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1.
The extensive use of pesticides for increasing the agricultural production is affecting the quality of groundwater. The objectives of this article are to (i) develop pesticide relative leaching ranks for well sites, (ii) develop maps for human health risks due to pesticide applications, and (iii) identify the most significant parameters in pesticide simulations for groundwater vulnerability assessment. The methods include (i) development of acifluorfen relative leaching ranks for 25 well sites using ArcPRZM‐3, (ii) development of health risk maps using model simulated maximum dissolved bentazon concentrations on the basis of USA drinking water quality guidelines, (iii) sensitivity analysis for 14 ArcPRZM‐3 input parameters using the Plackett–Burman method. ArcPRZM‐3 is a user‐friendly system for spatial modeling of pesticide leaching from surface to groundwater. Thirteen acifluorfen relative leaching potential ranks were developed in which the pesticide leaching decrease from 1 to 13. The model predicted ranks for well 34 and well 9 were 2nd and 3rd, respectively, and acifluorfen was detected in both wells during the physical monitoring. The percentages of high health risks in the agricultural areas were 48.38 and 72.72% for Randolph and Independence Counties, respectively. The most significant parameters were thickness of horizon compartment, runoff curve number of antecedent moisture condition II for cropping, soil bulk density, and total application of pesticide. The irrigation, soil permeability, and numerical dispersion could impact the pesticide leaching in soils toward groundwater. The ArcPRZM‐3 system could be efficiently applied for spatial modeling and mapping of pesticide concentrations for groundwater vulnerability assessment on a large scale. 相似文献
2.
Numerical simulation of agricultural sediment and pesticide runoff: RZWQM and PRZM comparison 
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下载免费PDF全文 Agricultural sediment and pesticide runoff is a widespread ecological and human health concern. Numerical simulation models, such as Root Zone Water Quality Model (RZWQM) and Pesticide Root Zone Model (PRZM), have been increasingly used to quantify off‐site agricultural pollutant movement. However, RZWQM has been criticized for its inability to simulate sedimentation processes. The recent incorporation of the sedimentation module of Groundwater Loading Effects of Agricultural Management Systems has enabled RZWQM to simulate sediment and sediment‐associated pesticides. This study compares the sediment and pesticide transport simulation performance of the newly released RZWQM and PRZM using runoff data from 2 alfalfa fields in Davis, California. A composite metric (based on coefficient of determination, Nash–Sutcliffe efficiency, index of agreement, and percent bias) was developed and employed to ensure robust, comprehensive assessment of model performance. Results showed that surface water runoff was predicted reasonably well (absolute percent bias <31%) by RZWQM and PRZM after adjusting important hydrologic parameters. Even after calibration, underestimation bias (?89% ≤ PBIAS ≤ ?36%) for sediment yield was observed in both models. This might be attributed to PRZM's incorrect distribution of input water and uncertainty in RZWQM's runoff erosivity coefficient. Moreover, the underestimation of sediment might be less if the origin of measured sediment was considered. Chlorpyrifos losses were simulated with reasonable accuracy especially for Field A (absolute PBIAS ≤ 22%), whereas diuron losses were underestimated to a great extent (?98% ≤ PBIAS ≤ ?65%) in both models. This could be attributed to the underprediction of herbicide concentration in the top soil due to the limitations of the instantaneous equilibrium sorption model as well as the high runoff potential of herbicide formulated as water‐dispersible granules. RZWQM and PRZM partitioned pesticides into the water and sediment phases similarly. According to model predictions, the majority of pesticide loads were carried via the water phase. On the basis of this study, both RZWQM and PRZM performed well in predicting runoff that carried highly adsorptive pesticides on an event basis, although the more physically based RZWQM is recommended when field‐measured soil hydraulic properties are available. 相似文献
3.
Herman Bouwer 《Ground Water Monitoring & Remediation》1990,10(1):71-79
Anthropogenic agricultural chemicals of concern in ground water include nitrate and pesticides. Increased legislation and regulation of contaminant levels in ground water can be expected. Ground water contamination should be prevented from getting worse, but more research is necessary so as to base regulations on sound criteria. Health effects and acceptable risks must be better formulated. More research on chemical movement in the vadose zone is necessary for accurate predictive modeling of pesticide transport to ground water. Best management practices need to be developed so that farmers will be able to farm profitably while complying with regulations for maximum contaminant levels in underlying ground water. People from all concerned disciplines, citizens'groups, and policy-makers need to work together to develop realistic regulatory policies and management practices that will effectively protect public health while ensuring a viable and sustainable agriculture. 相似文献
4.
Worldwide pesticide usage has increased dramatically during the last three decades, coinciding with changing practices and increasing by intensive agriculture. This widespread use of pesticides for agricultural and non‐agricultural purposes has resulted in the presence of their residues in various environmental matrices. The occurrence of pesticides and their metabolite transported in rivers, channels, lakes, sea, air, soils, groundwater, and even drinking water, proves the high risk of these chemicals to human health and the environment. Therefore, pesticide removal is of an increasing concern. In this study, a review of the published literature dealing with pesticides removal process is presented. Firstly, pesticide removal by conventional means is briefly considered. Secondly, the use of the low‐cost sorbent through biosorption process is discussed comprehensively. The effect of factors such as pH, contact time, sorbent dosage, initial pesticide concentration, and optimization of biosorption conditions is also discussed. Kinetic, thermodynamic, and mechanism studies are also given. This study shows that both microorganisms and other materials with biological origin like agricultural by‐products may be used to this end. There is a significant potential for pesticide uptake by the use of various pristine and especially modified biosorbents. In the case of living organisms used as removal agents, degradation may also play a role in the total removal observed. 相似文献
5.
Agricultural pollutant runoff is a major source of water contamination in California's Sacramento River watershed where 8500 km2 of agricultural land influences water quality. The Soil and Water Assessment Tool (SWAT) hydrology, sediment, nitrate and pesticide transport components were assessed for the Sacramento River watershed. To represent flood conveyance in the area, the model was improved by implementing a flood routing algorithm. Sensitivity/uncertainty analyses and multi‐objective calibration were incorporated into the model application for predicting streamflow, sediment, nitrate and pesticides (chlorpyrifos and diazinon) at multiple watershed sites from 1992 to 2008. Most of the observed data were within the 95% uncertainty interval, indicating that the SWAT simulations were capturing the uncertainties that existed, such as model simplification, observed data errors and lack of agricultural management data. The monthly Nash–Sutcliffe coefficients at the watershed outlet ranged from 0.48 to 0.82, indicating that the model was able to successfully predict streamflow and agricultural pollutant transport after calibration. Predicted sediment loads were highly correlated to streamflow, whereas nitrate, chlorpyrifos and diazinon were moderately correlated to streamflow. This indicates that timing of agricultural management operations plays a role in agricultural pollutant runoff. Best management practices, such as pesticide use limits during wet seasons, could improve water quality in the Sacramento River watershed. The calibrated model establishes a modelling framework for further studies of hydrology, water quality and ecosystem protection in the study area. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
6.
辽西北地区农业干旱灾害风险评价与风险区划研究 总被引：5，自引：0，他引：5
以辽西北29个农业县（市、区）为研究区域,选取辽西北最主要的玉米作物作为研究对象,从造成农业干旱灾害的致灾因子危险性、承灾体暴露性、脆弱性和抗旱减灾能力4个方面着手,利用自然灾害风险指数法、加权综合评价法和层次分析法,建立了农业干旱灾害风险指数（ADRI）,用以表征农业干旱灾害风险程度;借助GIS技术,绘制辽西北农业干旱灾害风险评价区划图,将风险评价区划图与2006年辽西北受干旱影响粮食减产系数区划图对比,发现两者可以较好的匹配。研究结果可为当地农业干旱灾害预警、保险,以及有关部门的旱灾管理、减灾决策制定提供理论依据和指导。 相似文献
7.
基于遥感和GIS的建筑物震害损失评估方法研究与实现 总被引：9，自引：0，他引：9
介绍了一种使用遥感技术进行震后损失快速评估的方法,评估流程包括震害提取和损失评估两个部分。评估方式根据需求可以分为基于震害指数的评估和基于图像分类结果的评估两种模式,前者通过震害指数与烈度的关系得到地面居民住地的宏观震害情况,结合地震应急数据进行建筑物损失评估;后者采用图像处理技术,选取典型震害样本以图像分类技术得到地面居民住地的分级分类的震害结果,然后计算参数进行损失评估。损失评估的计算根据震害提取模式而不同。这种遥感震害评估方法和计算流程结合了遥感和GIS技术,以满足实际工作需求目标,提高了震害提取的自动化程度,实现多人工作模式,通过有效率的人机交互来提高遥感震害评估的速度。 相似文献
8.
In this research, an integrated simulation–optimization modeling approach (ISOMA) was developed for supporting agricultural N2O emission mitigation at the watershed scale. This approach can successfully combine soil N2O emission simulation and the consequential mitigation management within a general modeling framework. Also, uncertainties associated with the key soil parameter can be effectively reflected and addressed through adoption of Monte Carlo analysis for the simulation results. The Monte Carlo simulated results were then used to generate fuzzy membership functions that can be consequentially used for emission mitigation management, reflecting the combined uncertainties for N2O emission simulation and mitigation management. The developed ISOMA was then applied to a reservoir watershed in Miyun county of Beijing municipality. In the studying watershed, the simulation model was calibrated and verified. Then, N2O emission from multiple agricultural land-use patterns were predicted. The amounts of N2O emission of four land use patterns (i.e., cash tree, orchard, cropland, and natural forest) were (536.9, 590.8, 653.1), (237.7, 254.4, 275.9), (79.5, 100.7, 105.1), (33.0, 47.3, 61.1) kg CO2 eq ha?1 year?1, respectively. Two scenarios (i.e., G1 and G2) were set up according to development priorities of local economy and society. Meanwhile, multiple credibility levels were considered according to the risk of N2O emission. The land use patterns could be adjusted according to solutions of ISOMA. The developed methods could help regional manager choose various production patterns with cost-effective agriculture N2O emission management schemes in the Miyun reservoir watershed. The manager also can obtain deeply insights into the tradeoffs between agricultural benefits and system reliabilities. 相似文献
9.
逸度模型在湖泊流域农药多介质归趋研究中的应用与展望 总被引：1，自引：0，他引：1
农药的施用在促进农业经济发展的同时,也带来了诸多环境问题.农药由农业活动排放进入到环境后会通过不同的途径在各介质之间进行迁移和转化,最后由径流作用汇聚于湖泊中,破坏生态环境,影响人类健康.因此,研究湖泊流域生态系统中农药的多介质归趋具有重要意义.使用基于逸度的多介质模型模拟农药在环境中的行为是一个十分有效的方法.逸度模型利用"逸度"的概念描述污染物在各个环境介质之间的迁移和转化过程趋势,其结果建立在化学物质自身物化性质和环境系统性质之上,不仅适用于预测农药在环境各介质中的残留水平,还可以揭示区域内污染的空间分布特征,是湖泊流域生态系统管理中一个重要的工具.本文综述了逸度模型的理论基础,对近年来国内外逸度模型的发展现状、相关环境模型及其在农药归趋研究和湖泊流域生态系统管理中的运用进行了总结,并展望了逸度模型在农药多介质研究中的应用前景,以期对我国农药的管理、合理施用方面提供科学与技术支持. 相似文献
10.
O. Banton P. Lafranee R. Martel J.P. Villeneuve 《Ground Water Monitoring & Remediation》1992,12(3):195-202
Soil-pore water sampling by suction lysimeters monitors the fate of soil contaminants as a function of depth and time. However, sampling campaigns must be planned to most effectively monitor the migration of contaminants with a minimum expenditure of resources. The vertical migration of pesticides was studied at two sites treated with systemic s-triazine herbicides and equipped with suction lysimeters. The measured concentrations were compared with those calculated by a simulation model. This modeling was based on the processes that control the transport and fate of pesticide within the soil. The usefulness of such a tool was demonstrated by the good approximation obtained for pesticide concentrations and arrival times. Moreover, the significant spatial variability of concentrations observed justifies the use of a stochastic approach in modeling that takes into account the spatial variability of soil parameters. Also, the rapid transformation of herbicides observed in unsaturated soil zones demonstrates the importance of taking into account the sum of the toxic residues when evaluating the fate of s-triazines in soil. 相似文献
11.
Abstract Proper agricultural land management strategies improve soil structural properties, thereby reducing soil loss by water erosion. This study was conducted to estimate soil losses from plots of different agricultural land management using the Water Erosion Prediction Project (WEPP) (95.7) model. The study took place in a semiarid region in Kenya. The mean annual rainfall was 694 mm. The WEPP (95.7) model was initially used to estimate total sediment loading from the catchment into a reservoir. The estimate was about 2871 t corresponding to an average sedimentation rate of 1063 t km?2 year?1, which was about 76% of the measured total sediment inflow into the reservoir. Soil losses were estimated within 10 plots on the catchment of different sizes and slopes with the following treatments: conventional tillage (hand hoeing) with maize and soybean intercropping (HOCOBE); conservation tillage (disc plough) with maize and soybean intercropping (COBEAN); conservation tillage with only maize cultivation (CNTCORN); and conservation tillage with only soybean cultivation (CNTBEAN). The soil loss reduction of COBEAN, CNTCORN and CNTBEAN relative to HOCOBE ranged between 27–47%, 16–29% and 12–25%, respectively, depending on the size and slope of the plot. In general, conservation tillage reduced soil loss relative to conventional tillage. However, with conservation tillage, the single cropping system resulted in greater soil loss than the intercropping system. In the case of single cropping with conservation tillage, the soil loss reduction for maize ranged between 4 and 9%, relative to soybean. Overall, the study showed that there would be a significant reduction of soil losses from plots if conservation tillage with an intercropping system (maize and soybean) were to be adopted on agricultural lands in semiarid regions. 相似文献
12.
Mohamed M. Hantush Rao. S. Govindaraju Miguel A. Marioand Zhonglong Zhang 《Journal of Hydrology》2002,260(1-4):58-74
This paper develops mass fraction models for transport and fate of agricultural pollutants in structured two-region soils. Mass fraction index models, based on a semi-infinite domain solution, are derived that describe leaching at depth, vapor losses through soil surface, absorption, and degradation in the dynamic- and stagnant-water soil regions. The models predict that leaching is the result of the combined effect of the upward vapor-phase transport relative to downward advection, residence time relative to half-life, dispersion, and lateral diffusive mass transfer. Simulations show that leached fraction of volatile compounds does not always decrease monotonically with increased residence time relative to the pollutant half-life, as a result of complex interactions among the different physical and biochemical processes. The results show that leaching, volatilization, and degradation losses can be affected significantly by lateral diffusive mass transfer into immobile-water regions and advection relative to dispersion (i.e. Peclet number) in the mobile-water regions. It is shown that solute diffusion into the immobile phase and subsequent biochemical decay reduces leaching and vapor losses through soil surface. Potential use of the modified leaching index for the screening of selected pesticides is illustrated for different soil textures and infiltration rates. The analysis may be useful to the management of pesticides and the design of landfills. 相似文献
13.
Eduardo Luquin Miguel A. Campo-Bescós Rafael Muñoz-Carpena Ronald L. Bingner Richard M. Cruse Henrique G. Momm Robert R. Wells Javier Casalí 《地球表面变化过程与地形》2021,46(10):1909-1925
Ephemeral gully (EG) erosion has an important impact on agricultural soil losses and increases field surface hydrology connectivity and transport of pollutants to nearby water bodies. Watershed models including an EG component are scarce and not yet properly evaluated. The objective of this study is to evaluate the capacity of one such tool, AnnAGNPS, to simulate the evolution of two EG formed in a conservation tillage system. The dataset for model testing included runoff measurements and EG morphological characteristics during 3 years. Model evaluation focused on EG evolution of volume, width, and length model outputs, and included calibration and testing phases and a global sensitivity analysis (GSA). While the model did not fully reproduce width and length, the model efficiency to simulate EG volume was satisfactory for both calibration and testing phases, supporting the watershed management objectives of the model. GSA revealed that the most sensitive factors were EG depth, critical shear stress, headcut detachment exponent coefficient b, and headcut detachment leading coefficient a. For EG outputs the model was additive, showing low sensitivity to interactions between the inputs. Prediction of EG spatial evolution on conservation tillage systems requires improved development of gully erosion components, since many of the processes were developed originally for traditional tillage practices or larger channel systems. Our results identify the need for future research when EG form within conservation tillage systems, in particular to study gully headcut, soil erodibility, and width functions specific to these practices. 相似文献
14.
基于三维GIS技术的地震灾情场景模拟系统 总被引：4，自引：0，他引：4
设计并实现了基于三维GIS技术的地震灾情场景模拟系统。根据现场救援工作的特点和需求,对基于基础地理信息数据的自动三维建模方法和场景生成技术进行了研究,建立了基于地震动影响场和结构易损性的地震灾情场景模型;基于ArcGISEngine开发组件,实现了灾前、灾后场景的自动生成和直观显示,实现了整体破坏情况分析、重点搜索区域判定、关键目标震害与属性查询等灾情分析和辅助决策功能。该系统以震区基础地理信息数据和地震基本参数作为数据源,可以在获得地震基本参数之后快速地估计和分析震区建筑结构的破坏及其空间分布情况,预判重点搜索救援区域,为应急指挥决策和救援行动提供有效的支持,适合在现场救援工作中实际应用。 相似文献
15.
GIS‐based modelling of soil erosion processes using the modified‐MMF (MMMF) model in a large watershed having vast agro‐climatological differences 下载免费PDF全文
下载免费PDF全文 The present study demonstrates a spatially distributed application of a field‐scale annual soil loss model, the modified‐MMF (MMMF), to a large watershed using hydrological routing techniques, remote sensing data and geospatial technologies. In this study, the MMMF model is implemented after incorporating the corrections suggested in recent literature along with appropriate modifications of the model to suit the agro‐climatological conditions prevailing in most parts of India. Sensitivity analysis carried out through an Average Linear Sensitivity approach indicates that the model outputs are highly sensitive to soil moisture (MS), bulk density (BD), effective hydraulic depth (EHD), ground cover (GC) and settling velocity for clay (VSc). During calibration and validation, the performance evaluation statistics are mostly in the range of very good to satisfactory for both runoff and soil loss at the watershed outlet. Even spatial validation of the results of intermediate processes in the water phase and the sediment phase, although qualitative, seems to be reasonable and rational. Furthermore, the soil erosion severity analysis for different land‐uses existing in the watershed indicates that about 90% of the watershed area, especially that occupied by agricultural lands, is vulnerable to the long‐term effects of soil erosion. Copyright © 2018 John Wiley & Sons, Ltd. 相似文献
16.
An integrated fuzzy simulation-assessment method (FSAM) was developed for assessing environmental risks from petroleum hydrocarbon contamination in ground water. In the FSAM, techniques of fuzzy simulation and fuzzy risk assessment were coupled into a general framework to reflect a variety of system uncertainties. A petroleum-contaminated site located in western Canada was selected as a study case for demonstrating applicability of the proposed method. The risk assessment results demonstrated that system uncertainties would significantly impact expressions of risk-level outputs. A relatively deterministic expression of the risks would have clearer representations of the study problem but may miss valuable uncertain information; conversely, an assessment under vaguer system conditions would help reveal potential consequences of adverse effects but would suffer from a higher degree of fuzziness in presenting the modeling outputs. Based on the risk assessment results, a decision analysis procedure was used to calculate a general risk index (GRI) to help identify proper responsive actions. The proposed method was useful for evaluating risks within a system containing multiple factors with complicated uncertainties and interactions and providing support for identifying proper site management strategies. 相似文献
17.
Xingwei Wang Hao Yang Yanpeng Cai Chunxue Yu Wencong Yue 《Stochastic Environmental Research and Risk Assessment (SERRA)》2016,30(1):137-153
In this study, an environmental-friendly modeling system was developed and applied to an agriculture nonpoint source (AGNPS) management in Ulansuhai Nur watershed. In this system, water environmental capacity, credibility-based chance-constrained programming (CCCP), and AGNPS optimization models were integrated into a general modeling framework. It could be used to calculate water environmental capacity of total nitrogen and total phosphorus in Ulansuhai Nur watershed, which could consequentially provide input data for the developed AGNPS optimization model. Also, the inherent uncertainties in estimating water environmental capacities that can be expressed as possibilistic distributions were reflected and addressed based on computational results of three widely used methods. Such uncertainties were consequentially transferred to the proposed CCCP model based on the adoption of multiple credibility satisfactory levels, significantly facilitating objectivity reflection of decision alternatives. The developed modeling system was then applied to Ulansuhai Nur watershed of Inner Mongolia, a semi-arid river basin in northwestern China. Optimal strategies for AGNPS management in Ulansuhai Nur watershed were generated with consideration of the maximum total agricultural income under multiple policy scenarios. The results showed that the total agricultural income would increase with point source pollution being cut down, and would decrease with rising credibility levels, representing decreasing system violation risks. It was indicated that the higher of total nitrogen/phosphorus discharge being less than water environmental capacity of Ulansuhai Nur, the lower the total agriculture incomes. The proposed methods could help decision makers establish various production patterns with cost-effective agriculture nonpoint source management schemes in the basin of Ulansuhai Nur, and gain in-depth insights into the trade-offs between total agricultural incomes and system reliabilities. 相似文献
18.
《Ground Water Monitoring & Remediation》1989,9(4):141-146
Pollution of ground water by agricultural practices has gained considerable attention in recent years. Mathematical models have been developed to evaluate the effects of agricultural best management practices on pesticide transport to ground water. The GLEAMS model was evaluated to determine its suitability for use in predicting managerial effects on pesticide leaching from agricultural systems in the Atlantic Coastal Plain. Model predictions of pesticide concentrations in percolation from the root zone were compared to observed concentrations in ground water beneath field-sized areas. The model underpredicted runoff from these areas. Model predictions were used to produce rankings of the magnitudes of pesticide losses that paralleled rankings of observed ground water data in some cases but not others. Differences in observed and predicted rankings were assessed to be the result of sampling schedule inefficiences. The magnitudes of predicted pesticide concentrations in leachate from the root zone were three to seven times higher than observed concentrations in shallow ground water. Results support the use of GLEAMS for comparison of managerial effects on pesticide movement to ground water if appropriate limitations are recognized. 相似文献
19.
传统水资源信息管理模型采用GIS网络技术,对水资源信息进行优化配置,未对地震多发区域水资源管网进行综合规划,存在地震破坏后受污染水资源信息管理性能差的问题。设计考虑区域水资源地震破坏后污染的信息管理模型,模型包括受污染水资源信息规划设计模块、信息监测和采集模块、信息管理模块。3个模块分别实现对地震破坏后污染的水资源管网的合理规划、监测和采集以及污染信息的综合管理。实验结果表明,所设计模型对区域水资源地震破坏后污染的信息管理的平均时间达到1.38 s,且在管理过程中各项功能的评分都高于93.5分,具有较高的管理性能。 相似文献
20.
基于GIS的地质数据库系统:研究现状和发展趋势 总被引：31，自引：5，他引：31
有效地存储、管理、交流、进而充分利用正日益增多的地质资料和数据，离不开功能强大的数据库管理系统，然而，地学数据显著的空间特征和复杂的结构属性又不能简单运用常规的数据库管理系统进行表述、处理，地理信息系统（GIS）技术，以其对空间数据强大的储存查询和分析处理功能而鲜明地区 地普通管理信息系统，正适合于对复杂的地球空间数据进行采集、储存、分类、检索查询、刻划表达、以及分析建模，因此，先进的GIS技术与强大的地质数据库系统相结合，亦即是，基于GIS的地质数据库系统的开发和应用，是计算机技术应用于地学研究的发展方向和应用趋势，是当今地学发展所必需的基础技术之一，本文结合我们的近期工作概述了这一新兴领域的研究现状和发展趋势。 相似文献