Identification of groundwater recharge sources and processes in a heterogeneous alluvial aquifer: results from multi‐level monitoring of hydrochemistry and environmental isotopes in a riverside agricultural area in Korea     

Byoung‐Young Choi  Seong‐Taek Yun  Bernhard Mayer  Gi‐Tak Chae  Kyoung‐Ho Kim  Kangjoo Kim  Yong‐Kwon Koh 《水文研究》2010,24(3):317-330

We evaluated sources and pathways of groundwater recharge for a heterogeneous alluvial aquifer beneath an agricultural field, based on multi‐level monitoring of hydrochemistry and environmental isotopes of a riverside groundwater system at Buyeo, Korea. Two distinct groundwater zones were identified with depth: (1) a shallow oxic groundwater zone, characterized by elevated concentrations of NO₃^? and (2) a deeper (>10–14 m from the ground surface) sub‐oxic groundwater zone with high concentrations of dissolved Fe, silica, and HCO₃^?, but little nitrate. The change of redox zones occurred at a depth where the aquifer sediments change from an upper sandy stratum to a silty stratum with mud caps. The δ¹⁸O and δ²H values of groundwater were also different between the two zones. Hydrochemical and δ¹⁸O? δ²H data of oxic groundwater are similar to those of soil water. This illustrates that recharge of oxic groundwater mainly occurs through direct infiltration of rain and irrigation water in the sandy soil area where vegetable cropping with abundant fertilizer use is predominant. Oxic groundwater is therefore severely contaminated by agrochemical pollutants such as nitrate. In contrast, deeper sub‐oxic groundwater contains only small amounts of dissolved oxygen (DO) and NO₃^?. The ³H contents and elevated silica concentrations in sub‐oxic groundwater indicate a somewhat longer mean residence time of groundwater within this part of the aquifer. Sub‐oxic groundwater was also characterized by higher δ¹⁸O and δ²H values and lower d‐excess values, indicating significant evaporation during recharge. We suggest that recharge of sub‐oxic groundwater occurs in the areas of paddy rice fields where standing irrigation and rain water are affected by strong evaporation, and that reducing conditions develop during subsequent sub‐surface infiltration. This study illustrates the existence of two groundwater bodies with different recharge processes within an alluvial aquifer. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

A Geochemical Approach to Determine Sources and Movement of Saline Groundwater in a Coastal Aquifer   总被引：1，自引：0，他引：1  

Robert Anders  Gregory O. Mendez  Kiyoto Futa  Wesley R. Danskin 《Ground water》2014,52(5):756-768

Geochemical evaluation of the sources and movement of saline groundwater in coastal aquifers can aid in the initial mapping of the subsurface when geological information is unavailable. Chloride concentrations of groundwater in a coastal aquifer near San Diego, California, range from about 57 to 39,400 mg/L. On the basis of relative proportions of major‐ions, the chemical composition is classified as Na‐Ca‐Cl‐SO₄, Na‐Cl, or Na‐Ca‐Cl type water. δ²H and δ¹⁸O values range from ?47.7‰ to ?12.8‰ and from ?7.0‰ to ?1.2‰, respectively. The isotopically depleted groundwater occurs in the deeper part of the coastal aquifer, and the isotopically enriched groundwater occurs in zones of sea water intrusion. ⁸⁷Sr/⁸⁶Sr ratios range from about 0.7050 to 0.7090, and differ between shallower and deeper flow paths in the coastal aquifer. ³H and ¹⁴C analyses indicate that most of the groundwater was recharged many thousands of years ago. The analysis of multiple chemical and isotopic tracers indicates that the sources and movement of saline groundwater in the San Diego coastal aquifer are dominated by: (1) recharge of local precipitation in relatively shallow parts of the flow system; (2) regional flow of recharge of higher‐elevation precipitation along deep flow paths that freshen a previously saline aquifer; and (3) intrusion of sea water that entered the aquifer primarily during premodern times. Two northwest‐to‐southeast trending sections show the spatial distribution of the different geochemical groups and suggest the subsurface in the coastal aquifer can be separated into two predominant hydrostratigraphic layers.  相似文献   

Denitrification in a Deep Basalt Aquifer: Implications for Aquifer Storage and Recovery     

Dennis Nelson  Jason Melady 《Ground water》2014,52(3):414-423

Aquifer storage and recovery (ASR) can provide a means of storing water for irrigation in agricultural areas where water availability is limited. A concern, however, is that the injected water may lead to a degradation of groundwater quality. In many agricultural areas, nitrate is a limiting factor. In the Umatilla Basin in north central Oregon, shallow alluvial groundwater with elevated nitrate‐nitrogen of <3 mg/L to >9 mg/L is injected into the Columbia River Basalt Group (CRBG), a transmissive confined aquifer(s) with low natural recharge rates. Once recovery of the injected water begins, however, NO₃‐N in the recovered water decreases quickly to <3 mg/L (Eaton et al. 2009), suggesting that NO₃‐N may not persist within the CRBG during ASR storage. In contrast to NO₃‐N, other constituents in the recovered water show little variation, inconsistent with migration or simple mixing as an explanation of the NO₃‐N decrease. Nitrogen isotopic ratios (δ¹⁵N) increase markedly, ranging from +3.5 to > +50, and correlate inversely with NO₃‐N concentrations. This variation occurs in <3 weeks and recovery of <10% of the originally injected volume. TOC is low in the basalt aquifer, averaging <1.5 mg/L, but high in the injected source water, averaging >3.0 mg/L. Similar to nitrate concentrations, TOC drops in the recovered water, consistent with this component contributing to the denitrification of nitrate during storage.  相似文献   

Assessing the Relative Bioavailability of DOC in Regional Groundwater Systems   总被引：2，自引：0，他引：2  

Francis H. Chapelle  Paul M. Bradley  Celeste A. Journey  Peter B. McMahon 《Ground water》2013,51(3):363-372

It has been hypothesized that the degree to which a hyperbolic relationship exists between concentrations of dissolved organic carbon (DOC) and dissolved oxygen (DO) in groundwater may indicate the relative bioavailability of DOC. This hypothesis was examined for 73 different regional aquifers of the United States using 7745 analyses of groundwater compiled by the National Water Assessment (NAWQA) program of the U.S. Geological Survey. The relative reaction quotient (RRQ), a measure of the curvature of DOC concentrations plotted versus DO concentrations and regressed to a decaying hyperbolic equation, was used to assess the relative bioavailability of DOC. For the basalt aquifer of Oahu, Hawaii, RRQ values were low (0.0013 mM^?2), reflecting a nearly random relationship between DOC and DO concentrations. In contrast, on the island of Maui, treated sewage effluent injected into a portion of the basalt aquifer resulted in pronounced hyperbolic DOC‐DO behavior and a higher RRQ (142 mM^?2). RRQ values for the 73 aquifers correlated positively with mean concentrations of ammonia, dissolved iron, and manganese, and correlated negatively with mean pH. This indicates that greater RRQ values are associated with greater concentrations of the final products of microbial reduction reactions. RRQ values and DOC concentrations were negatively correlated with the thickness of the unsaturated zone (UNST) and depth to the top of the screened interval. Finally, RRQ values were positively correlated with mean annual precipitation (MAP), and the highest observed RRQ values were associated with aquifers receiving MAP rates ranging between 900 and 1300 mm/year. These results are uniformly consistent with the hypothesis that the hyperbolic behavior of DOC‐DO plots, as quantified by the RRQ metric, can be an indicator of relative DOC bioavailability in groundwater systems.  相似文献   

Groundwater recharge sources in semiarid irrigated mountain fronts     

Houssne Bouimouass  Younes Fakir  Sarah Tweed  Marc Leblanc 《水文研究》2020,34(7):1598-1615

High-elevation mountains often constitute for basins important groundwater recharge sources through mountain-front recharge processes. These processes include streamflow losses and subsurface inflow from the mountain block. However, another key recharge process is from irrigation practices, where mountain streamflow is distributed across the irrigated piedmont. In this study, coupled groundwater fluctuation measurements and environmental tracers (¹⁸O, ²H, and major ions) were used to identify and compare the natural mountain-front recharge to the anthropogenically induced irrigation recharge. Within the High Atlas mountain front of the Ourika Basin, Central Morocco, the groundwater fluctuation mapping from the dry to wet season showed that recharge beneath the irrigated area was higher than the recharge along the streambed. Irrigation practices in the region divert more than 65% of the stream water, thereby reducing the potential for in-stream groundwater recharge. In addition, the irrigation areas close to the mountain front had greater water table increases (up to 3.5 m) compared with the downstream irrigation areas (<1 m increase). Upstream crops have priority to irrigation with stream water over downstream areas. The latter are only irrigated via stream water during large flood events and are otherwise supplemented by groundwater resources. These changes in water resources used for irrigation practices between upstream and downstream areas are reflected in the spatiotemporal evolution of the stable isotopes of groundwater. In the upstream irrigation area, the groundwater stable isotope values (δ¹⁸O: −8.4‰ to −7.4‰) reflect recharge by the diverted stream water. In the downstream irrigation area, the groundwater isotope values are lower (δ¹⁸O: −8.1‰ to −8.4‰) due to recharge via the flood water. In the nonirrigation area, the groundwater has the highest stable isotope values (δ¹⁸O: −6.8‰ to −4.8‰). This might be due to recharge via subsurface inflow from the mountain block to the mountain front and/or recharge via local low altitude rainfall. These findings highlight that irrigation practices can result in the dominant mountain-front recharge process for groundwater.  相似文献   

Rapid nutrient load reduction during infiltration of managed aquifer recharge in an agricultural groundwater basin: Pajaro Valley,California     

C. M. Schmidt  A. T. Fisher  A. Racz  C. G. Wheat  M. Los Huertos  B. Lockwood 《水文研究》2012,26(15):2235-2247

Artificial recharge of groundwater is an increasingly important method for augmenting groundwater supply and can have a positive or negative influence on the quality of water resources. We instrumented a managed aquifer recharge (MAR) pond in central coastal California to assess how patterns of infiltration and recharge affect the load of nitrate delivered to the underlying aquifer. The concentration of nitrate in infiltrating water consistently decreased during passage through the first metre of subsurface soils. Enrichment of ¹⁸O and ¹⁵ N in the residual nitrate in infiltrating water proceeded in a ratio of 1:2, indicating that denitrification plays a significant role in the quantitative reduction of nutrients exported during infiltration through shallow soils. The extent and rate of nitrate removal was spatially and temporally variable across the bottom of the recharge pond, with 30% to 60% of the nitrate load being removed over the first 6 weeks of managed aquifer recharge operation. During the period of highest N loading to the system, when the average infiltration rate was > 1 m/day, the recharge pond achieved a load reduction efficiency of 7 kg NO₃^?‐N/day/ha, which compares favourably to nitrate load reductions achieved by treatment wetlands. Groundwater mounding and water composition below the recharge pond suggest that recharge and subsequent lateral transport occur heterogeneously in the underlying aquifer. Nitrate concentrations in the aquifer following infiltration were lowered primarily by dilution, with little evidence for additional denitrification occurring in the aquifer in comparison to high rates documented during shallow infiltration. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

A Black Hills-Madison Aquifer Origin for Dakota Aquifer Groundwater in Northeastern Nebraska     

Randy Stotler  F. Edwin Harvey  David C. Gosselin 《Ground water》2010,48(3):448-464

Previous studies of the Dakota Aquifer in South Dakota attributed elevated groundwater sulfate concentrations to Madison Aquifer recharge in the Black Hills with subsequent chemical evolution prior to upward migration into the Dakota Aquifer. This study examines the plausibility of a Madison Aquifer origin for groundwater in northeastern Nebraska. Dakota Aquifer water samples were collected for major ion chemistry and isotopic analysis (¹⁸O, ²H, ³H, ¹⁴C, ¹³C, ³⁴S, ¹⁸O-SO₄, ⁸⁷Sr, ³⁷Cl). Results show that groundwater beneath the eastern, unconfined portion of the study area is distinctly different from groundwater sampled beneath the western, confined portion. In the east, groundwater is calcium-bicarbonate type, with δ¹⁸O values (−9.6 to −12.4) similar to local, modern precipitation (−7.4 to −10), and tritium values reflecting modern recharge. In the west, groundwater is calcium-sulfate type, having depleted δ¹⁸O values (−16 to −18) relative to local, modern precipitation, and ¹⁴C ages 32,000 to more than 47,000 years before present. Sulfate, δ¹⁸O, δ²H, δ³⁴S, and δ¹⁸O-SO₄ concentrations are similar to those found in Madison Aquifer groundwater in South Dakota. Thus, it is proposed that Madison Aquifer source water is also present within the Dakota Aquifer beneath northeastern Nebraska. A simple Darcy equation estimate of groundwater velocities and travel times using reported physical parameters from the Madison and Dakota Aquifers suggests such a migration is plausible. However, discrepancies between ¹⁴C and Darcy age estimates indicate that ¹⁴C ages may not accurately reflect aquifer residence time, due to mixtures of varying aged water.  相似文献   

Arsenic Control During Aquifer Storage Recovery Cycle Tests in the Floridan Aquifer     

June E. Mirecki  Michael W. Bennett  Marie C. López‐Baláez 《Ground water》2013,51(4):539-549

Implementation of aquifer storage recovery (ASR) for water resource management in Florida is impeded by arsenic mobilization. Arsenic, released by pyrite oxidation during the recharge phase, sometimes results in groundwater concentrations that exceed the 10 µg/L criterion defined in the Safe Drinking Water Act. ASR was proposed as a major storage component for the Comprehensive Everglades Restoration Plan (CERP), in which excess surface water is stored during the wet season, and then distributed during the dry season for ecosystem restoration. To evaluate ASR system performance for CERP goals, three cycle tests were conducted, with extensive water‐quality monitoring in the Upper Floridan Aquifer (UFA) at the Kissimmee River ASR (KRASR) pilot system. During each cycle test, redox evolution from sub‐oxic to sulfate‐reducing conditions occurs in the UFA storage zone, as indicated by decreasing Fe²⁺/H₂S mass ratios. Arsenic, released by pyrite oxidation during recharge, is sequestered during storage and recovery by co‐precipitation with iron sulfide. Mineral saturation indices indicate that amorphous iron oxide (a sorption surface for arsenic) is stable only during oxic and sub‐oxic conditions of the recharge phase, but iron sulfide (which co‐precipitates arsenic) is stable during the sulfate‐reducing conditions of the storage and recovery phases. Resultant arsenic concentrations in recovered water are below the 10 µg/L regulatory criterion during cycle tests 2 and 3. The arsenic sequestration process is appropriate for other ASR systems that recharge treated surface water into a sulfate‐reducing aquifer.  相似文献   

Response of deep groundwater to land use change in desert basins of the Trans‐Pecos region,Texas, USA: Effects on infiltration,recharge, and nitrogen fluxes          下载免费PDF全文

Wendy Marie Robertson  J. K. Böhlke  John M. Sharp Jr 《水文研究》2017,31(13):2349-2364

Quantifying the effects of anthropogenic processes on groundwater in arid regions can be complicated by thick unsaturated zones with long transit times. Human activities can alter water and nutrient fluxes, but their impact on groundwater is not always clear. This study of basins in the Trans‐Pecos region of Texas links anthropogenic land use and vegetation change with alterations to unsaturated zone fluxes and regional increases in basin groundwater NO₃^? concentrations. Median increases in groundwater NO₃^? (by 0.7–0.9 mg‐N/l over periods ranging from 10 to 50+ years) occurred despite low precipitation (220–360 mm/year), high potential evapotranspiration (~1570 mm/year), and thick unsaturated zones (10–150+ m). Recent model simulations indicate net infiltration and groundwater recharge can occur beneath Trans‐Pecos basin floors, and may have increased due to irrigation and vegetation change. These processes were investigated further with chemical and isotopic data from groundwater and unsaturated zone cores. Some unsaturated zone solute profiles indicate flushing of natural salt accumulations has occurred. Results are consistent with human‐influenced flushing of naturally accumulated unsaturated zone nitrogen as an important source of NO₃^? to the groundwater. Regional mass balance calculations indicate the mass of natural unsaturated zone NO₃^? (122–910 kg‐N/ha) was sufficient to cause the observed groundwater NO₃^? increases, especially if augmented locally with the addition of fertilizer N. Groundwater NO₃^? trends can be explained by small volumes of high NO₃^? modern recharge mixed with larger volumes of older groundwater in wells. This study illustrates the importance of combining long‐term monitoring and targeted process studies to improve understanding of human impacts on recharge and nutrient cycling in arid regions, which are vulnerable to the effects of climate change and increasing human reliance on dryland ecosystems.  相似文献   

Innovative Environmental Tracer Techniques for Evaluating Sources of Spring Discharge from a Carbonate Aquifer Bisected by a River   总被引：2，自引：0，他引：2  

Victor M. Heilweil  Donald S. Sweetkind  Steven J. Gerner 《Ground water》2014,52(1):71-83

Littlefield Springs discharge about 1.6 m³/s along a 10‐km reach of the Virgin River in northwestern Arizona. Understanding their source is important for salinity control in the Colorado River Basin. Environmental tracers suggest that Littlefield Springs are a mixture of older groundwater from the regional Great Basin carbonate aquifer and modern (post‐1950s) seepage from the Virgin River. While corrected ¹⁴C apparent ages range from 1 to 9 ka, large amounts of nucleogenic ⁴He and low ³He/⁴He ratios suggest that the carbonate aquifer component is likely even older Pleistocene recharge. Modeled infiltration of precipitation, hydrogeologic cross sections, and hydraulic gradients all indicate recharge to the carbonate aquifer likely occurs in the Clover and Bull Valley Mountains along the northern part of the watershed, rather than in the nearby Virgin Mountains. This high‐altitude recharge is supported by relatively cool noble‐gas recharge temperatures and isotopically depleted δ²H and δ¹⁸O. Excess (crustal) SF₆ and ⁴He precluded dating of the modern component of water from Littlefield Springs using SF₆ and ³H/³He methods. Assuming a lumped‐parameter model with a binary mixture of two piston‐flow components, Cl^?/Br^?, Cl^?/F^?, δ²H, and CFCs indicate the mixture is about 60% Virgin River water and 40% groundwater from the carbonate aquifer, with an approximately 30‐year groundwater travel time for Virgin River seepage to re‐emerge at Littlefield Springs. This suggests that removal of high‐salinity sources upstream of the Virgin River Gorge would reduce the salinity of water discharging from Littlefield Springs into the Virgin River within a few decades.  相似文献   

Bioattenuation in groundwater impacted by landfill leachate traced with δ13C     

Mohammadzadeh H  Clark I 《Ground water》2011,49(6):880-890

The impact on groundwater imparted by the infiltration of high dissolved organic carbon (DOC) leachate from capped, unlined landfills can be attenuated by biogeochemical reactions beyond the waste source, although such reactive loss in the aquifer is difficult to distinguish from conservative advective dispersion. Compound-specific measurement of δ(13)C in carbon species, including CH(4), dissolved inorganic carbon (DIC), and the major DOC compounds (acetate, humic acid, and fulvic acid) provides a constraint in this assessment that can assist in exercises of modeling and prediction of leachate transport. The Trail Road municipal landfill near Ottawa, Ontario, Canada, hosts an unlined sector which produces a highly enriched leachate (DOC >4500 mg/L) that provides a good site to examine reactive attenuation within the receptor aquifer. Acetate, a sentinel component of leachate DOC (~1000 mg C/L), is absent in impacted groundwater. Mass balance calculations together with reaction modeling suggest continued acetate fermentation with calcite control on DIC and δ(13)C(DIC) evolution. In groundwater within 50 m of the landfill, methane concentrations are elevated (~10 mg/L), consistent with acetate fermentation, whereas δ(13)C(CH4) measurements in deeper groundwater range down to -51‰ compared with -60‰ in the landfill demonstrating oxidative loss. DOC in the deep aquifer is remarkably depleted to values less than -40‰ suggesting methanotrophic bacteria selectively consume isotopically light CH(4) to fix carbon. Continued reaction of leachate DOC in groundwater is demonstrated by evolution away from conservative mixing lines on diagrams of δ(13)C vs. concentrations of DIC and DOC.  相似文献   

Multivariate statistical analysis and environmental isotopes of Amman/Wadi Sir (B2/A7) groundwater,Yarmouk River Basin,Jordan     

Mutewekil Mamdouh Obeidat  Muheeb Awawdeh  Fahmi Abu Al‐Rub 《水文研究》2013,27(17):2449-2461

Multivariate statistical techniques, cluster and factor analyses were applied on the Amman/Wadi Sir groundwater chemistry, Yarmouk River basin, north Jordan. The main objective was to investigate the main processes affecting the groundwater chemical quality and its evolution. The k‐means cluster analysis yields three groups with distinct ionic concentrations. Cluster 1 comprises the vast majority of the sampled wells, and the water that belongs to this cluster can be classified as freshwater. Cluster 2 comprises only 2% of the sampled wells; it has the highest ionic concentration. The water of this cluster can be classified as brackish water. Cluster 3 involves 23% of the sampled wells, and it has total ionic concentration intermediate to that of clusters 1 and 2. Factor analysis yields a three‐factor model, which explains 76.77% of the groundwater quality variation. Factor 1 ‘salinity factor’ involves EC, Na⁺, Cl^‐, SO₄^‐2, K⁺ and Mg⁺² and reflects groundwater salinization because of overpumping. Factor 2 ‘hardness factor’ includes Ca⁺², HCO₃^‐ and the pH value and signifies soil–water/rock interaction. Factor 3 ‘nitrate factor’ involves only NO₃^‐ and points to groundwater contamination because of human activities, mainly untreated wastewater, and crops and animal cultivation in the unconfined portion of the aquifer. Factors 1 and 3 can be described as human‐induced factors, whereas factor 2 can be described as geogenic factor. Factors' scores were mapped to deduce the controlling processes on the groundwater chemistry. Stable isotope composition of ¹⁸O and ²H has revealed that the groundwater is a mixture of two water types. The radioactive isotopes tritium and ¹⁴ C were used to evaluate present day recharge to the aquifer and to estimate the groundwater age, respectively. Present day recharge to the groundwater is taking place in the unconfined portion of the aquifer as it is indicated by the measurable tritium content and low groundwater age. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

Impacts of human activities on recharge in a multilayered semiarid aquifer (Campo de Cartagena,SE Spain)   总被引：1，自引：0，他引：1       下载免费PDF全文

Paul Baudron  Florent Barbecot  José Luis García Aróstegui  Christian Leduc  Yves Travi  David Martinez‐Vicente 《水文研究》2014,28(4):2223-2236

The development of intense agriculture in semiarid areas modifies intensity and spatial distribution of groundwater recharge by summing irrigation return flow to limited rainfall infiltration. Environmental tracers provide key information, but their interpretation is complicated by more complex groundwater flow patterns. In multilayered aquifers, the real origin of the groundwater samples is hard to assess because of local mixing processes occurring inside long‐screened boreholes. We use environmental tracers (¹⁴C, ¹³C, ²H, ¹⁸O, ³H) to investigate the long‐term evolution of recharge in the five‐layer Campo de Cartagena aquifer in South‐Eastern Spain, in addition to high‐resolution temperature loggings to identify the depth of origin of groundwater. Despite the complex background, this methodology allowed a reliable interpretation of the geochemistry and provided a better understanding of the groundwater flow patterns. The tritium method did not give good quantitative results because of the high variability of the recharge signal but remained an excellent indicator of recent recharge. Nonetheless, both pre‐anthropization and post‐anthropization recharge regime could be identified and quantified by radiocarbon. Before the development of agriculture, recharge varied from 17 mm.year^‐1 at the mountain ranges to 6 mm.year^‐1 in the plain, whereas the mean annual rainfall is about 300 mm. In response to the increase of agricultural activity, recharge fluxes to the plain were amplified and nowadays reach up to 210 mm.year^‐1 in irrigated areas. These values are strengthened by global water budget and local unsaturated zone studies. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

Field‐Scale Relationships Among Soil Properties and Shallow Groundwater Quality     

Nathan E. Derby  Scott F. Korom  Francis X.M. Casey 《Ground water》2013,51(3):373-384

It is important to understand the link between land surface/soil properties and shallow groundwater quality. To that end, soil properties and near‐water‐table groundwater chemistry of a shallow, unconfined aquifer were measured on a 100‐m grid on a 64‐ha irrigated field in southeastern North Dakota. Soil properties and hydrochemistry were compared via multivariate analysis that included product‐moment correlations and factor analysis/principal component analysis. Topographic low areas where the water table was in close proximity to the soil surface generally had higher apparent electrical conductivity (EC_a) and higher percent silt and clay than higher positions on the landscape. The majority of the groundwater was characterized by Ca‐ and Mg‐HCO₃ type water and was associated with topographic high areas with lower EC_a and net groundwater recharge. Small topographic depressions were areas of higher EC_a (net groundwater discharge) where salts that precipitated via evapotranspiration and evaporative discharge dissolved and leached to the groundwater during short‐term depression‐focused recharge events. At this site, groundwater quality and soil EC_a were related to surface topography. High‐resolution topography and EC_a measurements are necessary to characterize the land surface/soil properties and surficial groundwater quality at the field‐scale and to delineate areas where the shallow groundwater is most susceptible to contamination.  相似文献   

Relationships between microbial communities and groundwater chemistry in two pristine confined groundwater aquifers in central China     

Jie Ma  Hui Liu  Lei Tong  Yan Wang  Rong Chen  Shan Liu  Lei Zhao  Zhimin Li  Liegang Cai 《水文研究》2019,33(14):1993-2005

This study explores linkages between the microbial composition and hydrochemical variables of pristine groundwater to identify active redox conditions and processes. Two confined aquifers underlying the city of Qianjiang in the Jianghan Plain in China were selected for this study, having different recharge sources and strong hydrochemical gradients. Typical methods for establishing redox processes according to threshold concentration criteria for geochemical parameters suggest iron or sulphate reduction processes. High‐throughput 16S rRNA sequencing was used to obtain diversity and taxonomic information on microbial communities. Instead of revealing iron‐ and sulphate‐reducing bacteria, salt‐ and alkali‐tolerant bacteria, such as the phylum Firmicutes and the class Gammaproteobacteria, and in particular, the family Bacillaceae, were dominant in the downstream groundwater of the first aquifer that had high ion concentrations caused by the dissolution of calcite and dolomite; meanwhile, the heterotrophic microaerophilic families Comamonadaceae and Rhodocyclaceae prevailed in the upstream groundwater of the first aquifer. Sulphate‐reducing bacteria were extremely abundant in the upstream groundwater of the second aquifer, as the SO₄^2? concentration was especially high. Methanogens and methanotrophs were predominant in the downstream groundwater of the second aquifer even though the concentration of SO₄^2? was much higher than 0.5 mg L^?1. The microbial communities, together with the geochemical parameters, indicated that the upstream region of the first aquifer was suboxic, that Fe(III) and Mn(IV) reductions were not the main redox processes in the downstream groundwater of the first aquifer with high Fe and Mn concentrations, and that the redox processes in the upstream and downstream regions of the second confined aquifer were SO₄^2? reduction and methanogenesis, respectively. This study expands understanding of the linkages between microbial communities and hydrogeochemistry in pristine groundwaters and provides more evidence for identifying active redox conditions and processes.  相似文献   

Variation of hydrogeochemical characteristics of water in surface flows,shallow wells,and boreholes in the coastal city of Douala (Cameroon)     

Wilson Y. Fantong  Brice T. Kamtchueng  Beatrice Ketchemen-Tandia  Doris Kuitcha  Josephine Ndjama  Alain T. Fouepe 《水文科学杂志》2013,58(16):2916-2929

ABSTRACT

Groundwater is used by 3?million inhabitants in the coastal urban city of Douala, Cameroon, but comprehensive data are too sparse for it to be managed in a sustainable manner. Hence this study aimed to (1) assess the potability of the groundwater; (2) evaluate the spatial variation of groundwater composition; and (3) assess the interaction and recharge mechanisms of different water bodies. Hydrogeochemical tools and methods revealed the following results in the Wouri and Nkappa formations of the Douala basin, which is beneath Douala city: 30% of water samples from hand-dug wells in the shallow Pleistocene alluvium aquifer were saline and highly mineralized. However, water from boreholes in the deeper (49–92 m depth) Palaeocene aquifer was saline-free, less mineralized and potable. Water in the shallow aquifer (0.5–22 m depth) was of Na⁺-K⁺-Cl^?-NO₃^? type and not potable due to point source pollution, whereas Ca⁺-HCO₃^? unpolluted water dominates in the deeper aquifer. Water in the deep and shallow aquifers indicates the results of preferential flow pass and evaporative recharge, respectively. Possible hydrogeochemical processes include point source pollution, reverse ion exchange, remote recharge areas and mixing of waters with different chemical signatures.