K–Ar and ⁴⁰Ar/³⁹Ar phengite ages of Sanbagawa schist clasts from the Kuma Group, central Shikoku, southwest Japan     

Nguyen D.  Nuong  Tetsumaru  Itaya    Hironobu  Hyodo  Kazumi  Yokoyama 《Island Arc》2009,18(2):282-292

Conglomerates of the Kuma Group, central Shikoku, southwest Japan contain Sanbagawa schist clasts with a variety of metamorphic grades and lithologies. K–Ar and ⁴⁰Ar/³⁹Ar dating of phengite show all the pelitic schist clasts from low- to high-grade zones have similar phengite ages (82–84 Ma) that are significantly older than those from the in situ Sanbagawa sequence of central Shikoku. This is because the Kuma–Sanbagawa sequence was exhumed earlier than the in situ Asemi sequence with an exhumation process intermediate between those for the Kanto Mountains and the in situ Asemi sequences. ⁴⁰A/³⁹Ar plateau ages (103 and 117 Ma) of phengite in amphibolites indicate the timing of the early stage of the exhumation of the metamorphic pile, probably close to the peak metamorphic age.  相似文献   

⁴⁰Ar/³⁹Ar ages of blueschist facies pelitic schists from Qingshuigou in the Northern Qilian Mountains, western China     

Yong-Jiang  Liu  Franz  Neubauer  Johann  Genser  Akira  Takasu  Xiao-Hong  Ge Robert  Handler 《Island Arc》2006,15(1):187-198

Abstract   Pelitic schists from Qingshuigou in the Northern Qilian Mountains of China contain mainly glaucophane, garnet, white mica, clinozoisite, chlorite and piemontite. Isotopic age dating of these schists provides new constraints on the formation of the high-grade blueschists at Qingshuigou. White mica ⁴⁰Ar/³⁹Ar ages range from 442.1 to 447.5 Ma (total fusion age of single grain) and from 445.7 to 453.9 Ma (integrated age of white mica concentrates). These ages (442.1–453.9 Ma) represent the peak metamorphic ages or cooling ages of the blueschists during exhumation shortly after peak metamorphism. The ⁴⁰Ar/³⁹Ar dates in the present study are similar to ages previously reported for eclogites and blueschists in the area; this suggests that both the eclogites and pelitic sediments underwent high-grade metamorphism during the same subduction event. From this chronological evidence and the presence of well-developed Silurian remnant-sea flysch and Devonian molasse, it is concluded that the Northern Qilian Ocean had closed by the end of the Ordovician, and rapid orogenic uplift followed in the Devonian.  相似文献   

Geology of the summit limestone of Mount Qomolangma (Everest) and cooling history of the Yellow Band under the Qomolangma detachment     

Harutaka  Sakai  Minoru  Sawada  Yutaka  Takigami  Yuji  Orihashi  Tohru  Danhara  Hideki  Iwano  Yoshihiro  Kuwahara  Qi  Dong  Huawei  Cai  Jianguo  Li 《Island Arc》2005,14(4):297-310

Abstract   Newly discovered peloidal limestone from the summit of Mount Qomolangma (Mount Everest) contains skeletal fragments of trilobites, ostracods and crinoids. They are small pebble-sized debris interbedded in micritic bedded limestone of the Qomolangma Formation, and are interpreted to have been derived from a bank margin and redeposited in peri-platform environments. An exposure of the Qomolangma detachment at the base of the first step (8520 m), on the northern slope of Mount Qomolangma was also found. Non-metamorphosed, strongly fractured Ordovician limestone is separated from underlying metamorphosed Yellow Band by a sharp fault with a breccia zone. The ⁴⁰Ar–³⁹Ar ages of muscovite from the Yellow Band show two-phase metamorphic events of approximately 33.3 and 24.5 Ma. The older age represents the peak of a Barrovian-type Eo-Himalayan metamorphic event and the younger age records a decompressional high-temperature Neo-Himalayan metamorphic event. A muscovite whole-rock ⁸⁷Rb–⁸⁶Sr isochron of the Yellow Band yielded 40.06 ± 0.81 Ma, which suggests a Pre-Himalayan metamorphism, probably caused by tectonic stacking of the Tibetan Tethys sediments in the leading margin of the Indian subcontinent. Zircon and apatite grains, separated from the Yellow Band, gave pooled fission-track ages of 14.4 ± 0.9 and 14.4 ± 1.4 Ma, respectively. These new chronologic data indicate rapid cooling of the hanging wall of the Qomolangma detachment from approximately 350°C to 130°C during a short period (15.5–14.4 Ma).  相似文献   

Emerald dating through Ar/Ar step-heating and laser spot analysis of syngenetic phlogopite     

A. Cheilletz  G. F  raud  G. Giuliani  G. Ruffet 《Earth and Planetary Science Letters》1993,120(3-4):473-485

Emerald, occurring in K-metasomatic rocks developed at the contact of the Carnaíba leucogranite with serpentinite (Bahia State, Brazil), has been dated using an original ⁴⁰Ar/³⁹Ar procedure. It combines step heating and spot fusion experiments on two types of phlogopite crystals: (1) bulk samples and individual grains extracted from the enclosing K-metasomatic host rocks; and (2) syngenetic solid inclusions precipitated along growing zones of the emerald host crystals. The second procedure uses in situ laser probe experiments on rock sections. In spite of the huge amounts of excess ⁴⁰Ar detected in adjacent emerald, we could measure reliable ages of 1951 ± 8 Ma and 1934 ± 8 Ma for the Trecho Velho and Braulia occurrences, respectively. Spot fusion data had higher discrepancy than the step heating data, but minute crystals of phlogopite included in emeralds bearing excess argon do not reveal excess argon. A muscovite belonging to the same granite hydrothermal complex gave a plateau age of 1976 ± 8 Ma, which may correspond to a higher closure temperature of the KAr system during the cooling of the whole pluton and associated hydrothermal halo.

These accurate measurements lead to the following conclusions: (1) direct emerald dating is possible; (2) in spite of a polyphase history during the Transamazonian orogenesis (2 Ga), combined step heating and spot fusion experiments give a better precision for granite-related emerald mineralization than the scattered ages obtained by Rb-Sr and K-Ar methods; (3) the late-Transamazonian tectonothermal retrograde event which probably caused the dispersion of previous Rb-Sr and K-Ar data is not revealed by our procedure; (4) the emerald mineralization and K-metamorphism appear to be linked with the thermal history of the leucogranite; (5) in addition to its use in polyphase crustal domains, accurate ⁴⁰Ar/³⁹Ar dating is of major interest in the field of metallogenic models, even, for instance, for mineralizations characterized by disturbed isotopic systems, which record effects as excess argon.  相似文献   

Age of Jurassic continental tholeiites of French Guyana, Surinam and Guinea: Implications for the initial opening of the Central Atlantic Ocean     

Katja Deckart  Gilbert F  raud  Herv  Bertrand 《Earth and Planetary Science Letters》1997,150(3-4):205-220

A detailed ⁴⁰Ar/³⁹Ar study, of mineral separates from the Jurassic Atlantic Continental Tholeiites (JACT) of Guyana (French Guyana and Surinam, South America), and Guinea (West Africa) related to the initial opening of the Central Atlantic, has been carried out. In French Guyana, plateau ages of 196.0 ± 5.7 Ma and 196.1 ± 7.5 Ma were obtained on single, small amphibole grains from NNW—SSE trending dykes. In Guinea, single biotite grains from intrusive formations from the Kakoulima and Fouta Djalon areas yielded plateau ages of 200.4 ± 0.2 Ma and 194.8 ± 0.5 Ma, concordant with high temperature apparent ages on other biotites. The bulk plagioclase samples display disturbed age spectra due to alteration and excess argon. However, intermediate temperature, weighted mean plagioclase ages are similar in both regions of Guyana and Guinea, ranging from 200.2 ± 2.4 Ma to 188.7 ± 1.9 Ma, partly in agreement with the amphibole and biotite data.

These data, combined with previous ⁴⁰Ar/³⁹Ar and U/Pb results from the northern part of the Central Atlantic margins, indicate intense magmatic activity distributed over a large area from Iberia to Liberia (ca. 4500 km long) for a short period of time (204-195 Ma, perhaps less for the bulk of the magmatism) during the initial break-up of Pangea continent. These data do not support an initiation of the magmatism from a radial volcano-tectonic system centred in the south of the region, as suggested by May [1], and the initial break-up seems to affect the whole Central Atlantic during a period of 9 Ma.  相似文献   

Ar/Ar ages and paleomagnetism of São Miguel lavas, Azores     

Catherine L. Johnson  Jan R. Wijbrans  Catherine G. Constable  Jeff Gee  Hubert Staudigel  Lisa Tauxe  Victor-H. Forjaz  Mrio Salgueiro 《Earth and Planetary Science Letters》1998,160(3-4):637-649

We present new ⁴⁰Ar/³⁹Ar ages and paleomagnetic data for São Miguel island, Azores. Paleomagnetic samples were obtained for 34 flows and one dike; successful mean paleomagnetic directions were obtained for 28 of these 35 sites. ⁴⁰Ar/³⁹Ar age determinations on 12 flows from the Nordeste complex were attempted successfully: ages obtained are between 0.78 Ma and 0.88 Ma, in contrast to published K–Ar ages of 1 Ma to 4 Ma. Our radiometric ages are consistent with the reverse polarity paleomagnetic field directions, and indicate that the entire exposed part of the Nordeste complex is of a late Matuyama age. The duration of volcanism across São Miguel is significantly less than previously believed, which has important implications for regional melt generation processes, and temporal sampling of the geomagnetic field. Observed stable isotope and trace element trends across the island can be explained, at least in part, by communication between different magma source regions at depth. The ⁴⁰Ar/³⁹Ar ages indicate that our normal polarity paleomagnetic data sample at least 0.1 Myr (0–0.1 Ma) and up to 0.78 Myr (0–0.78 Ma) of paleosecular variation and our reverse polarity data sample approximately 0.1 Myr (0.78–0.88 Ma) of paleosecular variation. Our results demonstrate that precise radiometric dating of numerous flows sampled is essential to accurate inferences of long-term geomagnetic field behavior. Negative inclination anomalies are observed for both the normal and reverse polarity time-averaged field. Within the data uncertainties, normal and reverse polarity field directions are antipodal, but the reverse polarity field shows a significant deviation from a geocentric axial dipole direction.  相似文献   

The composition of back-arc basin lower crust and upper mantle in the Mariana Trough: A first report   总被引：1，自引：0，他引：1  

Robert J.  Stern  Sherman H.  Bloomer  Fernando  Martinez  Toshitsugu  Yamazaki T. Mark  Harrison 《Island Arc》1996,5(3):354-372

Abstract The Mariana Trough is an active back-arc basin, with the rift propagating northward ahead of spreading. The northern part of the Trough is now rifting, with extension accommodated by combined stretching and igneous intrusion. Deep structural graben are found in a region of low heat flow, and we interpret these to manifest a low-angle normal fault system that defines the extension axis between 19°45' and 21°10'N. A single dredge haul from the deepest (∼5.5 km deep) of these graben recovered a heterogeneous suite of volcanic and plutonic crustal rocks and upper mantle peridotites, providing the first report of the deeper levels of back-arc basin lithosphere. Several lines of evidence indicate that these rocks are similar to typical back-arc basin lithosphere and are not fragments of rifted older arc lithosphere. Hornblende yielded an ⁴⁰Ar/³⁹Ar age of 1.8 ± 0.6 Ma, which is interpreted to approximate the time of crust formation. Harzburgite spinels have moderate Cr# (<40) and coexisting compositions of clinopyroxene (CPX) and plagioclase (PLAB) fall in the field of mid-ocean ridge basalt (MORB) gabbros. Crustal rocks include felsic rocks (70-80% SiO₂) and plutonic rocks that are rich in amphibole. Chemical compositions of crustal rocks show little evidence for a 'subduction component', and radiogenic isotopic compositions correspond to that expected for back-arc basin crust of the Mariana Trough. These data indicate that mechanical extension in this part of the Mariana Trough involves lithosphere that originally formed magmatically. These unique exposures of back-arc basin lithosphere call for careful study using ROVs and manned submersibles, and consideration as an ocean drilling program (ODP) drilling site.  相似文献   

Tectonothermal evolution of the Lesser Himalaya, Nepal: Constraints from ⁴⁰Ar/³⁹Ar ages from the Kathmandu Nappe     

Kazunori  Arita  R. David  Dallmeyer Akira  Takasu 《Island Arc》1997,6(4):372-385

Abstract The Himalaya is a fold-and-thrust wedge formed along the northern margin of the Indian continent, and consists of three thrust-bounded lithotectonic units; the Sub-Himalaya, the Lesser Himalaya, and the Higher Himalaya with the overlying Tethys Himalaya from south to north, respectively. The orogen-scale, intracrustal thrusts which bound the above lithotectonic units are splays off an underlying subhorizontal dkcollement, and show a southward propagating piggy-back sequence with an out-of-sequence thrust. Among these thrusts, the Main Central Thrust zone (MCT zone) has played a major role in Himalayan tectonics. The MCT zone represents a shear zone which has accommodated southward thrusting of the Higher Himalayan crystalline thrust sheet over the Lesser Himalayan sequence for ～140 km. The Kathmandu Nappe in central Nepal has been transported over the Lesser Himalayan metasediments along the MCT zone, and is locally separated from the Higher Himalayan thrust sheet in the north by an out-of-sequence thrust. ⁴⁰Ar/³⁹Ar ages have been determined for one whole-rock phyllite and six muscovite concentrates from metasedimenta-ry rocks and variably deformed granites in the Kathmandu Nappe. These ages range from 44 Ma to 14 Ma, and suggest a record of both Eo-Himalayan (Eocene) and Neo-Himalayan (Miocene) tectonothermal events in the Tertiary Himalayan orogeny. The Miocene event was associated with translation along the MCT zone. No tectonothermal event of the Late Miocene to Early Pliocene ages have been reported near the MCT zone in southern Lesser Himalayan crystalline nappe or klippe, although such events have been documented within and around the MCT zone in the northern root zone of the Higher Himalaya. This suggests that out-of-sequence thrusting may have occurred between 14 Ma and 5 Ma, probably during the period 10-7.5 Ma. Since then the frontal MCT zone below the Kathmandu Nappe has been inactive, but the MCT zone in the northern root zone has remained active. The rapid increase in denudation rates of the Higher Himalaya since the Late Miocene may have been caused by ramping along the out-of-sequence thrust at depth.  相似文献   

²³⁰Th/²³⁴U and ¹⁴C dating of a lowstand coral reef beneath the insular shelf off Irabu Island, Ryukyus, southwestern Japan     

Keiichi  Sasaki  Akio  Omura  Tetsuo  Miwa  Yoshihiro  Tsuji  Hiroki  Matsuda  Toru  Nakamori  Yasufumi  Iryu  Tsutomu  Yamada  Yuri  Sato  Hiroshi  Nakagawa 《Island Arc》2006,15(4):455-467

Abstract   High-resolution seismic reflection profiles delineated the distribution of mound-shaped reflections, which were interpreted as reefs, beneath the insular shelf western off Irabu Island, Ryukyus, southwestern Japan. A sediment core through one of the mounded structures was recovered from the sea floor at a depth of −118.2 m by offshore drilling and was dated by radiometric methods. The lithology and coral fauna of the core indicate that the mounded structure was composed of coral–algal boundstone suggesting a small-scaled coral reef. High-precision α-spectrometric ²³⁰Th/²³⁴U dating coupled with calibrated accelerator mass spectrometric ¹⁴C ages of corals obtained reliable ages of this reef ranging from 22.18 ± 0.63 to 30.47 ± 0.98 ka. This proves that such a submerged reef was formed during the lowstand stage of marine oxygen isotope stages 3–2. The existence of low-Mg calcite in the aragonitic coral skeleton of 22.18 ± 0.63 ka provides evidence that the reef had once been exposed by lowering of the relative sealevel to at least −126 m during the last glacial maximum in the study area. There is no room for doubt that a coral reef grew during the last glacial period on the shelf off Irabu Island of Ryukyus in the subtropical region of western Pacific.  相似文献   

⁴⁰Ar/ ³⁹Ar and K–Ar geochronological age constraints for the inception and early evolution of the Izu–Bonin – Mariana arc system     

MICHAELA.  COSCA  RICHARDJ.  ARCULUS  JULIANA.  PEARCE & JOHNG.  MITCHELL 《Island Arc》1998,7(3):579-595

K–Ar and ⁴⁰Ar/³⁹Ar dates are presented for locations in the Izu–Bonin – Mariana (IBM) forearc (Ocean Drilling Program (ODP) sites 786 & 782, Chichijima, Deep Sea Drilling Program (DSDP) sites 458 & 459, Saipan), and Palau on the remnant arc of the Kyushu–Palau Ridge. For a number of these locations, the ⁴⁰Ar/³⁹Ar plateau and ³⁶Ar/⁴⁰Ar versus ³⁹Ar/⁴⁰Ar isochrons give older ages than the K–Ar results. The most important results are: (i) at site 786, initial construction of the proto-IBM (now forearc) basement occurred at least by ca 47–45 Ma, consistent with the age of the immediately overlying sediments (middle Eocene nannofossil Zone CP13c); the younger pulse of construction dated at ca 35 Ma by K–Ar could not be confirmed by ⁴⁰Ar/³⁹Ar analysis; (ii) ⁴⁰Ar/³⁹Ar ages for the initial construction of the Mariana portion of the IBM system are as old as those of the Izu–Bonin portion, for example at site 458, initial construction commenced at least by ca 49 Ma and at ca 47 Ma at Saipan (Sankakayuma Formation); and (iii) a combination of K–Ar and ⁴⁰Ar/³⁹Ar ages indicate continued boninite magmatism in the Izu–Bonin forearc (and remnant arc at Palau) until ca 35 Ma. Subduction inception including boninite series rocks along most of the exposed length of the IBM system, clearly preceded by some 5 million years the Middle Eocene (ca 43.5 Ma) change in Pacific plate motion. Boninitic series magmatism persisted at locations now exposed in the forearc for ～ 15 million years after arc inception concurrently with low-K tholeiitic series eruptions from a subaerial arc system, established at ≥ 40 Ma, on the Kyushu–Palau Ridge. For the Mariana portion of the IBM system, reconstruction of the proto-arc places this activity adjacent to the concurrent but orthogonally spreading Central Basin Ridge of the West Philippine Basin. It is possible that a combination of subduction of a young North New Guinea Plate beneath newly created back-arc basin crust may account for some of the features of the Mariana system. It is clear, however, that the understanding of the processes of subduction initiation and early IBM arc development is incomplete.  相似文献   

Ar / Ar dating of high-pressure rocks from the Ligurian Alps: Evidence for a continuous subduction–exhumation cycle     

Laura Federico  Giovanni Capponi  Laura Crispini  Marco Scambelluri  Igor M. Villa   《Earth and Planetary Science Letters》2005,240(3-4):668-680

We present ³⁹Ar–⁴⁰Ar dating of phengite, muscovite and paragonite from a set of mafic and metasedimentary rocks sampled from the high-pressure (HP) metaophiolites of the Voltri Group (Western Alps) and from clasts in the basal layer conglomerates from the Tertiary molasse which overlie the high-pressure basement. The white mica-bearing rocks display peak eclogitic and blueschist-facies parageneses, locally showing complex greenschist-facies replacement textures. The internal discordance of age spectra is proportional to the chemical complexity of the micas. High-Si phengites from eclogite clasts record a ³⁹Ar–⁴⁰Ar age of ca. 49 Ma for the eclogite stage and ca. 43 Ma for the blueschist retrogression; phengites from a blueschist basement sample yield an age of ca. 40 Ma; low-Si muscovite from a metasediment dates the formation of the greenschist paragenesis at ca. 33 Ma. Our data indicate that the analyzed samples reached high-pressure conditions at different times over a time-span of c.a. 10 Ma. Subduction was continuing during exhumation and blueschist retrograde re-equilibration of higher-pressure, eclogite-facies rocks. This process kept the isotherms depressed, allowing the older HP-rocks to escape thermal re-equilibration. Our results, added to literature data, fit a tectonic model of a subduction–exhumation cycle, with different tectonic slices subducted at different times from Early Eocene until the Eocene–Oligocene boundary.  相似文献   

Noble gases in pillow basalt glasses from the northern Mariana Trough back-arc basin     

YASUO  IKEDA  KEISUKE  NAGAO  ROBERT J.  STERN  MAKOTO  YUASA & SALLY  NEWMAN 《Island Arc》1998,7(3):471-478

Noble gas concentrations and isotopic compositions have been measured in eight samples of pillow basalt glasses collected from seven different localities along 250 km of the Mariana Trough spreading and rifting axis. The samples have uniform and mid-ocean ridge basalt (MORB)-like ³He/⁴He values of 9–12 × 10^–6 (6.4–8.6 times atmospheric) despite large variations in ⁴He. Concentrations of the noble gases Ne, Ar, Kr, and Xe show much smaller variations between samples, but larger variations in isotopic compositions of Ne, Ar, and Xe. Excess radiogenic ²¹Ne is observed in some samples. ⁴⁰Ar/³⁶Ar varies widely (atmospheric to 1880). Kr is atmospheric in composition for all samples. Some samples show a clear excess ¹²⁹Xe, which is a well-known MORB signature. Isotopic compositions of the heavier noble gases (Ar, Kr, and Xe) in some samples, however, show more atmospheric components. These data reflect the interaction of a MORB-like magma with an atmospheric component such as seawater or of a depleted mantle source with a water-rich component that was probably derived from the subducting slab.  相似文献   

Stable Isotopes (δ¹⁸O, δ²H) of Pore Waters in Clay-Rich Aquitards: A Comparison and Evaluation of Measurement Techniques     

《Ground Water Monitoring & Remediation》2001,21(2):108-116

Pore water collected from piezometers installed in a thick clay-rich till were used to compare and evaluate four techniques for obtaining δD and δ¹⁸O values in these media. The techniques included mechanical squeezing, centrifugation, azeotropic distillation, and a direct soil-water equilibration technique. Direct CO₂-core equilibration yielded sufficiently accurate and reproducible δ¹⁸O results of pore water in clay-rich tills. In addition, this method eliminated the need for labor-intensive complete extraction of water from the geologic media. Mechanical squeezing and centrifugation produced results similar to direct equilibration. However, both of these methods exhibited a greater degree of variability and were laborious and more time consuming. Small differences in δ¹⁸O values between piezometer water and equilibrated, squeezed, and centhfuged samples suggested that each method collected different fractions of the clay-water reservoir. Although these subtle differences were not conclusive, they did suggest the presence of weakly bound water and highlighted the difference between these three techniques for determining the stable isotopic composition of pore water in clay-rich aquitards. Azeotropic distillation produced a high level of discrepancy in δD andδ¹⁸O results compared to the other methods. Incomplete extraction was considered the most probable cause of this error. The results of this study suggested that direct equilibration is the best method for determining detailed δD and δ¹⁸O values of pore water in clay-rich aquitards.  相似文献   

A critical evaluation of young (near-zero) K–Ar ages     

St  phane Scaillet  Herv  Guillou 《Earth and Planetary Science Letters》2004,220(3-4):265-275

An evaluation of the precision and resolution of the unspiked K–Ar dating method is presented with particular regard to the statistical significance of ages that are measured near or at the detection limit of the technique. Near-zero (historical) ages can be measured by the unspiked K–Ar technique with a precision that is essentially controlled by the precision with which the ⁴⁰Ar/³⁶Ar of the sample can be resolved from the present-day atmospheric value of 295.5. The best analytical precision on the isotopic ratio is ±0.05% (1σ) by this technique, which currently limits the lower detection limit of unspiked K–Ar ages to samples featuring at least 0.14% of radiogenic ⁴⁰Ar. The corresponding youngest resolvable K–Ar age depends on the K content and atmospheric contamination of the sample. Total-fusion analysis of high-K refractory minerals like sanidine is not practicable via K–Ar, and the lowest resolvable age for medium-K samples more amenable to complete fusion is around 1.5 ka (on a single-run basis). It is argued that near-zero age measured with a probability density straddling or narrowing the time-origin cannot be handled without accounting for the non-negativity constraint imposed by the physical requirement of a positive age. The pertinent equations are derived both for the single-run case and for the case of independent replicates made on a single sample. We show that pooled K–Ar replicates can theoretically reduce the nominal uncertainty of individual unspiked ages (typically ±1.5 ka, 2σ) to a value that is close to the smallest ⁴⁰Ar/³⁹Ar isochron age uncertainty achievable on sanidine in the 0–2 ka range (±0.2 ka, 2σ). However, this performance is obtained at the cost of prohibitively large-sample statistics (n≥15) for medium-K feldspars datable via K–Ar. Coupled with the inability of the K–Ar approach to obviate the problems of excess/fractionated ⁴⁰Ar and/or xenocrystic contamination, this makes the ⁴⁰Ar/³⁹Ar technique the method of choice for dating historical events by the K–Ar scheme.  相似文献   

Ar/Ar illite dating of Late Caledonian (Acadian) metamorphism and cooling of K-bentonites and slates from the Welsh Basin, U.K.     

Hailiang Dong  Chris M. Hall  Alex N. Halliday  Donald R. Peacor  Richard J. Merriman  Brin Roberts 《Earth and Planetary Science Letters》1997,150(3-4):337-351

The vacuum-encapsulation laser ⁴⁰Ar³⁹Ar technique allows extremely small (10⁻⁶ g) samples of fine-grained materials such as diagenetic clays to be dated. Here we show that the method can be extended to higher-grade clay minerals. The integration of transmission electron microscopic (TEM) characterization with ⁴⁰Ar³⁹Ar dating of vacuum encapsulated samples permits the resolution of the timing of metamorphic growth/cooling from the time of diagenesis. We have applied this technique to well characterized Lower Paleozoic slates and K-bentonites from the Welsh Basin, which span the transition from anchizonal to epizonal grade, which had been previously studied using RbSr and SmNd dating.

TEM observations of epizonal K-bentonites and slate showed that illite in these samples is of 2M₁ polytype, of muscovite-like composition, and oriented parallel to cleavage, suggesting that they are of metamorphic origin. Total gas ages (equivalent to conventional KAr ages) for encapsulated epizonal K-bentonites and slate (340–408 Ma) are considerably variable. The Ar retention ages (calculated from ³⁹Ar and ⁴⁰Ar atoms retained in the sample after irradiation) are more consistent (383–411 Ma). The ³⁹Ar recoil losses are minor for illites from whole rock samples of epizonal K-bentonites but very significant for clay separates of epizonal slate. Plateaus in age spectra were observed in epizonal K-bentonites and slate. The plateau ages (414–421 Ma) and retention ages (383–411 Ma) can be correlated with the onset of Acadian metamorphism and culmination of uplift and inversion of the Welsh Basin, respectively. These ages are significantly younger than the 450 Ma ages previously reported for diagenetic clays using the same method, suggesting that diagenetic history has been lost in these epizonal K-bentonites and slate.

TEM observations of anchizonal slates showed that there are two modes of illite. The first mode is similar to that observed in epizonal samples, suggesting a metamorphic origin. The second mode consists of the 1M_d polytype, has typical diagenetic illite composition, and is oriented parallel to bedding, suggesting a diagenetic origin. Total gas ages for encapsulated anchizonal slates vary considerably (361–422 Ma). The retention ages are more consistent (413–432 Ma) than the total gas ages. The ³⁹Ar recoil losses are more significant than those for epizonal K-bentonites and slate. Plateaus in age spectra are generally not observed. However, the consistent retention ages for the anchizonal slates correspond to the plateau ages for the epizonal samples, and are inferred to represent the onset of Acadian metamorphism.

These data, when combined with our previously published results for diagenetic shales, suggest that thermal conditions near the boundary of anchizonal and epizonal grades are necessary to completely reset Ar systems in shales and slates.  相似文献   

Sm–Nd, Rb–Sr and K–Ar geochronology of the Higo metamorphic terrane, west-central Kyushu, Japan     

Takuji Hamamoto  Yasuhito Osanai  & Yhiroo Kagami 《Island Arc》1999,8(2):323-334

The Higo metamorphic terrane situated in west-central Kyushu island, southwest Japan, is composed of greenschist- to granulite-facies metamorphic rocks. The southern part of the metamorphic terrane consists mainly of garnet–biotite gneiss and garnet–cordierite–biotite gneiss, and orthopyroxene or cordierite-bearing S-type tonalite with subordinate amounts of hornblende gabbro. Rb–Sr, Sm–Nd and K–Ar isotopic ages for these rocks have been determined here. The garnet–biotite gneiss gives an Sm–Nd age of 227.1 ± 4.9 Ma and a Rb–Sr age of 101.0 ± 1.0 Ma. The hornblende gabbro has an Sm–Nd age of 257.9 ± 2.5 Ma and a K–Ar age of 103.4 ± 1.1 Ma. These age differences of the same samples are due to the difference in the closure temperature for each system and minerals. The garnet-cordierite–biotite gneiss contains coarse-grained garnet with a zonal structure conspicuously distinguished in color difference (core: dark red; rim: pink). Sm–Nd internal isochrons of the garnet core and the rim give ages of 278.8 ± 4.9 Ma (initial ¹⁴³Nd/¹⁴⁴Nd ratio = 0.512311 ± 0.000005) and 226.1 ± 28.4 Ma (0.512277 ± 0.000038), respectively. These ages are close to formation of the garnet core and the rim. It has been previously suggested that the Higo metamorphic terrane belongs to the Ryoke metamorphic belt. But Sr and Nd isotopic features of the rocks from the former are different from those of the Ryoke metamorphic rocks, and are similar to those of the granulite xenoliths contained in the Ryoke younger granite.  相似文献   

Noble gas isotopic composition of deep underground water in Osaka plain, central Japan: Evidence for mantle He and model for new volcanism     

Toshinori  Okada  Tetsumaru  Itaya  Mitsuo  Sato Keisuke  Nagao 《Island Arc》1994,3(3):221-231

Abstract Elemental and isotopic compositions of noble gases extracted from the bore hole water in Osaka plain, central Japan were examined. The water samples were collected from four shallow bore holes (180-450 m) and seven deep bore holes (600-1370 m) which have been used for an urban resort hot spring zone. The water temperatures of the deep bore holes were 22-50°C and that of the shallow bore holes, 13-23°C. The elemental abundance patterns show the progressive enrichment of the heavier noble gases compared with the atmospheric noble gas composition except for He, which is heavily enriched in deep bore hole water samples. ³He/⁴He ratios from the bore holes reaching the Ryoke granitic basement were higher than the atmospheric value (1.4 × 10⁻⁶), indicating a release of mantle He through the basement. The highest value of 8.2 × 10⁻⁶ is in the range of arc volcanism. On the other hand, the bore holes in sedimentary rocks overlying the basement release He enriched in radiogenic ⁴He, resulted in a low ³He/⁴He ratio of 0.5 × 10⁻⁶. ⁴He/²⁰Ne and ⁴⁰Ar/³⁶Ar ratios indicate that the air contamination is generally larger in shallow bore holes than in deep ones from each site. The helium enriched in mantle He is compatible with the previous work which suggested up-rising magma in 'Kinki Spot', the area of Osaka and western Wakayama, in spite of no volcanic activity in the area. A model to explain an initiation of magma generation beneath this area is presented.  相似文献   

Nitrate Source Identification Using δ¹⁵N in a Ground Water Plume Near an Intensive Swine Operation     

Jonathan D. Karr  William J. Showers  Thomas H. Hinson 《Ground Water Monitoring & Remediation》2002,22(2):68-75

Nitrate-contaminated ground water beneath and adjacent to an intensive swine ( Sus scrofa domesticus ) production facility in the Middle Coastal Plain of North Carolina was analyzed for δ¹⁵N of nitrate (δ¹⁵N-NO₃). Results show that the isotopic signal of animal waste nitrogen is readily identifiable and traceable in nitrate in this ground water. The widespread land application of animal wastes from intensive livestock operations constitutes a potential source of nitrogen contamination to natural water throughout large regions of the United States and other countries. The site of the present study has been suspected as a nitrate contamination source to nearby domestic supply wells and has been monitored for several years by government and private water quality investigators through sampling of observation wells, ditches, and streams. δ¹⁵N of nitrate allowed direct identification of animal waste-produced nitrate in 11 of 14 wells sampled in this study, as well as recognition of nitrate contributions from non-animal waste agricultural sources in remaining wells.  相似文献   

Age and significance of the North Pyrenean metamorphism   总被引：1，自引：0，他引：1  

Francis Albarde  Annie Michard-Vitrac 《Earth and Planetary Science Letters》1978,40(3):327-332

³⁹Ar-⁴⁰Ar and ⁸⁷Rb-⁸⁷Sr studies of some metamorphic minerals from the North Pyrenean zone indicate that they crystallized about 92–104 m.y. ago on the east, 85 m.y. or older on the west. An amphibole from a lherzolite in the eastern area gives a plateau age at 103 m.y. The North Pyrenean metamorphism is shown to be a thermal effect of forcible lherzolite emplacement along the North Pyrenean zone. This latter process is related to the early breakup of the Europe-Iberia plate during the middle Cretaceous time.  相似文献   

Repeated thermal resetting of phengites in the Mulhacen Complex (Betic Zone, southeastern Spain) shown byAr/Ar step heating and single grain laser probe dating     

Koen de Jong  Jan R. Wijbrans  Gilbert F  raud 《Earth and Planetary Science Letters》1992,110(1-4):173-191

This study reports the results of the first⁴⁰Ar/³⁹Ar combined induction furnace and laser probe dating of phengites from the Mulhacen HP/LT metamorphic complex in the Betic Cordilleras, southern Spain. Laser step heating and spot fusion analyses on different halves of a split single grain were made with a continuous laser probe. Spot fusion analysis resulted in ages of about 30–31 Ma in the core and ages as low as 25–26 Ma in the rim. Laser step heating on the other half of the grain gave a spectrum with apparent ages increasing from about 25 Ma to 29.5 Ma. The age spectrum and the decreasing ages towards the rim of the grain may imply that resetting essentially occurred by volume diffusion of radiogenic⁴⁰Ar due to late stage reheating resulting from extensional tectonics. Ages around 30 Ma in the core of the grain are interpreted as minimum estimates of the cooling age of the main tectono-metamorphic phaseD₂.

Induction furnace step heating on phengite separates from mica schists and one gneiss resulted in two types of age spectra. Type I spectra show monotonously rising apparent ages from14.5 ± 1.9 Ma to20.7 ± 0.2 Ma, and in a second sample from16.9 ± 0.7 to29.7 ± 0.2 Ma. Type II spectra are characterized by plateaus of14.4 ± 0.1 Ma (the gneiss sample),17.3 ± 0.1 Ma and17.6 ± 0.1 Ma. Type II spectra show low temperature apparent ages significantly below the plateau age, implying resetting subsequent to initial cooling. Modelling of the age spectra demonstrated that the plateau ages are possibly the result of strong resetting (75–85% of argon loss) of an older isotope system. Total fusion of a number of phengite single grains from marbles taken close to type II mica schists yielded ages of15.4 ± 1.2 Ma and17.0 ± 0.7 Ma. The observed repeated resetting is coeval with major volcanic activity in basins adjacent to the metamorphic ranges, pointing to a resetting by advective fluid transport related to volcanism.  相似文献