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1.
High-pressure phase relations in the system NaAl3Si3O11–CaAl4Si2O11 were examined at 13–23 GPa and 1600–1900 °C, using a multianvil apparatus. A Ca-aluminosilicate with CaAl4Si2O11 composition, designated CAS phase, is stable above about 13 GPa at 1600 °C. In the system NaAl3Si3O11–CaAl4Si2O11, the CAS phase dissolving NaAl3Si3O11 component coexists with jadeite, corundum and stishovite below 22 GPa, above which the CAS phase coexists with Na-rich calcium ferrite, corundum and stishovite. At 1600 °C, the solubility of NaAl3Si3O11 component in the CAS solid solution increases with increasing pressure up to about 50 mol% at about 22 GPa, above which the solubility decreases with pressure. The maximum solubility of NaAl3Si3O11 component in the CAS phase increases with temperature up to around 70 mol% at 1900 °C at 22 GPa. The dissociation of NaAlSi2O6 jadeite to NaAlSiO4 calcium ferrite plus stishovite occurs at about 22 GPa. Lattice parameters of the CAS phase with the hexagonal Ba-ferrite structure change with increase of the NaAl3Si3O11 component: a-axis decreases and c-axis slightly increases, resulting in decrease of molar volume. Enthalpies of the CAS solid solutions were measured by high-temperature drop-solution calorimetry techniques. The results show that enthalpy of hypothetical NaAl3Si3O11 CAS phase is much higher than the mixture of NaAlSi2O6 jadeite, corundum and stishovite and is close to that of the mixture of NaAlSiO4 calcium ferrite, corundum and stishovite. When we adopt the Na:Ca ratio of 75:25 of the natural Na-rich CAS phase in a shocked Martian meteorite, Zagami, the phase relations determined above suggest that the natural CAS phase crystallized from melt at pressure around 22 GPa and temperature close to or higher than 2000–2200 °C. The inferred P, T conditions are consistent with those estimated using other high-pressure minerals in the shocked meteorite.  相似文献   

2.
Outcrops of the Cretaceous Upper sandstone formation some 375 km to the East of Addis Ababa on the motor Highway to Harar was paleomagnetically investigated. About seventy core samples were collected at various stratigraphic levels from 250–300 meters thick sedimentary formation. After standard sample preparations in the laboratory the resulting specimens were subjected to routine paleomagnetic demagnetization protocol. In the first steps of demagnetizations process the recent and viscous magnetizations were removed by heating until a temperature of level of 300 °C. Further demagnetization of the samples resulted in the isolation of the final magnetization with stable line segments that is directed towards the origin, which is interpreted as Characteristic Remanent Magnetization (ChRM). Rock – magnetic experiments have identified goethite (αFeOOH), hematite (αFe2O3), detritial hematite, and magnetite as the magnetic mineral phases carrying the remanence. The ChRM identified resulted in an average value of (Ds = 0.5°, Is = ?0.7°, α95 = 4.3°, N = 34) for the red sandstones while an average value of (Ds = 335.8°, Is = ?31.8°, α95 = 4.7°, N = 14) for the limestone intercalations. The former ChRM in the red sandstone is determined to be secondary while the latter ChRM is known to be primary. Comparison of these directional results and their pole equivalents with the African plate Apparent Polar Wander Path curve established by Besse and Courtillot (2003) give ages of between 115–130 Million years for the limestone intercalation and ages of 30 million years for red sandstone unit. These are interpreted respectively as estimates of the age of deposition and a later remagnetization respectively.  相似文献   

3.
The evolution with pressure of the unit-cell parameters brownmillerite (Ca2Fe2O5), a stoichiometric defect perovskite structure, has been determined to a maximum pressure of 9.46 GPa, by single-crystal X-ray diffraction measurements at room temperature. Brownmillerite does not exhibit any phase transitions in this pressure range. A fit of a third-order Birch–Murnaghan equation-of-state to the P–V data yields values of KT0=127.0(5) GPa and K0′=5.99(13). Analysis of the unit-cell parameter data shows that the structure compresses anisotropically. Compressional moduli for the axes are Ka0=141(1) GPa, Kb0=118(3) GPa and Kc0=122.2(2) GPa, with Ka0′=8.9(3), Kb0′=6.2(6) and Kc0′=4. The stiffest direction (i.e. along a) coincides with the direction of the FeO4 tetrahedral chains. Comparison of these data with the elasticity systematics of Ca-perovskites shows that the presence of oxygen vacancies in the brownmillerite structure softens the structure by ∼25% and that the ordering of vacancies in the perovskite structure increases the anisotropy of compression.  相似文献   

4.
The elastic moduli of polycrystalline ringwoodite, (Mg0.91Fe0.09)2SiO4, were measured up to 470 K by means of the resonant sphere technique. The adiabatic bulk (KS) and shear (μ) moduli were found to be 185.1(2) and 118.22(6) GPa at room temperature, and the average slopes of dKS/dT and dμ/dT in the temperature range of the study were determined to be −0.0193(9) and −0.0148(3) GPa/K, respectively. Using these results, we estimate seismic wave velocity jumps for a pure olivine mantle model at 520 km depth. We find that the jump for the S-wave velocity is about 1.5 times larger than that for the P-wave velocity at this depth. This suggests that velocity jumps at the 520 km discontinuity are easier to detect using S-waves than P-waves.  相似文献   

5.
Mechanisms and kinetics of the post-spinel transformation in Mg2SiO4 were examined at 22.7–28.2 GPa and 860–1200 °C by in situ X-ray diffraction experiments using synchrotron radiation combined with microstructural observations of the recovered samples. The post-spinel phases nucleated on spinel grain boundaries and grew with a lamellar texture. Under large overpressure conditions, reaction rims were formed along spinel grain boundaries at the initial stage of the transformation, whereas under small overpressure conditions, the transformation proceeded without formation of reaction rims. Mg2SiO4 spinel metastably dissociated into MgSiO3 ilmenite and periclase, and stishovite and periclase as intermediate steps in the transformation into the stable assemblage of MgSiO3 perovskite and periclase. Topotactic relationships were found in the transformation from spinel into ilmenite and periclase. Kinetic parameters in the Avrami rate equation, time taken to 10% completion, and the growth rate were estimated by analysis of the kinetic data obtained by in situ X-ray observations. The empirical activation energy for 10% transformation decreases with increasing pressure because the activation energy for nucleation becomes smaller at larger overpressure conditions. Extrapolations of the 10% transformation to ∼700 °C, which is the lowest temperature expected for the cold slabs at ∼700 km depth, suggest that overpressure of more than ∼1 GPa is needed for the transformation. Because the growth rate is estimated to be large even at low-temperatures of ∼700 °C and overpressures of 1 GPa, the depth of the post-spinel transformation in the cold slabs is possibly controlled by nucleation kinetics.  相似文献   

6.
We report experimental observation of a sizable elastic anisotropy in a polycrystalline sample of ferromagnesian silicate in post-perovskite (ppv) structure. Using a novel composite X-ray transparent gasket to contain and synthesize ppv in a panoramic diamond-anvil cell along with oblique X-ray diffraction geometry, we observed the anisotropic lattice strain and {1 0 0} or {1 1 0} slip-plane texture in the sample at 140 GPa. We deduced the elasticity tensor (cij), orientation-dependent compressional wave velocities, polarization-dependent shear-wave velocities, and the velocity anisotropy of the silicate ppv. Our results are consistent with calculations and indicate that with sufficient preferred orientation, the elastic anisotropy of this phase can produce large shear-wave splitting.  相似文献   

7.
Serpentinization of the mantle wedge is an important process that influences the seismic and mechanical properties in subduction zones. Seismic detection of serpentines relies on the knowledge of elastic properties of serpentinites, which thus far has not been possible in the absence of single-crystal elastic properties of antigorite. The elastic constants of antigorite, the dominant serpentine at high-pressure in subduction zones, were measured using Brillouin spectroscopy under ambient conditions. In addition, antigorite lattice preferred orientations (LPO) were determined using an electron back-scattering diffraction (EBSD) technique. Isotropic aggregate velocities are significantly lower than those of peridotites to allow seismic detection of serpentinites from tomography. The isotropic VP/VS ratio is 1.76 in the Voigt–Reuss–Hill average, not very different from that of 1.73 in peridotite, but may vary between 1.70 and 1.86 between the Voigt and Reuss bonds. Antigorite and deformed serpentinites have a very high seismic anisotropy and remarkably low velocities along particular directions. VP varies between 8.9 km s? 1 and 5.6 km s? 1 (46% anisotropy), and 8.3 km s? 1 and 5.8 km s? 1 (37%), and VS between 5.1 km s? 1 and 2.5 km s? 1 (66%), and 4.7 km s? 1 and 2.9 km s? 1 (50%) for the single-crystal and aggregate, respectively. The VP/VS ratio and shear wave splitting also vary with orientation between 1.2 and 3.4, and 1.3 and 2.8 for the single-crystal and aggregate, respectively. Thus deformed serpentinites can present seismic velocities similar to peridotites for wave propagation parallel to the foliation or lower than crustal rocks for wave propagation perpendicular to the foliation. These properties can be used to detect serpentinite, quantify the amount of serpentinization, and to discuss relationships between seismic anisotropy and deformation in the mantle wedge. Regions of high VP/VS ratios and extremely low velocities in the mantle wedge of subduction zones (down to about 6 and 3 km.s?1 for VP and VS, respectively) are difficult to explain without strong preferred orientation of serpentine. Local variations of anisotropy may result from kilometer-scale folding of serpentinites. Shear wave splittings up to 1–1.5 s can be explained with moderately thick (10–20 km) serpentinite bodies.  相似文献   

8.
Volume measurements for magnesiowüstite (Mg0.6Fe0.4)O, were carried out up to pressures of 10.1 GPa in the temperature range 300–1273 K, using energy-dispersive synchrotron X-ray diffraction. These data allow reliable determination of the temperature dependence of the bulk modulus and good constraint on the thermal expansitivity at ambient pressure which was previously not known for magnesiowüstite. From these data, thermal and elastic parameters were derived from various approaches based on the Birch–Murnaghan equation of state (EOS) and on the relevant thermodynamic relations. The results from three different equations of state are remarkably consistent. With (∂KT/∂P)T fixed at 4, we obtained K0=158(2) GPa, (∂KT/∂T)P=−0.029(3) GPa K−1, (∂KT/∂T)V=−3.9(±2.3)×10−3 GPa K−1, and αT=3.45(18)×10−5+1.14(28)×10−8T. The K0, (∂KT/∂T)P, and (∂KT/∂T)V values are in agreement with those of Fei et al. (1992) and are similar to previously determined values for MgO. The zero pressure thermal expansitivity of (Mg0.6Fe0.4)O is found to be similar to that for MgO (Suzuki, 1975). These results indicate that, for the compositional range x=0–0.4 in (Mg1−xFex)O, the thermal and elastic properties of magnesiowüstite exhibit a dependence on the iron content that is negligibly small, within uncertainties of the experiments. They are consequently insensitive to the Fe–Mg partitioning between (Mg, Fe)SiO3 perovskite and magnesiowüstite when applied to compositional models of the lower mantle. With the assumption that (Mg0.6Fe0.4)O is a Debye-like solid, a modified equation of heat capacity at constant pressure is proposed and thermodynamic properties of geophysically importance are calculated and tabulated at high temperatures.  相似文献   

9.
The aggregate shear wave velocities of MgO (periclase) have been determined throughout Earth's lower mantle pressure regime approaching 130 GPa using Brillouin spectroscopy in conjunction with synchrotron X-ray diffraction technique in a diamond anvil cell apparatus. We found that the extrapolations of the high-pressure shear wave velocities and shear moduli to ambient pressure are highly consistent with earlier studies. However, the measurements over a wide pressure range revealed that the pressure derivative of the shear modulus (dG/dP = G0′) of MgO is 1.92(2), which is distinctly lower than that of previous lower-pressure experiments. Compared with the previous results on (Mg,Fe)O ferropericlase, there is no clear correlation between iron content and G0′. We calculate that the shear wave velocity profile of lower mantle along the adiabatic geotherm applied by the lower G0′ value of periclase can remarkably well reproduce the global seismological 1-D velocity profile model with uniform composition model. The best-fitting result indicates the possibility of a lower mantle mineralogy with ~ 92 vol.% silicate perovskite phase, implying that the bulk composition of lower mantle is likely not to be pyrolitic but more chondritic. The present acoustic measurements performed over the large pressure range have thus led us to a better understanding of compositional model of the Earth's lower mantle.  相似文献   

10.
The single backscattering model was used to estimate total attenuation of coda waves (Qc) of local earthquakes recorded on eight seismological stations in the complex area of the western continental Croatia. We estimated Q0 and n, parameters of the frequency dependent coda-Q using the relation Qc = Q0fn. Lapse time dependence of these parameters was studied using a constant 30 s long time window that was slid along the coda of seismograms. Obtained Qc were distributed into classes according to their lapse time, tL. For tL = 20–50 s we estimated Q0 = 45–184 and n = 0.49–0.94, and for tL = 60–100 s we obtained Q0 = 119–316 and n = 0.37–0.82. There is a tendency of decrease of parameter n with increasing Q0, and vice versa. The rates of change of both Q0 and n seem to decrease for lapse times larger than 50–80 s, indicating an alteration in rock properties controlling coda attenuation at depths of about 100–160 km. A very good correlation was found between the frequency dependence parameter n and the Moho depths for lapse times of 50, 60 and 70 s.  相似文献   

11.
New Late Cretaceous paleomagnetic results from the Okhotsk-Chukotka Volcanic Belt in the Kolyma-Omolon Composite Terrane yield stable and consistent remanent directions. The Late Cretaceous (86–81 Ma) ignimbrites from the Kholchan and Ola suites were sampled at 19 sites in the Magadan area (60.4° N, 151.0° E). We isolated the characteristic paleomagnetic directions from 16 sampled sites using an alternating field demagnetization procedure. The primary nature of these directions is ascertained by dual polarities and positive fold tests. A tilt-corrected mean direction (D = 42.8°, I = 84.7°, k = 46.0, α95 = 10.0°) yields a paleomagnetic pole of 66.7° N, 168.5° E (A95 = 18.8°) which appears almost identical to the 90–67 Ma pole reported from the Lake El’gygytgyn area of the Okhotsk-Chukotka Volcanic Belt (Chukotka Terrane). This consistency suggests that the Kolyma-Omolon Composite Terrane and Chukotka Terrane has acted as a single tectonic unit since 80 Ma without any significant internal deformation. Accordingly, we calculate a combined 80 Ma characteristic paleomagnetic pole (Long. = 164.7° E, Lat. = 68.0°, A95 = 10.9°, N = 12) for the Kolyma-Omolon-Chukotka Block which falls 16.5–17.5° south of the same age poles from Europe and East Asia. We ascribe this discrepancy in pole positions to tectonic activity in the area and infer a southward displacement of 1640 ± 1380 km for the Kolyma-Omolon-Chukotka Block with respect to the North American and Eurasian blocks since 80 Ma; more than 260 km of it is attributed to tectonic displacement in the Arctic Ocean due to the opening of the Canadian Basin.  相似文献   

12.
Recent studies have indicated that a significant amount of iron in MgSiO3 perovskite (Pv) is Fe3+ (Fe3+/ΣFe = 10–60%) due to crystal chemistry effects at high pressure (P) and that Fe3+ is more likely than Fe2+ to undergo a high-spin (HS) to low-spin (LS) transition in Pv in the mantle. We have measured synchrotron Mössbauer spectroscopy (SMS), X-ray emission spectroscopy (XES), and X-ray diffraction (XRD) of Pv with all iron in Fe3+ in the laser-heated diamond-anvil cell to over 100 GPa. Fe3+ increases the anisotropy of the Pv unit cell, whereas Fe2+ decreases it. In Pv synthesized above 50 GPa, Fe3+ enters into both the dodecahedral (A) and octahedral (B) sites approximately equally, suggesting charge coupled substitution. Combining SMS and XES, we found that the LS population in the B site gradually increases with pressure up to 50–60 GPa where all Fe3+ in the B site becomes LS, while Fe3+ in the A site remains HS to at least 136 GPa. Fe3+ makes Pv more compressible than Mg-endmember below 50 GPa because of the gradual spin transition in the B site together with lattice compression. The completion of the spin transition at 50–60 GPa increases bulk modulus with no associated change in density. This elasticity change can be a useful seismic probe for investigating compositional heterogeneities associated with Fe3+.  相似文献   

13.
Magnetic Resonance Sounding (MRS) is nowadays accepted as a new geophysical method that can be used for a reliable determination of the ground water content distribution in the top 150 m. A great effort has also been made in MRS development to deduce the hydraulic transmissivity, based on empiric relationships of the permeability with a factor F which is calculated with NMR parameters measured at laboratory scale. To use this relationship under field conditions a calibration coefficient CT = Tpt / F has to be previously established, which demands the knowledge of the transmissivity Tpt evaluated in the pumping test. The transmissivity can then be calculated at any other site of the same aquifer using the relation Tmrs = CTF. The CT values reported suggest a certain relationship with the lithology, but with a great dispersion and contradictory results. MRS surveys carried out in alluvial aquifers in Spain have shown that the value of CT evaluated at one site may not be valid at another place of the same aquifer, because of the great heterogeneity of this kind of geological environment. The demand of a pumping test at each site where a MRS is measured invalidates the method actually used for MRS transmissivity evaluation. More than 50 MRS have been used to propose a new methodology. The aquifers visited cover a great range of transmissivities (from 2 × 10− 6 to 9 × 10− 3 m2/s). The MRS signal amplitude varies between 20 and 1400 nV, the signal/noise ratio is in the range from 0.6 to 42, and the value of the decay time constant varies from 200 to 800 ms. It has been demonstrated that when the transmissivity increases, the value of F decreases, and CT increases, except for certain groups of MRS taken at the same aquifer or part of one aquifer, for which F increases with Tpt, keeping CT constant. A function CT(F) of the type CT = mF− n has been obtained that allows the transmissivity evaluation without the need of Tpt. Considering that both values of transmissivity, Tpt and Tmrs, are subjected to deviations due to the experimental errors as well as due to evaluation errors, the prediction achieved by the proposed equation is rather good. To perform a better evaluation of the values of the coefficients m and n it is necessary to have a greater number of MR soundings of good quality and with a trustworthy inversion at locations where a really comparable and good performed pumping test is available, covering a sufficient range of transmissivities. Though the data we have used do not always fulfil these conditions, the result is promising. Once a trustable function is available, the forecast of the transmissivity using MRS will not need the existence of any pumping test in the area. The general extension of this methodology demands the availability of MRS taken at all kinds of geological and hydrogeological environments, which is impossible without the existence of a universal MRS data base.  相似文献   

14.
Evapotranspiration (LE) is an important factor for monitoring crops, water requirements, and water consumption at local and regional scale. In this paper, we applied the semi-empirical model to estimate the daily latent heat flux (LEd = Rnd + A − B(Ts − Ta)). LEd has been estimated using satellite images (Thematic Mapper sensor) and a local dataset (incoming and outgoing short- and long-wave radiation) measured during three years. We first estimated the daily net Radiation (Rnd) from a linear equation derived from the instantaneous net Radiation (Rnd = CRni + D). Subsequently, coefficients A and B have been estimated for two different cover vegetations (pasture and soybean). For each vegetation cover, an error analysis combining Rnd, A, B, and surface and air temperatures has been calculated. Results showed that Rnd had good performance (nonbias and low RMSE). LEd errors for pasture and soybean were ±28 W m−2 and ±40 W m−2 respectively.  相似文献   

15.
We have determined the density evolution of the sound velocity of dhcp-FeHx (x ≈ 1) up to 70 GPa at room temperature, by inelastic X-ray scattering and by X-ray diffraction. We find that the variation of VP with density is different for the ferromagnetic and nonmagnetic dhcp-FeHx, and that only nonmagnetic dhcp-FeHx follows Birch's law. Combining our results with Birch's law for iron and assuming an ideal two-component mixing model, we obtain an upper bound of the hydrogen content in the Earth's inner core, 0.23(6) wt.% H, corresponding to FeH0.13(3). The iron alloy with 0.23(6) wt.% H can satisfy the density, and compressional and shear sound velocities of the PREM inner core, assuming that there are no other light elements in the inner core.  相似文献   

16.
We characterized the seasonal cycle of productivity in Reloncaví Fjord (41°30′S), Chilean Patagonia. Seasonal surveys that included measurements of gross primary production, community respiration, bacterioplankton secondary production, and sedimentation rates along the fjord were combined with continuous records of water-column temperature variability and wind forcing, as well as satellite-derived data on regional patterns of wind stress, sea surface temperatures, and surface chlorophyll concentrations. The hydrography and perhaps fjord productivity respond to the timing and intensity of wind forcing over a larger region. Seasonal changes in the direction and intensity of winds, along with a late-winter improvement in light conditions, may determine the timing of phytoplankton blooms and potentially modulate productivity cycles in the region.Depth-integrated gross primary production estimates were higher (0.4–3.8 g C m?2 d?1) in the productive season (October, February, and May), and lower (0.1–0.2 g C m?2 d?1) in the non-productive season (August). These seasonal changes were also reflected in community respiration and bacterioplankton production rates, which ranged, respectively, from 0.3 to 4.8 g C m?2 d?1 and 0.05 to 0.4 g C m?2 d?1 during the productive and non-productive seasons and from 0.05 to 0.6 g C m?2 d?1 and 0.05 to 0.2 g C m?2 d?1 during the same two periods. We found a strong, significant correlation between gross primary production and community respiration (Spearman, r=0.95; p<0.001; n=12), which suggests a high degree of coupling between the synthesis of organic matter and its usage by the planktonic community. Similarly, strong correlations were found between bacterioplankton secondary production and both gross primary production (Spearman, r=0.7, p<0.05, n=9) and community respiration (Spearman, r=0.8, p<0.05, n=9), indicating that bacterioplankton may be processing an important fraction (8–59%) of the organic matter produced by phytoplankton in Reloncaví Fjord. In winter, bacterial carbon utilization as a percentage of gross primary production was >100%, suggesting the use of allochthonous carbon sources by bacterioplankton when the levels of gross primary production are low. Low primary production rates were associated with a greater contribution of small cells to autotrophic biomass, highlighting the importance of small-sized plankton and bacteria for carbon cycling and fluxes during the less productive winter months. Fecal pellet sedimentation was minimal during this period, also suggesting that most of the locally produced organic carbon is recycled within the microbial loop. During the productive season, on the other hand, the area exhibited a great potential to export organic matter, be it to higher trophic levels or vertically towards the bottom.  相似文献   

17.
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18.
Many authors have proposed that the study of seismicity rates is an appropriate technique for evaluating how close a seismic gap may be to rupture. We designed an algorithm for identification of patterns of significant seismic quiescence by using the definition of seismic quiescence proposed by Schreider (1990). This algorithm shows the area of quiescence where an earthquake of great magnitude may probably occur. We have applied our algorithm to the earthquake catalog on the Mexican Pacific coast located between 14 and 21 degrees of North latitude and 94 and 106 degrees West longitude; with depths less than or equal to 60 km and magnitude greater than or equal to 4.3, which occurred from January, 1965 until December, 2014. We have found significant patterns of seismic quietude before the earthquakes of Oaxaca (November 1978, Mw = 7.8), Petatlán (March 1979, Mw = 7.6), Michoacán (September 1985, Mw = 8.0, and Mw = 7.6) and Colima (October 1995, Mw = 8.0). Fortunately, in this century earthquakes of great magnitude have not occurred in Mexico. However, we have identified well-defined seismic quiescences in the Guerrero seismic-gap, which are apparently correlated with the occurrence of silent earthquakes in 2002, 2006 and 2010 recently discovered by GPS technology.  相似文献   

19.
The Late Permian (260 Ma) Emeishan large igneous province of SW China contains numerous magmatic Fe–Ti oxide deposits. The Fe–Ti oxide deposits occur in the lower parts of evolved layered gabbroic intrusions which are spatially and temporally associated with A-type granitic rocks. The 260 Ma Panzhihua layered gabbroic intrusion hosts one of the largest magmatic Fe–Ti oxide deposits in China and is coeval with a peralkaline A-type granitic pluton. The granite has intruded the overlying Emeishan flood basalts and fed at least one dyke which erupted onto the surface producing columnar jointed trachytes. The presence of syenodiorite between the layered gabbro and granite is evidence for compositional evolution from mafic to intermediate to felsic rocks. The syenodiorites have intermediate to felsic composition with SiO2 = 61 to 65 wt.%, MgO = 0.27 to 0.6 wt.% and CaO = 1.0 to 2.5 wt.% as compared to the granite SiO2 = 65 to 72 wt.%, MgO = 0.1 to 0.4 wt.%, CaO = < 1.0 wt.%. Primitive-mantle-normalized incompatible element plots show corresponding reciprocal patterns between the mafic and felsic rocks. The chondrite-normalized REE patterns show Eu anomalies changing from > 1(Eu/Eu? = 1.1 to 2.6) in the gabbroic intrusion, to < 1 in the syenodiorite (Eu/Eu? = 0.75 to 0.83), granites and trachytes (Eu/Eu? = 0.55–0.87). Previously published εNd(T) values from clinopyroxenes (εNd(T) = + 1.1 to + 3.2) of the gabbroic intrusion match the whole-rock values of the syenodiorite (εNd(T) = + 2.1 to + 2.5), granite and trachyte (εNd(T) = + 2.2 to + 2.9), suggesting that all rock types originated from the same mantle source. MELTS and trace element modeling confirm that all rock types can be generated by fractional crystallization of high-Ti Emeishan basalt. The jump in SiO2 from the gabbro to the syenodiorite is attributed to the en masse crystallization of the Fe–Ti oxides. The geological and geochemical data indicate that fractional crystallization of a common parental magma produced the layered gabbroic intrusion and Fe–Ti oxide deposit, the syenodiorite, granites and trachyte of the Panzhihua region, which thus form a genetically related plutonic-hypabyssal-volcanic complex. Other granite–gabbro complexes in the region likely formed in a similar manner.  相似文献   

20.
We have carried out in situ X-ray diffraction experiments on the FeS–H system up to 16.5 GPa and 1723 K using a Kawai-type multianvil high-pressure apparatus employing synchrotron X-ray radiation. Hydrogen was supplied to FeS from the thermal decomposition of LiAlH4, and FeSHx was formed at high pressures and temperatures. The melting temperature and phase relationships of FeSHx were determined based on in situ powder X-ray diffraction data. The melting temperature of FeSHx was reduced by 150–250 K comparing with that of pure FeS. The hydrogen concentration in FeSHx was determined to be x = 0.2–0.4 just before melting occurred between 3.0 and 16.5 GPa. It is considered that sulfur is the major light element in the core of Ganymede, one of the Galilean satellites of Jupiter. Although the interior of Ganymede is differentiated today, the silicate rock and the iron alloy mixed with H2O, and the iron alloy could react with H2O (as ice or water) or the hydrous silicate before the differentiation occurred in an early period, resulting in a formation of iron hydride. Therefore, Ganymede's core may be composed of an Fe–S–H system. According to our results, hydrogen dissolved in Ganymede's core lowers the melting temperature of the core composition, and so today, the core could have solid FeSHx inner core and liquid FeHx–FeSHx outer core and the present core temperature is considered to be relatively low.  相似文献   

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