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福建紫金山铜矿床属高硫浅成中低温热液矿床,矿石中主要含铜矿物为蓝辉铜矿、铜蓝和硫砷铜矿等,且铜矿物与黄铁矿密切共生。由于铜矿石中硫含量较高,导致铜精矿中硫含量超标,w(S)/w(Cu)比值为2.0~2.1,远高于冶炼要求的1.15~1.20,影响其经济价值。使用X射线荧光(XRF)光谱分析对紫金山铜矿中S元素的分布进行数字化研究,查明硫的空间分布规律和赋存状态,划分铜矿石类型,为紫金山铜矿今后的采选工作提供参考。 相似文献
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在电子探针微区化学成分分析的基础上,结合 X 射线粉末衍射分析,对福建紫金山铜金矿床中的 Cu-S 体系矿物进行 了化学成分和晶体结构特征的研究。结果在该矿床中发现较完整的 Cu-S 体系矿物系列,包括铜蓝、雅硫铜矿、斯硫铜矿、 吉硫铜矿、斜方蓝辉铜矿、蓝辉铜矿、久辉铜矿和辉铜矿。此外,利用粉末 X 射线衍射数据,计算了铜蓝、斜方蓝辉铜矿、 蓝辉铜矿、久辉铜矿、辉铜矿等五种矿物的晶胞参数。基于系统矿物学的研究,建立了紫金山铜金矿床 Cu-S 体系完整矿物 的结晶与变化序列,该工作在国内尚属首次,同时也丰富了 Cu-S 体系矿物基础矿物学研究的资料。 相似文献
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《吉林大学学报(地球科学版)》2015,(Z1)
<正>1研究背景及意义福建省上杭县的紫金山铜金矿床是我国大陆发现的首例高硫化型浅成低温热液矿床,具有"上金下铜"的垂直矿化分带特征,铜矿体主要分布在+928~-400 m,铜金属量丰富,大于300万t。该矿床目前已发现Cu-S体系8种矿物[1],硫砷铜矿、块硫砷铜矿、斑铜矿、黄铜矿等21种铜矿物。铜矿物中蓝辉铜矿、铜蓝、块硫砷铜矿、硫砷铜矿占99%以上。前人对铜蓝-蓝辉铜矿的矿物成分和矿物组合分布特征有较深 相似文献
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福建紫金山铜矿是我国高硫化型浅成低温热液矿床研究的热点之一。本文针对该矿床中普遍发育的硫砷铜矿进行了仔细的矿相观察及电子探针化学成分分析,对其成因进行了初步研究。该矿床中硫化物矿物之间存在着一定的交代、穿插以及化学组分的继承关系。矿物生长遵循黄铁矿-硫砷铜矿-斜方蓝辉铜矿、蓝辉铜矿-铜蓝的交代生长顺序。结合室内水热反应模拟实验结果,推测矿床经历了2期、4阶段热液事件:第1期第1阶段形成黄铁矿;第2阶段形成硫砷铜矿;第2期第1阶段形成各种铜硫化物,铜蓝在第2期第2阶段形成。其中硫砷铜矿中的砷元素来自于岩浆热液,其显示出交代先成黄铁矿的特征,也有少量结晶于矿石的较大裂缝处形成自形柱状晶体。表生带中的硫化物矿物曝露在地表或潜水中遭受风化剥蚀,逐渐形成高硫型浅成热液,并沿构造裂隙持续下渗至岩体附近受热折返,在下渗和折返的过程中交代先成的黄铁矿和硫砷铜矿,生成斜方蓝辉铜矿和蓝辉铜矿等铜硫化物,该交代反应符合"耦合的溶解再沉淀"的成因机制。热液下渗和受热折返是1个循环往复的过程。 相似文献
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福建上杭紫金山高硫化型铜矿床矿化分带特征 总被引：3，自引：0，他引：3
通过矿相学,系统分析铜硫化物以及脉石矿物的结构构造、形态特征以及嵌布特征,主要铜硫化物为铜蓝、斜方蓝辉铜矿;通过电子探针,分析铜硫化物各种元素含量,尤其是主量元素Cu/S比值垂向变化规律在钻孔浅部无明显规律,随着深度增加Cu/S比值逐渐减小,最后趋近于一个常数约为1.3。铜矿成矿影响因素:(1)火山机构的温度影响范围有限,并未改变铜硫化物的矿物组合特征,只是影响铜硫化物Cu/S比值分配,表现为越远离火山机构Cu/S比值越高;(2)高氧逸度条件是形成稳定铜硫化物的重要条件。氧逸度垂向由上至下先是具有高氧逸度,随着深度增加氧逸度逐渐减小,最后增加为高氧逸度。Cu/S比值变化规律为今后紫金山铜矿深部找矿提供重要的矿化信息。 相似文献
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多接收杯电感耦合等离子体质谱仪(MC-ICP-MS)实现了对Cu同位素组成(δ65Cu)的精确测定,推动了Cu同位素在矿床研究中的发展和应用。在收集铜同位素近年来研究进展的基础上,系统归纳了不同铜矿床类型(岩浆熔离铜镍硫化物型矿床、接触交代型铜矿床、斑岩型铜矿床、热液型铜矿床、火山气液型铜矿床、沉积型铜矿床等)以及主要矿物(黄铜矿、辉铜矿、黄铁矿等)的Cu同位素组成特征及变化规律。研究表明,不同类型铜矿床和矿物Cu同位素组成差异较大,岩浆熔离铜镍硫化物型矿床、热液型铜矿床、沉积型铜矿床相对富集轻铜同位素,接触交代型铜矿床、斑岩型铜矿床、火山气液型铜矿床相对富集重铜同位素;黄铜矿、斑铜矿、铜蓝、硫砷铜矿、硅孔雀石等矿物相对富集重铜同位素,辉铜矿、黝铜矿、砷黝铜矿、孔雀石等矿物相对富集轻铜同位素;接触交代型铜矿床、火山气液型铜矿床中的黄铜矿相对富集重铜同位素,岩浆熔离铜镍硫化物矿床、斑岩型铜矿床、热液型铜矿床、沉积型铜矿床中的黄铜矿相对富集轻铜同位素;斑岩型铜矿床中的辉铜矿相对富集重铜同位素,热液型铜矿床、沉积型铜矿床中的辉铜矿相对富集轻铜同位素;接触交代型铜矿床中的黄铁矿相对富集重铜同位素;铜的硫化物和氧化物均相对富集轻铜同位素。 相似文献
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西藏多龙矿集区发现浅成低温热液型铜(金银)矿床 总被引：14，自引：0，他引：14
根据2013年最新勘查成果、详细的地质编录,对西藏多龙铜金矿集区铁格龙南(荣那)铜(金银)矿床地质特征、矿床类型进行了初步研究,认为该矿床是斑岩-浅成低温热液成矿系统的产物,是典型的高硫型浅成低温热液矿床。矿床规模巨大,矿石中发育条带状、层纹状、皮壳状、致密块状明矾石、地开石,深部发育黄铁绢英岩化,黄铁矿的含量为3%~35%,矿石矿物由铜蓝、蓝辉铜矿、硫砷铜矿、斯硫铜矿、雅硫铜矿、久辉铜矿、斜方蓝辉铜矿、斑铜矿、黝铜矿、黄铜矿等组成。综合研究表明,推断浅部或外围发育独立的高硫型浅成低温热液型金矿,深部存在斑岩型铜(金银)矿体。该矿体的发现结束了西藏至今没有发现典型浅成低温热液矿床的历史,对区域找矿具有极其重要的指导意义。 相似文献
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铁格隆南矿床位于班公湖-怒江成矿带西段多龙矿集区,是青藏高原发现的首例具有典型高硫型浅成低温热液矿化特征的超大型Cu(Au、Ag)矿床。笔者通过对该矿床进行系统的矿相学研究,结合电子探针显微分析,首次在该矿床发现了硫锡砷铜矿,虽然其总量不多,但其与不同矿物组合特征可反演其形成时的物化条件,对矿床成因类型判别具有一定指示意义。该矿床中的硫锡砷铜矿多为粒径约10μm的不规则细粒,无内反射,均质性,与硫砷铜矿、砷黝铜矿等Cu-As-S体系矿物伴生产出时呈乳黄色-淡黄色,与斑铜矿、黄铁矿、蓝辉铜矿等CuFe-S体系矿物伴生产出时呈乳褐色-浅褐色。根据矿物之间的交代关系发现,硫锡砷铜矿形成于黄铁矿、斑铜矿、砷黝铜矿、硫砷铜矿之后,蓝辉铜矿、铜蓝之前。电子探针分析显示,硫锡砷铜矿的基本成分包括Cu、As、V、S、Sn、Sb,普遍含有少量Fe、Ge、Zn,部分样品中含少量W、Au、Ag,以S原子数为32为基础,计算得出其分子式为Cu_(23.71～26.92)V_(1.43～2.10)(As_(2.55～5.86),Sb_(0～0.63))_(3.15～5.95)(Sn_(0～2.6),Ge_(0～0.7))_(0.01～2.60)(Fe_(0～2.4),Zn_(0～0.24))_(0～2.4)S_(32),其中,存在Sb~(5+)?As~(5+)和Sn~(4+)?Ge~(4+)、(As,Sb)~(5+)+Cu~+?(Sn,Ge)~(4+)+(Fe,Zn,Cu)~(2+)以及V~(5+)?V~(4+)+Cu~+等复杂的元素耦合置换。结合矿石矿物组合及蚀变组合分析指出,酸性或略偏中性的、中低温高硫化态环境是促使硫锡砷铜矿生成的关键控制因素。 相似文献
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The Zijinshan high-sulfidation epithermal Cu–Au deposit is located in the Zijinshan ore field of South China, comprising porphyry–epithermal Cu–Au–Mo–Ag ore systems. The Cu ore body is more than 1000 m thick and is characterized by an assemblage of digenite–covellite–enargite–alunite. Digenite is the dominant Cu-bearing mineral, which makes this deposit unique, although the mechanisms of digenite formation remain controversial. To elucidate the genesis of digenite, this paper presents the Cu isotopic compositions of Cu-sulfides in the Zijinshan high-sulfidation Cu–Au deposit. The Cu isotopic values (65Cu relative to NIST 976) of all samples range from −2.97‰ to +0.34‰, and most values fall in a narrow range from −0.49‰ to +0.34‰, which is similar to the Cu isotopic signature of typical porphyry systems. Copper isotope ratios of each mineral decrease with increasing depth, a trend that is also typical of porphyry deposits. The variation tendency of δ65Cu values between sulfides is consistent with the sequence of mineral formation. These observations suggest that the Cu-sulfides in the Zijinshan Cu–Au deposit have a hypogene origin. 相似文献
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Studies of Metallic and Trace Minerals of the Tiegelongnan Cu‐Au Deposit,Central Tibet,China 总被引：1，自引：0，他引：1
Electron probe micro-analysis(EPMA) and scanning electron microscopy(SEM) equipped with energy dispersive spectrometry(EDS) have been used to investigate the principal ore minerals and coexisting metallic mineral inclusions in polished thin sections from the Tiegelongnan deposit, which consists of a high-sulfidation epithermal system(HSES) and a porphyry system(PS). Molybdenite,chalcopyrite, bornite, tennantite, enargite, digenite, anilite, covellite, and tetrahedrite have been identified by EPMA. Intergrowth, cross-cutting and replacement relationships between the metallic minerals suggest that molybdenite formed first(stage 1),followed by chalcopyrite ± bornite ± hematite(stage 2),then bornite ± Cu-sulfides ± Cu-Fe-sulfoarsenides(stage 3),and lastly Cu-Fe-sulfoarsenides ±Cu-sulfides(stage 4). Pyrite is developed throughout all the stages. Droplet-like inclusions of Au-Te minerals commonly occur in tennantite but not in the other major sulfides(molybdenite, chalcopyrite and bornite),implying that tennantite is the most important Au telluride carrier. The pervasive binary equilibrium phases of calaverite and altaite constrain f_(Te2) in the range from ～-6.5 to ～-8 and f_(S2)-11.The intergrowth of bornite and chalcopyrite and the conversion from bornite to digenite suggest fluctuated and relatively low precipitation temperature conditions in the HSES relative to the PS.Contrastingly, the dominance of chalcopyrite in the PS, with minor bornite, suggests relatively high temperature conditions. These new results are important for further understanding the mineral formation processes superimposed by HSES and PS systems. 相似文献
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福建省上杭县罗卜岭斑岩铜钼矿床构造控矿规律研究 总被引：6，自引：0，他引：6
罗卜岭铜(钼)矿区位于紫金山矿田的东北部,是与晚中生代花岗闪长斑岩体有关的隐伏斑岩型铜钼矿床;主要斑岩矿体产于绿泥石化-绢英岩化和(弱)钾化-绢英岩化带中,矿石矿物组合为黄铜矿+辉钼矿;少量过渡类型矿体产于高级泥化带中,矿石矿物组合为蓝辉铜矿+铜蓝+辉钼矿。罗卜岭矿区地表露头含矿裂隙的统计结果显示,罗卜岭成矿晚期的含矿裂隙具有明显的方向性。远离斑岩体的含矿裂隙与其附近的区域构造方位或侵入体走向相近,表明受到北东向区域构造活动控制;而斑岩体西侧露头附近的含矿裂隙呈放射状,主要受到斑岩体侵入作用的影响。深部隐伏矿体则受到区域断裂和花岗闪长(斑)岩侵入体的共同控制,具体表现为:垂向上,以隐伏似斑状花岗闪长岩为中心,由深至浅,矿体铜钼品位比值依次变大,显示了Mo\Cu-Mo\Cu(Mo)的元素垂向分带;平面上,铜、钼元素沿着北东向、北西向断裂和岩体接触带附近有明显富集;斑岩型铜钼矿体主要产于似斑状花岗闪长岩外接触带的花岗闪长斑岩中,形态和产状受到区域北东向断裂或岩体接触带构造影响;蓝辉铜矿体主要产于罗卜岭花岗闪长斑岩外接触带的花岗闪长岩体内,形态和产状受接触带控制。区域构造和斑岩侵入体对斑岩型铜钼矿化有不同的影响,浅部铜、钼矿化受区域断裂构造控制作用明显,而深部矿体主要受花岗闪长(斑)岩体和断裂构造共同控制。区域上北东向背斜构造和北东、北西向断裂构造控制了花岗闪长质侵入岩体的侵位,矿区尺度的断裂构造对斑岩体的就位和成矿作用有一定的影响,罗卜岭花岗闪长斑岩体及其接触带则直接控制了斑岩型矿体的产出,这一规律对紫金山矿田深部和外围隐伏斑岩型矿体的勘查工作具有重要的参考意义。 相似文献
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福建省紫金山铜金矿床成矿物理化学条件的研究 总被引：4，自引：0，他引：4
紫金山高硫浅成低温热液型铜金矿床以一套独具特色的由地开石、明矾石组成的高级泥质蚀变和由硫砷铜矿、蓝辉铜矿、铜蓝组成的铜矿物组合为特征。本文根据矿床的蚀变矿物和矿石矿物组合及矿物的相互关系，着重应用热力学的原理与方法研究矿床形成的物理化学条件。认为形成这一类型矿床的流体是一种高氧逸度、高硫逸度的中低温酸性流体。 相似文献
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Joseph Onglo Espi Yoshimichi Kajiwara Mike A. Hawkins Tony Bainbridge 《Resource Geology》2002,52(4):301-313
Abstract. The Nena Cu‐Au deposit, located in the Frieda River mineral district of northwestern mainland Papua New Guinea, is a composite structurally‐lithologically controlled high sulfidation (HS) system. Its hydrothermal alteration and Cu‐Au mineralization are presented in this paper. Initially propylitized andesitic volcanics veined by epithermal quartz were pervasively superimposed by zoned HS alteration. The zonation grades from vuggy silica core to sulfur‐rich, pyritic silica‐alunite halo followed by pyrophyllite‐dickite‐kaolinite interval and finally to thin illite‐smectite margin, suggesting progressive decrease in temperature and increase in pH. This zonation is enveloped by chlorite‐epidote‐calcite‐gypsum alteration. The acid altered rocks were then invaded by multiple phases of pyrite, subsequently crosscut by quartz, vein alunite and barite. Then sequential deposition of bladed covellite, enargite, luzonite and stibioluzonite occurred from the NW to the SE portions of the deposit, forming a zonation suggestive of progressive decrease in temperature, sulfur fugacity and sulfidation stage. Most ore mineralization occurs in the vuggy silica core. Gold mineralization commenced from the transition of enargite to luzonite and continued throughout the stibioluzonite stage. Associated with gold deposition are Au‐rich pyrite, tennantite‐tetrahedrite, chalcopyrite‐bornite, native tellurium, electrum, calaverite, bismuthinite and galena. Native sulfur occupied the remaining cavities and represents the waning stage of the hydrothermal system. Fluid inclusions studies distinguished magmatic (>300–350d?C, 9–15 wt% NaCl equiv.) and meteoric (<150–200d?C, 1–2 wt% NaCl equiv.) fluids (Holzberger et al., 1996). Temperatures and salinities of fluid inclusions from barite associated with Cu sulfides show a general decrease from NW (330d?C, 9–15 wt% NaCl equiv.) to SE (172d?C, 10 wt% NaCl equiv.) parts of the deposit, indicating gradual entrainment of ground water (Hitchman and Espi, 1997). Interaction of magmatic fluids with meteoric water accompanied by changes in temperature, salinity, acidity and oxidation state of the resultant fluids is interpreted to have been the main cause of metal precipitation. Finally, supergene processes generated Au zone with an underlying chalcocite‐covellite‐digenite blanket over the primary sulfides at depth. Gold occurs as lattice constituent in scorodite, limonite‐goethite and jarosite. Chalcocite is more abundant and widespread than other Cu sulfides. Acidic fluids deposited powdery alunite and kaolinite, vein alunite and amorphous silica. Weakly secondary biotite‐quartz altered porphyry located below the known HS Cu‐Au deposit contains chalcopyrite‐bornite and is overprinted by quartz‐alunite‐pyro‐phyllite‐pyrite assemblage. This feature indicates close temporal, spatial and genetic relation between the two deposit types. 相似文献
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Geochronology and Genesis of the Tiegelongnan Porphyry Cu(Au) Deposit in Tibet: Evidence from U–Pb,Re–Os Dating and Hf,S, and H–O Isotopes 
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下载免费PDF全文 Bin Lin Ju‐Xing Tang Yu‐Chuan Chen Yang Song Greg Hall Qin Wang Chao Yang Xiang Fang Ji‐lin Duan Huan‐Huan Yang Zhi‐Bo Liu Yi‐Yun Wang Jun Feng 《Resource Geology》2017,67(1):1-21
The Tiegelongnan Cu (Au) deposit is the largest copper deposit newly discovered in the Bangong–Nujiang metallogenic belt. The deposit has a clear alteration zoning consisting of, from core to margin, potassic to propylitic, superimposed by phyllic and advanced argillic alteration. The shallow part of the deposit consists of a high sulphidation‐state overprint, mainly comprising disseminated pyrite and Cu–S minerals such as bornite, covellite, digenite, and enargite. At depth porphyry‐type mineralization mainly comprises disseminated chalcopyrite, bornite, pyrite, and a minor vein molybdenite. Mineralization is disseminated and associated with veins contained within the porphyry intrusions and their surrounding rocks. The zircon U–Pb ages of the mineralized diorite porphyry and granodiorite porphyry are 123.1 ± 1.7 Ma (2σ) and 121.5 ± 1.5 Ma (2σ), respectively. The molybdenite Re–Os age is 121.2 ± 1.2 Ma, suggesting that mineralization was closely associated with magmatism. Andesite lava (zircon U–Pb age of 111.7 ± 1.6 Ma, 2σ) overlies the ore‐bodies and is the product of post‐mineralization volcanic activity that played a critical role in preserving the ore‐bodies. Values of ?4.6 ‰ to + 0.8 ‰ δ34S for the metal sulfides (mean ? 1.55 ‰) suggest that S mainly has a deep magmatic source. The H and O isotopic composition is (δD = ?87 ‰ to ?64 ‰; δ18OH2O = 5.5 ‰ to 9.0 ‰), indicating that the ore‐forming fluids are mostly magmatic‐hydrothermal, possibly mixed with a small amount of meteoric water. The zircon εHf(t) of the diorite porphyry is 3.7 to 8.3, and the granodiorite porphyry is 1.8 to 7.5. Molybdenite has a high Re from 382.2 × 10?6 to 1600 × 10?6. Re and Hf isotope composition show that Tiegelongnan has some mantle source, maybe the juvenile lower crust from crust–mantle mixed source. Metallogenesis of the Tiegelongnan giant porphyry system was associated with intermediate to acidic magma in the Early Cretaceous (~120 Ma). The magma provenance of the Tiegelongnan deposit has some mantle‐derived composition, possibly mixed with the crust‐derived materials. 相似文献