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1.
Solute transport through structured, undisturbed soil has been studied in transient, unsaturated experiments using columns from grass and woodland sites on the Lancaster University campus. Three anionic tracers have been used, bromide (Br−) and two fluorinated organic acids (pentraflurobenzoic acid and 2,6-diflurobenzoic acid). The process of displacement of stored water from undisturbed columns was investigated using successive inputs of different tracers under similar antecedent conditions. The results indicated that initial breakthrough was rapid, with a relative concentration of 0.8 being reached between 0.4 and 0.5 pore volumes of discharge. It was found that there was an apparent continued discharge of ‘old’ water, stored in the column before any additions of tracer, even after the addition of a total of 4.9 and 5.4 pore volumes of water for the grass and woodland columns, respectively. The implications of the results of these tracer studies for modelling solute transport in structured soils are considered.  相似文献   

2.
The transport of bromide (Br) under matric heads of 0, ?2, ?5, and ?10 cm using undisturbed soil columns was investigated for understanding the solute transport in arid soils. Undisturbed soil cores were collected at ground surface, directly below where tension infiltrometer measurements were made in the Amargosa Desert, Nevada, United States. Laboratory experiments were conducted by introducing water containing Br tracer into a soil column maintained at steady‐state conditions. The observed data of breakthrough curves (BTC) were well fitted to an one‐region model, except for the cores at saturation, and a core at the matric head of ?5 cm, from which the observed data were better fitted to a two‐region model. Fitted pore water velocities with the one‐region model ranged from 1.2 to 56.6 cm/h, and fitted dispersion coefficients (D) ranged from 2.2 to 100 cm2/h. Results for the core analyzed with the two‐region model indicated that D ranged from 27.6 to 70.9 cm2/h at saturation, and 25.7 cm2/h at the matric head of ?5 cm; fraction of mobile water (β) ranged from 0.18 to 0.65, and mass transfer coefficient (ω) ranged from 0.006 to 0.03. In summary, the water fluxes and Br dispersion coefficients at investigated matric heads were very high due to the coarseness of the soils and possibly due to preferential flow pathways. These high water fluxes and Br dispersion coefficients would lead to a higher risk of deeper leaching accumulating nitrate nitrogen to the groundwater, and have significant effects on the desert ecosystem.  相似文献   

3.
A new probe was designed to quantify groundwater-surface water exchange in the hyporheic zone under dynamic stage condition. Current methods focus on either vertical pore water velocity or Darcy flux measurements. Both parameters must be understood to evaluate residence time and mass flux of constituents. Furthermore, most instruments are not well suited for monitoring instantaneous velocity or flux under dynamic exchange conditions. For this reason, the flux detection probe (FDP) was designed that employs electrogeophysical measurements to estimate in situ sediment porosity, which can be used to convert pore water velocity to Darcy flux. Dynamic pore water velocity is obtained by monitoring fluid conductivity and temperature along the FDP probe. Pressure sensors deployed at the top and bottom of the probe provide the additional information necessary to estimate vertical permeability. This study focuses on the use of a geophysical method to estimate pore water velocity, porosity, and permeability within a controlled soil column where simulated river water displaces simulated groundwater. The difference between probe derived and theoretical pore water velocity using natural tracers such as electrical conductivity and temperature was −4.9 and 3.9% for downward flow and 1.1 and 12.8% for upward flow, respectively. The difference in porosity calculated from mass and volume packed in the soil column and probe measure porosity ranged between −3.2% and 1.5%. Also, the calculated hydraulic conductivity differed from probe derived values by −8.9%.  相似文献   

4.
In this paper, five model approaches with different physical and mathematical concepts varying in their model complexity and requirements were applied to identify the transport processes in the unsaturated zone. The applicability of these model approaches were compared and evaluated investigating two tracer breakthrough curves (bromide, deuterium) in a cropped, free-draining lysimeter experiment under natural atmospheric boundary conditions. The data set consisted of time series of water balance, depth resolved water contents, pressure heads and resident concentrations measured during 800 days. The tracer transport parameters were determined using a simple stochastic (stream tube model), three lumped parameter (constant water content model, multi-flow dispersion model, variable flow dispersion model) and a transient model approach. All of them were able to fit the tracer breakthrough curves. The identified transport parameters of each model approach were compared. Despite the differing physical and mathematical concepts the resulting parameters (mean water contents, mean water flux, dispersivities) of the five model approaches were all in the same range. The results indicate that the flow processes are also describable assuming steady state conditions. Homogeneous matrix flow is dominant and a small pore volume with enhanced flow velocities near saturation was identified with variable saturation flow and transport approach. The multi-flow dispersion model also identified preferential flow and additionally suggested a third less mobile flow component. Due to high fitting accuracy and parameter similarity all model approaches indicated reliable results.  相似文献   

5.
Evidence for the functioning of macropores and the presence of preferential flow in forest soils is equivocal. This is partly because many workers use only one diagnostic technique to indicate whether or not macropore flow occurs. In this paper three lines of evidence are used to suggest that preferential flow does not occur in the percolating waters of a coniferous forest soil under the range of hydrological conditions that prevail in the field. To simulate field conditions, realistic rainfall intensities were used in conservative solute transport experiments on four undisturbed soil columns. A method is described in which breakthrough data can be used to calculate the percentage of antecedent water displaced from a soil column during frontal-type breakthrough experiments. Calculations based on this method using the experimental data show that as little as five percent of the antecedent water was immobile. The simple form of the functional advection–dispersion equation, based on a single value for linear velocity and the dispersion coefficient was fitted to two of the breakthrough curves with reasonable accuracy, further suggesting that preferential flow did not occur in the experiments. Finally, soil moisture characteristic curves were determined for replicate soil samples from the forest soil. The operational water contents of the columns during the breakthrough experiments were compared with the soil moisture characteristics and it was found that pores exerting pressure heads greater than −0·5 kPa did not appear to contribute to flow through the columns, again suggesting an absence of preferential flow. © 1997 by John Wiley & Sons, Ltd.  相似文献   

6.
Tracers provide one of the few ways of obtaining realistic information on the flows of water and solutes in undisturbed structured soils. Three fluorinated organic acids [pentafluorobenzoic acid, 2,6-diflurobenzoic acid and o-(trifluoromethyl) benzoic acid] and bromide were tested as anionic tracers in situations where the separation of different flow components is of interest. The fluorobenzoates were relatively conservative (approximately 90% for loam soil) although, in some instances, co-elution or complexation may lead to apparently non-conservative behaviour. Tracer mixtures applied to soils, were separated and quantified by high-performance liquid chromatography. The relative mobilities of the tracers were studied during unidirectional steady flow in large undisturbed soil columns brought back to the laboratory. The breakthrough curves showed highly dispersive behaviour, with very early breakthrough of solute and a long tail. Contributions to the column outflow of different simultaneous applications of rainfall and return flow, labelled with different tracers, were separated using multicomponent mixing equations. The results show the importance of preferential flow and relatively immobile storage in the transport process.  相似文献   

7.
Peat soils are heterogeneous, anisotropic porous media. Compared to mineral soils, there is still limited understanding of physical and solute transport properties of fen peat soils. In this study, we aimed to explore the effect of soil anisotropy on solute transport in degraded fen peat. Undisturbed soil cores, taken in vertical and horizontal direction, were collected from one drained and one restored fen peatland both in a comparable state of soil degradation. Saturated hydraulic conductivity (K s) and chemical properties of peat were determined for all soil cores. Miscible displacement experiments were conducted under saturated steady state conditions using potassium bromide as a conservative tracer. The results showed that (1) the K s in vertical direction (K sv) was significantly higher than that in horizontal direction (Ksh), indicating that K s of degraded fen peat behaves anisotropically; (2) pronounced preferential flow occurred in vertical direction with a higher immobile water fraction and a higher pore water velocity; (3) the 5% arrival time (a proxy for the strength of preferential flow) was affected by soil anisotropy as well as study site. A strong correlation was found between 5% arrival time and dispersivity, K s and mobile water fraction; (4) phosphate release was observed from drained peat only. The impact of soil heterogeneity on phosphate leaching was more pronounced than soil anisotropy. The soil core with the strongest preferential flow released the highest amount of phosphate. We conclude that soil anisotropy is crucial in peatland hydrology but additional research is required to fully understand anisotropy effects on solute transport.  相似文献   

8.
We studied the temporal patterns of tracer throughput in the outflow of large (30 cm diameter by 38 cm long) undisturbed cores from the Panola Mountain Research Watershed, Georgia. Tracer breakthrough was affected by soil structure and rainfall intensity. Two rainfall intensities (20 and 40 mm hr−1) for separate Cl− and Br− amended solutions were applied to two cores (one extracted from a hillslope soil and one extracted from a residual clay soil on the ridge). For both low and high rainfall intensity experiments, preferential flow occurred in the clay core, but not in the hillslope core. The preferential flow is attributed to well‐developed interpedal macrochannels that are commonly found in structured clay soils, characteristic of the ridge site. However, each rainfall intensity exceeded the matrix infiltration capacity at the top of the hillslope core, but did not exceed the matrix infiltration capacity at the middle and bottom of the hillslope core and at all levels in the clay core. Localized zones of saturation created when rainfall intensity exceeds the matrix infiltration capacity may cause water and tracer to overflow from the matrix into macrochannels, where preferential flow occurs to depth in otherwise unsaturated soil. Copyright © 1999 John Wiley & Sons, Ltd.  相似文献   

9.
Dry saline soils are common in the arid and hyper‐arid basins located in the Chilean Altiplano, where evaporation from shallow groundwater is typically the major component of the water balance. Thus, a good understanding of evaporation processes is necessary for improving water resource planning and management in these regions. In this study, we conducted laboratory experiments with a natural saline soil column to estimate evaporation rates and assess the liquid and water vapor fluxes under different water table levels. Water content, electrical conductivity and temperature at different depths were utilized to assess the liquid and water vapor fluxes in the soil column. We observed movement of water that dissolves salts from the soil and transports them to areas in the column where they accumulate. Isothermal liquid flux was predominant, while thermal and isothermal liquid and thermal water vapor fluxes were negligible, except for deep water table levels where isothermal and thermal water vapor fluxes had similar magnitude but opposite directions. Differences observed in total fluxes for all water table levels were due to different upward and downward fluxes, which depend on changes in water content and temperature within the soil profile. Both the vapor flux magnitude and direction were found to be very sensitive to the choice of empirical parameters used in flux quantification, such as tortuosity and the enhancement factor for local temperature gradients in the air phase within the column. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

10.
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11.
The relevance of bypass flow on water flow, solute or pesticide transport is becoming increasingly recognized. Recent investigations proved that soil salinization may be influenced by bypass flow, i.e. the rapid transport of water and solutes via macropores and/or shrinkage cracks to subsoil and groundwater. This paper explores the role of bypass flow in the process of accumulation and leaching of solutes, as well as of sodium, in a Mediterranean cracking soil irrigated with saline/sodic waters. The results of bypass flow experiments performed on undisturbed soil cores showed that leaching of solutes occurred in concomitance with bypass fluxes when a low salinity solution was alternated with a high salinity solution. Exchange of solutes between the incoming solution and the soil matrix occurred during the bypass flow events at the contact surfaces (cracks walls) between the solution and the soil matrix and where cracks terminated in the soil samples. Concomitant exchanges of sodium were indicated by measurements performed in the effluent solution during the bypass flow measurements. The amount of Sodium released from the soil during the bypass flow events, as well as that of the soluble salts leached from the soil, were found to depend on the degree of soil cracking. These results indicated that:
  • 1 in management of irrigation in cracking soils, under the occurrence of bypass fluxes, alternating a low salinity/sodicity water with a high salinity/sodicity solution can be effective for preventing salinization and sodification:
  • 2 greater efficiency of removal of sodium/soluble salts can be obtained if application of the leaching solution is performed when the soil is at a considerable degree of cracking.
Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   

12.
The characterization of pore-space connectivity in porous media at the sediment/water interface is critical in understanding contaminant transport and reactive biogeochemical processes in zones of groundwater and surface-water exchange. Previous in situ studies of dual-domain (i.e., mobile/less-mobile porosity) systems have been limited to solute tracer injections at scales of meters to hundreds of meters and subsequent numerical model parameterization using fluid concentration histories. Pairing fine-scale (e.g., sub-meter) geoelectrical measurements with fluid tracer data over time alleviates dependence on flowpath-scale experiments, enabling spatially targeted characterization of shallow sediment/water interface media where biogeochemical reactivity is often high. The Dual-Domain Porosity Apparatus is a field-tested device capable of variable rate-controlled downward flow experiments. The Dual-Domain Porosity Apparatus facilitates inference of dual-domain parameters, i.e., mobile/less-mobile exchange rate coefficient and the ratio of less mobile to mobile porosity. The Dual-Domain Porosity Apparatus experimental procedure uses water electrical conductivity as a conservative tracer of differential loading and flushing of pore spaces within the region of measurement. Variable injection rates permit the direct quantification of the flow-dependence of dual-domain parameters, which has been theorized for decades but remains challenging to assess using existing experimental methodologies.  相似文献   

13.
In a tropical rainforest catchment, shallow piezometers respond almost instantaneously to rainfall, but the dominant ground water recharge mechanisms are not well understood. To improve understanding, the downward movement of soil water on a runoff plot was traced using tritiated water injected at 0·20 m below the surface which marks the lower boundary of active subsurface storm flow. The tritium pulse was translated slowly down the profile, apparently dominated by interstitial piston flow on the lines described by Zimmermann's theoretical model. This recharge mechanism accounted for about 35 per cent of rainfall or 50 per cent of throughfall. The pulse's advance may have also been delayed by the upward movement of soil water indicated by the distribution of hydraulic potential under different hydrological conditions. The result was an increase in soil water transit time particularly below 1·0 m. There was also evidence in the tracer profiles for rapid by-pass flow but the volumes concerned could not be quantified in this experiment.  相似文献   

14.
Infiltration into frozen soil plays an important role in soil freeze–thaw and snowmelt-driven hydrological processes. To better understand the complex thermal energy and water transport mechanisms involved, the influence of antecedent moisture content and macroporosity on infiltration into frozen soil was investigated. Ponded infiltration experiments on frozen macroporous and non-macroporous soil columns revealed that dry macroporous soil produced infiltration rates reaching 103 to 104 mm day−1, two to three orders of magnitude larger than dry non-macroporous soil. Results suggest that rapid infiltration and drainage were a result of preferential flow through initially air-filled macropores. Using recorded flow rates and measured macropore characteristics, calculations indicated that a combination of both saturated flow and unsaturated film flow likely occurred within macropores. Under wet conditions, regardless of the presence of macropores, infiltration was restricted by the slow thawing rate of pore ice, producing infiltration rates of 2.8 to 5.0 mm day−1. Reduced preferential flow under wet conditions was attributed to a combination of soil swelling, due to smectite-rich clay (that reduced macropore volume), and pore ice blockage within macropores. In comparison, dry soil column experiments demonstrated that macropores provided conduits for water and thermal energy to bypass the frozen matrix during infiltration, reducing thaw rates compared with non-macroporous soils. Overall, results showed the dominant control of antecedent moisture content on the initiation, timing, and magnitude of infiltration and flow in frozen macroporous soils, as well as the important role of macropore connectivity. The study provides an important data set that can aid the development of hydrological models that consider the interacting effects of soil freeze–thaw and preferential flow on snowmelt partitioning in cold regions.  相似文献   

15.
Considering heterogeneity in porous media pore size and connectivity is essential to predicting reactive solute transport across interfaces. However, exchange with less‐mobile porosity is rarely considered in surface water/groundwater recharge studies. Previous research indicates that a combination of pore‐fluid sampling and geoelectrical measurements can be used to quantify less‐mobile porosity exchange dynamics using the time‐varying relation between fluid and bulk electrical conductivity. For this study, we use macro‐scale (10 s of cm) advection–dispersion solute transport models linked with electrical conduction in COMSOL Multiphysics to explore less‐mobile porosity dynamics in two different types of observed sediment water interface porous media. Modeled sediment textures contrast from strongly layered streambed deposits to poorly sorted lakebed sands and cobbles. During simulated ionic tracer perturbations, a lag between fluid and bulk electrical conductivity, and the resultant hysteresis, is observed for all simulations indicating differential loading of pore spaces with tracer. Less‐mobile exchange parameters are determined graphically from these tracer time series data without the need for inverse numerical model simulation. In both sediment types, effective less‐mobile porosity exchange parameters are variable in response to changes in flow direction and fluid flux. These observed flow‐dependent effects directly impact local less‐mobile residence times and associated contact time for biogeochemical reaction. The simulations indicate that for the sediment textures explored here, less‐mobile porosity exchange is dominated by variable rates of advection through the domain, rather than diffusion of solute, for typical low‐to‐moderate rate (approximately 3–40 cm/day) hyporheic fluid fluxes. Overall, our model‐based results show that less‐mobile porosity may be expected in a range of natural hyporheic sediments and that changes in flowpath orientation and magnitude will impact less‐mobile exchange parameters. These temporal dynamics can be assessed with the geoelectrical experimental tracer method applied at laboratory and field scales.  相似文献   

16.
Todd Redding  Kevin Devito 《水文研究》2010,24(21):2995-3010
Rainfall simulation experiments by Redding and Devito ( 2008 , Hydrological Processes 23: 4287–4300) on two adjacent plots of contrasting antecedent soil moisture storage on an aspen‐forested hillslope on the Boreal Plain showed that lateral flow generation occurred only once large soil storage capacity was saturated combined with a minimum event precipitation of 15–20 mm. This paper extends the results of Redding and Devito ( 2008 , Hydrological Processes 23: 4287–4300) with detailed analysis of pore pressure, soil moisture and tracer data from the rainfall simulation experiments, which is used to identify lateral flow generation mechanisms and flow pathways. Lateral flow was not generated until soils were wet into the fine textured C horizon. Lateral flow occurred dominantly through the clay‐rich Bt horizon by way of root channels. Lateral flow during the largest event was dominated by event water, and precipitation intensity was critical in lateral flow generation. Lateral flow was initiated as preferential flow near the soil surface into root channels, followed by development of a perched water table at depth, which also interacted with preferential flow pathways to move water laterally by the transmissivity feedback mechanism. The results indicate that lateral flow generated by rainfall on these hillslopes is uncommon because of the generally high available soil moisture storage capacity and the low probability of rainfall events of sufficient magnitude and intensity. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

17.
Electro-osmosis (EO), the movement of water through porous media in response to an electric field, offers a means for extracting contaminated ground water from fine-grained sediments, such as clays, that are not easily amenable to conventional pump-and-treat approaches. The EO-induced water flux is proportional to the voltage gradient in a manner analogous to the flux dependence on the hydraulic gradient under Darcy's law. The proportionality constant, the soil electro-osmotic conductivity or keo, is most easily measured in soil cores using bench-top tests, where flow is one-dimensional and interfering effects attributable to Darcy's law can be directly accounted for. In contrast, quantification of EO fluxes and keo in the field under deployment conditions can be difficult because electrodes are placed in ground water wells that may be screened across a heterogeneous mixture of lithologies. As a result, EO-induced water fluxes constitute an approximate radial flow system that is superimposed upon a Darcy flow regime through permeable pathways that may or may not be coupled with hydraulic head differences created by the EO-induced water fluxes. A single well comparative tracer test, which indirectly measures EO fluxes by comparing wellbore tracer dilution rates between background and EO-induced water fluxes, may provide a means for routinely quantifying the efficacy of EO systems in such settings. EO fluxes measured in field tests through this technique at a ground water contamination site were used to estimate a mean keo value through a semianalytic line source model of the electric field. The resulting estimate agrees well with values reported in the literature and with values obtained with bench-top tests conducted on a soil core collected in the test area.  相似文献   

18.
Changes in the water table level result in variable water saturation and variable hydrological fluxes at the interface between the unsaturated and saturated zone. This may influence the transport and fate of contaminants in the subsurface. The objective of this study was to examine the impact of a decreasing and an increasing water table on solute transport. We conducted tracer experiments at downward flow conditions in laboratory columns filled with two different uniform porous media under static and transient flow conditions either increasing or decreasing the water table. Tracer breakthrough curves were simulated using a mobile–immobile transport model. The resulting transport parameters were compared to identify dominant transport processes. Changes in the water table level affected dispersivities and mobile water fractions depending on the direction of water table movement and the grain size of the porous media. In fine glass beads, the water flow velocity was similar to the decline rate of the water table, and the mobile water fraction was decreased compared with steady‐state saturated conditions. However, immobile water was negligible. In coarse glass beads, water flow was faster because of fingered flow in the unsaturated part, and the mobile water fraction was smaller than in the fine material. Here, a rising water table led to an even smaller mobile water fraction and increased solute spreading because of diffusive interaction with immobile water. We conclude that changes of the water table need to be considered to correctly simulate transport in the subsurface at the transition of the unsaturated–saturated zone. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

19.
Models must effectively represent velocities and celerities if they are to address the old water paradox. Celerity information is recorded indirectly in hydrograph observations, whereas velocity information is more difficult to measure and simulate effectively, requiring additional assumptions and parameters. Velocity information can be obtained from tracer experiments, but we often lack information on the influence of soil properties on tracer mobility. This study features a combined experimental and modelling approach geared towards the evaluation of different structures in the multiple interacting pathways (MIPs) model and validates the representation of velocities with laboratory tracer experiments using an undisturbed soil column. Results indicate that the soil microstructure was modified during the experiment. Soil water velocities were represented using MIPs, testing how the (a) shape of the velocity distribution, (b) transition probability matrices (TPMs), (c) presence of immobile storage, and (d) nonstationary field capacity influence the model's performance. In MIPs, the TPM controls exhanges of water between pathways. In our experiment, MIPs were able to provide a good representation of the pattern of outflow. The results show that the connectedness of the faster pathways is important for controlling the percolation of water and tracer through the soil. The best model performance was obtained with the inclusion of immobile storage, but simulations were poor under the assumption of stationary parameters. The entire experiment was adequately simulated once a time‐variable field capacity parameter was introduced, supporting the need for including the effects of soil microstructure changes observed during the experiment.  相似文献   

20.
Part of a small drainage basin on the Sevilleta National Wildlife Refuge (about 25 km north of Socorro, NM) was intensively instrumented with soil monitoring equipment to estimate natural ground-water recharge. Soil-moisture data were analysed with special attention to characterizing the influence of topography on the direction of vadose water flow paths in fine to medium aeolian sand. Moisture content data were obtained by the neutron scattering technique, and hydraulic head data were obtained using tensiometers. In addition, tracer experiments were conducted on a sandy hillslope to delineate the flow paths of vadose water. The results indicate that there is a strong lateral component to unsaturated flow on a hillslope, even in the absence of apparent sublayers of much lower permeability. Darcian calculations estimate the long-term, steady, deep flux beneath a concave location to be about 4 per cent of an assumed mean annual precipitation of 20 cm. The deep soil water flux downward varied by several orders of magnitude during the 17 month period of record.  相似文献   

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