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1.
Activity ratios of 234U/238U, 230Th/234U, and 230Th/232Th have been determined for calcite, gypsum and halite speleothems from caves of the Nullarbor Plain, mostly in the area N and NW of Mundrabilla Station, for the purpose of U-series dating. All calcite speleothems contain adequate amounts of uranium for dating, but some show an excess of 230Th. Stratigraphic relationships indicate that there were at least three phases of calcium carbonate deposition in the Nullarbor caves. The calcite samples, with one possible exception, have ages in excess of ca. 400000 yrs BP. This suggests that no significant amounts of calcium carbonate deposition have taken place during the last 400ka. At present, active deposition of speleothems is restricted almost entirely to gypsum and halite. The only gypsum speleothem dated was found to have a finite age of ca. 185 ka. Six dates on a small halite speleothem containing insect and arachnid remains indicate that it formed rapidly during Holocene time.  相似文献   

2.
The Mawsmai cave and Krem Phyllut caves, East Khasi hills, Meghalaya, India has so far not yet attracted the attention of geomicrobiologists. Observations and hypotheses on the possible influence of identified microorganisms for speleothem formations in Meghalaya are reported for the first time. XRD studies identified calcite in speleothems and gypsum in cave wall deposits as the dominant minerals. SEM-EDAX showed interesting microfabric features showing strong resemblance with fossilised bacteria, calcified filaments, needle calcite and numerous nano scale calcite crystals, highly weathered and disintegrated crystals of calcite, that point towards a significant microbial influence in its genesis. Thin section petrography showed laminated stromatolitic features. The microorganisms identified by conventional isolation and further evaluation of isolates by molecular techniques include Bacillus cereus, Bacillus mycoides, Bacillus licheniformis, Micrococcus luteus, and Actinomycetes. Microscopic observations also showed unidentifiable cocci and four unidentifiable strains of CaSO4 (gypsum) precipitating bacteria. Experimental studies confirmed that these bacteria are able to precipitate calcium minerals (calcite, gypsum, minor amounts of dolomite) in the laboratory. These results allow us to postulate that species like these may contribute to active biogenic influence in the cave formations at Meghalaya.  相似文献   

3.
Carbon isotopes in speleothems can vary in response to a number of complex processes active in cave systems that are both directly and indirectly related to climate. Progressing downward from the soil zone overlying the cave, these processes include soil respiration, fluid-rock interaction in the host limestone, degassing of CO2 and precipitation of calcite upflow from the speleothem drip site, and calcite precipitation at the drip site. Here we develop a new approach to independently constrain the roles of water-rock interaction and soil processes in controlling stalagmite δ13C. This approach uses the dead carbon proportion (dcp) estimated from coupled 14C and 230Th/U measurements, in conjunction with Sr isotope analyses on stalagmite calcite from a central Sierra Nevada foothills cave in California, a region characterized by a highly seasonal Mediterranean-type climate, to determine the roles of water-rock interaction and soil processes in determining stalagmite δ13C. Increases in stalagmite dcp between 16.5 and 8.8 ka are coincident with decreased δ13C, indicating a varying yet substantial contribution from the soil organic matter (SOM) reservoir, likely due to significantly increased average age of SOM in the soil veneer above the cave during wet climatic intervals.We use geochemical and isotope mixing models to estimate the host-carbonate contribution throughout the δ13C time series and determine the degree of degassing and calcite precipitation that occurred prior to precipitation of stalagmite calcite. The degree of degassing and prior calcite precipitation we calculate varies systematically with other climate indicators, with less degassing and prior calcite precipitation occurring during wetter climatic intervals and more during drier intervals. Modeled δ13C values and degassing calculations suggest that some degree of prior calcite precipitation is necessary at all time intervals to explain measured stalagmite δ13C values, even during relatively wet intervals. These results illustrate the importance of constraining degassing and prior calcite precipitation in the interpretation of speleothem δ13C records, particularly those from caves that formed in seasonal semi-arid to arid environments.  相似文献   

4.
洞穴碳酸盐有机质荧光发光特征研究及其展望   总被引：1，自引：1，他引：0  
洞穴碳酸盐是洞穴滴水沉淀的结果,其有机质的荧光性质响应于外界气候与生态环境的高频率、周期性变化,是高分辨率反映气候- 环境变化的有效手段。本文详细分析了洞穴碳酸盐荧光物质的组成、来源及影响其荧光光谱的因素,并总结了其分析方法; 回顾了国内外在洞穴碳酸盐荧光发光性的古气候- 环境研究方面的应用,并对其将来的发展方向作了展望; 认为洞穴碳酸盐发光微层及其光谱特征形成机制的现代过程、微层层内物质组成,以及土壤、植被、气候三者响应关系是值得今后进一步加强研究的主要内容。   相似文献   

5.
重庆丰都雪玉洞群包括羊子洞、雪玉洞和水鸣洞,西南大学的研究团队从2008年开始对雪玉洞群开展了系统的现代过程监测,以了解洞穴系统气候和环境信息的传输、转化和记录过程。通过对雪玉洞洞穴内外的大气、植被、土壤、基岩、滴水和洞穴沉积物等的动态监测,研究了碳酸盐沉积过程的水化学指标变化,揭示了现代洞穴滴水的影响因素和变化过程,以及碳酸盐沉积物对现代气候环境变化的响应,也为古气候的定量化研究提供了基础支撑。现代过程监测记录表明:雪玉洞CO2主要来源于上覆土壤,其季节变化受降水的影响较大;在短时间尺度上受到游客旅游活动的影响明显,但幅度远远小于自然过程引起的变化。雪玉洞内次生沉积物的沉积速率具有明显的旱季、雨季特征,不同滴水点下方沉积物的沉积速率变化较大。雪玉洞群三个洞穴的石笋古环境记录研究表明,本区石笋的230Th/232Th比值较适合高精度铀系测年;部分石笋沉积速率较快,平均沉积速率达到0.25 mm·a?1,可以开展高分辨率的气候和环境变化研究。羊子洞YZ1石笋的年龄范围在116~3 ka B.P.之间（平均测年精度2σ,269年）,覆盖了整个末次冰期,δ18O和δ13C的变化曲线和东亚季风区的其他记录具有明显的一致性。同位素测试的时间分辨率平均为88年,成功记录了一些百年－千年尺度的气候突变事件,如Heinrich事件、7.2 ka事件、小冰期等。在精确年代学的基础上,雪玉洞群石笋具有重建高分辨率气候环境变化的潜力。   相似文献   

6.
The Cretaceous was one of the most remarkable ‘greenhouse' climate periods in geological history. Most of the reported studies of the Cretaceous paleoclimate are based upon marine sedimentary records. Large spatial scale paleoclimatic reconstruction, which has a higher time resolution based upon continental sediments in China, is rarely found. This study presents paleoclimate reconstruction for the six time periods of the Early Cretaceous in China by employing continental climate-indicative sediments, including calcareous deposits, coal, oil shale, gypsum, halite, desert sedimentary systems, ferruginous deposits and laterite, copper-bearing deposits, limestone and dolomite. Based on the distribution of the association of climate-indicative sediments and the influences of paleotopography and orogenic belts(or important structural belts) on climate, seven climatic zones have been identified: 1) a warm and humid zone; 2) a warm and humid-warm and arid zone; 3) a warm and arid zone; 4) an arid and hot zone; 5) the Tibet hot and humid zone; 6) a hot and arid-semiarid zone; and 7) a hot and humid-hot and arid one. It is found that the Early Cretaceous climatic zones of China were nearly latitudinally distributed from northwest to southeast. The aridhot climatic zone expanded in the Aptian, suggesting that a hotter and drier climate prevailed in later period of the Early Cretaceous. Conversely, the humid climatic zone expanded in the Albian, indicating that a wetter climate appeared at the end of the Early Cretaceous. The overall distribution pattern of the seven climatic zones indicates that a hot-warm and arid climate was predominant in China; this coincides with a global ‘greenhouse climate' background. However, palaeogeographic features and specific geologic events, such as the existence and disappearance of the eastern high plateau, and the uplift and denudation of Yinshan, Yanshan, Tianshan, Qinling and Dabie Mountains, led to distinctive regional climatic features of the Cretaceous in China.  相似文献   

7.
The Pleistocene speleothems of Sa Bassa Blanca cave, Mallorca, are excellent indicators of palaeoclimate variations, and are samples that allow evaluation of the products and processes of mixing‐zone diagenesis in an open‐water cave system. Integrated stratigraphic, petrographic and geochemical data from a horizontal core of speleothem identified two main origins for speleothem precipitates: meteoric‐marine mixing zone and meteoric‐vadose zone. Mixing‐zone precipitates formed at and just below the water–air interface of cave pools during interglacial times, when the cave was flooded as a result of highstand sea‐level. Mixing‐zone precipitates include bladed and dendritic high‐Mg calcite, microporous‐bladed calcite with variable Mg content, and acicular aragonite; their presence suggests that calcium‐carbonate cementation is significant in the studied mixing‐zone system. Fluid inclusion salinities, δ13C and δ18O compositions of the mixing‐zone precipitates suggest that mixing ratio was not the primary control on whether precipitation or dissolution occurred, rather, the proximity to the water table and degassing of CO2 at the interface, were the major controls on precipitation. Thus, simple two‐end‐member mixing models may apply only in mixing zones well below the water table. Meteoric‐vadose speleothems include calcite and high‐Mg calcite with columnar and bladed morphologies. Vadose speleothems precipitated during glacial stages when sea level was lower than present. Progressive increase in δ13C and δ18O of the vadose speleothems resulted from cooling temperatures and more positive seawater δ18O associated with glacial buildup. Such covariation could be considered as a valid alternative to models predicting invariant δ18O and highly variable δ13C in meteoric calcite. Glacio‐eustatic oscillations of sea‐level are recorded as alternating vadose and mixing‐zone speleothems. Short‐term climatic variations are recorded as alternating aragonite and calcite speleothems precipitated in the mixing zone. Fluid‐inclusion and stable‐isotope data suggest that aragonite, as opposed to calcite, precipitated during times of reduced meteoric recharge.  相似文献   

8.
Arabia is an important potential pathway for the dispersal of Homo sapiens (“out of Africa”). Yet, because of its arid to hyper-arid climate humans could only migrate across southern Arabia during pluvial periods when environmental conditions were favorable. However, knowledge on the timing of Arabian pluvial periods prior to the Holocene is mainly based on a single and possibly incomplete speleothem record from Hoti Cave in Northern Oman. Additional terrestrial records from the Arabian Peninsula are needed to confirm the Hoti Cave record. Here we present a new speleothem record from Mukalla Cave in southern Yemen. The Mukalla Cave and Hoti Cave records clearly reveal that speleothems growth occurred solely during peak interglacial periods, corresponding to Marine Isotope Stages (MIS) 1 (early to mid-Holocene), 5.1, 5.3, 5.5 (Eemian), 7.1, 7.5 and 9. Of these humid periods, highest precipitation occurred during MIS 5.5 and lowest during early to middle Holocene.  相似文献   

9.
洞穴沉积物—石笋已成为研究岩溶区环境气候变化历史的重要载体。在我国湘西地区,某些洞穴石笋原始沉积多为不稳定的文石矿物,极易发生重结晶,可能使石笋中相关化学元素含量最终偏离原生矿物的特征,限制了文石石笋某些代用指标在古气候研究中的应用。文章以前人研究成果为基础,总结梳理了文石石笋发生重结晶的影响因素及其对石笋记录古气候的影响:（1）石笋剖面特征、XRD结果、显微镜观察和地球化学元素特征等可作为石笋发生重结晶的判别依据;（2）洞穴滴水和石笋孔隙水饱和度、文石晶体缺陷和晶体之间的方解石胶结物以及岩溶水体中Mg2+浓度等均会影响文石石笋的矿物转变;（3）在文石向方解石转变过程中,石笋铀含量会有一定程度的流失,可导致放射性铀系定年的异常或年代倒序;（4）矿物重结晶可导致δ18O、δ13C及石笋微量元素浓度（或比值）等指标发生改变,其变化特征因洞穴而异,从而影响其作为环境指示器的可靠性;（5）湖南龙山惹迷洞石笋（RM2）发生了不均一的矿物重结晶,自顶部至20.3 cm以放射状为主,20.3 cm至底部主要为糖粒状,并结合年代结果发现文石重结晶对石笋铀系定年产生了影响,而重结晶作用对该石笋其他指标的影响还有待进一步研究。   相似文献   

10.
Variations in speleothem oxygen-isotope values (δ18O) result from a complicated interplay of environmental controls and processes in the ocean, atmosphere, soil zone, epikarst, and cave system. As such, the controls on speleothem δ18O values are extremely complex. An understanding of the processes that control equilibrium and kinetic fractionation of oxygen isotopes in water and carbonate species is essential for the proper interpretation of speleothem δ18O as paleoclimate and paleoenvironmental proxies, and is best complemented by study of site-specific cave processes such as infiltration, flow routing, drip seasonality and saturation state, and cave microclimate, among others. This review is a process-based summary of the multiple controls on δ18O in the atmosphere, soil, epikarst, and speleothem calcite, illustrated with case studies. Primary controls of δ18O in the atmosphere include temperature and relative humidity through their role in the multiple isotope “effects”. Variability and modifications of water δ18O values in the soil and epikarst zones are dominated by evaporation, mixing, and infiltration of source waters. The isotopically effective recharge into a cave system consists of those waters that participate in precipitation of CaCO3, resulting in calcite deposition rates which may be biased to time periods with optimal dripwater saturation state. Recent modeling, experimental, and observational data yield insight into the significance of kinetic fractionation between dissolved carbonate phases and solid CaCO3, and have implications for the ‘Hendy’ test. To assist interpretation of speleothem δ18O time series, quantitative and semi-quantitative δ18O-climate calibrations are discussed with an emphasis on some of the difficulties inherent in using modern spatial and temporal isotope gradients to interpret speleothems as paleoclimate proxy records. Finally, several case studies of globally significant speleothem paleoclimate records are discussed that show the utility of δ18O to reconstruct past climate changes in regions that have been typically poorly represented in paleoclimate records, such as tropical and subtropical terrestrial locations. The new approach to speleothem paleoclimatology emphasizes climate teleconnections between regions and attribution of forcing mechanisms. Such investigations allow paleoclimatologists to infer regional to global-scale climate dynamics.  相似文献   

11.
This paper presents the results of morphological and microclimatic surveys and speleothem analyses of ten karst caves located in different isles in Ha Long Bay, a famous tourist attraction in Vietnam. Characteristically, the caves have enormous entrances, roomy interiors, but short length, typical of karst caves in tropical climates. The cave microclimate was found to be significantly dependent on the outside atmosphere and human activities. There was a clear spatial variation in macro features and fabrics of speleothems from entrance (porous, microcrystalline) to rear (solid, macrocrystalline) of the caves. Microstructure analysis with the use of an environmental scanning electron microscope shows a gradual decrease of biological activity and microclimate instability from outside to the innermost parts of the caves are the causes for this spatial variation. Past and present deterioration of caves and speleothems directly due to tourist activities and vandalism has been observed. On the other hand, there are signs of speleothem regrowth in the caves where tourism has been stopped. This study has proved that caves and their speleothems in Ha Long Bay are highly dynamic and understanding of their environment requires immediate methodological attention. Based on the analytical results, it is recommended that regulation of visitor frequency and removal of lamp-flora are necessary for sustainable development of the show caves and their speleothems.  相似文献   

12.
A 4-year study in a central Texas cave quantifies multiple mechanisms that control dripwater composition and how these mechanisms vary at different drip sites. We monitored cave-air compositions, in situ calcite growth, dripwater composition and drip rate every 4-6 weeks. Three groups of drip sites are delineated (Groups 1-3) based on geochemical variations in dripwater composition. Quantitative modeling of mineral-solution reactions within the host carbonate rock and cave environments is used to identify mechanisms that can account for variations in dripwater compositions. The covariation of Mg/Ca (and Sr/Ca) and Sr isotopes is key in delineating whether Mg/Ca and Sr/Ca variations are dictated by water-rock interaction (i.e., calcite or dolomite recrystallization) or prior calcite precipitation (PCP). Group 1 dripwater compositions reflects a narrow range of the extent of water-rock interaction followed by varying amounts of prior calcite precipitation (PCP). Group 2 dripwater compositions are controlled by varying amounts of water-rock interaction with little to no PCP influence. Group 3 dripwater compositions are dictated by variable extents of both water-rock interaction and PCP. Group 1 drip sites show seasonal variations in dripwater Mg/Ca and Sr/Ca, whereas the other drip sites do not. In contrast to the findings of most previous dripwater Mg/Ca-Sr/Ca studies, these seasonal variations (at Group 1 drip sites) are independent of changes in water flux (i.e., rainfall and/or drip rate), and instead significantly correlate with changes in cave-air CO2 concentrations. These results are consistent with lower cave-air CO2, related to cool season ventilation of the cave atmosphere, enhancing calcite precipitation and leading to dripwater geochemical evolution via PCP. Group 1 dripwater Mg/Ca and Sr/Ca seasonality and evidence for PCP as a mechanism that can account for that seasonality, have two implications for many other regions where seasonal ventilation of caves is likely: (1) speleothem trace-element records may provide seasonal signals, and (2) such records may be biased toward recording climate conditions during the season when calcite is depositing. Additionally, we use our results to construct a forward model that illustrates the types of speleothem Mg/Ca and Sr/Ca variations that would result from varying controls on dripwater compositions. The model provides a basis for interpreting paleo-dripwater controls from high frequency Mg/Ca and Sr/Ca variations for speleothems from caves at which long term monitoring studies are not feasible.  相似文献   

13.
The oxygen isotope composition of speleothems is an important proxy of continental paleoenvironments, because of its sensitivity to variations in cave temperature and drip water δ18O. Interpreting speleothem δ18O records in terms of absolute paleotemperatures and δ18O values of paleo-precipitation requires quantitative separation of the effects of these two parameters, and correcting for possible kinetic isotope fractionation associated with precipitation of calcite out of thermodynamic equilibrium. Carbonate clumped-isotope thermometry, based on measurements of Δ47 (a geochemical variable reflecting the statistical overabundance of 13C18O bonds in CO2 evolved from phosphoric acid digestion of carbonate minerals), potentially provides a method for absolute speleothem paleotemperature reconstructions independent of drip water composition. Application of this new technique to karst records is currently limited by the scarcity of published clumped-isotope studies of modern speleothems. The only modern stalagmite reported so far in the literature yielded a lower Δ47 value than expected for equilibrium precipitation, possibly due to kinetic isotope fractionation.Here we report Δ47 values measured in natural speleothems from various cave settings, in carbonate produced by cave precipitation experiments, and in synthetic stalagmite analogs precipitated in controlled laboratory conditions designed to mimic natural cave processes. All samples yield lower Δ47 and heavier δ18O values than predicted by experimental calibrations of thermodynamic equilibrium in inorganic calcite. The amplitudes of these isotopic disequilibria vary between samples, but there is clear correlation between the amount of Δ47 disequilibrium and that of δ18O. Even pool carbonates believed to offer excellent conditions for equilibrium precipitation of calcite display out-of-equilibrium δ18O and Δ47 values, probably inherited from prior degassing within the cave system.In addition to these modern observations, clumped-isotope analyses of a flowstone from Villars cave (France) offer evidence that the amount of disequilibrium affecting Δ47 in a single speleothem can experience large variations at time scales of 10 kyr. Application of clumped-isotope thermometry to speleothem records calls for an improved physical understanding of DIC fractionation processes in karst waters, and for the resolution of important issues regarding equilibrium calibration of Δ47 in inorganic carbonates.  相似文献   

14.
Speleothems occurring in some caves of the carbonate Dinarides line all channel surfaces, and have been deposited from meteoric waters under phreatic conditions. Such phreatic speleothemic deposition modifies common experience (l) that meteoric phreatic conditions cause dissolutional widening of cave voids, and (2) that speleothems imply vadose conditions. The phreatic speleothems described here postdate an early polygenetic evolution of the cave voids, and predate the last, vadose stage. They were likely produced during the late/postglacial warming period, when dissolved carbonate was amply supplied, and when there was much water available for saturation of underground voids. Phreatic speleothems may be used as a tool for time correlation of internal deposits, both within one cave and within a karst region. They indicate an important stage in the history of the ground-water regime of an area. In general, phreatic speleothems help in better understanding of the development of subterranean voids and related karst/palaeokarst.  相似文献   

15.
Speleothems, mostly composed of calcium carbonate, are widely present in modern karst‐originated caves, but have rarely been reported in palaeokarst systems. This study presents a novel type of dolomite speleothem and subsequent submarine dolomite cement, which are widely present in the upper Ediacaran Dengying Formation in the upper Yangtze area. These precipitated materials occur in the cavity system that cuts across several peritidal cycles. The interconnected cavity networks with irregular shapes, embayed walls, internal breccias on cavity floor and their preferential development in the shallower cycle tops (for example, tepee‐deformed beds) suggest that they were initially generated by subaerial dissolution. As the earliest infills, the hemispherical protrusions, icicle‐like pendants and ground‐up columns show similar morphological features and occurrence patterns to the cave popcorn, stalactites and stalagmites, respectively. Thus, these earliest infills are speleothems resulting from associated meteoric precipitation during subaerial exposure. The isopachous growth pattern of subsequent more extensive fibrous dolomite cements points to a submarine diagenetic environment in which they were precipitated. Microscopically, the micritic to micro‐crystalline dolomite, acicular dolomite in speleothems and the subsequent fibrous dolomite share similar crystal fabrics to metastable precursors (for example, Mg‐calcite). Meanwhile, the carbon‐oxygen isotope compositions of the speleothem and fibrous dolomite, although partly altered by burial diagenesis, share a large overlap with host rock and coeval marine carbonates all over the Yangtze Platform. For these reasons, these speleothems and fibrous cements are considered to have been initially precipitated as metastable carbonate precursors in meteoric and submarine environments, respectively, and stabilized during submarine mimetic dolomitization. The cyclic occurrence of cavity systems filled with speleothems and submarine cements reflects periodic subaerial exposure and marine flooding of broad tidal flat in the upper Yangtze area, driven by high‐frequency sea‐level fluctuations. Furthermore, the Neoproterozoic seawater chemistry that favoured early dolomitization of carbonate precursor mineralogies was an advantage for the preservation of fabrics from metastable precursor minerals.  相似文献   

16.
洞穴碳酸钙沉积的古气候记录研究   总被引：22，自引：3，他引：22  
洞穴碳酸钙是陆地环境中一种极好的古气候信息库。本文比较论述了中外科学家在该领域的研究历史与最新进展，指出该项研究需要通过高精度地质年代学、同位素地球化学和洞穴沉积学密切配合；并结合作者自己的工作，提出洞穴碳酸钙的稳定同位素和年轮记录是我国东部季风区古季风强弱、干湿变化、干旱事件及强降水事件的极好的高分辨档案  相似文献   

17.
Some speleothems (CaCO3 cave deposits) can be demonstrated to have been formed in oxygen isotopic equilibrium with their parent seepage waters and thus a record of relative fluctuations in depositional temperature can be obtained from the δ18O variations in successive growth layers of such deposits. These temperature fluctuations reflect variations in the average annual air temperature at the surface above the cave, and therefore permit inference of past continental climate changes. Equilibrium deposits have been obtained from caves in San Luis Potosi, Bermuda, Kentucky, West Virginia, Iowa, and Alberta, ranging in age from 200,000 years BP to the present, as determined by 230Th234>U dating of the speleothems. The δ18O time curves for the six sites show the following synchronous climatic fluctuations: warm periods from 190 to 165 and from 120 to 100 Ka, at 60 and 10 Ka, and cold periods from 95 to 65 and from 55 to 20 Ka. The periods of thermal maxima correspond in time to the interglacial periods of the marine foraminiferal isotopic and faunal temperature records and to periods of high sea stand as observed from radiometric dating of raised coral reefs. Maxima and minima in insolation appear to be synchronous with this record as well.  相似文献   

18.
The suitability of speleothems for interpreting palaeoclimate is typically determined by using either the Hendy Test, overlapping analysis or long‐term cave environment monitoring. However, in many cases, these methods are not applicable, because a speleothem lacks clearly traceable layers for the Hendy Test, it is difficult to obtain an overlapping speleothem nearby, or long‐term cave monitoring is impractical. The authors propose a multiple cave deposit approach to assess the suitability of speleothems for palaeoclimate study. Speleothems collected from two sites within Raccoon Mountain Cave, Tennessee (USA) exhibit remarkable spatial variation (δ13C: ?10·3‰ to ?2·2‰) over a relatively short distance (ca 260 m). Drip water δ18O values exhibit a seasonal precipitation signal at Site 1 and an annual signal at Site 2. Combining field observations, water isotope analysis and trace‐element data, the authors propose that the speleothem formation at Site 1 and Site 2 tapped distinct sources of CO2: (i) CO2 derived from overlying soils for Site 1; and (ii) limestone dissolved inorganic carbon induced by ground water dissolution for Site 2. Using fresh cave deposits (modern speleothem) δ13C (100% C3 vegetation) as an analogue, a simple model was developed to estimate land surface vegetation for speleothems. The speleothem formation temperature estimated using fresh cave deposit δ18O values generally reflects the mean annual temperature in this region. This study indicates that spatial variations in carbon isotopes could be caused by different carbon sources dominating in different parts of the cave, which should be taken into consideration by researchers when using speleothem δ13C values to reconstruct temporal palaeo‐vegetation changes. This study demonstrates a practical sampling strategy for verifying suitability of speleothems for palaeo‐vegetation and palaeo‐temperature reconstructions by analysing multiple cave deposits, especially for cases in which the Hendy Test, parallel sampling and long‐term monitoring of cave environment are not feasible.  相似文献   

19.
Chemical kinetics, speleothem growth and climate   总被引：7，自引：0，他引：7  
The morphology and stratigraphy of speleothems are controlled by parameters that depend on climate. These are the water supply rates feeding the speleothem, e.g. a stalagmite, the growth rates dependent on the chemical kinetics of calcite precipitation and the supersaturation of the solution from which calcite is precipitated. To elucidate the basic principles of speleothem growth, a physical-chemical model of calcite precipitation is used to estimate growth rates under various geologically relevant conditions. Furthermore, we present a model that allows the computation of the growth history of stalagmites, i.e. their morphology and stratigraphy under varying climatic conditions. This enables us to see how climatic signals are inscribed into stalagmites. Owing to the counter-balancing effects of some parameters, it is not possible to read climatic conditions backwards from the morphology and stratigraphy of a speleothem in a simple way, but a basic understanding of the growth of speleothems can be a helpful supporting tool in the interpretation of palaeoclimatic records.  相似文献   

20.
已有工作对地质环境指标空间分布特征的研究揭示出,我国的环境在新生代期间经历了从近于东西向的带状格局向与现今相似的非带状格局的转变,代表了东亚地区重大的环境变化,但对这一转变的时间、空间变化的详细过程还缺少深入的认识。越来越多的证据显示,渐新世/中新世之交和中新世可能是这一环境变化最为关键的时期,因而有必要对渐新世和中新世内部不同时期的环境格局进行更详细的研究。近十年来,大量新的研究工作积累了更多的资料和证据,为进一步研究上述问题提供了新的可能。文章根据已有文献资料,对有明确环境意义和较可靠年代控制的地质记录进行了重新整理和分类,对渐新世和中新世不同时期的环境格局进行了详细的考察。研究显示,以内陆干旱为基本特征的非带状环境格局至少出现于中新世早期,与我国北方风尘堆积出现的时代具有一致性。  相似文献   

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