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1.
Biostimulation is increasingly used to accelerate microbial remediation of recalcitrant groundwater contaminants. Effective application of biostimulation requires successful emplacement of amendment in the contaminant target zone. Verification of remediation performance requires postemplacement assessment and contaminant monitoring. Sampling‐based approaches are expensive and provide low‐density spatial and temporal information. Time‐lapse electrical resistivity tomography (ERT) is an effective geophysical method for determining temporal changes in subsurface electrical conductivity. Because remedial amendments and biostimulation‐related biogeochemical processes often change subsurface electrical conductivity, ERT can complement and enhance sampling‐based approaches for assessing emplacement and monitoring biostimulation‐based remediation. Field studies demonstrating the ability of time‐lapse ERT to monitor amendment emplacement and behavior were performed during a biostimulation remediation effort conducted at the Department of Defense Reutilization and Marketing Office (DRMO) Yard, in Brandywine, Maryland, United States. Geochemical fluid sampling was used to calibrate a petrophysical relation in order to predict groundwater indicators of amendment distribution. The petrophysical relations were field validated by comparing predictions to sequestered fluid sample results, thus demonstrating the potential of electrical geophysics for quantitative assessment of amendment‐related geochemical properties. Crosshole radar zero‐offset profile and borehole geophysical logging were also performed to augment the data set and validate interpretation. In addition to delineating amendment transport in the first 10 months after emplacement, the time‐lapse ERT results show later changes in bulk electrical properties interpreted as mineral precipitation. Results support the use of more cost‐effective surface‐based ERT in conjunction with limited field sampling to improve spatial and temporal monitoring of amendment emplacement and remediation performance.  相似文献   

2.
Stream–subsurface exchange strongly influences the transport of contaminants, fine particles, and other ecologically relevant substances in streams. We used a recirculating laboratory flume (220 cm long and 20 cm wide) to study the effects of particle size, overlying velocity, and biofilm formation on stream–subsurface exchange of particles. Sodium chloride was used as a non‐reactive dissolved tracer and 1‐ and 5‐µm fluorescent microspheres were used as particulate tracers. Surface–subsurface exchange was observed with a clean sand bed and a bed colonized by an autotrophic–heterotrophic biofilm under two different overlying velocities, 0·9 and 5 cm s?1. Hydrodynamic interactions between the overlying flow and sand bed resulted in a reduction of solute and particle concentrations in the water column, and a corresponding accumulation of particles in both the sediments and in the biofilm. Increasing overlying velocity and particle size resulted in faster removal from the overlying water due to enhanced mass transfer to the bed. The presence of the biofilm did not affect solute exchange under any flow condition tested. The presence of the biofilm significantly increased the deposition of particles under an overlying velocity of 5 cm s?1, and produced a small but statistically insignificant increase at 0·9 cm?1. The particles preferentially deposited within the biofilm matrix relative to the underlying sand. These results demonstrate that hydrodynamic transport conditions, particle size, and biofilm formation play a key role in the transport of suspended particles, such as inorganic sediments, particulate organic matter, and pathogenic microorganisms in freshwater ecosystems, and should be taken into consideration when predicting the fate and transport of particles and contaminants in the environment. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

3.
Electrical geophysical methods, including electrical resistivity, time‐domain induced polarization, and complex resistivity, have become commonly used to image the near subsurface. Here, we outline their utility for time‐lapse imaging of hydrological, geochemical, and biogeochemical processes, focusing on new instrumentation, processing, and analysis techniques specific to monitoring. We review data collection procedures, parameters measured, and petrophysical relationships and then outline the state of the science with respect to inversion methodologies, including coupled inversion. We conclude by highlighting recent research focused on innovative applications of time‐lapse imaging in hydrology, biology, ecology, and geochemistry, among other areas of interest. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

4.
A modified version of the MODFLOW/MT3DMS‐based reactive transport model PHT3D was developed to extend current reactive transport capabilities to the variably‐saturated component of the subsurface system and incorporate diffusive reactive transport of gaseous species. Referred to as PHT3D‐UZF, this code incorporates flux terms calculated by MODFLOW's unsaturated‐zone flow (UZF1) package. A volume‐averaged approach similar to the method used in UZF‐MT3DMS was adopted. The PHREEQC‐based computation of chemical processes within PHT3D‐UZF in combination with the analytical solution method of UZF1 allows for comprehensive reactive transport investigations (i.e., biogeochemical transformations) that jointly involve saturated and unsaturated zone processes. Intended for regional‐scale applications, UZF1 simulates downward‐only flux within the unsaturated zone. The model was tested by comparing simulation results with those of existing numerical models. The comparison was performed for several benchmark problems that cover a range of important hydrological and reactive transport processes. A 2D simulation scenario was defined to illustrate the geochemical evolution following dewatering in a sandy acid sulfate soil environment. Other potential applications include the simulation of biogeochemical processes in variably‐saturated systems that track the transport and fate of agricultural pollutants, nutrients, natural and xenobiotic organic compounds and micropollutants such as pharmaceuticals, as well as the evolution of isotope patterns.  相似文献   

5.
The remediation industry has witnessed multiple innovations arising from a greater understanding of the physical, chemical, and biological processes that control the fate and transport of chemicals in the subsurface environment. In addition, increasing emphasis is being placed on remediation solutions that are greener, simpler, and more resource efficient. The positive impacts that can be derived from this emphasis include reduced energy consumption, reduced waste emissions, and lower costs. Temperature‐activated auto‐decomposition reactions represent a potentially underutilized option for the in situ remediation of certain organic contaminants, and an option that can be both highly effective and greener than other available technologies.  相似文献   

6.
Stream–subsurface exchange plays a significant role in the fate and transport of contaminants in streams. It has been modelled explicitly by considering fundamental processes such as hydraulic exchange, colloid filtration, and contaminant interactions with streambed sediments and colloids. The models have been successfully applied to simulate the transport of inorganic metals and nutrients. In this study, laboratory experiments were conducted in a recirculating flume to investigate the exchange of a hydrophobic organic contaminant, p,p′‐dichloro‐diphenyl‐dichloroethane (DDE), between a stream and a quartz sand bed. A previously developed process‐based multiphase exchange model was modified by accounting for the p,p′‐DDE kinetic adsorption to and desorption from the bed sediments/colloids and was applied to interpret the experimental results. Model input parameters were obtained by conducting independent small‐scale batch experiments. Results indicate that the immobilization of p,p′‐DDE in the quartz sand bed can occur under representative natural stream conditions. The observed p,p′‐DDE exchange was successfully simulated by the process‐based model. The model sensitivity analysis results show that the exchange of p,p′‐DDE can be sensitive to either the sediment sorption/desorption parameters or colloidal parameters depending on the experimental conditions tested. For the experimental conditions employed here, the effect of colloids on contaminant transport is expected to be minimal, and the stream–subsurface exchange of p,p′‐DDE is dominated by the interaction of p,p′‐DDE with bed sediment. The work presented here contributes to a better mechanistic understanding of the complex transport process that hydrophobic organic contaminants undergo in natural streams and to the development of reliable, predictive models for the assessment of impacted streams. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

7.
Understanding the transport behavior, survival, and persistence of pathogens such as Escherichia coli O157:H7 in the subsurface is essential to protection of public health. In this study, the transport of E. coli O157:H7 in a two‐dimensional bench‐scale sand aquifer system, hereafter referred to as the sandbox, was investigated, with a focus on the impact of biofilm development on E. coli retention and survival. Biofilm growth was initiated through flushing with unsterilized groundwater and addition of glucose, nitrate, and phosphate. Retention of E. coli from an injection test in clean sand, prior to promotion of biofilm growth, was approximately 9%. Subsequent to biofilm growth, 47% of injected E. coli cells were retained under similar flow conditions. After 10 d of no flow, sterile water was flushed through the biofouled sandbox and substantial concentrations (up to 1.5 × 105 cells/mL) of E. coli were measured in the effluent indicating that E. coli had survived the starvation period. Confocal laser scanning microscopy revealed that E. coli were located not only on the surface but also within the biofilm. Imposition of starvation conditions resulted in biofilm sloughing and possible mobilization of biofilm‐associated E. coli.  相似文献   

8.
This study presents the first high‐resolution dataset of dissolved oxygen (DO) measurements in an ice‐lidded cryoconite hole on Canada Glacier, McMurdo Dry Valleys, Antarctica. Fibre optic DO minisensors were installed in a cryoconite hole prior to seasonal internal melting and hydrological connection to the subsurface drainage system. Oxygen air saturation in the cryoconite hole typically ranged from 50 to 80%, in broad agreement with previous single measurements, indicating net respiration (R). This is consistent with results of simple incubation experiments performed in the field. Simultaneous time series for electrical conductivity, water temperature, and DO over the four‐week study period provide information regarding the connectivity of cryoconite holes with the near‐surface drainage system. The main driver of the observed variations in DO is likely to be periodic melt‐freeze cycles. We conclude that automated sensing techniques, such as those described here, when used in conjunction with physical measurements, have great potential for high‐resolution monitoring of the factors that perturb biogeochemical processes in cryospheric surface aquatic ecosystems. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

9.
We reformulate the original model of Hatchell and Bourne and Røste, Stovas and Landrø that couples fractional velocity change to subsurface strain via a fundamental constant R. The new model combines elastic compressibility of a dual‐porosity system for a sand–shale mixture with horizontal planes of inter‐granular weakness. The majority of observed R‐factor magnitudes from post‐stack 4D seismic data in both the reservoir and overburden can thus be explained. R is predicted to depend strongly on lithology and also initial strain state. The model is also extended to predict the observed angle‐dependence of time‐lapse time‐shifts from pre‐stack data. An expression for the gradient of time‐shift with incidence angle is obtained in terms of the background VP/VS, and also the ratio of tangential to normal compliances BT/BN representing loss or creation of inter‐granular coupling. If accurately estimated from data, this compliance ratio can be used as an additional parameter to assess the post‐production state of the overburden. It is concluded that whilst R remains the over‐arching parameter controlling the magnitude of time‐shifts measured from 4D seismic data, BT/BN is a subtler parameter that may also prove of future value.  相似文献   

10.
Time‐lapse seismic analysis is utilized in CO2 geosequestration to verify the CO2 containment within a reservoir. A major risk associated with geosequestration is a possible leakage of CO2 from the storage formation into overlaying formations. To mitigate this risk, the deployment of carbon capture and storage projects requires fast and reliable detection of relatively small volumes of CO2 outside the storage formation. To do this, it is necessary to predict typical seepage scenarios and improve subsurface seepage detection methods. In this work we present a technique for CO2 monitoring based on the detection of diffracted waves in time‐lapse seismic data. In the case of CO2 seepage, the migrating plume might form small secondary accumulations that would produce diffracted, rather than reflected waves. From time‐lapse data analysis, we are able to separate the diffracted waves from the predominant reflections in order to image the small CO2 plumes. To explore possibilities to detect relatively small amounts of CO2, we performed synthetic time‐lapse seismic modelling based on the Cooperative Research Centre for Greenhouse Gas Technologies (CO2CRC) Otway project data. The detection method is based on defining the CO2 location by measuring the coherency of the signal along diffraction offset‐traveltime curves. The technique is applied to a time‐lapse stacked section using a stacking velocity to construct offset‐traveltime curves. Given the amount of noise found in the surface seismic data, the predicted minimum detectable amount of CO2 is 1000–2000 tonnes. This method was also applied to real data obtained from a time‐lapse seismic physical model. The use of diffractions rather than reflections for monitoring small amounts of CO2 can enhance the capability of subsurface monitoring in CO2 geosequestration projects.  相似文献   

11.
A small‐diameter nuclear magnetic resonance (NMR) logging tool has been developed and field tested at various sites in the United States and Australia. A novel design approach has produced relatively inexpensive, small‐diameter probes that can be run in open or PVC‐cased boreholes as small as 2 inches in diameter. The complete system, including surface electronics and various downhole probes, has been successfully tested in small‐diameter monitoring wells in a range of hydrogeological settings. A variant of the probe that can be deployed by a direct‐push machine has also been developed and tested in the field. The new NMR logging tool provides reliable, direct, and high‐resolution information that is of importance for groundwater studies. Specifically, the technology provides direct measurement of total water content (total porosity in the saturated zone or moisture content in the unsaturated zone), and estimates of relative pore‐size distribution (bound vs. mobile water content) and hydraulic conductivity. The NMR measurements show good agreement with ancillary data from lithologic logs, geophysical logs, and hydrogeologic measurements, and provide valuable information for groundwater investigations.  相似文献   

12.
ZVI‐Clay is an emerging remediation approach that combines zero‐valent iron (ZVI)‐mediated degradation and in situ stabilization of chlorinated solvents. Through use of in situ soil mixing to deliver reagents, reagent‐contaminant contact issues associated with natural subsurface heterogeneity are overcome. This article describes implementation, treatment performance, and reaction kinetics during the first year after application of the ZVI‐Clay remediation approach at Marine Corps Base Camp Lejeune, North Carolina. Primary contaminants included trichloroethylene, 1,1,2,2‐tetrachloroethane, and related natural degradation products. For the field application, 22,900 m3 of soils were treated to an average depth of 7.6 m with 2% ZVI and 3% sodium bentonite (dry weight basis). Performance monitoring included analysis of soil and water samples. After 1 year, total concentrations of chlorinated volatile organic compounds (CVOCs) in soil samples were decreased by site‐wide average and median values of 97% and >99%, respectively. Total CVOC concentrations in groundwater were reduced by average and median values of 81% and >99%, respectively. In several of the soil and groundwater monitoring locations, reductions in total CVOC concentrations of greater than 99.9% were apparent. Further reduction in concentrations of chlorinated solvents is expected with time. Pre‐ and post‐mixing average hydraulic conductivity values were 1.7 × 10?5 and 5.2 × 10?8 m/s, respectively, indicating a reduction of about 2.5 orders of magnitude. By achieving simultaneous contaminant mass depletion and hydraulic conductivity reduction, contaminant flux reductions of several orders of magnitude are predicted.  相似文献   

13.
Stone surfaces are sensitive to their environment. This means that they will often respond to exposure conditions by manifesting a change in surface characteristics. Such changes can be more than simply aesthetic, creating surface/subsurface heterogeneity in stone at the block scale, promoting stress gradients to be set up as surface response to, for example, temperature fluctuations, can diverge from subsurface response. This paper reports preliminary experiments investigating the potential of biofilms and iron precipitation as surface‐modifiers on stone, exploring the idea of block‐scale surface‐to‐depth heterogeneity, and investigating how physical alteration in the surface and near‐surface zone can have implications for subsurface response and potentially for long‐term decay patterns. Salt weathering simulations on fresh and surface‐modified stone suggest that even subtle surface modification can have significant implications for moisture uptake and retention, salt concentration and distribution from surface to depth, over the period of the experimental run. The accumulation of salt may increase the retention of moisture, by modifying vapour pressure differentials and the rate of evaporation. Temperature fluctuation experiments suggest that the presence of a biofilm can have an impact on energy transfer processes that occur at the stone surface (for example, buffering against temperature fluctuation), affecting surface‐to‐depth stress gradients. Ultimately, fresh and surface‐modified blocks mask different kinds of system, which respond to inputs differently because of different storage mechanisms, encouraging divergent behaviour between fresh and surface‐modified stone over time. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

14.
Nuclear magnetic resonance (NMR) logging provides a new means of estimating the hydraulic conductivity (K) of unconsolidated aquifers. The estimation of K from the measured NMR parameters can be performed using the Schlumberger‐Doll Research (SDR) equation, which is based on the Kozeny–Carman equation and initially developed for obtaining permeability from NMR logging in petroleum reservoirs. The SDR equation includes empirically determined constants. Decades of research for petroleum applications have resulted in standard values for these constants that can provide accurate estimates of permeability in consolidated formations. The question we asked: Can standard values for the constants be defined for hydrogeologic applications that would yield accurate estimates of K in unconsolidated aquifers? Working at 10 locations at three field sites in Kansas and Washington, USA, we acquired NMR and K data using direct‐push methods over a 10‐ to 20‐m depth interval in the shallow subsurface. Analysis of pairs of NMR and K data revealed that we could dramatically improve K estimates by replacing the standard petroleum constants with new constants, optimal for estimating K in the unconsolidated materials at the field sites. Most significant was the finding that there was little change in the SDR constants between sites. This suggests that we can define a new set of constants that can be used to obtain high resolution, cost‐effective estimates of K from NMR logging in unconsolidated aquifers. This significant result has the potential to change dramatically the approach to determining K for hydrogeologic applications.  相似文献   

15.
The hyporheic zone of riverbed sediments has the potential to attenuate nitrate from upwelling, polluted groundwater. However, the coarse‐scale (5–10 cm) measurement of nitrogen biogeochemistry in the hyporheic zone can often mask fine‐scale (<1 cm) biogeochemical patterns, especially in near‐surface sediments, leading to incomplete or inaccurate representation of the capacity of the hyporheic zone to transform upwelling NO3?. In this study, we utilised diffusive equilibrium in thin‐films samplers to capture high resolution (cm‐scale) vertical concentration profiles of NO3?, SO42?, Fe and Mn in the upper 15 cm of armoured and permeable riverbed sediments. The goal was to test whether nitrate attenuation was occurring in a sub‐reach characterised by strong vertical (upwelling) water fluxes. The vertical concentration profiles obtained from diffusive equilibrium in thin‐films samplers indicate considerable cm‐scale variability in NO3? (4.4 ± 2.9 mg N/L), SO42? (9.9 ± 3.1 mg/l) and dissolved Fe (1.6 ± 2.1 mg/l) and Mn (0.2 ± 0.2 mg/l). However, the overall trend suggests the absence of substantial net chemical transformations and surface‐subsurface water mixing in the shallow sediments of our sub‐reach under baseflow conditions. The significance of this is that upwelling NO3?‐rich groundwater does not appear to be attenuated in the riverbed sediments at <15 cm depth as might occur where hyporheic exchange flows deliver organic matter to the sediments for metabolic processes. It would appear that the chemical patterns observed in the shallow sediments of our sub‐reach are not controlled exclusively by redox processes and/or hyporheic exchange flows. Deeper‐seated groundwater fluxes and hydro‐stratigraphy may be additional important drivers of chemical patterns in the shallow sediments of our study sub‐reach. © 2015 The Authors. Hydrological Processes Published by John Wiley & Sons Ltd.  相似文献   

16.
The Membrane‐Interface Probe and Hydraulic Profiling Tool (MiHpt) is a direct push probe that includes both the membrane interface probe (MIP) and hydraulic profiling tool (HPT) sensors. These direct push logging tools were previously operated as separate logging systems for subsurface investigation in unconsolidated formations. By combining these two probes into one logging system the field operator obtains useful data about the distribution of both volatile organic contaminants (VOCs) and relative formation permeability in a single boring. MiHpt logging was conducted at a chlorinated VOC contaminated site in Skuldelev, Denmark, to evaluate performance of the system. Formation cores and discrete interval slug tests are used to assess use of the HPT and electrical conductivity (EC) logs for lithologic and hydrostratigraphic interpretation. Results of soil and groundwater sample analyses are compared to the adjacent MiHpt halogen specific detector (XSD) logs to evaluate performance of the system to define contaminant distribution and relative concentrations for the observed VOCs. Groundwater profile results at moderate to highly contaminated locations were found to correlate well with the MiHpt‐XSD detector responses. In general, soil sample results corresponded with detector responses. However, the analyses of saturated coarse‐grained soils at the site proved to be unreliable as demonstrated by high RPDs for duplicate samples. The authors believe that this is due to pore water drainage observed from these cores during sampling. Additionally, a cross section of HPT pressure and MiHpt‐XSD detector logs provides insight into local hydrostratigraphy and formation control on contaminant migration.  相似文献   

17.
Stream chemistry is often used to infer catchment‐scale biogeochemical processes. However, biogeochemical cycling in the near‐stream zone or hydrologically connected areas may exert a stronger influence on stream chemistry compared with cycling processes occurring in more distal parts of the catchment, particularly in dry seasons and in dry years. In this study, we tested the hypotheses that near‐stream wetland proportion is a better predictor of seasonal (winter, spring, summer, and fall) stream chemistry compared with whole‐catchment averages and that these relationships are stronger in dryer periods with lower hydrologic connectivity. We evaluated relationships between catchment wetland proportion and 16‐year average seasonal flow‐weighted concentrations of both biogeochemically active nutrients, dissolved organic carbon (DOC), nitrate (NO3‐N), total phosphorus (TP), as well as weathering products, calcium (Ca), magnesium (Mg), at ten headwater (<200 ha) forested catchments in south‐central Ontario, Canada. Wetland proportion across the entire catchment was the best predictor of DOC and TP in all seasons and years, whereas predictions of NO3‐N concentrations improved when only the proportion of wetland within the near‐stream zone was considered. This was particularly the case during dry years and dry seasons such as summer. In contrast, Ca and Mg showed no relationship with catchment wetland proportion at any scale or in any season. In forested headwater catchments, variable hydrologic connectivity of source areas to streams alters the role of the near‐stream zone environment, particularly during dry periods. The results also suggest that extent of riparian zone control may vary under changing patterns of hydrological connectivity. Predictions of biogeochemically active nutrients, particularly NO3‐N, can be improved by including near‐stream zone catchment morphology in landscape models.  相似文献   

18.
A common factor in landslide activation (or reactivation) is subsurface moisture and associated pore pressure variations linked to rainfall. Monitoring of these subsurface hydrogeological processes is necessary to improve our understanding of water‐induced landslide activation. Geophysical approaches, electrical methods in particular, are increasingly being applied to landslide monitoring because they provide non‐invasive spatial information in heterogeneous subsurface environments that can be difficult to characterise using surface observations or intrusive sampling alone. Electrical techniques are sensitive to changing subsurface moisture conditions, and have proven to be a useful tool for investigating the hydrogeology of natural and engineered slopes. The objectives of this investigation were to further develop electrical resistance monitoring for slope stability assessment, and to validate the approach at an intermittently‐active UK landslide system to advance the understanding of complex landslide activation mechanisms. A long‐term transfer resistance dataset was collected from a grid of electrodes to allow spatial monitoring of the landslide. These data were interpreted using a synthesis of rainfall, temperature, GPS and piezometric records. The resistance data were corrected for seasonal temperature variations and electrode movements were monitored, as these processes were shown to mask moisture related changes. Results reveal that resistance monitoring is sensitive to soil moisture accumulation, including changes in piezometric levels, and can be used to study the principal activation mechanism of slow‐moving shallow earthflows. Spatial monitoring using resistance maps was shown to be particularly valuable as it revealed the evolution of subsurface moisture distribution, in the lead up to landslide activation. Key benefits of this approach are that it provides a simple, rapid and non‐invasive means of spatially monitoring subsurface moisture dynamics linked to landslide activation at high‐temporal resolution. Crucially, it provides a means of monitoring subsurface hydraulic changes in the build‐up to slope failure, thereby contributing to early warning of landslide events. Copyright © 2018 John Wiley & Sons, Ltd.  相似文献   

19.
Estimating permeability from NMR well logs or mobile NMR core scanner data is an attractive method as the measurements can be performed directly in the formation or on fresh cores right after drilling. Furthermore, the method is fast and non-destructive. Compared to T 1 relaxation times, commonly measured T 2 distributions are influenced by external and internal magnetic field gradients. We performed two-dimensional T 1 and T 2 relaxation experiments on samples of Rhaetian sandstone, a rock with low porosity and small pore radii, using a mobile NMR core scanner which operates within a nearly homogeneous static magnetic field. Because small pore sizes are associated with high internal magnetic field gradients, standard methods from NMR logging in the oil industry cannot be applied for accurate permeability prediction. Therefore, a new model theory was developed, which describes the pore radius dependence of the surface relaxivity ρ 2 by both an analytical and a more practical empirical equation. Using corrected ρ 2 values, permeability can be predicted accurately from the logarithmic mean of the T 2 distribution and the physically based Kozeny-Carman equation. Additional core plug measurements of structural parameters such as porosity, permeability, specific inner surface area and pore radius distributions supported the NMR results.  相似文献   

20.
Phytoscreening has been proven to rapidly delineate subsurface contaminant plumes for semiquantitative site assessment, with minimal impact to property or ecology through the collection and analysis of tree cores. Here, three phytoscreening methods were applied concurrently to identify multiple chlorinated volatile organic compounds (cVOCs) in a phytoremediation treatment system at a contaminated industrial facility. Tree coring, in planta gas chromatography–mass spectrometry (GC‐MS), and in planta passive sampling showed general agreement, with the in planta GC‐MS providing the quickest but least quantitative results. The portable GC‐MS sampling and analysis method identified six cVOCs in the xylem of hybrid poplars (Populus sp.) in the phytoremediation plot. These real‐time data can permit onsite identification and delineation of the contaminants, allowing for adaptive sampling during a single mobilization to a site. The in vitro methods provided quantitative data across two sampling campaigns, as relative cVOC concentrations remained similar between the two trips, despite a decrease in absolute cVOC concentrations from August to October. Overall, this research demonstrates the advantages and limitations of three phytoscreening techniques.  相似文献   

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