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1.
The thermoelastic parameters of synthetic Ca3Al2Si3O12 grossular garnet were examined in situ at high-pressure and high-temperature by energy dispersive X-ray diffraction, using a Kawai-type multi-anvil press apparatus coupled with synchrotron radiation. Measurements have been conducted at pressures up to 20 GPa and temperatures up to 1,650 K: this P, T range covered the entire high-P, T stability field of grossular garnet. The analysis of room temperature data yielded V 0,300 = 1,664 ± 2 ?3 and K 0 = 166 ± 3 GPa for K￠0 K^{\prime}_{0} fixed to 4.0. Fitting of our P–V–T data by means of the high-temperature third order Birch–Murnaghan or the Mie–Grüneisen–Debye thermal equations of state, gives the thermoelastic parameters: (∂K 0,T /∂T) P  = −0.019 ± 0.001 GPa K−1 and α 0,T  = 2.62 ± 0.23 × 10−5 K−1, or γ 0 = 1.21 for fixed values q 0 = 1.0 and θ 0 = 823 (Isaak et al. Phys Chem Min19:106–120, 1992). From the comparison of fits from two different approaches, we propose to constrain the bulk modulus of grossular garnet and its pressure derivative to K T0 = 166 GPa and K￠T0 K^{\prime}_{T0}  = 4.03–4.35. Present results are compared with previously determined thermoelastic properties of grossular-rich garnets.  相似文献   

2.
Although hydrotalcite, or layered double hydroxides （LDHs）, is not a common mineral, it is an important material that can be easily synthesized in laboratory. In this study, structural evolvement and BET surface area changes of heat treated Mg/AI-LDH is evaluated by XRD, TEM and N2-BET analyses. The results indicate that the magnesium-aluminum LDH with carbonate as interlayer anion, periclase-like oxides was formed at temperatures of 400-800℃. Meanwhile, 2-3 nanometer mesoporous were formed during decomposition of LDH. However, the heat treated samples still preserve the morphology of the original LDH plates. Periclase-like formed from LDH heat treatment may re-hydrolyze and recover the structure of LDH. However, crystallinity of the recovered LDH is lower than that of the original LDH. This heat treatment will result in formation of （Mg, Al）-oxide nano-crystals and nanopores among the nano-crystals. When heating temperature exceeds 1000, the periclase-like （Mg, Al）-oxide is transformed into a composite with periclase （MgO） and spinel phases. The periclase can be re-hydrolyzed and dissolved in HCl solution. After acid treatment, the sample with a high surface area is composed of spinel nano-crystals and nanopores among them. Our results will provide a new and economic way to synthesize mesoporous materials through pathways of phase transformation of precursor materials with different composition.  相似文献   

3.
A natural Ca-poor pigeonite (Wo6En76Fs18) from the ureilite meteorite sample PCA82506-3, free of exsolved augite, was studied by in situ high-temperature single-crystal X-ray diffraction. The sample, monoclinic P21/c, was annealed up to 1,093°C to induce a phase transition from P21/c to C2/c symmetry. The variation with increasing temperature of the lattice parameters and of the intensity of the b-type reflections (h + k = 2n + 1, present only in the P21/c phase) showed a displacive phase transition P21/c to C2/c at a transition temperature T Tr = 944°C, first order in character. The Fe–Mg exchange kinetics was studied by ex situ single-crystal X-ray diffraction in a range of temperatures between the closure temperature of the Fe–Mg exchange reaction and the transition temperature. Isothermal disordering annealing experiments, using the IW buffer, were performed on three crystals at 790, 840 and 865°C. Linear regression of ln k D versus 1/T yielded the following equation: ln k\textD = - 3717( ±416)/T(K) + 1.290( ±0.378);    (R2 = 0.988) \ln \,k_{\text{D}} = - 3717( \pm 416)/T(K) + 1.290( \pm 0.378);\quad (R^{2} = 0.988) . The closure temperature (T c) calculated using this equation was ∼740(±30)°C. Analysis of the kinetic data carried out taking into account the e.s.d.'s of the atomic fractions used to define the Fe–Mg degree of order, performed according to Mueller’s model, allowed us to retrieve the disordering rate constants C 0 K dis+ for all three temperatures yielding the following Arrhenius relation: ln( C0 K\textdis + ) = ln K0 - Q/(RT) = 20.99( ±3.74) - 26406( ±4165)/T(K);    (R2 = 0.988) \ln \left( {C_{0} K_{\text{dis}}^{ + } } \right) = \ln \,K_{0} - Q/(RT) = 20.99( \pm 3.74) - 26406( \pm 4165)/T(K);\quad (R^{2} = 0.988) . An activation energy of 52.5(±4) kcal/mol for the Fe–Mg exchange process was obtained. The above relation was used to calculate the following Arrhenius relation modified as a function of X Fe (in the range of X Fe = 0.20–0.50): ln( C0 K\textdis + ) = (21.185 - 1.47X\textFe ) - \frac(27267 - 4170X\textFe )T(K) \ln \left( {C_{0} K_{\text{dis}}^{ + } } \right) = (21.185 - 1.47X_{\text{Fe}} ) - {\frac{{(27267 - 4170X_{\text{Fe}} )}}{T(K)}} . The cooling time constant, η = 6 × 10−1 K−1 year−1 calculated on the PCA82506-3 sample, provided a cooling rate of the order of 1°C/min consistent with the extremely fast late cooling history of the ureilite parent body after impact excavation.  相似文献   

4.
The structural evolution with pressure and the equations of state of three members of the brownmillerite solid solution, Ca2(Fe2−x Al x )O5, have been determined by single-crystal X-ray diffraction up to a maximum pressure of 9.73 GPa. The compositions of the samples were x = 0.00 and x = 0.37 (with Pnma symmetry) and x = 0.55 (with I2mb symmetry). No phase transitions were observed in the experiments. The equation of state parameters determined from the pressure-volume data are K 0T = 128.0 (7) GPa, K′0 = 5.8 (3) for the sample with x = 0.00, K 0T = 131 (2) GPa, K′0 = 5.5 (4) for x = 0.37, and K 0T = 137.5 (6) GPa, K′0 = 4 for x = 0.55. The bulk modulus therefore increases with Al content, being 11% higher in the x = 0.55 sample than in the Al-free sample. The unit-cell compression is anisotropic, with the c-axis being stiffer than a or b, and the anisotropy increases with increasing Al content of the structure. The structural response to pressure of all samples is similar. The (Al,Fe)O4 tetrahedra and the (Al,Fe)O6 octahedra undergo approximately isotropic compression. There is an increase in the twists of the chains of corner-sharing (Al,Fe)O4 tetrahedra, and an increase in the tilts of the (Al,Fe)O6 octahedra, because these framework polyhedra are stiffer than the Ca–O bonds to the extra-framework Ca site. The alignment of the two shortest Ca–O bonds sub-parallel to [001] accounts for the relative stiffness of the c-axis and thus the elastic anisotropy. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.  相似文献   

5.
Zeolite/TiO2 composite photocatalysts were prepared by adding a certain amount of mordenite in TiO2, and degradation experiments on toluene through photocatalytic reactions were implemented. In this paper, these photocatalysts were characterized by using SEM, IR, RAMAN, XRD and UV-Vis to shed light on the microstructure and photocatalytic performance of the composite photocatalysts. The results indicated that the structural hydroxy of zeolite can participate in bonding reaction with TiO2, the addition of zeolite can greatly reduce the diameter of nanometer TiO2 particles in the composite photocatalysts, and enhance the ultraviolet light absorptance of the composite photocatalysts. When the percentage content of zeolite reached 20%, the photocatalytic performance of this catalyst would be highest, with the toluene conversion rate up to 94.58%.  相似文献   

6.
1Introduction Researchontheapplicationofnaturalminerals(zeolite,montmorillonite,etc.)inenvironmentalpro tectionisattractinggreatattentionofmoreandmorere searchers(WuPingxiaoetal.,2001;Suhasetal.,2000).Asthenaturalmineralshavelargenumbersof micro poresandbigsurfaceareas,thezeolite/TiO2compositephotocatalystcanbepreparedbycombining TiO2withzeolite.Nucleus formationfreeenergyof TiO2crystaldecreasesinamulti phasesystemofzeo lite,whichhelpsformnanometerTiO2crystalanden richstructuralhydroxyl;op…  相似文献   

7.
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8.
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9.
Doklady Earth Sciences - The first data of U/Pb and 40Ar/39Ar dating of volcanogenic rocks of the Pre-Dzhugdzhur volcano-tectonic trough (PDVT) of the Okhotsk–Chukotka volcanogenic belt...  相似文献   

10.
Thermodynamic analysis of the system Na2O-K2O-CaO-Al2O3-SiO2-H2O-F2O–1 provides phase equilibria and solidus compatibilities of rock-forming silicates and fluorides in evolved granitic systems and associated hydrothermal processes. The interaction of fluorine with aluminosilicate melts and solids corresponds to progressive fluorination of their constituent oxides by the thermodynamic component F2O–1. The chemical potential (F2O–1) buffered by reaction of the type: MOn/2 (s)+n/2 [F2O–1]=MFn (s, g) where M=K, Na, Ca, Al, Si, explains the sequential formation of fluorides: carobbiite, villiaumite, fluorite, AlF3, SiF4 as well as the common coexistence of alkali- and alkali-earth fluorides with rock-forming aluminosilicates. Formation of fluorine-bearing minerals first starts in peralkaline silica-undersaturated, proceeds in peraluminous silica-oversaturated compositions and causes progressive destabilization of nepheline, albite and quartz, in favour of villiaumite, cryolite, topaz, chiolite. Additionally, it implies the increase of buffered fluorine solubilities in silicate melts or aqueous fluids from peralkaline silica-undersaturated to peraluminous silica-oversaturated environments. Subsolidus equilibria reveal several incompatibilities: (i) topaz is unstable with nepheline or villiaumite; (ii) chiolite is not compatible with albite because it only occurs only at very high F2O–1 levels. The stability of topaz, fluorite, cryolite and villiaumite in natural felsic systems is related to their peralkalinity (peraluminosity), calcia and silica activity, and linked by corresponding chemical potentials to rock-forming mineral buffers. Villiaumite is stable in strongly peralkaline and Ca-poor compositions (An<0.001). Similarly, cryolite stability requires coexistence with nearly-pure albite (An<2). Granitic rocks with Ca-bearing plagioclase (An>5) saturate with topaz or fluorite. Crystallization of topaz is restricted to peraluminous conditions, consistent with the presence of Li-micas or anhydrous aluminosilicates (cordierite, garnet, andalusite). Fluorite is predicted to be stable in peraluminous biotite granites, amphibole-, clinopyroxene- or titanite-bearing calc-alkaline suites as well as in peralkaline granitic and syenitic rocks. Fluorine concentrations in felsic melts buffered by the coexistence of F-bearing minerals and feldspars increase from peralkaline through metaluminous to mildly peraluminous compositions. At low-temperature conditions, the hydrothermal evolution of peraluminous granitic and greisen systems is controlled by white mica-feldspar-fluoride equilibria. With decreasing temperature, topaz gradually breaks down via: (i) (OH)F–1 substitution and fluorine transfer to fluorite by decalcification of plagioclase below 600 °C, (ii) formation of muscovite and additional fluorite at 475–315 °C, and (iii) formation of paragonite and cryolite, consuming F-rich topaz and albite below 315 °C. These equilibria explain the absence of magmatic fluorite in Ca-bearing topaz granitic rocks; its abundance in hydrothermal rocks is due to: (i) closed-system defluorination of topaz, (ii) open-system decalcification of plagioclase or (iii) hydrolytic alteration. These results provide a complete framework for the investigation of fluorine-bearing mineral stabilities in felsic igneous suites.Electronic Supplementary Material Supplementary material is available in the online version of this article at . A link in the frame on the left on that page takes you directly to the supplementary material.Editorial responsibility: T.L. Grove  相似文献   

11.
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12.
The degradation of ground water quality due to human activities is a widespread environmental problem. Furthermore, coastal aquifers are threatened by sea water intrusion as a result of increasing water exploitation. The investigation area near Dörtyol is located at the Mediterranean coast, southern Turkey, and dominated by agricultural land use. Drinking, domestic and agricultural purposes require different amounts of uncontaminated water. In this study the hydrogeological characteristics of the coastal plain were investigated. Discharge and ground water level measurements as well as geological investigations were undertaken in field in addition to anion and cation analyses of ground and surface water. The results show geological and anthropogenic influence on ground and surface water composition. In spite of a large number of wells in the coastal area sea water intrusion was not detected. With the goal of devising sustainable water use regulations, more emphasis and research needs to be directed to the long-term observation of ground and surface water quality as well as the detailed investigation of hydraulic characteristics of the local aquifer.  相似文献   

13.
Bayesian lithology/fluid inversion—comparison of two algorithms   总被引：1，自引：0，他引：1  
Algorithms for inversion of seismic prestack AVO data into lithology-fluid classes in a vertical profile are evaluated. The inversion is defined in a Bayesian setting where the prior model for the lithology-fluid classes is a Markov chain, and the likelihood model relates seismic data and elastic material properties to these classes. The likelihood model is approximated such that the posterior model can be calculated recursively using the extremely efficient forward–backward algorithm. The impact of the approximation in the likelihood model is evaluated empirically by comparing results from the approximate approach with results generated from the exact posterior model. The exact posterior is assessed by sampling using a sophisticated Markov chain Monte Carlo simulation algorithm. The simulation algorithm is iterative, and it requires considerable computer resources. Seven realistic evaluation models are defined, from which synthetic seismic data are generated. Using identical seismic data, the approximate marginal posterior is calculated and the exact marginal posterior is assessed. It is concluded that the approximate likelihood model preserves 50% to 90% of the information content in the exact likelihood model.  相似文献   

14.
 X-band electron paramagnetic resonance experiments on a gamma-irradiated α-quartz crystal have revealed a new hydrogarnet-like defect. Analysis of the spectral data suggests that the centre consists of an oxygenic electron hole adjacent to a silicon vacancy, charge-compensated by a proton and two lithium +1 ions. The principal directions of the spin-Hamiltonian g matrix indicate that the oxygenic hole occurs on the oxygen ion that would be long-bonded to the missing silicon atom. Modelling of the proton and lithium hyperfine matrices via three different methods has provided a detailed physical view for the structure of the defect centre, which is presented here. Received: 12 June 2002 / Accepted: 10 January 2003 RID="‡" ID="‡" Deceased August 2001  相似文献   

15.
To understand the aqueous species important for transport of rhenium under supercritical conditions, we conducted a series of solubility experiments on the Re–ReO2 buffer assemblage and ReS2. In these experiments, pH was buffered by the K–feldspar–muscovite–quartz assemblage; in sulfur-free systems was buffered by the Re–ReO2 assemblage; and and in sulfur-containing systems were buffered by the magnetite–pyrite–pyrrhotite assemblage. Our experimental studies indicate that the species ReCl4 0 is dominant at 400°C in slightly acidic to near-neutral, and chloride-rich (total chloride concentrations ranging from 0.5 to 1.0 M) environments, and ReCl3 + may predominate at 500°C in a solution with total chloride concentrations ranging from 0.5 to 1.5 M. The results also demonstrate that the solubility of ReS2 is about two orders of magnitude less than that of ReO2. This finding not only suggests that ReS2 (or a ReS2 component in molybdenite) is the solubility-controlling phase in sulfur-containing, reducing environments but also implies that a mixing process involving an oxidized, rhenium-containing solution and a solution with reduced sulfur is one of the most effective mechanisms for deposition of rhenium. In analogy with Re, TcS2 may be the stable Tc-bearing phase in deep geological repositories of radioactive wastes.  相似文献   

16.
Quantitative analyses of soil texture with the help of the fractal dimensions of soil particle sizes show that fractal dimensions exhibit a significant linear negative correlation with the sand content (>0.1 mm) and a significant power-law positive correlation with the content of clay and silt (<0.05 mm) (P < 0.0001). However, results revealed that the range of spatial heterogeneity was not restricted to the range of the shrub canopies of the dominant Ammopiptanthus mongolicus communities in the desert region. These results did not support the theory of the “fertile island effect” arising from the interception of fine-grained materials including dust by the shrubs in a desert ecosystem. We hypothesize that the high spatial heterogeneity existing beyond the scope of the shrub canopies and the lack of proper soil substrate conditions required for the invasion of other species, lead to the steady dominance of A. mongolicus communities in these arid desert regions.  相似文献   

17.
Doklady Earth Sciences -  相似文献   

18.
(U-Th)/He dating is a newly developed low temperature thermochronometry,and it elaborately reflects cooling history of geologic body under low temperature.It can be applied to analyze thermal evolution of the sedimentary basin,combining with vitrinite reflectance and fission track.(U-Th)/He dating of apatite and zircon from drilling cores in Puguang (普光)-Maoba (毛坝) area and outcrops in Tongjiang (通江) area indicates that the Northeast Sichuan (四川) basin underwent great uplift and denudation during the Tertiary and the Quaternary.During the period,denudation rates changed from 74.8 to 172.5 m/Ma and denudation thickness was between 2 800 and 3 000 m,geotemperature gradually declined into the current temperature,passing through helium closure temperature of apatite.The uplift and denudation relate to new tectonic movement response in the Sichuan basin aroused by the Qinghai (青海)-Tibet plateau.Drilling samples above 4 000 m did not undergo closure temperature of zircon,but the samples nearly 4 000 m might approach closure temperature of zircon and all the samples underwent closure temperature of apatite.According to (U-Th)/He ages of zircon,it is concluded that the Northeast Sichuan basin began to uplift in the Late Jurassic.From the Late Jurassic to the Paleogene,Northeast Sichuan basin was in slow uplift and denudation,but the denudation of Puguang-Maoba area was earlier than that of Tongjiang area.(U-Th)/He ages of zircon indicate the denudation time of provenance areas.On the basis of paleodrainage characteristics,provenance transport and other related data,provenance areas of the clastic rocks are decided,which is worthy to be investigated further.  相似文献   

19.
Sediment from three different trophic states （Meiliang Bay, Xukou Bay and Gonghu Bay） in spring, summer, autumn and winter were collected and analyzed in Taihu Lake. At the same time, seasonal variations in adsorption/desorption equilibrium were investigated with corresponding sediments from these three trophic states, including adsorption efficiency, adsorption/desorption equilibrium concentration and equilibrium adsorption quantity. Variations of TP and P fractions＇ concentrations in the initial and end of adsorption experiment were also documented in order to find the most active P fractions. The following conclusions were obtained： （1） Concentrations of total phosphorus （TP） and its fractions in the sediments were coincided with the trophic state of corresponding overlying water, Meiliang Bay〉Gonghu Bay〉Xukou Bay. The Meiliang Bay located in the north of Taihu Lake is in the eutrophic state and belong to alga-type lake; the Xukou Bay located in the northeast of Taihu Lake is relatively clean lake region; the Gonghu Bay is located in the east of Taihu Lake is in the meso-trophic state. Fe-P concentrations in the Meiliang Bay, Gonghu By and Xukou Bay account for 35.1%-70.9%, 19.6%-26.8%, 16.5%-34.3% of TP, Ca-P account for 20.6%-43.7%, 40.7%-45.0%, 23.0%-41.1% and OP accounts for 15.3%-20.2%, 28.4%-37.4%, 23.6%-54.3%, which changes obviously in different seasons. Fe-P is the major fraction in the eutrophic lake region, which is significantly correlated with the TP concentrations. （2） Adsorption and desorption processes in these three lake regions varied with season.  相似文献   

20.
The unsaturated poromechanical behavior of Callovo-Oxfordian argillite (also referred to as Meuse/Haute–Marne argillite) is analyzed by means of indentation tests at different hygrometries. Numerical simulations carried out with a finite element code are then used to simulate flat punch indentation tests at different controlled hygrometries. The numerical response F(h) is compared to experimental data in order to estimate the drained Young’s modulus E and the internal friction angle \Upphi\Upphi (at high confinement) by means of a back analysis. A linear decrease in the drained Young’s modulus and quasi-constant values of the internal friction angle are observed when the relative humidity ranges. Some predictions of the model are also presented to quantify the activation of hydraulic phenomena. Indeed, the maximal variation of the saturation and porosity relative to the initial state of the specimen are lower than 10% and 8%, respectively.  相似文献   

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