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1.
Clay minerals, although ubiquitous on the ancient terrains of Mars, have not been observed in Martian meteorite Allan Hills (ALH) 84001, which is an orthopyroxenite sample of the early Martian crust with a secondary carbonate assemblage. We used a low‐temperature (20 °C) one‐dimensional (1‐D) transport thermochemical model to investigate the possible aqueous alteration processes that produced the carbonate assemblage of ALH 84001 while avoiding the coprecipitation of clay minerals. We found that the carbonate in ALH 84001 could have been produced in a process, whereby a low‐temperature (~20 °C) fluid, initially equilibrated with the early Martian atmosphere, moved through surficial clay mineral and silica‐rich layers, percolated through the parent rock of the meteorite, and precipitated carbonates (thereby decreasing the partial pressure of CO2) as it evaporated. This finding requires that before encountering the unweathered orthopyroxenite host of ALH 84001, the fluid permeated rock that became weathered during the process. We were able to predict the composition of the clay minerals formed during weathering, which included the dioctahedral smectite nontronite, kaolinite, and chlorite, all of which have been previously detected on Mars. We also calculated host rock replacement in local equilibrium conditions by the hydrated silicate talc, which is typically considered to be a higher temperature hydrothermal phase on Earth, but may have been a common constituent in the formation of Martian soils through pervasive aqueous alteration. Finally, goethite and magnetite were also found to precipitate in the secondary alteration assemblage, the latter associated with the generation of H2. Apparently, despite the limited water–rock interaction that must have led to the formation of the carbonates ~ 3.9 Ga ago, in the vicinity of the ALH 84001 source rocks, clay formation would have been widespread.  相似文献   

2.
Abstract— We present here ion microprobe analyses of rare earth and other selected trace and minor elements in pyroxenes of shergottite Queen Alexandra Range 94201 and lunar basalt 15555. Pyroxene zonation patterns record the crystallization histories of these two basaltic samples from Mars and the Moon, respectively, and allow a comparison of mafic melt evolution on these two planetary bodies. Elemental abundances and trends in pyroxenes of these two rocks indicate that their minerals formed by continuous, closed system fractional crystallization of their respective parent melts. This further supports the idea that QUE 94201 closely represents the composition of a true Martian basaltic melt (McSween et al., 1996). The main differences in pyroxene elemental zonation patterns in these two objects are attributed to earlier crystallization of whitlockite in QUE 94201 (i.e., before the Fe-rich pyroxenes) than in 15555 (after the Fe-rich pyroxenes). The size of Eu anomalies in pyroxenes of QUE 94201 is intermediate between that in pyroxenes of 15555 and the other shergottites and may imply that fO2 conditions during crystallization of this Martian basalt were significantly more reducing than for other shergottites, although not quite as reducing as for lunar basalts. Cerium anomalies appear to be less prevalent in pyroxenes of QUE 94201 than other Antarctic shergottites and could be indicative of lesser degree of weathering in the Antarctic.  相似文献   

3.
A. Gaudin  E. Dehouck  N. Mangold 《Icarus》2011,216(1):257-268
Phyllosilicates on Mars are widespread in the ancient crust suggesting the presence of liquid water at the martian surface and therefore warmer conditions during its early history. However, the role of the ancient climate in the alteration process, which produced these phyllosilicates, remains under debate, because similar mineral assemblages can be produced by hydrothermal alteration at depth. This paper focuses on the origin of coincident outcrops of Fe/Mg bearing phyllosilicates and Al-bearing phyllosilicates, which are observed in several regions of Mars. We performed a detailed mineralogical comparison between a section in Nili Fossae, Mars, and a weathering profile located at Murrin Murrin, Western Australia. The Murrin Murrin profile is developed in Archaean serpentinized peridotite massifs over a ∼40 m thick sequence. It has three alteration zones: the serpentine mineral saprolite is found at the bottom, immediately overlain by Fe/Mg-bearing smectites and then Al-bearing phyllosilicates (kaolinite) mixed with iron hydroxides. This example illustrates how Al-dominated minerals can derive from the alteration of initially Al-poor ultramafic rocks by the intense leaching of Mg2+. This mineralogical sequence is very similar to that detected locally in Nili Fossae by orbital spectroscopy. By analogy, we propose that the mineral assemblage detected on Mars is the result of long-term weathering, and thus could be the best evidence of past weathering as a direct result of a climate significantly warmer than at present.  相似文献   

4.
To assess whether life existed on Mars, it is crucial to identify geochemical biosignatures that are relevant to specific Martian environments. In this paper, thermochemical modeling was used to investigate fluid chemistries and secondary minerals that would have evolved biotically over geological time scales in Martian fluvio-lacustrine and evaporitic settings, and that could be used as potential inorganic biosignatures for life detection on Mars. Modeling was performed using fluid and rock chemistries relevant to Gale crater aqueous environments. Potential inorganic biosignatures were identified investigating alteration deposits found at the surface of a simulant exposed to short-term bio-mediated weathering and comparing experimental and modeling results. In a fluvio-lacustrine setting (water/rock of 2000–278), models suggest that less complex mineral assemblages form during biotic basalt dissolution and subsequent brine evaporation compared to what would happen in an abiotic system. Mainly nontronite, kaolinite, and quartz form under biotic conditions, whereas celadonite, talc, and goethite would also precipitate abiotically. Quartz, sepiolite, and gypsum would precipitate from the evaporation of fluids evolved biotically, whereas nontronite, talc, zeolite, and gypsum would form in an abiotic evaporitic environment. These results could be used to distinguish products of abiotic and biotic processes, aiding the interpretation of data from Mars exploration missions.  相似文献   

5.
The weathering products present in igneous terrestrial Antarctic samples were analyzed, and compared with those found in the four Miller Range nakhlite Martian meteorites. The aim of these comparisons was to determine which of the alteration phases in the Miller Range nakhlites are produced by terrestrial weathering, and what effect rock composition has on these phases. Antarctic terrestrial samples MIL 05031 and EET 96400, along with the Miller Range nakhlites MIL 03346 and 090032, were found to contain secondary alteration assemblages at their externally exposed surfaces. Despite the difference in primary mineralogy, the assemblages of these rocks consist mostly of sulfates (jarosite in MIL 05031, jarosite and gypsum in EET 96400) and iddingsite‐like Fe‐clay. As neither of the terrestrial samples contains sulfur‐bearing primary minerals, and these minerals are rare in the Miller Range nakhlites, it appears that SO42?, possibly along with some of the Na+, K+, and Ca+ in these phases, was sourced from wind‐blown sea spray and biogenic emissions from the southern ocean. Cl enrichment in the terrestrially derived “iddingsite” of MIL 05031 and MIL 03346, and the presence of halite at the exterior edge of MIL 090032, can also be explained by this process. However, jarosite within and around the olivine‐bound melt inclusions of MIL 090136 is present in the interior of the meteorite and, therefore, is probably the product of preterrestrial weathering on Mars.  相似文献   

6.
Terrestrial analog studies of potential Martian weathering processes are reported. Four major weathering environments are identified: (i) hydrothermal alteration of impact melt sheets and impact breccias, (ii) solid-gas and related reactions, (iii) subpermafrost intrusion of lavas involving liquid water, and (iv) subaerial extrusion of lavas in the absence of liquid water. Weathering in environments (i)?(iii) has been discussed by other authors; this report discusses weathering in environment (iv), an analog of which is Antarctica. We conclude that weathering is geologically slow in the absence of liquid water, and that zeolites predominate over clays as secondary minerals. On volumetric grounds it appears that hydrothermal alteration of impact melt sheets should be the most important time-averaged weathering mechanism, provided that H2O was present as liquid or permafrost. Such hydrothermal alteration should operate predominately on ancient crustal material. Gas-solid reactions and photochemical weathering should also operate primarily on ancient crustal material on a time-averaged basis. Weathering products of younger subpermafrost or subaerially erupted basalts should be subordinate to hydrothermal alteration and gas-solid reactions. It appears that the present Martian regolith as analyzed by the Viking landers contains a major contribution from ancient crust as typified today by the southern cratered highlands, with a lesser contribution from the younger, hemispherically restricted basaltic lavas.  相似文献   

7.
Salt compounds are apparently an important component of the finite-grained regolith on Mars. Salt enrichment may be explained either as a secondary concentration of chemical weathering products or as direct incorporation of planetary released volatiles. Geochemical measurements and chemical relationships constrain the salt species and resultant physicochemical consequences. A likely assemblage is dominated by (Mg,Na)SO4, NaCl, and (Mg,Ca)CO3. Formation of brine in equilibrium with such a salt mixture is unlikely under the temperature and water-vapor restrictions prevalent over most, if not all, of the Martian surface. Acidic conditions, accompanying salt formation, favor the preferential destruction of susceptible igneous minerals.  相似文献   

8.
Mariner 9 has provided a refutation or reinterpretation of several historical claims for Martian biology, and has permitted an important further characterization of the environmental constraints on possible Martian organisms. Four classes of conceivable Martian organisms are identified, depending on the environmental temperature, T, and water activity, aw: Class I, high T, high aw; Class II, low T, high aw; Class III, high T, low aw; and Class IV, low T, low aw. The Viking lander biology experiments are essentially oriented toward Class I organisms, although arguments are given for the conceivable presence on Mars of organisms in any of the four classes. Organisms which extract their water requirements from hydrated minerals or from ice are considered possible on Mars, and the high ultraviolet flux and low oxygen partial pressure are considered to be negligible impediments to Martian biology. Large organisms, possibly detectable by the Viking lander cameras, are not only possible on Mars; they may be favored. The surface distribution of Martian organisms and future search strategies for life on Mars are discussed.  相似文献   

9.
The Thermal Emission Spectrometer (TES) has observed a high-silica material in the dark regions of Mars that is spectrally similar to obsidian glass and may have a volcanic origin. An alternate interpretation is that the spectrally amorphous material consists of clay minerals or some other secondary material, formed by chemical alteration of surface rocks. The regions where this material is observed (e.g., Acidalia Planitia) have relatively high spectral contrast, suggesting that the high-silica material exists as coarse particulates, indurated soils or cements, within rocks, or as indurated coatings on rock surfaces. The geologic interpretation of this spectral result has major implications for understanding magmatic evolution and weathering processes on Mars. One of the complications in interpreting spectral observations of glasses and clay minerals is that both are structurally and compositionally complex. In this study, we perform a detailed spectroscopic analysis of indurated smectite clay minerals and relate their thermal emission spectral features to structural and crystal chemical properties. We examine the spectral similarities and differences between smectite clay minerals and obsidian glass from a structural-chemical perspective, and make further mineralogical interpretations from previous TES results. The results suggest that neither smectite clays nor any clay mineral with similar structural and chemical properties can adequately explain TES observations of high-silica materials in some martian dark regions. If the spectrally amorphous materials observed by TES do represent an alteration product, then these materials are likely to be poorly crystalline aluminosilicates. While all clay minerals have Si/O ratios ?0.4, the position of the emissivity minimum at Mars suggests a Si/O ratio of 0.4-0.5. The spectral observation could be explained by the existence of a silica-rich alteration product, such as Al- or Fe-bearing opal, an intimate physical mixture of relatively pure silica and other aluminosilicates (such as clay minerals or clay precursors), or certain zeolites. The chemical alteration of basaltic rocks on Mars to phyllosilicate-poor, silica-rich alteration products provides a geologically reasonable and consistent explanation for the global TES surface mineralogical results.  相似文献   

10.
Knowledge of Martian igneous basaltic compositions is crucial for constraining mantle evolution, including early differentiation and mantle convection. Primitive magmas provide direct information about their mantle source regions, but most Martian meteorites either contain cumulate olivine or crystallized from fractionated melts. The recently discovered Martian meteorite Northwest Africa (NWA) 5789 is an olivine‐phyric shergottite. NWA 5789 has special significance among the Martian meteorites because it appears to represent one of the most magnesian Martian magmas known, other than Yamato (Y) 980459. Its most magnesian olivine cores (Fo85) are in Mg‐Fe equilibrium with a magma of the bulk rock composition, suggesting that the bulk represents a magma composition. Based on the Al/Ti ratio of its pyroxenes, we infer that the rock began to crystallize at a high pressure consistent with conditions in Mars’ lower crust/upper mantle. It continued and completed its crystallization closer to the surface, where cooling was rapid and produced a mesostasis of radiating sprays of plagioclase and pyroxene. The mineralogy, petrology, mineral chemistry, and bulk rock composition of NWA 5789 are very similar to those of Y‐980459. The similarities between the two meteorites suggest that NWA 5789 (like Y‐980459) represents a primitive, mantle‐derived magma composition. They also suggest the possibility that NWA 5789 and Y‐980459 formed in the same lava flow. However, based on the mineralogy and texture of its mesostasis, NWA 5789 must have cooled more slowly than Y‐980459. NWA 5789 will help elucidate the igneous geology and geochemistry of Mars.  相似文献   

11.
Near Eagle Plains, northern Yukon, Canada, acidic Ca-Fe-Mg sulfate waters are discharging year-long from disturbed permafrosted sandstone bedrock overlying pyritiferous black shales. These acidic waters are precipitating gypsum with minor amounts of jarosite-K (Na), schwertmannite and hematite. This mineral assemblage is similar to that observed at Meridiani Planum (and other location on Mars), making this site a valuable analogue for low-temperature sulfate geochemistry and mineral formation on Mars. Stable O-S isotope analysis of the acidic waters near Eagle Plains revealed that the oxygen in the dissolved sulfate is mostly derived from water (ca. 70%), suggesting that the sulfide oxidation process could be in part biomediated (i.e., accelerated by acidophilic Fe-oxidizing bacteria). However, unlike the dissolved sulfate in the waters, the formation of the Ca-Fe-SO4 minerals appears to be purely abiotic. The stable O-S isotope composition of the sulfate minerals is well within the predicted equilibrium range at low temperature, suggesting that they formed through physico-chemical processes (i.e., evaporation or freezing). Low-temperature geochemical modeling with FREZCHEM and PHREEQC suggests that the mineral assemblage at Eagle Plains precipitated mainly through the freezing of Ca-Fe-Mg-SO4 acidic waters, rather than through evaporation during the dry summer season, although the latter is still possible. This suggests that the sulfate mineral assemblage observed on Mars could have also formed under a periglacial-type climate. Considering that the active layer in the zone affected by acid drainage does not freeze-over during winter, the residual talik offers a localized niche environment to support acidophilic microorganisms. Overall, the fact that acid drainage is presently active near Eagle Plains allows the direct observation of the low-temperature geochemical processes responsible for generating acid drainage conditions and precipitation of gypsum, schwertmannite, jarosite-K, jarosite-Na, goethite and hematite.  相似文献   

12.
Compositions of basaltic and ultramafic rocks analyzed by Mars rovers and occurring as Martian meteorites allow predictions of metamorphic mineral assemblages that would form under various thermophysical conditions. Key minerals identified by remote sensing roughly constrain temperatures and pressures in the Martian crust. We use a traditional metamorphic approach (phase diagrams) to assess low‐grade/hydrothermal equilibrium assemblages. Basaltic rocks should produce chlorite + actinolite + albite + silica, accompanied by laumontite, pumpellyite, prehnite, or serpentine/talc. Only prehnite‐bearing assemblages have been spectrally identified on Mars, although laumontite and pumpellyite have spectra similar to other uncharacterized zeolites and phyllosilicates. Ultramafic rocks are predicted to produce serpentine, talc, and magnesite, all of which have been detected spectrally on Mars. Mineral assemblages in both basaltic and ultramafic rocks constrain fluid compositions to be H2O‐rich and CO2‐poor. We confirm the hypothesis that low‐grade/hydrothermal metamorphism affected the Noachian crust on Mars, which has been excavated in large craters. We estimate the geothermal gradient (>20 °C km?1) required to produce the observed assemblages. This gradient is higher than that estimated from radiogenic heat‐producing elements in the crust, suggesting extra heating by regional hydrothermal activity.  相似文献   

13.
Abstract— Zagami and Nakhla are achondrites and belong to the Shergotty-Nakhla-Chassigny (SNC) meteorite group. It is generally accepted that Mars is their parent body. Mineralogical and chemical analyses have revealed that the major mineral phases of these two meteorites are pyroxene, olivine, maskelynite, and plagioclase. In this work, near-infrared biconical reflectance measurements were performed on sawed surfaces of chips from Zagami and Nakhla. Spectra obtained with an analytical spot diameter on the order of the mineral grain size reflect the heterogeneous distribution of different mineral phases. The characteristic absorption bands of the pyroxenes are numerically evaluated in terms of the modified Gaussian model. Spectra with overlapping absorption features are resolved into the basic absorption bands. From these results, it can be estimated what kind of clinopyroxenes belong to the investigated mineral assemblages. As a result, the major clinopyroxene phase in Nakhla is Ca-rich augite, whereas in Zagami both Ca-rich and Ca-poor pyroxenes are present. By means of such a procedure, laboratory spectra of minerals become more informative and may help in discussing Martian remote sensing data in the near-infrared region.  相似文献   

14.
The existence of methane in the Martian atmosphere is well established today. Several mechanisms have been discussed, which could be able to produce methane. However no mechanism is presently accepted to explain the observations satisfactorily.It is the aim of this paper to describe results of experimental laboratory investigations to study relationships and possible chemical reactions between Martian atmospheric carbon dioxide, liquid interfacial water (at least temporarily present), UV irradiation, and the possibly catalyzing influence of minerals like hematite with respect to the possible formation of oxygenate molecules. It is assumed that hematite can act as a photocatalyst under laboratory conditions (and also on the surface of Mars), and the formation of oxygenates evolves in course of the irradiation of carbon dioxide with UV-light in the presence of water, finally resulting in C–, O–, and H– containing molecules, which have been identified by GC–MS. The experiments were carried out under terrestrial atmospheric pressure and room temperature. Oxygenate molecules with one carbon atom like formaldehyde and methanol were found to be reaction products, but also C2- and C3-species like acetone. The important role of hematite as a photocatalytic active solid could be shown. The conversion of carbon dioxide increases in the presence of hematite. It has also a significant influence on the distribution of the products. Experiments with 18O-labeled water show a transfer of oxygen from water to carbon, which results in labeled oxygenate molecules. Oxygenates could have been formed from CO2 via a photocatalytic reduction processes. The observed formation of C2- and C3-species might point to secondary competitive and consecutive reactions via complex and less selective mechanisms.All these results indicate the action of different reaction mechanisms, supporting therefore the assumption that both photocatalytic and radical reactions can contribute to the formation of oxygenates from carbon dioxide and water by UV irradiation. More importantly, the results give indication of a potential formation of hydrocarbons, such as methane, via conversion of atmospheric carbon dioxide and water on Martian soil mineral/water interfaces.Summarizing, it must be stated that, based on these first and promising results, a deeper and more quantitative understanding is necessary to model the contribution of photocatalytic processes to the apparent presence of oxygenates and hydrocarbons in the near surface atmosphere of Mars.  相似文献   

15.
Abstract— We report the results of a study of a halite-siderite-anhydrite-chlorapatite assemblage in the Shergotty-Nakhla-Chassigny (SNC) Martian meteorite Nakhla. These minerals are found associated with each other in interstitial areas, with halite often being adjacent to or enclosing siderite. We suggest the halite and other minerals are Martian in origin because (1) the conditions of fall preclude significant amounts of terrestrial contamination or weathering having taken place; (2) textures indicate that the minerals within this assemblage crystallized at the same stage as some silicate and oxide minerals within the Nakhla parent; and (3) the association with siderite, which previous studies have shown has C and O-isotopic compositions incompatible with an origin on the Earth. Siderite has the range of compositions: CaCO3, 0.1–5.7; MgCO3, 2.0–40.9; FeCO3, 23.2–87.0; MnCO3, 1.0–39.9 mol%. There are two compositional groupings: high-MnCO3 (≥30 mol%) and low-MnCO3/high-FeCO3, with a gap identified between the two. This may be a miscibility gap or, alternatively, the two compositional groupings may mark separate generations of carbonate. We have not found any textural evidence for the latter explanation, but acceptance of the presence of a miscibility gap would require independent work on Fe-Mn carbonates to verify its existence. Trace element abundances have been determined by ion microprobe analysis on three siderite and one anhydrite grains. Siderite has light rare earth elements (2.2–7.3 × C1) greater than heavy rare earth elements (0.32–0.79 × C1) without Ce or Eu anomalies, and the anhydrite has a similar pattern. These abundances reflect the source composition rather than partitioning or complexing controls. They are not typical of hydrothermal signatures which generally do not have such smooth REE abundance patterns. The nature of the mineral assemblage suggests that its source rocks on Mars were evaporites. These may be common in the craters and flood plains of the Martian southern highlands. Two models are suggested in this paper to explain the incorporation of evaporitic material into the Nakhla igneous parent. It may have happened as a low-temperature process (<200 °C) by crystallisation from an aqueous fluid. An origin at low temperature is compatible with the available experimental data on siderite stability. Alternatively, we suggest evaporitic material may have been incorporated into the Nakhla parent while melt was still present and crystallized ～800 °C. The latter model can more readily explain the trace element abundances and also the siderite textures that imply intergrowth with residual interstitial melt. Both high- and low-temperature models are consistent with the presence of evaporite sediments on Mars.  相似文献   

16.
Phyllosilicates, carbonates, zeolites, and sulfates on Mars give clues about the planet's past environmental conditions, but little is known about the specific conditions in which these minerals formed within the crust and at the surface. The aim of the present study was to gain increased understanding on the formation of secondary phases by hydrothermal alteration of basaltic glass. The reaction processes were studied under varying conditions (temperature, pCO2, water:rock ratio, and fluid composition) with relevance to aqueous hydrothermal alteration in fully and partly saturated Martian basalt deposits. Analyses made on reaction products using X‐ray diffraction (XRD) and scanning electron microscope (SEM) were compared with near infrared spectroscopy (NIR) to establish relative detectability and spectral signatures. This study demonstrates that comparable alteration minerals (phyllosilicates, carbonates, zeolites) form from vapor condensing on mineral surfaces in unsaturated sediments and not only in fully water‐saturated sediments. In certain environments where water vapor might be present, it can alter the basaltic bedrock to a suite of authigenic phases similar to those observed on the Martian surface. For the detection of the secondary phases, XRD and SEM‐EDS were found to be superior to NIR for detecting and characterizing zeolites. The discrepancy in detectability of zeolites between NIR and XRD/SEM‐EDS might indicate that zeolites on Mars are more abundant than previously thought.  相似文献   

17.
Abstract— Isotopic signatures and concentrations of xenon have been measured in Shergotty mineral separates by laser step heating. Martian atmosphere and ‘martian interior’ xenon are present, as is a spallation component. Martian atmospheric xenon is 5–10 times more concentrated in opaque minerals (magnetite, ilmenite, and pyrrhotite) and maskelynite than in pyroxenes, perhaps reflecting grain size variation. This is shown to be consistent with shock incorporation. A component consisting of solar xenon with a fission contribution, similar to components previously identified in martian meteorites and associated with the martian interior, is best defined in the pyroxene‐dominated separates. This component exhibits a consistent 129Xe (129Xe/132Xe ?1.2) excess over solar/planetary (129Xe/132Xe ?1.04). We suggest that gas present in the melt, perhaps a mixture of interior xenon and martian atmosphere, was incorporated into the pyroxenes in Shergotty as the minerals crystallized.  相似文献   

18.
Abstract– Xenon‐isotopic ratios, step‐heating release patterns, and gas concentrations of mineral separates from Martian shergottites Roberts Massif (RBT) 04262, Dar al Gani (DaG) 489, Shergotty, and Elephant Moraine (EET) 79001 lithology B are reported. Concentrations of Martian atmospheric xenon are similar in mineral separates from all meteorites, but more weathered samples contain more terrestrial atmospheric xenon. The distributions of xenon from the Martian and terrestrial atmospheres among minerals in any one sample are similar, suggesting similarities in the processes by which they were acquired. However, in opaque and maskelynite fractions, Martian atmospheric xenon is released at higher temperatures than terrestrial atmospheric xenon. It is suggested that both Martian and terrestrial atmospheric xenon were initially introduced by weathering (low temperature alteration processes). However, the Martian component was redistributed by shock, accounting for its current residence in more retentive sites. The presence or absence of detectable 129Xe from the Martian atmosphere in mafic minerals may correspond to the extent of crustal contamination of the rock’s parent melt. Variable contents of excess 129Xe contrast with previously reported consistent concentrations of excess 40Ar, suggesting distinct sources contributed these gases to the parent magma.  相似文献   

19.
We studied the occurrence of secondary minerals and inferred their formation in the Yamato-000593 Martian meteorite using multiple technological approaches such as electron probe micro analysis, optical microscope, Raman spectroscopy, scanning electron microscopy, as well as Fourier transform-infrared microscopy and spectroscopy. Two separate hydrothermal alteration events and their sequence of formation (based on superpositional relationship) can be identified: an elevated temperature phase producing high-temperature sulfidic hydrothermal alteration and a lower temperature hydrothermal alteration phase by iron-rich fluids. This meteorite shows signatures more compatible with magmatic effects, rather than impact-induced hydrothermal alteration, as has been proposed earlier. The sulfidic alteration probably formed by magmatic hydrothermal fluids, whereas iron-rich hydrothermal fluid circulation after a possible early impact event has also been proposed, when the fluids cooled down to 50 °C. Most of the secondary minerals formed at alkaline-neutral conditions, and the few observed signatures (clay–silica-bearing veins, siderite-iron-oxide veins) of briny conditions are probably from local spatial effects in larger cavities. The ferrous minerals (hematite and siderite) along the fractures could be crystallized from Fe-HCO3-bearing fluids. Alternatively, the primary magmatic minerals could have been oxidized easily (Fe-rich olivines, magnetite) during the cooling to iron oxides (hematite, goethite). The results suggest the possible existence of at least ephemerally habitable environments on Mars, mainly at volcanically heated locations. Following published geochemical models, the carbonates formed within acidic-circumneutral condition, which was followed by formation of phyllosilicates in alkaline condition.  相似文献   

20.
T.R. McGetchin  J.R. Smith 《Icarus》1978,34(3):512-536
The density of the Martian mantle is estimated to be about 3.55 g/cm3 (Reasenberg, 1977). Model mineral assemblages for the Martian mantle (at 30 kbar) were calculated using a modified CIPW norm scheme by adding FeO to model terrestrial mantle compositions. The density of the resulting mineral assemblages vary with increasing FeO content. With pyrolite starting compositions for the terrestrial mantle, the resulting model Martian mantle with density of 3.55 g/cm3 is not garnet-lherzolite like the Earth; rather it is an assemblage properly called oxide-garnet wehrlite: oxide (periclase-wüstite) 2%; garnet 11%; olivine 73%; clinopyroxene 12%; with no orthopyroxene. Partial melting of such an assemblage wouldyield iron-rich, ultrabasic lavas, with extremely low viscosities. Specifically, model partial melts, assuming production from the quaternary eutectic (inferred to be near: op7 g42 cpx43 ox8) yields an ultrabasic (SiO2, 41 to 44%) picritic alkali-basaltic melt (norm composition ne 2.5, plag 32, or 2.4, di 20, ol 37, mt 4.4 and ilm, tr), with a computed viscosity of about 12 P at 1200°C. This model for the composition of the Martian surface lavas (derived from geophysical data and petrologic arguments) is in remarkable agreement with a recently published model by Maderazzo and Huguenin (1977) (derived from reflection spectroscopy, experimental and theoretical models for weathering in the Martian environment). The result also appears to be consistent with recent interpretations (Rasool and Le Sergeant, 1977) of Viking atmospheric chemistry results, namely that the Martian crust is potassium poor. There are a number of geological implications which follow, including (1) superfluid lavas may account for some flood and erosional features observed on Mars; (2) the XRF inorganic chemistry experiment on Vikings 1 and 2 (Baird, 1976) indeed may be measuring compositions approaching primary lavas, contrary to current interpretations which favor a rather mature (weathered) soil; (3) ultrabasic (ferrokimberlitic) ash might be a major constituent of the Martian soil, especially if cosmological models concerning the incorporation of a much volatile material within the early accreting Mars are correct—a matter of current debate; (4) a number of mineral assemblages not previously considered are possible in the Martian mantle depending principally on the activity of volatile substances, (S, O, C, H); it is possible that some very unusual magmas are produced on partial melting; and (5) some ferro-granite melts might be produced by liquid immiscibility.  相似文献   

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