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1.
The USGS conducted a geophysical investigation in support of a U.S. Naval Facilities Engineering Command, Southern Division field-scale biostimulation pilot project at Anoka County Riverfront Park (ACP), down-gradient of the Naval Industrial Reserve Ordnance Plant, Fridley, Minnesota. The goal of the pilot project is to evaluate subsurface injection of vegetable oil emulsion (VOE) to stimulate microbial degradation of chlorinated hydrocarbons. To monitor the emplacement and movement of the VOE and changes in water chemistry resulting from VOE dissolution and/or enhanced biological activity, the USGS acquired cross-hole radar zero-offset profiles, travel-time tomograms, and borehole geophysical logs during five site visits over 1.5 years. Analysis of pre- and postinjection data sets using petrophysical models developed to estimate VOE saturation and changes in total dissolved solids provides insights into the spatial and temporal distribution of VOE and ground water with altered chemistry. Radar slowness-difference tomograms and zero-offset slowness profiles indicate that the VOE remained close to the injection wells, whereas radar attenuation profiles and electromagnetic induction logs indicate that bulk electrical conductivity increased down-gradient of the injection zone, diagnostic of changing water chemistry. Geophysical logs indicate that some screened intervals were located above or below zones of elevated dissolved solids; hence, the geophysical data provide a broader context for interpretation of water samples and evaluation of the biostimulation effort. Our results include (1) demonstration of field and data analysis methods for geophysical monitoring of VOE biostimulation and (2) site-specific insights into the spatial and temporal distributions of VOE at the ACP.  相似文献   

2.
Electrical geophysical methods, including electrical resistivity, time‐domain induced polarization, and complex resistivity, have become commonly used to image the near subsurface. Here, we outline their utility for time‐lapse imaging of hydrological, geochemical, and biogeochemical processes, focusing on new instrumentation, processing, and analysis techniques specific to monitoring. We review data collection procedures, parameters measured, and petrophysical relationships and then outline the state of the science with respect to inversion methodologies, including coupled inversion. We conclude by highlighting recent research focused on innovative applications of time‐lapse imaging in hydrology, biology, ecology, and geochemistry, among other areas of interest. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

3.
ZVI‐Clay is an emerging remediation approach that combines zero‐valent iron (ZVI)‐mediated degradation and in situ stabilization of chlorinated solvents. Through use of in situ soil mixing to deliver reagents, reagent‐contaminant contact issues associated with natural subsurface heterogeneity are overcome. This article describes implementation, treatment performance, and reaction kinetics during the first year after application of the ZVI‐Clay remediation approach at Marine Corps Base Camp Lejeune, North Carolina. Primary contaminants included trichloroethylene, 1,1,2,2‐tetrachloroethane, and related natural degradation products. For the field application, 22,900 m3 of soils were treated to an average depth of 7.6 m with 2% ZVI and 3% sodium bentonite (dry weight basis). Performance monitoring included analysis of soil and water samples. After 1 year, total concentrations of chlorinated volatile organic compounds (CVOCs) in soil samples were decreased by site‐wide average and median values of 97% and >99%, respectively. Total CVOC concentrations in groundwater were reduced by average and median values of 81% and >99%, respectively. In several of the soil and groundwater monitoring locations, reductions in total CVOC concentrations of greater than 99.9% were apparent. Further reduction in concentrations of chlorinated solvents is expected with time. Pre‐ and post‐mixing average hydraulic conductivity values were 1.7 × 10?5 and 5.2 × 10?8 m/s, respectively, indicating a reduction of about 2.5 orders of magnitude. By achieving simultaneous contaminant mass depletion and hydraulic conductivity reduction, contaminant flux reductions of several orders of magnitude are predicted.  相似文献   

4.
Between the years 2008 and 2013, approximately 67 kilotons of CO2 have been injected at the Ketzin site, Germany. As part of the geophysical monitoring programme, time‐lapse electrical resistivity tomography has been applied using crosshole and surface‐downhole measurements of electrical resistivity tomography. The data collection of electrical resistivity tomography is partly based on electrodes that are permanently installed in three wells at the site (one injection well and two observation wells). Both types of ERT measurements consistently show the build‐up of a CO2‐related resistivity signature near the injection point. Based on the imaged resistivity changes and a petrophysical model, CO2 saturation levels are estimated. These CO2 saturations are interpreted in conjunction with CO2 saturations inferred from neutron‐gamma loggings. Apart from the CO2–brine substitution response in the observed resistivity changes, significant imprints from the dynamic behaviour of the CO2 in the reservoir are observed.  相似文献   

5.
Salt water intrusion models are commonly used to support groundwater resource management in coastal aquifers. Concentration data used for model calibration are often sparse and limited in spatial extent. With airborne and ground‐based electromagnetic surveys, electrical resistivity models can be obtained to provide high‐resolution three‐dimensional models of subsurface resistivity variations that can be related to geology and salt concentrations on a regional scale. Several previous studies have calibrated salt water intrusion models with geophysical data, but are typically limited to the use of the inverted electrical resistivity models without considering the measured geophysical data directly. This induces a number of errors related to inconsistent scales between the geophysical and hydrologic models and the applied regularization constraints in the geophysical inversion. To overcome these errors, we perform a coupled hydrogeophysical inversion (CHI) in which we use a salt water intrusion model to interpret the geophysical data and guide the geophysical inversion. We refer to this methodology as a Coupled Hydrogeophysical Inversion‐State (CHI‐S), in which simulated salt concentrations are transformed to an electrical resistivity model, after which a geophysical forward response is calculated and compared with the measured geophysical data. This approach was applied for a field site in Santa Cruz County, California, where a time‐domain electromagnetic (TDEM) dataset was collected. For this location, a simple two‐dimensional cross‐sectional salt water intrusion model was developed, for which we estimated five uniform aquifer properties, incorporating the porosity that was also part of the employed petrophysical relationship. In addition, one geophysical parameter was estimated. The six parameters could be resolved well by fitting more than 300 apparent resistivities that were comprised by the TDEM dataset. Except for three sounding locations, all the TDEM data could be fitted close to a root‐mean‐square error of 1. Possible explanations for the poor fit of these soundings are the assumption of spatial uniformity, fixed boundary conditions and the neglecting of 3D effects in the groundwater model and the TDEM forward responses.  相似文献   

6.
Major challenges exist in delineating bedrock fracture zones because these cause abrupt changes in geological and hydrogeological properties over small distances. Borehole observations cannot sufficiently capture heterogeneity in these systems. Geophysical techniques offer the potential to image properties and processes in between boreholes. We used three‐dimensional cross borehole electrical resistivity tomography (ERT) in a 9 m (diameter) × 15 m well field to capture high‐resolution flow and transport processes in a fractured mudstone contaminated by chlorinated solvents, primarily trichloroethylene. Conductive (sodium bromide) and resistive (deionized water) injections were monitored in seven boreholes. Electrode arrays with isolation packers and fluid sampling ports were designed to enable acquisition of ERT measurements during pulsed tracer injections. Fracture zone locations and hydraulic pathways inferred from hydraulic head drawdown data were compared with electrical conductivity distributions from ERT measurements. Static ERT imaging has limited resolution to decipher individual fractures; however, these images showed alternating conductive and resistive zones, consistent with alternating laminated and massive mudstone units at the site. Tracer evolution and migration was clearly revealed in time‐lapse ERT images and supported by in situ borehole vertical apparent conductivity profiles collected during the pulsed tracer test. While water samples provided important local information at the extraction borehole, ERT delineated tracer migration over spatial scales capturing the primary hydrogeological heterogeneity controlling flow and transport. The fate of these tracer injections at this scale could not have been quantified using borehole logging and/or borehole sampling methods alone.  相似文献   

7.
The reliable characterization of subsurface contamination of spatially extended contaminated sites is a challenging task, especially with an unknown history of land use. Conventional technologies often fail due to temporal and financial constraints and thus hinder the redevelopment of abandoned areas in particular. Here we compare two site screening techniques that can be applied quickly at relatively low cost, namely Direct Push (DP)‐based groundwater sampling and tree core sampling. The effectiveness of both methods is compared for a rural megasite contaminated with chlorinated hydrocarbons. Unexpected pollution hot spots could be identified using both of these methods, while tree coring even enabled the delineation of the contaminant plume flowing into an adjacent wetland inaccessible for DP units. Both methods showed a good agreement in revealing the spatial pattern of the contamination. The correlation between groundwater concentrations and equivalent concentrations in wood was linear and highly significant for trichloroethene. Correlation was less obvious for its metabolite cis‐dichloroethene, but still significant. As outcome of our study we recommend tree coring and for initial screening in combination with a DP sampling to retrieve quantitative data on groundwater pollutants in order to assess the contamination situation of a non‐ or only partly investigated site. The subsequent placement of monitoring wells for long‐term monitoring of contamination levels is recommended. A combination of methods would achieve more relevant information at comparable or possibly even lower efforts in comparison to a conventional site investigation.  相似文献   

8.
The use of electrical resistivity tomography (ERT; non‐intrusive geophysical technique) was assessed to identify the hydrogeological conditions at a surface water/groundwater test site in the southern Black Forest, Germany. A total of 111 ERT transects were measured, which adopted electrode spacings from 0·5 to 5 m as well as using either Wenner or dipole‐dipole electrode arrays. The resulting two‐dimensional (2D) electrical resistivity distributions are related to the structure and water content of the subsurface. The images were interpreted with respect to previous classical hillslope hydrological investigations within the same research basin using both tracer methods and groundwater level observations. A raster‐grid survey provided a quasi 3D resistivity pattern of the floodplain. Strong structural heterogeneity of the subsurface could be demonstrated, and (non)connectivities between surface and subsurface bodies were mapped. Through the spatial identification of likely flow pathways and source areas of runoff, the deep groundwater within the steeper valley slope seems to be much more connected to runoff generation processes within the valley floodplain than commonly credited in such environmental circumstances. Further, there appears to be no direct link between subsurface water‐bodies adjacent to the stream channel. Deep groundwater sources are also able to contribute towards streamflow from exfiltration at the edge of the floodplain as well as through the saturated areas overlying the floodplain itself. Such exfiltrated water then moves towards the stream as channelized surface flow. These findings support previous tracer investigations which showed that groundwater largely dominates the storm hydrograph of the stream, but the source areas of this component were unclear without geophysical measurements. The work highlighted the importance of using information from previous, complementary hydrochemical and hydrometric research campaigns to better interpret the ERT measurements. On the other hand, the ERT can provide a better spatial understanding of existing hydrochemical and hydrometric data. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

9.
Successful in situ groundwater remediation relies on the adequate distribution of treatment materials within the subsurface. Zero‐valent iron (ZVI) is widely used for the remediation of soils contaminated with chlorinated organic compounds. Because ZVI is a solid, various techniques are used to distribute ZVI in the subsurface; however, a major uncertainty in this process involves determining the distribution of the iron during emplacement. A method of mapping the distribution of ferromagnetic material such as ZVI is by magnetic susceptibility (MS), a novel approach that is highly sensitive, quantitative, objective, and easily applied in field. The method has been tested in the laboratory on synthetic cores containing EHC®, an organic amendment containing 40 to 50% ZVI, using an MS meter with two types of sensors (loop and handheld). Both sensors have high sensitivity (e.g., 1% disseminated EHC is easily detected), whereas the hand‐held sensor has greater spatial resolution (e.g., differences are notable on a scale of 1 cm). Following the laboratory studies, the handheld instrument was used to perform field measurements for multiple pilot studies and a full‐scale application of EHC using various delivery methods (pneumatic fracturing, hydraulic fracturing, and direct injection) to construct a biobarrier at a field remedial site. The MS method has proven invaluable in quantifying amendment distribution and ensuring appropriate application of this remedial technology.  相似文献   

10.
A groundwater recharge process of heterogeneous hard rock aquifer in the Moole Hole experimental watershed, south India, is being studied to understand the groundwater flow behaviour. Significant seasonal variations in groundwater level are observed in boreholes located at the outlet area indicating that the recharge process is probably taking place below intermittent streams. In order to localize groundwater recharge zones and to optimize implementation of boreholes, a geophysical survey was carried out during and after the 2004 monsoon across the outlet zone. Magnetic resonance soundings (MRS) have been performed to characterize the aquifer and measure groundwater level depletion. The results of MRS are consistent with the observation in boreholes, but it suffers from degraded lateral resolution. A better resolution of the regolith/bedrock interface is achieved using electrical resistivity tomography (ERT). ERT results are confirmed by resistivity logging in the boreholes. ERT surveys have been carried out twice—before and during the monsoon—across the stream area. The major feature of recharge is revealed below the stream with a decrease by 80% of the calculated resistivity. The time‐lapse ERT also shows unexpected variations at a depth of 20 m below the slopes that could have been interpreted as a consequence of a deep seasonal water flow. However, in this area time‐lapse ERT does not match with borehole data. Numerical modelling shows that in the presence of a shallow water infiltration, an inversion artefact may take place thus limiting the reliability of time‐lapse ERT. A combination of ERT with MRS provides valuable information on structure and aquifer properties respectively, giving a clue for a conceptual model of the recharge process: infiltration takes place in the conductive fractured‐fissured part of the bedrock underlying the stream and clayey material present on both sides slows down its lateral dissipation. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

11.
Heterogeneity of hydraulic properties in aquifers may lead to contaminants residing in lower‐permeability zones where it is difficult to deliver remediation amendments using conventional injection processes. The focus of this study is to examine use of a shear‐thinning fluid (STF) to improve the uniformity of remedial amendment distribution within a heterogeneous aquifer. Previous studies have demonstrated the significant potential of STFs for improving remedial amendment delivery in heterogeneous aquifers, but quantitative evaluation of these improvements from field applications is lacking. A field‐scale test was conducted that compares data from successive injection of a tracer in water followed by injection of a tracer in an STF to evaluate the impact of the STF on tracer distribution uniformity in the presence of permeability contrasts within the targeted injection zone. Data from tracer breakthrough at multiple depth‐discrete monitoring intervals and electrical resistivity tomography (ERT) showed that inclusion of STF in the injection solution improved the distribution of the injected fluid within the targeted treatment zone. One improvement was a reduction in the movement of injected fluids through high‐permeability pathways, as evidenced by slower breakthrough of tracer at monitoring locations where breakthrough in baseline tracer‐only injection data was faster. In addition, STF‐amended injection solutions arrived faster and to a greater extent in monitoring locations within low‐permeability zones. ERT data showed that the STF injection covered a higher percentage of a two‐dimensional cross section within the injection interval between the injection well and a monitoring well about 3 m away.  相似文献   

12.
张弛  董毅 《地球物理学报》2015,58(8):2718-2729
微生物广泛参与了其所处地质环境的物理和化学性质改造过程.监控微生物与地质介质之间相互作用的过程并了解其机制对近地面环境工程中土壤及地下水污染整治等实际应用有着至关重要的作用.地球物理勘测成像技术不仅能够在传统应用中测量和表征地表以下的物理特性变化,大量直接有效的证据表明这些方法还可以捕获孔隙介质中的生物地球化学变化的动态过程,包括监测微生物、微生物活动以及它们与矿物之间的相互作用.生物地球物理(Biogeophysics)作为勘探地球物理的一个新兴分支学科,包含了微生物学、生物地球科学以及地球物理勘测等多个学科,侧重于研究微生物与地质介质相互作用对地球物理场的影响.过去十几年在生物地球物理领域的研究充分表明和验证了地球物理勘测方法的独特优点(最小化侵入、时空连续及跨尺度运用),并为将传统勘测方法用于探索跨时间空间各尺度的地下生物地球化学动态过程提供了理论及实验依据.本篇综述将系统介绍生物地球物理学科的理论背景、发展和研究前沿.首先讨论微生物及其活动引起的孔隙介质中物理化学性质的变化.其次,将侧重于探讨微生物活动对包括地电法、电磁法、探地雷达以及地震法等不同地球物理场的响应.最后将讨论生物地球物理领域的机遇、挑战和潜在应用.  相似文献   

13.
Remediation of subsurface contamination requires an understanding of the contaminant (history, source location, plume extent and concentration, etc.), and, knowledge of the spatial distribution of hydraulic conductivity (K) that governs groundwater flow and solute transport. Many methods exist for characterizing K heterogeneity, but most if not all methods require the collection of a large number of small‐scale data and its interpolation. In this study, we conduct a hydraulic tomography survey at a highly heterogeneous glaciofluvial deposit at the North Campus Research Site (NCRS) located at the University of Waterloo, Waterloo, Ontario, Canada to sequentially interpret four pumping tests using the steady‐state form of the Sequential Successive Linear Estimator (SSLE) ( Yeh and Liu 2000 ). The resulting three‐dimensional (3D) K distribution (or K‐tomogram) is compared against: ( 1 ) K distributions obtained through the inverse modeling of individual pumping tests using SSLE, and ( 2 ) effective hydraulic conductivity (Keff) estimates obtained by automatically calibrating a groundwater flow model while treating the medium to be homogeneous. Such a Keff is often used for designing remediation operations, and thus is used as the basis for comparison with the K‐tomogram. Our results clearly show that hydraulic tomography is superior to the inversions of single pumping tests or Keff estimates. This is particularly significant for contaminated sites where an accurate representation of the flow field is critical for simulating contaminant transport and injection of chemical and biological agents used for active remediation of contaminant source zones and plumes.  相似文献   

14.
We implemented multiple independent field techniques to determine the direction and velocity of groundwater flow at a specific stream reach in a glacier forefield. Time‐lapse experiments were conducted using two electrical resistivity tomography (ERT) lines installed in a cross pattern. A circular array of groundwater tubes was also installed to monitor groundwater flow via discrete salt injections. Both inter‐borehole and ERT results confirmed this stream section as a losing reach and enabled quantification of the flow direction. Both techniques yielded advection velocities varying between 5.7 and 21.8 m/day. Estimates of groundwater flow direction and velocity indicated that groundwater infiltrates from the stream nearby and not from the adjacent lateral moraine. Groundwater age estimated from radon concentration measurements supported this hypothesis. Despite uncertainties inherent to each of the methods deployed, the combination of multiple field techniques allowed drawing consistent conclusions about local groundwater flow. We thus regard our multi‐method approach as a reliable way to characterize the two‐dimensional groundwater flow at sites where more invasive groundwater investigation techniques are difficult to carry out and local heterogeneities can make single measurements unreliable. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

15.
Delineating hydrologic and pedogenic factors influencing groundwater flow in riparian zones is central in understanding pathways of water and nutrient transport. In this study, we combined two‐dimensional time‐lapse electrical resistivity imaging (ERI) (depth of investigation approximately 2 m) with hydrometric monitoring to examine hydrological processes in the riparian area of FD‐36, a small (0.4 km2) agricultural headwater basin in the Valley and Ridge region of east‐central Pennsylvania. We selected two contrasting study sites, including a seep with groundwater discharge and an adjacent area lacking such seepage. Both sites were underlain by a fragipan at 0.6 m. We then monitored changes in electrical resistivity, shallow groundwater, and nitrate‐N concentrations as a series of storms transitioned the landscape from dry to wet conditions. Time‐lapse ERI revealed different resistivity patterns between seep and non‐seep areas during the study period. Notably, the seep displayed strong resistivity reductions (～60%) along a vertically aligned region of the soil profile, which coincided with strong upward hydraulic gradients recorded in a grid of nested piezometers (0.2‐ and 0.6‐m depth). These patterns suggested a hydraulic connection between the seep and the nitrate‐rich shallow groundwater system below the fragipan, which enabled groundwater and associated nitrate‐N to discharge through the fragipan to the surface. In contrast, time‐lapse ERI indicated no such connections in the non‐seep area, with infiltrated rainwater presumably perched above the fragipan. Results highlight the value of pairing time‐lapse ERI with hydrometric and water quality monitoring to illuminate possible groundwater and nutrient flow pathways to seeps in headwater riparian areas.  相似文献   

16.
This paper is presenting the results from near-surface geophysical surveys near the waste site of Hoc Mon in southern Vietnam where leachate contamination has been recognized at the surface. Using EM and GPR surveys, we were able to determine the lateral extent of a contaminated area of high electrical conductivity and have identified channels that concentrate the contaminant flow. The simple relationship between the electrical resistivity and the leachate concentration is suggested and estimated the in situ leachate concentration from the inversion of the EM data; values are as high as 40%. Thanks to a permeability barrier leachate flow is confined to the shallow subsurface, making it easier to apply possible site remediation projects.  相似文献   

17.
The complex ecohydrological processes of rangelands can be studied through the framework of ecological sites (ESs) or hillslope‐scale soil–vegetation complexes. High‐quality hydrologic field investigations are needed to quantitatively link ES characteristics to hydrologic function. Geophysical tools are useful in this context because they provide valuable information about the subsurface at appropriate spatial scales. We conducted 20 field experiments in which we deployed time‐lapse electrical resistivity tomography (ERT), variable intensity rainfall simulation, ground‐penetrating radar (GPR), and seismic refraction, on hillslope plots at five different ESs within the Upper Crow Creek Watershed in south‐east Wyoming. Surface runoff was measured using a precalibrated flume. Infiltration data from the rainfall simulations, coupled with site‐specific resistivity–water content relationships and ERT datasets, were used to spatially and temporally track the progression of the wetting front. First‐order constraints on subsurface structure were made at each ES using the geophysical methods. Sites ranged from infiltrating 100% of applied rainfall to infiltrating less than 60%. Analysis of covariance results indicated significant differences in the rate of wetting front progression, ranging from 0.346 m min?1/2 for sites with a subsurface dominated by saprolitic material to 0.156 m min?1/2 for sites with a well‐developed soil profile. There was broad agreement in subsurface structure between the geophysical methods with GPR typically providing the most detail. Joint interpretation of the geophysics showed that subsurface features such as soil layer thickness and the location of subsurface obstructions such as granite corestones and material boundaries had a large effect on the rate of infiltration and subsurface flow processes. These features identified through the geophysics varied significantly by ES. By linking surface hydrologic information from the rainfall simulations with subsurface information provided by the geophysics, we can characterize the ES‐specific hydrologic response. Both surface and subsurface flow processes differed among sites and are directly linked to measured characteristics.  相似文献   

18.
Sudicky EA  Illman WA 《Ground water》2011,49(5):630-648
This article summarizes several of many field-based studies of subsurface contaminant transport conducted over the last 30 years at the Canadian Forces Base (CFB) Borden site. The field research initially consisted of extensive monitoring of a leachate plume from an abandoned landfill and its analytical and numerical modeling. Lessons learned from these initial studies led to the execution and interpretation of a variety of tracer tests involving conservative and reactive/organic solutes tests performed at various scales. The lessons learned from these tracer tests revealed a number of deficiencies in classical theories of contaminant dispersion and reaction processes as they occur in groundwater, and thus spawned a new era of process-oriented research within the hydrogeological community. The extensively monitored tracer tests were followed by controlled spills of organic contaminants to observe their subsurface movement and distribution as well as the emplacement of a variety of contaminant sources in the saturated and unsaturated zones to study the ambient transport of contaminants. The controlled spills and emplaced sources of various contaminants were then utilized for testing various active and passive remediation technologies. These studies have led to fundamental insights and lessons learned that have significantly contributed to research on contaminant transport in both the saturated and unsaturated zones. Over the years, data generated by the University of Waterloo (UW) researchers and their collaborators continues to be examined by various research groups and has led to additional new insights on subsurface transport of various chemicals.  相似文献   

19.
We conducted an integrated groundwater–surface water monitoring programme in a 3.2‐km2 experimental catchment in the Scottish Highlands by sampling all springs, seepages, and wells in six, spatially extensive synoptic surveys over a 2‐year period. The catchment has been glaciated, with steep hillslopes and a flat valley bottom. There is around 70% glacial drift cover in lower areas. The solid geology, which outcrops at higher elevations, is granite and metamorphic schist. The springs and seepages generally occur at the contact between the solid geology and drift or at breaks of slopes in the valley bottom. Samples were analysed for stable isotopes, Gran alkalinity and electrical conductivity. Despite the surveys encompassing markedly different antecedent conditions, the isotopic composition of groundwater at each location exhibited limited temporal variability, resulting in a remarkable persistence of spatial patterns indicating well‐mixed shallow, groundwater stores. Moreover, line‐conditioned excess values derived from the isotope data indicated no evidence of fractionation affecting the groundwater, which suggests that most recharge occurs in winter. The alkalinity and electrical conductivity of groundwater reflected geological differences in the catchment, being highest where more weatherable calcareous rocks outcrop at higher altitudes in the catchment. Springs draining these areas also had the most variable isotope composition, which indicated that they have shorter residence times than the drift covered part of the catchment. The study showed that even in geologically heterogeneous upland catchments, groundwater can be characterized by a consistent isotopic composition, reflecting rapid mixing in the recharge zone. Our work, thus, emphasizes the critical role of groundwater in upland catchments and provides tracer data that can help constrain quantitative groundwater models.  相似文献   

20.
The results of comprehensive field testing of on‐site vapor‐phase‐based groundwater monitoring methods are presented to demonstrate their utility as a robust and cost‐effective approach for rapidly obtaining volatile organic compounds (VOCs) concentration data from a monitoring well. These methods—which rely on sensitive, commercially available field equipment to analyze vapor in equilibrium with groundwater—proved easy to implement and can be tailored to site‐specific needs, including multilevel sampling. During field testing, low‐flow groundwater concentrations could be reasonably estimated using submerged passive vapor diffusion samplers or field equilibration of collected groundwater (R2 = 0.85 to 0.96). These two methods are not as reliant on in‐well mixing to overcome vertical stratification within wells as simpler headspace methods. The importance of well and aquifer‐specific factors on concentration data (and therefore method selection) is highlighted, including the effect of changing in‐well patterns due to seasonal temperature gradients. Results indicated that vertical stratification was relatively limited within the set of wells included in these studies, resulting in similar performance for short depth‐discrete passive vapor diffusion samplers (constructed from 40‐mL vials) and longer samplers (2.5 to 5 feet in length) designed to cover a larger portion of the screened interval. A year‐long, multi‐event evaluation demonstrated that vapor‐phase‐based monitoring methods are no more variable than conventional groundwater monitoring methods, with both types subject to similar spatial and temporal variability that can be difficult to reduce. Vapor sampling methods represent a promising approach for estimation of groundwater concentrations by reducing the cost liabilities associated with monitoring while providing a more sustainable approach.  相似文献   

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