroxenite xenoliths from this locality are interpreted to have formed by crystal fractionation processes from parent alkali basalts similar to the Wikieup host basalt. Mineral and whole rock compositions show consistent trends of increasing incompatible element contents (Fe, Al, Ca, Na, K, LIL, and LREE), and decreasing compatible element contents (Mg, Cr, Ni) from spinel peridotite to wehrlite to plagioclase peridotite to the host basalt composition. These compositional trends are interpreted as resulting from varying degrees of magma-mantle wall rock interaction as ascending mafic magmas infiltrated upper mantle peridotite. Small degrees of melt infiltration resulted in slightly modified spinel peridotite compositions while moderate degrees metasomatized spinel peridotite to wehrlite, and the highest degrees metasomatized it to plagioclase peridotite. Whole rock compositions and clinopyroxene, plagioclase, and whole rock isotopic data suggest that the infiltrating magmas were the same as those from which the gabbros and pyroxenites crystallized, and that they were alkalic in composition, similar to the Wikieup host alkali olivine basalts. Relatively uniform 143Nd/144Nd for the mineral separates and whole rocks in spite of the significantly wide range in their 147Sm/144Nd (0.71–0.23 in clinopyroxene) suggests that the Wikieup xenoliths including gabbro, pyroxenite, peridotite, wehrlite, and plagioclase peridotite, are all relatively young rocks formed or metasomatized by a relatively recent magmatic episode. Received: 21 May 1996 / Accepted: 23 December 1996  相似文献   

17.
We report Lithium (Li) concentrations and isotopic compositions for co-existing olivine, orthopyroxene (opx), and clinopyroxene (cpx) mineral separates from depleted and metasomatised peridotite xenoliths hosted by basaltic lavas from northwestern Ethiopian plateau (Gundeweyn area). The peridotites contain five lherzolites and one harzburgite and are variably depleted and enriched in LREE relative to HREE. In both depleted and enriched lherzolites, Li is preferentially incorporated into olivine (2.4-3.3 ppm) compared to opx (1.4-2.1 ppm) and cpx (1.4-2.0 ppm) whereas the Li contents of olivines (5.4 ppm) from an enriched harzburgiteare higher than those of lherzolites. Olivines from the samples show higher Li abundances than normal mantle olivines (1.6-1.9 ppm) indicating the occurrence of Li enrichments through melt-preroditite interaction. The average δ7 Li values range from +2.2 to +6.0‰ in olivine, from -0.1 to +2.0‰ in opx and from -4.4 to -0.9‰ in cpx from the lherzolites. The Li isotopic composition (3.5‰) of olivines from harzburgite fall within the range of olivine from lherzolites but the opxs show low in δ7Li (-2.0‰). Overall Li isotopic compositions of olivines from the peridotites fall within the range of normal mantle olivine, δ7Li values of ~+4±2‰ within uncertainty, reflecting metasomatism (enrichment) of the peridotites by isotopically heavy Li-rich asthenospheric melt. Li isotope zonation is also observed in most peridotite minerals. Majority of olivine grains display isotopically heavy cores and light rims and the reverse case is observed for some olivine grains. Orthopyroxene and clinopyroxene grains show irregular distribution in δ7Li. These features of Li isotopic compositions within and between grains in the samples reflect the effect of diffusion-driven isotopic fractionation during meltperidotite interaction and cooling processes.  相似文献   

18.
The Sopcheozero chromite deposit is hosted in dunite of the Monchegorsk layered intrusion as a sheetlike body of disseminated ore with a chromite grade varying from 20 to 60%. The total PGM content in the ore attains 0.5–0.8 g/t. The composition of host rocks varies from plagioclase peridotite to dunite, but PGM were found only in chromite-bearing dunite. PGM inclusions were detected in the interstices of chromite and olivine grains and within grains themselves. The data obtained confirm the known tendency toward variation in PGM composition with increasing sulfur and light PGE contents in the residual magmatic melt. The first particles of refractory Ir, Os, and Ru intermetallides appeared at the final stage of olivine crystallization, whereas laurite (Ru,Os,Ir)S2 and pentlandite (Fe,Ni)9S8 were formed at the final stage of chromite crystallization, when the sulfur concentration in the residual melt became sufficient.  相似文献   

19.
A technique is described for determining the cooling historyof olivine phenocrysts. The technique is based on the analysisof the diffusive re-equilibration of melt inclusions trappedby olivine phenocrysts during crystallization. The mechanismof re-equilibration involves diffusion of Fe from and Mg intothe initial volume of the inclusion. The technique applies toa single crystal, and thus the cooling history of differentphenocrysts in a single erupted magma can be established. Weshow that melt inclusions in high-Fo olivine phenocrysts frommantle-derived magmas are typically partially re-equilibratedwith their hosts at temperatures below trapping. Our analysisdemonstrates that at a reasonable combination of factors suchas (1) cooling interval before eruption (<350°C), (2)eruption temperatures (>1000°C), and (3) inclusion size(<70 µm in radius), partial re-equilibration of upto 85% occurs within 3–5 months, corresponding to coolingrates faster than 1–2°/day. Short residence timesof high-Fo phenocrysts suggest that if eruption does not happenwithin a few months after a primitive magma begins cooling andcrystallization, olivines that crystallize from it are unlikelyto be erupted as phenocrysts. This can be explained by efficientseparation of olivine crystals from the melt, and their rapidincorporation into the cumulate layer of the chamber. Theseresults also suggest that in most cases erupted high-Fo olivinephenocrysts retain their original composition, and thus compositionsof melt inclusions in erupted high-Fo olivine phenocrysts donot suffer changes that cannot be reversed. Short residencetimes also imply that large unzoned cores of high-Fo phenocrystscannot reflect diffusive re-equilibration of originally zonedphenocrysts. The unzoned cores are a result of fast efficientaccumulation of olivines from the crystallizing magma, i.e.olivines are separated from the magma faster than melt changesits composition. Thus, the main source of high-Fo crystals inthe erupted magmas is the cumulate layers of the magmatic system.In other words, olivine-phyric rocks represent mixtures of anevolved transporting magma (which forms the groundmass of therock) with crystals that were formed during crystallizationof more primitive melt(s). Unlike high-Fo olivine phenocrysts,the evolved magma may reside in the magmatic system for a longtime. This reconciles long magma residence times estimated fromthe compositions of rocks with short residence times of high-Foolivine phenocrysts. KEY WORDS: melt inclusions; olivine; picrites; residence time; diffusion  相似文献   

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