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1.
云南大姚地区上白垩统马头山组六苴段中亚段 总被引：3，自引：0，他引：3
上白垩统马头山组六苴段中亚段(K2ml2)是云南六苴砂岩型铜矿区内含铜层位之一。六苴段中亚段含铜砂岩Mo、Cd、As、Cu等亲硫元素富集。微量元素多富集于浅色砂岩中,向紫色砂岩一侧逐渐亏损,呈现分带特征。铜矿石V/(V+Ni)值大于0.7,反映缺氧环境的特点。稀土元素总量(∑REE)101.71×10-6～157.55×10-6,稀土元素分配模式为Eu、Ce亏损-轻稀土元素富集型。从铜矿石→浅色矿化砂岩→浅色无矿砂岩,随着铜含量的降低,Mo、Cd、As、Hg平均含量逐渐降低,∑REE与高场强元素Nb、 Zr、 Hf、Th平均含量逐渐升高。六苴段中亚段砂岩具“矿源层”的特征,铜矿石与围岩具物源一致性,铜矿石在弱碱性、还原条件下由砂岩经水-岩作用形成,与六苴铜矿床(K2ml1)成矿机理相似。小河地段纵向上从北向南,六苴段中亚段中铜矿化的能力逐渐减弱,推测矿化带在走向上向西(紫色砂岩一侧)发生了偏移。 相似文献
2.
《地质通报》2010,(6)
上白垩统马头山组六苴段中亚段(K2ml2)是云南六苴砂岩型铜矿区内含铜层位之一。六苴段中亚段含铜砂岩Mo、Cd、As、Cu等亲硫元素富集。微量元素多富集于浅色砂岩中,向紫色砂岩一侧逐渐亏损,呈现分带特征。铜矿石V/(V+Ni)值大于0.7,反映缺氧环境的特点。稀土元素总量(∑REE)101.71×10-6～157.55×10-6,稀土元素分配模式为Eu、Ce亏损-轻稀土元素富集型。从铜矿石→浅色矿化砂岩→浅色无矿砂岩,随着铜含量的降低,Mo、Cd、As、Hg平均含量逐渐降低,∑REE与高场强元素Nb、Zr、Hf、Th平均含量逐渐升高。六苴段中亚段砂岩具"矿源层"的特征,铜矿石与围岩具物源一致性,铜矿石在弱碱性、还原条件下由砂岩经水-岩作用形成,与六苴铜矿床(K2ml1)成矿机理相似。小河地段纵向上从北向南,六苴段中亚段中铜矿化的能力逐渐减弱,推测矿化带在走向上向西(紫色砂岩一侧)发生了偏移。 相似文献
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《矿物学报》2013,(3)
滇中楚雄盆地砂岩型铜矿床,如大姚六苴铜矿床,赋存于上白垩统马头山组六苴下亚段(K2mml1)紫色砂岩与浅色砂岩过渡带靠近浅色一侧,铜矿化受氧化还原界面控制。从紫色砂岩向浅色砂岩,金属矿物依次呈现赤铁矿→辉铜矿→斑铜矿→黄铜矿→黄铁矿的水平分带规律。以矿物分带中的金属矿物为主要研究对象,结合流体包裹体测试成果,构建和绘制了大姚六苴铜矿床主要成矿温度下的pH-Eh相图,理论计算结果与宏观地质特征吻合。依据pH-Eh相图,阐述了主要金属矿物的沉淀条件及其分带机理,认为楚雄盆地砂岩铜矿床金属矿物分带受pH和Eh双重控制;在373～523 K间温度变化对金属矿物沉淀的pH和Eh影响不大;S2-只能在低于473 K下的热液中稳定存在,辉铜矿(Cu2S)形成温度低于473 K。该研究为该类矿床成矿机制研究提供了重要依据。 相似文献
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云南六苴砂岩型铜矿床地球化学异常模式 总被引：5，自引：0，他引：5
云南六苴铜矿床是楚雄陆相红层盆地砂(页)岩型铜矿的典型代表.矿体(平均品位1.34%)赋存于K2ml1中紫色砂岩与浅色砂岩交互带,从紫色砂岩到浅色砂岩,依次呈现赤铁矿、辉铜矿、斑铜矿、黄铜矿、黄铁矿水平分带.采集9个钻孔岩芯样品,分析其主元素与微量元素地球化学异常特征,指示成矿元素组合为Cu-Ag-As-Sb-Hg.K2ml1中铜矿体,从上至下具有v-Ni-Cu-Ag-Hg-(As-Sb)-Pb-(Zn)-V-(Ni)垂向分带;由西(全紫带)至东(全浅带)具有Sb-Hg-v-Cu-As-Sb-Ag-Co-Ni-Pb-Zn横向分带.通过不同剖面地球化学异常特征对比,建立矿床的地球化学异常模式:Co-Ni-V组合异常位于矿体上方,Pb-Zn组合异常位于矿体下方,矿体处元素组合异常为Cu-Ag-As-Sb-Hg.出现Cu-Ag-As-Sb-Hg组合异常,Cu/Ag>315、Cu/(Pb Zn)>320、Cu/(As sb Hg)为1000-5800时,矿体较富,品位稳定;出现Pb-Zn-Co-(Ni)组合异常,Cu/Ag<105、Cu/(Pb Zn)<7、Cu/(As Sb Hg)<36时无矿;出现Sb-Hg-V组合异常,Cu/(As Sb Hg)>5800时则无矿.Cu、Ag、As、Sb、Hg含量及元素对比值沿矿床走向从北向南降低,预示"矿化能力"减弱或矿体中心位置偏移.该地球化学异常模式为深部成矿预测提供了重要依据. 相似文献
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《矿产与地质》2017,(2)
纳雍枝铅锌矿床位于五指山背斜南东翼,矿体产于下寒武统清虚洞组白云岩中,矿石矿物以闪锌矿为主。利用ICP-MS对矿床矿石、矿化岩石及围岩的微量及稀土元素进行测试,结果显示,矿石中以富集As、Cd、Sb、Bi、Ge、Mo、Sn、Cs、Tl等微量元素,亏损V、Cr、Co、Cu、Rb、Sr、Nb、Ba、Ta等元素。分散元素Ga、Ge、Cd富集与Zn、As呈正相关,说明流体本身富含该类元素。Ga/In值及矿石产出状态指矿床是中低温热液成因。矿石、矿化白云岩及围岩的稀土配分模式相似,均以Eu负异常为特征,不同矿石类型之间富集元素类型及富集程度差别较大,认为该矿床成矿物质可能来源于含矿地层本身和下伏的灯影组地层及深部基底。 相似文献
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铜陵狮子山矿田金矿床和铜矿床矿石稀土元素地球化学 总被引：5，自引：0，他引：5
在全面收集前人有关安徽铜陵狮子山矿田主要矿床矿石和蚀变岩石稀土元素分析结果的基础上,对比研究了矿田内金矿床和铜矿床的稀土元素地球化学特征。研究表明,金矿床和铜矿床矿石和蚀变岩石的稀土元素组成、轻重稀土比值和(La/Yb)N 值等特征参数承袭了矿区岩浆岩的特征,显示成矿物质的来源以岩浆来源为主,富集地壳组分,反映在成矿过程中深部热液对已固结岩浆岩的淋滤萃取作用和对沉积围岩的叠加改造作用,成矿作用与岩浆作用密切相关;不同成矿阶段和不同类型矿石或蚀变岩石的REE 特征反映REE 的来源和演化可能与成矿金属元素的来源及其富集成矿机制相一致。此外,金矿床和铜矿床矿石稀土元素地球化学行为亦显示出明显的差异性,铜矿床矽卡岩阶段矿石比石英硫化物阶段矿石相对低的REE 含量,以及部分矽卡岩矿石具有La,Ce 明显亏损的富集LREE 折线型配分模式,反映铜矿床这部分矽卡岩具有岩浆成因的特征;而金矿床和部分铜矿床中的矽卡岩及矽卡岩型矿石则以热液交代成因为主;金矿床和铜矿床Eu异常特征则反映了其成矿热液流体起源压力的差异及流体性质的阶段性演化。 相似文献
8.
天鹿铜矿床是古生代海相砂页岩型铜矿.其铜矿石主要为粉砂岩型,包括斑铜矿矿石、辉铜矿矿石、辉铜矿斑铜矿矿石、黄铜矿斑铜矿矿石、黄铜矿矿石、黄铁矿黄铜矿矿石等6种自然类型.矿石结构主要为结晶结构和交代结构,矿石构造以浸染状为主.主矿层中的矿化沿岩层垂向具有明显的分带性,从底部到顶板为:斑铜矿→辉铜矿→黄铜矿→黄铁矿,具有典型的化学沉积成因铜的硫化物排列组合特征.这些特点与中国及国外海相砂页岩型铜矿相一致. 相似文献
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六苴砂岩铜矿是滇中中生代红层中的几种沉积铜矿床类型之一.滇中中生代红层为河湖交替相的沉积岩层,六苴矿床发育于白垩系马头山组红层所夹的浅色岩层中,而这浅色砂岩部分常具有明显的流动水沉积的特征.有关该矿床形成的岩相古地理分析,已有一些文章论述,这里试图结合野外观察和室内岩矿鉴定,着重从另一个侧面——岩石和矿石的胶结物方面,来讨论成矿作用,不妥之处,敬请指正.成矿作用和矿床形成后所经历的过程是一个复杂的过程.遵照毛主席关于抓主要矛盾的教导,我们认为六苴砂岩铜矿的岩石和矿石都是由碎屑和胶结物所组成,二者的区别主要不在于碎屑组分,而在于胶结物的组成.金属矿物就是岩石和矿石的胶结物成分之一,也由于金属矿物含量的差别而显示了岩石和矿石的不同,有时甚至是两者唯一的不同.因此,研究 相似文献
10.
楚雄盆地砂岩铜矿床同位素特征及矿床成因 总被引：6，自引：1，他引：6
楚雄盆地砂岩铜矿形成于白垩系高峰寺组凹地苴段、马头山组六苴段和大村段,以六苴、郝家河及大村铜矿床为代表。不论是硫同位素,还是氢氧同位素、铅同位素,六苴铜矿床和郝家河铜矿床均不相同。六苴铜矿硫化物中的硫以来自围岩为主,成矿溶液来自上部天水和建造水,成矿金属物质来自围岩,推测成岩成矿作用是主要矿化机制。而郝家河铜矿,成矿物质更多的是来自地下深处,与深部地下水循环作用有关,表明郝家河铜矿床以改造成矿为主。 相似文献
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Influences of the unsaturated,saturated, and riparian zones on the transport of nitrate near the Merced River,California, USA 总被引：1，自引：0，他引：1
Joseph L. Domagalski Steven P. Phillips E. Randall Bayless Celia Zamora Carol Kendall Richard A. WildmanJr Janet G. Hering 《Hydrogeology Journal》2008,16(4):675-690
Transport and transformation of nitrate was evaluated along a 1-km groundwater transect from an almond orchard to the Merced River, California, USA, within an irrigated agricultural setting. As indicated by measurements of pore-water nitrate and modeling using the root zone water quality model, about 63% of the applied nitrogen was transported through a 6.5-m unsaturated zone. Transport times from recharge locations to the edge of a riparian zone ranged from approximately 6 months to greater than 100 years. This allowed for partial denitrification in horizons having mildly reducing conditions, and essentially no denitrification in horizons with oxidizing conditions. Transport times across a 50–100-m-wide riparian zone of less than a year to over 6 years and more strongly reducing conditions resulted in greater rates of denitrification. Isotopic measurements and concentrations of excess N2 in water were indicative of denitrification with the highest rates below the Merced River. Discharge of water and nitrate into the river was dependent on gradients driven by irrigation or river stage. The results suggest that the assimilative capacity for nitrate of the groundwater system, and particularly the riverbed, is limiting the nitrate load to the Merced River in the study area. 相似文献
12.
山西五台山区滹沱群变质玄武岩岩石学、地球化学特征及其成因意义 总被引：10，自引：0，他引：10
在野外地质调查的基础上,选取滹沱群豆村亚群底部四集庄组玄武岩、顶部青石村组玄武岩和东冶亚群中下部河边村组玄武岩,进行岩石学和地球化学研究。分析结果表明：玄武岩主量元素高TiO2、TFeO,低MgO,具有演化的基性岩浆的特征。稀土元素含量相对较高,具有弱—中等程度的轻稀土元素富集,中等程度的轻重稀土元素分异,轻微的Eu异常;玄武岩中Cr、Ni含量变化较大,但与Mg#具有很好的正相关性。微量元素配分图解中具有明显的Sr负异常,部分样品具有Nb、Ta和Ti负异常,无Zr、Hf负异常,与岛弧火山岩不同;同时Nb、Ta无分异,Zr/Hf值较高,具有板内玄武岩浆的特征。综合分析认为,滹沱群玄武岩可能形成于板内裂谷环境。在岩浆上升过程中发生橄榄石与尖晶石的分离结晶作用,同时不同程度地受到地壳的混染。 相似文献
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扬子北缘马元铅锌矿床闪锌矿微量元素及S-Pb-He-Ar-C同位素地球化学研究 总被引：7，自引：3，他引：4
马元铅锌矿床是近年扬子陆块北缘铅锌找矿的新突破。矿体呈层状、似层状产于碑坝隆起翼部震旦系灯影组角砾状白云岩层间构造带中,围岩蚀变很弱。矿石中硫化物以闪锌矿、方铅矿为主,中粗粒晶质结构,充填于白云岩角砾间。闪锌矿富集Cd、Ge、Ag,贫In、Tl、Se,Ga/In为6~132,Ge/In多1000,成矿温度以中-低温为主。金属硫化物ε~(34)S值相对集中,为12.9‰~19.4‰,平均为17.4‰,来自于海相硫酸盐的还原。铅同位素组成稳定,~(206)Pb/~(204)Pb为17.858~17.918:~(207)Pb/~(204)Pb为15.603~15.694;~(208)Pb/~(204)Pb为37.756~38.046,具有造山带和上地壳铅的特征,震旦系可能提供了金属成矿物质。闪锌矿中流体包裹体的~3He/~4He为0.03Ra~1.05Ra,~(40)Ar/~(36)Ar为326.1~765.1,~(38)Ar/~(36)Ar为0.183~0.204,表明成矿流体主要为地壳流体和饱和大气水(大气降水或海水)的混合。闪锌矿内流体包裹体挥发分δ~(13)C_(CH_4)值为-36.01‰~-28.80‰,δ~(13)C_(C_2H_6)值为-27.72‰~-22.44‰,δ~(13)C_(CO_2)值为-23.24‰~-9.68‰,表明有机流体参与了成矿作用。石英、方解石的H-O同位素结果表明具有海水和有机水混合的特征。可见,成矿流体具有两种流体混合的特征,一为蒸发海水与围岩反应所形成的盆地卤水,二为有机流体。推测矿区可能存在一个古油气藏,由于TSR生成一高硫气藏,为区内还原性有机流体的主要来源。当富含Pb、Zn等成矿物质的成矿流体运移至富含CH_4和H_2S的还原性流体的矿区角砾岩带时,两种流体混合,Pb、Zn等遇到H_2S发生反应而沉淀成矿,并伴生热液白云石等,形成了马元铅锌矿床。综上所述,我们认为马元矿床属MVT型铅锌矿床。 相似文献
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以出露在西藏南木林县秦马弄地区二长花岗岩体为研究对象,从野外地质调查、岩石学、LA-ICP-MS锆石U-Pb定年、元素和Lu-Hf同位素地球化学等方面对其进行了分析研究。结果显示：秦马弄地区二长花岗岩体类似于A型花岗岩,形成于古近纪(E1),其LA-ICP-MS锆石U-Pb年龄为(62.0±0.5)~(63.0±0.5) Ma;岩体形成的温度较高(锆石饱和温度为745~805 ℃,平均766 ℃);岩石富SiO2(72.6%~75.0%)、Na2O(2.86%~3.59%)和K2O(4.12%~5.25%),贫CaO(0.72%~1.39%)和MgO(0.26%~0.36%),高FeOT/MgO值(7.26~10.3),属高钾钙碱性系列,弱过铝质;岩石具明显的负Eu异常(Eu/Eu*=0.40~0.70),普遍表现出Ba、Sr、P、Ti元素的亏损和Rb、Th、K、Zr、Hf元素的富集。εHf(t)值为-4.7~-1.8,其两阶段地壳Hf模式年龄tDM2为(1.1~1.3) Ga。秦马弄A型花岗岩体是冈底斯基底地壳物质部分熔融的岩浆产物,形成于古近纪印度板块与欧亚板块俯冲碰撞引起的总体为岛弧背景下的局部拉张构造环境。 相似文献
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E. M. Prasolov S. A. Sergeev B. V. Belyatsky E. S. Bogomolov K. A. Gruzdov I. N. Kapitonov R. Sh. Krymsky V. O. Khalenev 《Geochemistry International》2018,56(1):46-64
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others. 相似文献
18.
I. A. Tararin V. M. Chubarov E. K. Ignat’ev S. V. Moskaleva 《Russian Journal of Pacific Geology》2007,1(1):82-97
The geology and mineralogy of host metamorphic rocks, the mineralogy of sulfide ores, and the distribution of PGE mineralization were studied in detail for the Kvinum-1 and Kvinum-2 copper-nickel occurrences of the Kvinum ore field, which are the most promising targets for the copper-nickel-PGE mineralization of the Sredinny Range of Kamchatka. It was established that stringer-disseminated and massive copper-nickel ores are localized in amphibole peridotites, cortlandites, and form ore bodies varying from tens of centimeters to 5–20 m thick among the layered cortlandite-gabbroid massifs. The massive sulfide ores were found only at the bottom of cortlandite bodies and upsection grade into stringer-disseminated and disseminated ores. Pyrrhotite, chalcopyrite, and pentlandite are the major ore minerals with a sharply subordinate amount of pyrite, sphalerite, galena, arsenopyrite, and löllingite. Besides pentlandite, the Ni-bearing minerals include sulforasenides (gersdorffite), arsenides (nickeline), and tellurides (melonite) of nickel. It was found that PGE mineralization represented by antimonides (sudburyite) and tellurobismuthides (michenerite) of Pd with sharply subordinate platinum arsenide (sperrylite) is confined to the apical parts of massive sulfide zones and the transition zone to the stringer-disseminated ores. Ore intervals enriched in arsenides and tellurides of Ni, Pd, and Bi contain high-purity gold. In the central parts of the orebodies, the contents of PGE and native gold are insignificant. It is suggested that the contents of major sulfide minerals and the productivity of PGE mineralization in the cortlandites are defined by combined differentiation and sulfurization of ultramafic derivatives under the effect of fluids, which are accumulated at the crystallization front and cause layering of parental magmas with different sulfur contents. The fluid-assisted layering of mafic-ultramafic massifs resulted in the contrasting distribution of PGM in response to uneven distribution of sulfur (as well as As, Te, and Bi) during liquid immiscibility. The productivity of PGE mineralization significantly increases with increasing contents of S, As, Te, and Bi (elements to which Pt and, especially, Pd have high affinity) in fluids. 相似文献
19.
A geophysical survey was conducted to determine the depth of the base of the water-table aquifer in the southern part of
Jackson Hole, Wyoming, USA. Audio-magnetotellurics (AMT) measurements at 77 sites in the study area yielded electrical-resistivity
logs of the subsurface, and these were used to infer lithologic changes with depth. A 100–600 ohm-m geoelectric layer, designated
the Jackson aquifer, was used to represent surficial saturated, unconsolidated deposits of Quaternary age. The median depth
of the base of the Jackson aquifer is estimated to be 200 ft (61 m), based on 62 sites that had sufficient resistivity data.
AMT-measured values were kriged to predict the depth to the base of the aquifer throughout the southern part of Jackson Hole.
Contour maps of the kriging predictions indicate that the depth of the base of the Jackson aquifer is shallow in the central
part of the study area near the East and West Gros Ventre Buttes, deeper in the west near the Teton fault system, and shallow
at the southern edge of Jackson Hole. Predicted, contoured depths range from 100 ft (30 m) in the south, near the confluences
of Spring Creek and Flat Creek with the Snake River, to 700 ft (210 m) in the west, near the town of Wilson, Wyoming.
Received, May 1997 · Revised, February 1998 · Accepted, April 1998 相似文献