共查询到20条相似文献，搜索用时 937 毫秒
1.
用金属铝与液态溴发生反应生成的AlBr3溶于甲醇、而Al2O3在无水条件下不与液态溴发生反应的不同化学行为特性，实现了Al与Al2O3的分离，采用铝试剂光度法测定铝锭中的微量AAl2O3。结果表明，在pH4．4的NaAc—HCI缓冲溶液中，铝与铝试剂形成的配合物在530nm处有最大吸收。Al2O3含量在0～3．0mg／L遵循比尔定律。方法检出限为0．005mg／L。建立的方法用于实际铝锭样品中Al2O3的测定，精密度（RSD，n=5）为3．50％～14．3％，加标回收率为98．9％～99、7％。 相似文献
2.
以粉煤灰为主要原料, CaF2为矿化剂,设计MG和MS值,控制CaO和CaSO4含量,分别在1 150、1 200、1 250、1 300和1 350℃温度下烧制高胶凝性硫铝酸钙-阿利特复合矿相水泥熟料.运用X射线粉晶衍射(XRD)和扫描电镜(SEM)等手段,研究原料配方和煅烧温度对熟料物相组成的影响,对熟料物相形成的反应历程作了探讨.实验结果表明,在1-300℃,当MG=1.05、MS =0.95时,形成较理想的熟料,物相组成约为C4A3-S 58.73%,C3S 23.99%,C2S 2.87%,C11A7·CaF2/C12A7 14.07 %,f-CaO 0.35%.熟料中主要物相硫铝酸钙晶体呈菱形十二面体,发育完整,形态规则,颗粒大小约为1～3 μm;阿利特(C3S)相物相为板状六角形,晶体发育相对细小. 相似文献
3.
4.
东疆雅西371-西北坡铜金矿化带下石炭统火山岩地球化学特征与成矿背景 总被引：4，自引：2，他引：4
新疆东天山雅西371-西北坡铜金化带中下石炭统火山岩属钙碱性系列。流纹岩类中SiO2（73．96％～78．01％）和Al2O3（11．3％～14．63％）含量高，含Na2O为2．04％～4．15％，K2O为2．74％～3．74％，（Na2O＋K2O）为5．34％～7．03％；流纹岩类属过铝质、中钾-高钾火山岩系列。微量和稀土元素分析结果显示：流纹岩类具有Ti、Nb、P和Ta明显负异常、Sr中等负异常，LREE明显富集，La／Nb值为0．4～2．3，La／Th值0．4—1，Th／Ta值高（6～36．5），具有明显δEu（0．17-0．29）负异常，地球化学特征表明流纹岩类可能形成在活动大陆边缘上的陆缘岛弧构造背景中。本区（含矿）酸性火山岩特征对于寻找与长英质火山岩有关的金属硫化物矿床十分有利，因此认为本区具有较大找矿前景。 相似文献
5.
对湖南柏坊铜矿床矿石和脉石矿物进行矿物包裹体、碳、氧、氢和硫同位素测定,获得成矿均一温度约为182℃～192℃,盐度为1．2～4．7wt％。方解石的δ^13C为-2．0‰～3．1‰,δ^18Osmow为12．6‰～20．9‰,δD为-67．3‰～-131．6‰,氢、氧和碳同位素数值随矿体浅部到深部由小到大的变化,显示出热液可能是多来源的。硫化物中辉铜矿的δ^34S为-31．8‰～2．9‰,黄铁矿的δ^34S为-2．1‰～＋2．9‰。黄铁矿的硫同位素组成大于辉铜矿的硫同位素组成,表明硫同位素达到平衡,并估算出δ^34S∑s为0‰,δ^34S∑s值小,指示出硫可能是岩浆来源。 相似文献
6.
河南商城鲢鱼尖变形花岗岩岩体的地质、地球化学特征、成因及含矿性研究表明，岩体具有贫SiO2、K2O，富Al2O3、TiO2、CaO、MgO、Fe2O3＋FeO之特征，Na2O＋K2O为7．65％～8．84％。K2O／Na2O为0．66～0．9；分异指数（Dr）为71．2～80．7，ASI值为0．81～0．98，氧化指数（OX）为0．55～0．32，8值为3．1～4．05，为准铝质钙碱性岩石系列。在An—Ab—Or图解及R1-R2多阳离子图解上多落于花岗闪长岩一二长花岗岩区，为斑状二长花岗岩-斑状花岗闪长岩。岩体与围岩接触带上可形成Cu、Pb、Zn、Ag、Mo多金属矿（床）。 相似文献
7.
氧化物及复合添加剂对硫酸钙高温稳定性的影响 总被引：2，自引：0，他引：2
在硫酸钙高温分解行为的研究基础上,探讨了氧化物SiO_2、Fe_2O_3、ZnO和SiO_2_Fe_2O_3、CaCO_3-Al_2O_3复合添加剂对硫酸钙分解的影响。结果表明ZnO、SiO_2、SiO_2-Fe_2O_3均有利于固硫,这分别与反应过程中形成能起包覆作用的Ca_2SiO_4和耐热含硫物相Ca2Fe2S2O3有关;复合添加剂CaCO3_Al2O3固硫效果更佳,当CaCO3∶Al2O3∶CaSO4摩尔比为3∶3∶1时,固硫作用最理想,1400℃时CaSO4的分解率从87.5%降低到21.2%,这与形成大量高温耐热物相硫铝酸钙有关。 相似文献
8.
改良酸碱联合法利用高铝粉煤灰制备氧化铝的实验研究 总被引：2，自引：0，他引：2
本实验以高铝粉煤灰为原料、Na2CO3为助剂,经中温烧结,酸溶除硅,碱溶除铁,加入铝酸钡除微量硅后,制得较纯净的铝酸钠溶液;向该溶液中加入Al(OH)3晶种,采用种分分解法制备得到Al(OH)3沉淀,于1200℃下煅烧2 h后,制得α-Al2O3。分析结果表明,制备的-αAl2O3粉体形态不规则,粒径在10μm以下,性能达到国标GB8178-87三级标准。本项技术符合国家发展循环经济的要求,是高铝粉煤灰资源化高效利用的有效途径之一。 相似文献
9.
湘东南瑶岗仙岩体岩石化学特征、成因与构造环境 总被引：2，自引：0，他引：2
湘东南燕山早期瑶岗仙岩体主要由黑云母二长花岗岩组成。岩石SiO2和K20平均含量分别为75．83％和4．78％,Na2O＋K2O平均8．02％,K2O／Na2O比值平均为1．53,Al2O3平均为12．98％。总体属弱过铝质钙碱性花岗岩类。εNd（t）值为-11．13～-9．13;t20M为1．70～1．86Ga,与湘桂内陆带花岗岩的背景值（1．8～2．4Ga）和区域基底的时代（1．7～2．7Ga）相吻合。上述特征表明,瑶岗仙岩体岩浆来源为中地壳结晶基底,属典型S型花岗岩。氧化物构造环境判别图解及区域构造演化背景反映瑶岗仙岩体形成于后造山构造环境。 相似文献
10.
发射光谱法测定勘查地球化学样品中银硼锡钼铅 总被引：21，自引：13，他引：21
以K2S2O7、NaF、Al2O3和炭粉为缓冲剂，Ge为内标，电弧发射光谱法测定勘查地球化学样品中Ag、B、Sn、Mo、Pb。方法检出限为Ag0．013μg／g、B0．83μg/g、Sn0．23μg／g、Mo0．073μg/g、Pb0．37μg／g。方法精密度（RSD，n=12）为Ag4．2％～11．3％、B3．2％～6．5％、Sn2．6％～7．1％、Mo2．9％～6．3％、Pb1．57％～5．18％。测定了国家一级地球化学标准物质，结果与标准值相符。 相似文献
11.
吉林省集安活龙金矿区位于一巨大剪切带中,强烈糜棱岩化,产生了Lister and Snoke(1984)所定义的Ⅰ和Ⅱ两类SC糜棱岩。依据两种主要糜棱面理S(Sm)与C的几何关系及局部发育的拉伸线理,初步确定了发生于中生代的两次剪切运动。含金石英脉(金矿体)均顺沿C面空间形成,当转入S时,则很快变薄消失。但S面大面积低品位金矿化现象表明,S面在含金流体渗透时曾起到通道作用。宏观上,含金石英脉集中分布于由接近平行的或交织的C面组成的、且排列较规则的构造带中,因C面通常倾角极缓,故构造带和相关的含金石英脉组呈一定间距出现于某些标高段内。金矿体的品位、厚度的稳定方位与S∧C交线方位接近,而且金矿体往往呈串珠状和透镜状顺此方位排列。 相似文献
12.
G. Musumeci 《Geodinamica Acta》2013,26(1-2):119-133
AbstractThe Monte Grighini Complex (Central-Western Sardinia) is a NW-SE trending metamorphic complex of Hereynian age made up of a medium grade Lower tectonic unit with mylonitie granitoids and a low grade Upper tectonic unit exposed in the westernmost and southernmost portions of this complex. The Lower Unit shows a prograde metamor phism from garnet to sillimanite zone and the transition from MP/MT to LP/HT metamorphism. The metamorphic climax was reached at the end of the main deformative phase 1)2 (600° C. 6 kbar). After the main tectonic and metamorphic phase. the Lower Unit was affected by a wide NW-SE trending ductile dextral wrench shear zone. Intrusive rocks emplaced within the shear zone yielded radiometric ages of 305-300 Ma. Shear deformation leads to low temperature C-S mylonites and retrograde phyllonitic rocks with subhorizontal NW-SE trending stretching lineations. Kinematic analysis of the shear zone points to a dextral sense of shear with an amount of ductile displacement of about 7 km. Later low angle N-S and E-W trending normal faults are associated with cataclastic zones separating the Lower Unit from the Upper one. These faults originated during a later evolutionary stage of the shear zone. This shows a progressive change of deformation regime from duetile wrenching to brittle normal faulting. The Monte Grighini Complex is a good example of ductile wrench tectonics. followed by uplift and extension in the Paleozoic basement of Sardinia. 相似文献
13.
14.
15.
北准噶尔增生杂岩带重磁场特征及构造解译 总被引：1，自引：0，他引：1
通过系统统计新疆准噶尔北部地区主要岩矿石磁性、密度参数,重点研究了该区航空磁场、区域重力场分布规律。按照布格重力和航磁异常形态,准噶尔地区可以划分为三个布格重力异常单元和五个航磁异常单元,认为北准噶尔地区的布格重力异常和航磁异常揭示该区可能为一陆缘增生杂岩带。该增生杂岩带形态上呈"锲形",其北缘位于阿尔泰–富蕴断裂一带,西部与哈萨克斯坦板块毗邻,南部边缘为阿尔曼太蛇绿混杂岩带。该增生杂岩带由多个增生单元"拼贴"而成,具北东向凸起特点。阿尔泰–阿尔金地学断面揭示了增生杂岩带深部俯冲形态。本次研究成果为研究新疆北部与邻区大地构造提供了新的依据。 相似文献
16.
钛铁矿单项铁测定新思路 总被引：1，自引：0，他引：1
含钛铁矿石是一种很难分解的矿石。由于钛含量高,且易水解形成难溶的偏钛酸(H2TiO3)析出,常常给分析带来困难。选择合适酸作助溶酸,精心操作,效果较好。 相似文献
17.
QIN Xiwei MA Haizhou ZHANG Xiying CHENG Huaide HAN Jibin LI Yongshou MIAO Weiliang HAI Qingyu 《《地质学报》英文版》2019,93(4):1097-1112
Chemical and isotopic data were measured for 51 leached brine springs in the Changdu-Lanping-Simao Basin (CD-LP-SM), China. The predominance of Cl and Na, saturation indices of carbonate minerals, and Na/Cl and Ca/SO4 ratios of ~1 suggest that halite, sulphate, and carbonate are the solute sources. Integration of geochemical, δ18O, and δD values suggests that springs are mainly derived from meteoric water, ice-snow melt, and water-rock interactions. B concentrations range from 0.18 to 11.9 mg/L, with δ11B values of ?4.37‰ to +32.39‰, indicating a terrestrial source. The δ11B-B relationships suggest B sources of crustal origin (marine carbonates with minor crust-derived volcanics); we did not identify a marine or deep mantle origin. The δ11B values of saline springs (+4.61‰ to +32.39‰) exceed those of hot (?4.37‰ to +4.53‰) and cold (?3.47‰ to +14.84‰) springs; this has contributed to strong water-rock interactions and strong saturation of dissolved carbonates. Conversely, the global geothermal δ11B-Cl/B relationship suggests mixing of marine and non-marine sources. The δ11B-Cl/B relationships of the CD-LP-SM are similar to those of the Tibet geothermal belt and the Nangqen Basin, indicating the same B origin. These differ from thermal waters controlled by magmatic fluids and seawater, suggesting that B in CD-LP-SM springs has a crustal origin. 相似文献
18.
用一种新的合成方法在水相中合成了钛磁铁矿(Fe3-xTixO4),并用XRD和FTIR对已合成的Fe3-xTixO4进行了表征。结果表明:合成的Fe3-xTixO4为立方晶系尖晶石结构,样品中的钛离子都已经进入Fe3-xTixO4晶格中,且Fe3-xTixO4表面羟基量随着钛掺杂量的增加而增加。随后,以亚甲基蓝为模拟染料污染物,考察了Fe3-xTixO4的吸附性能。实验表明:钛掺杂能够显著促进Fe3-xTixO4对亚甲基蓝的吸附,吸附反应在0.5h内就能达到吸附平衡。 相似文献
19.
Dr M. J. Wooller D. L. Swain K. J. Ficken A. D. Q. Agnew F. A. Street-Perrott G. Eglinton 《第四纪科学杂志》2003,18(1):3-15
Woody, subalpine shrubs and grasses currently surround Lake Rutundu, Mount Kenya. Multiple proxies, including carbon isotopes, pollen and grass cuticles, from a 755‐cm‐long core were used to reconstruct the vegetation over the past 38 300 calendar years. Stable carbon‐isotope ratios of total organic carbon and terrestrial biomarkers from the lake sediments imply that the proportion of terrestrial plants using the C4 photosynthetic pathway was greater during the Late Pleistocene than in the Holocene. Pollen data show that grasses were a major constituent of the vegetation throughout the Late Pleistocene and Holocene. The proportion of grass pollen relative to the pollen from other plants was greatest at the last glacial maximum (LGM). Grass cuticles confirm evidence that C4 grass taxa were present at the LGM and that the majority followed the cold‐tolerant NADP‐MEC4 subpathway. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
20.
The δ18O stratigraphy of the Hoxnian lacustrine sequence at Marks Tey,Essex, UK: implications for the climatic structure of MIS 11 in Britain 
下载免费PDF全文
下载免费PDF全文 G. J. Tye J. Sherriff I. Candy P. Coxon A. Palmer E. L. McClymont D. C. Schreve 《第四纪科学杂志》2016,31(2):75-92
Marine Isotope Stage 11 (MIS 11) is considered one of the best analogues for the Holocene. In the UK the long lacustrine sequence at Marks Tey, Essex, spans the entirety of the Hoxnian interglacial, the British correlative of MIS 11c. We present multiproxy evidence from a new 18.5‐m core from this sequence. Lithostratigraphy, pollen stratigraphy and biomarker evidence indicate that these sediments span the pre‐, early and late temperate intervals of this interglacial as well as cold climate sediments that post‐date the Hoxnian. The δ18O signal of endogenic carbonate from this sequence produces several clear patterns that are interpreted as reflecting the climatic structure of the interglacial. As well as providing evidence for long‐term climate stability during the interglacial and a major post‐Hoxnian stadial/interstadial oscillation the δ18O signal provides strong evidence for abrupt cooling events during the interglacial itself. One of these isotopic events occurs in association with a short‐lived increase in non‐arboreal pollen (the NAP phase). The results presented here are discussed in the context of other MIS 11 records from Europe and the North Atlantic, particularly with respect to our understanding of the occurrence of abrupt climatic events in pre‐Holocene interglacials. Copyright © 2016 The Authors. Journal of Quaternary Science Published by John Wiley & Sons Ltd. 相似文献